JP2017206483A - Hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hair cosmetic, which is excellent in smooth passing of fingers during rinsing and providing hair with bounce and resilience and voluminous feeling after drying, and to provide a hair cosmetic exhibiting excellent dyeability, for example the hair cosmetic being a color rinse containing a dye and exhibiting excellent dyeability.SOLUTION: According to the present invention, there is provided a hair cosmetic composition comprising component A: 0.05 to 2.0 mass% of silicone powder; component B: a microcrystalline wax having a melting point of 72°C or higher, and/or 0.5 to 6.0 mass% of a polyethylene wax having a melting point of 83°C or higher, and component C: 0.1 to 2.0 mass% of a cationic polymer.SELECTED DRAWING: None

Description

  The present invention relates to a hair cosmetic. Specifically, the present invention relates to a hair cosmetic that is preferably used as a hair rinse, a hair conditioner, a hair treatment, a hair manicure or the like.

  Traditionally used in hair rinses, hair conditioners, hair treatments, etc., applied to shampooed hair and then washed away, to give the hair a finger when rinsing, a comb of hair after drying, a smooth feeling, a moist feeling, etc. Hair cosmetics that exhibit the effect of improving are widely used (see, for example, Patent Documents 1 to 3).

  In addition, for the purpose of improving the decrease in the volume of the entire hair due to the hair becoming thinner due to aging, a hair rinse composition having an effect of giving the hair a firmness, volume, and volume has been proposed (for example, (See Patent Document 4).

JP 2010-265195 A JP 2012-171890 A JP 2014-1111574 A JP 2009-120557 A

  However, the effects of the above prior art are not yet sufficient, and the present situation is that further excellent elasticity and volume feeling are required.

  Therefore, the present invention has been made in view of the above prior art, and provides a hair cosmetic that is excellent in fingering of the hair at the time of rinsing and gives the hair a firmness, firmness and volume after drying. With the goal. Moreover, in the case of hair cosmetics, such as a color rinse which mix | blended dye, it aims at providing the hair cosmetics which exhibit the outstanding dyeability.

  As a result of intensive studies, the inventor has formulated silicone powder, microcrystalline wax having a melting point of 72 ° C. or higher and / or polyethylene wax having a melting point of 83 ° C. or higher, and a cationic polymer in a specific blending amount. The inventors have found that a hair cosmetic that is excellent in fingering during rinsing and that gives the hair a firm, firm feel and volume after drying has been obtained, and the invention has been completed.

That is, this invention contains 0.05-2.0 mass% of the following component A, 0.5-6.0 mass% of the following component B, and 0.1-2.0 mass% of the following component C. A hair cosmetic characterized by the above is provided.
Component A: Silicone powder Component B: Microcrystalline wax having a melting point of 72 ° C. or higher and / or polyethylene wax having a melting point of 83 ° C. or higher Component C: Cationic polymer

The hair cosmetic composition preferably further contains 0.1 to 5.0% by mass of the following component D.
Component D: Volatile silicone oil, methyl polysiloxane less kinematic viscosity ^{1 mm} 2 / s or more 20 mm ² / s at 25 ° C., and a kinematic viscosity of less than ^{1 mm} 2 / s or more 20 mm ² / s at 25 ° C. methylphenylpolysiloxanes Silicone oil selected from the group consisting of siloxanes

  Component A is preferably a methylsiloxane network polymer.

  Component C includes O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose, dimethylmethylenepiperidinium chloride, dimethyldiallylammonium chloride / acrylamide copolymer, and vinylpyrrolidone / N, N-dimethyl chloride. It is preferably a cationic polymer selected from the group consisting of aminoethyl methacrylic acid copolymer diethyl sulfate.

The hair cosmetic composition preferably further contains the following component E.
Component E: Dye

  When the said hair cosmetics contain the component E, it is preferable not to contain a cationic surfactant or to contain less than 0.5 mass%. Furthermore, it is preferable not to contain an anionic surfactant or to contain less than 0.1 mass%.

    The hair cosmetic is preferably a hair rinse, a hair conditioner, a hair treatment or a hair manicure.

  Since the hair cosmetic composition of the present invention has the above-described configuration, it is excellent as a finger when rinsed with water after being applied to the hair. Further, after drying, it has an effect of giving the hair a firmness and a firm feeling. Furthermore, when the hair cosmetic of the present invention is a hair cosmetic such as a color rinse containing a dye, the hair cosmetic of the present invention is also excellent in dyeability.

  The hair cosmetic composition of the present invention contains at least a silicone powder; a microcrystalline wax having a melting point of 72 ° C. or higher and / or a polyethylene wax having a melting point of 83 ° C. or higher; and a cationic polymer. In the present specification, the “silicone powder” may be referred to as “component A”. In addition, the above-mentioned “microcrystalline wax having a melting point of 72 ° C. or higher and / or polyethylene wax having a melting point of 83 ° C. or higher” may be referred to as “component B”. Further, the “cationic polymer” may be referred to as “component C”. The hair cosmetic composition of the present invention contains at least Component A, Component B, and Component C.

The hair cosmetic composition of the present invention may further contain components other than the above components A to C, which are essential components, depending on the application. Hair cosmetic composition of the present invention of the present invention, further, volatile silicone oils, 25 methylpolysiloxane of less than ^{1 mm} 2 / s or more 20 mm ² / s kinematic viscosity at ° C., and 25 kinematic viscosity at ° C. is ^{1 mm} 2 / s It is preferable to include a silicone oil selected from the group consisting of methylphenylpolysiloxane of less than 20 mm ² / s. In the present specification, the "volatile silicone oil, methyl polysiloxane less kinematic viscosity ^{1 mm} 2 / s or more 20 mm ² / s at 25 ° C., and kinetic viscosity at 25 ℃ ^1mm 2 / s or more 20 mm ² / s The “silicone oil selected from the group consisting of less than methylphenyl polysiloxane” may be referred to as “component D”.

