JP7294642B2 - hair cosmetics - Google Patents
hair cosmetics Download PDFInfo
- Publication number
- JP7294642B2 JP7294642B2 JP2019077793A JP2019077793A JP7294642B2 JP 7294642 B2 JP7294642 B2 JP 7294642B2 JP 2019077793 A JP2019077793 A JP 2019077793A JP 2019077793 A JP2019077793 A JP 2019077793A JP 7294642 B2 JP7294642 B2 JP 7294642B2
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- JP
- Japan
- Prior art keywords
- hair
- agent
- mass
- extract
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003676 hair preparation Substances 0.000 title description 8
- 210000004209 hair Anatomy 0.000 claims description 221
- 239000003795 chemical substances by application Substances 0.000 claims description 85
- 239000000284 extract Substances 0.000 claims description 57
- 239000002537 cosmetic Substances 0.000 claims description 43
- 238000011282 treatment Methods 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 39
- 241000222350 Pleurotus Species 0.000 claims description 17
- 239000003093 cationic surfactant Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 239000002453 shampoo Substances 0.000 claims description 15
- 229920001282 polysaccharide Polymers 0.000 claims description 14
- 239000005017 polysaccharide Substances 0.000 claims description 14
- 150000004676 glycans Chemical class 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 7
- 238000011156 evaluation Methods 0.000 description 27
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 26
- 239000000126 substance Substances 0.000 description 26
- -1 cationic polysaccharide Chemical class 0.000 description 23
- 125000002091 cationic group Chemical group 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000003921 oil Substances 0.000 description 15
- 235000019198 oils Nutrition 0.000 description 15
- 235000014113 dietary fatty acids Nutrition 0.000 description 13
- 229930195729 fatty acid Natural products 0.000 description 13
- 239000000194 fatty acid Substances 0.000 description 13
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 150000004665 fatty acids Chemical class 0.000 description 12
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 12
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 12
- 238000009472 formulation Methods 0.000 description 11
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- 235000013399 edible fruits Nutrition 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
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- 230000000694 effects Effects 0.000 description 9
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- 230000003766 combability Effects 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
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- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
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- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 6
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- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 6
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- FWWQKRXKHIRPJY-UHFFFAOYSA-N octadecyl aldehyde Natural products CCCCCCCCCCCCCCCCCC=O FWWQKRXKHIRPJY-UHFFFAOYSA-N 0.000 description 6
- 239000002304 perfume Substances 0.000 description 6
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- 235000009566 rice Nutrition 0.000 description 6
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- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 5
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- 229920001296 polysiloxane Polymers 0.000 description 5
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 5
- 239000004299 sodium benzoate Substances 0.000 description 5
- 235000010234 sodium benzoate Nutrition 0.000 description 5
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
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- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 229940024606 amino acid Drugs 0.000 description 4
- 235000001014 amino acid Nutrition 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 235000013922 glutamic acid Nutrition 0.000 description 4
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- KSCKTBJJRVPGKM-UHFFFAOYSA-N octan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-] KSCKTBJJRVPGKM-UHFFFAOYSA-N 0.000 description 4
- 229940057950 sodium laureth sulfate Drugs 0.000 description 4
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- 239000002904 solvent Substances 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
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Description
本発明は、毛髪の動きを改善するための毛髪化粧料、毛髪処理キット及び毛髪処理方法に関する。より詳しくは、本発明は、ムラサキシキブ属コムラサキ抽出物とカチオン性物質を含む、毛髪の動き改善のための毛髪化粧料、毛髪処理キット及びそれらを用いた毛髪処理方法に関する。 The present invention relates to a hair cosmetic, a hair treatment kit and a hair treatment method for improving the movement of hair. More specifically, the present invention relates to a hair cosmetic composition, a hair treatment kit, and a hair treatment method using the same for improving the movement of hair, containing an extract of the genus Pleurotus purpurea and a cationic substance.
女性のヘアスタイルの流行に伴って、求められる髪の仕上がりや感触も変化している。最近では、髪へのカラーリング、レイヤー、パーマの施術、コテの使用等で、軽やかで動きのあるヘアスタイルにすることが主流である。そのため、コテ等の熱器具やカラーリング、パーマ等の施術によるダメージを受けた毛髪に対し、ダメージをケアしながらも軽やかで動きのある仕上がりが求められている。 Along with the fashion of women's hairstyles, the desired finish and feel of hair are also changing. Recently, it is mainstream to make the hair style light and dynamic by coloring the hair, layering, perming, and using a trowel. Therefore, there is a demand for hair that has been damaged by heating tools such as irons, coloring, perming, and the like, while taking care of the damage while providing a light and moving finish.
このような仕上がりを実現するために、シャンプー、ヘアリンス、洗い流すタイプのインバスヘアトリートメントや、洗い流さないタイプのアウトバストリートメント等の毛髪化粧料においては、従来、毛髪の滑りやくし通りを良くしたり、しっとりとした感触を与えるためにシリコーンや、液状・固形状の油剤の配合が試みられている(例えば特許文献1)。 In order to achieve such a finish, hair cosmetics such as shampoos, hair rinses, wash-off type in-bath hair treatments, and leave-on type out-bath treatments have conventionally been used to make the hair slippery, easier to comb, and moist. Attempts have been made to blend silicones and liquid/solid oil agents in order to provide a smooth feel (for example, Patent Document 1).
また、軽い仕上がりとなるようにカチオン性ポリマー、カチオン性界面活性剤、シリコーン、油剤、糖類等の配合や量を調整し、毛髪の重さをなくすことによって、髪の動きを出すことも試みられている。 In addition, attempts have been made to make the hair move by adjusting the composition and amount of cationic polymers, cationic surfactants, silicones, oil agents, sugars, etc., to reduce the weight of the hair so as to achieve a light finish. ing.
一方、ムラサキシキブ属に属する植物の果実の抽出物を用いて毛髪のくし通り、しっとり感、つやを付与する組成物(例えば特許文献2)や、水道水等に残存する塩素を除去することにより毛髪のダメージを抑制するための、ムラサキシキブ属の植物の抽出物を含む塩素除去剤(例えば特許文献3)や、安全性が高く、使用性に優れ、著しい養毛促進効果があり禿、薄毛及び脱毛の予防・改善に有用な化粧料(例えば特許文献4)等、植物抽出物を用いる技術も提案されている。 On the other hand, a composition that uses an extract of the fruit of a plant belonging to the genus Murasakishibu to comb through the hair and imparts a moist feeling and gloss (for example, Patent Document 2), and a composition that removes chlorine remaining in tap water etc. A chlorine remover containing an extract of a plant of the genus Murasakib (for example, Patent Document 3), which is highly safe, has excellent usability, and has a remarkable effect of promoting hair nourishing, baldness, thinning hair, and hair loss. Techniques using plant extracts have also been proposed, such as cosmetics useful for the prevention and improvement of (for example, Patent Document 4).
しかしながら、特許文献1のようにシリコーンや、液状・固形状の油剤を配合した毛髪化粧料では、毛髪がしっとりと重くまとまるために動きを出しにくく、近年のヘアスタイルにおいて要求されているニーズを満足させることは困難であり、ダメージをケアしながらも軽やかで動きのあるヘアスタイルにすることが課題であった。また、軽い仕上がりとなるようにシリコーン及び油剤の配合や量を調整することにより髪の動きを出す毛髪化粧料では、毛髪の重さはなくなるもののぱさつきが生じてしまい、髪のダメージを補習しながらも軽やかな動きを出すエアリー感を出せないという課題があった。 However, hair cosmetics containing silicone and liquid/solid oils as in Patent Document 1 make the hair moist and heavy, making it difficult for the hair to move, thus satisfying the needs of recent hairstyles. The challenge was to create a light and dynamic hairstyle while caring for the damage. In addition, hair cosmetics that make the hair move by adjusting the formulation and amount of silicone and oil so as to give a light finish, the weight of the hair is lost, but the hair becomes dry, and while repairing the damage to the hair. However, there was a problem that it was not possible to create an airy feeling that gives a light movement.
更に、毛髪のくし通りを良好にし、しっとり感を与えてダメージを抑制したり、養毛促進効果を実現する等、技術は年々進歩しているものの、毛髪のダメージをケアしながらも、特に軽やかで動きのあるヘアスタイルにしたいという要求も拡大し続けており、更なる技術の向上が求められている。 In addition, although the technology is improving year by year, such as improving the combability of the hair, giving a moist feeling to suppress damage, and realizing the effect of promoting hair growth, it is particularly light while caring for hair damage. Demand for hairstyles with movement continues to grow, and further improvements in technology are required.
本発明は上記事情に鑑みてなされたものであり、ダメージをケアしながらも毛髪が軽やかで動きやすい仕上がりとなるように、毛髪の動きを改善することを課題とする。 The present invention has been made in view of the above circumstances, and an object of the present invention is to improve the movement of hair so that the hair can be light and easy to move while taking care of damage.
発明者は、上記課題に対して鋭意研究した結果、ムラサキシキブ属コムラサキ抽出物とカチオン性物質を含む毛髪の動き改善のための毛髪化粧料、毛髪処理キット、及びそれらを用いた毛髪処理方法が、上記目的を達成できることを見出して、本発明を完成した。 As a result of intensive research on the above-mentioned problems, the inventors have developed a hair cosmetic, a hair treatment kit, and a hair treatment method using the same for improving the movement of hair containing an extract of the genus Pleurotus purpurea and a cationic substance. The inventors have completed the present invention by finding that the above object can be achieved.
すなわち、本発明は、第一剤若しくは第二剤のいずれか一方を使用する一剤式又は、第一剤及び第二剤の両方を使用する二剤式の毛髪化粧料であって、(A)ムラサキシキブ属コムラサキ抽出物と(B)カチオン性物質、を含むことを特徴とする、毛髪の動き改善のための毛髪化粧料である。 That is, the present invention is a one-agent hair cosmetic that uses either the first agent or the second agent, or a two-agent hair cosmetic that uses both the first agent and the second agent, ) an extract of the genus Pleurotus purpurea and (B) a cationic substance, a hair cosmetic for improving the movement of hair.
さらに本発明の一態様において、(A)ムラサキシキブ属コムラサキ抽出物の配合量は、第一剤と第二剤のそれぞれの質量に対して0.001質量%~20質量%であり、(B)カチオン性物質の配合量は、第一剤と第二剤のそれぞれの質量に対して0.001質量%~10質量%であることが好ましい。 Furthermore, in one aspect of the present invention, (A) the content of the extract of the genus Pleurotus purpurea is 0.001% by mass to 20% by mass with respect to the mass of each of the first agent and the second agent, and (B) The amount of the cationic substance compounded is preferably 0.001% by mass to 10% by mass with respect to the mass of each of the first agent and the second agent.
さらに本発明の一態様において、第一剤は、成分(B)として(B-1)カチオン化多糖類を含むことが好ましい。 Furthermore, in one aspect of the present invention, the first agent preferably contains (B-1) a cationized polysaccharide as component (B).
さらに本発明の一態様において、第二剤は、成分(B)として(B-2)カチオン性界面活性剤を含むことが好ましい。 Furthermore, in one aspect of the present invention, the second agent preferably contains (B-2) a cationic surfactant as component (B).
さらに本発明の一態様において、前記第一剤と第二剤はいずれも洗い流さないトリートメントでも良いが、好ましくは、前記第一剤はシャンプーであり、前記第二剤はヘアリンス、ヘアコンディショナー、ヘアトリートメント、又はヘアパックであることが好ましい。 Furthermore, in one aspect of the present invention, both the first agent and the second agent may be treatments that are not rinsed off, but preferably the first agent is a shampoo and the second agent is a hair rinse, hair conditioner, or hair treatment. , or a hair pack.
さらに本発明の一態様において、本発明は、前記第一剤と前記第二剤とからなり、前記第一剤を毛髪へ塗布した後に前記第二剤を毛髪へ塗布する毛髪の動き改善のための毛髪処理キットである。 Furthermore, in one aspect of the present invention, the present invention comprises the first agent and the second agent, and is for improving the movement of hair in which the second agent is applied to the hair after the first agent is applied to the hair. is a hair treatment kit.
