JP6655299B2 - Hair cosmetic composition - Google Patents
Hair cosmetic composition Download PDFInfo
- Publication number
- JP6655299B2 JP6655299B2 JP2015076845A JP2015076845A JP6655299B2 JP 6655299 B2 JP6655299 B2 JP 6655299B2 JP 2015076845 A JP2015076845 A JP 2015076845A JP 2015076845 A JP2015076845 A JP 2015076845A JP 6655299 B2 JP6655299 B2 JP 6655299B2
- Authority
- JP
- Japan
- Prior art keywords
- extract
- derived
- hair
- range
- segment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 63
- 239000002537 cosmetic Substances 0.000 title claims description 56
- 239000000284 extract Substances 0.000 claims description 159
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- 150000001875 compounds Chemical class 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 18
- 235000007460 Coffea arabica Nutrition 0.000 claims description 17
- 150000001767 cationic compounds Chemical class 0.000 claims description 13
- 238000013329 compounding Methods 0.000 claims description 13
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- 125000000217 alkyl group Chemical group 0.000 claims description 5
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Description
本発明は、くせ毛の毛髪に適用する毛髪化粧料に関する。さらに詳しくは、本発明は、ブラシや手ぐし等でくせ毛を引っ張ると、より強いくせ毛となるという現象を抑制するための毛髪化粧料に関する。 The present invention relates to a hair cosmetic applied to curly hair. More specifically, the present invention relates to a hair cosmetic for suppressing the phenomenon that when hair is pulled by a brush or a handgear, the hair becomes stronger.
くせ毛は、毛髪がカールした状態の髪質であるため、整髪時に髪がまとまらず、上手くヘアスタイリングができないという問題がある。これに対して、ストレートパーマ等、くせ毛を矯正して直毛化する方法が知られている。この方法では、半永久的にくせ毛を矯正することができるが、毛髪内ケラチン蛋白質のＳ−Ｓ結合を開裂・再結合させるため、毛髪が損傷を受け、枝毛や切れ毛が増えたり、好ましくない感触になるという不都合が生じる。 The curly hair has a curled hair quality, and thus has a problem in that the hair is not clumped at the time of styling and that hair styling cannot be performed well. On the other hand, there is known a method of straightening the hair by straightening the curly hair, such as straight perm. With this method, it is possible to rectify the curly hair semipermanently. However, since the S--S bond of the keratin protein in the hair is cleaved and recombined, the hair is damaged, and split ends and cut hairs increase, which is not preferable. There is an inconvenience of feeling.
一方、毛髪化粧料を適用することにより、一時的にくせ毛をのばす方法が知られている。例えば、特許文献１には、毛髪に優れた光沢を与え、なめらかな感触を付与し、さらに、くせ毛のばし効果に優れた毛髪化粧料として、両性界面活性剤と高級脂肪酸とを混合して得られる複合体と、シリル化ペプチドを含有する毛髪化粧料が記載されている。 On the other hand, there has been known a method of temporarily extending hair by applying hair cosmetics. For example, Patent Literature 1 provides a hair with excellent gloss, imparts a smooth feel, and is obtained by mixing an amphoteric surfactant and a higher fatty acid as a hair cosmetic having an excellent combing effect. Hair cosmetics containing a conjugate and a silylated peptide are described.
その他、同様な効果を奏する毛髪化粧料として、特許文献２には、有機シリコーン樹脂、ポリエーテル変性シリコーン及び低級アルコールを含有する毛髪化粧料、特許文献３には、有機シリコーン樹脂及びポリビニルピロリドン−酢酸ビニル共重合体を含有する毛髪化粧料が記載されている。 In addition, as hair cosmetics having the same effect, Patent Document 2 discloses a hair cosmetic containing an organic silicone resin, polyether-modified silicone and a lower alcohol, and Patent Document 3 describes an organic silicone resin and polyvinylpyrrolidone-acetic acid. Hair cosmetics containing a vinyl copolymer are described.
くせ毛は、手ぐしやブラシ等に絡まりやすいため、ドライヤー時やスタイリング時に、日常的に引っ張られる。発明者は、くせ毛の毛髪を引っ張ると、その前後でカール半径が小さくなり、より強いくせ毛になるという現象を発見した。そこで、本発明では、毛髪を引っ張ることにより生じるカール半径の低下を抑制することを課題とする。尚、カール半径とは、毛髪の曲がり度合いに対して接するように真円を描いたときの半径のことであり、くせのカールの強さを示す指標である。カール半径が小さいほどくせが強いことを表す。 Curly hair is liable to be entangled with a handgear, brush, or the like, and is therefore pulled on a daily basis when drying or styling. The inventor of the present invention has discovered a phenomenon in which the curl radius is reduced before and after pulling the hair of the curly hair, resulting in stronger curly hair. Therefore, an object of the present invention is to suppress a decrease in a curl radius caused by pulling hair. Note that the curl radius is a radius when a perfect circle is drawn so as to be in contact with the degree of curl of the hair, and is an index indicating a habit of curl. The smaller the curl radius, the stronger the habit.
発明者は、上記課題に対して鋭意検討した結果、ザクロ由来の抽出物、コーヒーノキ由来の抽出物、ヒマラヤユキノシタ由来の抽出物、及び、スモモ由来の抽出物から選択される植物由来抽出物を含有する毛髪化粧料組成物を、塗布後洗い流さない使用形態で毛髪に適用することにより、その後毛髪を引っ張ることにより生じるカール半径の低下を抑制することを見いだして、本発明を完成した。 The inventor has conducted extensive studies on the above problems, and as a result, contained a plant-derived extract selected from an extract derived from pomegranate, an extract derived from coffee tree, an extract derived from Himalayan saxifrage, and an extract derived from plum. The present invention has been completed by applying a hair cosmetic composition to a hair in a use form which is not washed away after application, thereby suppressing a decrease in a curl radius caused by pulling the hair thereafter.
すなわち、本発明は、（Ａ）ザクロ由来の抽出物、コーヒーノキ由来の抽出物、ヒマラヤユキノシタ由来の抽出物、及び、スモモ由来の抽出物から選択される１種又は２種以上の植物由来抽出物を含有する洗い流さないタイプの毛髪化粧料組成物である。
この毛髪化粧料組成物を毛髪に適用すると、その後の引っ張りにより生じるくせ毛のカール半径の低下を抑制することができ、毛髪がまとまりやすく、良好なヘアスタイリングを実現することができる。
また、この毛髪化粧料組成物を毛髪に適用しても、不自然なべたつき感や、硬さなどの感触がなく、素髪のように軽やかでしなやかな状態を維持することができる。
That is, the present invention relates to (A) one or two or more plant-derived extracts selected from pomegranate-derived extracts, coffee tree-derived extracts, Himalayan snow-spotted extract, and plum-derived extracts And a non-washable type hair cosmetic composition.
When this hair cosmetic composition is applied to hair, a reduction in the curl radius of the curly hair caused by subsequent pulling can be suppressed, the hair can be easily united, and good hair styling can be realized.
Further, even when this hair cosmetic composition is applied to hair, there is no unnatural feeling of stickiness or feel such as hardness, and a light and supple state like bare hair can be maintained.
さらに本発明は、（Ｂ）シリコーン化合物、又は、（Ｃ）カチオン性界面活性剤及びカチオン化高分子化合物から選択されるカチオン性化合物を含有することが好ましい。
これらの化合物を配合すると、毛髪の引っ張りによるカール半径の低下抑制、毛髪のまとまりやすさや自然な風合い等の本発明の効果を相乗的に高めることができる。
Further, the present invention preferably contains (B) a silicone compound or (C) a cationic compound selected from a cationic surfactant and a cationized polymer compound.
When these compounds are blended, the effects of the present invention, such as suppression of a decrease in the curl radius due to pulling of the hair, ease of cohesion of the hair, and natural texture, can be synergistically enhanced.
さらに本発明は、前記植物由来抽出物の配合量に対する前記シリコーン化合物の配合量の比［（Ｂ）／（Ａ）］は、１〜１００００００であるという特徴を有することが好ましい。
または、本発明は、前記植物由来抽出物の配合量に対する前記カチオン性化合物の配合量の比［（Ｃ）／（Ａ）］は、１〜５０００００であるという特徴を有することが好ましい。
これらの配合比とすることにより、（Ａ）植物由来抽出物と（Ｂ）シリコーン化合物又は（Ｃ）カチオン性化合物の相乗効果を最大限に発揮することができる。
Further, the present invention preferably has a feature that a ratio [(B) / (A)] of a blending amount of the silicone compound to a blending amount of the plant-derived extract is 1 to 1,000,000.
Alternatively, the present invention preferably has a feature that the ratio [(C) / (A)] of the amount of the cationic compound to the amount of the plant-derived extract is 1 to 500,000.
By setting these compounding ratios, it is possible to maximize the synergistic effect of (A) the plant-derived extract and (B) the silicone compound or (C) the cationic compound.
本発明の毛髪化粧料組成物は、毛髪を引っ張ることにより生じるくせ毛のカール半径の低下を抑制することができる。 ADVANTAGE OF THE INVENTION The hair cosmetic composition of this invention can suppress the fall of the curl radius of curly hair which arises by pulling hair.
次に、本発明を実施するための最良の形態を含めて説明する。
［毛髪化粧料組成物］
本発明の毛髪化粧料組成物とは、（Ａ）ザクロ由来の抽出物、コーヒーノキ由来の抽出物、ヒマラヤユキノシタ由来の抽出物、及び、スモモ由来の抽出物から選択される１種又は２種以上の植物由来抽出物を含有する洗い流さないタイプの毛髪化粧料組成物である。
ここで、「洗い流さないタイプ」の毛髪化粧料組成物とは、洗い流さず塗布したままにする、いわゆるアウトバスタイプの毛髪化粧料組成物である。
Next, description will be made including the best mode for carrying out the present invention.
[Hair cosmetic composition]
The hair cosmetic composition of the present invention is (A) one or two or more selected from pomegranate-derived extracts, coffee tree-derived extracts, Himalayan snow-spotted extract, and plum-derived extracts A non-washable type hair cosmetic composition containing the plant-derived extract of the present invention.
Here, the “non-rinse-type” hair cosmetic composition is a so-called out-bath type hair cosmetic composition that is applied without being washed away.
