JP4979126B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
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- JP4979126B2 JP4979126B2 JP2007187929A JP2007187929A JP4979126B2 JP 4979126 B2 JP4979126 B2 JP 4979126B2 JP 2007187929 A JP2007187929 A JP 2007187929A JP 2007187929 A JP2007187929 A JP 2007187929A JP 4979126 B2 JP4979126 B2 JP 4979126B2
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- hair
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- hair cosmetic
- oil
- gloss
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- 239000003676 hair preparation Substances 0.000 title description 13
- 239000000284 extract Substances 0.000 claims description 33
- 239000002537 cosmetic Substances 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 26
- 235000007164 Oryza sativa Nutrition 0.000 claims description 14
- 235000009566 rice Nutrition 0.000 claims description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 235000018597 common camellia Nutrition 0.000 claims description 11
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 11
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 8
- 150000007524 organic acids Chemical class 0.000 claims description 6
- 239000008158 vegetable oil Substances 0.000 claims description 6
- 240000001548 Camellia japonica Species 0.000 claims description 4
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 4
- 235000015165 citric acid Nutrition 0.000 claims description 4
- 239000004220 glutamic acid Substances 0.000 claims description 4
- 235000013922 glutamic acid Nutrition 0.000 claims description 4
- 239000004310 lactic acid Substances 0.000 claims description 4
- 235000014655 lactic acid Nutrition 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 235000005985 organic acids Nutrition 0.000 claims description 4
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims 1
- 241000209094 Oryza Species 0.000 description 13
- 239000003921 oil Substances 0.000 description 9
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- 239000000243 solution Substances 0.000 description 9
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- -1 amide lipids Chemical class 0.000 description 7
- 241000272185 Falco Species 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 240000007049 Juglans regia Species 0.000 description 5
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- 238000013329 compounding Methods 0.000 description 5
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- 238000012360 testing method Methods 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 235000020234 walnut Nutrition 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 206010020112 Hirsutism Diseases 0.000 description 4
- 235000019482 Palm oil Nutrition 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
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- 229920001296 polysiloxane Polymers 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000003699 hair surface Effects 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 239000000419 plant extract Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
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- 241000580955 Sapindus mukorossi Species 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000013736 caramel Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 108090000765 processed proteins & peptides Proteins 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- QLAVHMSZFMBGNY-UHFFFAOYSA-N 3-chloro-5-methyl-1,2-thiazol-4-one Chemical compound CC1SN=C(Cl)C1=O QLAVHMSZFMBGNY-UHFFFAOYSA-N 0.000 description 1
- DLICJXPMMTZITN-UHFFFAOYSA-N 3-methyl-1,2-thiazol-4-one Chemical compound CC1=NSCC1=O DLICJXPMMTZITN-UHFFFAOYSA-N 0.000 description 1
- YDNKGFDKKRUKPY-JHOUSYSJSA-N C16 ceramide Natural products CCCCCCCCCCCCCCCC(=O)N[C@@H](CO)[C@H](O)C=CCCCCCCCCCCCCC YDNKGFDKKRUKPY-JHOUSYSJSA-N 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 1
- CRJGESKKUOMBCT-VQTJNVASSA-N N-acetylsphinganine Chemical compound CCCCCCCCCCCCCCC[C@@H](O)[C@H](CO)NC(C)=O CRJGESKKUOMBCT-VQTJNVASSA-N 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- 206010044625 Trichorrhexis Diseases 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940069780 barley extract Drugs 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940106189 ceramide Drugs 0.000 description 1
- ZVEQCJWYRWKARO-UHFFFAOYSA-N ceramide Natural products CCCCCCCCCCCCCCC(O)C(=O)NC(CO)C(O)C=CCCC=C(C)CCCCCCCCC ZVEQCJWYRWKARO-UHFFFAOYSA-N 0.000 description 1
- 229940081733 cetearyl alcohol Drugs 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 150000001875 compounds Chemical group 0.000 description 1
- 108010006161 conchiolin Proteins 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- MNAZHGAWPCLLGX-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C MNAZHGAWPCLLGX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- 239000010497 wheat germ oil Substances 0.000 description 1
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- Cosmetics (AREA)
Description
本発明は、毛髪のパサつきを抑えてしっとりさせ、毛髪にすべり性、柔軟性、ツヤを与えることが可能な毛髪化粧料に関する。 The present invention relates to a hair cosmetic that can suppress hairiness and moisturize the hair, and can provide slipperiness, flexibility, and gloss.
