JP2004210674A - Hair cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hair cosmetic which can protect the oxidative damage to hair by light exposure and drier employment, has an excellent effect for giving glossy hair having good tension and stiffness, and has a very high fading-preventing effect on dyed hair. <P>SOLUTION: This hair cosmetic is characterized by comprising one or more extracts selected from Chaenomeles sinensis extract, Prunus domestica extract and Momordica grosvenorii extract and one or more polymers selected from 2-methacryloyloxyethylphosphorylcholine homopolymer and 2-methacryloyloxyethylphosphorylcholine-hydrophobic monomer copolymers. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【００１４】
本発明に用いられる成分（ｂ）は、ＭＰＣの単独重合体または、ＭＰＣと疎水性モノマーとの共重合体から選ばれる一種または二種以上であればよく、毛髪の損傷を防御し、ハリやコシのあるつややかな髪とする優れた使用感を得るには、単独重合体の場合は、分子量が５０００以上であることが好ましく、１００００以上がより好ましい。疎水性モノマーとの共重合体の場合、疎水性モノマーの種類は、特に限定されないが、スチレン、アクリル酸エステル、メタクリル酸エステルであることが好ましい。疎水性モノマーとの共重合体の分子量も、優れた毛髪損傷防御効果や、ハリやコシのあるつややかな髪とする効果を得るには、分子量が５０００以上であることが好ましく、１００００以上がより好ましい。また、ＭＰＣと疎水性モノマーの構成モル比については、優れた毛髪損傷防御効果や、ハリやコシのあるつややかな髪とする効果を得るには、５０：５０〜９７：３の範囲が好ましい。
【００１５】
本発明に用いられる成分（ｂ）のＭＰＣの単独重合体または、ＭＰＣと疎水性モノマーとの共重合体を更に具体的に例示するならば、ＭＰＣの単独重合体として、Ｌｉｐｉｄｕｒｅ−ＨＭ、Ｌｉｐｉｄｕｒｅ−ＨＭ−５００（日本油脂株式会社製）、ＭＰＣとメタクリル酸ブチルとの共重合体として、Ｌｉｐｉｄｕｒｅ−ＰＭＢ（日本油脂株式会社製）等の市販品を使用することができる。
【００１６】
本発明に用いられる成分（ｂ）のＭＰＣの単独重合体または、ＭＰＣと疎水性モノマーとの共重合体の含有量は、特に限定されないが、成分（ａ）との併用により、毛髪損傷防御効果や、ハリやコシのあるつややかな髪とする効果、或いは染色した髪の色落ち防止効果を充分に得るには、毛髪化粧料中０．００１〜４％であることが好ましく、０．０１〜３％がより好ましい。
【００１７】
本発明の毛髪化粧料は、上記必須成分の他に、目的に応じて本発明の効果を損なわない量的、質的範囲において、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤、ノニオン性界面活性剤等の界面活性剤、エステル油、高級脂肪酸、高級アルコール、炭化水素、油脂類等の油剤、鎖状シリコーン、環状シリコーン、変性シリコーン等のシリコーン類、天然水溶性高分子、半合成水溶性高分子、合成水溶性高分子等の水溶性高分子、多価アルコール、糖類、低級アルコール等の水性成分、アミノ酸、アミノ酸誘導体、ペプチド、ペプチド誘導体、植物エキス等の毛髪用美容成分、エデト酸塩等の金属キレート剤、クエン酸、乳酸、リン酸またはこれらの塩等のｐＨ調整剤、香料、防腐剤、殺菌剤、紫外線吸収剤、酸化防止剤、色素、顔料等、毛髪用化粧料あるいは化粧料一般において汎用される他の成分を配合することができる。
【００１８】
また、本発明の毛髪化粧料の製法は特に限定はなく常法により製造することができ、他の成分との併用や容器の機構により、液状、乳液状、クリーム状、ゲル状、ミスト状、フォーム（泡）状など、種々の形態にて実施することができ、シャンプー、ヘアリンス、ヘアトリートメント、ヘアパック、ヘアローション、ヘアクリーム、ヘアジェル、などとして用いることができる他、液化石油ガス、ジメチルエーテル、窒素ガス、炭酸ガス等の噴射剤とともにエアゾール用容器に充填し、ヘアスプレー、ヘアフォーム等のエアゾール製品としても用いることもできる。使用方法としては、毛髪に塗布した後洗い流す方法、または乾いた毛髪に塗布する方法等のいずれの方法も適用できる。
【００１９】
【実施例】
以下に植物抽出物の製造例、実施例を挙げて、本発明を更に説明する。なお、これらは本発明を何ら限定するものではない。
【００２０】
製造例１：羅漢果抽出物の製造
モモルディカ グロスベノリイＭｏｍｏｒｄｉｃａ ｇｒｏｓｖｅｎｏｒｉｉの果実を乾燥したもの１０ｇに、５０ｖｏｌ％含水エチルアルコール１００ｍＬを加え、室温にて３日間抽出を行った後ろ過して羅漢果抽出物を得た。この時、羅漢果抽出物の乾燥固形分は０．７％であった。
【００２１】
実施例１〜５および比較例１〜６；ヘアコンディショナー
表１に示す組成および下記製造方法にて、インバス使用の洗い流し型のヘアコンディショナーを調製し、得られたヘアコンディショナーの各試料について専門評価者が下記方法により官能評価を行い判定した。得られた結果を表１に併記する。
【００２２】
（組成及び結果）
【表１】

