JP5856375B2 - Emulsion hair styling - Google Patents

Description

  The present invention relates to an emulsified hair preparation containing two kinds of oils having a specific melting point in a specific ratio, and further containing an emulsifier, an ester of a monohydric alcohol having 6 to 18 carbon atoms and salicylic acid, More particularly, the present invention relates to an emulsified hair styling composition that has a good feeling of use, is not sticky, is not sticky, and has excellent styling effects such as set power, re-hair styling, and durability of set power.

Conventionally, various ingredients have been blended in hairdressing preparations according to functions and effects such as desired use feeling, styling properties, styling sustainability, re-styling properties, and moisture resistance.
In order to give styling power, which is the most important function of hairdressing materials, film-forming polymers and resins have been widely used and have been used in various dosage forms such as gels, sprays and foams (for example, patents) References 1-3).
On the other hand, it is also known to add styling power by blending solid oil, and it has been studied to blend various oils in combination, and also to use polymers and resins having film-forming properties in combination. . In recent years, many emulsifier-type hair conditioners containing solid oil have been studied (see, for example, Patent Documents 4 to 6).
JP 09-2922 A JP 09-25220 A JP 09-143038 A JP 2007-230926 A JP 2007-70233 A JP 2009-256257 A

  As a characteristic of hair styling blended with film-forming polymers and resins, it can give superior setting power and styling sustaining effect by forming a hard film on the hair. As described above, there is a case where the user feels stiff, the hair styling property becomes worse, and the hair washing property becomes worse. On the other hand, as a hair styling product with excellent re-styling properties, there are those containing solid oil instead of polymer and resin with film-forming properties, and depending on the desired function, the type and amount of solid oil can be adjusted Has been used. However, when functions such as styling power are increased, stickiness peculiar to solid oil may occur. For this reason, the use feeling has been improved by using an emulsifier type instead of an oily type as a hairdressing agent, but there are cases where a sufficient effect cannot be obtained.

In order to obtain a non-sticky feeling in an emulsifier-type hair styling compounded with a solid oil, for example, there is a method using a silicone oil or a film-forming water-soluble polymer. In the method using silicone oil, the stickiness can be suppressed by the smoothness that is the characteristic of silicone oil, but on the other hand, the hair is appropriately bundled in a bundle due to the adhesiveness of the hair surface of each hair, There was less sense of bundled hair that could be styled, and the setting power and re-styling could be impaired. In the method using a film-forming water-soluble polymer, even when the sticky feeling is suppressed, on the other hand, a sticky feeling may occur. That is, a technique of blending a plurality of solid oils having different melting points as in Patent Document 6 is also disclosed, but in this case as well, it is necessary to contain a film-forming acrylic polymer or the like.
Accordingly, there has been a demand for the development of an emulsifier-type hair styling agent that has no feeling of stickiness and stickiness, is excellent in set power such as bundled feeling, and has excellent re-hair styling properties and durability of setting power.

  In view of this situation, the present inventor has intensively studied, and as a result, an oil having a melting point of 60 ° C. or higher and 105 ° C. or lower, an oil having a melting point of 35 ° C. or higher and lower than 60 ° C., an emulsifier, and a carbon that is a specific ester oil. The mass ratio of the oil agent containing a monohydric alcohol of formula 6 to 18 and an ester of salicylic acid, and further having a melting point of 35 ° C. or more and less than 60 ° C. The emulsified hair conditioner with a specific range of 0.1 to 10 has a good feeling of use, no stickiness or stickiness, excellent setting power, and excellent re-hairing properties and durability of setting power. As a result, the present invention has been completed.

That is, the present invention provides the following components (A) to (D);
(A) Oil agent having a melting point of 60 ° C. or more and 105 ° C. or less (B) Oil agent having a melting point of 35 ° C. or more and less than 60 ° C. (C) Emulsifier (D) An ester of monohydric alcohol having 6 to 18 carbon atoms and salicylic acid The emulsification type hair styling characterized in that the contained mass ratio (B) / (A) of the component (A) and the component (B) is in the range of 0.1-10.

  Moreover, content of the ester of a component (D) C6-C18 monohydric alcohol and salicylic acid is 0.01-5 mass%, The said emulsification type hairstyling characterized by the above-mentioned is provided. . Further, the present invention provides the above-mentioned emulsified hair styling characterized by containing highly polymerized polyethylene glycol as the component (E).