アウトバスタイプの毛髪化粧料組成物としては、例えば、洗い流さないトリートメントや、ヘアフォーム、ヘアワックス、ポマード、ヘアジェル、ヘアクリーム、ヘアスプレー、ヘアミスト、ヘアウォーター、ヘアリキッド、ヘアオイル等の整髪剤や、ヘアカラースプレー等の一時染毛剤や、ヘアトニック、養毛剤等が挙げられる。 As an out bath type hair cosmetic composition, for example, treatments that do not wash away, hair foams, hair waxes, pomades, hair gels, hair creams, hair sprays, hair mist, hair water, hair liquids, hair liquids, hair styling agents such as hair oils, Temporary hair dyes such as hair color sprays, hair tonics, hair tonics and the like can be mentioned.
毛髪化粧料組成物の剤型は、公知の剤型の中から、その用途や使用目的等に応じて任意に選択することができる。例えば、液体状、乳液状、クリーム状、ゲル状、ペースト状、泡状等とすることができ、泡状の場合、エアゾール形態、ノンエアゾール形態のいずれでもよい。 The dosage form of the hair cosmetic composition can be arbitrarily selected from known dosage forms according to the use and purpose of use. For example, it can be in the form of a liquid, an emulsion, a cream, a gel, a paste, a foam, etc. In the case of a foam, any of an aerosol form and a non-aerosol form may be used.
以下、本発明の毛髪化粧料組成物の各成分について詳細に説明する。
〔（Ａ）植物由来抽出物〕
（ザクロ由来の抽出物）
本発明のザクロ由来の抽出物は、ミソハギ科ザクロ属の植物の抽出物である。好ましくは、ザクロ（学名：Punica granatum）由来の抽出物である。
植物の部位は、どの部位でもよく、例えば、全草、葉、幹、茎、枝、枝葉、果皮、果実、樹皮、樹液、種子、根茎、根、頭花、花などの１又は２以上の部位を生のまま若しくは乾燥させて使用する。好ましくは、ザクロの花の抽出物である。
Hereinafter, each component of the hair cosmetic composition of the present invention will be described in detail.
[(A) plant-derived extract]
(Pomegranate-derived extract)
The extract derived from pomegranate according to the present invention is an extract of a plant belonging to the genus Pomegranate of the family Pestidae. Preferably, it is an extract derived from pomegranate (scientific name: Punica granatum).
The plant part may be any part, for example, one or more of whole plant, leaf, stem, stem, branch, branch and leaf, pericarp, fruit, bark, sap, seed, rhizome, root, head flower, flower, etc. Use the part as it is or after drying it. Preferably, it is an extract of pomegranate flowers.
（コーヒーノキ由来の抽出物）
本発明のコーヒーノキ由来の抽出物は、アカネ科コーヒーノキ属の植物の抽出物である。好ましくは、アラビカコーヒーノキ（学名：Coffea arabica）由来の抽出物である。
植物の部位は、どの部位でもよく、例えば、全草、葉、幹、茎、枝、枝葉、果皮、果実、樹皮、樹液、種子、根茎、根、頭花、花などの１又は２以上の部位を生のまま若しくは乾燥させて使用する。好ましくは、コーヒーノキ種子の抽出物である。
(Extract from coffee tree)
The extract derived from coffee tree of the present invention is an extract of a plant belonging to the genus Rubiaceae. Preferably, it is an extract derived from Arabica coffee tree (scientific name: Coffea arabica).
The plant part may be any part, for example, one or more of whole plant, leaf, stem, stem, branch, branch and leaf, pericarp, fruit, bark, sap, seed, rhizome, root, head flower, flower, etc. Use the part as it is or after drying it. Preferably, it is an extract of coffee tree seeds.
（ヒマラヤユキノシタ由来の抽出物）
本発明のヒマラヤユキノシタ由来の抽出物は、ユキノシタ科ヒマラヤユキノシタ属の植物の抽出物である。好ましくは、パシャンベ（学名：Bergenia ligulata）由来の抽出物である。
植物の部位は、どの部位でもよく、例えば、全草、葉、幹、茎、枝、枝葉、果皮、果実、樹皮、樹液、種子、根茎、根、頭花、花などの１又は２以上の部位を生のまま若しくは乾燥させて使用する。好ましくは、パシャンベ根の抽出物である。
(Extract from Himalayan Saxifraga)
The extract derived from the Himalayan saxifrage of the present invention is an extract of a plant belonging to the genus Himalayan saxifrage of the family Saxifragaceae. Preferably, it is an extract derived from Pashanbe (scientific name: Bergenia ligulata).
The plant part may be any part, for example, one or more of whole plant, leaf, stem, stem, branch, branch and leaf, pericarp, fruit, bark, sap, seed, rhizome, root, head flower, flower, etc. Use the part as it is or after drying it. Preferably, it is an extract of Pashanbe root.
（スモモ由来の抽出物）
本発明のスモモ由来の抽出物は、バラ科スモモ亜属の植物の抽出物である。好ましくは、ウメ（学名：Prunus mume）由来の抽出物である。
植物の部位は、どの部位でもよく、例えば、全草、葉、幹、茎、枝、枝葉、果皮、果実、樹皮、樹液、種子、根茎、根、頭花、花などの１又は２以上の部位を生のまま若しくは乾燥させて使用する。好ましくは、ウメ果実の抽出物である。
(Plum extract)
The extract derived from plums of the present invention is an extract of a plant belonging to the genus Plum subfamily Rosaceae. Preferably, it is an extract derived from plum (scientific name: Prunus mume).
The plant part may be any part, for example, one or more of whole plant, leaf, stem, stem, branch, branch and leaf, pericarp, fruit, bark, sap, seed, rhizome, root, head flower, flower, etc. Use the part as it is or after drying it. Preferably, it is an extract of plum fruit.
（植物由来抽出物の抽出方法）
植物由来抽出物の抽出方法は、抽出溶媒により抽出する。抽出溶媒としては、特に限定されず、水、エタノール、メタノール、イソプロパノール、イソブタノール、ｎ−ヘキサノール、メチルアミルアルコール、２−エチルブタノール、ｎ−オクチルアルコール等の１価アルコール類、グリセリン、エチレングリコール、エチレングリコールモノメチルエーテル、プロピレングリコール、プロピレングリコールモノメチルエーテル、プロピレングリコールモノエチルエーテル、トリエチレングリコール、１，３−ブチレングリコール、ヘキシレングリコール等の多価アルコール又はその誘導体、アセトン、メチルエチルケトン、メチルイソブチルケトン、メチル−ｎ−プロピルケトン等のケトン類、酢酸エチル、酢酸イソプロピル等のエステル類、エチルエーテル、イソプロピルエーテル、ｎ−ブチルエーテル等のエーテル類、スクワラン、ワセリン、パラフィンワックス、パラフィン油等の炭化水素類、オリーブ油、小麦胚芽油、米油、ゴマ油、マカダミアンナッツ油、アルモンド油、ヤシ油等の植物油脂、牛脂、豚脂、鯨脂等の動物油脂などが例示される。また、リン酸緩衝生理食塩水等の無機塩類を添加した極性溶媒や界面活性剤を添加した溶媒を用いることができ、さらに、水、二酸化炭素、エチレン、プロピレン、エタン、プロパン、一酸化二窒素、クロロジフルオロメタン、クロロトリフルオロメタン、キセノン、アンモニア、メタノール、エタノール等の１種又は２種以上の超臨界流体、若しくは亜臨界流体を用いてもよい。
(Method of extracting plant-derived extract)
The extraction method of the plant-derived extract is performed using an extraction solvent. The extraction solvent is not particularly limited and includes water, ethanol, methanol, isopropanol, isobutanol, n-hexanol, methylamyl alcohol, 2-ethylbutanol, monohydric alcohols such as n-octyl alcohol, glycerin, ethylene glycol, Polyhydric alcohols such as ethylene glycol monomethyl ether, propylene glycol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, triethylene glycol, 1,3-butylene glycol, and hexylene glycol or derivatives thereof, acetone, methyl ethyl ketone, methyl isobutyl ketone, Ketones such as methyl-n-propyl ketone, esters such as ethyl acetate and isopropyl acetate, ethyl ether, isopropyl ether, n-butyl Ethers such as ether, squalane, petrolatum, paraffin wax, hydrocarbons such as paraffin oil, olive oil, wheat germ oil, rice oil, sesame oil, macadamian nut oil, almond oil, vegetable oils such as coconut oil, tallow, pork Animal fats and oils such as fat and whale fat are exemplified. Further, a polar solvent added with an inorganic salt such as a phosphate buffered saline or a solvent added with a surfactant can be used. Further, water, carbon dioxide, ethylene, propylene, ethane, propane, nitrous oxide can be used. One or more supercritical fluids such as chlorodifluoromethane, chlorotrifluoromethane, xenon, ammonia, methanol, and ethanol, or a subcritical fluid may be used.
好ましい抽出溶媒としては、水溶性溶媒である。水溶性溶媒を用いることにより、水溶性の植物由来抽出物を得ることができる。水溶性の植物由来抽出物を用いると、本発明の毛髪化粧料組成物を毛髪に適用した際に、不自然な光沢を抑え、自然な風合いを得ることができる。更に好ましくは、水、エタノール、１，３−ブチレングリコール及びこれらの混合溶媒であり、特に好ましくは、水、エタノール及びこれらの混合溶媒である。水とエタノールの混合溶媒を用いる場合、混合比は特に限定されないが、好ましくは、水：エタノール＝２０：８０〜８０：２０である。これらの溶媒を用いることにより、くせ毛のカール半径の低下を抑制するという本発明の効果をより発揮することができる。
なお、上記水溶性溶媒とは、溶解パラメータ（ＳＰ値）が１０以上のものである。
Preferred extraction solvents are water-soluble solvents. By using a water-soluble solvent, a water-soluble plant-derived extract can be obtained. When a water-soluble plant-derived extract is used, when the hair cosmetic composition of the present invention is applied to hair, unnatural luster can be suppressed and a natural texture can be obtained. More preferred are water, ethanol, 1,3-butylene glycol and a mixed solvent thereof, and particularly preferred are water, ethanol and a mixed solvent thereof. When a mixed solvent of water and ethanol is used, the mixing ratio is not particularly limited, but is preferably water: ethanol = 20: 80 to 80:20. By using these solvents, the effect of the present invention of suppressing a decrease in the curl radius of the curly hair can be further exhibited.