  The hair cosmetic composition of the present invention may be a hair dye composition containing a dye. In the present specification, the “dye” may be referred to as “component E”.

  The hair cosmetic composition of the present invention may further contain components other than A to E (other components). As for said component, for example, component A, component B, component C, component D, component E, and another component, only 1 type may respectively be used and 2 or more types may be used.

  The hair cosmetic of the present invention is a cosmetic used by applying to hair. Among these, the hair cosmetic composition of the present invention is preferably a hair cosmetic composition that is used after being applied to the hair, from the viewpoint of being excellent as a finger when rinsing with water. Examples of the hair cosmetic of the present invention include hair rinse, hair conditioner, hair treatment and the like. In addition, said hair rinse, a hair conditioner, and a hair treatment are not clearly distinguished, respectively, and may represent the same thing. Furthermore, the hair cosmetic composition of the present invention is preferably a hair dye composition containing a dye. Examples of the hair cosmetic composition of the present invention that is the hair dye include color rinses, color conditioners, color treatments, and hair manicures. The color rinse, the color conditioner, and the color treatment are not clearly distinguished from each other, and may represent the same thing.

[Component A: Silicone powder]
Component A is silicone powder (ie, silicone fine particles). Component A adsorbs to the hair. As a result, the hairs get caught and the whole hair feels soft and voluminous. For this reason, the effect which gives the hair a volume feeling by using component A is acquired. That is, after applying the hair cosmetic composition of the present invention to hair, rinsing with water, and drying the hair, the hair becomes easy to stand up, and the whole hair has a soft and voluminous hairstyle (the volume of the whole hair is large). Hairstyle) can be formed. Component A includes, for example, a methylsiloxane network polymer. The above-mentioned methylsiloxane network polymer is a compound represented by the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Volume 2, 2014, p.2751-2752): POLYMETHYLSILSESQUIOXANE (polymethylsilsesquioxane). It is. As for component A, only 1 type may be used and 2 or more types may be used.

  The shape of component A is not particularly limited, but a spherical shape is preferable from the viewpoint of improving fingering during washing. The aspect ratio of component A is not particularly limited, but is preferably 0.9 or more (0.9 to 1.0), more preferably 0.95 or more.

  The average particle diameter of component A is not particularly limited, but is preferably 2.0 to 30.0 μm, more preferably 5.0 to 15.0 μm, and still more preferably from the viewpoint of improving finger feeling and volume feeling during washing. Is 5.0 to 11.0 μm. The average particle diameter is a volume average particle diameter, and can be measured by, for example, a laser diffraction / scattering particle diameter distribution measuring apparatus.

 Component A may be a commercially available product. Specific examples of the above-mentioned commercially available products include, for example, a product name “Tospearl 2000B” manufactured by Momentive Performance Materials Japan LLC; a product name “Tospearl 1110” manufactured by Momentive Performance Materials Japan LLC. Momentive Performance Materials Japan G.K., trade name “Tospearl 145”; Momentive Performance Materials Japan G.K., trade name “Tospearl 150KA”.

  Content of the component A in 100 mass% of hair cosmetics of this invention is 0.05-2.0 mass%, Preferably it is 0.1-1.0 mass%. When the content is 0.05% by mass or more, an effect of giving the hair a volume feeling can be obtained. Moreover, when the said content is 2.0 mass% or less, it is easy to follow the finger | toe at the time of washing | cleaning and it can prevent that hair is caught. Content of the said component A is a total amount of content of all the components A in the hair cosmetics of this invention.

[Component B: Microcrystalline wax having a melting point of 72 ° C. or higher and / or polyethylene wax having a melting point of 83 ° C. or higher]
Component B is a microcrystalline wax having a melting point of 72 ° C. or higher and / or a polyethylene wax having a melting point of 83 ° C. or higher. That is, one or both of a microcrystalline wax having a melting point of 72 ° C. or higher and a polyethylene wax having a melting point of 83 ° C. or higher. Component B reinforces the hair by coating the surface of the hair and improves the slipperiness of the hair surface. Furthermore, the effect of component A is enhanced by adsorbing component A and retaining it in the hair. For this reason, the effect which gives elasticity and firmness to hair by using component B is acquired. In addition, the effect of giving the hair a volume feeling is improved. In addition, fingering when rinsing with water after application to hair is improved. In the present specification, the “microcrystalline wax having a melting point of 72 ° C. or higher” may be referred to as “component B1”, and the “polyethylene wax having a melting point of 83 ° C. or higher” may be referred to as “component B2”. There is. As for component B1 and component B2, only 1 type may be used respectively and 2 or more types may be used.

  The melting point of component B1 is 72 ° C. or higher, preferably 72 to 104 ° C., more preferably 85 to 91 ° C., from the viewpoint of adsorption of component A. Specific examples of component B1 include microcrystalline wax having a melting point of 75 ° C., microcrystalline wax having a melting point of 88 ° C., and microcrystalline wax having a melting point of 101 ° C.

  Component B2 has a melting point of 83 ° C. or higher, preferably 83 to 105 ° C., more preferably 95 to 105 ° C., from the viewpoint of adsorption of component A. Specific examples of component B2 include polyethylene wax having a melting point of 83 to 90 ° C., polyethylene wax having a melting point of 95 to 105 ° C., and the like.