  The emulsified hair dressing of the present invention has no feeling of stickiness and stickiness, and is excellent in use feeling. In addition, it has excellent styling setting power, and also has excellent styling and durability.

Hereinafter, the present invention will be described in detail. In the present specification, “to” means a range including numerical values before and after.
The component (A) used in the emulsified hairdressing composition of the present invention contains an oil agent having a melting point of 60 ° C. or higher and 105 ° C. or lower for the purpose of imparting a setting power that is a styling effect. By setting the melting point to 60 ° C. or higher, an advantageous setting force effect can be obtained. This can be achieved by using an oil agent having a high melting point. However, since there is no significant difference in the effect even at 105 ° C. or higher, in the present invention, it is necessary to use an oil agent having a melting point of 60 ° C. or higher and 105 ° C. or lower. There is. Moreover, it has the effect which provides the outstanding setting power and re-hair-setting property by containing the component (B) melting | fusing point mentioned later and 35 degreeC or more and less than 60 degreeC oil agent in combination in a specific ratio.

  Component (A) used in the emulsified hairdressing material of the present invention is not particularly limited as long as it has an melting point of 60 ° C. or higher and 105 ° C. or lower as long as it can be used in cosmetics. Hydrocarbons, esters, waxes Oils and fats, higher alcohols and the like can be used. Specifically, solid paraffin wax, ceresin wax, microcrystalline wax, hydrogenated microcrystalline wax, carnauba wax, candelilla wax, candelilla wax hydrocarbons, candelilla wax esters, polyethylene wax, ethylene / propylene copolymer Synthetic wax, Fischer-Tropsch wax, montan wax, beeswax, behenyl alcohol and the like can be exemplified, and one or more of these can be appropriately selected and used as necessary. In the present invention, microcrystalline wax, solid paraffin wax, and behenyl alcohol are particularly preferable for obtaining an excellent setting force.

  The content of the oil agent having a melting point of component (A) of 60 ° C. or higher and 105 ° C. or lower is not particularly limited as long as it is within the range of the mass ratio of the component (A) and component (B) described later. 2 to 40% by mass (hereinafter abbreviated as%) is preferable, and 5 to 30% is more preferable.

  The component (B) used in the emulsified hairdressing material of the present invention has an melting point of 35 ° C. or higher and lower than 60 ° C. for the purpose of imparting re-styling properties, which is a styling effect. In addition, as will be described later, the effect of synergistically providing particularly excellent setting power and re-styling is achieved by containing an oil agent having a melting point of component (A) of 60 ° C. or higher and 105 ° C. or lower in a specific ratio. Have.

  The oil agent having a melting point of 35 ° C. or higher and lower than 60 ° C. used in the emulsified hair dressing of the present invention is not particularly limited as long as it can be used in cosmetics. Hydrocarbons, esters, waxes Oils and fats, higher alcohols, silicone waxes and the like can be used. Specifically, solid paraffin wax, gay wax, hydrogenated hard oil obtained by hydrogenating palm oil, palm oil, castor oil, petrolatum, shea butter, cetyl myristate, cetyl palmitate, cetyl alcohol, stearyl alcohol, ceto Stearyl alcohol, stearyl-modified polysiloxane, and the like can be exemplified, and one or two or more can be appropriately selected and used as necessary. In the present invention, solid paraffin wax, petrolatum, and cetostearyl alcohol are particularly preferable for obtaining excellent hair re-styling properties.

  Component (B) The melting point of the oil agent having a melting point of 35 ° C. or higher and lower than 60 ° C. is not particularly limited as long as it is within the range of the mass ratio of the component (A) and the component (B) described later. In order to obtain the effect of re-styling, 1 to 40% is preferable, and 2 to 30% is more preferable.

  The component (A) oil used in the emulsified hairdressing composition of the present invention has a mass ratio (B) / (A) of the oil of the components (A) and (B) in the range of 0.1 to 10. It is essential. By containing the component (A) oil agent in combination at a specific ratio, it has the effect of synergistically imparting particularly excellent setting power and re-styling. Furthermore, a more prominent effect can be acquired when content mass ratio (B) / (A) exists in the range of 0.3-4. Further, if the mass ratio is less than 0.1, the re-hairing property may be insufficient, and if it exceeds 10, the setting force or the sustainability of the setting force may be deteriorated.