The water-soluble solvent has a solubility parameter (SP value) of 10 or more.
抽出の際の植物と溶媒との比率は特に限定されないが、植物１重量部に対して溶媒０．１〜１０００重量部、特に抽出操作や抽出効率の観点から、０．５〜１００重量部であることが好ましい。
また、抽出温度は０℃〜溶媒の沸点以下の範囲であり、抽出時間は、抽出温度等により異なるが３０分間〜２週間とすることが好ましい。
The ratio of the plant to the solvent at the time of extraction is not particularly limited, but the solvent is 0.1 to 1000 parts by weight relative to 1 part by weight of the plant, particularly from 0.5 to 100 parts by weight from the viewpoint of extraction operation and extraction efficiency. Preferably, there is.
The extraction temperature is in the range from 0 ° C. to the boiling point of the solvent, and the extraction time is preferably 30 minutes to 2 weeks, depending on the extraction temperature and the like.
毛髪化粧料組成物中に配合される植物由来抽出物の配合量は、エキス分として０．０００００１〜１質量％であり、好ましくは、０．００００１〜０．５質量％、特に好ましくは、０．０００１〜０．１質量％である。ここで、エキス分とは、植物由来抽出物から抽出溶媒を除したものを示す。 The amount of the plant-derived extract to be added to the hair cosmetic composition is 0.000001 to 1% by mass, preferably 0.00001 to 0.5% by mass, particularly preferably 0 to 0% by mass as an extract component. 0.0001 to 0.1% by mass. Here, the extract refers to the extract obtained by removing the extraction solvent from the plant-derived extract.
〔（Ｂ）シリコーン化合物〕
さらに、本発明の毛髪化粧料組成物は、（Ｂ）シリコーン化合物を配合することが好ましい。
シリコーン化合物は、シロキサン結合を有する有機ケイ素化合物である。例えば、ジメチルシリコーン油、メチルフェニルシリコーン油、環状ジメチルシリコーン油、メチルハイドロジェンシリコーン油等のストレートシリコーン油、アルコール変性シリコーン油、アルキル変性シリコーン油、アミノ変性シリコーン油等の変性シリコーン油、ポリエーテル変性シリコーン、アミノ変性シリコーン、ポリグリセリン変性シリコーン、グリセリルエーテル変性シリコーン、オキサゾリン変性シリコーン等のシリコーン系界面活性剤等が挙げられる。好ましくは、ジメチルシリコーン油、ポリエーテル変性シリコーンである。
本発明の毛髪化粧料組成物において、（Ｂ）シリコーン化合物を添加することにより、引っ張りによるくせ毛のカール半径の低下抑制、髪のまとまり、自然な風合い等の（Ａ）植物由来抽出物の効果を相乗的に高めることができる。
[(B) silicone compound]
Further, the hair cosmetic composition of the present invention preferably contains (B) a silicone compound.
The silicone compound is an organosilicon compound having a siloxane bond. For example, straight silicone oils such as dimethyl silicone oil, methylphenyl silicone oil, cyclic dimethyl silicone oil, methyl hydrogen silicone oil, etc., modified silicone oils such as alcohol-modified silicone oil, alkyl-modified silicone oil, amino-modified silicone oil, polyether-modified Examples include silicone-based surfactants such as silicone, amino-modified silicone, polyglycerin-modified silicone, glyceryl ether-modified silicone, and oxazoline-modified silicone. Preferred are dimethyl silicone oil and polyether-modified silicone.
In the hair cosmetic composition of the present invention, by adding the silicone compound (B), the effect of the plant-derived extract (A) such as suppression of a decrease in curl radius of the curly hair due to tension, unity of hair, and natural texture can be improved. Can be synergistically enhanced.
（Ｂ）シリコーン化合物の配合量は、０．０１〜２０質量％の範囲で配合すればよく、好ましくは０．２〜１５質量％であり、特に好ましくは、１〜１０質量％である。 (B) The compounding amount of the silicone compound may be in the range of 0.01 to 20% by mass, preferably 0.2 to 15% by mass, and particularly preferably 1 to 10% by mass.
また、（Ａ）植物由来抽出物の配合量に対する（Ｂ）シリコーン化合物の配合量の配合比［（Ｂ）／（Ａ）］は、好ましくは１〜１００００００であり、更に好ましくは２０〜１０００００であり、特に好ましくは５０〜５００００である。
この配合比とすることにより、（Ａ）植物由来抽出物と（Ｂ）シリコーン化合物をバランスよく配合することができるため、本発明の効果をさらに発揮することができる。
The compounding ratio [(B) / (A)] of the compounding amount of the (B) silicone compound to the compounding amount of the (A) plant-derived extract is preferably from 1 to 1,000,000, and more preferably from 20 to 100,000. And particularly preferably 50 to 50,000.
By setting the blending ratio, (A) the plant-derived extract and (B) the silicone compound can be blended in a well-balanced manner, so that the effects of the present invention can be further exhibited.
〔（Ｃ）カチオン性化合物〕
さらに、本発明の毛髪化粧料組成物は、（Ｃ）カチオン性界面活性剤及びカチオン化高分子化合物から選択されるカチオン性化合物を配合することが好ましい。なお、上記（Ｂ）シリコーン化合物と併用して配合してもよい。
[(C) cationic compound]
Further, the hair cosmetic composition of the present invention preferably contains (C) a cationic compound selected from a cationic surfactant and a cationized polymer compound. In addition, you may mix | blend together with the said (B) silicone compound.
カチオン性界面活性剤は、水に溶解してイオン解離をする親水基が陽イオンとなる界面活性剤である。例えば、４級アンモニウムやその塩である界面活性剤、脂肪酸アミドアミンやその中和物である界面活性剤等が好ましい。例えば、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム（セトリモニウムクロリド）、塩化ステアリルトリメチルアンモニウム（ステアルトリモニウムクロリド）、塩化アルキルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウム（ベヘントリモニウムクロリド）、塩化ジステアリルジメチルアンモニウム（ジステアリルジモニウムクロリド）、塩化ジココイルジメチルアンモニウム、臭化セチルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、ステアリルトリメチルアンモニウムサッカリン、セチルトリメチルアンモニウムサッカリン、メチル硫酸ベヘニルトリメチルアンモニウム、クオタニウム−９１等の４級アンモニウム塩や、ステアリン酸ジエチルアミノエチルアミド、ステアリン酸ジメチルアミノエチルアミド、パルミチン酸ジエチルアミノエチルアミド、パルミチン酸ジメチルアミノエチルアミド、ミリスチン酸ジエチルアミノエチルアミド、ミリスチン酸ジメチルアミノエチルアミド、ベヘニン酸ジエチルアミノエチルアミド、ベヘニン酸ジメチルアミノエチルアミド、ステアリン酸ジエチルアミノプロピルアミド、ステアリン酸ジメチルアミノプロプルアミド、パルミチン酸ジエチルアミノプロピルアミド、パルミチン酸ジメチルアミノプロピルアミド、ミリスチン酸ジエチルアミノプロピルアミド、ミリスチン酸ジメチルアミノプロピルアミド、ベヘニン酸ジエチルアミノプロピルアミド、ベヘニン酸ジメチルアミノプロピルアミド等の脂肪酸アミドアミンの中和物から選ばれる１種以上が好ましい。より好ましくは、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム（セトリモニウムクロリド）、塩化ステアリルトリメチルアンモニウム（ステアルトリモニウムクロリド）、及び塩化ベヘニルトリメチルアンモニウム（ベヘントリモニウムクロリド）から選ばれる１種以上である。 The cationic surfactant is a surfactant in which a hydrophilic group that dissolves in water and dissociates ions becomes a cation. For example, a surfactant such as a quaternary ammonium or a salt thereof, and a surfactant such as a fatty acid amidoamine or a neutralized product thereof are preferable. For example, lauryltrimethylammonium chloride, cetyltrimethylammonium chloride (cetrimonium chloride), stearyltrimethylammonium chloride (stealtrimonium chloride), alkyltrimethylammonium chloride, behenyltrimethylammonium chloride (behentrimonium chloride), distearyldimethylammonium chloride ( Distearyldimonium chloride), dicocoyldimethylammonium chloride, cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, lanolin fatty acid aminopropylethyldimethylammonium sulfate, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, behenyltrimethylammonium methyl sulfate , Quotanium-91 Quaternary ammonium salts, diethylaminoethylamide stearate, dimethylaminoethylamide stearate, diethylaminoethylamide palmitate, dimethylaminoethylamide palmitate, diethylaminoethylamide myristic, dimethylaminoethylamide myristic, diethylaminoethyl behenate Amide, dimethylaminoethylamide behenate, diethylaminopropylamide stearate, dimethylaminopropylamide stearate, diethylaminopropylamide palmitate, dimethylaminopropylamide palmitate, diethylaminopropylamide myristate, dimethylaminopropylamide myristate, behenine Diethylaminopropylamide, dimethylaminopropyl behenate Least one member selected from the neutralization of the fatty acid amidoamines bromide are preferred. More preferably, it is at least one member selected from lauryltrimethylammonium chloride, cetyltrimethylammonium chloride (cetrimonium chloride), stearyltrimethylammonium chloride (stealtrimonium chloride), and behenyltrimethylammonium chloride (behentrimonium chloride).
カチオン性高分子化合物は、水に溶解してイオン解離をする親水基が陽イオンとなる高分子化合物である。例えば、カチオン化セルロース、カチオン化グアガム、カチオン化多糖、カチオン化加水分解たん白、カチオン化ビニル系又はアクリル系ポリマー、ポリグリコールポリアミン縮合物、アジピオン酸ジメチル−アミノヒドロキシプロピルジエチルトリアミン共重合体、及びアミノエチルアミノプロピル・メチルポリシロキサン共重合体が挙げられる。 The cationic polymer compound is a polymer compound in which a hydrophilic group that dissolves in water and dissociates ions becomes a cation. For example, cationized cellulose, cationized guar gum, cationized polysaccharide, cationized hydrolysis protein, cationized vinyl or acrylic polymer, polyglycol polyamine condensate, dimethyl adipionate-aminohydroxypropyl diethyltriamine copolymer, and An aminoethylaminopropyl / methylpolysiloxane copolymer is exemplified.