【００２３】
（製造方法）
Ａ．成分（３）〜（５）、（９）を加熱溶解する。
Ｂ．成分、（１０）、（１１）、（１３）を加熱溶解する。
Ｃ．ＢにＡを添加して均一に乳化混合し、冷却後に成分（１）、（２）、（６）〜（８）および（１２）を添加する。
Ｄ．Ｃを容器に充填してヘアコンディショナーを得た。
【００２４】
（評価方法）
（１）ドライヤーによる毛髪の損傷防止（ツヤ付与）効果
コールドパーマやブリーチ等の美容処理を行っていない日本人女性の頭髪２０ｃｍを３０ｇ束ねて毛束としたものを用いた。この毛束を市販のシャンプーにて洗浄し、タオルで水気を拭き取った後、１束をブランクとし、他の毛束の各々に実施例１〜５および比較例１〜６の各試料を１．５ｇずつ塗布した。その後、試料を塗布した毛束を３０秒間水ですすぎ、ドライヤーにて乾燥した。この洗浄から乾燥までの工程を２０回繰り返した。各々の毛束について、毛束の損傷具合およびツヤに関し、専門評価者がブランクとの比較をし、下記（イ）判定基準を用いて判定した。結果を表１に併記する。
【００２５】
（イ）判定基準
（評価基準） （判定）
損傷が無く、非常にツヤがある ： ◎
損傷が無く、ツヤがある ： ○
やや損傷があり、ツヤがあまりない ： △
損傷しており、ツヤが全くない ： ×
【００２６】
（評価方法）
（２）日光曝露による染色毛髪の褪色防止効果
日本人白髪１０ｃｍで２ｇの束を市販の２剤式永久染毛剤（ダークブラウン）を用いて染色し、市販のシャンプーにて洗浄した後、１束は何も塗布せず（ブランク）、他の毛束には実施例１〜５および比較例１〜６の各試料をそれぞれ塗布し、水洗後軽く水を切り、２週間日光に曝露した。各毛束について、専門評価者が毛束の褪色具合をブランクと比較し、下記（ロ）判定基準を用いて判定した。結果を表１に併記する。
【００２７】
（ロ）判定基準
（評価基準） （判定）
ほとんど差がない ： ◎
わずかに色落ちがみられる ： ○
かなりの色落ちがみられる ： △
ほとんど色落ちしている ： ×
【００２８】
表１の結果から明らかなように、本発明のヘアコンディショナーは比較例１〜６のものと比較して、毛髪の損傷防止効果に優れ、毛髪へのツヤ付与効果において良好な結果を示し、なおかつ染色毛髪の色落ち防止効果が高い、ヘアコンディショナーとして優れた効果を有するものであることが実証された。
【００２９】
実施例６ シャンプー
下記に示す組成および製法で、シャンプーを調製した。

