JP5788372B2 - Perm solution and hair conditioner - Google Patents

Description

  The present invention relates to a permanent solution that can impart gloss, firmness and moisture to the hair while suppressing damage to the hair when the hair is permanently treated, and to change the shape of the hair, decolorize or color the hair. It is related to a hair conditioner that can be added to the hair treatment agent for hair treatment, and can reduce the damage of the hair and give it gloss, firmness and moisture when treating the hair with the hair treatment agent. is there.

  The liquid for applying permanent to the hair (so-called permanent liquid) is for imparting wave to the head hair or correcting curly hair or crushed hair by oxidizing after reducing the head hair. However, since the perm solution exposes the hair to severe conditions such as reduction and oxidation, it tends to cause damage to the hair such as cuticle peeling, split ends, and broken hair. In addition, bleaching agents for decolorizing the hair are decolorized mainly by decomposing the melanin pigment in the hair by an oxidizing action by an oxidizing agent such as hydrogen peroxide. Like, it can damage your hair. Hair dyes, on the other hand, cause hair coloring by allowing the dye precursor to penetrate into the hair and oxidizing and polymerizing the dye precursor. Similarly, it may lead to hair damage. In addition, these hair treatment agents such as perm liquids, bleaching agents, and hair coloring agents may adversely affect the skin, such as rashes, by chemical action.

  In order to eliminate the damage to the hair and the adverse effects on the skin caused by such a hair treatment agent, as disclosed in Patent Document 1, a method of using a damage preventing component such as a protein hydrolyzate in combination with the hair treatment agent has been developed.

JP 2003-55169 A

  However, the above-mentioned hair treatment agent containing an ingredient for preventing damage such as protein hydrolyzate can alleviate the hair damage such as cuticle peeling, split ends, and cut hairs and adverse effects on the skin to some extent. However, the effect is not necessarily sufficient.

  The object of the present invention is to solve the problems of the above-mentioned conventional permanent liquid, suppress damage to the hair and adverse effects on the skin, and can effectively impart gloss, firmness and moisture to the hair, and is inexpensive. The object is to provide a practical perm solution that can be manufactured. In addition, the object of the present invention is to solve the problems of the conventional hair treatment agent described above, and by adding to the hair treatment agent, suppressing damage to the hair and adverse effects on the skin, the hair is glossy, firm and moisturized. An object of the present invention is to provide a practical hair conditioner that can be effectively applied and can be produced at low cost.

Among the present inventions, the invention described in claim 1 is a permanent liquid that is attached to the hair and changes the shape of the hair by winding the attached hair around a rod or the like, to which propolis and amino acids are added. In addition, the amino acid is a mixture of arginine, cysteine, lysine hydrochloride and threonine, the addition amount of amino acid is 0.1 to 5% by mass, and the addition ratio of propolis to amino acid is 20 to 500 %, And propolis is added by 0.01 to 15% by mass by diluting an ethanol extract having a solid concentration of 10 to 30% in an aqueous solvent.

The invention described in claim 2 is a hair conditioner to be added to a hair treatment agent for changing the shape of the hair, decolorizing or coloring the hair, and having added propolis and amino acids. The amino acid is a mixture of arginine, cysteine, lysine hydrochloride and threonine, the added amount of the amino acid is 0.5 to 7% by mass, and the addition ratio of propolis to the amino acid is 0.5 to 2 , 000%, and propolis is added by 0.01 to 10% by mass by diluting an ethanol extract having a solid content of 10 to 30% in an aqueous solvent. .

The invention described in claim 3 is the invention described in claim 2 , wherein the hair treatment agent is any one of a perm solution, a bleaching agent, a hair dye (a hair coloring agent or a hair dye), a treatment, or a conditioner. It is characterized by being.

  The permanent solution according to the present invention has good ridge coverage when the hair is permanently treated, and can suppress damage to the hair and impart sufficient gloss, firmness and moisture to the hair.

  In addition, the hair conditioner according to the present invention, when treating the hair with a hair treatment agent (permanent treatment, decoloring or coloring treatment), just adding to the hair treatment agent, suppressing damage to the hair, Sufficient luster, firmness and moisture can be given to the hair. That is, when the hair conditioner according to the present invention is added to the permanent solution, the ridge is improved, and the hair is glossy, firm and moist, and can be made supple. Moreover, when the hair conditioner according to the present invention is added to the hair dye, it can be finished in a good state with no color spots. Furthermore, when the hair conditioner according to the present invention is added to a bleaching agent or a hair dye, irritation to the skin during decolorization or hair dyeing can be suppressed. In addition, when the hair conditioner according to the present invention is added to a treatment or conditioner, the hair can be maintained in a supple state with gloss, firmness and moisture over a long period of time. In addition, once the hair is dried, it is possible to further impart luster, firmness and moisture to the hair by applying heat again with an iron or the like.