カチオン化セルロースとしては、例えば、塩化Ｏ−［２−ヒドロキシ−３−（トリメチルアンモニオ）プロピル］ヒドロキシエチルセルロース、塩化Ｏ−［２−ヒドロキシ−３−（ラウリルジメチルアンモニオ）プロピル］ヒドロキシエチルセルロース、及びヒドロキシエチルセルロースジメチルジアリルアンモニウムクロリドが挙げられる。 Examples of the cationized cellulose include O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride, O- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydroxyethylcellulose, and Hydroxyethylcellulose dimethyldiallylammonium chloride.
カチオン化グアガムとしては、例えば、塩化Ｏ−［２−ヒドロキシ−３−（トリメチルアンモニオ）プロピル］グアガムが挙げられる。
カチオン化多糖は、セルロース誘導体、天然ガム、澱粉、デキストラン等の多糖類をカチオン化して得られるものであり、カチオン化多糖としては、例えば、デキストラン塩化ヒドロキシプロピルトリメチルアンモニウムエーテル等のカチオン化デキストランが挙げられる。
Examples of the cationized guar gum include O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum.
The cationized polysaccharide is obtained by cationizing a polysaccharide such as a cellulose derivative, a natural gum, starch, or dextran. Examples of the cationized polysaccharide include cationized dextran such as dextran chloride hydroxypropyltrimethylammonium ether. Can be
カチオン化加水分解たん白としては、例えば、塩化Ｎ−［２−ヒドロキシ−３−（トリメチルアンモニオ）プロピル］加水分解コラーゲン、塩化Ｎ−［２−ヒドロキシ−３−（トリメチルアンモニオ）プロピル］加水分解シルク、塩化Ｎ−［２−ヒドロキシ−３−（トリメチルアンモニオ）プロピル］加水分解ケラチン、塩化Ｎ−［２−ヒドロキシ−３−（トリメチルアンモニオ）プロピル］加水分解コンキオリン、塩化Ｎ−［２−ヒドロキシ−３−（ステアリルジメチルアンモニオ）プロピル］加水分解ケラチン、塩化Ｎ−［２−ヒドロキシ−３−（ステアリルジメチルアンモニオ）プロピル］加水分解コラーゲン、塩化Ｎ−［２−ヒドロキシ−３−（ステアリルジメチルアンモニオ）プロピル］加水分解シルク、塩化Ｎ−［２−ヒドロキシ−３−（ステアリルジメチルアンモニオ）プロピル］加水分解コンキオリン、塩化Ｎ−［２−ヒドロキシ−３−（ラウリルジメチルアンモニオ）プロピル］加水分解ケラチン、塩化Ｎ−［２−ヒドロキシ−３−（ラウリルジメチルアンモニオ）プロピル］加水分解コラーゲン、塩化Ｎ−［２−ヒドロキシ−３−（ラウリルジメチルアンモニオ）プロピル］加水分解シルク、塩化Ｎ−［２−ヒドロキシ−３−（ラウリルジメチルアンモニオ）プロピル］加水分解コンキオリン、塩化Ｎ−［２−ヒドロキシ−３−（ヤシ油アルキルジメチルアンモニオ）プロピル］加水分解大豆たん白、塩化Ｎ−［２−ヒドロキシ−３−（ヤシ油アルキルジメチルアンモニオ）プロピル］加水分解コラーゲン、塩化Ｎ−［２−ヒドロキシ−３−（ヤシ油アルキルジメチルアンモニオ）プロピル］加水分解シルク、塩化Ｎ−［２−ヒドロキシ−３−（ヤシ油アルキルジメチルアンモニオ）プロピル］加水分解ケラチン、及び塩化Ｎ−［２−ヒドロキシ−３−（ヤシ油アルキルジメチルアンモニオ）プロピル］加水分解コンキオリンが挙げられる。 Examples of the cationized hydrolysis protein include N- [2-hydroxy-3- (trimethylammonio) propyl] hydrolyzed collagen and N- [2-hydroxy-3- (trimethylammonio) propyl] hydrochloride. Decomposed silk, N- [2-hydroxy-3- (trimethylammonio) propyl] hydrolyzed keratin, N- [2-hydroxy-3- (trimethylammonio) propyl] hydrolyzed conchiolin, N- [2 chloride -Hydroxy-3- (stearyldimethylammonio) propyl] hydrolyzed keratin, N- [2-hydroxy-3- (stearyldimethylammonio) propyl] hydrolyzed collagen, N- [2-hydroxy-3- (chloride) Stearyldimethylammonio) propyl] hydrolyzed silk, N- [2-hydroxy chloride -3- (stearyldimethylammonio) propyl] hydrolyzed conchiolin, N- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydrolyzed keratin, N- [2-hydroxy-3- (lauryldimethyl) chloride Ammonio) propyl] hydrolyzed collagen, N- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydrolyzed silk, N- [2-hydroxy-3- (lauryldimethylammonio) propyl] hydrochloride Degraded conchiolin, N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrolyzed soybean protein, N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrochloride Degraded collagen, N- [2-hydroxy-3- (coconut oil alkyl) chloride Methylammonio) propyl] hydrolyzed silk, N- [2-hydroxy-3- (coconut oil alkyldimethylammonio) propyl] hydrolyzed keratin, and N- [2-hydroxy-3- (coconut oil alkyldimethyl) chloride Ammonio) propyl] hydrolyzed conchiolin.
カチオン化ビニル系又はカチオン化アクリル系ポリマーとしては、例えば、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体、β−メタクリロキシエチルトリメチルアンモニウム・アクリルアミド共重合物、ビニルピロリドン・Ｎ，Ｎ−ジメチルアミノエチルメタクリル酸共重合物ジエチル硫酸塩、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体、β−メタクリロキシエチルトリメチルアンモニウム・アクリルアミド共重合物、及びポリ塩化ジメチルメチレンピペリジニウムが挙げられる。 Examples of the cationized vinyl-based or cationized acrylic-based polymer include dimethyldiallylammonium chloride / acrylamide copolymer, β-methacryloxyethyltrimethylammonium / acrylamide copolymer, vinylpyrrolidone / N, N-dimethylaminoethylmethacrylic acid The copolymer includes diethyl sulfate, dimethyldiallylammonium chloride / acrylamide copolymer, β-methacryloxyethyltrimethylammonium / acrylamide copolymer, and polydimethylmethylenepiperidinium chloride.
ポリグリコールポリアミン縮合物としては、例えば、Ｎ，Ｎ−ジメチルアミノエチルメタクリル酸ジエチル硫酸塩・Ｎ，Ｎ−ジメチルアクリルアミド・ジメタクリル酸ポリエチレングリコールが挙げられる。 Examples of the polyglycol polyamine condensate include N, N-dimethylaminoethyl methacrylate diethyl sulfate / N, N-dimethylacrylamide / polyethylene glycol dimethacrylate.
本発明の毛髪化粧料組成物において、（Ｃ）カチオン性界面活性剤及びカチオン化高分子化合物から選択されるカチオン性化合物を添加することにより、引っ張りによるくせ毛のカール半径の低下抑制、髪のまとまり、自然な風合い等の（Ａ）植物由来抽出物の効果を相乗的に高めることができる。 In the hair cosmetic composition of the present invention, by adding (C) a cationic surfactant selected from a cationic surfactant and a cationized polymer compound, the curl radius of the curly hair is suppressed from being reduced by pulling, and the hair is united. The effect of the plant-derived extract (A), such as natural texture, can be synergistically enhanced.
（Ｃ）カチオン性化合物の配合量は、０．０１〜２０質量％の範囲で配合すればよく、好ましくは０．２〜１５質量％であり、特に好ましくは、１〜１０質量％である。 (C) The compounding amount of the cationic compound may be in the range of 0.01 to 20% by mass, preferably 0.2 to 15% by mass, and particularly preferably 1 to 10% by mass.
また、（Ａ）植物由来抽出物の配合量に対する（Ｃ）カチオン性化合物の配合量の配合比［（Ｃ）／（Ａ）］は、好ましくは１〜５０００００であり、更に好ましくは２０〜５００００であり、特に好ましくは５０〜２００００である。
この配合比とすることにより、（Ａ）植物由来抽出物と（Ｃ）カチオン性化合物をバランスよく配合することができるため、本発明の効果をさらに発揮することができる。
The compounding ratio [(C) / (A)] of the compounding amount of the (C) cationic compound to the compounding amount of the (A) plant-derived extract is preferably 1 to 500,000, and more preferably 20 to 50,000. And particularly preferably 50 to 20,000.
By setting the mixing ratio, (A) the plant-derived extract and (C) the cationic compound can be mixed in a well-balanced manner, so that the effects of the present invention can be further exhibited.