さらに本発明の一態様において、本発明は、前記第一剤を塗布した後に前記第二剤を塗布する毛髪の動き改善のための毛髪処理方法である。 Furthermore, in one aspect of the present invention, the present invention is a hair treatment method for improving movement of hair, wherein the second agent is applied after the first agent is applied.
本発明によれば、ムラサキシキブ属コムラサキ抽出物が毛髪化粧料におけるカチオン性物質の分散性を良くすることで毛髪に対するムラづきやべたつきが解消し、ダメージをケアしながらも毛髪にべたつきや重さを与えることなく、毛髪の軽やかで動きやすい仕上がりに優れる毛髪化粧料を提供することができる。 According to the present invention, the extract of the genus Pleurotus tricolor improves the dispersibility of the cationic substance in the hair cosmetic, thereby eliminating unevenness and stickiness to the hair, and while caring for damage, the stickiness and heaviness of the hair are eliminated. It is possible to provide a hair cosmetic excellent in the finish of hair that is light and easy to move without imparting moisture.
以下、本発明の毛髪化粧料について詳細に説明する。 The hair cosmetic composition of the present invention will be described in detail below.
[毛髪化粧料]
本発明の毛髪化粧料とは、ムラサキシキブ属コムラサキ抽出物とカチオン性物質を含む、洗い流すタイプの毛髪化粧料である。
ここで、「洗い流すタイプ」の毛髪化粧料とは、塗布したままにせずに洗い流すことを特徴とする浴室内で使用される毛髪化粧料のことであり、いわゆるインバスタイプの毛髪化粧料である。
[Hair cosmetics]
The hair cosmetic composition of the present invention is a wash-off type hair cosmetic composition containing an extract of the genus Violet purpurea and a cationic substance.
Here, the "rinse-off type" hair cosmetic is a hair cosmetic used in the bathroom that is characterized by rinsing off without leaving it applied, and is a so-called in-bath type hair cosmetic.
インバスタイプの毛髪化粧料としては、例えば、シャンプー、ヘアリンス、リンスインシャンプー、ヘアコンディショナー、ヘアトリートメント、ヘアパック等が挙げられる。 Examples of in-bath hair cosmetics include shampoos, hair rinses, rinse-in shampoos, hair conditioners, hair treatments, and hair packs.
本発明の毛髪化粧料は、第一剤又は第二剤のいずれかを単独で使用する一剤式としてもよいが、第一剤及び第二剤を組み合わせて使用する二剤式とすることが好ましい。本発明の毛髪化粧料において、第一剤はカチオン性物質としてカチオン化多糖類を含み、第二剤はカチオン性物質としてカチオン性界面活性剤を含む。また、本発明の第一剤及び第二剤はいずれもヘアリンス、ヘアコンディショナー、ヘアトリートメントであってもよいが、第一剤はシャンプーであり、第二剤はヘアリンス、ヘアコンディショナー、又はヘアトリートメントであることが好ましい。 The hair cosmetic composition of the present invention may be of a one-agent type in which either the first agent or the second agent is used alone, but may be of a two-agent type in which the first agent and the second agent are used in combination. preferable. In the hair cosmetic composition of the present invention, the first agent contains a cationic polysaccharide as a cationic substance, and the second agent contains a cationic surfactant as a cationic substance. Both the first and second agents of the present invention may be a hair rinse, hair conditioner, or hair treatment, but the first agent is a shampoo and the second agent is a hair rinse, hair conditioner, or hair treatment. Preferably.
以下、本発明の毛髪化粧料の各成分について詳細に説明する。
[(A)ムラサキシキブ属コムラサキ抽出物]
本発明において、ムラサキシキブ属コムラサキ抽出物は、下記の成分(B)カチオン性物質の分散性を改善し、毛髪の指通りを良くして重くならずにまとまりやすくするための成分として用いられる。本発明のムラサキシキブ属コムラサキ抽出物は、クマツヅラ科ムラサキシキブ属コムラサキの抽出物である。ムラサキシキブ属コムラサキ(学名Callicarpa dichotoma)は日本、朝鮮、中国の湿地付近に自生する落葉低木である。抽出物を得るための植物の部位はどの部位でもよく、例えば、全草、葉、幹、茎、枝、枝葉、果皮、果実、樹皮、樹液、種子、根茎、根、花等の1又は2以上の部位を生のままで若しくは乾燥させて使用する。好ましくは、ムラサキシキブ属コムラサキの果実の抽出物である。また、本発明においては、ムラサキシキブ属コムラサキ抽出物は市販品を用いてもよく、これに限定されるものではないが、コムラサキ果実BG30(丸善製薬株式会社製)が挙げられる。
Each component of the hair cosmetic composition of the present invention will be described in detail below.
[(A) Murasakikibu genus Komurasaki extract]
In the present invention, an extract of the genus Pleurotus purpurea is used as a component for improving the dispersibility of the following component (B) cationic substance and improving the combability of the hair to make it easy to comb without making it heavy. The extract of the genus Pleurotus purpurea according to the present invention is an extract of the genus Pleurotus purpurea of the family Verbenaceae. Callicarpa dichotoma (scientific name: Callicarpa dichotoma) is a deciduous shrub that grows naturally near marshes in Japan, Korea, and China. The part of the plant for obtaining the extract may be any part, for example, whole plant, leaf, trunk, stem, branch, foliage, pericarp, fruit, bark, sap, seed, rhizome, root, flower, etc. 1 or 2 The above parts are used raw or dried. Preferably, it is an extract of the fruit of the genus Murasakikibu. In addition, in the present invention, a commercially available product may be used as the extract of the genus Pleurotus purpurea, and examples include, but are not limited to, Pleurotus purpurea fruit BG30 (manufactured by Maruzen Pharmaceutical Co., Ltd.).
(ムラサキシキブ属コムラサキ抽出物の抽出方法)
ムラサキシキブ属コムラサキ抽出物は、抽出溶媒により抽出する。抽出溶媒としては、特に限定されるものではないが、例えば、水、エタノール、メタノール、イソプロパノール、イソブタノール、n-ヘキサノール、メチルアミルアルコール、2-エチルブタノール、n-オクチルアルコール等の1価アルコール類、グリセリン、エチレングリコール、エチレングリコールものメチルエーテル、プロピレングリコール、プロピレングリコールモノメチルエーテル、プロピレングリコールモノエチルエーテル、トリエチレングリコール、1,3-ブチレングリコール、へキシレングリコール等の多価アルコール又はその誘導体、アセトン、メチルエチルケトン、メチルイソブチルケトン、メチル-n-プロピルケトン等のケトン類、酢酸エチル、酢酸イソプロピル等のエステル類、エチルエーテル、イソプロピルエーテル、n-ブチルエーテル等のエーテル類、スクワラン、ワセリン、パラフィンワックス、パラフィン油等の炭化水素類、オリーブ油、小麦麦芽油、米油、ゴマ油、マカデミアンナッツ油、アーモンド油、ヤシ油等の植物油脂、牛脂、豚脂、鯨脂等の動物油脂等が挙げられる。また、リン酸緩衝生理食塩水等の無機塩類を添加した極性溶媒や界面活性剤を添加した溶媒を用いることができ、さらに、水、二酸化炭素、エチレン、プロピレン、エタン、プロパン、一酸化二窒素、クロロジフルオロメタン、クロロトリフルオロメタン、キセノン、アンモニア、メタノール、エタノール等の1種又は2種以上の超臨界流体、若しくは亜臨界流体を用いてもよい。ムラサキシキブ属コムラサキ抽出物は
抽出溶媒と純分の混合物の状態で使用され、その純分の濃度は限定されるものではないが抽出物全体の0.001質量%~50%質量(以下、特に記載のあるもの以外は、質量%を単に「%」で示す。)であり、好ましくは0.1%~5%である。
(Method for Extraction of Murasakikibu Genus Miurasaki Extract)
The extract of the genus Murasakikibu is extracted with an extraction solvent. Examples of the extraction solvent include, but are not limited to, monohydric alcohols such as water, ethanol, methanol, isopropanol, isobutanol, n-hexanol, methylamyl alcohol, 2-ethylbutanol, and n-octyl alcohol. , glycerin, ethylene glycol, ethylene glycol methyl ether, propylene glycol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, triethylene glycol, 1,3-butylene glycol, hexylene glycol and other polyhydric alcohols or derivatives thereof, acetone , methyl ethyl ketone, methyl isobutyl ketone, methyl-n-propyl ketone and other ketones, ethyl acetate, isopropyl acetate and other esters, ethyl ether, isopropyl ether, n-butyl ether and other ethers, squalane, petrolatum, paraffin wax, paraffin Examples include hydrocarbons such as oils, vegetable oils such as olive oil, wheat germ oil, rice oil, sesame oil, macadamia nut oil, almond oil and coconut oil, and animal oils such as beef tallow, lard and whale tallow. In addition, a polar solvent containing inorganic salts such as phosphate buffered saline or a solvent containing a surfactant can be used, and water, carbon dioxide, ethylene, propylene, ethane, propane, dinitrogen monoxide , chlorodifluoromethane, chlorotrifluoromethane, xenon, ammonia, methanol, ethanol, or the like, or one or more supercritical fluids or subcritical fluids may be used. The extract of the genus Pleurotus purpurea is used in the form of a mixture of the extraction solvent and the pure content, and the concentration of the pure content is not limited, but it is 0.001% by mass to 50% by mass of the entire extract (hereinafter, particularly described The mass % is simply indicated by "%" except for some items, and is preferably 0.1% to 5%.
本発明の毛髪化粧料における(A)ムラサキシキブ属コムラサキ抽出物の配合量は、特に限定されるものではないが、第一剤、第二剤のそれぞれの質量に対して、好ましくは0.001%~20%であり、更に好ましくは0.01%~10%の範囲である。(A)成分が0.001%以上であれば、カチオン性物質の分散性を良くすることで、毛髪に対してべたつきや重さを感じることなく、ダメージをケアし、毛髪が軽やかで動きやすい仕上がりになるという本発明の効果を十分に発揮することができ、(A)成分が20%以下であれば、分離等の問題が生じることがないことから好ましい。 The amount of (A) the extract of the genus Pleurotus purpurea in the hair cosmetic composition of the present invention is not particularly limited, but is preferably 0.001% based on the mass of each of the first agent and the second agent. to 20%, more preferably 0.01% to 10%. If the component (A) is 0.001% or more, by improving the dispersibility of the cationic substance, the hair does not feel sticky or heavy, it cares for damage, and the hair is light and easy to move. The effect of the present invention, that is, the finished product can be sufficiently exhibited, and if the component (A) is 20% or less, problems such as separation do not occur, which is preferable.
[(B)カチオン性物質]
本発明のカチオン性物質は、水に溶解して陽イオンとなる物質のことである。本発明において、カチオン性物質は水に溶解して陽イオンとなるのであれば、溶解前は4級アンモニウム塩の形態であってもよく、3級アミンの形態であってもよい。カチオン性物質の具体例としては、主にシャンプー等で用いられるカチオン性多糖類や合成系のカチオン性ポリマー、主にコンディショナーやトリートメント、洗い流さないタイプのアウトバストリートメント等に使用されるカチオン性界面活性剤、またその両者に配合される塩基性アミノ酸やアミノ糖等である。本発明においてこのようなカチオン性物質を1種又は2種以上組み合わせて使うことができる。
[(B) cationic substance]
The cationic substance of the present invention is a substance that becomes a cation when dissolved in water. In the present invention, the cationic substance may be in the form of a quaternary ammonium salt or a tertiary amine before dissolution, as long as it dissolves in water and becomes a cation. Specific examples of cationic substances include cationic polysaccharides and synthetic cationic polymers that are mainly used in shampoos, etc., and cationic surfactants that are mainly used in conditioners, treatments, and leave-on bath treatments. agents, and basic amino acids and amino sugars blended in both. In the present invention, such cationic substances can be used singly or in combination of two or more.