  The permanent liquid and hair conditioner according to the present invention are characterized by containing propolis and / or amino acids or derivatives thereof. The term “propolis” as used in the present invention refers to a sticky substance that a bee collects and uses for nesting various substances secreted by plants, and is a so-called bee crabs. The perm solution according to the present invention preferably contains 0.01 to 15% by mass of an extraction solution (ethanol solution or the like) having a solid content concentration of 10% to 30%, and 3.0 to 10% by mass. (Thus, the solid content concentration is preferably 0.001% to 4.5% by mass, more preferably 0.3% to 3.0% by mass. ). As the propolis extraction solution, it is most preferable to use an extraction solution having a solid concentration of about 20%. If the added amount of propolis is below the above range (solid content concentration is less than 0.001% by mass), it is not preferable because sufficient hair damage preventing effect, gloss, firmness and moisturizing effect cannot be obtained. If the added amount of propolis exceeds the above range (the solid content concentration exceeds 4.5% by mass), it is uneconomical and the feeling of stickiness of the hair becomes high, making it difficult to clean the hair. This is not preferable because the odor of the perm liquid becomes poor.

  The hair conditioner according to the present invention preferably contains 0.01 to 10% by mass, and 1.0 to 5% by mass of an extraction solution having a solid content concentration of propolis of 10% to 30%. More preferably, the solid content concentration is 0.001% by mass to 3.0% by mass, and more preferably 0.1% by mass to 1.5% by mass. As the propolis extraction solution, it is most preferable to use an extraction solution (such as an ethanol solution) having a solid concentration of about 20%. If the added amount of propolis is below the above range (solid content concentration is less than 0.001% by mass), it is not preferable because sufficient hair damage preventing effect, gloss, firmness and moisturizing effect cannot be obtained. If the added amount of propolis exceeds the above range (the solid content concentration exceeds 3.0% by mass), it is uneconomical and the feeling of stickiness of the hair becomes high, making it difficult to clean the hair. It is not preferable.

  In addition, the permanent liquid and hair conditioner according to the present invention may contain an amino acid or a derivative thereof as necessary. Examples of amino acids or derivatives thereof include alanine, arginine, asparagine, aspartic acid, cysteine, glutamine, glutamic acid, or derivatives thereof such as hydrochloride, sulfate, etc., but arginine, cysteine, lysine (or lysine) It is preferable to mix one or more of threonine and tryptophan, since it is possible to efficiently give gloss, firmness and moisture to the hair with a small amount. In addition, it is more preferable to use a mixture of threonine, cysteine, and arginine because gloss, elasticity and moisture can be imparted to the hair very efficiently. In addition, cysteine (L-cysteine), arginine (L-arginine), or a hydrochloride thereof (or one or a combination of two or more thereof) is used as an amino acid to be used with propolis in the perm solution according to the present invention. When used, it is more preferable because it can impart gloss, firmness and moisture to the hair very efficiently.

  The permanent liquid according to the present invention preferably contains 0.05 to 10% by mass, more preferably 0.1 to 5% by mass of the above-described amino acid or derivative thereof. If the content of the amino acid or its derivative is below the above range, synergy with propolis cannot be obtained, and it is not preferable because sufficient hair damage prevention effect, gloss, firmness and moisturizing effect cannot be obtained, If the content of the amino acid or derivative thereof exceeds the above range, it is not preferable because it is uneconomical and may damage hair.

  Moreover, it is preferable to contain 0.3-15 mass% of the above-mentioned amino acid or its derivative (s) in the hair conditioner which concerns on this invention, and it is more preferable to contain 0.5-7 mass%. If the content of the amino acid or its derivative is below the above range, synergy with propolis cannot be obtained, and it is not preferable because sufficient hair damage prevention effect, gloss, firmness and moisturizing effect cannot be obtained, If the content of the amino acid or derivative thereof exceeds the above range, it is not preferable because it is uneconomical and may damage hair.

  On the other hand, the addition ratio of propolis to amino acid in the perm solution according to the present invention is not particularly limited, but if the addition ratio is 0.5 to 2,000%, it is very good due to the synergistic effect of propolis and amino acid. It is preferable because the effect of preventing damage to hair and the effect of imparting luster, firmness and moisture can be obtained, and more preferably 20 to 500%.

  In addition, the ratio of the propolis to the amino acid in the hair conditioner according to the present invention is not particularly limited, but if the ratio is 0.5 to 2,000%, the permanent action is caused by the synergistic effect of the propolis and the amino acid. In addition to being good, the effect of preventing damage to the hair and the effect of imparting gloss, firmness and moisture can be obtained, and it is more preferably 100 to 500%.

