CN105581917B - Increase the tensile strength of keratin fiber, particularly hair and ductile cosmetic composition - Google Patents
Increase the tensile strength of keratin fiber, particularly hair and ductile cosmetic composition Download PDFInfo
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- CN105581917B CN105581917B CN201610098318.7A CN201610098318A CN105581917B CN 105581917 B CN105581917 B CN 105581917B CN 201610098318 A CN201610098318 A CN 201610098318A CN 105581917 B CN105581917 B CN 105581917B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4953—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom containing pyrimidine ring derivatives, e.g. minoxidil
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/673—Vitamin B group
- A61K8/675—Vitamin B3 or vitamin B3 active, e.g. nicotinamide, nicotinic acid, nicotinyl aldehyde
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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Abstract
The present invention relates to keratin fiber, particularly the nursing cosmetic composition of hair, said composition can increase tensile strength and the extension property of keratin fiber.Concrete, the keratin fiber care composition of the present invention contains baicalin, caffeine, agedoite and nicotiamide.Said composition obtains the excellent tensile strength of keratin fiber and extension property effect by the synergism of baicalin, caffeine, agedoite and nicotiamide.
Description
Technical field
The present invention relates to keratin fiber, particularly the care composition of hair.Concrete, the present invention's
Care composition contains baicalin, caffeine, agedoite and nicotiamide.This care composition is by Huang
The tension that the synergism of a kind of reed mentioned in ancient books element, caffeine, agedoite and nicotiamide improves keratin fiber is slight
And extensibility.
Background technology
Hair be a kind of be made up of the horn cell of keratinization, baroque natural polymer subbundle.Cutin is thin
Primary structure in born of the same parents is fusiform keratinous fibers, there is substrate, residual cells core that quantity does not waits therebetween
And melanin granule.Keratinous fibers is successively made up of complicated keratin network.Angle egg in hair fiber
There is crystal region and amorphous region in vain, crystalline portion accounts for the ratio of whole fiber and is referred to as degree of crystallinity.Hair fiber
Internal macromolecular chain main shaft is referred to as the degree of orientation with the parallel degree of fiber axis.Degree of crystallinity and the degree of orientation can characterize
The quantity of regular regional and the height of order degree in hair fiber.Many character of macromolecular fibre are (such as mechanics
Character) depend greatly on high molecular coherent condition and the strand company between each construction unit
Connect mode.
Hair can be adversely affected by several factors, such as environment (light, heat etc.), chemical substance
(have hair dyed, hair-waving etc.) etc. all can affect the health of hair.
The damage of hair is according to causing its extraneous factor difference changed can be roughly divided into following several types:
Physical damnification refers to apply the damage that external force is brought to hair.Cause one of them external force of hair damage
It is comb brings during combing hair tensile force and the frictional force that comb causes.When hair surface is coarse
And when being difficult to combing, this damage the most easily occurs.Close stripping fork, metal and plastic comb are likely to increase combing
The chance of damage.When carrying out reverse combing against the scale coverage direction of hair cuticle, the tilting of hair cuticle so that
It is easiest to occur in peeling.When additionally also having haircut shears and blunt cut the power of cutting, extraneous various to hair
Frictional force.
The damage that chemical damage refers to cause the structure component-keratic structure of hair to change and causes
Wound, is mainly caused by the various chemical reactions in hair.These chemical reactions include in life various
The keratin structure of hair is destroyed by agent for permanent hair waving, hair dye, bleach and hair straighten.They are all little from hair
Skin penetrates into cortical layer structure and various effect occurs.Hair-waving and straight hair process are that reducing substances is first by angle
Disulfide bond in albumen destroys, is more again combined in new position by oxidant.Hair dyeing is to pass through oxygen
Changing dyestuff occurs oxidation polymerization effect formation macromolecule pigment to complete dyeing course inside hair.Decolouring is then
It is that the melanin material utilizing bleach to come in oxidation hair is bleached to the decolouring realizing hair.These chemistry are made
Form structure with the inside destroying hair without exception, hair is caused inevitable damage.
Hot injury refers to that temperature is too high and causes the damage of hair during using hair dryer or hair-waving.High temperature
The moisture evaporation in hair can be made, cause the withered fragility of hair fiber, add stretching or the friction of external force
Act on and easily make hairs break.
Ultraviolet in daylight irradiates accumulation and reaches some strength, can cause change and the protein of hair structure
Light degradation phenomenon.Melanin in hair fiber is oxidizable and discolouration phenomena occurs by dayligth effect, and
And tryptophan, cystine and the tyrosine in keratin structure also can occur light degradation.It addition, hair all day
Being exposed in external environment, hair all can be caused damage by various climatic phenomenons, accelerates the aging of hair.
Hair damage mainly to show as feel poor, hair surface is coarse, jaundice and lackluster, elastic becomes
Difference, stretching easily broken etc., particularly hair shows significantly after impaired in tensile strength and extensibility
Difference.The most existing technology exist multiple to improve hair tensile strength and ductile nursing technique.
