JP3881109B2 - Hairdresser - Google Patents

Hairdresser Download PDF

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Publication number
JP3881109B2
JP3881109B2 JP19550698A JP19550698A JP3881109B2 JP 3881109 B2 JP3881109 B2 JP 3881109B2 JP 19550698 A JP19550698 A JP 19550698A JP 19550698 A JP19550698 A JP 19550698A JP 3881109 B2 JP3881109 B2 JP 3881109B2
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JP
Japan
Prior art keywords
hair
acid
oil
fatty acid
styling agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
JP19550698A
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Japanese (ja)
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JP2000026254A (en
Inventor
清竹 多田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
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Priority to JP19550698A priority Critical patent/JP3881109B2/en
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Description

【0001】
【発明の属する技術分野】
本発明は毛髪のくせづけがしやすく、セット保持性に優れ、かつ仕上がりが油っぽくない整髪剤に関する。
【0002】
【従来の技術】
毛髪を固定、セットするための組成物としては高分子樹脂を用いるタイプと常温で固形もしくはペースト状又は粘性のある液状の油脂類や保湿剤を用いるタイプがある。前者は主にハードセット用であり、髪が固まるためスタイルの仕上がりが不自然、適用後の髪の感触がゴワつく、指や櫛で触れると白化しやすい等の欠点があるのに対し、後者には髪が固まらず自然な仕上がりのスタイルが得られるだけでなく、パサつきが抑えられる、保湿効果が付与できる、好ましい感触が付与できる等の利点がある。
【0003】
後者の整髪剤の例としては、油剤とカルボキシビニルポリマー等の増粘剤を配合したものやグリセリン等の保湿剤とカルボキシビニルポリマー等の増粘剤を配合したもの等がある。しかし、これらはいずれも、セット保持性が良好な場合には仕上がりが油っぽくなり、一方油っぽくない場合はセット保持性が十分でないという問題があった。
【0004】
【発明が解決しようとする課題】
本発明の目的は、毛髪のくせづけがしやすく、セット保持性に優れ、かつ仕上がりの油っぽさのない整髪剤を提供することにある。
【0005】
【課題を解決するための手段】
本発明者らは多価アルコールに高分子量のポリエチレングリコールと高級脂肪酸とを一定量配合すれば、くせづけがしやすいだけでなく、セット保持性と油っぽさの問題を同時に解消した整髪剤が得られることを見出した。
【0006】
すなわち、本発明は、(A)多価アルコール10〜50重量%、(B)平均分子量100万〜500万のポリエチレングリコール0.01〜2重量%、及び(C)高級脂肪酸0.01〜5重量%を含有する、ヘアクリーム、ヘアジェル及びセットローションから選ばれる形態の整髪剤を提供するものである。
【0007】