毛髪は、パーマネントウェーブやブリーチ・ヘアカラー、紫外線、ドライヤーの熱など化学的または物理的刺激により損傷を受け、枝毛、切れ毛、ぱさつき、ツヤの低下などが生じる。これらは、化学的、物理的刺激により、毛髪内部、及び、外部、表層部の構造が変化してしまうことによるものである。毛髪の内部からはシャンプーなどの洗浄行為によって脂質やたんぱく質の流出が生じてしまう。また、毛髪表面では疎水膜の欠落によって親水化が生じてしまうことや、キューティクルの剥がれ、脱落が生じてしまうことがある。このような損傷状態を治癒する手法として、可溶性シルクペプチド、コラーゲン、ケラチン又はコンキオリンなどのタンパク質や、アミノ酸、植物抽出物、第４級アンモニウム塩、３級アミン、カチオン性ポリマー、セラミド、両親媒性アミド、シリコーンなどを配合した毛髪化粧料が提案されており、例えば、不揮発性シリコーン類及び植物抽出物を配合した毛髪化粧料（例えば、特許文献１参照。）、カチオン化蛋白誘導体及び中性アミノ酸を配合した毛髪化粧料（例えば、特許文献２参照。）、可溶性シルクペプチド、糖アルコール及び中性アミノ酸を配合した毛髪化粧料（例えば、特許文献３参照。）、両親媒性アミド脂質及び三級アミンを配合した毛髪化粧料（例えば、特許文献４参照。）などが開示されている。しかしながらこれら単独の使用では、指どおりや櫛どおり、ツヤの改善、うるおい感、まとまり感の付与などすべてを兼ね備えているものはなく、それぞれを組み合わせた場合でも、期待する相乗効果を発揮しない、もしくはお互いの効果を打ち消しあったりするなどの問題点があった。 Hair is damaged by chemical or physical irritation such as permanent wave, bleach hair color, ultraviolet rays, and heat from a dryer, resulting in split ends, broken hair, crispness, and loss of gloss. These are due to changes in the structure of the hair inside, the outside, and the surface layer due to chemical and physical stimulation. From the inside of the hair, the outflow of lipids and proteins occurs due to the washing action such as shampoo. In addition, the hair surface may be hydrophilized due to lack of the hydrophobic film, and the cuticle may be peeled off or dropped off. As a method for healing such a damaged state, protein such as soluble silk peptide, collagen, keratin or conchiolin, amino acid, plant extract, quaternary ammonium salt, tertiary amine, cationic polymer, ceramide, amphiphilic Hair cosmetics containing amides, silicones and the like have been proposed. For example, hair cosmetics containing non-volatile silicones and plant extracts (see, for example, Patent Document 1), cationized protein derivatives and neutral amino acids. Hair cosmetics (see, for example, Patent Document 2), soluble silk peptides, sugar alcohols and neutral amino acids (for example, see Patent Document 3), amphiphilic amide lipids and tertiary compounds Hair cosmetics containing an amine (for example, see Patent Document 4) are disclosed. However, these single uses do not have all of them, such as fingering or combing, improving gloss, moisturizing, giving a feeling of unity, etc., even if they are combined, they do not exhibit the expected synergistic effect, or There were problems such as canceling each other's effects.
そこで、上記背景技術において、上記問題点を解消する技術が求められていた。即ち、本発明の目的とするところは、毛髪のパサつきを抑えてしっとりさせ、毛髪にすべり性、柔軟性、ツヤを与えることが可能な毛髪化粧料を提供することにある。 Therefore, a technique for solving the above-described problems has been demanded in the background art. That is, an object of the present invention is to provide a hair cosmetic that can suppress hairiness and moisturize and give the hair slipperiness, flexibility, and gloss.