  The component (C) emulsifier used in the emulsified hairdressing material of the present invention is an essential component for constituting the emulsified hairdressing material. The component (C) emulsifier is not particularly limited as long as it can be used in cosmetics, and anionic surfactants, nonionic surfactants, amphoteric surfactants, cationic surfactants, and the like can be used. These can be used by appropriately selecting one kind or two or more kinds as necessary.

  Specific examples of the anionic surfactant include salts of fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, alkylbenzene sulfate, alkyl sulfate, α-olefin sulfonate, dialkyl sulfosuccinate, and alkyl sulfosuccinate. Acid salt, polyoxyethylene alkyl ether acetate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, N-acylalkyl taurine salt, N-acyl taurine salt, alkyl phosphate, polyoxyethylene alkyl Examples thereof include ether phosphates, polyoxyethylene alkylphenyl ether phosphates, N-acyl amino acid salts, N-acyl-N-alkyl amino acid salts, etc. You can select and use That. Among these, fatty acid salts such as lauric acid, myristic acid, palmitic acid, stearic acid, N-acylmethyl such as cocoyl methyl taurine salt, lauroyl methyl taurine salt, myristoyl taurine salt, palmitoyl methyl taurine salt, stearoyl methyl taurine salt It is preferable that it is 1 type (s) or 2 or more types chosen from N-acyl amino acid salts, such as a taurine salt, N-stearoyl-L-glutamate, N-coconut oil fatty acid-L-glutamate. Furthermore, the base of the salt is more preferably one or more selected from sodium, potassium, aminomethylpropanol, monoethanolamine, and triethanolamine.

  Specific examples of the nonionic surfactant include polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, and polyoxyethylene hydrogenated castor oil. Fatty acid ester, polyoxyethylene sorbitol tetra fatty acid ester, polyoxyethylene glycerin fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, alkyl polyglucoside, N-alkyldimethylamine oxide, polyoxyethylene Cholesteryl ether, polyoxyethylene phytosteryl ether, polyoxyethylene alkyl ether, polyoxyethylene poly Alkoxy polyoxypropylene alkyl ethers, can be exemplified polyoxyethylene alkyl phenyl ether, can be appropriately selected one or more kinds as necessary. Among these, glycerin fatty acid esters, polyoxyethylene alkyl ethers such as polyoxyethylene behenyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene fatty acid esters, and sorbitan fatty acid esters such as sorbitan palmitate are particularly preferable.

  Specific examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid type, sulfuric acid ester type, sulfonic acid type, and phosphoric acid ester type. For example, N, N-dimethyl-N-alkyl- N-carboxymethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N-dialkyl-N, N-bis (polyoxyethylene sulfate) ) Ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, coconut oil fatty acid amidopropyl betaine, phospholipid, etc. It is possible to select and use seeds or two or more kinds as appropriate. That.

  Specific examples of the cationic surfactant include a mono long chain alkyl type quaternary ammonium salt, a di long chain alkyl type quaternary ammonium salt, or an ethylene oxide addition type quaternary ammonium salt, dicocoylethylhydroxy. Examples thereof include ethylmethylammonium methylsulfate, distearoylethylhydroxyethylmethylammonium methylsulfate, and the like, and one or more can be appropriately selected and used as necessary.

Among the component (C) emulsifiers used in the emulsified hair preparation of the present invention, an anionic surfactant and a nonionic surfactant are particularly preferable in order to obtain excellent usability and function.
Although content of a component (C) emulsifier is not specifically limited, 1-10% is preferable and 2-7% is more preferable.

  The component (D) ester of monohydric alcohol having 6 to 18 carbon atoms and salicylic acid used in the emulsified hairdressing material of the present invention has a feeling of stickiness and stickiness without impairing the re-styling properties and setting power as a hairdressing material. It is contained for the purpose of mitigating.