 A commercial item may be used for component B1. Specific examples of the above-mentioned commercially available products include, for example, trade name “HI-MIC-2065” (melting point 75 ° C.) manufactured by Nippon Seiwa Co., Ltd .; trade name “HI-MIC-1090” (melting point 88) manufactured by Nippon Seiwa Co., Ltd. ° C); manufactured by Nippon Seiwa Co., Ltd., trade name “HI-MIC-2095” (melting point: 101 ° C.) and the like.

  A commercial item may be used for component B2. Specific examples of the above-mentioned commercially available products include, for example, a product name “PERFORMALENE PL POLYETHLENE” (melting point: 83 to 90 ° C.) manufactured by New Phase Technologies; ° C) and the like.

  Content of component B in 100 mass% of hair cosmetics of this invention is 0.5-6.0 mass%, Preferably it is 1.0-4.0 mass%. When the content is 0.5% by mass or more, an effect of giving hair a sense of volume can be obtained. Moreover, when the content is 6.0% by mass or less, it is easy to follow a finger when washing, and a volume feeling can be maintained. The content of component B is the total content of all components B in the hair cosmetic of the present invention, that is, the content of all components B1 and B2 in the hair cosmetic of the present invention. Total amount.

  As the component B, the component B1 is more preferable from the viewpoint of finger washing. The content of component B1 in 100% by mass of the hair cosmetic composition of the present invention is preferably 0.5 to 6.0% by mass, more preferably 1.0 to 4.0% by mass. Content of the said component B1 is a total amount of content of all the components B1 in the hair cosmetics of this invention.

[Component C: Cationic polymer]
Component C is a cationic polymer. Component C adheres to the negatively charged portion of the hair surface, thereby reducing the squeaky feeling during water washing and reinforcing the hair. For this reason, the use of Component C provides excellent fingering when rinsing with water after application to the hair. In addition, the effect of giving elasticity and firmness to the hair is improved. As for component C, only 1 type may be used and 2 or more types may be used.

  Examples of the cationic polymer (cationic polymer) include quaternary nitrogen-containing cellulose ether derivatives such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl chloride chloride; O- [2-hydroxy chloride]. Quaternary nitrogen-containing guar gum derivatives such as -3- (trimethylammonio) propyl] guar gum; diallyl quaternary ammonium salt polymers such as dimethylmethylenepiperidinium chloride; diallyl such as dimethyldiallylammonium chloride / acrylamide copolymer Quaternary ammonium salt / acrylamide copolymer; quaternized polyvinylpyrrolidone derivative such as vinyl pyrrolidone / N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate; cationic starch; polyglycol polyamine condensate; Acid dimethylaminohydroxypropyl ethylene triamine copolymers; and cationic dextran and the like. Among these, O- [2-hydroxy-3- (trimethylammonio) propyl chloride] is an effective compound that accumulates on the hair surface and reinforces the hair, and is particularly excellent in the effect of giving firmness and firmness upon repeated use. Hydroxyethyl cellulose, dimethylmethylene piperidinium chloride, dimethyldiallylammonium chloride / acrylamide copolymer, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, and more preferably O- [2 chloride -Hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose.

  Content of the component C in 100 mass% of hair cosmetics of this invention is 0.1-2.0 mass%, Preferably it is 0.3-1.0 mass%. When the content is 0.1% by mass or more, excellent fingering when rinsing with water is exhibited. In addition, when the content is 2.0% by mass or less, the flexibility after drying is maintained, and in the case of hair cosmetics such as color rinses containing a dye, the dyeing property is lowered. Can be prevented. Content of the said component C is a total amount of content of all the components C in the hair cosmetics of this invention. In particular, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride, dimethylmethylenepiperidinium chloride, dimethyldiallylammonium chloride-acrylamide copolymer, and vinylpyrrolidone N, N-dimethylaminoethyl It is preferable that the total content of the methacrylic acid copolymer diethyl sulfate satisfies the above range.

  Further, the content of chloride O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose in 100% by mass of the hair cosmetic composition of the present invention is 0.1 to 2.0% by mass. Is more preferable, and 0.3 to 1.0 mass% is more preferable.

[Component D: Volatile silicone oil, etc.]
Component D, volatile silicone oils, of less than 20 mm ² / s kinematic viscosity of ^{1 mm} 2 / s or more at 25 ° C. methylpolysiloxane, and kinematic viscosity is less than ^{1 mm} 2 / s or more 20 mm ² / s at 25 ° C. methylphenyl A silicone oil (at least one silicone) selected from the group consisting of polysiloxanes. By using the component D, the excellent fingering at the time of rinsing with water can be further improved without inhibiting the effect of giving the hair a volume feeling. In the present specification, “volatile silicone oil” refers to a silicone oil having a boiling point of 250 ° C. or less at a pressure of 1 atm. The boiling point of the volatile silicone oil at 1 atm is preferably 100 to 250 ° C, more preferably 100 to 230 ° C. Component D may use only 1 type and may use 2 or more types.

Examples of component D include cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylcyclopolysiloxane; octamethyltrisiloxane, tetradecamethylhexasiloxane, kinematic viscosity at 25 ° C. There ^{1 mm} 2 / s or more 20mm less than ² / s (preferably not more than 10 mm ² / s) methylpolysiloxane, and a kinematic viscosity at 25 ℃ ^1mm 2 / s or more 20mm less than ² / s (preferably 10 mm ² / s or less ) And chain silicones such as methylphenylpolysiloxane. Among these, volatile silicone oils are preferable and cyclic silicones are particularly preferable from the viewpoint that the amount of adhesion to hair is small after drying and does not impair the sense of volume of hair.