本発明者は上記課題に鑑み、鋭意研究した結果、特定の植物成分と有機酸を含有する毛髪化粧料が上記目的を達成できることを見出し、本発明を完成した。即ち、本発明は、（Ａ）ヒオウギエキス、（Ｂ）コメヌカエキス、（Ｃ）ツバキエキスおよび（Ｄ）乳酸、クエン酸およびグルタミン酸から選択される１種または２種以上の有機酸を含有し、（Ａ）、（Ｂ）および（Ｃ）の合計配合量が毛髪化粧料組成物全体に対して乾燥固形分として０．００１〜５．０質量％である。そして、この毛髪化粧料には、さらに（Ｅ）植物油を含有することが好ましく、この（Ｅ）の配合量が毛髪化粧料組成物全体に対して０．０１〜５．０質量％であることがより好ましい。
As a result of intensive studies in view of the above problems, the present inventor has found that a hair cosmetic containing a specific plant component and an organic acid can achieve the above object, and has completed the present invention. That is, the present invention contains (A) a barley extract, (B) rice bran extract, (C) camellia extract and (D) one or more organic acids selected from lactic acid, citric acid and glutamic acid, The total amount of A), (B) and (C) is 0.001 to 5.0% by mass as the dry solid content with respect to the entire hair cosmetic composition. And it is preferable that this hair cosmetic contains (E) vegetable oil further, and the compounding quantity of this (E) is 0.01-5.0 mass% with respect to the whole hair cosmetic composition. Is more preferable.
本発明によれば、毛髪のパサつきを抑えてしっとりさせ、毛髪にすべり性、柔軟性、ツヤを与えることが可能な毛髪化粧料を提供できる。 ADVANTAGE OF THE INVENTION According to this invention, the hair cosmetics which can suppress the hairiness of a hair and make it moist and can give a slipperiness | flexibility, a softness | flexibility, and gloss can be provided.
本発明の毛髪化粧料に用いる（Ａ）成分であるヒオウギエキスは、ヒオウギの根茎を水、１．３−ブチレングリコール、および無水エタノールの混液で抽出して得られるエキスである。市販品としては、一丸ファルコス社製の「ファルコレックス ヒオウギ １．１７％溶液」が挙げられる。 The cypress extract, which is the component (A) used in the hair cosmetic composition of the present invention, is an extract obtained by extracting rhizomes of cypress with water, 1.3-butylene glycol, and absolute ethanol. As a commercially available product, “Falcolex Hiogi 1.17% solution” manufactured by Ichimaru Falcos is mentioned.
本発明の毛髪化粧料に用いる（Ｂ）成分であるコメヌカエキスは、コメヌカを、水、または１．３−ブチレングリコール、あるいは、両者の混液で抽出して得られるエキスである。市販品としては、香栄興業社製の「米ぬか抽出液 １％溶液」が挙げられる。 The rice bran extract which is the component (B) used in the hair cosmetic composition of the present invention is an extract obtained by extracting rice bran with water, 1.3-butylene glycol, or a mixture of both. As a commercially available product, “rice bran extract 1% solution” manufactured by Koei Kogyo Co., Ltd. may be mentioned.
本発明の毛髪化粧料に用いる（Ｃ）ツバキエキスは、ツバキの種子の脱脂物から水にて抽出して得られるエキスである。市販品としては、丸善製薬社製の「ツバキ種子抽出物 １００％粉」が挙げられる。 The camellia extract (C) used in the hair cosmetic composition of the present invention is an extract obtained by extracting with water from a defatted product of camellia seeds. As a commercially available product, “Camellia seed extract 100% flour” manufactured by Maruzen Pharmaceutical Co., Ltd. can be mentioned.
本発明の毛髪化粧料に用いる成分（Ａ）、（Ｂ）および（Ｃ）の配合量は、それぞれの配合量は特に限定されないが、３成分あわせて、毛髪化粧料組成物全体に対して、乾燥固形分として０．００１〜５．０質量％（以下、単に％と記す。）であり、好ましくは０．００３〜３．０％である。０．００１％以下であると、充分な効果が得られず、５．０％以上であると、原料臭が強く好ましくない。 The compounding amounts of the components (A), (B) and (C) used in the hair cosmetic composition of the present invention are not particularly limited, but the three components are combined with the entire hair cosmetic composition. The dry solid content is 0.001 to 5.0% by mass (hereinafter simply referred to as%), preferably 0.003 to 3.0%. If it is 0.001% or less, a sufficient effect cannot be obtained, and if it is 5.0% or more, the raw material odor is strong and not preferred.