【００３０】
（製法）
Ａ．成分（１）〜（１５）を均一に混合する。
Ｂ．Ａを容器に充填し、シャンプーを得た。
【００３１】
実施例６のシャンプーは、光曝露やドライヤー使用による毛髪の酸化損傷を防御する効果に優れ、良好なツヤ、ハリやコシを付与し、染色した髪に対しては色落ちを防ぐ効果のきわめて高い毛髪化粧料であった。
【００３２】
実施例７ ヘアトリートメントローション
下記に示す組成および製法で、ヘアトリートメントローションを調製した。

【００３３】
（製造方法）
Ａ．成分（１）〜（６）および（１４）を混合溶解する。
Ｂ．成分（７）〜（１３）を混合溶解する。
Ｃ．ＡにＢを添加して均一に混合する。
Ｄ．Ｃをミストディスペンサー容器に充填し、ヘアトリートメントローションを得た。
【００３４】
以上のようにして得られた実施例７のヘアトリートメントローションは、ミスト状で毛髪に良好に使用でき、光曝露やドライヤー使用による毛髪の酸化損傷を防御する効果に優れ、良好なツヤ、ハリやコシを付与し、染色した髪に対しては色落ちを防ぐ効果の高いヘアトリートメントローションとして優れた効果を有するものであった。
【００３５】
実施例８ ヘアパック
下記に示す組成および製法で、ヘアパックを調製した。

注６：ＳＭ８７０４Ｃ（４０％エマルション）（東レ・ダウコーニング社製）処方中の配合量はアミノ変性シリコーン純分の値である。
【００３６】
（製造方法）
Ａ．成分（３）〜（６）を加熱溶解する。
Ｂ．成分（９）〜（１４）および（１７）を加熱溶解する。
Ｃ．ＢにＡを添加して均一に乳化混合し、冷却後に成分（１）、（２）、（７）、（８）、（１５）および（１６）を添加する。
Ｄ．Ｃを容器に充填し、ヘアパックを得た。
【００３７】
実施例８のヘアパックは、光曝露やドライヤー使用による毛髪の酸化損傷を防御する効果に優れ、良好なツヤ、ハリやコシを付与し、染色した髪に対しては色落ちを防ぐ効果が非常に高くヘアパックとして優れた効果を有するものであった。
【００３８】
実施例９ ヘアジェル
下記に示す組成および製法で、ヘアジェルを調製した。