本発明における(B)カチオン性物質の配合量は、特に限定されるものではないが、第一剤、第二剤のそれぞれの質量に対して、配合量は、好ましくは0.001%~10%であり、更に好ましくは0.01%~3%である。 The amount of the cationic substance (B) in the present invention is not particularly limited. %, more preferably 0.01% to 3%.
[(B-1)カチオン性多糖類]
本発明において一剤に配合される好ましいカチオン性物質としてカチオン化多糖類があげられる。カチオン化多糖類とは多糖類をカチオン化したものであれば、特に限定されないが、ポリクオタニウム-10等のカチオン化セルロース、グァーヒドロキシプロピルトリモニウムクロリドやカッシアヒドロキシプロピルトリモニウムクロリド等のカチオン化ガラクトマンナン、塩化ヒドロキシプロピルトリモニウムデンプン等のカチオン化デンプン等が挙げられる。このようなカチオン化多糖類を1種又は2種以上組み合わせて使うことができるが、その中でもグアーヒドロキシプロピルトリモニウムクロリド及びポリクオタニウム-10を用いることが望ましい。
[(B-1) Cationic Polysaccharide]
In the present invention, a cationic polysaccharide is a preferred cationic substance to be blended into one agent. The cationized polysaccharide is not particularly limited as long as it is a cationized polysaccharide, and includes cationized cellulose such as polyquaternium-10, cationized galactomannan such as guar hydroxypropyltrimonium chloride and cassia hydroxypropyltrimonium chloride. , cationized starch such as hydroxypropyltrimonium chloride starch, and the like. Such cationic polysaccharides can be used singly or in combination of two or more. Among them, it is preferable to use guar hydroxypropyltrimonium chloride and polyquaternium-10.
[(B-2)カチオン性界面活性剤]
本発明において二剤に配合される好ましいカチオン性物質としてカチオン性界面活性剤があげられる。カチオン性界面活性剤とは水に溶解して親水基が陽イオンとなる界面活性剤である。本発明のカチオン性界面活性剤としては、アルキル型4級アンモニウム塩、ジアルキル型4級アンモニウム塩、エーテル型4級アンモニウム塩、脂肪酸アミドアミン、脂肪族アミンを用いることができる。また、本発明において、カチオン性界面活性剤はそれぞれ一種単独で又は二種以上を組み合わせて用いることができる。
[(B-2) Cationic surfactant]
A cationic surfactant is a preferable cationic substance to be blended in the second agent in the present invention. A cationic surfactant is a surfactant whose hydrophilic group becomes a cationic ion when dissolved in water. As the cationic surfactant of the present invention, alkyl-type quaternary ammonium salts, dialkyl-type quaternary ammonium salts, ether-type quaternary ammonium salts, fatty acid amidoamines, and aliphatic amines can be used. Moreover, in the present invention, the cationic surfactants can be used singly or in combination of two or more.
(アルキル型4級アンモニウム塩)
本発明のアルキル型4級アンモニウム塩(脂肪族4級アンモニウム塩)は、下記一般式(1)で示される。
一般式(1)で表される脂肪族4級アンモニウム塩として、限定されるものではないが具体例を示すと、ラウリルトリモニウムクロリド、セトリモニウムクロリド、セテアルトリモニウムクロリド、ステアルトリモニウムクロリド、ベヘントリモニウムクロリド、オレイルトリモニウムクロリド、ココトリモニウムクロリド、ラウリルトリモニウムブロミド、セトリモニウムブロミド、セテアルトリモニウムブロミド、ステアルトリモニウムブロミド、ベヘントリモニウムブロミド、オレイルトリモニウムブロミド、ココトリモニウムブロミド、ラウリルトリモニウムメトサルフェート、セトリモニウムメトサルフェート、セテアルトリモニウムメトサルフェート、ステアルトリモニウムメトサルフェート、ベヘントリモニウムメトサルフェート、オレイルトリモニウムメトサルフェート、ココトリモニウムメトサルフェート、ラウリルトリモニウムエトサルフェート、セトリモニウムエトサルフェート、セテアルトリモニウムエトサルフェート、ステアルトリモニウムエトサルフェート、ベヘントリモニウムエトサルフェート、オレイルトリモニウムエトサルフェート、ココトリモニウムエトサルフェートが挙げられる。好ましくはベヘントリモニウムクロリドである。
(Alkyl-type quaternary ammonium salt)
The alkyl-type quaternary ammonium salt (aliphatic quaternary ammonium salt) of the present invention is represented by the following general formula (1).
Specific examples of the aliphatic quaternary ammonium salt represented by the general formula (1) include, but are not limited to, lauryltrimonium chloride, cetrimonium chloride, ceteartrimonium chloride, steartrimonium chloride, and behene. trimonium chloride, oleyltrimonium chloride, cocotrimonium chloride, lauryltrimonium bromide, cetrimonium bromide, ceteartrimonium bromide, steartrimonium bromide, behentrimonium bromide, oleyltrimonium bromide, cocotrimonium bromide, lauryltri monium methosulfate, cetrimonium methosulfate, ceteartrimonium methosulfate, steartrimonium methosulfate, behentrimonium methosulfate, oleyltrimonium methosulfate, cocotrimonium methosulfate, lauryltrimonium ethosulfate, cetrimonium ethosulfate, Ceteartrimonium ethosulfate, steartrimonium ethosulfate, behentrimonium ethosulfate, oleyltrimonium ethosulfate, cocotrimonium ethosulfate. Behentrimonium chloride is preferred.
本発明の(B-2)カチオン性界面活性剤として上記脂肪族4級アンモニウム塩を用いる場合、その配合量は、第二剤の質量に対して、好ましくは0.1%~10%、更に好ましくは0.5%~5%の範囲である。この配合量の範囲であれば、コムラサキによる分散性が良くなり、毛髪に対して、べたつきや重さを感じることなく、エアリーな仕上がり感を与えることができるため好ましい。 When the aliphatic quaternary ammonium salt is used as the cationic surfactant (B-2) of the present invention, the amount thereof is preferably 0.1% to 10%, relative to the mass of the second agent, and further It is preferably in the range of 0.5% to 5%. Within this range of blending amount, dispersibility by Komurasaki is improved, and an airy finish feeling can be given to the hair without feeling sticky or heavy.
(ジアルキル型4級アンモニウム塩)
本発明のジアルキル型4級アンモニウム塩は、下記一般式(2)で示される。
一般式(2)で表されるジアルキル型4級アンモニウムとして、限定されるものではないが具体例を示すと、ジラウリルトジモニウムクロリド、ジセチルジモニウムクロリド、ジセテアルジモニウムクロリド、ジステアルジモニウムクロリド、ジベヘニルジモニウムクロリド、ジオレイルジモニウムクロリド、ジココジモニウムクロリド等が挙げられる。
(Dialkyl-type quaternary ammonium salt)
The dialkyl-type quaternary ammonium salt of the present invention is represented by the following general formula (2).
Specific examples of the dialkyl-type quaternary ammonium represented by the general formula (2) include, but are not limited to, dilauryltodimonium chloride, dicetyldimonium chloride, dicetealdimonium chloride, distealdimonium chloride, monium chloride, dibehenyldimonium chloride, dioleyldimonium chloride, dicocodimonium chloride and the like.
本発明の(B-2)カチオン性界面活性剤として上記ジアルキル型4級アンモニウム塩を用いる場合、その配合量は、毛髪化粧料全体に対して、好ましくは0.1%~10%、更に好ましくは0.5%~5%の範囲である。この配合量の範囲であれば、コムラサキによる分散性が良くなり、毛髪に対して、べたつきや重さを感じることなく、エアリーな仕上がり感を与えることができるため好ましい。 When the dialkyl-type quaternary ammonium salt is used as the cationic surfactant (B-2) of the present invention, the amount thereof is preferably 0.1% to 10%, more preferably 0.1% to 10%, based on the total amount of the hair cosmetic. is in the range of 0.5% to 5%. Within this range of blending amount, dispersibility by Komurasaki is improved, and an airy finish feeling can be given to the hair without feeling sticky or heavy.
(エーテル型4級アンモニウム塩)
本発明のエーテル型4級アンモニウム塩は、下記一般式(3)で示される。
ル硫酸基を表し、A1は炭素数1~3のアルキル基またはヒドロキシアルキル基を表す。)
一般式(3)で表されるエーテル型4級アンモニウム塩として、限定されるものではないが具体例を示すと、ラウロキシプロピルトリモニウムクロリド、セトキシプロピルトリモニウムクロリド、セテアロキシプロピルトリモニウムクロリド、ステアロキシプロピルトリモニウムクロリド、ベヘノキシプロピルトリモニウムクロリド、オレオキシプロピルトリモニウムクロリド、ラウリルPGトリモニウムクロリド、セチルPGトリモニウムクロリド、セテアルPGトリモニウムクロリド、ステアリルPGトリモニウムクロリド、ベヘニルPGトリモニウムクロリド、オレイルPGトリモニウムクロリド、ココイルPGトリモニウムクロリドがあげられる。
(Ether type quaternary ammonium salt)
The ether-type quaternary ammonium salt of the present invention is represented by the following general formula (3).
Specific examples of the ether-type quaternary ammonium salt represented by the general formula (3) include, but are not limited to, lauroxypropyltrimonium chloride, cethoxypropyltrimonium chloride, and cetearyloxypropyltrimonium chloride. , stearyl PG trimonium chloride, behenoxypropyltrimonium chloride, oleoxypropyltrimonium chloride, lauryl PG trimonium chloride, cetyl PG trimonium chloride, ceteal PG trimonium chloride, stearyl PG trimonium chloride, behenyl PG trimonium chloride monium chloride, oleyl PG trimonium chloride, and cocoyl PG trimonium chloride.
本発明の(B-2)カチオン性界面活性剤として上記エーテル型4級アンモニウム塩を用いる場合、その配合量は、第二剤の質量に対して、好ましくは0.1%~10%、更に好ましくは0.5%~5%の範囲である。この配合量の範囲であれば、コムラサキによる分散性が良くなり、毛髪に対して、べたつきや重さを感じることなく、エアリーな仕上がり感を与えることができるため好ましい。 When the ether-type quaternary ammonium salt is used as the cationic surfactant (B-2) of the present invention, the amount thereof is preferably 0.1% to 10%, relative to the mass of the second agent, and further It is preferably in the range of 0.5% to 5%. Within this range of blending amount, dispersibility by Komurasaki is improved, and an airy finish feeling can be given to the hair without feeling sticky or heavy.
(脂肪酸アミドアミン)
本発明の脂肪酸アミドアミンは、下記一般式(4)で示される。
一般式(4)で表される脂肪酸アミドアミンとして、限定されるものではないが具体例を示すと、ラウラミドプロピルジメチルアミン、セタミドプロピルジメチルアミン、セテアラミドプロピルジメチルアミン、ステアラミドプロピルジメチルアミン、ベヘナミドプロピルジメチルアミン、オレアラミドプロピルジメチルアミン、コカミドプロピルジメチルアミンがあげられる。好ましくはベヘナミドプロピルジメチルアミンである。
(Fatty acid amidoamine)
The fatty acid amidoamine of the present invention is represented by the following general formula (4).
Specific examples of the fatty acid amidoamine represented by formula (4) include, but are not limited to, lauramidopropyldimethylamine, cetamidopropyldimethylamine, cetearamidopropyldimethylamine, stearamidopropyldimethylamine, behenamidopropyldimethylamine, olearamidopropyldimethylamine, and cocamidopropyldimethylamine. Behenamidopropyldimethylamine is preferred.