本発明の毛髪化粧料に用いる（Ｄ）成分である有機酸は特に限定されるものではないが、例えば乳酸、クエン酸、酒石酸、グルタミン酸等が挙げられる。これら有機酸を適宜選択し、１種または２種以上を用いることができる。これら有機酸の配合量は特に限定されるものではないが、毛髪化粧料組成物全体に対して、０.１〜３．０％が好ましく、さらに好ましくは０.５〜２．０％である。０.１％以上であれば充分な柔軟性を与えることができ、また、３．０％以下であれば製剤上好ましくなる。 Although the organic acid which is (D) component used for the hair cosmetics of this invention is not specifically limited, For example, lactic acid, a citric acid, tartaric acid, glutamic acid etc. are mentioned. These organic acids can be appropriately selected, and one or more can be used. The blending amount of these organic acids is not particularly limited, but is preferably 0.1 to 3.0%, more preferably 0.5 to 2.0% with respect to the entire hair cosmetic composition. . If it is 0.1% or more, sufficient flexibility can be given, and if it is 3.0% or less, it is preferable in terms of formulation.
本発明の毛髪化粧料に好適に用いられる（Ｅ）成分である植物油としては、特に限定されるものではないが、例えばコメヌカ油、コメ胚芽油、コムギ胚芽油、ツバキ油、クルミ種子油、ホホバ油、サフラワー油、オリーブ油、ヒマワリ油、サザンカ油等が挙げられる。これら植物油を適宜選択し、１種または２種以上を用いることができる。これら植物油の配合量は特に限定されるものではないが、毛髪化粧料組成物全体に対して、０．００１〜１０．０％が好ましく、さらに好ましくは０．０１〜５．０％である。０．００１％以上であれば充分なツヤが得られ、また、１０．０％以下であるとべたつきが強くでることはなく好ましい。 The vegetable oil which is the component (E) preferably used in the hair cosmetic composition of the present invention is not particularly limited, but for example rice bran oil, rice germ oil, wheat germ oil, camellia oil, walnut seed oil, jojoba Oil, safflower oil, olive oil, sunflower oil, sasanqua oil and the like. These vegetable oils are appropriately selected, and one or more kinds can be used. Although the compounding quantity of these vegetable oils is not specifically limited, 0.001-10.0% is preferable with respect to the whole hair cosmetic composition, More preferably, it is 0.01-5.0%. If it is 0.001% or more, sufficient gloss can be obtained, and if it is 10.0% or less, stickiness does not occur strongly, which is preferable.
本発明の毛髪用化粧料には、上述した成分の他にも、目的に応じて毛髪用化粧料に通常使用されている成分を本発明の目的を達成する範囲内で、適宜配合することができる。これらの成分としては、例えば、アニオン活性剤、ノニオン界面活性剤、カチオン界面活性剤、保湿剤、シリコーン誘導体、油分、植物抽出エキス、粘度調整剤、パール化剤、薬剤、防腐剤、キレート剤、酸化防止剤、ＰＨ調整剤、色素、香料等が挙げられる。 In addition to the above-described components, the hair cosmetic of the present invention may be appropriately blended with components that are usually used in hair cosmetics depending on the purpose within a range that achieves the object of the present invention. it can. Examples of these components include anionic surfactants, nonionic surfactants, cationic surfactants, moisturizers, silicone derivatives, oils, plant extracts, viscosity modifiers, pearling agents, drugs, preservatives, chelating agents, Antioxidants, pH adjusting agents, pigments, fragrances and the like can be mentioned.
本発明の毛髪用化粧料は、特に対象、剤型にとらわれず、ヘアシャンプー、ヘアリンスヘアトリートメント、ヘアローション、ヘアリクイド、ヘアフォーム等に使用することができる。これらは常法により、本発明の毛髪化粧料を配合して製造することができる。 The hair cosmetic composition of the present invention can be used for hair shampoos, hair rinse hair treatments, hair lotions, hair liquids, hair foams and the like, regardless of the subject and dosage form. These can be produced by blending the hair cosmetic composition of the present invention in a conventional manner.