【発明の実施の形態】
本発明に用いられる(A)多価アルコールとしては、グリセリン、プロピレングリコール、ソルビトール、ジプロピレングリコール、1,3−ブチレングリコール等が挙げられるが、グリセリンが油っぽさのないしっとり感を付与する点で特に好ましい。(A)成分の配合量は、整髪剤中10〜50重量%(以下、単に「%」で示す)であるが、10〜30%が特に好ましい。該配合量が10%未満ではセット保持性や保湿効果が十分でなく、50%を超えると油っぽさが生じる。
【0008】
(B)成分のポリエチレングリコールは平均分子量100万〜500万のものが使用されるが、特にセット保持性の点から120万〜500万のものが好ましい。該分子量が100万未満ではセット保持性が十分でなく、500万を超えるとべたつきが生じてくる。また、(B)成分の配合量は、整髪剤中0.01〜2%であるが、くせづけのしやすさの点から0.05〜1.5%が好ましい。該配合量が0.01%未満ではセット保持性及びくせづけのしやすさが十分でなく、2%を超えるとべたつきが生じる。
【0009】
(C)高級脂肪酸としては、炭素数12〜30の飽和又は不飽和脂肪酸、例えばラウリン酸、ミリスチン酸、18−メチルエイコサン酸、パルミチン酸、ステアリン酸、イソステアリン酸、ベヘニン酸、セロチン酸、ヤシ油脂肪酸、オレイン酸等が挙げられる。このうち、ステアリン酸、ミリスチン酸、パルミチン酸が、セット保持の向上の点で特に好ましい。(C)成分の配合量は整髪剤中、0.01〜5%であるが、感触とセット保持性の両立の点から0.5〜3%が特に好ましい。該配合量が0.01%未満だとセット保持性が十分でなく、5%を超えると油っぽさが生じ、またくせづけがし難くなる傾向にある。
【0010】
また、本発明の整髪剤には、上記成分に加えて非イオン界面活性剤、陰イオン界面活性剤及び油剤から選ばれる1種以上を配合するのが好ましい。非イオン界面活性剤としては、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレンヒマシ油、ポリオキシエチレン硬化ヒマシ油、脂肪酸アルキロールアミド等が挙げられる。このうち、モノステアリン酸ソルビタン等のソルビタン脂肪酸エステルが好ましい。これら非イオン界面活性剤の配合量は、0.1〜10%、特に0.5〜5%が好ましい。
【0011】
陰イオン界面活性剤としては、N−アシル−N−アルキルタウリン塩、アルキルエーテルリン酸エステル塩、ポリオキシエチレンアルキルエーテル硫酸塩、アルキル硫酸エステル塩等が挙げられる。陰イオン界面活性剤の配合量は3%以下、特に0.5〜1.5%が好ましい。
【0012】
油剤としては、流動パラフィン、液状ラノリン、シリコーン油、トリグリセライド、動植物性油脂、エステル油等が挙げられる。これらの中でも、流動パラフィン、シリコーン油、エステル油等が好ましい。油剤の配合量は、0〜30%、特に5〜20%が好ましい。
【0013】
本発明の整髪剤には上記の成分に加えて、シリコーン誘導体、高級アルコール、低級アルコール、香料、色素、粉体、防腐剤、紫外線吸収剤、酸化防止剤、殺菌剤、美容成分等を使用できる。
【0014】
本発明の整髪剤は、ヘアクリーム、ヘアジェル、セットローションの形態から選ばれるものである。
【0015】
【実施例】
実施例1〜8及び比較例1〜7
表1及び表2に示すヘアクリームを製造し、くせづけのしやすさ、セット保持性、及び仕上がり後の油っぽさの少なさを評価した。なお、表1中の実施例5は、参考例であって、特許請求の範囲に含まれるものではない。
【0016】
〔評価方法〕
専門の女性パネラー10名が使用し、1人10点満点で前記の3項目について評価した。
【0017】
非常に良い:10〜9
良い:7〜8
普通:5〜6
悪い:3〜4
非常に悪い:1〜2
【0018】
<評価基準>
得られた得点を下記基準でランク分けした結果を表1及び表2に示した。
◎:総得点80点以上
○:総得点60点以上
△:総得点40点以上
×:総得点40点未満
【0019】
【表1】