〔その他の成分〕
本発明の洗い流さないタイプの毛髪化粧料組成物においては、本発明の効果を損なわない範囲で、必要に応じて、さらに通常毛髪化粧料組成物に用いられている他の追加成分を配合することができる。これら追加成分としては、例えば、油脂類、蝋類、エステル油類、炭化水素類、高級アルコール類、脂肪酸類、界面活性剤、増粘剤類、植物抽出物、保湿剤、色素類、殺菌剤、香料等を配合することができる。油脂類としては、例えば、椿油、ココナッツ油、大豆油、米油、ナタネ油等の植物油、牛脂、豚脂等の動物油等を挙げることができ；蝋類としては、例えば、蜜蝋、羊毛ろう、カルナウバロウ等を挙げることができ；エステル油としては、例えば、パルミチン酸オクチル、ミリスチン酸イソステアリル等を挙げることができ；炭化水素類としては、例えば、α−オレフィンオリゴマー、軽質イソパラフィン、軽質流動イソパラフィン、合成スクワラン、植物性スクワラン、スクワラン、ポリブテン、流動イソパラフィン、流動パラフィン等を挙げることができ；高級アルコール類としては、例えば、セタノール、イソステアリルアルコール、２−オクチルドデカノール、デシルテトラデカノール、オレイルアルコール、２−ヘキシルデカノール、リノレイルアルコール、リノレニルアルコール等を挙げることができ；脂肪酸類としては、例えば、イソステアリン酸、オレイン酸、リノール酸等を挙げることができ；界面活性剤としては、例えば、ノニオン性界面活性剤、両性界面活性剤及びアニオン性界面活性剤の何れであってもよく、ノニオン性界面活性剤として、例えば、ポリオキシエチレンセチルエーテル等のポリオキシエチレンアルキルエーテル、モノラウリン酸ソルビタン、モノステアリン酸ポリオキシエチレンソルビタン、モノオレイン酸グリセリン及びその他ポリオキシエチレン硬化ヒマシ油などが例示でき、両性界面活性剤として、例えば、ラウリルジメチルアミノ酢酸ベタイン等のＮ，Ｎ−ジメチル−Ｎ−アルキル−Ｎ−カルボキシメチルアンモニウムベタイン、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタイン等などを例示することができ、アニオン性界面活性剤として、例えば、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ラウリル硫酸トリエタノールアミン等を例示することができ；増粘剤類としては、例えば、ビニル系高分子化合物、アクリル系高分子化合物等が挙げられ、ビニルピロリドン・ヘキサデセン共重合体などを例示することができる。
[Other components]
In the non-washable type hair cosmetic composition of the present invention, if necessary, other additional components which are usually used in hair cosmetic compositions may be added as long as the effects of the present invention are not impaired. Can be. These additional components include, for example, fats and oils, waxes, ester oils, hydrocarbons, higher alcohols, fatty acids, surfactants, thickeners, plant extracts, humectants, pigments, fungicides , Fragrance and the like can be blended. Examples of oils and fats include vegetable oils such as camellia oil, coconut oil, soybean oil, rice oil, rapeseed oil, and animal oils such as tallow, lard, and the like; examples of waxes include beeswax, wool wax, Carnauba wax and the like; ester oils such as octyl palmitate and isostearyl myristate; and hydrocarbons such as α-olefin oligomers, light isoparaffin, light liquid isoparaffin, and the like. Synthetic squalane, vegetable squalane, squalane, polybutene, liquid isoparaffin, liquid paraffin and the like; examples of higher alcohols include cetanol, isostearyl alcohol, 2-octyldodecanol, decyltetradecanol, oleyl alcohol , 2-hexyldecano Linoleyl alcohol, linolenyl alcohol, and the like; fatty acids include, for example, isostearic acid, oleic acid, and linoleic acid; surfactants include, for example, nonionic surfactant Any of a surfactant, an amphoteric surfactant and an anionic surfactant may be used. Examples of the nonionic surfactant include polyoxyethylene alkyl ethers such as polyoxyethylene cetyl ether, sorbitan monolaurate and polystearate monostearate. Examples include oxyethylene sorbitan, glycerin monooleate, and other polyoxyethylene hydrogenated castor oil. Examples of the amphoteric surfactant include N, N-dimethyl-N-alkyl-N-carboxymethyl such as betaine lauryldimethylaminoacetate. Ammonium betaine, Examples thereof include 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine and the like. Examples of the anionic surfactant include sodium polyoxyethylene lauryl ether sulfate and triethanolamine lauryl sulfate. Examples of the thickeners include vinyl polymer compounds and acrylic polymer compounds, and examples thereof include vinyl pyrrolidone hexadecene copolymer.
［美容方法］
本発明の美容方法とは、（Ａ）ザクロ由来の抽出物、コーヒーノキ由来の抽出物、ヒマラヤユキノシタ由来の抽出物、及び、スモモ由来の抽出物から選択される１種又は２種以上の植物由来抽出物を含有する毛髪化粧料組成物を頭髪に塗布し、塗布後に洗い流さないことを特徴とする方法である。本発明の美容方法に用いる毛髪化粧料組成物は、洗い流すタイプの毛髪化粧料組成物でもよいことを除いて、本発明の毛髪化粧料組成物と同様である。
本発明の美容方法を適用すると、くせ毛のカール半径の低下を抑制することができ、良好なスタイリングを施すことができる。
なお、塗布後に洗い流さないとは、塗布後に洗い流さないまま、スタイリングを終えるということである。
[Beauty method]
The cosmetic method of the present invention is defined as (A) one or two or more plants selected from an extract derived from pomegranate, an extract derived from coffee tree, an extract derived from Himalayan snowspot, and an extract derived from plum The method is characterized in that a hair cosmetic composition containing the extract is applied to the hair, and is not washed off after the application. The hair cosmetic composition used in the cosmetic method of the present invention is the same as the hair cosmetic composition of the present invention, except that the hair cosmetic composition may be a flush-type hair cosmetic composition.
By applying the cosmetic method of the present invention, it is possible to suppress a decrease in the curl radius of the curly hair, and it is possible to perform good styling.
Note that not washing off after application means that styling is finished without washing off after application.
以下に、実施例により本発明を具体的に説明するが、これらの実施例により本発明の技術範囲が限定されるものではない。
表１〜表９に示す実施例及び比較例に係る組成の毛髪化粧料組成物を、常法に従って調製し、以下の試験を実施して評価を行った。その結果を合わせて表に示す。
なお、各試料を塗布後、洗い流さないまま乾燥させ、その後各試験を実施した場合は、使用方法として「アウトバス」と記し、各試料を塗布後、洗浄・乾燥してから各試験を実施した場合は、「インバス」と記した。インバスにおける洗浄・乾燥は、流水にて試料を洗い流し、自然乾燥した。
Hereinafter, the present invention will be described specifically with reference to Examples, but the technical scope of the present invention is not limited by these Examples.
Hair cosmetic compositions having compositions according to Examples and Comparative Examples shown in Tables 1 to 9 were prepared according to a conventional method, and evaluated by performing the following tests. The results are shown in the table.
In addition, after applying each sample, it was dried without being washed away, and when each test was thereafter performed, the usage method was described as “out bath”, and after each sample was applied, each test was performed after washing and drying. In this case, it was described as "imbass". For washing and drying in the in-bath, the sample was washed away with running water and air-dried.
（評価１：引っ張りによるカール半径の変化率）
天然くせ毛の同一人毛を用いて、引っ張りによるカール半径の変化率について評価した。人毛は、ダメージの少ない根元側を使用し、予めカール半径を測定して、カール半径が２０ｍｍ以下の人毛を試験用のくせ毛人毛として選定した。カール半径の測定は、同心円上に１ｍｍ間隔で円を描いた測定板を用い、くせ毛を円に沿わせ、毛髪の曲がり度合いに対して接するような真円を描いたときの半径を目視にて測定した。
くせ毛人毛に各試料を塗布した後、０．２５Ｎで１００回の繰り返しの引っ張り負荷を与えた。引っ張り処理後のカール半径を計測し、処理前のカール半径からの変化率を求めた。カール半径の変化率は、以下の式１により算出し、１０本のくせ毛人毛の平均値を求めた。カール半径の変化率が小さいほど、くせが強くなったことを表す。
カール半径の変化率＝（引っ張り処理後のカール半径）／（引っ張り処理前のカール半径）・・・式１
(Evaluation 1: Change rate of curl radius due to pulling)
Using the same human hair of natural curly hair, the rate of change of the curl radius due to tension was evaluated. For the human hair, the curl radius was measured in advance by using the root side with less damage, and the human hair having a curl radius of 20 mm or less was selected as the curly human hair for the test. The curl radius is measured by using a measuring plate with circles drawn at 1 mm intervals on concentric circles, making the curly hairs follow the circle, and visually checking the radius when drawing a true circle that touches the degree of bending of the hair It was measured.
After each sample was applied to the curly human hair, 100 repetitive tensile loads at 0.25N were applied. The curl radius after the tension treatment was measured, and the rate of change from the curl radius before the treatment was determined. The rate of change of the curl radius was calculated by the following equation 1, and the average value of ten curly human hairs was obtained. The smaller the rate of change of the curl radius, the stronger the habit.
Rate of change of curl radius = (curl radius after tension processing) / (curl radius before tension processing) Equation 1
カール半径の変化率について、以下とおり◎〜×で評価し、表の「評価１」の上段に示した。なお、下段には、カール半径の変化率の平均値を示した。
◎ ：カール半径の変化率が０．９６以上
○＋：カール半径の変化率が０．９４以上０．９６未満
○ ：カール半径の変化率が０．９２以上０．９４未満
△ ：カール半径の変化率が０．９０以上０．９２未満
× ：カール半径の変化率が０．９０未満
The rate of change in the curl radius was evaluated as ◎ to × as follows, and is shown in the upper part of “Evaluation 1” in the table. The lower part shows the average value of the rate of change of the curl radius.
◎: Change rate of curl radius is 0.96 or more ○ +: Change rate of curl radius is 0.94 or more and less than 0.96 ○: Change rate of curl radius is 0.92 or more and less than 0.94 △: Curve radius Change rate is 0.90 or more and less than 0.92 ×: Change rate of curl radius is less than 0.90
（評価２：髪のまとまり感）
評価１と同様に選定されたくせ毛人毛を用いて、１．２ｇ、２０ｃｍの毛束を作製した。この毛束をシャンプー（ホーユー株式会社製プロマスターカラーケアＬＸ）で洗浄後、各試料０．６ｇを塗布し、ドライヤーで乾燥させながらロールブラシでブローを２０回行った。なお、インバスの使用方法では、シャンプーで洗浄後、各試料を同量塗布し、流水にて試料を洗い流してから、ブローを行った。
温度２５℃、湿度９０％の恒温恒湿槽に毛束を１５分間静置したときの、毛束の広がり幅（ｃｍ）を測定し、まとまり感を評価した。広がり幅が小さいほど、まとまりが良好であることを表す。
(Evaluation 2: Hair unity)
Using a curly human hair selected in the same manner as in Evaluation 1, a hair bundle of 1.2 g and 20 cm was produced. After washing the bristle bundle with a shampoo (Promaster Color Care LX manufactured by Hoyu Co., Ltd.), 0.6 g of each sample was applied, and blowing was performed 20 times with a roll brush while drying with a dryer. In the method of using in bath, after washing with shampoo, the same amount of each sample was applied, and the sample was washed off with running water, and then blown.
When the hair bundle was allowed to stand in a thermo-hygrostat at a temperature of 25 ° C. and a humidity of 90% for 15 minutes, the spread width (cm) of the hair bundle was measured, and the sense of unity was evaluated. The smaller the spread width, the better the unity.
広がり幅について、以下とおり◎〜×で評価し、表の「評価２」の上段に示した。なお、下段には、広がり幅の実測値を示した。
◎ ：広がり幅が４ｃｍ未満
○＋：広がり幅が４ｃｍ以上５ｃｍ未満
○ ：広がり幅が５ｃｍ以上６ｃｍ未満
△ ：広がり幅が６ｃｍ以上７ｃｍ未満
× ：広がり幅が７ｃｍ以上
The spread width was evaluated as ◎ to × as follows, and is shown in the upper part of “Evaluation 2” in the table. In the lower part, the measured value of the spread width is shown.