なお、上記成分（Ｅ）の植物油を本発明の毛髪化粧料に配合することは、ツヤを得るのに効果的であるが、ヘアシャンプー等の洗浄用の毛髪化粧料の場合は、泡立ちの低下などを招く虞もあるため、必ずしも配合することが好ましいとは限らない。もちろん泡立ちの
低下などを招かない範囲内で、ツヤを得るために配合することは好ましい。
In addition, blending the vegetable oil of the above component (E) into the hair cosmetic composition of the present invention is effective for obtaining a gloss, but in the case of a hair cosmetic composition for washing such as a hair shampoo, the foaming is reduced. Therefore, it is not always preferable to mix them. Of course, it is preferable to blend in order to obtain a gloss within a range that does not cause a decrease in foaming.
本発明を、実施例に基づき詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。なお、配合組成の各配合量は、特に断りのない限り、質量％である。 The present invention will be described in detail based on examples, but the present invention is not limited thereto. Prior to the examples, test methods and evaluation methods employed in each example will be described. In addition, each compounding quantity of a compounding composition is the mass% unless there is particular notice.
＜使用感の試験法・評価法＞
１０名のパネルが各実施例の試料（以下、単に「試料」という）で洗髪し、洗髪乾燥後の髪のしっとり感、柔軟性の有無、香り等の使用感について「良い」、「普通」、「悪い」の３段階で判定し、判定結果を「良い」と回答した人数により判断した。
<Testing and evaluation methods for feeling of use>
Ten panel members wash their hair with the samples of each example (hereinafter simply referred to as “samples”), and “good” or “normal” regarding the moist feeling of the hair after washing and drying, the presence or absence of flexibility, and the feeling of use such as aroma. , “Bad” was determined in three stages, the determination result was determined by the number of people who answered “good”.
判断基準は以下の通りである。
◎：大変優れている 「良い」と答えた試験対象者の数が８名以上
○：優れている 「良い」と答えた試験対象者の数が６名以上、８名未満
△：劣っている 「良い」と答えた試験対象者の数が４名以上、６名未満
×：大変劣っている 「良い」と答えた試験対象者の数が４名未満
Judgment criteria are as follows.
◎: Very good The number of test subjects who answered “good” is 8 or more ○: Excellent The number of test subjects who answered “good” is 6 or more and less than 8 △: Inferior The number of test subjects who answered “good” is 4 or more and less than 6 ×: very poor The number of test subjects who answered “good” is less than 4
＜毛髪調製方法＞
本実施例において、毛髪化粧料は各実施例の組成物が有効成分濃度２％になるように水溶液を調整した。この調製した水溶液を毛髪に塗布し、以下の評価を行った。
<Hair preparation method>
In this example, the hair cosmetic was prepared as an aqueous solution so that the composition of each example had an active ingredient concentration of 2%. The prepared aqueous solution was applied to hair and evaluated as follows.
＜すべり性の評価＞
動摩擦係数計（ＮＲＦ型：エルクエスト社製）を使用して、毛髪表面の動摩擦係数を測定し、以下の式（１）に従い動摩擦係数比を算出した。この動摩擦係数比が１以上のとき損傷毛の改善効果が見られることになる。
［式１］
毛髪化粧料未処理の毛髪の動摩擦係数（μｋ） …（１）
毛髪化粧料処理した毛髪の動摩擦係数（μｋ）
<Slip evaluation>
Using a dynamic friction coefficient meter (NRF type: manufactured by Elquest Co.), the dynamic friction coefficient of the hair surface was measured, and the dynamic friction coefficient ratio was calculated according to the following equation (1). When this dynamic friction coefficient ratio is 1 or more, the effect of improving damaged hair is seen.
[Formula 1]
Coefficient of dynamic friction of untreated hair cosmetics (μk) (1)
Coefficient of dynamic friction of hair treated with hair cosmetics (μk)
＜ツヤの評価＞
ゴニオフォトメーター（ＧＰ−２００型：村上色彩研究所社製）を使用して、毛髪表面のツヤ値を算出、以下の式（２）に従いツヤ比を算出した。このツヤ比が１以上のとき損傷毛の改善効果が見られることになる。
［式２］
毛髪化粧料処理した毛髪のツヤ値 …（２）
毛髪化粧料未処理の毛髪のツヤ値
<Evaluation of gloss>
Using a goniophotometer (GP-200 type: manufactured by Murakami Color Research Laboratory), the gloss value of the hair surface was calculated, and the gloss ratio was calculated according to the following formula (2). When the gloss ratio is 1 or more, the effect of improving damaged hair is seen.