(脂肪族アミン)
本発明の脂肪族アミンは、下記一般式(5)で示される。
(式中、R9は、直鎖又は分岐した炭素数12~24の飽和もしくは不飽和アルキル基、R10、R11は同一であっても異なっていてもよくC3H7O2で表されるヒドロキシプロピル基またはC2H4Oで表されるあるエチレングリコール基、a、bは1~2の整数を示す。)
一般式(5)で表される脂肪族アミンとして、限定されるものではないが具体例を示すと、PPG-1/PEG-1ラウラミン、PPG-1/PEG-1セタミン、PPG-1/PEG-1セテアラミン、PPG-1/PEG-1ステアラミン、PPG-1/PEG-1オレアラミン、PPG-1/PEG-1ベヘナミン、PPG-2/PEG-1ラウラミン、PPG-2/PEG-1セタミン、PPG-2/PEG-1セテアラミン、PPG-
2/PEG-1ステアラミン、PPG-2/PEG-1オレアラミン、PPG-2/PEG-1ベヘナミン、PPG-1/PEG-2ラウラミンPPG-1/PEG-2セタミン、PPG-1/PEG-2セテアラミン、PPG-1/PEG-2ステアラミン、PPG-1/PEG-2オレアラミン、PPG-1/PEG-2ベヘナミン、PPG-2/PEG-2ラウラミン、PPG-2/PEG-2セタミン、PPG-2/PEG-2セテアラミン、PPG-2/PEG-2ステアラミン、PPG-2/PEG-2オレアラミン、PPG-2/PEG-2等が挙げられる。これらの中でも、R9が炭素数18のステアリル基、a=1、b=1である、PPG-1/PEG-1ステアラミンが特に好ましい。
(aliphatic amine)
The aliphatic amine of the present invention is represented by the following general formula (5).
(wherein R 9 is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms; R 10 and R 11 may be the same or different and are represented by C 3 H 7 O 2 ; or an ethylene glycol group represented by C 2 H 4 O, a and b are integers of 1 to 2.)
Specific examples of the aliphatic amine represented by formula (5) include, but are not limited to, PPG-1/PEG-1 lauramine, PPG-1/PEG-1 cetamine, PPG-1/PEG -1 cetearamine, PPG-1/PEG-1 stearamine, PPG-1/PEG-1 olearamine, PPG-1/PEG-1 behenamine, PPG-2/PEG-1 lauramine, PPG-2/PEG-1 cetamine, PPG -2/PEG-1 cetearamine, PPG-
2/PEG-1 stearamine, PPG-2/PEG-1 olealamine, PPG-2/PEG-1 behenamine, PPG-1/PEG-2 lauramine PPG-1/PEG-2 cetamine, PPG-1/PEG-2 cetearamine , PPG-1/PEG-2 stearamine, PPG-1/PEG-2 olealamine, PPG-1/PEG-2 behenamine, PPG-2/PEG-2 lauramine, PPG-2/PEG-2 cetamine, PPG-2/ PEG-2 cetealamine, PPG-2/PEG-2 stearamine, PPG-2/PEG-2 olealamine, PPG-2/PEG-2 and the like. Among these, PPG-1/PEG-1 stearamine, in which R 9 is a stearyl group having 18 carbon atoms, a=1 and b=1, is particularly preferred.
上記の脂肪族アミンや脂肪酸アミドアミンは水に溶解させ、適宜酸を添加し中和することでカチオン性を示す。使用する酸は限定されるものではないが有機酸が好ましい。具体的に示すとグリコール酸、乳酸、グリセリン酸、グルコン酸、パントテン酸等のヒドロキシモノカルボン酸;リンゴ酸、酒石酸等のヒドロキシジカルボン酸;クエン酸等のヒドロキシトリカルボン酸、シュウ酸、マロン酸、マレイン酸、コハク酸、グルタル酸等のジカルボン酸;L-グルタミン酸、L-アスパラギン酸等の酸性アミノ酸;ピログルタミン酸;安息香酸、p-トルエンスルホン酸等の芳香族酸等が挙げられる。これらの中でも、乳化性の点から、ヒドロキモノカルボン酸、ヒドロキシジカルボン酸、ヒドロキシトリカルボン酸が挙げられる。 The above-mentioned aliphatic amines and fatty acid amidoamines are dissolved in water and neutralized by adding an appropriate acid to exhibit cationic properties. Although the acid to be used is not limited, an organic acid is preferred. Specifically, hydroxymonocarboxylic acids such as glycolic acid, lactic acid, glyceric acid, gluconic acid and pantothenic acid; hydroxydicarboxylic acids such as malic acid and tartaric acid; hydroxytricarboxylic acids such as citric acid, oxalic acid, malonic acid and maleic acid. acids, dicarboxylic acids such as succinic acid and glutaric acid; acidic amino acids such as L-glutamic acid and L-aspartic acid; pyroglutamic acid; aromatic acids such as benzoic acid and p-toluenesulfonic acid; Among these, hydroxymonocarboxylic acid, hydroxydicarboxylic acid, and hydroxytricarboxylic acid can be mentioned from the viewpoint of emulsifiability.
[(B-3)その他のカチオン性物質]
本発明のカチオン性物質として、水に溶解してイオン解離をする親水基が陽イオンとなる物質であれば、上記成分(B-1)カチオン化多糖類、上記成分(B-2)カチオン性界面活性剤以外のカチオン性物質であってもよい。
そのような物質としては、例えば、メタクリロイルエチルベタインとメタクリル酸PEG-9と塩化メタクリロイルエチルトリメチルアンモニウムの共重合体である、ポリオクタニウム-49、塩基性アミノ酸であるリシンやアルギニン、アミノ糖であるアセチルグルコサミン等が挙げられる。
[(B-3) Other cationic substances]
As the cationic substance of the present invention, if it is a substance in which the hydrophilic group that dissolves in water and dissociates ions becomes a cation, the above component (B-1) cationic polysaccharide, the above component (B-2) cationic Cationic substances other than surfactants may be used.
Examples of such substances include polyoctanium-49, which is a copolymer of methacryloylethyl betaine, PEG-9 methacrylate, and methacryloylethyltrimethylammonium chloride, basic amino acids such as lysine and arginine, and amino sugars. acetylglucosamine and the like.
このようなカチオン性物質の配合量は、本発明の効果を発揮する限りにおいては限定されるものではないが、第一剤、第二剤のそれぞれの質量に対して、好ましくは0.001%~10%であり、より好ましくは0.01%~5%である。この範囲内であれば、毛髪表面に被膜を形成し、泡立ち中やすすぎ時に毛髪が軋みにくく滑りやすくなることから、良好な使用感を実現することができることから、好ましい。 The amount of such a cationic substance compounded is not limited as long as the effects of the present invention are exhibited, but is preferably 0.001% based on the mass of each of the first agent and the second agent. to 10%, more preferably 0.01% to 5%. Within this range, a film is formed on the surface of the hair, and the hair does not creak easily during lathering or rinsing, and the hair becomes slippery.
[(C)その他の成分]
また、本発明の毛髪化粧料には、本発明の効果を損なわない範囲で公知の成分を適宜配合することができる。公知の成分としては、例えば、ラウリル硫酸塩、ポリオキシエチレンラウリルーテル硫酸塩、ラウリルベンゼンスルホン酸塩、ラウロイルメチル-β-アラニンナトリウム等のアニオン性界面活性剤;2-アルキル-N-カルボキシメチル-N-ヒドロキシエチルイミダゾニウムベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ヤシ油アルキルN-カルボキシエチル-N-ヒドロキシエチルイミダゾリニウムベタインナトリウム等の両性界面活性剤;ポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリン脂肪酸エステル等の非イオン界面活性剤;カチオン化セルロース、ヒドロキシエチルセルロース、ポリ(塩化ジアリルジメチルアンモニウム)、高重合ポリエチレングリコール等の高分子化合物;グリセリン、プロピレングリコール、ブチレングリコール、ジプロピレングリコール等の湿潤剤;ステアリン酸、ベヘニン酸、オレイン酸等の高級脂肪酸;ミリスチン酸イソプロピル等のエステル油;流動イソパラフィン、ワセリン、スクワラン等の炭化水素;ジメチルポリシロキサン、高重合シリコーン、ポリエーテル変性シリコーン等のシリコーン類;ジンクピリチオン、塩化ベンザルコニウム等の抗フケ成分;エタノール、メタノール、プロピルアルコール、イソプロピ
ルアルコール等の低級アルコール;L-アスパラギン酸、L-アスパラギン酸ナトリウム、DL-アラニン、L-アルギニン、グリシン、L-グルタミン酸、L-システイン、Lスレオニン等のアミノ酸;その他紫外線吸収剤、防腐剤、糖類、香料、色剤、金属イオン封鎖剤、酸化防止剤、各種薬剤等が挙げられる。
[(C) other components]
In addition, the hair cosmetic composition of the present invention can contain known ingredients as appropriate within a range that does not impair the effects of the present invention. Known components include, for example, anionic surfactants such as lauryl sulfate, polyoxyethylene lauryluther sulfate, laurylbenzenesulfonate, sodium lauroylmethyl-β-alanine; 2-alkyl-N-carboxymethyl- Amphoteric surfactants such as N-hydroxyethylimidazonium betaine, coconut oil fatty acid amidopropyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethylimidazolinium betaine sodium; polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid Nonionic surfactants such as esters and glycerin fatty acid esters; polymer compounds such as cationized cellulose, hydroxyethyl cellulose, poly(diallyldimethylammonium chloride), and highly polymerized polyethylene glycol; glycerin, propylene glycol, butylene glycol, dipropylene glycol, etc. higher fatty acids such as stearic acid, behenic acid and oleic acid; ester oils such as isopropyl myristate; hydrocarbons such as liquid isoparaffin, vaseline and squalane; Silicones; anti-dandruff ingredients such as zinc pyrithione and benzalkonium chloride; lower alcohols such as ethanol, methanol, propyl alcohol and isopropyl alcohol; L-aspartic acid, sodium L-aspartate, DL-alanine, L-arginine, glycine, Amino acids such as L-glutamic acid, L-cysteine, and L-threonine; and other UV absorbers, preservatives, sugars, fragrances, colorants, sequestering agents, antioxidants, various chemicals, and the like.
本発明の毛髪化粧料はシャンプー、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック、ヘアクリーム、アウトバストリートメント等に用いることが出来るが、上記のように本発明の効果をより効率よく発現させるという観点から、第一剤をシャンプー、第二剤をヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパックとして組み合わせて使用することが好ましい。また、本発明の毛髪化粧料は、常法により製造することができる。 The hair cosmetic composition of the present invention can be used for shampoos, hair rinses, hair conditioners, hair treatments, hair packs, hair creams, out-bath treatments, and the like, but as described above, the effect of the present invention is more efficiently expressed. Therefore, it is preferable to use the first agent as a shampoo and the second agent as a hair rinse, hair conditioner, hair treatment or hair pack. Moreover, the hair cosmetic composition of the present invention can be produced by a conventional method.
[毛髪処理キット]
本発明の毛髪処理キットは、第一剤及び第二剤からなり、前記第一剤を毛髪へ塗布した後に前記第二剤を塗布することを特徴とする、毛髪の動き改善のための毛髪処理キットである。本発明の毛髪処理キットにおける第一剤及び第二剤、並びにそれらの成分は、本発明の毛髪化粧料について上述したものと同一である。
[Hair treatment kit]
The hair treatment kit of the present invention comprises a first agent and a second agent, and is characterized in that the second agent is applied after the first agent is applied to the hair to treat hair for improving movement of the hair. It's a kit. The first and second agents and their components in the hair treatment kit of the present invention are the same as those described above for the hair cosmetic composition of the present invention.
[毛髪処理方法]
本発明の毛髪処理方法は、第一剤で毛髪を処理する工程、及び第二剤で毛髪を処理する工程を含む、毛髪の動き改善のための毛髪処理方法である。ムラサキシキブ属コムラサキ抽出物とカチオン化多糖類を含む前記第一剤で毛髪を処理した後に、ムラサキシキブ属コムラサキ抽出物とカチオン性界面活性剤を含む前記第二剤で毛髪を処理することにより、本発明の毛髪化粧料の効果を効率よく発現させることができることから好ましい。また、第一剤で毛髪を処理した後、第二剤で毛髪を処理する前にすすぎの行程をはさむことが好ましい。本発明の毛髪処理方法における第一剤及び第二剤、並びにそれらの成分は、本発明の毛髪化粧料について上述したものと同一である。
[Hair treatment method]
The hair treatment method of the present invention is a hair treatment method for improving movement of hair, comprising a step of treating hair with a first agent and a step of treating hair with a second agent. By treating the hair with the first agent containing an extract of the genus S. purpurea and a cationized polysaccharide, and then treating the hair with the second agent containing the genus S. purpurea extract and a cationic surfactant, the present invention. It is preferable because the effect of the hair cosmetic can be efficiently expressed. In addition, it is preferable to perform a rinsing step after treating the hair with the first agent and before treating the hair with the second agent. The first and second agents and their components in the hair treatment method of the present invention are the same as those described above for the hair cosmetic composition of the present invention.