CN1077371A discloses the cosmetic composition containing polyoxyethylene groups vitamin E, and its consumption is
0.01-50%, when on skin and hair, they can resist harmful active oxygen, shows moisturizing energy
Power, increases the tensile strength of hair, and 2, 2-Oxydiphenol given birth to by the polyoxyethylene (18) in consumption 4-5% scope can be bright
The aobvious tensile strength increasing hair, but the polyoxyethylene of 4-5% (18) fertility 2, 2-Oxydiphenol large usage quantity, for
For supplier, there is the immense pressure on cost.
CN102406587A discloses bactericidal shampoo prescription and forms: deep-sea mineral salt 10%, Flos Rosae Rugosae
Quintessence oil 3%, Oleum Curcumae 3%, Oleum Eucalypti 1%, Radix Ginseng extract 4%, Fructus Forsythiae extract 3%, Radix Scutellariae
Extract 3%, Fructus Cnidii 3%, Radix Polygoni Multiflori 4%, Fructus Lycii 2%, Semen Sesami Nigrum 1%, Radix Sophorae Flavescentis 5%,
Flos Lonicerae 4%, Ganoderma 3%, Flos Chrysanthemi 3%, Radix Glycyrrhizae 2%, Semen Ginkgo 1%, Fructus Mori 2%, Folium Nelumbinis 1%.
There is cleaning, health care, sterilization, easy to use, it is possible to effectively to kill hair top layer antibacterial, nourish control oil,
Improve hair quality, make the most tough and tensile resilient feature of hair quality.But owing to becoming containing more Chinese medicine extraction
Point, formula outward appearance and less stable, Consumer acceptance is less, and improves tensile strength and extensibility
Scarce capacity.
CN104434734A discloses kangaroo oil and repairs shampoo, magnificent, oily containing kangaroo olein in said composition
Acid, pine nut extract, plant foaming agent, citric acid and nicotiamide, said composition can increase the tough of hair
Property and intensity, but the important component kangaroo olein Huawei in said composition carrys out the material of animal origin, makes
Use and needed to limit, and for the lifting effect of hair strength inconspicuous.
" Beijing traditional Chinese medical science " phase calendar year 2001 the 2nd, Huang Feili " Chinese medicine application in modern cosmetics " points out,
The extract of Chinese medicine ingredients, such as Radix Ginseng can expanded head blood capillary, blood circulation promoting, increase head
Send out nutrition, improve tensile strength and the extensibility of hair.But further study show that, Radix Ginseng extract is only
Having can obtain under enough consumptions and effectively promote effect, this has cost for supplier
On immense pressure.
Therefore need nonetheless remain for finding and a kind of have stable compositions, said composition can easily be prepared and improve
The tensile strength of hair and ductile effect.
CN101511331A discloses a kind of hair that enables to and looks denser that and abundanter hair protects
Reason compositions, said composition contains caffeine, nicotiamide and pantothenylol etc., and it is straight that said composition can increase hair shaft
Footpath is so that hair looks the densest abundant, but the document is not disclosed its tensile strength for hair
With the effect in terms of extensibility.
W02014095289A2 discloses the care composition containing materials such as baicalins, and said composition can be prevented
Only hair is aging, but the document is not disclosed it for the effect in terms of the tensile strength of hair and extensibility.
JP2014012645A discloses containing esculetin (esculetin), Quercetin (quercetin),
With the care composition of baicalin, said composition is prevented from the aging of hair, but the document is not disclosed it
For the effect in terms of the tensile strength of hair and extensibility.
CN104257596A discloses the gentle control salted cake fried in sesame oil ripple with refrigerant sense, and this shampoo contains nicotiamide, ferment
Female extract, Aesculus hippocastanum L. extract, caffeine etc., but the document is not disclosed it to be resisted for hair
Effect in terms of tensile strength and extensibility.
Applicant is found surprisingly that, be used in conjunction with Radix Scutellariae extract (baicalin), caffeine, agedoite and
Nicotiamide is obtained in that the hair tensile strength of excellence and ductile raising, and said composition is easily to join
System.Find based on this, complete the present invention.
Summary of the invention
The present invention relates to the care composition of a kind of keratin fiber particularly hair, wherein, total with compositions
Weight, described compositions contains:
0.1%-10.0% baicalin, preferably 0.5%-5.0%, more preferably 1.0%-2.0%；
0.1%-10.0% caffeine, preferably 0.5%-5.0%, more preferably 1.0%-2.0%；
0.1%-10.0% agedoite, preferably 0.5%-5.0%, more preferably 1.0%-2.0%；
0.1%-10.0% nicotiamide, preferably 0.5%-5.0%, more preferably 1.0%-2.0%；
And physiology's acceptable carrier.
Described care composition, it is shampoo, hair conditioner, ointment, sends out film.