[Formula 2]
Gloss value of hair treated with hair cosmetics (2)
Gloss value of untreated hair cosmetics
実施例１〜６及び比較例１〜６（ヘアトリートメント）
表１に記載の配合組成によるヘアトリートメントを常法により調整し、洗髪乾燥後の香り、しっとり感、および柔軟性などの使用感、動摩擦係数比によるすべり性、ツヤ比によるツヤについて調べ、その結果を表１に併せて示した。
Examples 1-6 and Comparative Examples 1-6 (hair treatment)
The hair treatment according to the composition shown in Table 1 was prepared by a conventional method, and the scent after shampooing and drying, the feeling of use such as moistness and flexibility, the sliding property by the dynamic friction coefficient ratio, the gloss by the gloss ratio, and the results Is also shown in Table 1.
表１から明らかなように、本発明による毛髪化粧料は比較例の組成物に比べて、優れた性能を見出した。 As is apparent from Table 1, the hair cosmetic composition according to the present invention found superior performance as compared with the composition of the comparative example.
実施例７ シャンプー
Ｎ−ラウロイルサルコシントリエタノールアミン １２．０
ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミン ４．０
ポリオキシプロピレンヤシ油脂肪酸モノエタノールアミド ３．５
ヤシ油脂肪酸モノエタノールアミド １．０
ヤシ油脂肪酸アミドプロピルベダイン ６．０
カチオン化セルロース誘導体 ０．３
（商品名：カチナールＨＣ−２００［東邦化学工業社製］）
塩化Ｏ−［２−ヒドロキシ−３−（トリメチルアンモニオ）
プロピル］グアーガム ０．１
ポリオキシプロピレンヤシ油脂肪酸イソプロパノールアミド ３．０
ジステアリン酸エチレングリコール ２．０
ムクロジエキス ０．５
（商品名：ムクロジ抽出液Ｋ ０．４％溶液〔丸善製薬社製〕）
ヒオウギエキス ０．５
（商品名：ヒオウギ抽出液 １．１７％溶液〔一丸ファルコス社製〕）
ツバキエキス ０．００１
（商品名：ツバキ種子抽出物 １００％粉〔丸善製薬社製〕）
コメヌカエキス ０．５
（商品名：米ぬか抽出液 １％溶液〔香栄興業社製〕）
クエン酸 ０．３
安息香酸ナトリウム ０．５
ＥＤＴＡ ０．１
塩化ナトリウム ０．５
カラメル ０．２
香料 ０．５
精製水 バランス
Example 7 Shampoo N-lauroyl sarcosine triethanolamine 12.0
Polyoxyethylene lauryl ether sulfate triethanolamine 4.0
Polyoxypropylene palm oil fatty acid monoethanolamide 3.5
Palm oil fatty acid monoethanolamide 1.0
Palm oil fatty acid amidopropyl bedain 6.0
Cationized cellulose derivative 0.3
(Product name: Kachinar HC-200 [manufactured by Toho Chemical Industry Co., Ltd.])
O- [2-hydroxy-3- (trimethylammonio) chloride
Propyl] guar gum 0.1
Polyoxypropylene palm oil fatty acid isopropanolamide 3.0
Ethylene glycol distearate 2.0
Mukuroji extract 0.5
(Product name: Mukuroji Extract K 0.4% solution [Maruzen Pharmaceutical Co., Ltd.])
Hinogi extract 0.5
(Brand name: Hinogi extract 1.17% solution [made by Ichimaru Falcos])
Camellia extract 0.001
(Product name: Camellia seed extract 100% powder [Maruzen Pharmaceutical Co., Ltd.])
Rice bran extract 0.5
(Product name: Rice bran extract 1% solution [manufactured by Koei Kogyo Co., Ltd.])
Citric acid 0.3
Sodium benzoate 0.5
EDTA 0.1
Sodium chloride 0.5
Caramel 0.2
Fragrance 0.5
Purified water balance
常法により上記組成のシャンプーを調整し、洗髪乾燥後のしっとり感、すべり性、ツヤを評価したところ、いずれの特性も優れており良好な結果を得た。 When a shampoo having the above composition was prepared by a conventional method and the moist feeling, dryness and gloss after hair washing and drying were evaluated, all the characteristics were excellent and good results were obtained.