  Furthermore, the permanent liquid and hair conditioner according to the present invention include various alcohols, fermented alcohols, glycols (such as butyl glycol), extracts extracted from plants, preservatives, fragrances, viscosity modifiers as necessary. It is also possible to add a pH adjusting agent or the like. Furthermore, a moisturizing agent (moisture adjusting agent) such as hyaluronic acid (particularly high molecular hyaluronic acid) or the like can be added to the permanent liquid and hair conditioning agent according to the present invention as necessary. In addition, when adding hyaluronic acid to the permanent liquid and hair conditioner according to the present invention, the amount of addition is not particularly limited, but if it is 0.005 to 5% by mass, the moisture retention and economic efficiency of the hair From the viewpoint of, it is more preferable that it is 0.05-2 mass%.

  Furthermore, in the permanent liquid according to the present invention, it is possible to add amines such as isopropanolamine and triethanolamine, if necessary, in order to make the degree of permanent application better. Triethanolamine is more preferable because it can maintain a state of less irritation to the skin. Moreover, it is also possible to use AMPD (2-amino-2-methyl-1,3-propanediol) instead of triethanolamine. The addition amount of amines and AMPD is not particularly limited, but it is preferably 1 to 10% by mass because it causes less irritation to the skin. In addition, various shampoos (so-called protective shampoos and the like) can be added to the permanent liquid according to the present invention.

  Furthermore, the hair conditioner according to the present invention can be added to various hair treatment agents such as perm solution, hair coloring agent, bleaching agent, shampoo, treatment, conditioner and the like. In addition, the addition amount to the hair treatment agent of the hair conditioner according to the present invention is not particularly limited, but the addition amount is preferably 1 to 40% by mass, and more preferably 5 to 20% by mass. If the amount of hair conditioner added to the hair treatment agent is below the above range, it is not preferable because sufficient hair damage preventing effect, gloss, firmness and moisturizing effect cannot be obtained. If the amount added to the hair treatment agent exceeds the above range, it is not preferable because it is uneconomical and the feeling of stickiness of the hair becomes high, making it difficult to clean the hair.

  In addition, the method of applying permanent treatment to the hair using the permanent liquid according to the present invention is not particularly limited, and a digital permanent with heating at around 100 ° C. or a straight permanent using an iron heated at around 180 ° C. In addition, various methods such as air wave, creep perm, aqua perm, water perm (moist perm), and system curl can be used.

  Hereinafter, the permanent liquid and the hair conditioner according to the present invention will be described in more detail with reference to examples. However, the present invention is not limited to the embodiments of the examples and does not depart from the spirit of the present invention. Thus, it can be changed as appropriate. Moreover, the evaluation methods of physical properties and characteristics in the examples are as follows. In the following sensory evaluations, the average stage (◎, ○, Δ, ×) of the evaluation results for the three subjects was used as the final evaluation result.

<Damage to hair>
Perm was applied to the hair of three subjects by the method described later, and the damaged state of the hair after perm was subjected to sensory evaluation in the following four stages by a beautician.
A: No damage to the hair such as exfoliation of the cuticle, split ends, and cut hairs, and the hair has sufficient luster, firmness and moisture.
○: Hair damage such as cuticle peeling, split ends and cut hair is hardly seen, and the hair has gloss, firmness and moisture.
Δ: Cuticle peeling, split hairs, broken hairs and other hair damages are observed, and the hairs are not glossy, firm or moist.
X: Many damages to the hair such as peeling of the cuticle, split ends, and cut hairs were observed, and there was almost no gloss, firmness or moisture on the hair.

<Decolorization of hair>
Perm was applied to the hair of three test subjects by the method described later, and the decolored state of the hair after perm was subjected to sensory evaluation in the following three stages by a hairdresser.
○: No decolorized part is seen in the hair.
(Triangle | delta): A decoloring part is scattered on hair.
X: Many decoloring parts are seen in the hair.

<Degree of perm>
The condition of the ridges (waves) of the hair after the perm of three subjects was sensorially evaluated by the hairdresser in the following three stages.
○: Perm is sufficiently applied.
Δ: Perm is weak.
X: Perm is very weak.

<Skin irritation>
The sensory evaluation of the skin irritation felt by the subjects when the permanent hair was applied to the hair of three subjects was evaluated in the following three stages.
○: I hardly feel any irritation.
Δ: Slight irritation is felt.
X: I feel pain.

<Perm liquid smell>
Sensory evaluation of the odor of the perm solution with the permanent applied to the subject was performed in the following three stages.
○: No particular bad odor is felt.
Δ: A slight odor is felt.
X: A bad smell is felt.