Further, the present invention relates to the care composition of a kind of conditioning keratin fibers, particularly hair,
Wherein, with composition total weight, described compositions contains:
0.5-50.0% foaming surfactant, preferably 5.0-30.0%, more preferably 10.0-20.0%；
0.05-5.0% thickening agent, preferably 0.1-1%, more preferably 0.5%；
0.05-10.0% conditioner, preferably 0.1-5.0%, more preferably 0.5-2%；
0.1%-10.0% baicalin, preferably 0.5%-5.0%, more preferably 1.0%-2.0%；
0.1%-10.0% caffeine, preferably 0.5%-5.0%, more preferably 1.0%-2.0%；
0.1%-10.0% agedoite, preferably 0.5%-5.0%, more preferably 1.0%-2.0%；
0.1%-10.0% nicotiamide, preferably 0.5%-5.0%, more preferably 1.0%-2.0%；
And the acceptable aqueous carrier of physiology.
Further, the present invention relates to described care composition and preparing keratin fiber, particularly hair
Purposes in care composition, the tension that described compositions can improve keratin fiber, particularly hair is strong
Degree and extension property.
According to the care composition of the present invention, wherein foaming surfactant selected from anion surfactant,
Cationic surfactant, nonionic surfactant and/or amphoteric surfactant or a combination thereof.
Further, the present invention relates to hair care composition, with composition total weight, described compositions contains
Have:
5.0-20.0% anion surfactant；
0.3-5.0% amphoteric surfactant；
0.5-5.0% nonionic surfactant；
0.1-3.0% cationic surfactant；
0.05-5.0% thickening agent；
0.05-10.0% conditioner；
0.1%-10.0% baicalin；
0.1%-10.0% caffeine；
0.1%-10.0% agedoite；
0.1%-10.0% nicotiamide；
And the acceptable aqueous carrier of physiology.
In a special embodiment, described hair care composition, with composition total weight, described
Compositions contains:
5.0-20.0% anion surfactant；
0.3-5.0% amphoteric surfactant；
0.5-5.0% nonionic surfactant；
0.05-5.0% carbomer；
0.05-10.0% guar hydroxypropyltrimonium chloride；
0.05-5.0% polyquaternary ammonium salt；
0.00-5.0% polysiloxanes；
0.00-5.0% pearling agent；
0-5.0% sodium chloride；
0.01-1.0% chelating agen；
0.01-1.0%pH regulator；
0.00-3.0% essence；
0.0001-1.0% preservative；
0.1%-10.0% baicalin；
0.1%-10.0% caffeine；
0.1%-10.0% agedoite；
0.1%-10.0% nicotiamide.
Further, according to the hair care composition of the present invention, it contains 0.1-10% alkyl further and changes
Property siloxanes, preferably 0.5-5%, more preferably 1.0-2.0%.Described alkyl modified siloxane includes C20-C24
Siloxanes.
Lathering surfactant component
The Wo 2008069000 of the present invention contains lathering surfactant component, and it includes that one or more are cloudy
Ionic surface active agent, amphoteric surfactant or anion and the combination of zwitterionic surfactant.
The anionic detergent being applicable to the present invention includes alkyl sulfate and alkyl ether sulfate.It is applicable to this
The particular instance of the alkyl ether sulfate of invention is coconut alkyl sodium sulfate and ammonium salt；Adeps Bovis seu Bubali alkane
Base triethylene glycol ether sodium sulfate and ammonium salt, and tallow alkyl six ethylene oxide sodium sulfate and ammonium salt.The most excellent
The alkyl ether sulfate of choosing is the salt of those mixture comprising each compound.
Another kind of anionic detersive surfactant is soluble in the example of the anionic detersive surfactant of water
It is eterified with isethionic the product of the fatty acid with sodium hydroxide neutralization, wherein, such as, this fat
Fat acid is derived by Oleum Cocois or Palmic acid；The sodium salt of the fatty acid amide of methyl tauride or potassium
Salt, wherein said fatty acid is e.g. derived by Oleum Cocois or Palmic acid.
Other anionic detersive surfactant being applicable to the present invention is succinamic acid salt.This type
Including surfactant be such as N-octadecyl sulfosuccinamic acid disodium, lauryl 2-Sulfosuccinic acid
Disodium, lauryl 2-Sulfosuccinic acid diammonium；N-(1,2-bis-carboxyethyl)-N-octadecyl sulfosuccinic amide
Acid four sodium, the diamyl ester of sodium sulfosuccinate, the dihexyl ester of sodium sulfosuccinate；And 2-Sulfosuccinic acid
The dioctyl ester of sodium.