  The ester of the component (D) monohydric alcohol having 6 to 18 carbon atoms and salicylic acid used in the emulsified hairdressing material of the present invention is not particularly limited as long as it can be used in cosmetics, and specifically, salicylic acid. Examples include ethylhexyl, isodecyl salicylate, butyloctyl salicylate, tridecyl salicylate, isocetyl salicylate, and the like, and one or two or more can be appropriately selected and used as necessary. Among these, ethylhexyl salicylate is particularly preferable for obtaining an excellent effect.

  The content of the component (D) the ester of monohydric alcohol having 6 to 18 carbon atoms and salicylic acid used in the emulsified hairdressing material of the present invention is not particularly limited. -5% is preferable, and 0.1-3% is particularly preferable.

  The emulsified hair dressing of the present invention can also contain highly polymerized polyethylene glycol as component (E). The highly polymerized polyethylene glycol of component (E) is contained for the purpose of imparting the effect of further improving the feeling of use, such as improving the sustainability of setting force and suppressing stickiness, and is a component (A ) And the aqueous component (E), which is an aqueous component, can be expected to maintain a particularly excellent effect in the emulsifier type.

  The highly polymerized polyethylene glycol of component (E) is not particularly limited as long as it is a highly polymerized polyethylene glycol having the above-mentioned effects, and in particular, a highly polymerized polyethylene glycol having an average molecular weight in the range of 10,000 to 10,000,000 is preferable, and 250,000 Those in the range of ˜7 million are more preferred. As the highly polymerized polyethylene glycol, one or more kinds having different average molecular weights can be appropriately selected and used as necessary. Here, the molecular weight is calculated by the average value of the molecular weight by the hydrodynamic measurement method.

  The content of the component (E) highly polymerized polyethylene glycol used in the emulsified hairdressing material of the present invention is not particularly limited, but 0.001 to 1% is preferable to obtain an excellent feeling of use, and 0.01 to 0.5% is particularly preferred.

  The emulsified hair preparation of the present invention contains water in addition to the above essential components, but is not particularly limited as long as it is generally used in cosmetics. In addition to water, purified water, hot spring water, deep water, or steam distilled water from plants may be used, and one or two or more kinds may be appropriately selected and used as necessary. Moreover, content is not specifically limited, Although it can contain suitably according to the amount of other components, it can be used in 10 to 70% of range in general.

  The emulsified hair styling composition of the present invention may be any of O / W type and W / O type as a dosage form, and further a multilayer type such as O / W / O type and W / O / W type. However, the O / W type is particularly preferable for obtaining an excellent feeling of use.

  In the hairdressing composition of the present invention, components other than the above components (A) to (E) that are usually used in cosmetics, oils other than components (A) and (B), silicone oils, ultraviolet absorbers, components Water-soluble polymers other than (E), thickeners, polyhydric alcohols, sugars, lower alcohols and other aqueous components, antibacterial agents, preservatives, pH adjusters, refreshing agents, vitamins, cosmetic ingredients, fragrances, powders Etc. can be suitably blended within a range not impairing the effects of the present invention.

  Examples of oils having a melting point of less than 35 ° C. include higher alcohols such as oleyl alcohol, isostearyl alcohol, hexyl decanol, octyldodecanol, hydrocarbons such as squalane, squalene, liquid paraffin, isocetyl isostearate, trimethylol triisostearate Propane, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octoate, oleyl oleate, octyldodecyl oleate, decyl oleate, neocapric dicaprate Pentyl glycol, di-2-ethylhexyl sebacate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, isopropyl myristate Ester oils such as octyldodecyl myristate and 2-hexyldecyl myristate, fatty acids such as oleic acid, linoleic acid and isostearic acid, low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methylphenylpolysiloxane, Decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, alkoxy-modified polysiloxane, alkyl-modified polysiloxane, cross-linked organopolysiloxane, Examples include silicone oils such as fluorine-modified polysiloxane, glycerin-modified polysiloxane, and amino-modified silicone.