◎: Spread width of less than 4 cm ○ +: Spread width of 4 cm to less than 5 cm ○: Spread width of 5 cm to less than 6 cm △: Spread width of 6 cm to less than 7 cm ×: Spread width of 7 cm or more
（評価３：自然な風合い）
評価２と同様に処理したくせ毛人毛の毛束について、ブロー後の毛束の風合いについて評価した。風合いの評価については、専門パネラー１０名により評価した。なお、以下の評価において、「自然な風合い」とは、不自然なべたつき感や、硬さなどの感触がなく、素髪のように軽やかでしなやかな状態をいう。
(Evaluation 3: natural texture)
About the hair bundle of the curly human hair treated in the same manner as in Evaluation 2, the texture of the hair bundle after blowing was evaluated. The evaluation of the texture was evaluated by 10 expert panelists. In the following evaluations, “natural texture” refers to a light and supple state like bare hair without any unnatural feeling of stickiness or hardness.
◎ ：「自然な風合い」と回答したパネラーが９〜１０名
○＋：「自然な風合い」と回答したパネラーが７〜８名
○ ：「自然な風合い」と回答したパネラーが５〜６名
△ ：「自然な風合い」と回答したパネラーが１〜４名
× ：「自然な風合い」と回答したパネラーが０名
◎: 9 to 10 panelists who answered “natural texture” ○ +: 7 to 8 panelists who answered “natural texture” ○: 5 to 6 panelists who answered “natural texture” △ : 1-4 panelists who answered "natural texture" ×: 0 panelists who answered "natural texture"
なお、表中の原料については、以下に示した。
「ザクロ花エキス」：原料名「ザクロ花エキスＢＧ５０」（香栄興業株式会社製、エキス分１．０％）
「コーヒー種子エキス」：原料名「カフェノアージュ」（一丸ファルコス株式会社製、エキス分０．６％）
「パシャンベ根エキス」：原料名「パシャンベエキスＳＫ」（香栄興業株式会社製、エキス分０．５％）
「ウメ果実エキス」：原料名「和ｉｓｍ＜ウメ＞」（丸善製薬株式会社製、エキス分２．０％）
The raw materials in the table are shown below.
"Pomegranate flower extract": Raw material name "Pomegranate flower extract BG50" (manufactured by Koei Kogyo Co., Ltd., extract content 1.0%)
"Coffee seed extract": Ingredient name "Caffenoage" (Ichimaru Falcos Co., Ltd., extract 0.6%)
"Pashanbe root extract": Raw material name "Pashanbe extract SK" (manufactured by Koei Kogyo Co., Ltd., extract content 0.5%)
"Plum fruit extract": Raw material name "wasm <ume>" (Maruzen Pharmaceutical Co., Ltd., 2.0% extract)
表１を見ると、ザクロ花エキス、コーヒー種子エキス、パシャンベ根エキス、ウメ果実エキスを含まない比較例１−１では、引っ張り試験によりカール半径が小さくなり、くせが強くなった。それに伴い、髪のまとまり感も悪くなった。一方、これらのエキスを含む実施例１−１〜１−４では、カール半径の低下が抑制され、髪のまとまり感が優れていた。 Referring to Table 1, in Comparative Example 1-1 containing no pomegranate flower extract, coffee seed extract, pashanbe root extract, and plum fruit extract, the curl radius was reduced by the tensile test, and the habit became stronger. Along with that, the feeling of unity of hair also became worse. On the other hand, in Examples 1-1 to 1-4 containing these extracts, a decrease in curl radius was suppressed, and the sense of unity of hair was excellent.
また、これらのエキスを含む毛髪化粧料を塗布した後、お湯で試料を洗い流した比較例１−２〜１−５では、実施例１−１〜１−４で認められた効果が得られなかった。よって、これらのエキスを含む毛髪化粧料組成物を、シャンプーやトリートメント等のインバス用の毛髪化粧料組成物として利用しても効果がないことがわかる。 In addition, in Comparative Examples 1-2 to 1-5 in which the hair cosmetics containing these extracts were applied and the sample was washed away with hot water, the effects observed in Examples 1-1 to 1-4 were not obtained. Was. Therefore, it can be seen that the use of a hair cosmetic composition containing these extracts as a hair cosmetic composition for in-bath such as shampoo and treatment has no effect.
表２〜９を見ると、ザクロ花エキス、コーヒー種子エキス、パシャンベ根エキス、ウメ果実エキスに加えて、（Ｂ）ジメチコン、ＰＥＧ−１１メチルエーテルジメチコン、あるいは、（Ｃ）ベヘントリモニウムクロリド、ステアルトリモニウムクロリドまたはカチオン化セルロースを配合すると、「引っ張りによるカール半径の変化率」、「髪のまとまり感」、「自然な風合い」の各項目について、優れた評価が得られた。
なお、比較例２−１に示すように、（Ｂ）ジメチコンのみを０．１質量％配合しても、比較例１−１と同等の評価であるのに対して、実施例２−１において、（Ｂ）ジメチコンを０．１質量％配合した場合には、実施例１−１より「引っ張りによるカール半径の変化率」、「自然な風合い」の項目について評価が高くなった。すなわち、（Ｂ）ジメチコンは、ザクロ花エキスと相乗的に機能していると考えられる。
Tables 2 to 9 show that, in addition to the pomegranate flower extract, coffee seed extract, pashanbe root extract and plum fruit extract, (B) dimethicone, PEG-11 methyl ether dimethicone, or (C) behentrimonium chloride, When artilmonium chloride or cationized cellulose was blended, excellent evaluations were obtained for each item of "change rate of curl radius due to tension", "feeling of hair unity", and "natural texture".
As shown in Comparative Example 2-1, even when only (B) dimethicone was blended at 0.1% by mass, the evaluation was the same as that of Comparative Example 1-1. When (B) dimethicone was compounded in an amount of 0.1% by mass, the evaluations of the items “change rate of curl radius due to tension” and “natural texture” were higher than those of Example 1-1. That is, (B) dimethicone is considered to function synergistically with the pomegranate flower extract.
また、エキスの配合量に対するシリコーン化合物の配合量の比［（Ｂ）／（Ａ）］、及び、エキスの配合量に対するカチオン性化合物の配合量の比［（Ｃ）／（Ａ）］は、ザクロ花エキスの場合１００〜１０００の範囲、コーヒー種子エキスの場合１６７〜１６６７の範囲、パシャンベ根エキスの場合２００〜２０００の範囲、ウメ果実エキスの場合５０〜５００の範囲において、各評価項目について極めて優れた効果が認められた。 The ratio of the amount of the silicone compound to the amount of the extract [(B) / (A)] and the ratio of the amount of the cationic compound to the amount of the extract [(C) / (A)] are as follows: In the range of 100 to 1000 for pomegranate flower extract, 167 to 1667 for coffee seed extract, 200 to 2000 for pashanbe root extract, and 50 to 500 for pome fruit extract, each evaluation item is extremely high. Excellent effects were observed.
以下、本発明の毛髪化粧料組成物のその他の処方例をあげる。なお、これらの処方例の毛髪化粧料組成物についても、上記の「引っ張りによるカール半径の変化率」、「髪のまとまり感」、「自然な風合い」に関する試験を検討したところ、いずれの処方例においても、優れた特性を有し、良好であった。 Hereinafter, other formulation examples of the hair cosmetic composition of the present invention will be described. In addition, the hair cosmetic compositions of these formulation examples were also examined for the above-described "rate of change in curl radius by pulling", "feeling of hair unity", and "natural texture". Also had excellent characteristics and was good.
処方例１（ヘアミルク）
配合量（％）
（１）グリセリン ２．０
（２）ミリスチン酸オクチルドデシル ５．０
（３）ステアリルアルコール ２．０
（４）セトステアリルアルコール ０．５
（５）ホホバ種子油 ３．０
（６）メチルポリシロキサン ３．０
（７）塩化ベヘニルトリメチルアンモニウム １．５
（８）イソステアリン酸 １．０
（９）ヒドロキシエチルセルロース ０．５
（１０）ザクロ花エキス ０．２５
（１１）コーヒー種子エキス ０．２５
（１２）パシャンベ根エキス ０．２５
（１３）ウメ果実エキス ０．２５
（１４）メトキシケイヒ酸エチルヘキシル ０．１
（１５）フェノキシエタノール ０．３
（１６）香料 ０．２
（１７）精製水 残部
Formulation Example 1 (hair milk)
Amount (%)
(1) Glycerin 2.0
(2) Octyldodecyl myristate 5.0
(3) Stearyl alcohol 2.0
(4) cetostearyl alcohol 0.5
(5) Jojoba seed oil 3.0
(6) Methyl polysiloxane 3.0
(7) Behenyltrimethylammonium chloride 1.5
(8) Isostearic acid 1.0
(9) Hydroxyethyl cellulose 0.5
(10) Pomegranate flower extract 0.25
(11) Coffee seed extract 0.25
(12) Pashanbe root extract 0.25
(13) Plum fruit extract 0.25
(14) Ethylhexyl methoxycinnamate 0.1
(15) Phenoxyethanol 0.3
(16) Fragrance 0.2
(17) Remaining purified water
（製法）
（１）〜（８）、（１４）〜（１６）を８０℃に加温して、均一に溶解させ、８０℃に加温した（９）〜（１３）、（１７）を混合したものを加えて乳化した後、ホモミキサーで混合分散を行い、３０℃まで冷却してヘアエッセンスを得た。
(Production method)
(1) to (8), (14) to (16) heated to 80 ° C., uniformly dissolved, and a mixture of (9) to (13) and (17) heated to 80 ° C. Was added and emulsified, then mixed and dispersed with a homomixer, and cooled to 30 ° C. to obtain a hair essence.