実施例８ ヘアリンス
セテアリルアルコール ５．０
ベヘナミドプロピルジメチルアミン ２．５
パラフィン ０．５
ヒドロキシエチルセルロース ０．１
グリコシルトレハロース １．０
グリセリン ４．０
シリコンエマルジョン ２．０
（商品名：シリコンＢＹ２２−０７９〔東レ・ダウコーニング社製〕）
ジメチコン １．０
乳酸 ０．６
ヒオウギエキス ０．５
（商品名：ヒオウギ抽出液 １．１７％溶液〔一丸ファルコス社製〕）
ツバキエキス ０．００１
（商品名：ツバキ種子抽出物 １００％粉〔丸善製薬社製〕）
コメヌカエキス ０．５
（商品名：米ぬか抽出液 １％溶液〔香栄興業社製〕）
コメ胚芽油（商品名：オリザオイル〔一丸ファルコス社製〕） ０．５
クルミ種子油（商品名：クルミ種子油〔サミット製油社製〕） ０．５
カラメル ０．０５
メチルクロロイソチアゾリンオン・メチルイソチアゾリンオン ０．０５
（１．５％水溶液） （商品名：ケーソンＣＧ〔ローム・アンド・ハース社製〕）
香料 ０．５
精製水 バランス
Example 8 Hair rinse cetearyl alcohol 5.0
Behenamidopropyldimethylamine 2.5
Paraffin 0.5
Hydroxyethyl cellulose 0.1
Glycosyl trehalose 1.0
Glycerin 4.0
Silicone emulsion 2.0
(Product name: Silicon BY22-079 [Toray Dow Corning Co., Ltd.])
Dimethicone 1.0
Lactic acid 0.6
Hinogi extract 0.5
(Brand name: Hinogi extract 1.17% solution [made by Ichimaru Falcos])
Camellia extract 0.001
(Product name: Camellia seed extract 100% powder [Maruzen Pharmaceutical Co., Ltd.])
Rice bran extract 0.5
(Product name: Rice bran extract 1% solution [manufactured by Koei Kogyo Co., Ltd.])
Rice germ oil (trade name: Oriza oil (manufactured by Ichimaru Falcos)) 0.5
Walnut seed oil (trade name: Walnut seed oil [manufactured by Summit Oil Co., Ltd.]) 0.5
Caramel 0.05
Methylchloroisothiazolineone / methylisothiazolineone 0.05
(1.5% aqueous solution) (Brand name: Caisson CG [Rohm and Haas Co., Ltd.])
Fragrance 0.5
Purified water balance
常法により上記組成のヘアリンスを調整し、しっとり感、柔軟性、すべり性、ツヤを評価したところ、いずれの特性も優れており良好な結果を得た。 When the hair rinse of the above composition was adjusted by a conventional method and the moist feeling, flexibility, slipperiness, and gloss were evaluated, all the characteristics were excellent and good results were obtained.
実施例９ 洗い流さないヘアトリートメント
セタノール １．０
ステアリルアルコール ２．０
ベへトリモニウムクロライド ０．５
イソステアリン酸 １．０
ミリスチン酸オクチルドデシル ５．０
スクワラン １．０
グリセリン １．０
ジメチコン ０．５
（商品名：シリコンＫＦ−９６Ａ（６ＣＳ 〔信越化学社製〕）
ヒドロキシエチルセルロース ０．１
ヒオウギエキス ０．５
（商品名：ヒオウギ抽出液 １．１７％溶液〔一丸ファルコス社製〕）
ツバキエキス ０．００１
（商品名：ツバキ種子抽出物 １００％粉〔丸善製薬社製〕）
コメヌカエキス ０．１
（商品名：米ぬか抽出液 １％溶液〔香栄興業社製〕）
コメ胚芽油（商品名：オリザオイル〔一丸ファルコス社製〕） ０．５
クルミ種子油（商品名：クルミ種子油〔サミット製油社製〕） ０．５
サザンカ油（商品名：精製山茶花油〔横関油脂工業社製〕） ０．５
フェノキシエタノール ０．１
グルタミン酸 ０．１
香料 ０．５
精製水 バランス
Example 9 Hair Treatment Cetanol 1.0 Not Washed Out
Stearyl alcohol 2.0
Beethrimonium chloride 0.5
Isostearic acid 1.0
Octyldodecyl myristate 5.0
Squalane 1.0
Glycerin 1.0
Dimethicone 0.5
(Product name: Silicon KF-96A (6CS [Shin-Etsu Chemical Co., Ltd.])