  Examples of water-soluble polymers include chondroitin sulfate, hyaluronic acid, mucin, dermatan sulfate, mucopolysaccharides selected from heparin and keratan sulfate and salts thereof, gum arabic, tragacanth, galactan, carob gum, guar gum, caraya gum, carrageenan, pectin, agar Plant polymers such as quince seed, algae colloid, Trant gum, locust bean gum, galactomannan, microbial polymers such as xanthan gum, dextran, succinoglucan, pullulan, starch, carboxymethyl starch, methylhydroxypropyl starch, etc. Starch polymers, methylcellulose, ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose Nitrocellulose, sodium cellulose sulfate, sodium carboxymethyl cellulose, crystalline cellulose, cellulose polymer of cellulose powder, alginic acid polymers such as sodium alginate, propylene glycol alginate, polyvinyl methyl ether, carboxyvinyl polymer, alkyl-modified carboxyvinyl Inorganic water such as vinyl polymers such as polymers, polyoxyethylene polymers, polyoxyethylene polyoxypropylene copolymer polymers, sodium polyacrylate, polyethyl acrylate, polyethyleneimine, bentonite, laponite, hectorite Functional polymers. Examples of the anionic polymer widely used as a setting agent include acrylic acid / ethyl acrylate / N-tert-butylacrylamide copolymer, acrylic resin alkanolamine, vinyl methyl ether / ethyl maleate copolymer, vinyl Examples thereof include a methyl ether / butyl maleate copolymer and a vinyl acetate / crotonic acid copolymer. As amphoteric polymers, N-methacryloylethyl N, N-dimethylammonium / α-N-methylcarboxybetaine / alkyl methacrylate copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer Examples thereof include acrylic acid / dimethyldiallylammonium chloride / acrylamide copolymer, dimethyldiallylammonium chloride / acrylic acid copolymer, and the like. As cationic polymers, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate, diallyldimethylammonium chloride / hydroxyethylcellulose, glycidyltrimethylammonium chloride / hydroxyethylcellulose, dimethyldiallylammonium chloride polymer, dimethyl chloride Examples thereof include diallylammonium / acrylamide copolymer. Examples of the nonionic polymer include polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, polyvinyl alcohol, polyurethane and the like.

  Examples of aqueous components include glycerin, diglycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, low-polymerized polyethylene glycol and other polyhydric alcohols, ethyl alcohol, isopropanol, etc. Of lower alcohols.

  Antibacterial agents include benzoic acid, sodium benzoate, salicylic acid, coalic acid, sorbic acid, potassium sorbate, parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitizer, bis (2 -Pyridylthio-1-oxide) zinc, isopropylmethylphenol and the like, and examples of the preservative include paraoxybenzoic acid ester, phenoxyethanol and the like.

  Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, malic acid, potassium carbonate, sodium bicarbonate, ammonium bicarbonate, sodium hydroxide, potassium hydroxide, triethanolamine, monoethanolamine, Examples of the refreshing agent include L-menthol and camphor.

  Vitamins such as vitamin A and derivatives thereof, vitamin B and derivatives thereof, vitamin C and derivatives thereof, vitamin E and derivatives thereof, linolenic acid and derivatives thereof, and vitamins such as phytonadione, menaquinone, menadione, menadiol Ks; vitamin Ps such as eriocitrin and hesperidin; and biotin, carcinine, ferulic acid and the like.

  Examples of the cosmetic component include amino acids and amino acid derivatives, peptides, sterols, 2-methacryloyloxyethyl phosphorylcholine homopolymer, and a copolymer of 2-methacryloyloxyethyl phosphorylcholine and a hydrophobic monomer. Specifically, examples of amino acids include glycine, alanine, valine, isoleucine, serine, threonine, aspartic acid, glutamic acid, acetylglutamic acid, asparagine, glutamine, lysine, hydroxylysine, arginine, cystine, cysteine, acetylcysteine, methionine. , Phenylalanine, tyrosine, proline, hydroxyproline, ornithine, citrulline, theanine, trimethylglycine and the like. As amino acid derivatives, N-lauroyl-L-glutamate di (phytosteryl 2-octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl behenyl octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl Octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl), N-lauroylsarcosine isopropyl, N-lauroyl-L-glutamate dioctyldodecyl, and the like. Peptides may be derived from animals, fish, shellfish, plants and silk. Specifically, collagen and derivatives thereof or hydrolysates thereof, elastin and derivatives thereof or hydrolysates thereof, keratin and derivatives thereof Alternatively, a degradation product thereof, wheat protein and a derivative thereof or a hydrolyzate thereof, soybean protein and a derivative thereof or a hydrolyzate thereof, and the like can be given. Examples of sterols include cholesterol and phytosterol.