  As for content of the component D in 100 mass% of hair cosmetics of this invention, 0.1-5.0 mass% is preferable, More preferably, it is 0.5-3.0 mass%. When the content is 0.1% by mass or more, excellent fingering when rinsing with water is further improved. Moreover, when the said content is 5.0 mass% or less, the hair after drying does not become heavy and a volume-up feeling can be maintained. Content of the said component D is a total amount of content of all the components D in the hair cosmetics of this invention.

  Especially, content of volatile silicone oil in 100 mass% of hair cosmetics of this invention has preferable 0.1-5.0 mass%, More preferably, it is 0.5-3.0 mass%. Furthermore, it is preferable that content of cyclic silicone in 100 mass% of hair cosmetics of this invention is 0.1-5.0 mass%, More preferably, it is 0.5-3.0 mass%. is there.

[Component E: Dye]
The hair cosmetic composition of the present invention may be a hair dye composition containing a dye (component E). Component E includes basic dyes, HC dyes, nitro dyes, disperse dyes, natural dyes, and the like. Of these, basic dyes and HC dyes are preferred. As for the component E, only 1 type may be used and 2 or more types may be used.

  The basic dyes include basic blue 75, basic blue 77, basic blue 99, basic blue 124, basic brown 16, basic brown 17, basic red 51, basic red 76, basic yellow. 57, basic yellow 87, basic orange 2, basic orange 31 and the like.

  Examples of the HC dye include HC blue 2, HC blue 5, HC blue 11, HC blue 12, HC blue 13, HC red 1, HC red 13, HC orange 1, HC yellow 2, HC yellow 4, HC purple 1, etc. Is mentioned.

  The content of component E in 100% by mass of the hair cosmetic composition of the present invention is not particularly limited, but is preferably 0.005 to 2.0% by mass, more preferably from the viewpoint of improving dyeability and preventing background stains. 0.01 to 1.0% by mass. Content of the said component E is a total amount of content of all the components E in the hair cosmetics of this invention. Among them, the total amount of the basic dye content and the HC dye content in 100% by mass of the hair cosmetic composition of the present invention is preferably 0.005 to 2.0% by mass, more preferably 0. 0.01 to 1.0% by mass.

  Specific examples of preferable component E include, for example, a basic blue 75 content of 0.01 to 0.05% by mass and a basic tea 16 content of 0 in 100% by mass of the hair cosmetic composition of the present invention. Examples include a combination of 0.05 to 1.0 mass%, HC yellow 2 content of 0.01 to 0.1 mass%, and HC blue 2 content of 0.05 to 1.0 mass%.

  The hair cosmetic composition of the present invention preferably contains a polyhydric alcohol from the viewpoints of formulation stability and dye solubility. Examples of the polyhydric alcohol include ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, and mannitol. Sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and the like. The content of the polyhydric alcohol in 100% by mass of the hair cosmetic composition of the present invention is not particularly limited, but is preferably 0.5 to 10.0% by mass, more preferably 1.0 to 5.0% by mass. is there. The content of the polyhydric alcohol is the total content of all the polyhydric alcohols in the hair cosmetic composition of the present invention.

  The hair cosmetic composition of the present invention preferably contains a higher alcohol from the viewpoint of stability over time. Examples of the higher alcohol include cetyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol, and oleyl alcohol. Although content of the higher alcohol in 100 mass% of hair cosmetics of this invention is not specifically limited, 1.0-10.0 mass% is preferable, More preferably, it is 3.0-8.0 mass%. . The content of the higher alcohol is the total content of all the higher alcohols in the hair cosmetic composition of the present invention.

  It is preferable that the hair cosmetic composition of the present invention contains a hydrocarbon oil from the viewpoint of ease of adaptation at the time of application. Examples of the hydrocarbon oil include α-olefin oligomer, light isoparaffin, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, liquid isoparaffin, and liquid paraffin. Although content of hydrocarbon oil in 100 mass% of hair cosmetics of this invention is not specifically limited, 0.5-10.0 mass% is preferable, More preferably, it is 1.0-5.0 mass%. is there. The content of the hydrocarbon oil is a total content of all the hydrocarbon oils in the hair cosmetic composition of the present invention.

  The hair cosmetic composition of the present invention preferably contains a nonionic surfactant (nonionic surfactant) from the viewpoint of stability over time. Examples of the nonionic surfactant include polyoxyethylene fatty acid, glycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxy Examples include ethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyglycerin alkyl ether, polyoxyethylene (cured) castor oil, and fatty acid alkylolamide. Although content of nonionic surfactant in 100 mass% of hair cosmetics of this invention is not specifically limited, 0.5-10.0 mass% is preferable, More preferably, it is 1.0-5.0 mass. %. The content of the nonionic surfactant is the total content of all the nonionic surfactants in the hair cosmetic composition of the present invention.

  The hair cosmetic composition of the present invention contains water. The water is not particularly limited, but purified water is preferable. Although content of water in 100 mass% of hair cosmetics of this invention is not specifically limited, 50.0-90.0 mass% is preferable, More preferably, it is 60.0-80.0 mass%.