Hydroxyethyl cellulose 0.1
Hinogi extract 0.5
(Brand name: Hinogi extract 1.17% solution [made by Ichimaru Falcos])
Camellia extract 0.001
(Product name: Camellia seed extract 100% powder [Maruzen Pharmaceutical Co., Ltd.])
Rice bran extract 0.1
(Product name: Rice bran extract 1% solution [manufactured by Koei Kogyo Co., Ltd.])
Rice germ oil (trade name: Oriza oil (manufactured by Ichimaru Falcos)) 0.5
Walnut seed oil (trade name: Walnut seed oil [manufactured by Summit Oil Co., Ltd.]) 0.5
Sasanka oil (trade name: Refined Sancha Flower Oil (manufactured by Yokoseki Yushi Kogyo Co.)) 0.5
Phenoxyethanol 0.1
Glutamic acid 0.1
Fragrance 0.5
Purified water balance
常法により上記組成の洗い流さないヘアトリートメントを調整し、しっとり感、柔軟性、すべり性、ツヤを評価したところ、いずれの特性も優れており良好な結果を得た。 When a hair treatment having the above composition not washed off was prepared by a conventional method and evaluated for moist feeling, flexibility, slipperiness, and gloss, all the characteristics were excellent and good results were obtained.
本発明により、毛髪のパサつきを抑えてしっとりさせ、毛髪にすべり性、柔軟性、ツヤを与えることが可能な毛髪化粧料を提供できる。 According to the present invention, it is possible to provide a hair cosmetic that can suppress hairiness and moisturize the hair, and can provide slipperiness, flexibility, and gloss.
Claims (3)
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| KR101493483B1 (en) | 2012-02-13 | 2015-02-16 | 주식회사 세화 피앤씨 | Hair and scalp protective composition for hair dyeing |
| JP2013193968A (en) * | 2012-03-16 | 2013-09-30 | Kracie Home Products Ltd | Shampoo composition |
| CN104887602B (en) * | 2015-05-29 | 2017-11-07 | 陈文创 | Jasmine hair washing face washing liquid |
| JP7012997B2 (en) * | 2017-09-19 | 2022-02-15 | 株式会社東洋新薬 | External application for scalp or hair |
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| JPH06693B2 (en) * | 1985-05-13 | 1994-01-05 | 鐘紡株式会社 | Emulsified cosmetics |
| JPH09301883A (en) * | 1996-05-15 | 1997-11-25 | Ichimaru Pharcos Co Ltd | Cell activator containing blackberry lily extract and alpha-hydroxyl acid and its application |
| JP2000344632A (en) * | 1999-06-07 | 2000-12-12 | Ichimaru Pharcos Co Ltd | Hair grower containing plant extract |
| JP2002020243A (en) * | 2000-07-06 | 2002-01-23 | Lion Corp | Agent for preventing and improving gray hair |
| JP5201771B2 (en) * | 2001-04-06 | 2013-06-05 | 丸善製薬株式会社 | Testosterone 5α-reductase inhibitor, androgen receptor binding inhibitor, antiandrogen hormone and hair nourishing cosmetic. |
| JP2003048818A (en) * | 2001-07-31 | 2003-02-21 | Chuo Aerosol Kagaku Kk | Hair cosmetic |
| JP2003146860A (en) * | 2001-11-09 | 2003-05-21 | Pola Chem Ind Inc | Hair cosmetic |
| JP2003300835A (en) * | 2002-04-08 | 2003-10-21 | Kao Corp | Hair cosmetic |
| JP2005126347A (en) * | 2003-10-22 | 2005-05-19 | Taisho Pharmaceut Co Ltd | Aerosol composition for hair |
| JP2006219449A (en) * | 2005-02-14 | 2006-08-24 | Lion Corp | Hair shampoo composition |
| JP5158672B2 (en) * | 2007-02-23 | 2013-03-06 | クラシエホームプロダクツ株式会社 | Hair cosmetics |
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