<State after decolorization>
The hair of three test subjects was decolorized with a bleaching agent according to the method described later, and the state of the hair after decolorization was sensory-evaluated in the following three stages by a hairdresser.
○: No damage to the hair such as exfoliation of the cuticle, split ends or cut hairs, and gloss, firmness and moisture remain on the hair.
Δ: Cuticle peeling, split hairs, broken hairs and other hair damages are observed in some cases, and gloss, firmness and moisture do not remain in the hairs.
X: Many hair damages such as exfoliation of cuticles, split ends and cut hairs were observed, and gloss, firmness and moisture did not remain on the hair.

<Skin irritation>
When the hair of three subjects was decolorized with a bleaching agent, the skin irritation felt by the subjects was subjected to sensory evaluation in the following three stages.
○: I hardly feel any irritation.
Δ: Slight irritation is felt.
X: I feel pain.

<State after hair dyeing>
After the hair of three test subjects was dyed with a hair dye by the method described later, the state of the hair after dyeing was subjected to sensory evaluation in the following three stages by a hairdresser.
◯: No cuticle peeling, split hair, broken hair, or other hair damage was observed, and the hair had gloss, firmness and moisture.
Δ: Cuticle peeling, split hairs, broken hairs, and other damage to the hair are observed, and the hair is not glossy, firm, or moist.
X: Many damages to the hair such as peeling of the cuticle, split ends, and cut hairs were observed, and there was almost no gloss, firmness or moisture on the hair.

<Dyed hair spots>
After the hair of three subjects was dyed with a hair dye, the hair dyeing state of the hair after dyeing was subjected to sensory evaluation in the following three stages by a hairdresser.
○: There is no dyed spots, and the dyeing is neatly and uniformly.
Δ: Slightly dyed spots are observed.
X: Many dyed spots are seen.

[Example 1]
<Preparation of hair conditioner>
The following components were mixed at room temperature to obtain hair conditioner A.
L-lysine hydrochloride: 0.10% by mass
L-threonine: 0.05% by mass
L-cysteine: 0.75% by mass
L-arginine: 0.10% by mass
・ Plant extract (Clara leaf extract, ginger root extract, Senkyo rhizome extract, Toki root extract, peach leaf extract, Panax ginseng extract, ethanol, purified water mixed solution): 0.5% by mass
・ Adsorption-type hyaluronic acid: 0.03 mass%
・ Soybean seed extract: 0.20% by mass
-Liquid hyaluronic acid (hyaluronic acid Na, methylparaben, purified water mixed solution): 0.5% by mass
・ 95% fermented alcohol: 30.00% by mass
Propolis (ethanol extract with a solid content of 20%): 0.50% by mass
-Fragrance: 0.50% by mass
-Antibacterial agent (ethoxydiglycol, phenoxyethanol, methylparaben, propylparaben, butylparaben, ethylparaben mixed solution): 0.10% by mass
・ Butyl glycol: 30.00 mass%
・ Purified water: remaining amount

<Preparation of perm solution>
A liquid having the following composition was prepared as the first agent.
L-cysteine hydrochloride: 4.85% by mass
N-acetyl-L-cysteine: 2.35% by mass
・ Isopropanolamine: 2.50% by mass
・ Sodium carbonate: 2.50 mass%
L-arginine: 0.10% by mass
-Trisodium edetate: 0.10% by mass
・ Polyoxyethylene sorbitan monooleate (20E.O.): 1.20% by mass
-Fragrance: 0.80% by mass
Palm oil fatty acid amidopropyl betaine: 2.02% by mass
・ Purified water: remaining amount

Moreover, the liquid of the following compositions was prepared as a 2nd agent.
・ Sodium bromate: 4.00% by mass
-Sodium monohydrogen phosphate: 0.10% by mass
・ Sodium dihydrogen phosphate: 0.10% by mass
Palm oil fatty acid amidopropyl betaine: 0.50% by mass
・ Sodium benzoate: 0.30% by mass
・ Polyoxyethylene sorbitan monooleate (20E.O.): 0.30% by mass
-Fragrance: 0.20% by mass
-Aminoethylpropylsiloxane-Dimethylsiloxane: 0.10% by mass
..Polyoxyethylene lauryl ether: 0.01% by mass
・ Purified water: remaining amount

<Application of perm solution>
By adding the hair conditioner A prepared as described above to the first agent and the second agent obtained as described above so as to have a ratio of 10% by mass with respect to each perm liquid, Examples 1 modified perm liquid (first modifying agent and second modifying agent) was prepared. Then, after the first modifier was attached to the hair, the hair was shaped by blowing with a dryer as it was without washing the hair, and adjusting the hairstyle while applying heat at about 80 ° C. with an iron or a heating rod. Further, a second modifier was attached to the hair to regenerate the cut disulfide bonds and salt bonds, thereby giving the hair a permanent shape. Thereafter, the hair was washed with a commercially available shampoo, heated at about 80 ° C. with a dryer to dry the hair, and then the condition after permanent was evaluated according to the above evaluation criteria. The evaluation results are shown in Table 1.