本発明の毛髪化粧料、毛髪処理キット及び毛髪処理方法においては、第一剤によりダメージしている髪の1本1本のキューティクルが均一に整った状態にすることで髪の弾力が付与され、更に第二剤により髪の1本1本が均一にコーティングされることで髪全体が柔軟かつなめらかになる。したがって、第一剤及び第二剤を組み合わせて使用することで、結果としてダメージをケアしながらも毛髪にべたつきや重さを与えることなく、毛髪が軽やかで動きやすい仕上がりを生み出すことができる。特に、第一剤及び第二剤を組み合わせて使用する場合には、頭を動かした際の毛束の毛先部分の跳ね上がり角度が向上するため、よりエアリー感を出すことができるという優れた効果を発揮するため好ましい。 In the hair cosmetic composition, hair treatment kit and hair treatment method of the present invention, the cuticles of each hair damaged by the first agent are evenly arranged, thereby imparting elasticity to the hair. Furthermore, the second agent uniformly coats each strand of hair, making the entire hair soft and smooth. Therefore, by using the first agent and the second agent in combination, as a result, it is possible to create a finish that makes the hair light and easy to move without giving the hair stickiness or heaviness while caring for the damage. In particular, when the first agent and the second agent are used in combination, the angle at which the ends of the hair tufts bounce when the head is moved is improved, resulting in an excellent effect that a more airy feeling can be produced. It is preferable to exhibit
次に本発明の毛髪化粧料について実施例を用いて詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で使用した試料の調製方法、及び採用した試験法、評価法を説明する。 Next, the hair cosmetic composition of the present invention will be described in detail using examples, but the present invention is not limited thereto. Prior to the examples, the preparation method of the samples used in each example, and the employed test methods and evaluation methods will be described.
[毛束試料の準備方法]
(1)評価用毛束調整
ビューラックス社製アジア人同一人毛(長さ30cm、重さ10g)の毛束を10%濃度のラウレス硫酸ナトリウム溶液にて洗浄してタオルドライを行ったあと、長さ25cm、毛量を同一に調整し、ヘアブリーチ処理することにより、ダメージさせたものを評価用毛束として用いた。
[Method for preparing hair bundle sample]
(1) Hair bundle adjustment for evaluation A hair bundle of the same Asian human hair (30 cm in length, 10 g in weight) manufactured by Beaulux was washed with a 10% sodium laureth sulfate solution and dried with a towel. Hair tresses having a length of 25 cm, adjusted to the same amount of hair, and damaged by bleaching were used as tresses for evaluation.
[毛髪化粧料試料の調製方法]
実施例及び比較例における毛髪化粧料試料を、下表1~7に記載の配合で常法により調製した。成分(A)、(B-1)、(B-2)のダミー成分として、成分(a)、(b-1)、(b-2)を用いた。
[Method for preparing hair cosmetic sample]
Hair cosmetic samples in Examples and Comparative Examples were prepared by a conventional method according to the formulations shown in Tables 1 to 7 below. Components (a), (b-1) and (b-2) were used as dummy components for components (A), (B-1) and (B-2).
[毛束の評価方法]
(1)毛束の処理方法
評価用毛束を、10%のラウレス硫酸ナトリウム溶液3gを用いて洗浄した後、下表1~7に示した本発明の実施例及び比較例の組成物3gを各毛束に塗布し、40℃のお湯で洗い流した。
その後、タオルドライを行い、コーミングをして吊るした状態で22℃、湿度50%の恒温恒湿室にて自然乾燥させてから処理後の状態として画像で記録した。
[Evaluation method of hair bundle]
(1) Treatment method for hair bundle After washing the hair bundle for evaluation with 3 g of a 10% sodium laureth sulfate solution, 3 g of the compositions of the examples and comparative examples of the present invention shown in Tables 1 to 7 below were applied. It was applied to each hair tress and washed off with hot water at 40°C.
After that, it was dried with a towel, combed and suspended, and dried naturally in a constant temperature and humidity room at 22° C. and a humidity of 50%.
(2)毛束の評価方法
5名の訓練された評価者が、下記評価基準に従って観察評価し、5人のスコアの合計の平均値を算出した。そのようにして算出した平均値を下記スコア基準に基づき判定した。
(2) Evaluation method of hair bundle Five trained evaluators observed and evaluated according to the following evaluation criteria, and calculated the average value of the total scores of the five persons. The average value thus calculated was judged based on the following scoring criteria.
(3)毛束の評価項目
<評価1:軽やかな髪のしなり>
(評価方法)
上記の処理を施した毛束を機械的に左右に振動させることで、人が左右に頭を動かした際の髪の動きに近い状態を再現した。毛束を左右に振動させる機器として、ダブルアクションラボシェイカー SRR-2(商品名;アズワン株式会社製)を用いた。
ダブルアクションラボシェイカー SRR-2へ毛束を吊るす台(高さ40cm、横幅40cm)を固定して台の中央に処理した毛束を吊るし、60rpmの振とう速度で振動させた。このようにして機械的に左右に振動させた毛束の根元から毛先まで弾力があってまとまりながらも柔らかく曲がってカーブする様子を、評価者が肉眼で観察して軽やかな髪のしなりを評価した。評価基準及びスコア基準は、以下のとおりである。
(評価基準)
5点:毛束全体の根元から毛先まで軽やかにしなっている
4点:毛束全体の根元から毛先までやや軽やかにしなっている
3点:毛束の一部の中間から毛先まで軽やかにしなっている
2点:毛束全体がやや軽さに欠け、しなっていない。
1点:毛束全体が軽やかにしなっていない。
(スコア基準)
◎:大変優れている・・・4.5点以上
○:優れている・・・・・3点以上、4.5点未満
△:劣っている・・・・・1.5点以上、3点未満
×:大変劣っている・・・1.5点未満
(3) Hair bundle evaluation items <Evaluation 1: light hair flexibility>
(Evaluation method)
By mechanically vibrating the hair tufts that have undergone the above process, we were able to reproduce a state similar to the movement of the hair when a person moves their head left and right. A double action lab shaker SRR-2 (trade name; manufactured by AS ONE Co., Ltd.) was used as a device for vibrating the hair tufts left and right.
A table (height 40 cm, width 40 cm) for hanging the hair bundle was fixed to the double action lab shaker SRR-2, and the treated hair bundle was hung in the center of the table and vibrated at a shaking speed of 60 rpm. The evaluator observed with the naked eye how the hair bundles, which were mechanically vibrated in this way from the roots to the ends, were elastic and gathered together, but were also softly curved. evaluated. Evaluation criteria and score criteria are as follows.
(Evaluation criteria)
5 points: The entire hair bundle is lightly curved from the roots to the ends. 4 points: The entire hair bundle is slightly curved from the roots to the ends. Bent 2 points: The entire hair bundle lacks lightness and is not bent.
1 point: The entire hair bundle is not lightly bent.
(Score criteria)
◎: Excellent: 4.5 points or more ○: Excellent: 3 points or more, less than 4.5 points △: Inferior: 1.5 points or more, 3 points Less than points ×: Very poor ... less than 1.5 points
<評価2:毛束の角度>
(評価方法)
上記の処理を施した毛束を機械的に左右に振動させることで、人が左右に頭を動かした際の髪の動きに近い状態を再現した。毛束を左右に振動させる機器として、ダブルアクションラボシェイカー SRR-2(商品名;アズワン株式会社製)を用いた。
ダブルアクションラボシェイカー SRR-2へ毛束を吊るす台(高さ40cm、横幅40cm)を固定して台の中央に処理した毛束を吊るし、吊るした毛束の10cm後方に方眼紙つきパネルを設置した。また、吊るした毛束の50cm前方に、吊るした毛束の根元から毛先へ向かって15cmの位置と平行に動画撮影用のカメラを設置した。
ダブルアクションラボシェイカー SRR-2の振とう速度を60rpmに設定し、振とう開始後設定速度に到達してから30秒~1分間の間において、根元から毛先までの左
右の動きの動画を撮影・記録した。そのようにして撮影・記録した動画から、根元から毛先の左右それぞれの振れ幅の最大値を静止画像で確認し、方眼紙のメモリから振れ幅の最大値の角度を算出し、下記のスコア基準に基づき評価した。このようにして算出した角度が大きいほど、毛束が動きやすく軽やかであるために好ましいと評価した。
(スコア基準)
○:角度が35°以上
△:角度が20°以上35°未満
×:角度が20°未満
<Evaluation 2: Angle of hair bundle>
(Evaluation method)
By mechanically vibrating the hair tufts that have undergone the above process, we were able to reproduce a state similar to the movement of the hair when a person moves their head left and right. A double action lab shaker SRR-2 (trade name; manufactured by AS ONE Co., Ltd.) was used as a device for vibrating the hair tufts left and right.
A stand (height 40 cm, width 40 cm) is fixed to the double action lab shaker SRR-2, the treated hair bundle is hung in the center of the stand, and a panel with graph paper is installed 10 cm behind the hung hair bundle. bottom. In addition, 50 cm in front of the suspended hair bundle, a camera for video recording was installed in parallel with a position 15 cm from the root of the suspended hair bundle toward the tip of the hair.
Set the shaking speed of the double action lab shaker SRR-2 to 60 rpm, and record the left and right movement from the root to the tip for 30 seconds to 1 minute after reaching the set speed after the start of shaking.・Recorded. From the video shot and recorded in this way, check the maximum value of the left and right swing width from the root to the tip of the hair with a still image, calculate the angle of the maximum swing width from the memory of the graph paper, and score the following Evaluated based on criteria. The larger the angle calculated in this way, the more the hair tuft moves easily and lightly, so it was evaluated as preferable.
(Score criteria)
○: The angle is 35 ° or more △: The angle is 20 ° or more and less than 35 ° ×: The angle is less than 20 °
<評価3:さらさら感>
(評価方法)
上記の処理を施した毛束を吊るした状態で、評価者が毛束の中間部分から毛をすくってから1本1本を落とすようにしたとき、1本1本がパラパラと落ちる様子を見て毛髪のさらさら感を評価した。評価基準及びスコア基準は、以下のとおりである。
(評価基準)
5点:毛束全体の根元から毛先まで1本1本がさらさらしている。
4点:毛束の一部の根元から毛先まで1本1本がややさらさらしている。
3点:毛束の一部の根元から中間までの1本1本がさらさらしている。
2点:毛束全体がややさらさらしていない。
1点:毛束全体がさらさらしていない。
(スコア基準)
◎:大変優れている・・・4.5点以上
○:優れている・・・・・3点以上、4.5点未満
△:劣っている・・・・・1.5点以上、3点未満
×:大変劣っている・・・1.5点未満
<Evaluation 3: Smooth feeling>
(Evaluation method)
When the evaluator scooped the hairs from the middle part of the hair bundle and dropped them one by one while hanging the hair bundles that had undergone the above treatment, they watched how the hair fell off one by one. The dry feeling of the hair was evaluated by Evaluation criteria and score criteria are as follows.
(Evaluation criteria)
5 points: Each strand is smooth from the root to the tip of the entire hair bundle.
4 points: Each strand from the root to the tip of a part of the hair tuft is slightly dry.
3 points: Each strand from the root to the middle of a part of the hair bundle is smooth.
2 points: The hair tress as a whole is slightly dry.
1 point: The entire hair bundle is not dry.