【００３９】
（製法）
Ａ．成分（１４）の一部に成分（１）、（２）および（６）を均一に混合する。
Ｂ．成分（１４）の一部に成分（３）および（４）を均一に混合する。
Ｃ．成分（７）〜（１０）を混合溶解する。
Ｄ．成分（５）および（１４）の残部を混合溶解する。
Ｅ．ＤにＣを添加して混合溶解し、さらにＡおよびＢを添加して均一に混合する。
Ｆ．Ｅに（１１）〜（１３）を添加して混合する。
Ｇ．Ｆを容器に充填してヘアジェルを得た。
【００４０】
実施例９のヘアジェルは、ヘアジェルとしての整髪力に加え、光曝露やドライヤー使用による毛髪の酸化損傷を防御する効果に優れ、染毛剤を用いて染色した髪に対しては色落ちを防ぐ効果の高いものであった。
【００４１】
【発明の効果】
本発明の毛髪化粧料は、日光曝露やドライヤー使用による毛髪の酸化損傷を防御する効果に優れ、ハリやコシのあるつややかな髪とする効果に優れ、染色した髪に対しては色落ちを防ぐ効果がきわめて高く、毛髪化粧料として優れた品質を有するものである。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a hair cosmetic, and more particularly, to an effect of protecting hair from oxidative damage due to sun exposure or use of a drier, having an excellent effect of producing a firm and shiny hair, and a color for dyed hair. The present invention relates to a hair cosmetic having a high effect of preventing falling.
[0002]
[Prior art]
Hair is damaged by the heat of the dryer and external influences such as exposure to sunlight and the atmosphere, such as fading of hair color and loss of strength. being called). The fading of hair color is due to the oxidative degradation of melanin pigments and pigments derived from hair dyes, and the decrease in tensile strength is due to the oxidative cleavage of disulfide bonds of keratin, a kind of protein that constitutes hair. Cuticles and keratin fibers inside hair are damaged in hair that has been degraded by these oxidation reactions, and components in hair such as melanin pigments, pigments derived from hair dyes, and lipids are easily eluted. For this reason, if these damaged hairs are left untreated, the damage will further progress. In the past, various attempts have been made to prevent such damage to hair and to protect hair damaged by weathering in hair compositions. In order to protect damaged hair, water-soluble polymers, protein derivatives, silicones, plant extracts, and the like are mixed (for example, see Patent Documents 1 to 5), or elution of components in hair is prevented. For this purpose, a polymer having 2-methacryloyloxyethyl phosphorylcholine (hereinafter sometimes abbreviated as MPC) as a constitutional unit or a copolymer of MPC and a hydrophobic monomer has been blended (for example, Patent Document 6). , 7). Further, in order to protect the hair from damage due to exposure to sunlight, an ultraviolet absorber has been added (for example, see Patent Document 8).
[0003]
[Patent Document 1]
JP-A-6-92824 [Patent Document 2]
JP-A-7-69844 [Patent Document 3]
JP-A-8-48698 [Patent Document 4]
JP-A-9-71516 [Patent Document 5]
JP-A-8-231348 [Patent Document 6]
JP-A-5-70321 [Patent Document 7]
JP-A-6-157269 [Patent Document 8]
JP-A-7-228510
[Problems to be solved by the invention]
However, when a water-soluble polymer or protein derivative, a homopolymer of MPC or a copolymer of MPC and a hydrophobic monomer, etc., is blended, dye elution is prevented for hair dyed with a hair dye or the like. Although having an effect, if these components are added in a large amount in an attempt to bring out a sufficient effect, the hair color may be impaired rather than causing dandruff-like flaking to the hair. In addition, these components were not sufficiently effective in preventing hair from oxidative damage due to exposure to a drier or sunlight. In addition, when an ultraviolet absorber is added, although it has an effect of preventing discoloration of the hair, if a large amount of this component is added to bring out a sufficient effect, the stability of the product may be impaired. Therefore, a hair cosmetic which has an excellent effect of protecting the hair from oxidation due to sun exposure, use of a dryer, etc., and having an excellent effect of making the hair shiny and stiff and highly effective in preventing discoloration of dyed hair is desired. I was
[0005]
[Means for Solving the Problems]
In view of such circumstances, the present inventors have conducted intensive studies to solve the above-described problems, and as a result, mocca extract, peach extract, and arhat extract which were not conventionally considered to be related to prevention of hair color fading. By using one or two or more selected from the group consisting of a homopolymer of MPC or a copolymer of MPC and a hydrophobic monomer, it has an excellent effect of protecting the hair from oxidation due to exposure to sunlight and use of a drier, It has been found that a hair cosmetic that has an excellent effect of making the hair shiny and stiff and has a high effect of preventing color fading on dyed hair can be obtained, and the present invention has been completed based on this finding. .
[0006]
That is, the present invention provides the following components (a) and (b):
(A) one or more selected from mocca extract, peach extract, arhat extract,
(B) A hair cosmetic comprising one or more selected from a homopolymer of 2-methacryloyloxyethyl phosphorylcholine (MPC) or a copolymer of MPC and a hydrophobic monomer.
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the configuration of the present invention will be described.
The mocca extract of the component (a) used in the present invention is obtained from deciduous tall trees of the family Rosaceae (Gourd melon) and Chaenomeles sinensis. Prunus peach extract is obtained from Prunus domestica, a deciduous tree in the family Rosaceae. Arhat extract is obtained from the vine perennial Momordica grosvenorii Momordica grosvenorii of the Cucurbitaceae family. The place of production and cultivation method are not particularly limited.
[0008]
The method for preparing the above mocca extract, peach extract, and arhat extract is not particularly limited, and the extract is extracted from any one or more places such as skins, buds, leaves, flowers, fruits, and seeds. But fruit is particularly preferred. After subjecting these to drying, shredding, squeezing, or fermentation as appropriate, a method of extracting with a solvent at a low temperature or at a temperature from room temperature to a heating temperature can be exemplified. The obtained extract can be used as a solution, paste, gel, or powder by subjecting the extract to filtration or purification using an ion exchange resin or the like, such as adsorption or decolorization. If necessary, purification treatment such as deodorization and decolorization may be performed within a range that does not affect the effect.
[0009]
As the extraction solvent, for example, water, lower monohydric alcohol (methyl alcohol, ethyl alcohol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, etc.), liquid polyhydric alcohol (glycerin, propylene glycol, 1,3 -Butylene glycol, etc.), lower alkyl esters (ethyl acetate, etc.), hydrocarbons (benzene, hexane, pentane, etc.), ketones (acetone, methyl ethyl ketone, etc.), ethers (diethyl ether, tetrahydrofuran, dipropyl ether, etc.), acetonitrile And the like, and one type or two or more types can be used.
[0010]
Further, as an example of a preferable extraction method, extraction is carried out at room temperature or by heating for 1 to 5 days using aqueous ethyl alcohol or 1,3-butylene glycol having a concentration of 0 to 100 vol%, followed by filtration. There is a method in which the obtained filtrate is left to mature for about one week, and then filtered again.
More specifically, the component (a) used in the present invention may be a commercially available product such as a mokka extract (Maruzen Pharmaceutical Co., Ltd.) or the like. Commercial products such as prune extract WC (manufactured by Maruzen Pharmaceutical Co., Ltd.) can be used.
[0011]
The contents of the mockery extract, peach extract and Arhat extract of the component (a) used in the present invention are not particularly limited, but they sufficiently protect the hair from oxidative damage, and make the hair shiny and firm. In order to obtain the effect of maintaining the color of the dyed hair, the solid content in the hair cosmetic is 0.00001 to 0.01% by mass (hereinafter simply referred to as "%"). Is preferably, and more preferably 0.0005 to 0.005%.
[0012]
On the other hand, the component (b) used in the present invention, 2-methacryloyloxyethyl phosphorylcholine constituting a homopolymer of 2-methacryloyloxyethyl phosphorylcholine (MPC) or a copolymer of MPC and a hydrophobic monomer is represented by the following formula. It is.
[0013]
Embedded image