[Example 2]
When preparing the hair conditioner, the mixing ratio of propolis was changed to 0.30% by mass (the weight ratio of purified water was also changed). Other than that, hair conditioner B was prepared in the same manner as hair conditioner A in Example 1. Thereafter, the hair conditioner B is added to the same first agent and second agent as in Example 1 so that the ratio is 10% by mass with respect to each permanent liquid. Modified perm liquid (first modifier and second modifier) was prepared. Then, after the first modifier of Example 2 is attached to the subject's hair in the same manner as in Example 1 and the hair is heated, the second modification of Example 2 is performed in the same manner as in Example 1. After the material was attached to the subject's hair, the hair was washed and dried. And the state after permanent was evaluated by the same evaluation criteria as Example 1. The evaluation results are shown in Table 1.

[Example 3]
When preparing the hair conditioner, the mixing ratio of propolis was changed to 3.00% by mass (the weight ratio of purified water was also changed). Other than that, hair conditioner C was prepared in the same manner as hair conditioner A in Example 1. Thereafter, the hair conditioner C is added to the same first agent and second agent as in Example 1 so that the ratio is 10% by mass with respect to each permanent liquid. Modified perm liquid (first modifier and second modifier) was prepared. Then, after the first modifier of Example 3 is attached to the subject's hair in the same manner as in Example 1 and the hair is heated, the second modification of Example 3 is performed in the same manner as in Example 1. After the material was attached to the subject's hair, the hair was washed and dried. And the state after permanent was evaluated by the same evaluation criteria as Example 1. The evaluation results are shown in Table 1.

<Comparative Example 1>
After heating the hair by attaching the first agent obtained by the same method as in Example 1 as it is (without adding a hair conditioning agent) to the subject's hair in the same manner as in Example 1, The second agent obtained by the same method as in Example 1 was directly attached to the subject's hair (without adding a hair conditioning agent), and then the hair was washed and dried. And the state after permanent was evaluated by the same evaluation criteria as Example 1. The evaluation results are shown in Table 1.

[Example 1 ']
<Preparation of hair conditioner>
The following components were mixed at room temperature to obtain hair conditioner D.
L-cysteine: 1.00% by mass
Plant extract (same as Example 1): 0.5% by mass
Adsorption type hyaluronic acid (same as in Example 1): 0.03% by mass
Soybean seed extract (same as Example 1): 0.20% by mass
Liquid hyaluronic acid (same as in Example 1): 0.50% by mass
・ 95% fermented alcohol: 30.00% by mass
Propolis (same as in Example 1): 0.50% by mass
-Fragrance: 0.50% by mass
Antibacterial agent (the same as Example 1): 0.20% by mass
・ Butyl glycol: 30.00 mass%
・ Purified water: remaining amount

  Thereafter, the hair conditioner D is added to the same first agent and second agent as in Example 1 so as to have a ratio of 10% by mass with respect to each permanent liquid, thereby causing Example 1 ′. The modified perm solution (first modifier and second modifier) was prepared. And after attaching the 1st modifier of Example 1 'to a test subject's hair by the method similar to Example 1, and heating a head hair, it is the method similar to Example 1, and the 1st modifier of Example 1'. After the two modifiers were attached to the subject's hair, the hair was washed and dried. And the state after permanent was evaluated by the same evaluation criteria as Example 1. The evaluation results are shown in Table 1.

[Example 1]
<Preparation of hair conditioner>
A hair conditioner E was obtained by mixing the following components at room temperature.
L-arginine: 1.25% by mass
Plant extract (same as Example 1): 0.5% by mass
Adsorption type hyaluronic acid (same as in Example 1): 0.03% by mass
Soybean seed extract (same as Example 1): 0.20% by mass
Liquid hyaluronic acid (same as in Example 1): 0.50% by mass
・ 95% fermented alcohol: 30.00% by mass
Propolis (same as in Example 1): 0.50% by mass
-Fragrance: 0.50% by mass
Antibacterial agent (the same as Example 1): 0.20% by mass
・ Butyl glycol: 30.00 mass%
・ Purified water: remaining amount

  Thereafter, the hair conditioner E is added to the same first agent and second agent as in Example 1 so as to have a ratio of 10% by mass with respect to each permanent solution, thereby causing Example 1 ”. A modified perm solution (first modifying agent and second modifying agent) was prepared, and the first modifying agent of Example 1 ″ was attached to the subject's hair in the same manner as in Example 1. After the hair was heated, the second modifier of Example 1 ″ was attached to the subject's hair in the same manner as in Example 1, and then the hair was washed and dried. The condition after permanent was evaluated according to the same evaluation criteria, and the evaluation results are shown in Table 1.