Figure 0003881109
【0020】
【表2】
Figure 0003881109
【0021】
表1及び表2より、(A)、(B)及び(C)成分を前記特定量配合したときにはじめて、くせづけのしやすさ、セット保持性及び油っぽさの少なさのすべてが満足できることがわかる。
【0022】
【発明の効果】
本発明によれば、容易にくせづけでき、得られたセット保持性に優れ、かつ仕上がりが油っぽくない整髪剤が得られる。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a hair styling agent that is easily combed, has excellent set retention, and does not have an oily finish.
[0002]
[Prior art]
As a composition for fixing and setting hair, there are a type using a polymer resin and a type using a solid or pasty or viscous liquid oil or humectant at room temperature. The former is mainly used for hard sets, and the hair is solidified, so the finish of the style is unnatural, the touch of the hair after application is irritated, and the latter tends to whiten when touched with a finger or comb, whereas the latter There are advantages such as not only stiffening of the hair but not only a natural finish style but also suppression of dryness, a moisturizing effect, and a favorable feel.
[0003]
Examples of the latter hair styling agent include those in which an oil agent and a thickener such as carboxyvinyl polymer are blended, and those in which a humectant such as glycerin and a thickener such as carboxyvinyl polymer are blended. However, any of these has a problem that the finish becomes oily when the set retainability is good, whereas the set retainability is not sufficient when it is not oily.
[0004]
[Problems to be solved by the invention]
An object of the present invention is to provide a hair styling agent that is easy to cause hair kinking, is excellent in set retention, and has no oily finish.
[0005]
[Means for Solving the Problems]
The inventors of the present invention have a hair styling agent that not only makes it easy to wear when a certain amount of a high molecular weight polyethylene glycol and a higher fatty acid are blended in a polyhydric alcohol, but also eliminates the problems of set retention and oiliness at the same time. It was found that can be obtained.
[0006]
That is, the present invention, (A) a polyhydric alcohol 10 to 50 wt%, (B) polyethylene glycol having an average molecular weight 10 00,000 to 5,000,000 0.01-2 wt%, and (C) a higher fatty acid 0.01 The present invention provides a hair styling agent in a form selected from hair cream, hair gel and set lotion, containing 5% by weight.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
Examples of the polyhydric alcohol (A) used in the present invention include glycerin, propylene glycol, sorbitol, dipropylene glycol, 1,3-butylene glycol, etc., but glycerin gives an oily or moist feeling. Particularly preferred in terms. The blending amount of the component (A) is 10 to 50% by weight (hereinafter, simply referred to as “%”) in the hairdressing agent, but 10 to 30% is particularly preferable. When the blending amount is less than 10 %, the set retaining property and the moisturizing effect are not sufficient, and when it exceeds 50%, oiliness is generated.
[0008]
(B) polyethylene glycol component is an average molecular weight 10 from 00,000 to 5,000,000 is used, in particular those from the viewpoint of set-keeping of 1,200,000 to 5,000,000 is preferred. Is not sufficient set retention in molecular weight is less than 10 00000, arise stickiness exceeds 5 million. Further, the blending amount of the component (B) is 0.01 to 2% in the hair styling agent, but 0.05 to 1.5% is preferable from the viewpoint of ease of fading. If the blending amount is less than 0.01%, the set retention and ease of habitability are not sufficient, and if it exceeds 2%, stickiness occurs.
[0009]
(C) As higher fatty acids, saturated or unsaturated fatty acids having 12 to 30 carbon atoms, such as lauric acid, myristic acid, 18-methyleicosanoic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, serotic acid, coconut Examples include oil fatty acids and oleic acid. Of these, stearic acid, myristic acid, and palmitic acid are particularly preferable from the viewpoint of improving the set retention. (C) Although the compounding quantity of a component is 0.01 to 5% in a hairdressing agent, 0.5 to 3% is especially preferable from the point of coexistence of a touch and set retainability. If the blending amount is less than 0.01%, the set retainability is not sufficient, and if it exceeds 5%, oiliness is generated and it tends to be difficult to wear.
[0010]
Moreover, in addition to the said component, it is preferable to mix | blend 1 or more types chosen from a nonionic surfactant, an anionic surfactant, and an oil agent with the hairdressing agent of this invention. Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene castor oil, polyoxyethylene cured Castor oil, fatty acid alkylolamide and the like can be mentioned. Of these, sorbitan fatty acid esters such as sorbitan monostearate are preferred. The blending amount of these nonionic surfactants is preferably 0.1 to 10%, particularly preferably 0.5 to 5%.
[0011]
Examples of the anionic surfactant include N-acyl-N-alkyl taurine salt, alkyl ether phosphate ester salt, polyoxyethylene alkyl ether sulfate, alkyl sulfate ester salt and the like. The amount of the anionic surfactant is preferably 3% or less, particularly preferably 0.5 to 1.5%.
[0012]
Examples of the oil include liquid paraffin, liquid lanolin, silicone oil, triglyceride, animal and vegetable oils and fats, and ester oils. Among these, liquid paraffin, silicone oil, ester oil and the like are preferable. The blending amount of the oil is preferably 0 to 30%, particularly preferably 5 to 20%.
[0013]
In addition to the above-described components, the hair styling agent of the present invention may contain silicone derivatives, higher alcohols, lower alcohols, fragrances, pigments, powders, preservatives, ultraviolet absorbers, antioxidants, bactericides, cosmetic ingredients, and the like .
[0014]
Styling agent of the present invention, Ru der those selected from hair cream, hair gel, Se Ttorosho down form.
[0015]
【Example】
Examples 1-8 and Comparative Examples 1-7
The hair creams shown in Table 1 and Table 2 were produced and evaluated for ease of habitability, set retention, and low oiliness after finishing. In addition, Example 5 in Table 1 is a reference example and is not included in the scope of claims.
[0016]
〔Evaluation methods〕
Ten professional female panelists used and evaluated the above three items with a maximum of 10 points per person.
[0017]
Very good: 10-9
Good: 7-8
Normal: 5-6
Bad: 3-4
Very bad: 1-2
[0018]
<Evaluation criteria>
The results of ranking the obtained scores according to the following criteria are shown in Tables 1 and 2.
◎: Total score of 80 points or more ○: Total score of 60 points or more △: Total score of 40 points or more ×: Total score of less than 40 points
[Table 1]
Figure 0003881109
[0020]
[Table 2]
Figure 0003881109
[0021]
From Table 1 and Table 2, it is only when the specific amounts of the components (A), (B) and (C) are blended that all the ease of habitability, set retention and low oiliness are obtained. It turns out that it is satisfactory.
[0022]
【The invention's effect】
According to the present invention, it is possible to obtain a hair styling agent that can be easily hazy, has excellent set retention, and does not have an oily finish.