[0014]
The component (b) used in the present invention may be a homopolymer of MPC or one or two or more selected from a copolymer of MPC and a hydrophobic monomer. In order to obtain an excellent feeling of use that gives a firm and lustrous hair, in the case of a homopolymer, the molecular weight is preferably 5,000 or more, more preferably 10,000 or more. In the case of a copolymer with a hydrophobic monomer, the type of the hydrophobic monomer is not particularly limited, but is preferably styrene, acrylate, or methacrylate. The molecular weight of the copolymer with the hydrophobic monomer is also preferably at least 5,000, more preferably at least 10,000, in order to obtain an excellent hair damage-protecting effect and an effect of making the hair shiny and stiff. preferable. Further, the constitutional molar ratio of MPC to the hydrophobic monomer is preferably in the range of 50:50 to 97: 3 in order to obtain an excellent hair damage-protecting effect and an effect of making the hair shiny and stiff.
[0015]
If the homopolymer of MPC or the copolymer of MPC and a hydrophobic monomer as the component (b) used in the present invention is more specifically exemplified, the homopolymer of MPC may be Lipidure-HM, Lipidure- As the copolymer of HM-500 (manufactured by NOF Corporation) and MPC and butyl methacrylate, commercially available products such as Lipidure-PMB (manufactured by NOF Corporation) can be used.
[0016]
The content of the homopolymer of MPC of the component (b) or the copolymer of the MPC and the hydrophobic monomer used in the present invention is not particularly limited. In order to sufficiently obtain the effect of making the hair shiny and stiff and the effect of preventing color fading of the dyed hair, the content is preferably 0.001 to 4% in the hair cosmetic, and 0.01 to 4%. 3% is more preferred.
[0017]
The hair cosmetic of the present invention may further comprise, in addition to the above essential components, an anionic surfactant, a cationic surfactant, and an amphoteric surfactant in a quantitative and qualitative range that does not impair the effects of the present invention depending on the purpose. , Surfactants such as nonionic surfactants, ester oils, higher fatty acids, higher alcohols, hydrocarbons, oils such as oils and fats, chain silicones, cyclic silicones, silicones such as modified silicones, natural water-soluble polymers, Water-soluble polymers such as semi-synthetic water-soluble polymers and synthetic water-soluble polymers, aqueous components such as polyhydric alcohols, saccharides and lower alcohols, and beauty components for hair such as amino acids, amino acid derivatives, peptides, peptide derivatives, and plant extracts. , Chelating agents such as edetates, pH adjusters such as citric acid, lactic acid, phosphoric acid or salts thereof, fragrances, preservatives, bactericides, ultraviolet absorbers, antioxidants, colors It may be blended with other ingredients commonly pigments, in hair cosmetic or cosmetics in general.
[0018]
In addition, the method for producing the hair cosmetic of the present invention is not particularly limited and can be produced by a conventional method, and is used in combination with other components or a mechanism of a container, so that a liquid, an emulsion, a cream, a gel, a mist, It can be carried out in various forms such as foam (foam), and can be used as a shampoo, a hair rinse, a hair treatment, a hair pack, a hair lotion, a hair cream, a hair gel, etc., as well as liquefied petroleum gas, dimethyl ether, The aerosol container may be filled together with a propellant such as nitrogen gas or carbon dioxide gas and used as an aerosol product such as a hair spray or a hair foam. As a method of use, any method such as a method of applying to hair and then rinsing it, or a method of applying to dry hair can be applied.
[0019]
【Example】
Hereinafter, the present invention will be further described with reference to Production Examples and Examples of plant extracts. Note that these do not limit the present invention at all.
[0020]
Production Example 1: Production of an extract of arhat fruit extract To 10 g of dried fruit of momordica grosvenoriii, 100 ml of 50 vol% aqueous ethyl alcohol was added to 10 g of dried fruit, extracted for 3 days at room temperature, and then filtered to obtain an extract of arhat fruit extract. . At this time, the dry solid content of the Arhat extract was 0.7%.
[0021]
Examples 1 to 5 and Comparative Examples 1 to 6: Hair conditioner A rinse-off type hair conditioner using an in-bath was prepared by the composition shown in Table 1 and the following production method, and a professional evaluator was used for each sample of the obtained hair conditioner. Was evaluated by sensory evaluation according to the following method. The results obtained are also shown in Table 1.
[0022]
(Composition and results)
[Table 1]