The anionic detersive surfactant being preferably applicable to care composition of the present invention includes dodecyl sulfur
Acid ammonium, Zetesol AP, lauryl sulphate acid triethylamine, laureth sulfate triethylamine, ten
Dialkyl group sulphuric acid triethanolamine, triethanolamine laureth, lauryl sulphate acid monoethanolamine, lauryl sulfur
Acid monoethanolamine, lauryl sulphate acid diethanolamine, laureth sulfate diethanolamine, lauric acid list
Ester sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, lauryl potassium sulfate, lauryl ether sulfate,
Sodium lauryl sarcosinate, sodium lauroyl sarcosine, cocoyl sarcosine, cocoyl sarcosine, cocos nucifera oil acyl sulfur
Acid ammonium, dodecanoyl ammonium sulfate, coconut palm sodium oleyl sulfate, lauroyl sodium sulfate, cocos nucifera oil acyl sulfate potassium, Laurel
Base potassium sulfate, dodecyltriethanolamine sulfate, cocos nucifera oil acyl sulfate monoethanolamine salt, lauryl sulfate one second
Hydramine, tritriacontyl benzene sulfonic acid sodium salt and dodecylbenzene sodium sulfonate and combinations thereof.
Both sexes and zwitterionic surfactant
The amphoteric surfactant composition being applicable to care composition of the present invention includes that those become known for conditioning group
In compound or other personal care cleansing compositions and containing being anion under the pH of this care composition
Or the composition of zwitterionic group.
The example that can be used for the amphoteric detersive surfactants in the present composition is as aliphatic series secondary and tertiary amines
Derivant broadly described those, wherein aliphatic group can be straight or branched, and one of them aliphatic series
Substituent group contains about 8 to about 18 carbon atoms, and an aliphatic substituent group contains anionic water solubilizing group
Such as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.The example of the compound belonging to this definition is
Dodecyl-alanine sodium, dodecylamino propane sulfonic acid sodium, Cortex cocois radicis both sexes acetate, Cortex cocois radicis both sexes
Diacetin, both sexes Laurel acetate, both sexes Laurel diacetin, sodium lauryl sarcosinate, both sexes Laurel
Sodium acetate, N-alkyl taurine.
Other amphion, as betaine is also applied for the present invention.It is applicable to the example of the betaine of the present invention
Including high alkyl betaines, as coco dimethyl carboxymethyl betaine, Cocamidopropyl Betaine,
Ammonium in cocos nucifera oil betaine, lauroyl amido sulfopropyl betaine, oil base betaine, lauryl dimethyl carboxymethyl
Salt, lauryl dimethyl α carboxyethyl betaine, cetyl dimethyl carboxymethyl betaine, lauryl two-(2-
Hydroxyethyl) carboxymethyl betaine, stearyl two-(2-hydroxypropyl) carboxymethyl betaine, oleyl dimethyl γ-
Carboxylic sulfopropyl betaine and lauryl two-(2-hydroxypropyl) α-carboxyethyl betaine.The representative of sultaines is
Coco dimethyl sulfapropyl betaine, stearyl dimethyl sulfopropyl betaine, lauryl dimethyl sulphur
Ethyl betaine, lauryl two-(2-hydroxyethyl) sulfapropyl betaine and the like；Amino betaine
It is also applied for the present invention with amidosulfobetaines betaine.
Nonionic surfactant
In addition to anionic detersive surfactant composition, the compositions of the present invention optionally contains other
Detersive surfactant.These compositions include nonionic surfactant.The Nonionic detersive table that can use
Face activating agent includes that those generalized definition are (can by alkylene oxide group (hydrophilic) and organic hydrophobic compound
Be aliphatic series or alkyl aromatic) condensation reaction and those prepared compounds.Preferably nonionic goes
The example of dirty surfactant is:
1. the polyethylene oxide condensation product of alkyl phenol, such as containing about 6 in straight or branched configuration in alkyl
To alkyl phenol and the condensation product of oxirane of about 20 carbon atoms, the content of described oxirane is about 10
To about 60 moles/mole alkyl phenols.
2. it is condensed derivative those by oxirane with reacting the product obtained from propylene oxide and ethylenediamine product
Composition.
3. straight or branched configuration contains the fatty alcohol of about 8 to about 18 carbon atoms and the condensation of oxirane
Product, such as coconut alcohol ethylene oxide condensation product, the content of its ethylene oxide be about 10 to about 30 moles/
Mole coconut alcohol, this coconut alcohol fraction has about 10 to about 14 carbon atoms.
4. Polyethylene Glycol (PEG) glyceryl fatty esters, such as R (O) OCH2CH (OH) CH2 (OCH2CH2) nOH
The material of definition, in formula, n is about 5 to about 200, is preferably from about 20 to about 100, and R is to have about 8 to about
The aliphatic alkyl of 20 carbon atoms.
Currently preferred compositions contain anion surfactant and zwitterionic surfactant and/or
The compositions of amphoteric surfactant.
Cationic polymer hair conditioner
The care composition of the present invention also includes water-soluble cationic organic polymer hair conditioner.
The cationic organic polymer being applicable to hair conditioner of the present invention is conditioning can be provided useful to hair
Effect and can being dissolved in care composition, or in care composition, form liquid coacervates
Organic polymer.Any cationic polymer that these beneficial effects can be provided can be used.Used herein
Term " polymer " " should both include, by the material of a kind of monomer polymerization generation, also including being gathered by two kinds of monomers
Close the material (i.e. copolymer) or the material produced by various of monomer or naturally occurring polymer produced.