  The hair cosmetic composition of the present invention may be substantially free of a cationic surfactant from the viewpoint of being able to exert excellent fingering upon rinsing with water by Component B and Component C. More specifically, the hair cosmetic composition of the present invention preferably contains no cationic surfactant or less than 0.5% by mass. Furthermore, it is more preferable that the hair cosmetic composition of the present invention does not contain a cationic surfactant or contains less than 0.1% by mass. In particular, when the hair cosmetic composition of the present invention contains component E, it is preferable that the above conditions are satisfied. Cationic surfactant is thought to be caused by having a relatively small molecular weight and a molecular weight close to that of a dye, but it inhibits dye dyeing and lowers the dyeability of hair cosmetics (hair dyes). There is. On the other hand, Component C is preferable because it does not inhibit dyeing. Examples of the cationic surfactant include monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, trialkyl quaternary ammonium salts, monoalkyl ether quaternary ammonium salts, alkylamines, and fatty acid amidoamines. Can be mentioned.

  The hair cosmetic composition of the present invention preferably contains substantially no anionic surfactant from the viewpoint of dyeability. More specifically, the hair cosmetic composition of the present invention preferably contains no anionic surfactant or less than 0.1% by mass. Furthermore, it is more preferable that the hair cosmetic composition of the present invention does not contain an anionic surfactant or contains less than 0.01% by mass. Examples of the anionic surfactant include sodium sulfate lauryl sulfate, triethanolamine lauryl sulfate, sodium myristyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate and sodium cetyl sulfate; polyoxyethylene lauryl ether sulfate sodium; , Polyoxyethylene alkyl ether sulfates such as sodium polyoxyethylene myristyl sulfate; α-olefin sulfonates such as sodium tetradecene sulfonate; N-acylmethyl taurine salts such as taurine sodium and palm oil fatty acid methyl taurine sodium; sulfo Sulfosuccinic acid alkyl salts such as dioctyl sodium succinate and lauryl disodium sulfosuccinate; sulfosuccinic acid polyoxyethylene alkyl salts such as polyoxyethylene lauryl disodium sulfosuccinate; monos such as sodium lauryl phosphate, sodium cetyl phosphate, diethanolamine cetyl phosphate Alkyl phosphate ester salt; sodium polyoxyethylene lauryl ether phosphate, sodium polyoxyethylene cetyl ether phosphate, sodium polyoxyethylene oleyl ether phosphate, sodium polyoxyethylene alkylphenyl ether phosphate, polyoxyethylene alkylphenyl ether phosphorus Polyoxyethylene alkyl ether phosphates such as acid triethanolamine; Lauroyl monkey N-acyl sarcosine salts such as kosine potassium, lauroyl sarcosine triethanolamine, myristoyl sarcosine sodium, coconut oil fatty acid sarcosine sodium; lauroyl methylalanine sodium, lauroyl methylalanine triethanolamine, myristoyl methylalanine sodium, coconut oil fatty acid methylalanine sodium, etc. N-acyl-N-methyl-β-alanine salt; sodium lauroylglutamate, triethanolamine lauroylglutamate, sodium myristoylglutamate, potassium stearoylglutamate, disodium stearoylglutamate, coconut oil fatty acid sodiumsodium glutamate, coconut oil fatty acid acylglutamate tri N-acyl glutamates such as ethanolamine; N-acylglycine salts such as potassium glyceryl fatty acid acylglycine, sodium coconut oil fatty acid acylglycine; sodium lauryl glycol acetate (sodium dodecane-1,2-diol acetate), potassium lauryl glycol acetate, myristyl glycol acetate sodium, myristyl glycol acetate Alkyl ether glycol acetates such as potassium, sodium palmityl glycol acetate, potassium palmityl glycol acetate, sodium stearyl glycol acetate, potassium stearyl glycol acetate, sodium behenyl glycol acetate, potassium behenyl glycol acetate and the like.

  The hair cosmetic composition of the present invention preferably contains no non-volatile silicone oil from the viewpoint of maintaining a sense of increasing volume. More specifically, it is preferable that the hair cosmetic composition of the present invention does not contain non-volatile silicone or contains less than 0.1% by mass. Furthermore, it is more preferable that the hair cosmetic composition of the present invention does not contain nonvolatile silicone or contains less than 0.01% by mass. Examples of the non-volatile silicone include highly polymerized methylpolysiloxane having an average degree of polymerization of 650 to 7000.

  The hair cosmetic composition of the present invention comprises a refreshing agent such as l-menthol, 1,8-cineole and camphor; a preservative such as phenoxyethanol; a vegetable oil such as olive oil, macadamia nut oil and argan oil; a hygroscopic agent such as silica; Derivatives thereof, collagen or derivatives thereof, amino acids or derivatives thereof, antioxidants, sequestering agents, vitamins, animal and plant extracts, pearlizing agents, coloring agents, fragrances, pH adjusting agents (for example, citric acid or salts thereof, lactic acid Or a salt thereof) or the like.

  Specific examples of the hair cosmetic composition of the present invention include hair rinses, hair conditioners, hair treatments, and the like. Specific examples of the hair cosmetic composition of the present invention containing a dye include color (hair) rinse, color (hair) conditioner, color (hair) treatment, hair manicure and the like.

  The pH of the hair cosmetic composition of the present invention is not particularly limited, but is preferably 4.0 to 8.0, more preferably 5.0 to 8.0 from the viewpoint of dyeability and the like.

  The dosage form of the hair cosmetic composition of the present invention is not particularly limited, and examples thereof include liquid, viscous liquid, gel, emulsion, and cream. Of these, cream is preferable from the viewpoint of dyeability and texture.