処方例２（ヘアローション）
配合量（％）
（１）ポリオキシエチレン・メチルポリシロキサン共重合体 ４．０
（２）ポリエチレングリコール２００ ２．０
（３）１，３−ブチレングリコール １．５
（４）ポリオキシエチレン・ポリオキシプロピレンステアリルエーテル １．５
（５）エタノール １．５
（６）ポリオキシエチレン（６０）硬化ヒマシ油 ０．４
（７）メトキシケイヒ酸エチルヘキシル ０．０１
（８）ザクロ花エキス ０．２５
（９）コーヒー種子エキス ０．２５
（１０）パシャンベ根エキス ０．２５
（１１）ウメ果実エキス ０．２５
（１２）クエン酸 ０．０１
（１３）クエン酸ナトリウム ０．０３
（１４）香料 ０．２
（１５）精製水 残部
Formulation Example 2 (Hair lotion)
Amount (%)
(1) Polyoxyethylene / methylpolysiloxane copolymer 4.0
(2) Polyethylene glycol 200 2.0
(3) 1,3-butylene glycol 1.5
(4) Polyoxyethylene / polyoxypropylene stearyl ether 1.5
(5) Ethanol 1.5
(6) Polyoxyethylene (60) hydrogenated castor oil 0.4
(7) Ethylhexyl methoxycinnamate 0.01
(8) Pomegranate flower extract 0.25
(9) Coffee seed extract 0.25
(10) Pashanbe root extract 0.25
(11) Plum fruit extract 0.25
(12) Citric acid 0.01
(13) Sodium citrate 0.03
(14) Fragrance 0.2
(15) Remaining purified water
（製法）
（１）〜（１５）を均一に混合溶解して、ヘアローションを得た。
(Production method)
(1) to (15) were uniformly mixed and dissolved to obtain a hair lotion.
処方例３（フォーム剤）
＜原液＞ 配合量（％）
（１）セトステアリルアルコール ０．６
（２）ポリオキシエチレンセチルエーテル １．０
（３）ポリオキシエチレンイソセチルエーテル １．０
（４）ジカプリル酸プロピレングリコール １．５
（５）ビニルピロリドン・ヘキサデセン共重合体 ０．５
（６）酢酸ビニル・ビニルピロリドン共重合体 １．０
（７）塩化ステアリルトリメチルアンモニウム ０．３
（８）ジプロピレングリコール ２．０
（９）ポリオキシエチレン・メチルポリシロキサン共重合体 ０．５
（１０）メチルポリシロキサン ０．２
（１１）ザクロ花エキス ０．２５
（１２）コーヒー種子エキス ０．２５
（１３）パシャンベ根エキス ０．２５
（１４）ウメ果実エキス ０．２５
（１５）パラオキシ安息香酸エステル ０．２
（１６）香料 ０．１
（１７）精製水 残部
＜ガス充填＞
（１８）エアゾール原液 ９５．０
（１９）噴射剤（液化石油ガス） ５．０
Formulation Example 3 (foam)
<Stock solution> Amount (%)
(1) Cetostearyl alcohol 0.6
(2) Polyoxyethylene cetyl ether 1.0
(3) Polyoxyethylene isocetyl ether 1.0
(4) Propylene glycol dicaprylate 1.5
(5) Vinylpyrrolidone / hexadecene copolymer 0.5
(6) Vinyl acetate / vinyl pyrrolidone copolymer 1.0
(7) Stearyl trimethyl ammonium chloride 0.3
(8) Dipropylene glycol 2.0
(9) Polyoxyethylene / methylpolysiloxane copolymer 0.5
(10) Methyl polysiloxane 0.2
(11) Pomegranate flower extract 0.25
(12) Coffee seed extract 0.25
(13) Pashanbe root extract 0.25
(14) Plum fruit extract 0.25
(15) Paraoxybenzoate 0.2
(16) Fragrance 0.1
(17) Remaining purified water <gas filling>
(18) Aerosol stock solution 95.0
(19) Propellant (liquefied petroleum gas) 5.0
（製法）
（１）、（２）、（４）、（５）、（７）〜（１０）、（１５）、（１６）を８０℃に加温して均一に溶解させ、８０℃に加温した（３）、（６）、（１１）〜（１４）、（１７）を混合したものを加えて乳化した後、ホモミキサーで混合分散を行い３０℃まで冷却してエアゾール原液を調整し、ついで原液と噴射剤をエアゾール耐圧容器に充填し、フォーム剤を得た。
(Production method)
(1), (2), (4), (5), (7) to (10), (15), and (16) were uniformly dissolved by heating to 80 ° C, and then heated to 80 ° C. After mixing and emulsifying a mixture of (3), (6), (11) to (14) and (17), mixing and dispersing with a homomixer, cooling to 30 ° C. to prepare an aerosol stock solution, The stock solution and the propellant were filled in an aerosol pressure container to obtain a foam.
処方例４（ヘアオイル）
配合量（％）
（１）軽質流動イソパラフィン １０．０
（２）コハク酸ジ2-エチルヘキシル ５．０
（３）メチルポリシロキサン ２０．０
（４）ジメチコノール ５．０
（５）ポリ（オキシエチレン・オキシプロピレン）・ジメチルポリシロキサンブロック共重合体 ５．０
（６）デカメチルシクロペンタシロキサン ５．０
（７）ザクロ花エキス ０．１
（８）コーヒー種子エキス ０．１
（９）パシャンベ根エキス ０．１
（１０）ウメ果実エキス ０．１
（１１）香料 ０．２
（１２）軽質イソパラフィン 残部
Formulation Example 4 (hair oil)
Amount (%)
(1) Light liquid isoparaffin 10.0
(2) di-2-ethylhexyl succinate 5.0
(3) Methyl polysiloxane 20.0
(4) Dimethiconol 5.0
(5) Poly (oxyethylene / oxypropylene) / dimethylpolysiloxane block copolymer 5.0
(6) Decamethylcyclopentasiloxane 5.0
(7) Pomegranate flower extract 0.1
(8) Coffee seed extract 0.1
(9) Pashanbe root extract 0.1
(10) Plum fruit extract 0.1
(11) Fragrance 0.2
(12) Light isoparaffin balance
（製法）
（１）〜（１２）を均一に混合溶解して、ヘアオイルを得た。
(Production method)
(1) to (12) were uniformly mixed and dissolved to obtain a hair oil.
処方例５（ヘアジェル）
配合量（％）
（１）カルボキシビニルポリマー ０．３
（２）ヒドロキシエチルセルロース ０．１
（３）ポリオキシエチレン（１７）ポリオキシプロピレン（１７）ブチルエーテル
５．０
（４）コハク酸ジエチルヘキシル ２．０
（５）１，３−ブチレングリコール ５．０
（６）グリセリン ３．０
（７）エタノール ５．０
（８）高重合メチルポリシロキサン（１） １．０
（９）ＰＰＧ−１４ジグリセリル ０．５
（１０）ＰＯＥ（６０）硬化ヒマシ油 ０．２
（１１）メトキシケイヒ酸エチルヘキシル ０．０１
（１２）ザクロ花エキス ０．２５
（１３）コーヒー種子エキス ０．２５
（１４）パシャンベ根エキス ０．２５
（１５）ウメ果実エキス ０．２５
（１６）トリエタノールアミン ０．４
（１７）エデト酸二ナトリウム ０．０５
（１８）香料 ０．１
（１９）フェノキシエタノール ０．３
（２０）精製水 残部
Formulation Example 5 (Hair gel)
Amount (%)
(1) Carboxyvinyl polymer 0.3
(2) hydroxyethyl cellulose 0.1
(3) polyoxyethylene (17) polyoxypropylene (17) butyl ether
5.0
(4) diethylhexyl succinate 2.0
(5) 1,3-butylene glycol 5.0
(6) Glycerin 3.0
(7) Ethanol 5.0
(8) Highly polymerized methylpolysiloxane (1) 1.0
(9) PPG-14 diglyceryl 0.5
(10) POE (60) hydrogenated castor oil 0.2
(11) Ethylhexyl methoxycinnamate 0.01
(12) Pomegranate flower extract 0.25
(13) Coffee seed extract 0.25
(14) Pashanbe root extract 0.25
(15) Plum fruit extract 0.25
(16) Triethanolamine 0.4
(17) disodium edetate 0.05
(18) Fragrance 0.1
(19) Phenoxyethanol 0.3
(20) Remaining purified water
（製法）
（５）、（６）、（１７）を（２０）に均一に溶解し、（１）、（２）を加えて分散させる。次に（１６）を加えてホモミキサーを用いて混合分散し、更に（３）、（４）、（７）〜（１５）、（１８）、（１９）を混合したものを添加して、ホモミキサーを用いて混合分散し、ヘアジェルを得た。
(Production method)
(5), (6), and (17) are uniformly dissolved in (20), and (1) and (2) are added and dispersed. Next, (16) was added, mixed and dispersed using a homomixer, and a mixture of (3), (4), (7) to (15), (18), and (19) was added, and A hair gel was obtained by mixing and dispersing using a homomixer.
処方例６（ヘアスプレー）
＜原液＞ 配合量（％）
（１）ポリオキシエチレン・メチルポリシロキサン共重合体 ０．５
（２）（ジメチルアクリルアミド／アクリル酸ヒドロキシエチル／アクリル酸メトキシエチル）コポリマー ４．０
（３）ポリオキシエチレン（１７）ポリオキシプロピレン（１７）ブチルエーテル
０．５
（４）エタノール ６０．０
（５）プロピレングリコール １．０
（６）メトキシケイヒ酸エチルヘキシル ０．０３
（７）ザクロ花エキス ０．２５
（８）コーヒー種子エキス ０．２５
（９）パシャンベ根エキス ０．２５
（１０）ウメ果実エキス ０．２５
（１１）香料 ０．１
（１２）精製水 残部
＜ガス充填＞
（１３）エアゾール原液 ５０．０
（１４）噴射剤（液化石油ガス） ５０．０
Formulation Example 6 (hair spray)
<Stock solution> Amount (%)
(1) Polyoxyethylene / methylpolysiloxane copolymer 0.5
(2) (dimethylacrylamide / hydroxyethyl acrylate / methoxyethyl acrylate) copolymer 4.0
(3) polyoxyethylene (17) polyoxypropylene (17) butyl ether
0.5
(4) Ethanol 60.0
(5) Propylene glycol 1.0
(6) Ethylhexyl methoxycinnamate 0.03
(7) Pomegranate flower extract 0.25
(8) Coffee seed extract 0.25
(9) Pashanbe root extract 0.25
(10) Plum fruit extract 0.25
(11) Fragrance 0.1
(12) Remaining purified water <gas filling>
(13) Aerosol stock solution 50.0
(14) Propellant (liquefied petroleum gas) 50.0
（製法）
（１）〜（１２）を均一に混合溶解して原液を調整し、原液と噴射剤をエアゾール耐圧容器に充填しヘアスプレーを得た。
(Production method)
(1) to (12) were uniformly mixed and dissolved to prepare a stock solution, and the stock solution and the propellant were filled in an aerosol pressure-resistant container to obtain a hair spray.