[Example 4]
<Preparation of bleaching agent>
A liquid having the following composition was prepared as the first bleaching agent.
・ Polyoxyethylene (10) hydrogenated castor oil: 2.0% by mass
Cetyl alcohol: 4.0% by mass
Polyoxyethylene (20) cetyl ether: 2.0% by mass
・ Oleyl alcohol: 1.0% by mass
Stearyl trimethyl ammonium chloride: 1.0% by mass
・ 1,3-Butylene glycol: 3.0% by mass
-0.1M edetate disodium: 3.0% by mass
・ 25% ammonia water: 0.5% by mass
-Monoethanolamine: 0.5% by mass
-Purified water: 63.0% by mass

Moreover, the liquid of the following compositions was prepared as a 2nd bleaching agent.
・ 33 mass% hydrogen peroxide solution: 10.0 mass%
・ Purified water: 10.0% by mass

  Then, a mixed bleaching agent was prepared by mixing 80% by mass of the first bleaching agent and 20% by mass of the second bleaching agent. Thereafter, to the mixed bleaching agent, hair conditioning agent A obtained by the same method as in Example 1 was added so that the proportion was 10% by mass with respect to the mixed bleaching agent. The modified bleaching agent was adjusted.

<Application of bleaching agent>
In a room temperature room, the subject's neck was wiped with a wet towel to remove sebum stains and left for 5 minutes. Thereafter, the prepared modified bleaching agent was attached to the hair of the entire subject's head, and was allowed to stand for a certain time, and then the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after decoloring and the irritation | stimulation to skin. The evaluation results are shown in Table 1.

[Example 5]
To the bleaching agent obtained in the same manner as in Example 4, the hair conditioning agent B obtained in the same manner as in Example 2 is added so that the proportion becomes 10% by mass with respect to the bleaching agent. Thus, the modified bleaching agent of Example 5 was prepared. Thereafter, the prepared modified bleach was attached to the hair of the entire subject's head. And the above-mentioned evaluation criteria evaluated the state after decoloring and the irritation | stimulation to skin. The evaluation results are shown in Table 1.

[Example 6]
To the mixed bleaching agent obtained in the same manner as in Example 4, the hair conditioning agent C obtained in the same manner as in Example 3 is added so that the proportion becomes 10% by mass with respect to the bleaching agent. Thus, the modified bleaching agent of Example 6 was prepared. Thereafter, the prepared modified bleach was attached to the hair of the entire subject's head. And the above-mentioned evaluation criteria evaluated the state after decoloring and the irritation | stimulation to skin. The evaluation results are shown in Table 1.

<Comparative Example 2>
The mixed bleaching agent obtained in the same manner as in Example 4 was directly attached to the subject's hair in the same manner as in Example 4 (without adding a hair conditioning agent) and left for a certain period of time. The hair was washed and dried. And the evaluation criteria similar to Example 1 evaluated the state after decoloring and the irritation | stimulation to skin. The evaluation results are shown in Table 1.

[Example 7]
<Preparation of hair dye>
A liquid having the following composition was prepared as the first hair dye.
・ 28% by mass ammonia water: 3.0% by mass
・ Ethanolamine: 1.5% by mass
-Ammonium bicarbonate: 0.3% by mass
-Paraphenylenediamine: 0.1% by mass
-Paraaminophenol: 0.2% by mass
・ Paraaminoorthocresol: 0.4% by mass
Decylglucoside: 4.0% by mass
・ Laureth-11 Na acetate: 4.0% by mass
・ Laureth-20: 2.0% by mass
・ Myristyl alcohol: 0.2% by mass
Propylene glycol: 4.0% by mass
・ Ethanol: 9.5% by mass
-Fragrance: 0.5% by mass
・ Purified water: remaining amount

Moreover, the liquid of the following compositions was prepared as a 2nd hair dye.
・ 35% by mass hydrogen peroxide solution: 16.3% by mass
・ Cocole glutamate Na: 0.5% by mass
・ Cetanol: 0.5% by mass
-Etidronic acid: 0.1% by mass
48% by weight aqueous sodium hydroxide solution: PH = 3.5 Adjustable amount Purified water: remaining

  Then, in a room temperature room, the 40% by mass of the first hair dye and 60% by mass of the second hair dye obtained as described above were placed in a squeeze foamer container (a nylon container with an internal volume of 150 ml, Yamato Seisakusho). To obtain a mixed hair dye. Thereafter, the hair conditioner A obtained in the same manner as in Example 1 was added so as to have a mixing ratio of 10% by weight with respect to the mixed hair dye. A hair dye was prepared.