Suitably cationic polymer include the vinyl monomer such as with cationic amine or quaternary ammonium functional group with
The copolymer of water soluble spacer monomers, described water soluble spacer monomers is such as acrylamide, methacryl
Amine, alkyl and dialkylacrylamides, alkyl and dialkyl methacrylamides, alkyl acrylate, first
Base alkyl acrylate, vinyl caprolactam and vinyl pyrrolidone.This alkyl and the substituted list of dialkyl group
Body preferably has C1-C7 alkyl, more preferably C1-C3 alkyl.Other suitable spacer monomers includes vinyl
Ester, vinyl alcohol (being made up of polyvinyl acetate hydrolysis), maleic anhydride, propylene glycol and ethylene glycol.
Suitably cation amino and quaternary ammonium monomer includes such as by propenoic acid dialkyl aminoalkyl ester, isobutyl
Olefin(e) acid dialkyl aminoalkyl ester, acrylic acid one alkylaminoalkyl, methacrylate one alkylaminoalkyl group
Ester, trialkyl methacryloxyalkyl acryloxyalkyl ammonium salt, trialkyl acryloxyalkyl ammonium salt, diallyl season
The substituted vinyl compound of ammonium salt, and there is cyclic cationic such as pyridine, imidazoles and season Han azo-cycle
The quaternary vinyl ammonium monomers of ammonium ketopyrrolidine, such as alkyl vinyl imidazolium, alkylvinylpyridines,
Alkyl vinyl pyrrolidone salt.
The substituted vinyl monomer of amine being applicable to the present invention includes propenoic acid dialkyl ammonia alkyl ester, methacrylate
Dialkyl aminoalkyl ester, dialkylaminoalkyl acrylamides and dialkyl aminoalkyl MAAm.
Cationic polymer herein can include by amine and/or the monomer of quaternary ammonium-substituted and/or compatible interval
The mixture of the monomeric unit of monomer derived.
Suitably cationic hair conditioning polymer includes such as: l-vinyl-2-pyrrolidone and 1-ethylene
The copolymer of base-3-methylimidazole salt (example hydrochloric acid salt)；L-vinyl-2-pyrrolidone and methacrylate two
The copolymer (in this industry, CTFA is called Onamer M 1) of methyl ammonia ethyl ester, such as with trade name
Those raw materials that GAFQUAT (such as GAFQUAT755N) is provided by GafCorporation (Wayne, NJ, USA)；
Containing the polymer of cation quaternary diallyl ammonium, including such as acrylamide and dimethyl diallyl chlorination
The copolymer of ammonium.
Other cationic polymer being suitable for can include polysaccharide polymer, such as cationic cellulose derivative,
Cationic guar gum and cationic starch derivative.
The Cationic polysaccharide polymer being applicable to the present invention includes the polymer of following formula:
Cationic cellulose is with its PolymerLR series polymer, as epoxidation substituted with trimethyl ammonium
The salt of the hydroxyethyl cellulose that thing reacts and obtains obtains from AmercholCorp. (Edison, NJ, USA),
It is referred to as polyquaternary amine 10 in industry (CTFA).Onamer M 0 cationic fiber preferred for the present invention
The polymer of element is from AmercholCorp., trade name PolymerLR-30M..
Another kind of cationic cellulose includes hydroxyethyl cellulose and the substituted epoxide of lauryl dimethyl ammonium
The polymeric quaternary ammonium salts that reaction is formed, (CTFA) is referred to as polyquaternary amine 24 in the industry.
Other cationic polymer that can use includes cationic guar derivative, such as guar
Trimethylammonium chloride (is obtained with its JaguarR series by CelaneseCorp.).Other material includes containing quaternary nitrogen
Cellulose ether and the copolymer of etherified cellulose and starch.
Insoluble hair conditioner
The care composition of the present invention also includes insoluble hair conditioner, and its concentration should be able to provide effectively
Hair conditioning effect.The conditioner being suitable for includes siloxanes, vaseline and hair conditioning oil-based liquid, as
Hydrocarbon ils, fatty ester, synthetic ester, and mixture.
Silicone Hair Conditioning Agent
The care composition of the present invention also includes nonvolatile, nonionic or cationic silicone hair conditioning
Agent and mixture thereof, they are insoluble in care composition.(gathering) siloxanes (silicone) hair conditioner
Care composition mixes, thus forms scattered soluble granule or droplet.This siloxanes hair conditioning
Agent includes nonvolatile, insoluble silicone liquid, and optionally includes Silicone gums, this natural gum
Do not dissolve in care composition generally, but dissolve in silicone liquid.This Silicone Hair Conditioning Agent is also
Including other composition, such as polyorganosiloxane resin, with enhanced deposition effect.