  The hair cosmetic composition of the present invention containing a dye is not particularly limited. For example, the hair can be dyed gray, black, brown, green, blue-violet, or the like. More preferably, they are gray, black, and brown. For this reason, it can be used as a hair dye for white hair dyeing, fashion dyeing and the like, and from the viewpoint of color tone, it is preferably a hair dye for white hair dyeing.

  Hair cosmetics such as the above hair rinses, hair conditioners, hair treatments, color rinses, color conditioners, and color treatments are hair treatment agents that are generally used at the time of shampooing and washed off after being applied to the hair after shampooing. The hair cosmetic is used, for example, by washing the hair with a shampoo, and then applying the hair cosmetic to the hair, immediately after application or acclimatizing the hair for about 3 to 10 minutes, and then washing it off. In addition, you may use the said hair cosmetics before hair washing. In that case, the said hair cosmetics are used by the usage method which apply | coats to wet hair, wash | cleans immediately after application | coating, or after making it adjust to hair for about 3 to 10 minutes, and also shampoos hair.

  The hair nail polish is a hair treatment agent that is generally applied to dry hair. The hair nail polish is used, for example, by applying hair nail polish to dry hair, leaving it for about 5 to 30 minutes after application, washing it off, and washing it with shampoo.

  The manufacturing method of the hair cosmetics of this invention is not specifically limited, It can manufacture according to a conventional method. Specific examples include the following methods. For example, in the case of color rinses, color conditioners, and color treatments, gradually add the oil phase heated to 70-90 ° C to the water phase that has been sufficiently dissolved by heating to 70-90 ° C and stir well for 5 minutes. , Emulsification. After emulsification, the solution is cooled to 20 to 40 ° C., a dye dissolved in purified water is added, and after sufficiently uniform stirring, a pH adjuster is added and sufficiently uniform stirring to obtain a creamy hair cosmetic.

  The hair cosmetic composition of the present invention contains the above components A to C as essential components. By blending component A and component B, component B keeps component A in the hair, component A hooks the hairs together to give a sense of volume, and component C coats the hair surface, so Enhance the feeling. Furthermore, by blending component D, the fingering during rinsing is good, and the effect of maintaining a sense of volume without drying the hair after drying is further improved. The hair cosmetic composition of the present invention has a composition in which the blending components are easily attached to the hair. Therefore, when the dye is further blended, it is considered that the dye adhesion is improved, but the dyeability is improved.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. In addition, the compounding quantity (the compounding quantity in 100 mass% of hair cosmetics) in the table | surface was shown by the compounding quantity (unit: mass%) of pure part.

Examples 1-24, Comparative Examples 1-7
Each component was blended according to the blending components and blending amounts (unit: mass%) in the following table to prepare hair cosmetics. The hair cosmetic is a hair rinse (hair treatment, hair conditioner), among which the hair cosmetics of Examples 18 to 24 are a color rinse (color treatment, color conditioner). The properties of the obtained hair cosmetic were creamy. Moreover, all the pH values of the obtained hair cosmetics were 5.0. The pH was measured using a pH meter (trade name “desktop pH meter F-74” manufactured by Horiba, Ltd.).

  The hair cosmetics obtained in the above Examples and Comparative Examples were subjected to the following evaluation test. The evaluation results are shown in the table.

Test Example 1: Evaluation as per finger Untreated hair sheet as a test hair sheet (Bulux Co., Ltd., 25 cm long, using a hair sheet in which hair is planted in 3.5 cm square. Weight of hair 4 g) Was used.
The hair sheet for testing was washed with a commercially available shampoo, and then lightly drained and used for the following preparation. Apply 5.0 g of each of the hair cosmetics obtained in the Examples and Comparative Examples immediately after production to the test hair sheet, and blend it into the whole hair bundle (hair) using a brush for 1 minute and leave it for 5 minutes. A hair sheet for evaluation (1) was prepared.
The hair sheet for evaluation (1) obtained above was evaluated according to the following criteria when the hair cosmetic was sufficiently washed away with fingers using 40 ° C. lukewarm water. In addition, 4 expert evaluators performed the evaluation according to the finger.
<Evaluation criteria as per finger>
◎ (Excellent): Very good fingering.
○ (Good): Good fingering.
X (Bad): Bad fingering.

Test Example 2: Evaluation of voluminous feel and firmness / toughness After the hair cosmetic was thoroughly washed out from the hair sheet for evaluation (1) in Test Example 1 above, towel drying was performed. Then, it dried over one day and obtained the hair sheet (2) for evaluation.
The hair sheet for evaluation (2) obtained above was visually observed, and the volume feeling was evaluated according to the following criteria. Moreover, the hair sheet for evaluation (2) obtained above was touched by hand, and the firmness and stiffness were evaluated according to the following criteria. The above evaluation was performed by four expert evaluators.
<Evaluation criteria for volume>
A (Excellent): Very voluminous.
○ (Good): Sufficient volume.
X (defect): There is no volume feeling.
<Evaluation criteria for elasticity and elasticity>
A (excellent): There is a very firm feeling.
○ (Good): Sufficient tension.
X (defect): There is no harshness.

  Furthermore, about the hair cosmetics (hair coloring material) obtained in the Examples of Examples 18 to 24, the dyeability of the following Test Example 3 was evaluated.