<Application of hair dye>
Then, the modified hair dye was discharged in the form of foam and adhered to the hair, and 80 g was adhered to the entire hair while repeating the work of foaming again for 2 seconds at the adhered portion. After that, the lathering operation was performed again for 15 seconds, and after standing for a certain time (20 minutes), the hair was rinsed, shampooed and rinsed, and then the hair was dried. And the above-mentioned evaluation criteria evaluated the state after hair dyeing, the hair spot, and the irritation | stimulation to skin. The evaluation results are shown in Table 1.

[Example 8]
The hair conditioner B obtained by the same method as in Example 2 is mixed with the hair dye obtained by the same method as in Example 7 so that the ratio becomes 10% by mass with respect to the mixed hair dye. The modified hair dye of Example 8 was prepared by adding to. Thereafter, the prepared modified hair dye is attached to the hair of the entire subject's head in the same manner as in Example 7, and after standing for a certain period of time, the hair is rinsed, shampooed, rinsed, and then the hair. Was dried. And the above-mentioned evaluation criteria evaluated the state after hair dyeing, the hair spot, and the irritation | stimulation to skin. The evaluation results are shown in Table 1.

[Example 9]
The hair conditioner C obtained by the same method as in Example 3 is mixed with the hair dye obtained by the same method as in Example 7 at a ratio of 10% by mass with respect to the mixed hair dye. The modified hair dye of Example 9 was prepared by adding to Thereafter, the prepared modified hair dye is attached to the hair of the entire subject's head in the same manner as in Example 7, and after standing for a certain period of time, the hair is rinsed, shampooed, rinsed, and then the hair. Was dried. And the above-mentioned evaluation criteria evaluated the state after hair dyeing, the hair spot, and the irritation | stimulation to skin. The evaluation results are shown in Table 1.

<Comparative Example 3>
The mixed hair dye obtained by the same method as in Example 1 was allowed to adhere to the hair of the entire subject's head in the same manner as in Example 7 without adding the hair conditioner (fixed). After standing for a period of time, the hair was rinsed, shampooed and rinsed, and then the hair was dried. And the above-mentioned evaluation criteria evaluated the state after hair dyeing, the hair spot, and the irritation | stimulation to skin. The evaluation results are shown in Table 1.

[Example 10]
The following components were mixed at room temperature to obtain a permanent solution of Example 10.
Propolis (same as Example 1): 3.0% by mass
-Purified water: remaining amount Then, after the perm liquid of Example 10 prepared was attached to the hair, it was blown with a drier as it was without washing the hair, and heat of about 80 ° C was applied with an iron or a heating rod. A regular shape was given to the hair by arranging the hairstyle. After that, after washing the hair with a commercially available shampoo and drying the hair by applying heat of about 80 ° C. with a dryer, the condition after the permanent, the degree of perm, the stimulation to the hair according to the above evaluation criteria. The decolorization state of the hair was evaluated. The evaluation results are shown in Table 2.