  If the powder is used in ordinary cosmetics, its shape (spherical, needle-like, plate-like, etc.), particle size (smoke-like, fine particles, pigment grade, etc.), particle structure (porous) , Non-porous, etc.) can be used.

  Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.

Example 1 (Invention products 1 to 14 and Comparative products 1 to 4): Hair styling materials Hair styling materials shown in Table 1 below were prepared by the following production method, and (b) no stickiness, (b) no stickiness. , (C) Set power, (d) Re-hair styling, and (e) Persistence of set power were evaluated and determined by the following evaluation methods and criteria, and the results are shown in Table 1.

(Production method)
A: Components 1 to 10 are heated to 80 ° C. and mixed.
B: Components 11 to 15 are heated to 80 ° C. and mixed.
C: A is added to B and emulsified.
D: C is cooled.
E: Component 16 was added to D and mixed uniformly to obtain a hair styling agent (O / W type).

[Evaluation methods for evaluation items (a) to (d) and (e)]
Human hair wigs (wigs) were washed with shampoo A of the following reference preparation example, treated with rinse B of the following reference preparation example, and then dried. Next, 3 g of each of the inventive products 1 to 9 and comparative products 1 to 4 were applied to the hair of human hair wigs, and the stylings were (i) no stickiness, (b) no stickiness, ( C) The set power was evaluated. Thereafter, the mixture was allowed to stand at 30 ° C. and 80% humidity for 1 hour, and then evaluated for (d) re-styling and (e) durability of setting power. These evaluations were performed by five expert evaluators in accordance with the following evaluation criteria (I) in five levels, and the average score of all professional evaluators was determined according to the following criteria (II).

Evaluation criteria (I)
[Evaluation Result]: [Score]
Very good: 5 points Good: 4 points Normal: 3 points Somewhat bad: 2 points Bad: 1 point Judgment criteria (II)
[Average score]: [Judgment]
4.5 or more: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than 1.5: ×

Reference preparation example: Shampoo A
Shampoo A was prepared by the following formulation and manufacturing method.
(Ingredient) (%)
1. Sodium tetradecenesulfonate 10
2. Palm oil fatty acid methyl taurine sodium 6
3. Palm oil fatty acid amidopropyl betaine 4
4). Coconut oil fatty acid acyl glutamic acid triethanolamine 3
5. Palm oil fatty acid diethanolamide 6
6.1,3-Butylene glycol 2
7). Cationized guar gum 1
8). Edetate disodium 0.2
9. Preservative 0.1
10. Fragrance 0.1
11. Purified water remaining amount (production method)
Ingredients 1 to 11 are uniformly heated and mixed at 70 ° C. and then cooled.

Reference Preparation Example: Rinse B
A rinse was prepared by the following formulation and manufacturing method.
(Ingredient) (%)
1. Cetostearyl alcohol 5
2. Isopropyl myristate 2
3. Stearyltrimethylammonium chloride 2
4). Propylene glycol 5
5. Hydroxyethyl cellulose 0.5
6). Preservative 0.1
7). Fragrance 0.1
8). Purified water remaining amount (production method)
Ingredients 1 and 2 are uniformly heated and mixed at 70 ° C., added to ingredients 3 to 6 and 8 dissolved by heating and emulsified. After cooling, component 7 is added.

As is clear from the results in Table 1, the hair styling products (O / W type) of the products 1 to 14 of the present invention are more fully exhibited than the comparative products 1 to 4, and the properties of each component are fully exhibited. It was also excellent in feeling of stickiness and stickiness, and excellent in setting power, hair styling, and sustainability of setting power.
On the other hand, the comparative product 1 in which the content ratio of the component (B) to the component (A) was 0.01 was good in stickiness, but had a feeling of stickiness and poor styling. Moreover, although the comparative product 2 whose mass ratio of the component (B) with respect to a component (A) is 20.0 has a feeling of firmness, it was inferior to the sustainability of a setting force and a setting force. Further, Comparative Product 3 containing no component (C) had good setting power and sustainability of setting power, but was inferior in stickiness. On the other hand, the comparative product 4 which did not contain the component (C) and contained silicone oil (dimethylpolysiloxane) instead had a good feeling of stickiness, but had poor hair styling properties.