The Silicone Hair Conditioning Agent being applicable to the present invention preferably has about 1,000 to about at 25 DEG C
2,000,000 centistokes, more preferably from about 10,000 to about 1,800,000, even more preferably about 100,000 to
The viscosity of about 1,500,000.
Suitably insoluble silicone liquid includes polyalkylsiloxane, polyarylsiloxane, polyoxyethylene alkyl aryl base
Siloxanes, polyether siloxane copolymer, and mixture.Other can also be used to have hair conditioning character
Insoluble, non-volatile silicone fluid.In this article, " silicone liquid " refers to flowable silica
Alkane material, its viscosity at 25 DEG C is less than 1,000,000 centistoke.Generally, this liquid gluing at 25 DEG C
Degree be about 5 to 1,000,000 centistokes, preferably from about 10 to about 100,000.
The Non-volatile polyalkylsiloxane that can use includes such as polydimethylsiloxane.These siloxanes
Purchased from such as GeneralElectricCompany, ViscasilR and SF96 series, and can be able to purchase
From DowCorning, DowCorning, 200 series.
The poly-alkaryl siloxanes fluids that can use also includes such as PSI.These silica
Alkane is purchased from such as GeneralElectricCompany, SF1075 methyl phenyl fluid, or is purchased from
DowCorning, 556 Cosmetic Grade Fluid.
The polyether siloxane copolymer that can use includes the polydimethylsiloxane of such as polypropylene oxide
(such as DowCorningDC1248), naturally it is also possible to use oxirane or oxirane and expoxy propane
Mixture.The content of oxirane and expoxy propane must be of a sufficiently low, to prevent it from combining at water and the present invention
Thing dissolves.
This Silicone Hair Conditioning Agent can also include polydimethylsiloxane glue, and (viscosity is greater than about
1,000,000 centistokes) and the mixing of polydimethylsiloxane liquid (viscosity is about 10 to about 100,000 centistokes)
Thing, wherein glue is about 30: 70 to about 70: 30, preferably from about 40: 60 to about 60: 40 with the ratio of liquid.
The ester of synthesis
The care composition of the present invention can include synthetic ester.These esters with the necessity in this care composition
When composition is used in combination, permissible when being particularly used in combination with foregoing cationic hair conditioning polymer
More preferable moistening is provided to send out sense.
Synthetic ester be applicable to this care composition is insoluble in water, and has about 1 to about 300 li
Pool, the viscosity of preferably from about 1 to about 150 centipoise, more preferably be about 2 to 50 centipoises.
The specific limiting examples of the synthetic ester be applicable to this care composition includes P-43 (trihydroxy methyl
C8-C10 tri-ester of propane), MCP-684 (four esters of 3,3 diethanol-1,5-PD), MCP121 (oneself
The C8-10 diester of diacid), all these it is purchased from MobilChemicalCompany, Edison,
NewJersey, U.S.A.
Dandruff removing agent
The dandruff removing agent of the present invention and conditioning care composition include being suitable for being administered to accounting on hair or skin
Composition weight about 0.1% is to about 4%, preferably from about 0.1% to about 3%, most preferably from about 0.3% to about 2%
Dandruff removing agent.This dandruff removing agent makes this care composition have antibacterial activity.This dandruff removing agent can be
Grain or solvable.The example of the non-limiting particulate anti-dandruff agent being suitable for includes: pyrithione, sulfuration
Selenium, granule sulfur, and mixture.Preferably pyrithione.Non-limiting solvable the decaptitating being suitable for
The example of bits agent is ketoconazole.This dandruff removing agent should physics with chemically with in said composition necessary become
Split-phase is held and would not too affect product stability, aesthetics or performance.
Aqueous carrier
Care composition of the present invention is typically liquid, and this liquid preferably can at room temperature be toppled over.For
For dumpable liquid formulations, said composition preferably includes aqueous carrier, and such as water, it generally accounts for this group
About the 20% of polymer weight is to about 95%, preferably from about 50% to about 94%, more preferably from about 60% to about 85%.
Optional components
The compositions of the present invention also includes multiple non-essential optional shampoo components, and they are applicable to make this combination
Thing is accepted in cosmetic or aesthetic being easier to, or makes said composition have additional use benefit, condition
It is that these optional members physically and chemically perhaps can appropriately damage product mutually with above-mentioned neccessary composition
Stability, aesthetic properties or performance.This constituents multiple is known to professionals in the field.They
Include but not limited to: pearlescent additive, preservative, fatty alcohol, sodium chloride, ethanol that pH regulator auxiliary agent
Toner or dyestuff, spice, and chelating agen, pediculicide, preservative, protein, skin active agent, suspend
Agent, styling polymer, sunscreen, thickening agent, micro-element and viscosity modifier.
The another kind of optional composition with useful use is antistatic additive.This antistatic additive would not undue shadow
Ring the performance in the use of shampoo and final beneficial effect, especially, this antistatic additive would not affect cloudy from
Sub-detersive surfactant.The antistatic additive being suitable for includes such as three cetyl ammonio methacrylates.