[Example 11]
The perm liquid of Example 11 was obtained by mixing the following components at room temperature.
L-cysteine hydrochloride: 1.0% by mass
Propolis (same as Example 1): 3.0% by mass
Purified water: remaining amount Thereafter, using the prepared permanent solution of Example 11, permanent hair was applied in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 12]
The following components were mixed at room temperature to obtain a permanent solution of Example 12.
L-cysteine hydrochloride: 1.0% by mass
L-arginine hydrochloride: 1.0% by mass
Propolis (same as Example 1): 3.0% by mass
-Purified water: The remaining amount was then permanently applied to the hair in the same manner as in Example 10 using the prepared permanent liquid of Example 12, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 13]
A perm solution of Example 13 was obtained by mixing the following components at room temperature.
L-arginine hydrochloride: 1.0% by mass
Propolis (same as Example 1): 3.0% by mass
-Purified water: remaining amount Thereafter, using the prepared permanent liquid of Example 13, permanent hair was applied in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 14]
The following components were mixed at room temperature to obtain a permanent solution of Example 14.
L-cysteine hydrochloride: 2.0% by mass
Propolis (same as Example 1): 7.0% by mass
-Purified water: remaining amount Thereafter, using the prepared permanent liquid of Example 14, the hair was permanently treated in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 15]
The following components were mixed at room temperature to obtain a permanent solution of Example 15.
L-cysteine hydrochloride: 1.0% by mass
Propolis (same as Example 1): 1.8% by mass
-Purified water: remaining amount Thereafter, using the prepared permanent liquid of Example 15, permanent hair was applied in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 16]
A permanent solution of Example 16 was obtained in the same manner as Example 10 except that the mixing ratio of propolis was changed to 1.5% by mass. Then, using the prepared permanent liquid of Example 16, permanent hair was applied to the hair in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 17]
A permanent solution of Example 16 was obtained in the same manner as Example 10 except that the mixing ratio of propolis was changed to 15.0% by mass. Then, using the prepared permanent liquid of Example 16, permanent hair was applied to the hair in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 18]
The following components were mixed at room temperature to obtain a permanent solution of Example 18.
L-cysteine (non-hydrochloride): 1.0% by mass
L-arginine (non-hydrochloride): 1.0% by mass
Propolis (same as Example 1): 3.0% by mass
-Purified water: remaining amount Thereafter, using the prepared permanent solution of Example 18, the hair was permanently treated in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 19]
The perm liquid of Example 19 was obtained by mixing the following components at room temperature.
L-cysteine (non-hydrochloride): 0.1% by mass
L-arginine (non-hydrochloride): 0.1% by mass
Propolis (same as Example 1): 10.0% by mass
Purified water: remaining amount Thereafter, using the prepared permanent liquid of Example 19, permanent hair was applied in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

[Example 20]
The following components were mixed at room temperature to obtain a permanent solution of Example 20.
L-cysteine hydrochloride: 1.0% by mass
L-arginine hydrochloride: 1.0% by mass
・ AMPD: 5.0% by mass
Propolis (same as Example 1): 3.0% by mass
-Purified water: remaining amount Thereafter, using the prepared permanent solution of Example 20, permanent hair was applied in the same manner as in Example 10, and the hair was washed and dried. And the above-mentioned evaluation criteria evaluated the state after permanent, the degree of perm application, the stimulation to the hair, the decolored state of the hair, and the like. The evaluation results are shown in Table 2.

  From Table 1, the hair conditioner is added to the perm solution, and the hair damage after treatment (after permanent or after hair dyeing) is suppressed compared with the case where it is added to the hair dye and not to the hair dye. It can be seen that the hair can be given gloss, firmness and moisture. In addition, it can be seen that when the hair conditioning agent is added to the bleaching agent, the hair damage after treatment (after decoloring) is less, and the gloss and firmness of the hair can be maintained as compared with the case where the hair conditioning agent is not added. In addition, it can be seen that when the hair conditioner is added to the hair dye, the hair can be uniformly dyed with less hair spots than when it is not added. In addition, when the hair conditioner is added to the bleaching agent, there is less irritation to the skin during treatment (during decoloring or hair dyeing) than when it is added to the hair dye and when it is not added. I understand that I can do it.

  Also, from Table 2, the permanent solution according to the present invention does not irritate the skin during permanent compared to a normal permanent solution containing no propolis and amino acids, suppresses damage to the hair after permanent, It can be seen that gloss, firmness and moisture can be imparted.

  Since the permanent liquid according to the present invention has excellent effects as described above, it can be suitably used as a permanent liquid that does not damage the hair. Further, since the hair conditioner according to the present invention has excellent effects as described above, it is an auxiliary agent to be added to hair treatment agents such as perm solution, bleaching agent, hair dye, shampoo, treatment, conditioner and the like. Can be suitably used.

Claims (3)

A permanent solution that changes the shape of the hair by attaching it to the hair and wrapping the attached hair around a rod or the like,
Propolis and amino acids are added,
The amino acid is a mixture of arginine, cysteine, lysine hydrochloride and threonine,
The amount of amino acid added is 0.1 to 5% by mass,
The addition ratio of propolis to amino acid is 20 to 500%, and
A permeic solution, wherein propolis is added by 0.01 to 15% by mass by diluting an ethanol extract having a solid content concentration of 10 to 30% in an aqueous solvent. A hair conditioner to be added to a hair treatment agent for changing the shape of the hair or decolorizing or coloring the hair,
Propolis and amino acids are added,
The amino acid is a mixture of arginine, cysteine, lysine hydrochloride and threonine,
The amount of amino acid added is 0.5-7% by mass,
The addition ratio of propolis to amino acid is 0.5 to 2,000%, and
A hair conditioner characterized in that propolis is added by 0.01 to 10% by mass by diluting an ethanol extract having a solid content concentration of 10 to 30% in an aqueous solvent.   The hair conditioner according to claim 2, wherein the hair treatment agent is one of a perm solution, a bleaching agent, a hair dye, a shampoo, a treatment, and a conditioner.