Example 2: Hair wax (O / W type)
(Ingredient) (%)
1. Carnauba wax (melting point 80 ° C) 2
2. Candelilla wax (melting point 70 ° C) 2
3. Beeswax (melting point 65 ° C) 2
4). (Ethylene / propylene) copolymer (melting point 95 ° C)
2
5. Polyethylene wax (melting point 88 ° C) 2
6). Ceresin wax (melting point 76 ° C) 2
7). Microcrystalline wax (melting point 79 ° C) 1
8). Paraffin wax (melting point 63 ° C) 1
9. Behenyl alcohol (melting point 69 ° C) 1
10. Cetostearyl alcohol (melting point 53 ° C.) 2
11. Cetyl palmitate (melting point 48 ° C) 2
12 Paraffin wax (melting point 50 ° C) 1
13. Vaseline (melting point 50 ° C) 1
14 Triethylhexanoin 5
15. Liquid paraffin 5
16. Octyl rearzone 0.2
17. Ethyl hexyl methoxycinnamate 0.2
18. N-stearoyl-L-glutamic acid 2
19. N-coconut oil fatty acid-L-glutamic acid 0.5
20. Polyoxyethylene behenyl ether (30E.O.) 0.5
21. Polyoxyethylene hydrogenated castor oil (60 EO) 0.5
22. PEG-55 stearate 0.5
23. Ethylhexyl salicylate 0.5
24. Purified water remaining amount 25. Sodium hydroxide 0.3
25.1,3-Butylene glycol 5
26. Dipropylene glycol 1
27. Glycerin 1
28. Highly polymerized polyethylene glycol (molecular weight 400,000) 0.1
29. Phenoxyethanol 0.5
30. Glycine 0.2
31. Hydrolyzed soy peptide 0.2
32. Hydrolyzed silk 0.2
33. Polymethacryloyloxyethyl phosphorylcholine 0.1
34. Fragrance 0.1

(Production method)
A: Components 1 to 23 are heated to 80 ° C. and mixed.
B: Components 24-29 are heated to 80 ° C. and mixed.
C: A is added to B and emulsified.
D: C is cooled.
E: Components 30 to 34 were sequentially added to D and mixed uniformly to obtain a hair wax.

  The hair wax of Example 2 (O / W type) was evaluated in the same manner as in Example 1. As a result, it was excellent in feeling of use without stickiness and stickiness, and set power, re-hair styling, and durability of setting power. It was excellent.

Example 3: Hair cream (O / W type)
(Ingredient) (%)
1. Fischer-Tropsch wax (melting point 93 ° C) 3
2. Rice bran (melting point 77 ° C) 3
3. Montan wax (melting point 70 ° C) 3
4). Candelilla wax hydrocarbon (melting point 65 ° C) 3
5. Candelilla wax esters (melting point 80 ° C) 2
6). Ceresin wax (melting point 76 ° C) 1
7). Microcrystalline wax (melting point 82 ° C) 1
8). Paraffin wax (melting point 63 ° C) 1
9. Behenyl alcohol (melting point 69 ° C) 1
10. Cetyl alcohol (melting point 49 ° C) 2
11. Shea butter (melting point 38 ° C) 2
12 Hydrogenated palm oil (melting point 48 ° C) 1
13. Hydrogenated coconut oil (melting point 45 ° C) 1
14 Cetyl ethylhexanoate 3
15. Squalane 2
16. N-lauroyl-L-glutamate di (phytosteryl, 2-octyldodecyl) 0.1
17. N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl) 0.2
18. Stearoyl methyl taurine sodium 1.5
19. Myristoyl methyl taurine sodium 0.5
20. Trioleic acid polyoxyethylene sorbitan (20EO) 0.5
21. Polyoxyethylene sorbitan monooleate (20E.O.) 0.5
22. Sorbitan monopalmitate 0.5
23. Ethylhexyl salicylate 1
24. Purified water remaining amount 25. Citric acid 0.1
25. Propylene glycol 5
26. Sorbitol 1
27. Diglycerin 1
28. Highly polymerized polyethylene glycol (molecular weight 2 million) 0.05
29.1,2-Pentanediol 0.5
30. Proline 0.2
31. Hydrolyzed conchiolin 0.2
32. Hydrolyzed collagen 0.2
33. Polyquaternium-51 0.1
34. Fragrance 0.1

(Production method)
A: Components 1 to 23 are heated to 80 ° C. and mixed.
B: Components 24-29 are heated to 80 ° C. and mixed.
C: A is added to B and emulsified.
D: C is cooled.
E: Components 30 to 34 were sequentially added to D and mixed uniformly to obtain a hair cream.