[0023]
(Production method)
A. Components (3) to (5) and (9) are heated and dissolved.
B. The components (10), (11) and (13) are dissolved by heating.
C. A is added to B and uniformly emulsified and mixed. After cooling, components (1), (2), (6) to (8) and (12) are added.
D. C was filled in a container to obtain a hair conditioner.
[0024]
(Evaluation method)
(1) Effect of Preventing Hair Damage (Glossing) by Dryer A hair bundle obtained by bundling 30 g of 20 cm of the hair of a Japanese woman who has not been subjected to beauty treatment such as cold perm or bleach was used. After washing this hair bundle with a commercially available shampoo and wiping off the water with a towel, one bundle was used as a blank, and each of the other hair bundles was subjected to the same procedure as in Examples 1 to 5 and Comparative Examples 1 to 6. Each 5 g was applied. Thereafter, the hair bundle to which the sample was applied was rinsed with water for 30 seconds and dried with a dryer. This process from washing to drying was repeated 20 times. For each bristle bundle, a professional evaluator compared the degree of damage and gloss of the bristle bundle with a blank, and made a determination using the following criteria (a). The results are also shown in Table 1.
[0025]
(A) Judgment criteria (Evaluation criteria) (Judgment)
No damage, very glossy: ◎
No damage and gloss: ○
Some damage and little gloss: △
Damaged, no gloss: ×
[0026]
(Evaluation method)
(2) Prevention of Fading of Dyed Hair Due to Sunlight Exposure A 2 g bundle of 10 cm Japanese white hair was dyed with a commercially available two-part permanent hair dye (dark brown) and washed with a commercially available shampoo. Nothing was applied to the bundle (blank), and the other hair bundles were coated with the samples of Examples 1 to 5 and Comparative Examples 1 to 6, respectively, washed with water, lightly drained, and exposed to sunlight for 2 weeks. For each hair bundle, a professional evaluator compared the degree of fading of the hair bundle with the blank, and made a determination using the following criteria (b). The results are also shown in Table 1.
[0027]
(B) Judgment criteria (evaluation criteria) (Judgment)
Little difference: ◎
Slight discoloration is observed: ○
Significant discoloration is observed: △
Almost discolored: ×
[0028]
As is clear from the results in Table 1, the hair conditioner of the present invention is superior to those of Comparative Examples 1 to 6 in the effect of preventing damage to the hair and showing a favorable result in the effect of imparting gloss to hair, and It has been proved that the hair conditioner has a high effect of preventing discoloration of dyed hair and has an excellent effect as a hair conditioner.
[0029]
Example 6 Shampoo A shampoo was prepared by the following composition and manufacturing method.