(Score criteria)
◎: Excellent: 4.5 points or more ○: Excellent: 3 points or more, less than 4.5 points △: Inferior: 1.5 points or more, 3 points Less than points ×: Very poor ... less than 1.5 points
<評価4:指通り>
(評価方法)
上記の処理を施した毛束を吊るした状態で、評価者が根元から毛先まで指を通して、指の通りやすさを評価した。評価基準及びスコア基準は、以下のとおりである。
(評価基準)
5点:毛束の根元から毛先までの指通りがとても良い。
4点:毛束の根元から毛先までの指通りがやや良い。
3点:毛束の根元から中間の指通りが良い。
2点:毛束の根元から毛先の指通りがやや悪い。
1点:毛束全体の指通りが悪い。
(スコア基準)
◎:大変優れている・・・4.5点以上
○:優れている・・・・・3点以上、4.5点未満
△:劣っている・・・・・1.5点以上、3点未満
×:大変劣っている・・・1.5点未満
<Evaluation 4: finger penetration>
(Evaluation method)
An evaluator evaluated the easiness of passing the hair by passing the finger through the hair bundle from the root to the tip of the hair in a suspended state. Evaluation criteria and score criteria are as follows.
(Evaluation criteria)
5 points: Very good combability with fingers from the root to the tip of the hair bundle.
4 points: Finger combing from the root to the tip of the hair bundle is slightly good.
3 points: Good combability with fingers from the root to the middle of the hair bundle.
2 points: Slightly poor finger combability from the root to the tip of the hair bundle.
1 point: Poor combability with the fingers of the entire hair bundle.
(Score criteria)
◎: Excellent: 4.5 points or more ○: Excellent: 3 points or more, less than 4.5 points △: Inferior: 1.5 points or more, 3 points Less than points ×: Very poor ... less than 1.5 points
<評価5:べたつきのなさ>
(評価方法)
上記の処理を施した毛束を吊るした状態で、評価者が毛束の根元から毛先までを触って、毛髪のべたつき感を評価した。評価基準及びスコア基準は、以下のとおりである。
(評価基準)
5点:毛束の根元から毛先までべたつきがない。
4点:毛束の根元から毛先までややべたつきがない。
3点:毛束の中間から毛先のべたつきがない。
2点:毛束の一部がややべたついている。
1点:毛束全体がべたついている。
(スコア基準)
◎:大変優れている・・・4.5点以上
○:優れている・・・・・3点以上、4.5点未満
△:劣っている・・・・・1.5点以上、3点未満
×:大変劣っている・・・1.5点未満
<Evaluation 5: Absence of stickiness>
(Evaluation method)
An evaluator touched the tress from the root to the tip of the tress while the tress that had been subjected to the above treatment was hung to evaluate the stickiness of the hair. Evaluation criteria and score criteria are as follows.
(Evaluation criteria)
5 points: No stickiness from the root to the tip of the hair bundle.
4 points: Slightly non-sticky from the root to the tip of the hair bundle.
3 points: No stickiness from the middle to the tip of the hair bundle.
2 points: Part of the hair bundle is slightly sticky.
1 point: The entire hair bundle is sticky.
(Score criteria)
◎: Excellent: 4.5 points or more ○: Excellent: 3 points or more, less than 4.5 points △: Inferior: 1.5 points or more, 3 points Less than points ×: Very poor ... less than 1.5 points
実施例1~30及び比較例1~13
表1~7に示す組成の毛髪化粧料を常法に準じて調製し、毛束処理後の指通り、さらさら、べたつきのなさ、軽やかな髪のしなり、毛束の角度について評価を行い、その結果を表1~7に示した。
Examples 1-30 and Comparative Examples 1-13
Hair cosmetics having the compositions shown in Tables 1 to 7 were prepared according to a conventional method, and evaluated for finger combability, smoothness, non-stickiness, light bending of the hair, and angle of the hair bundle after treatment of the hair bundle. The results are shown in Tables 1-7.
表1~7から明らかなように、本発明の毛髪化粧料に関する実施例1~30は、比較例1~13の組成物に比べていずれも優れた性能を見出した。特に、本発明の第一剤と第二剤とを組み合わせて使用した場合には一剤又は二剤のいずれか一方を使用した場合と比較して特に毛束の角度評価が優れており、評価1~5のいずれについても良好な効果を実現できた。比較例12及び13は、それぞれ軽く仕上げるためにジメチコンを少量配合した現行品及びダメージケアのためにジメチコンを多量配合した現行品の例である。 As is clear from Tables 1 to 7, all of Examples 1 to 30 regarding the hair cosmetic of the present invention were found to have superior performance compared to the compositions of Comparative Examples 1 to 13. In particular, when the first agent and the second agent of the present invention are used in combination, the evaluation of the angle of the hair bundle is particularly excellent compared to the case where either one of the first agent or the second agent is used. Good effects could be realized for any of 1 to 5. Comparative Examples 12 and 13 are examples of a current product containing a small amount of dimethicone for light finish and a current product containing a large amount of dimethicone for damage care, respectively.
以下、本発明の毛髪化粧料のその他の実施例を処方例1~5として記載する。なお、これらの処方例の毛髪化粧料についても、上記の毛束処理後の指通り、さらさら、べたつきのなさ、軽やかな髪のしなり、毛束の角度の各項目について評価したところ、いずれの処方例においても優れた特性を有しており良好であった。 Other examples of the hair cosmetic composition of the present invention are described below as Formulation Examples 1 to 5. The hair cosmetics of these formulation examples were also evaluated in terms of finger combability, smoothness, non-stickiness, light bending of the hair, and angle of the hair bundle after the treatment of the hair bundle. The formulation examples were also good with excellent properties.
処方例1 ヘアシャンプー(pH:5.9 /粘度2300 mPa・s 白濁粘性液)
(1) コムラサキ果実抽出物 1.0%
(2) ラウロイルサルコシンTEA 10.0%
(3) ココイルグルタミン酸TEA 1.0%
(4) ラウロイルヒドロキシエチル-β-アラニンNa 1.0%
(5) ココイルトレオニンNa 1.0%
(6) ラウレス硫酸Na 1.0%
(7) コカミドプロピルベタイン 0.5%
(8) ラウリルベタイン 0.5%
(9) コカミドMEA
2.0%
(10)PPG-2コカミド 1.0%
(11)PPG-3カプリリルエーテル 1.0%
(12)ジステアリン酸グリコール 1.0%
(13)ジメチコン 1.0%
(14)PPG-12ジメチコン 2.0%
(15)ポリクオタニウム-10 0.2%
(16)グアーヒドロキシプロピルトリモニウムクロリド 0.1%
(17)ポリクオタニウム-7 0.2%
(18)ポリクオタニウム-49 0.2%
(19)塩化Na 0.1%
(20)EDTA-2Na 0.1%
(21)BG 1.0%
(22)ヒマワリ種子油 0.1%
(23)ヒマワリ種子エキス 0.1%
(24)ヒマワリ花エキス 0.1%
(25)ヒマワリ芽エキス 0.1%
(26)メントール 0.1%
(27)アセチルグルコサミン 0.1%
(28)ラクトフェリン 0.1%
(29)ヨーグルト液 0.1%
(30)グリチルリチン酸2K 0.1%
(31)トコフェロール 0.1%
(32)ラウロイルグルタミン酸ジ(フィトステリル/オクチルドデシル) 0.1%
(33)セバシン酸ジエチル 0.1%
(34)ラウリン酸 1.0%
(35)安息香酸Na 0.5%
(36)フェノキシエタノール 1.0%
(37)メチルパラベン 1.0%
(38)香料 1.0%
(39)カラメル 1.0%
(40)水 残余
Formulation example 1 Hair shampoo (pH: 5.9 / Viscosity 2300 mPa s cloudy viscous liquid)
(1) Komurasaki fruit extract 1.0%
(2) Lauroyl sarcosine TEA 10.0%
(3) Cocoyl glutamic acid TEA 1.0%
(4) Lauroyl hydroxyethyl-β-alanine Na 1.0%
(5) Cocoyl threonine Na 1.0%
(6) Sodium laureth sulfate 1.0%
(7) Cocamidopropyl Betaine 0.5%
(8) Lauryl betaine 0.5%
(9) Cocamide MEA
2.0%
(10) PPG-2 cocamide 1.0%
(11) PPG-3 caprylyl ether 1.0%
(12) Glycol distearate 1.0%
(13) Dimethicone 1.0%
(14) PPG-12 Dimethicone 2.0%
(15) Polyquaternium-10 0.2%
(16) Guar hydroxypropyltrimonium chloride 0.1%
(17) Polyquaternium-7 0.2%
(18) Polyquaternium-49 0.2%
(19) Na chloride 0.1%
(20) EDTA-2Na 0.1%
(21) BG 1.0%
(22) Sunflower seed oil 0.1%
(23) Sunflower seed extract 0.1%
(24) Sunflower flower extract 0.1%
(25) Sunflower sprout extract 0.1%
(26) Menthol 0.1%
(27) Acetylglucosamine 0.1%
(28) Lactoferrin 0.1%
(29) Yogurt liquid 0.1%
(30) Glycyrrhizic acid 2K 0.1%
(31) Tocopherol 0.1%
(32) Di(phytosteryl/octyldodecyl) lauroyl glutamate 0.1%
(33) Diethyl Sebacate 0.1%
(34) Lauric acid 1.0%
(35) Sodium Benzoate 0.5%
(36) Phenoxyethanol 1.0%
(37) Methylparaben 1.0%
(38) Perfume 1.0%
(39) Caramel 1.0%
(40) water remainder
(製法)(40)に(1)、(15)~(18)を50℃にて均一に混合溶解し、(2)~(12)、(19)を添加し70℃まで昇温し均一に混合する。徐々に冷却を行い、55℃にて(13)、(14)、(20)~(39)を添加し、室温まで冷却して、シャンプーを調製した。 (Manufacturing method) (1), (15) to (18) are uniformly mixed and dissolved in (40) at 50 ° C., (2) to (12), (19) are added, and the temperature is raised to 70 ° C. to homogenize. to mix. After cooling gradually, (13), (14), (20) to (39) were added at 55° C. and cooled to room temperature to prepare a shampoo.
処方例2 ヘアシャンプー(pH:4.2/粘度4000mPa・s 透明粘性液)
(1) コムラサキ果実抽出物 1.5%
(2) ラウロイルサルコシンTEA 2.0%
(3) ココイルメチルタウリンNa 3.0%
(4) ココイルグルタミン酸2Na 2.0%
(5) ココイルグルタミン酸Na 2.0%
(6) ココイルグルタミン酸TEA 2.0%
(7) パーム核脂肪酸アミドプロピルベタイン 2.0%
(8) ココベタイン 2.0%
(9) コカミドプロピルベタイン 5.0%
(10)コカミドMEA 1.0%
(11)ラウラミドMIPA 5.0%
(12)PPG-3カプリリル 0.5%
(13)シクロヘキサン-1,4-ジカルボン酸ビスエトキシジグリコール 3.0%
(14)ヤシ油脂肪酸PEG-7グリセリル 0.5%
(15)ポリクオタニウム-10 0.1%
(16)グアーヒドロキシプロピルトリモニウムクロリド 1.0%
(17)ポリクオタニウム-7 0.2%
(18)ポリクオタニウム-107 0.01%
(19)クエン酸 0.1%
(20)EDTA-2Na 0.1%
(21)グリセリン 1.0%
(22)コメヌカ油 0.001%
(23)コメエキス 0.1%
(24)カワラナデシコ種子エキス 0.1%
(25)ムクロジエキス 0.1%
(26)コメ胚芽油 0.1%
(27)ヒオウギエキス 0.1%
(28)ツバキ種子エキス 0.1%
(29)コメヌカエキス 0.1%
(30)アンズ核油 0.001%
(31)チャ花エキス 0.1%
(32)ダイズ種子エキス 0.1%
(33)ミリスチン酸 0.1%
(34)安息香酸Na 0.5%
(35)フェノキシエタノール 1.0%
(36)メチルパラベン 1.0%
(37)香料 0.01%
(38)カラメル 1.0%
(39)水 残余
Formulation example 2 Hair shampoo (pH: 4.2/viscosity 4000mPa s transparent viscous liquid)
(1) Komurasaki fruit extract 1.5%
(2) Lauroyl sarcosine TEA 2.0%
(3) Cocoyl methyl taurine Na 3.0%
(4) 2.0% cocoyl glutamic acid disodium
(5) Sodium cocoyl glutamate 2.0%
(6) Cocoyl glutamic acid TEA 2.0%
(7) Palm kernel fatty acid amidopropyl betaine 2.0%
(8) Cocobetaine 2.0%
(9) Cocamidopropyl Betaine 5.0%
(10) Cocamide MEA 1.0%
(11) Lauramide MIPA 5.0%
(12) PPG-3 caprylyl 0.5%
(13) Cyclohexane-1,4-dicarboxylic acid bisethoxydiglycol 3.0%
(14) Coconut oil fatty acid PEG-7 glyceryl 0.5%
(15) Polyquaternium-10 0.1%
(16) Guar hydroxypropyltrimonium chloride 1.0%
(17) Polyquaternium-7 0.2%
(18) Polyquaternium-107 0.01%
(19) Citric acid 0.1%
(20) EDTA-2Na 0.1%
(21) Glycerin 1.0%
(22) Rice bran oil 0.001%
(23) Rice extract 0.1%
(24) Kawara dianthus seed extract 0.1%
(25) Sapindactyl extract 0.1%
(26) Rice germ oil 0.1%
(27) Blackberry Extract 0.1%
(28) Camellia seed extract 0.1%
(29) Rice bran extract 0.1%
(30) Apricot kernel oil 0.001%
(31) Tea flower extract 0.1%
(32) Soybean seed extract 0.1%
(33) Myristic acid 0.1%
(34) Sodium benzoate 0.5%
(35) Phenoxyethanol 1.0%
(36) Methylparaben 1.0%
(37) Perfume 0.01%
(38) Caramel 1.0%
(39) water residue
(製法)(39)に(1)、(15)~(18)を50℃にて均一に混合溶解し、(2)~(14)を添加し70℃まで昇温し均一に混合する。徐々に冷却を行い、55℃にて(19)~(38)を添加し、室温まで冷却して、シャンプーを調製した。 (Manufacturing method) (1), (15) to (18) are uniformly mixed and dissolved in (39) at 50°C, (2) to (14) are added, the temperature is raised to 70°C, and the mixture is uniformly mixed. After cooling gradually, (19) to (38) were added at 55° C. and cooled to room temperature to prepare a shampoo.