Detailed description of the invention
For being best understood from present disclosure, further illustrate present disclosure in conjunction with some specific embodiments.
Prepare hair care composition
Table 1
Blank group is the substrate without any active substance
Matrix formulations:
15% sodium laureth sulfate (70% content)
0.1%EDTA disodium
1% coconut oleoyl amine MEA
2% glycol distearate
0.3% guar hydroxypropyltrimonium ammonium chloride
0.2% carbomer
5% cocamido propyl betaine
Active component (preparation 1-7)
Add to 100% water
<experimental example 1>measures the compositions impact on hair tensile strength
After the hair in same source is cleaned with 5% sodium lauryl sulfate, by 5% soaking with sodium hydroxide 30 minutes,
After pure water cleans, soak 15 hours by the compositions of above-mentioned table 1, naturally dry.
Measure tension force reduction rate (%).Tension force reduction rate (%) is with flow graph (Model 200-2J, Fudo
Kogyo co., Japan) measure in the case of 20 DEG C ± 2 DEG C and relative humidity are 60 ± 4%.Hair
Original length be 50 millimeters, extension rate is 5 cm per minute and full scale is 200gf.
According to below equation calculate tension force reduce percent:
Tension force reduces (%)=(Fo-F1)/(Fo) × 100
Wherein F0 is to make the original power needed for elongate fiber 20%；F1 is to make same fiber uphold 20% institute again
The strength needed.(see N.B.Fair and B.S.Gupta:The use of multiple test methods
in the analysis of the effect of cosmetic treatment on the surface
Properties of human hair, XIVth IFSCC Congress, Barcelona, Vol II, p
113-1124(1986))。
Experimental result see table 2
Result shows: when being used alone baicalin, caffeine, agedoite and nicotiamide, and compositions has
There is certain tension force slip, when compounding baicalin, caffeine, agedoite and nicotiamide, compositions
Tension force slip is lower by more than 20% than the tension force slip being used alone, further, and alkyl modified siloxane
The tensile strength of compositions can be increased further.
(experimental example 2) hair draws high performance test
20 DEG C, 45% relative to damp condition under, use INSTRON-4466 type strength experimental machine test,
Drawing high speed is 15mm min-1, and force value resolution is 0.01N, the elongation at break (%) of test hair sample.
Experimental result see table 4
| Laboratory sample | Elongation at break (%) | Difference (%) with blank group |
| Preparation 1 | 35.0 | 4.5 |
| Preparation 2 | 35.5 | 5.0 |
| Preparation 3 | 36.0 | 5.5 |
| Preparation 4 | 34.5 | 4.0 |
| Preparation 5 | 39.0 | 8.5 |
| Preparation 6 | 43.5 | 13.0 |
| Preparation 7 | 46.0 | 15.5 |
| Blank group | 30.5 | 0 |
Result shows: when being used alone baicalin, caffeine, agedoite and nicotiamide, and compositions is broken
Split percentage elongation to improve relative to blank group tool, when compounding baicalin, caffeine, agedoite and
During nicotiamide, compositions tension force slip is lower by more than 10% than the tension force slip being used alone, and alkyl
Modified siloxane also has increase hair and draws high the effect of performance.
According to the present invention, preparing following care composition, if no special instructions, content is in terms of weight %.
Embodiment 1 shampoo
Sodium laureth sulfate (70%) 20.0%
Coconut oleoyl amine MFA 1.5%
Glycol distearate 2.0%
C20-24 alkylsiloxane 0.5%
Polydimethylsiloxane 2.0%
Agedoite 1.0%
Baicalin 1.0%
Caffeine 1.0%
Citric acid 0.2%
Guar hydroxypropyltrimonium ammonium chloride 0.3%
Polyquaternium-10 0.2%
Carbomer 0.2%
Cocamido propyl betaine 6.0%
Polyethylene Glycol-7M 0.05%
Methylchloroisothiazandnone/Methylisothiazolinone (3: 1) 0.06 (actual content is 9ppm)
Sodium chloride 0.5%
Embodiment 2 hair conditioner
Cetearyl alcohol 5.0%
Stearamidopropyl dimethylamine 2.0%
Lactic acid 0.5%
Hydroxyethyl cellulose 0.5%
Baicalin 1.0%
Caffeine 1.0%
Agedoite 0.5%
Nicotiamide 2.0%
Aminopropyl polydimethylsiloxane 2.0%
Essence 0.5%
Phenoxyethanol 0.5%
The most detailed application describing the present invention, on the premise of spirit of the invention and scope,
In some ins and outs may some amendment, after appended claims will contain some amendment.These
Amendment be probably such as size, medicament categories, raw material, shape, the mechanism of action and mode, production and
Use.