Test Example 3: Evaluation of Dyeability As a test hair bundle, an untreated yak hair bundle (manufactured by Stuffs, length 10 cm, weight 1 g) was used.
The test hair bundle was washed with a commercially available shampoo, then lightly drained and used for the following preparation. To the test hair bundle, 1.0 g of the hair cosmetic immediately after production was applied, and the whole hair bundle (hair) was blended with a brush for 1 minute. Next, after leaving for 5 minutes, the hair cosmetic was sufficiently washed out from the hair bundle using 40 ° C. lukewarm water, towel-dried, and then sufficiently dried using a dryer to prepare an evaluation hair bundle.
The evaluation hair bundle obtained above was visually observed, and the dyeability was evaluated according to the following criteria. The dyeability was evaluated by four expert evaluators.
<Evaluation criteria for dyeability>
(Excellent): It is dye | stained very deeply.
○ (Good): Stained sufficiently.
X (defect): Dyeing is light.

The details of the main components described in the table are as follows.
(Component A)
Polymethylcissesquioxane * 1: Product name “Tospearl 2000B” manufactured by Momentive Performance Materials Japan GK
Polymethylcissesquioxane * 2: Product name “Tospearl 145” manufactured by Momentive Performance Materials Japan GK
Polymethylcissesquioxane * 3: Product name “Tospearl 1110” manufactured by Momentive Performance Materials Japan GK
Polymethylcissesquioxane * 4: Product name “Tospearl 150KA”, manufactured by Momentive Performance Materials Japan GK
(Other than component A)
Silica: manufactured by Nippon Aerosil Co., Ltd., trade name “AEROSIL 300”
(Component B)
Microcrystalline wax * 5: Nippon Seiwa Co., Ltd., trade name “HI-MIC-1090”, melting point 88 ° C.
Microcrystalline wax * 6: Nippon Seiwa Co., Ltd., trade name “HI-MIC-2065”, melting point 75 ° C.
(Other than component B)
Microcrystalline wax * 7: Nippon Seiwa Co., Ltd., trade name “HI-MIC-2045”, melting point 64 ° C.
Beeswax: Miki Chemical Industry Co., Ltd., trade name "Kousan Dash Beeswax"
(Component C)
O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride: manufactured by Toho Chemical Co., Ltd., trade name “Catinal HC-100”
O- [2-hydroxy-3- (trimethylammonio) propyl] guam gum chloride: manufactured by Toho Chemical Co., Ltd., trade name “Catinal CG-100”
Dimethylmethylene piperidinium chloride: manufactured by Nalco, trade name “Marcote 100”, pure content 40% by mass
Dimethyldiallylammonium chloride / acrylamide copolymer: manufactured by Nalco, trade name “Mercoat 550”, pure content of 8.5% by mass
Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate: manufactured by Osaka Organic Chemical Industry Co., Ltd., trade name “HC Polymer 1N”, pure content 20% by mass
(Component D)
Decamethylcyclopentasiloxane: Momentive Performance Materials Japan GK, trade name “TSF405”
(Component E)
Basic Blue 75: Hodogaya Chemical Co., Ltd., trade name “AHC BLUE SP”
Basic tea 16: manufactured by Hodogaya Chemical Co., Ltd., trade name “AHC BROWN SP”
HC Yellow 2: Made by Telka, trade name “COLOREX HCY2”
HC Blue 2: Made by Telka, trade name “COLOREX HCB2”
(Other)
Polyoxyethylene cetyl ether (20E.O.): Aoki Yushi Kogyo Co., Ltd., trade name “Brownon CH-320L”
Glyceryl stearate: BASF, trade name “CUTINA GMS-V”

  Furthermore, the formulation example of the hair cosmetics of this invention is shown below.

(Formulation example 1) Conditioner (cream)
Stearyl alcohol 6.0% by mass
Polyoxyethylene cetyl ether (20E.O.) 3.0 mass%
Glyceryl stearate 1.5% by mass
Microcrystalline wax (melting point 88 ° C) 1.0% by mass
Liquid paraffin 3.0% by mass
Decamethylcyclopentasiloxane 1.0% by mass
Polymethylsilsesquioxane 0.5% by mass
Dipropylene glycol 3.0% by mass
O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride 0.5% by mass
Ethanol 3.0% by mass
Citric acid appropriate amount (adjusted to pH 5)
Sodium citrate appropriate amount (adjusted to pH 5)
Sodium benzoate 0.5% by mass
Water-soluble collagen (3) 0.1% by mass
Dilauroyl glutamic acid lysine sodium solution 0.1% by mass
Purified water Total remaining 100% by mass

(Formulation example 2) Color rinse (cream)
Basic blue 75 0.03% by mass
Basic tea 16 0.15% by mass
HC Yellow 2 0.03% by mass
HC Blue 2 0.8% by mass
Stearyl alcohol 7.0% by mass
Polyoxyethylene cetyl ether (20E.O.) 3.0 mass%
Glyceryl stearate 1.5% by mass
Microcrystalline wax (melting point 88 ° C) 0.5% by mass
Microcrystalline wax (melting point 75 ° C) 0.5% by mass
Liquid paraffin 3.0% by mass
Decamethylcyclopentasiloxane 1.0% by mass
Polymethylsilsesquioxane 0.5% by mass
Dipropylene glycol 3.0% by mass
O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride 0.5% by mass
Ethanol 3.0% by mass
Citric acid appropriate amount (adjusted to pH 5)
Sodium citrate appropriate amount (adjusted to pH 5)
Sodium benzoate 0.5% by mass
Dilauroyl glutamic acid lysine sodium solution 0.1% by mass
Hibamata extract 0.1% by mass
Purified water Total remaining 100% by mass