処方例3 ヘアシャンプー(pH:5.1 粘度 600 mPa・s 白濁粘性液)
(1) コムラサキ果実抽出物 2.0%
(2) ラウロイルサルコシンTEA 1.0%
(3) ラウレス硫酸Na 1.0%
(4) ラウリル硫酸Na 1.0%
(5) ココイルグルタミン酸TEA 1.0%
(6) ラウロイルメチルアラニンNa 1.0%
(7) ラウラミドプロピルベタイン 2.0%
(8) ジステアリン酸グリコール 2.0%
(9) セテアレス-60ミリスチルグリコール 1
.0%
(10)コカミドメチルMEA 1.0%
(11)ヤシ油脂肪酸PEG-7グリセリル 1.0%
(12)ジメチルポリシロキサン 2.0%
(13)アモジメチコン 5.0%
(14)(ジビニルジメチコン/ジメチコン)コポリマー 0.1%
(15)ポリクオタニウム-10 1.0%
(16)グアーヒドロキシプロピルトリモニウムクロリド 0.5%
(17)ポリクオタニウム-7 0.1%
(18)ポリクオタニウム-51 0.01%
(19)クエン酸Na 0.1%
(20)EDTA-2Na 0.1%
(21)ソルビトール 1.0%
(22)紅藻エキス 0.1%
(23)褐藻エキス 0.1%
(24)緑藻エキス 0.1%
(25)加水分解スサビノリ 0.1%
(26)海水 0.1%
(27)加水分解コラーゲン 0.1%
(28)水溶性コラーゲン 0.1%
(29)セリン
0.1%
(30)プロリン 0.1%
(31)グルタミン酸Na 0.1%
(32)アルギニン 0.1%
(33)アラニン 0.1%
(34)パルミチン酸 3.0%
(35)安息香酸Na 0.5%
(36)フェノキシエタノール
1.0%
(37)メチルパラベン 1.0%
(38)香料 1.0%
(39)カラメル 1.0%
(40)水 残余
Formulation example 3 Hair shampoo (pH: 5.1 viscosity 600 mPa s cloudy viscous liquid)
(1) Komurasaki fruit extract 2.0%
(2) Lauroyl sarcosine TEA 1.0%
(3) Sodium laureth sulfate 1.0%
(4) Sodium lauryl sulfate 1.0%
(5) Cocoyl glutamic acid TEA 1.0%
(6) Lauroylmethylalanine Na 1.0%
(7) Lauramidopropyl Betaine 2.0%
(8) Glycol distearate 2.0%
(9) Ceteareth-60 Myristyl Glycol 1
.0%
(10) Cocamidomethyl MEA 1.0%
(11) Coconut oil fatty acid PEG-7 glyceryl 1.0%
(12) Dimethylpolysiloxane 2.0%
(13) Amodimethicone 5.0%
(14) (divinyl dimethicone/dimethicone) copolymer 0.1%
(15) Polyquaternium-10 1.0%
(16) Guar hydroxypropyltrimonium chloride 0.5%
(17) Polyquaternium-7 0.1%
(18) Polyquaternium-51 0.01%
(19) Na citrate 0.1%
(20) EDTA-2Na 0.1%
(21) Sorbitol 1.0%
(22) Red algae extract 0.1%
(23) brown algae extract 0.1%
(24) Green algae extract 0.1%
(25) Hydrolyzed Sasabinori 0.1%
(26) Seawater 0.1%
(27) Hydrolyzed collagen 0.1%
(28) Water-soluble collagen 0.1%
(29) Serine
0.1%
(30) Proline 0.1%
(31) Sodium glutamate 0.1%
(32) Arginine 0.1%
(33) Alanine 0.1%
(34) Palmitic acid 3.0%
(35) Sodium Benzoate 0.5%
(36) Phenoxyethanol
1.0%
(37) Methylparaben 1.0%
(38) Perfume 1.0%
(39) Caramel 1.0%
(40) water remainder
(製法)(40)に(1)、(15)~(18)を50℃にて均一に混合溶解し、(2)~(11)を添加し70℃まで昇温し均一に混合する。徐々に冷却を行い、55℃にて(12)~(14)、(19)~(39)を添加し、室温まで冷却して、シャンプーを調製した。 (Manufacturing method) (1), (15) to (18) are uniformly mixed and dissolved in (40) at 50°C, (2) to (11) are added, the temperature is raised to 70°C, and the mixture is uniformly mixed. After cooling gradually, (12) to (14) and (19) to (39) were added at 55° C. and cooled to room temperature to prepare a shampoo.
処方例4 コンディショナー(pH:6.2 粘度 8000 mPa・s クリーム状)
(1) コムラサキ果実抽出物 3.0%
(2) セタノール 3.0%
(3) セテアリルアルコール 2.0%
(4) ステアリルアルコール 1.0%
(5) ベヘニルアルコール 1.0%
(6) ベヘナミドプロピルジメチルアミン 1.5%
(7) PPG-1/PEG-1ステアラミン 1.5%
(8) ステアルトリモニウムクロリド 1.0%
(9) ベヘニルPGトリモニウムクロリド 1.0%
(10)ステアロキシプロピルトリモニウムクロリド 0.7%
(11)高重合メチルポリシロキサン 0.2%
(12)メチルポリシロキサン 5.0%
(13)アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体
1.0%
(14)フェニルトリメチコン 0.1%
(15)(ビスイソブチルPEG-14/アモジメチコン)コポリマー 0.1%
(16)グリセリン 1.0%
(17)ミリスチン酸オクチルドデシル 5.0%
(18)グリコシルトレハロース 2.0%
(19)ヒドロキシエチルセルロース 0.5%
(20)ヒドロキシプロピルデンプンリン酸 0.2%
(21)パラフィン 1.0%
(22)ワセリン 1.0%
(23)ビスジグリセリルポリアシルアジペート-2 2.0%
(24)乳酸 0.1%
(25)クエン酸 0.1%
(26)コメヌカ油 0.1%
(27)アンズ核油 0.1%
(28)チャ花エキス 0.1%
(29)クルミ種子油 0.1%
(30)コメ胚芽油 0.1%
(31)ヒオウギエキス 0.1%
(32)ツバキ種子エキス 0.1%
(33)コメヌカエキス 0.1%
(34)トコフェロール 0.1%
(35)安息香酸Na 0.5%
(36)フェノキシエタノール 1.0%
(37)メチルパラベン 1.0%
(38)香料 1.0%
(39)カラメル 1.0%
(40)水 残余
(製法)80℃にて(2)~(5)を溶解させたものに(1)、(6)~(10)、(24)を加温しながら均一に分散して添加して、乳化を行う。徐々に冷却を行い、60℃にて(11)~(23)、(25)~(40)を添加し、室温まで冷却して、ヘアコンディショナーを調製した。
Formulation example 4 Conditioner (pH: 6.2 viscosity 8000 mPa s cream)
(1) Komurasaki fruit extract 3.0%
(2) Cetanol 3.0%
(3) Cetearyl alcohol 2.0%
(4) Stearyl alcohol 1.0%
(5) Behenyl alcohol 1.0%
(6) Behenamidopropyldimethylamine 1.5%
(7) PPG-1/PEG-1 stearamine 1.5%
(8) Steartrimonium chloride 1.0%
(9) Behenyl PG trimonium chloride 1.0%
(10) stearoxypropyltrimonium chloride 0.7%
(11) Highly polymerized methylpolysiloxane 0.2%
(12) Methylpolysiloxane 5.0%
(13) Aminoethylaminopropylmethylsiloxane/dimethylsiloxane copolymer
1.0%
(14) Phenyltrimethicone 0.1%
(15) (bisisobutyl PEG-14/amodimethicone) copolymer 0.1%
(16) Glycerin 1.0%
(17) Octyldodecyl myristate 5.0%
(18) Glycosyltrehalose 2.0%
(19) Hydroxyethyl cellulose 0.5%
(20) Hydroxypropyl starch phosphate 0.2%
(21) Paraffin 1.0%
(22) Vaseline 1.0%
(23) Bisdiglyceryl polyacyladipate-2 2.0%
(24) Lactic acid 0.1%
(25) Citric acid 0.1%
(26) Rice bran oil 0.1%
(27) Apricot kernel oil 0.1%
(28) Tea flower extract 0.1%
(29) Walnut seed oil 0.1%
(30) Rice germ oil 0.1%
(31) Blackberry Extract 0.1%
(32) Camellia seed extract 0.1%
(33) Rice bran extract 0.1%
(34) Tocopherol 0.1%
(35) Sodium Benzoate 0.5%
(36) Phenoxyethanol 1.0%
(37) Methylparaben 1.0%
(38) Perfume 1.0%
(39) Caramel 1.0%
(40) Water Remainder (manufacturing method) Dissolve (1), (6) to (10), and (24) in a solution of (2) to (5) at 80°C while heating and uniformly disperse. Add and emulsify. After cooling gradually, (11) to (23) and (25) to (40) were added at 60° C. and cooled to room temperature to prepare a hair conditioner.