[0030]
(Production method)
A. The components (1) to (15) are uniformly mixed.
B. A was filled in a container to obtain a shampoo.
[0031]
The shampoo of Example 6 has an excellent effect of protecting hair from oxidative damage due to light exposure and use of a dryer, imparts good luster, firmness and firmness, and has an extremely high effect of preventing discoloration of dyed hair. It was a hair cosmetic.
[0032]
Example 7 Hair treatment lotion A hair treatment lotion was prepared according to the following composition and manufacturing method.

[0033]
(Production method)
A. Components (1) to (6) and (14) are mixed and dissolved.
B. Components (7) to (13) are mixed and dissolved.
C. Add B to A and mix uniformly.
D. C was filled in a mist dispenser container to obtain a hair treatment lotion.
[0034]
The hair treatment lotion of Example 7 obtained as described above is mist-like, can be used favorably on hair, has an excellent effect of protecting the hair from oxidative damage due to light exposure and use of a dryer, and has a good gloss, firmness, The hair treatment lotion was given an excellent effect as a hair treatment lotion having a strong effect of preventing color fading on hair dyed with stiffness.
[0035]
Example 8 Hair pack A hair pack was prepared by the following composition and manufacturing method.

Note 6: The amount of SM8704C (40% emulsion) (manufactured by Dow Corning Toray Co., Ltd.) in the formulation is the value of pure amino-modified silicone.
[0036]
(Production method)
A. The components (3) to (6) are heated and dissolved.
B. Components (9) to (14) and (17) are dissolved by heating.
C. A is added to B and uniformly emulsified and mixed. After cooling, components (1), (2), (7), (8), (15) and (16) are added.
D. C was filled in a container to obtain a hair pack.
[0037]
The hair pack of Example 8 has an excellent effect of protecting hair from oxidative damage due to light exposure and use of a dryer, imparts a good luster, firmness and firmness, and has an extremely effective effect of preventing discoloration of dyed hair. And had an excellent effect as a hair pack.
[0038]
Example 9 Hair gel A hair gel was prepared by the following composition and manufacturing method.

[0039]
(Production method)
A. Components (1), (2) and (6) are uniformly mixed with a part of the component (14).
B. The components (3) and (4) are uniformly mixed with a part of the component (14).
C. Components (7) to (10) are mixed and dissolved.
D. The remaining components (5) and (14) are mixed and dissolved.
E. FIG. C is added to D, mixed and dissolved, and A and B are further added and uniformly mixed.
F. Add (11) to (13) to E and mix.
G. FIG. F was filled into a container to obtain a hair gel.
[0040]
The hair gel of Example 9 has an excellent effect of preventing hair from oxidative damage due to light exposure and use of a dryer in addition to the hair styling power as a hair gel, and an effect of preventing discoloration of hair dyed with a hair dye. Was high.
[0041]
【The invention's effect】
The hair cosmetic composition of the present invention has an excellent effect of protecting the hair from oxidative damage due to sun exposure and use of a drier, an excellent effect of making the hair shiny and stiff, and preventing discoloration of dyed hair. It is extremely effective and has excellent quality as a hair cosmetic.

Claims (1)

The following components (a) and (b):
(A) one or more selected from mocca extract, peach extract, arhat extract,
(B) A hair cosmetic comprising one or more selected from a homopolymer of 2-methacryloyloxyethyl phosphorylcholine or a copolymer of 2-methacryloyloxyethyl phosphorylcholine and a hydrophobic monomer.