本発明の毛髪化粧料組成物は、洗い流さないトリートメントや、整髪剤等のアウトバス毛髪化粧料組成物として利用することにより、ブラシ等で引っ張られた際に、くせ毛のカール半径が低下することを抑制する毛髪化粧料組成物を提供することができる。
また、本発明の美容方法は、くせ毛の人に良好なスタイリングを施す美容方法を提供することができる。
By using the hair cosmetic composition of the present invention as an out-bath hair cosmetic composition such as a treatment that is not washed away and a hair styling agent, it is possible to reduce the curl radius of curly hair when pulled with a brush or the like. It is possible to provide a hair cosmetic composition that suppresses hair.
In addition, the beauty method of the present invention can provide a beauty method for providing good styling to a person with hazy hair.
Claims (4)
（ア）主鎖を構成するオルガノポリシロキサンセグメントのケイ素原子の少なくとも２つに、ヘテロ原子を含むアルキレン基を介して、下記一般式（１）；
（イ）重量平均分子量１００万以上のポリ塩化メタクリロイルオキシエチルトリメチルアンモニウム
（ウ）フォルスコリン
（エ）ウメエキス）。 (A) one or two or more plant-derived extracts selected from pomegranate-derived extracts, coffee-tree-derived extracts, Himalayan saxifrage-derived extracts, and plum-derived extracts; and (B) silicone Containing a compound, the ratio [(B) / (A) (mass ratio)] of the blending amount of the silicone compound to the blending amount of the plant-derived extract as an extract component is 100 to 100 in the case of an extract derived from pomegranate. Non-washable type in the range of 105000, in the case of coffee tree-derived extract, in the range of 167 to 175000, in the case of Himalayan snow-spotted extract, in the range of 16.7 to 210,000, and in the case of plum-derived extract, in the range of 50 to 500. the hair cosmetic composition (however, the hair cosmetic composition, hair setting composition containing the following components (a) and (b), and, (c) and (d) Containing the MITF-M production-promoting agent consisting except for the hair cosmetic composition.
(A) At least two of silicon atoms of the organopolysiloxane segment constituting the main chain via an alkylene group containing a hetero atom through the following general formula (1);
(A) Poly (methacryloyloxyethyltrimethylammonium chloride having a weight average molecular weight of 1,000,000 or more)
(C) Forskolin
(D) Plum extract) .
（ア）主鎖を構成するオルガノポリシロキサンセグメントのケイ素原子の少なくとも２つに、ヘテロ原子を含むアルキレン基を介して、下記一般式（１）；
（イ）重量平均分子量１００万以上のポリ塩化メタクリロイルオキシエチルトリメチルアンモニウム
（ウ）フォルスコリン
（エ）ウメエキス）。 (A) one or two or more plant-derived extracts selected from pomegranate-derived extracts, coffee tree-derived extracts, Himalayan saxifrage-derived extracts, and plum-derived extracts; and (C) cations A cationic compound selected from a cationic surfactant and a cationized polymer compound, and the ratio of the compounding amount of the cationic compound to the compounding amount of the plant-derived extract as an extract [(C) / (A) ) (Mass ratio)] is in the range of 100 to 55000 in the case of an extract derived from pomegranate, in the range of 13.9 to 91667 in the case of an extract derived from coffee tree, and in the range of 16.7 to 110,000 in the case of an extract derived from Himalayan snowy citrus. range, the hair cosmetic composition if the type is not washed out in the range of 50 to 27,500 of extracts from plums (However, the hair cosmetic composition, the following components A) and (b) hair fixative compositions containing, and, except for the hair cosmetic composition containing (c) and (d) consisting of a MITF-M production promoter.
(A) At least two of silicon atoms of the organopolysiloxane segment constituting the main chain via an alkylene group containing a hetero atom through the following general formula (1);
(A) Poly (methacryloyloxyethyltrimethylammonium chloride having a weight average molecular weight of 1,000,000 or more)
(C) Forskolin
(D) Plum extract) .
（ア）主鎖を構成するオルガノポリシロキサンセグメントのケイ素原子の少なくとも２つに、ヘテロ原子を含むアルキレン基を介して、下記一般式（１）；
（イ）重量平均分子量１００万以上のポリ塩化メタクリロイルオキシエチルトリメチルアンモニウム
（ウ）フォルスコリン
（エ）ウメエキス）。 (A) one or two or more plant-derived extracts selected from pomegranate-derived extracts, coffee-tree-derived extracts, Himalayan saxifrage-derived extracts, and plum-derived extracts; and (B) silicone Containing a compound, the ratio [(B) / (A) (mass ratio)] of the blending amount of the silicone compound to the blending amount of the plant-derived extract as an extract component is 100 to 100 in the case of an extract derived from pomegranate. Hair cosmetics in the range of 105000, in the case of coffee tree-derived extract, in the range of 167 to 175000, in the case of extract of Himalayan snowfinch, in the range of 16.7 to 210,000, and in the case of extract of plum, in the range of 50 to 500. the composition is applied to hair, cosmetic wherein the no rinse after application (however, the cosmetic method comprises the following component (a) and (b) hairdressing Compositions, and, except for cosmetic method characterized by leave-(c) and the hair cosmetic composition containing the MITF-M production promoter consisting a (d) is applied to the hair, after application.
(A) At least two of silicon atoms of the organopolysiloxane segment constituting the main chain via an alkylene group containing a hetero atom through the following general formula (1);
(A) Poly (methacryloyloxyethyltrimethylammonium chloride having a weight average molecular weight of 1,000,000 or more)
(C) Forskolin
(D) Plum extract) .
（ア）主鎖を構成するオルガノポリシロキサンセグメントのケイ素原子の少なくとも２つに、ヘテロ原子を含むアルキレン基を介して、下記一般式（１）；
（イ）重量平均分子量１００万以上のポリ塩化メタクリロイルオキシエチルトリメチルアンモニウム
（ウ）フォルスコリン
（エ）ウメエキス）。 (A) one or two or more plant-derived extracts selected from pomegranate-derived extracts, coffee tree-derived extracts, Himalayan saxifrage-derived extracts, and plum-derived extracts; and (C) cations A cationic compound selected from a cationic surfactant and a cationized polymer compound, and the ratio of the compounding amount of the cationic compound to the compounding amount of the plant-derived extract as an extract [(C) / (A) ) (Mass ratio)] is in the range of 100 to 55000 in the case of an extract derived from pomegranate, in the range of 13.9 to 91667 in the case of an extract derived from coffee tree, and in the range of 16.7 to 110,000 in the case of an extract derived from Himalayan snowy citrus. range, cosmetic method for hair cosmetic composition is in the range of the case 50 to 27,500 of extracts from plum was applied to the hair, characterized in that it is not washed off after application However, the above-mentioned beauty method comprises a hair styling composition containing the following components (a) and (a), and a hair containing a MITF-M production promoter consisting of (c) and (d). The cosmetic method is characterized in that the cosmetic composition is applied to the hair and is not washed away after the application.
(A) At least two of silicon atoms of the organopolysiloxane segment constituting the main chain via an alkylene group containing a hetero atom through the following general formula (1);
(A) Poly (methacryloyloxyethyltrimethylammonium chloride having a weight average molecular weight of 1,000,000 or more)
(C) Forskolin
(D) Plum extract) .
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|---|---|---|---|
| JP2015076845A JP6655299B2 (en) | 2015-04-03 | 2015-04-03 | Hair cosmetic composition |
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|---|---|---|---|
| JP2015076845A JP6655299B2 (en) | 2015-04-03 | 2015-04-03 | Hair cosmetic composition |
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| JP6655299B2 true JP6655299B2 (en) | 2020-02-26 |
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| JP7076761B2 (en) * | 2017-02-15 | 2022-05-30 | クラシエホームプロダクツ株式会社 | Damage care agents that improve setting power, and hair care compositions and hair styling compositions containing them. |
| JP6829636B2 (en) * | 2017-03-27 | 2021-02-10 | 株式会社マンダム | Anti-gray hair agent |
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| JPH0892057A (en) * | 1994-09-16 | 1996-04-09 | Ichimaru Pharcos Co Ltd | Cosmetic blended with extract of seed of coffee tree |
| JP2001139429A (en) * | 1999-11-15 | 2001-05-22 | Kanebo Ltd | Hair cosmetic |
| JP4087035B2 (en) * | 2000-01-24 | 2008-05-14 | 花王株式会社 | Hairdressing cosmetics |
| JP4627107B2 (en) * | 2000-07-06 | 2011-02-09 | ライオン株式会社 | Hair preparation for external use |
| JP2004210674A (en) * | 2002-12-27 | 2004-07-29 | Kose Corp | Hair cosmetic |
| JP2004315492A (en) * | 2003-04-18 | 2004-11-11 | Koei Kogyo Kk | Anti-aging cosmetic |
| JP2007320950A (en) * | 2006-05-30 | 2007-12-13 | Koei Kogyo Kk | Hyaluronidase inhibitor and skin care composition |
| JP2008001628A (en) * | 2006-06-22 | 2008-01-10 | Ichimaru Pharcos Co Ltd | Hair cosmetic |
| EP2022471A1 (en) * | 2007-08-07 | 2009-02-11 | KPSS-Kao Professional Salon Services GmbH | Conditioning composition for hair |
| JP5461847B2 (en) * | 2009-02-13 | 2014-04-02 | 花王株式会社 | Hairdressing composition |
| JP2011037780A (en) * | 2009-08-13 | 2011-02-24 | Kracie Home Products Ltd | Hair cosmetic |
| JP2011190221A (en) * | 2010-03-16 | 2011-09-29 | Milbon Co Ltd | Hair treatment agent |
| JP5836666B2 (en) * | 2011-06-28 | 2015-12-24 | 日華化学株式会社 | MITF-M production promoter, hair cosmetic composition and skin cosmetic composition containing the MITF-M production promoter |
| JP2015034139A (en) * | 2013-08-08 | 2015-02-19 | クラシエホームプロダクツ株式会社 | Hair smoothness-imparting agent, and hair cosmetics containing the same |
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