処方例5 トリートメント(pH:5.1 粘度 40000 mPa・s クリーム状)
(1) コムラサキ果実抽出物 5.0%
(2) セテアリルアルコール 1.3%
(3) ステアリルアルコール 2.5%
(4) ベヘニルアルコール 5.0%
(5) PPG-1/PEG-1ステアラミン 0.5%
(6) ベヘントリモニウムクロリド 1.0%
(7) ベヘントリモニウムブロミド 1.0%
(8) ベヘントリモニウムメトサルフェート 1.0%
(9) ステアルトリモニウムクロリド 0.5%
(10)セトリモニウムクロリド 0.3%
(11)ベヘナミドプロピルジメチルアミン 1.3%
(12)高重合メチルポリシロキサン・メチルポリシロキサン 混合エマルション 5.0%
(13)ジメチコノール 1.0%
(14)(ジビニルジメチコン/ジメチコン)コポリマー エマルション 1.0%
(15)(PEG-40/PPG-8メチルアミノプロピル/ヒドロキシプロピルジメチコン)コポリマー 1.0%
(16)ヒドロキシエチルセルロース 0.2%
(17)ヒドロキシプロピルデンプンリン酸 3.0%
(18)セバチン酸ジエチル 5.0%
(19)ワセリン 0.5%
(20)水添ポリイソブテン 1.0%
(21)乳酸 1.0%
(22)クエン酸 1.2%
(23)加水分解水添デンプン 0.5%
(24)ヒマワリ種子油 0.1%
(25)ヒマワリ葉/茎エキス 0.1%
(26)ヒマワリ種子エキス 0.1%
(27)ヒマワリ花エキス 0.1%
(28)ヒマワリ芽エキス 0.1%
(29)ミツロウ 0.1%
(30)ネオペンタン酸イソデシル 0.1%
(31)ハチミツ 0.1%
(32)ポリクオタニウム-107 0.1%
(33)ラクトフェリン 0.1%
(34)ヨーグルト液 0.1%
(35)安息香酸Na 0.5%
(36)フェノキシエタノール
1.0%
(37)メチルパラベン 1.0%
(38)香料 1.0%
(39)カラメル 1.0%
(40)水 残余
(製法)(40)に(1)、(16)、(32)を70℃にて均一に混合溶解し水相とする。(2)~(15)、(18)、(19)、(21)、(22)を80℃にて均一に混合攪拌し油相とする。水相に油相を加えて乳化したのち、(17)、(20)、(23)
~(31)、(33)~(39)を加えて、ホモミキサーを用いて均一に混合する。混合しながら徐々に冷却を行い、室温まで冷却してヘアトリートメントを調製した。
Formulation example 5 Treatment (pH: 5.1 viscosity 40000 mPa s cream)
(1) Komurasaki fruit extract 5.0%
(2) Cetearyl alcohol 1.3%
(3) Stearyl alcohol 2.5%
(4) Behenyl alcohol 5.0%
(5) PPG-1/PEG-1 stearamine 0.5%
(6) Behentrimonium chloride 1.0%
(7) Behentrimonium bromide 1.0%
(8) Behentrimonium methosulfate 1.0%
(9) Steartrimonium chloride 0.5%
(10) Cetrimonium chloride 0.3%
(11) Behenamidopropyldimethylamine 1.3%
(12) Highly polymerized methylpolysiloxane/methylpolysiloxane mixed emulsion 5.0%
(13) Dimethiconol 1.0%
(14) (divinyl dimethicone/dimethicone) copolymer emulsion 1.0%
(15) (PEG-40/PPG-8 methylaminopropyl/hydroxypropyl dimethicone) copolymer 1.0%
(16) Hydroxyethyl cellulose 0.2%
(17) Hydroxypropyl starch phosphate 3.0%
(18) Diethyl Sebacate 5.0%
(19) Vaseline 0.5%
(20) Hydrogenated polyisobutene 1.0%
(21) Lactic acid 1.0%
(22) Citric acid 1.2%
(23) Hydrolyzed hydrogenated starch 0.5%
(24) Sunflower seed oil 0.1%
(25) Sunflower leaf/stem extract 0.1%
(26) Sunflower seed extract 0.1%
(27) Sunflower flower extract 0.1%
(28) Sunflower sprout extract 0.1%
(29) Beeswax 0.1%
(30) isodecyl neopentanoate 0.1%
(31) Honey 0.1%
(32) Polyquaternium-107 0.1%
(33) Lactoferrin 0.1%
(34) Yogurt liquid 0.1%
(35) Sodium Benzoate 0.5%
(36) Phenoxyethanol
1.0%
(37) Methylparaben 1.0%
(38) Perfume 1.0%
(39) Caramel 1.0%
(40) Water The remainder (manufacturing method) (1), (16) and (32) are uniformly mixed and dissolved in (40) at 70°C to form an aqueous phase. (2) to (15), (18), (19), (21) and (22) are uniformly mixed and stirred at 80° C. to form an oil phase. After emulsifying by adding the oil phase to the water phase, (17), (20), (23)
~ (31), (33) ~ (39) are added and uniformly mixed using a homomixer. Cooling was carried out gradually while mixing, and the hair treatment was prepared by cooling to room temperature.
処方例6 ヘアマスク(pH:3.8 粘度 82000 mPa・s クリーム状)
(1) コムラサキ果実抽出物 10.0%
(2) セタノール 3.0%
(3) ステアリルアルコール 3.0%
(4) ベヘニルアルコール 3.0%
(5) セトリモニウムクロリド 1.5%
(6) ベヘナミドプロピルジメチルアミン 1.0%
(7) PPG-1/PEG-1ステアラミン 1.0%
(8) ステアルトリモニウムクロリド 0.5%
(9) ベヘニルPGトリモニウムクロリド 0.5%
(10)ステアロキシプロピルトリモニウムクロリド 0.5%
(11)セバチン酸ジエチル 1.0%
(12)ミリスチン酸オクチルドデシル 0.3%
(13)水添ポリイソブテン 0.2%
(14)イソドデカン 1.0%
(15)ビスジグリセリルポリアシルアジペート-2 1.0%
(16)ワセリン 0.5%
(17)ヒマワリ種子油脂肪酸フィトステリル
1.0%
(18)ダイマージリノール酸(フィトステリル/イソステアリル/セチル/ステアリル/ベヘニル) 0.5%
(19)(ヒドロキシステアリン酸/ステアリン酸/ロジン酸)ジペンタエリスリチル 0.1%
(20)プロリン 0.1%
(21)グルタミン酸Na 0.1%
(22)アルギニン 0.1%
(23)アラニン 0.1%
(24)ラウロイルグルタミン酸ジ(フィトステリル/オクチルドデシル) 0.2%
(25)セバシン酸ジエチル 0.2%
(26)紅藻エキス 0.2%
(27)褐藻エキス 0.2%
(28)緑藻エキス 0.2%
(29)加水分解スサビノリ 0.2%
(30)海水 0.2%
(31)アロエベラ葉エキス 0.1%
(32)グリコシルトレハロース 0.1%
(33)アセチルグルコサミン 0.1%
(34)ブドウ種子油 0.1%
(35)
(36)フェノキシエタノール 1.0%
(37)メチルパラベン 1.0%
(38)香料 1.0%
(39)カラメル 1.0%
(40)水 残余
Formulation example 6 Hair mask (pH: 3.8 viscosity 82000 mPa s cream)
(1) Komurasaki fruit extract 10.0%
(2) Cetanol 3.0%
(3) Stearyl alcohol 3.0%
(4) Behenyl alcohol 3.0%
(5) Cetrimonium chloride 1.5%
(6) Behenamidopropyldimethylamine 1.0%
(7) PPG-1/PEG-1 stearamine 1.0%
(8) Steartrimonium chloride 0.5%
(9) Behenyl PG trimonium chloride 0.5%
(10) stearoxypropyltrimonium chloride 0.5%
(11) Diethyl Sebacate 1.0%
(12) Octyldodecyl myristate 0.3%
(13) Hydrogenated polyisobutene 0.2%
(14) Isododecane 1.0%
(15) Bisdiglyceryl polyacyladipate-2 1.0%
(16) Vaseline 0.5%
(17) Sunflower seed oil fatty acid phytosteryl
1.0%
(18) Dimer dilinoleic acid (phytosteryl/isostearyl/cetyl/stearyl/behenyl) 0.5%
(19) (hydroxystearic acid/stearic acid/rosin acid) dipentaerythrityl 0.1%
(20) Proline 0.1%
(21) Sodium glutamate 0.1%
(22) Arginine 0.1%
(23) Alanine 0.1%
(24) Di(phytosteryl/octyldodecyl) lauroyl glutamate 0.2%
(25) Diethyl Sebacate 0.2%
(26) Red algae extract 0.2%
(27) brown algae extract 0.2%
(28) Green algae extract 0.2%
(29) Hydrolyzed Sasabinori 0.2%
(30) Seawater 0.2%
(31) Aloe vera leaf extract 0.1%
(32) Glycosyltrehalose 0.1%
(33) Acetylglucosamine 0.1%
(34) Grape seed oil 0.1%
(35)
(36) Phenoxyethanol 1.0%
(37) Methylparaben 1.0%
(38) Perfume 1.0%
(39) Caramel 1.0%
(40) water remainder
(製法)(40)に(1)、(8)~(10)を70℃にて均一に混合溶解し水相とする。(2)~(7)、(21)を80℃にて均一に混合攪拌し油相とする。水相に油相を加えて乳化したのち、(11)~(20)、(22)~(39)を加えて、ホモミキサーを用いて均一に混合する。混合しながら徐々に冷却を行い、室温まで冷却してヘアトリートメントを調製した。
(Manufacturing method) (1) and (8) to (10) are uniformly mixed and dissolved in (40) at 70°C to form an aqueous phase. (2) to (7) and (21) are uniformly mixed and stirred at 80° C. to form an oil phase. After the oil phase is added to the water phase and emulsified, (11) to (20) and (22) to (39) are added and uniformly mixed using a homomixer. Cooling was carried out gradually while mixing, and the hair treatment was prepared by cooling to room temperature.
Claims (7)
当該毛髪化粧料は(A)ムラサキシキブ属コムラサキ抽出物及び(B-1)カチオン化多糖類を含有するか、又は
(A)ムラサキシキブ属コムラサキ抽出物及び(B-2)カチオン性界面活性剤を含有する
ことを特徴とする毛髪の動き改善のための毛髪化粧料。 It is a one- part type hair cosmetic,
The hair cosmetic composition contains (A) an extract of the genus Violet purpurea and (B-1) a cationized polysaccharide, or
A hair cosmetic for improving the movement of hair, characterized by containing (A) an extract of the genus Pleurotus purpurea and (B-2) a cationic surfactant.
前記(B-1)カチオン化多糖類の配合量は、前記毛髪化粧料の質量に対して0.001質量%~10質量%、
前記(B-2)カチオン性界面活性剤の配合量は、前記毛髪化粧料の質量に対して0.001質量%~10質量%
である請求項1に記載の毛髪化粧料。 The blending amount of the (A) Pleurotus purpurea extract is 0.001% by mass to 20% by mass with respect to the mass of the hair cosmetic ,
The content of the (B-1) cationized polysaccharide is 0.001% by mass to 10% by mass with respect to the mass of the hair cosmetic ,
The content of the cationic surfactant (B-2) is 0.001% by mass to 10% by mass with respect to the mass of the hair cosmetic.
The hair cosmetic according to claim 1.
前記第一剤は(A)ムラサキシキブ属コムラサキ抽出物及び(B-1)カチオン化多糖類を含有し、
前記第二剤は(A)ムラサキシキブ属コムラサキ抽出物及び(B-2)カチオン性界面活性剤を含有する
ことを特徴とする毛髪の動き改善のための毛髪化粧料。 A two-agent hair cosmetic that uses both the first agent and the second agent,
The first agent contains (A) an extract of the genus Pleurotus purpurea and (B-1) a cationized polysaccharide,
A hair cosmetic composition for improving the movement of hair, wherein the second agent contains (A) an extract of the genus Pleurotus purpurea and (B-2) a cationic surfactant.
前記(B-1)カチオン化多糖類の配合量は、前記第一剤の質量に対して0.001質量%~10質量%、
前記(B-2)カチオン性界面活性剤の配合量は、前記第二剤の質量に対して0.001質量%~10質量%
である請求項3に記載の毛髪化粧料。 The blending amount of the (A) Pleurotus purpurea extract is 0.001% by mass to 20% by mass with respect to the mass of each of the first agent and the second agent,
The amount of the cationized polysaccharide (B-1) is 0.001% by mass to 10% by mass with respect to the mass of the first agent,
The content of the cationic surfactant (B-2) is 0.001% by mass to 10% by mass with respect to the mass of the second agent.
The hair cosmetic according to claim 3.
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JP2017007984A (en) | 2015-06-24 | 2017-01-12 | 一丸ファルコス株式会社 | Skin cleansing agent which improves resident skin bacteria balance |
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