Claims (15)
1. a care composition for conditioning keratin fibers, wherein, with composition total weight, described compositions contains:
0.1%-10.0% baicalin；
0.1%-10.0% caffeine；
0.1%-10.0% agedoite；
0.1%-10.0% nicotiamide；
And physiology's acceptable carrier.
2. care composition as claimed in claim 1, wherein, with composition total weight, described compositions contains:
0.5%-5.0% baicalin；
0.5%-5.0% caffeine；
0.5%-5.0% agedoite；
0.5%-5.0% nicotiamide.
3. care composition as claimed in claim 1, wherein, with composition total weight, described compositions contains:
1.0%-2.0% baicalin；
1.0%-2.0% caffeine；
1.0%-2.0% agedoite；
1.0%-2.0% nicotiamide.
4. care composition as claimed in claim 1, its be shampoo, hair conditioner, ointment or
Send out film.
5. a care composition for conditioning keratin fibers, wherein, with composition total weight, described compositions contains:
0.5-50.0% foaming surfactant；
0.05-5.0% thickening agent；
0.05-10.0% conditioner；
0.1%-10.0% baicalin；
0.1%-10.0% caffeine；
0.1%-10.0% agedoite；
0.1%-10.0% nicotiamide；
And the acceptable aqueous carrier of physiology.
6. care composition as claimed in claim 5, wherein, with composition total weight, described compositions contains:
Foaming surfactant 5.0-30.0%；
Thickening agent 0.1-1%；
Conditioner 0.1-5.0%；
Baicalin 0.5%-5.0%；
Caffeine 0.5%-5.0%；
Agedoite 0.5%-5.0%；
Nicotiamide 0.5%-5.0%；
And the acceptable aqueous carrier of physiology.
7. care composition as claimed in claim 5, wherein, with composition total weight, described compositions contains:
Foaming surfactant 10.0-20.0%；
Thickening agent 0.5%；
Conditioner 0.5-2%；
Baicalin 1.0%-2.0%；
Caffeine 1.0%-2.0%；
Agedoite 1.0%-2.0%；
Nicotiamide 1.0%-2.0%；
And the acceptable aqueous carrier of physiology.
8. the care composition as described in any claim in claim 5-7, wherein foaming surfactant is selected from anion surfactant, cationic surfactant, nonionic surfactant and/or amphoteric surfactant or a combination thereof.
9. a care composition for conditioning keratin fibers, wherein, with composition total weight, described compositions contains:
5.0-20.0% anion surfactant；
0.3-5.0% amphoteric surfactant；
0.5-5.0% nonionic surfactant；
0.1-3.0% cationic surfactant；
0.05-5.0% thickening agent；
0.05-10.0% conditioner；
0.1%-10.0% baicalin；
0.1%-10.0% caffeine；
0.1%-10.0% agedoite；
0.1%-10.0% nicotiamide；
And the acceptable aqueous carrier of physiology.
10. a care composition for conditioning keratin fibers, wherein, with composition total weight, described compositions contains:
5.0-20.0% anion surfactant；
0.3-5.0% amphoteric surfactant；
0.5-5.0% nonionic surfactant；
0.05-5.0% carbomer；
0.05-10.0% guar hydroxypropyltrimonium chloride；
0.05-5.0% polyquaternary ammonium salt；
0.00-5.0% polysiloxanes；
0.00-5.0% pearling agent；
0-5.0% sodium chloride；
0.01-1.0% chelating agen；
0.01-1.0%pH regulator；
0.00-3.0% essence；
0.0001-1.0% preservative；
0.1%-10.0% baicalin；
0.1%-10.0% caffeine；
0.1%-10.0% agedoite；
0.1%-10.0% nicotiamide.
11. care compositions as described in aforementioned claim 5, it contains alkyl modified siloxane described in 0.1-10% alkyl modified siloxane further selected from C20-C24 siloxanes.
12. care compositions as claimed in claim 11, described alkyl modified siloxane content is 0.5-5 weight %.
13. care compositions as claimed in claim 11, described alkyl modified siloxane content is 1.0-2.0 weight %.
14. care compositions as described in aforementioned any one claim purposes in the care composition preparing keratin fiber, described compositions can improve tensile strength and the extension property of keratin fiber.
15. purposes as claimed in claim 14, described keratin fiber is hair.
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| KR102111719B1 (en) * | 2018-03-27 | 2020-05-15 | 주식회사 엘지생활건강 | Cosmetic Composition for Improving Flexibility of Hair |
| CN110025552B (en) * | 2019-05-05 | 2022-04-08 | 广州美思生物技术有限公司 | Amino acid shampoo capable of increasing tensile strength and elongation of hair and preparation method thereof |
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| DE102011086661A1 (en) * | 2011-11-18 | 2013-05-23 | Henkel Ag & Co. Kgaa | Hair treatment with cationic care and UV filter |
| CN104382760A (en) * | 2014-12-10 | 2015-03-04 | 唯美度科技（北京）有限公司 | Natural anti-dandruff shampoo and preparation method thereof |
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