  The hair cream of Example 3 (O / W type) was evaluated in the same manner as in Example 1. As a result, it was excellent in feeling of use without stickiness and stickiness, and set power, re-hair styling, and durability of setting power. It was excellent.

Example 4: Hair mat wax (O / W type)
(Ingredient) (%)
1. Microcrystalline wax (melting point 79 ° C) 8
2. Paraffin wax (melting point 63 ° C) 5
3. Behenyl alcohol (melting point 69 ° C) 5
4). Paraffin wax (melting point 50 ° C) 5
5. Vaseline (melting point 50 ° C) 5
6). Octyl rearzone 0.5
7). Diethylaminohydroxybenzoyl hexyl benzoate 0.1
8). Octocrylene 0.1
9. Bisethylhexyloxyphenol methoxyphenyl
Triazine 0.1
10. Phytosterol 0.1
11. Cholesterol 0.1
12 Polymethylsilsesquioxane 1
13. Crystalline cellulose 1
14 Talc 5
15. Mica 5
16. Propylene glycol dicaprate 5
17. Camellia oil 0.1
18. Stearic acid 2.5
19. Glycerin fatty acid ester 0.5
20. Triceteares-4-phosphate 0.5
21. Polyoxyethylene hydrogenated castor oil (40 EO) 0.5
22. PEG-40 stearate 0.5
23. Ethylhexyl salicylate 0.2
24. Purified water remaining amount 25. Potassium hydroxide 0.1
25. Triethanolamine 0.2
26. Propylene glycol 5
27. Polyvinylpyrrolidone 0.5
28. Highly polymerized polyethylene glycol (molecular weight 2 million) 0.05
29. Hydroxypropyl methylcellulose 0.05
30. Methylparaben 0.2
31. Hyaluronic acid 0.2
32. Cationized hyaluronic acid 0.2
33. Seaweed extract 0.1
34. Fragrance 0.1

(Production method)
A: Components 1 to 23 are heated to 80 ° C. and mixed.
B: Components 24-29 are heated to 80 ° C. and mixed.
C: A is added to B and emulsified.
D: C is cooled.
E: Components 31 to 34 were sequentially added to D and mixed uniformly to obtain a hair mat wax.

  The hair wax of Example 4 (O / W type) was evaluated in the same manner as in Example 1. As a result, it was excellent in feeling of use without stickiness and stickiness, and set power, re-hair styling, and durability of setting power. It was excellent.

Claims (6)

The following components (A) to (D);
(A) Oil agent having a melting point of 60 ° C. or more and 105 ° C. or less (B) Oil agent having a melting point of 35 ° C. or more and less than 60 ° C. (C) Emulsifier (D) An ester of monohydric alcohol having 6 to 18 carbon atoms and salicylic acid An emulsified hair styling composition, wherein the mass ratio (B) / (A) of the component (A) and the component (B) is in the range of 0.1 to 10.   The emulsified hair preparation according to claim 1, wherein the content of the component (D) an ester of a monohydric alcohol having 6 to 18 carbon atoms and salicylic acid is 0.01 to 5% by mass.   The emulsified hair styling composition according to claim 1 or 2, further comprising highly polymerized polyethylene glycol as component (E). The emulsified hair styling composition according to any one of claims 1 to 3, wherein the mass ratio (B) / (A) of the component (A) to the component (B) is in the range of 0.3 to 4. The content of the component (A) in the emulsified cosmetic is 2 to 40% by mass, the content of the component (B) is 1 to 40% by mass, the content of the component (C) is 1 to 10% by mass, the component ( The emulsified hair styling composition according to any one of claims 1 to 4, wherein the content of E) is 0.001 to 1 mass%. The emulsified hair styling composition according to any one of claims 1 to 5, which is O / W type.