Claims (2)

(A)多価アルコール10〜50重量%、(B)平均分子量100万〜500万のポリエチレングリコール0.01〜2重量%、及び(C)高級脂肪酸0.01〜5重量%を含有する、ヘアクリーム、ヘアジェル及びセットローションから選ばれる形態の整髪剤。(A) a polyhydric alcohol 10 to 50%, containing (B) polyethylene glycol 0.01 to 2 wt% of the average molecular weight 10 from 00,000 to 5,000,000, and (C) a higher fatty acid 0.01 to 5 wt% , Hair cream, hair gel and set lotion . ポリエチレングリコールの平均分子量が120万〜500万である請求項1記載の整髪剤。  The hair styling agent according to claim 1, wherein polyethylene glycol has an average molecular weight of 1,200,000 to 5,000,000.
JP19550698A 1998-07-10 1998-07-10 Hairdresser Expired - Fee Related JP3881109B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19550698A JP3881109B2 (en) 1998-07-10 1998-07-10 Hairdresser

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19550698A JP3881109B2 (en) 1998-07-10 1998-07-10 Hairdresser

Publications (2)

Publication Number Publication Date
JP2000026254A JP2000026254A (en) 2000-01-25
JP3881109B2 true JP3881109B2 (en) 2007-02-14

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Country Status (1)

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4574873B2 (en) * 2001-02-16 2010-11-04 ポーラ化成工業株式会社 Cosmetics for hair
JP2002370938A (en) * 2001-06-18 2002-12-24 Kanebo Ltd Hair cosmetic
JP4733325B2 (en) * 2001-09-28 2011-07-27 株式会社コーセー Hairdressing composition
JP3827992B2 (en) * 2001-11-07 2006-09-27 花王株式会社 Particles and production method thereof
US20040141926A1 (en) 2002-11-08 2004-07-22 Raquel De Carvalho Cosmetic composition for the hair with a waxy effect, in aerosol form
JP5839777B2 (en) * 2010-03-25 2016-01-06 株式会社マンダム Powder hairdressing agent
JP5856375B2 (en) * 2011-01-18 2016-02-09 株式会社コーセー Emulsion hair styling

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