(Formulation example 3) Color rinse (cream)
Basic blue 77 0.05 mass%
Basic tea 17 0.5% by mass
HC Yellow 4 0.1% by mass
HC Blue 2 0.4% by mass
Cetanol 5.0% by mass
Polyoxyethylene cetyl ether (40E.O.) 4.0% by mass
Stearic acid dimethylaminopropylamide 0.08 mass%
Polyethylene wax 1.0% by mass
Liquid paraffin 5.0% by mass
Octamethyltrisiloxane 1.0% by mass
Polymethylsilsesquioxane 0.5% by mass
Propylene glycol 3.0% by mass
Dimethyl diallylammonium chloride / acrylamide copolymer 0.2% by mass
Lactic acid appropriate amount (adjusted to pH 5)
Phenoxyethanol 0.1% by mass
Glutamic acid 0.1% by mass
Camellia oil 0.1% by mass
Purified water Total remaining 100% by mass

(Formulation example 4) Color rinse (milky lotion)
Basic blue 75 0.05 mass%
Basic tea 16 1.0% by mass
HC Yellow 2 0.08% by mass
HC Blue 2 1.2% by mass
Cetanol 3.0% by mass
Polyoxyethylene cetyl ether (5EO) 1.5% by mass
Polyoxyethylene cetyl ether (20E.O.) 1.5% by mass
Microcrystalline wax 1.0% by mass
Liquid paraffin 5.0% by mass
1,3-butylene glycol 3.0% by mass
Glyceryl caprate 2.0% by mass
Polydimethylmethylenepiperidinium chloride solution 0.1% by mass
Methyl polysiloxane (kinematic viscosity 5 mm ² / s) 1.0 mass%
Polymethylsilsesquioxane 0.5% by mass
Citric acid appropriate amount (adjusted to pH 5)
Sodium citrate appropriate amount (adjusted to pH 5)
Sodium benzoate 0.3% by mass
Hydroxypropyltrimonium hyaluronate 0.5% by mass
Hibamata extract 0.1% by mass
l-Menthol 0.1% by mass
Purified water Total remaining 100% by mass

(Prescription Example 5) Hair nail polish (gel)
Basic blue 77 0.1% by mass
Basic tea 16 1.0% by mass
Basic orange 31 0.1% by mass
HC Yellow 2 0.05% by mass
HC Blue 2 1.0% by mass
Polymethylsilsesquioxane 0.5% by mass
Hydroxyethyl cellulose 2.5% by mass
Ethanol 10.0% by mass
Benzyl alcohol 5.0% by mass
Propylene glycol 3.0% by mass
Isononyl isononanoate 1.0% by mass
Microcrystalline wax 0.5% by mass
O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride 0.5% by mass
Methylfephenyl polysiloxane (kinematic viscosity 20 mm ² / s) 0.5% by mass
Highly polymerized methylpolysiloxane (1) 0.008% by mass
Edetate disodium 0.2% by mass
Glycolic acid appropriate amount (adjusted to pH 5)
Camellia oil 0.1% by mass
Panthenol 0.1% by mass
Hydrolyzed conchiolin solution 0.1% by mass
Purified water Total remaining 100% by mass

(Formulation Example 6) Color shampoo basic blue 75 0.05 mass%
Basic tea 16 0.2% by mass
HC Yellow 2 0.2% by mass
HC Blue 2 1.5% by mass
Lauroylmethyl-β-alanine sodium 1.5% by mass
9.0% by mass of amidopropyl betaine laurate
Palm oil fatty acid N-methylethanolamide 2.0% by mass
O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride 0.2% by mass
Dipropylene glycol 3.0% by mass
Glyceryl caprate 1.0% by mass
Polyglyceryl monolaurate 0.1% by mass
Decamethylcyclopentasiloxane 0.5% by mass
Citric acid appropriate amount (adjusted to pH 5)
Phenoxyethanol 0.3% by mass
Water-soluble collagen (3) 0.1% by mass
Jojoba oil 0.1% by mass
Purified water Total remaining 100% by mass

Claims (8)

A hair comprising 0.05 to 2.0 mass% of the following component A, 0.5 to 6.0 mass% of the following component B, and 0.1 to 2.0 mass% of the following component C. Cosmetics.
Component A: Silicone powder Component B: Microcrystalline wax having a melting point of 72 ° C. or higher and / or polyethylene wax having a melting point of 83 ° C. or higher Component C: Cationic polymer Furthermore, the hair cosmetics of Claim 1 containing 0.1-5.0 mass% of the following component D.
Component D: Volatile silicone oil, methyl polysiloxane less kinematic viscosity ^{1 mm} 2 / s or more 20 mm ² / s at 25 ° C., and a kinematic viscosity of less than ^{1 mm} 2 / s or more 20 mm ² / s at 25 ° C. methylphenylpolysiloxanes Silicone oil selected from the group consisting of siloxanes   The hair cosmetic according to claim 1 or 2, wherein the component A is a methylsiloxane network polymer.   Component C is O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride, dimethylmethylenepiperidinium chloride, dimethyldiallylammonium chloride-acrylamide copolymer, and vinylpyrrolidone N, N- The hair cosmetic according to any one of claims 1 to 3, which is a cationic polymer selected from the group consisting of dimethylaminoethyl methacrylate copolymer diethyl sulfate. Furthermore, the hair cosmetics of any one of Claims 1-4 containing the following component E.
Component E: Dye   The hair cosmetic composition according to claim 5, which does not contain a cationic surfactant or contains less than 0.5% by mass.   The hair cosmetic composition according to any one of claims 1 to 6, which does not contain an anionic surfactant or contains less than 0.1% by mass.   The hair cosmetic according to any one of claims 1 to 7, which is a hair rinse, a hair conditioner, a hair treatment, or a hair manicure.