JP2006282566A - Hair-dressing preparation - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a hair-dressing preparation giving hair-setting ability and good feeling in use, and also having excellent hair-repairing effect on damaged hair in particular. <P>SOLUTION: The hair-dressing preparation is obtained by compounding (a) 0.001-10 mass% of an ester-type cationic surfactant having a specific structure, (b) 0.001-10 mass% of a hair-repairing component and (c) 0.1-20 mass% of a hair-setting agent. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a hair styling agent containing a specific cationic surfactant, a hair repair component, and a hair setting agent. More specifically, the present invention relates to an excellent feeling of use (stiffness at finish, flexibility, The present invention relates to a hair styling composition having a setting force) and an excellent hair repair effect.

Conventionally, hair setting agents such as resins and polymers have been used for hair styling products in order to maintain hair styling. For example, various polymers such as anionic, amphoteric, cationic, and nonionic are used, and these can be used individually or depending on the characteristics of the product, such as the strength and flexibility of the membrane and the speed of drying. Have been used in combination. However, when a large amount of a set agent is blended in order to realize a higher setting effect, there are cases where the finished hair is stiff or lacks flexibility. Therefore, various oil agents and cationic surfactants have been blended in order to improve the feel of the hair as long as the setting effect is not impaired.
Among these, cationic surfactants have been widely used because they have excellent adsorptivity to hair, and have a high effect of imparting flexibility and flexibility to hair even on the touch surface. Specifically, alkyl type quaternary ammonium salts such as stearyltrimethylammonium chloride and distearyldimethylammonium chloride have been used.

  On the other hand, recently, an ester-type cationic surfactant having an ester structure excellent in biodegradability in the molecule has been used. (For example, refer to Patent Documents 1 to 5).

JP 2002-255751 A Special Table 2002-505253 Japanese translation of PCT publication No. 2002-527373 JP 2002-293719 A Japanese translation of PCT publication No. 2003-51695

However, although ester-type cationic surfactants have the property of being excellent in biodegradability, hair conditioning effects are not sufficient when mixed alone with various set agents, especially for hair color and hair bleaching. The actual situation is that it is difficult to obtain sufficient effects of improving the feeling of use, such as stiffness and flexibility, for hair having a high degree of damage to the hair, such as applied damaged hair.
As described above, the problem to be solved by the present invention is to solve the problem that a hair styling compounded with an ester-type cationic surfactant could not have an excellent feeling of use and a hair repair effect. That is.

  In view of such a situation, the present inventors have intensively studied, and as a result, a specific ester-type cationic surfactant, a hair repair component, and a hair set agent are blended in specific amounts, respectively, so that excellent usability and excellent hair are obtained. The inventors have found that a hairdressing material having a repair effect can be obtained, and have completed the present invention.

That is, the present invention includes the following components (a) to (c);
(A) The following general formula (1)

Wherein R ² is an aliphatic acyl group having 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, n = 2 or 3, and X is a halogen compound, methosulfate or metho 0.001 to 10% by mass of a cationic surfactant represented by phosphate)
(B) Hair repair component 0.001-10 mass%
(C) Hair setting agent 0.1-20% by mass
Is a hair styling characterized by blending.
Furthermore, it is the said hair styling characterized by mix | blending a component (d) propellant.

  The hairdressing material of the present invention has an excellent feeling of use (no stiffness at the time of finishing, flexibility, setting power) and an excellent hair repair effect.

  The following general formula (1) of the component (a) used in the hair dressing of the present invention

Wherein R ² is an aliphatic acyl group having 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, n = 2 or 3, and X is a halogen compound, methosulfate or metho The cationic surfactant represented by (phosphate) can be used as a surfactant alone or as a composition containing other components.
DEHYQUAT L80 (manufactured by Cognis) containing 80% dicocoylethylhydroxyethylmonium methosulphate as a composition containing other components and containing propylene glycol as another component, 75 containing distearoylethylhydroxyethylmonium methosulphate DEHYQUART F75 (manufactured by Cognis) containing 90% of cetostearyl alcohol as another component, 90% of dipalmitoylethylhydroxyethylmonium methosulphate, and containing isopropyl alcohol as another component, DEHYQUAT AU56 / G ( Cognis), 25% dipalmitoylethylhydroxyethylmonium methosulfate, cetostearyl alcohol, POE (20) cetostearyl as other ingredients Containing ether, such as DEHYQUART C4046 (manufactured by Cognis) are commercially available.

  In the hair styling composition of the present invention, the component (a) is blended in order to impart conditioning effects such as suppleness and moistness to the hair, and to reduce the feeling of stiffness due to the set agent, and is biodegradable. Is also excellent.

  The blending amount of the component (a) in the hair styling of the present invention is 0.001 to 10% by mass (hereinafter simply referred to as “%”), and 0.01 to 5% to obtain an excellent feeling of use. Is more preferable. When component (a) is blended in this range, a hair styling that is particularly excellent in use feeling can be obtained.

The hair repair component of the component (b) used in the hair styling composition of the present invention is a component that cares for damaged parts of the hair surface or inside, such as amino acids, amino acid derivatives, peptides, saccharides and the like Derivatives, hair lipid components, phospholipids and derivatives thereof, plant extracts containing these components, and the like.
Specifically, examples of amino acids include glycine, alanine, valine, isoleucine, serine, threonine, aspartic acid, glutamic acid, asparagine, glutamine, lysine, hydroxylysine, arginine, cystine, cysteine, acetylcysteine, methionine, phenylalanine, Examples include tyrosine, proline, hydroxyproline, ornithine, citrulline, and theanine. As amino acid derivatives, N-lauroyl-L-glutamate di (phytosteryl 2-octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl behenyl octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl Octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl), N-lauroyl-L-glutamate di (2-octyldodecyl), and the like. Peptides may be derived from animals, fish, shellfish, plants, and specifically, collagen and derivatives thereof or hydrolysates thereof, elastin and derivatives thereof or hydrolysates thereof, keratin and derivatives thereof or the like. Degradation products, wheat proteins and derivatives thereof or hydrolysates thereof, soybean proteins and derivatives or hydrolysates thereof, and the like. Examples of the saccharide include sorbitol, erythritol, maltose, maltitol, xylitol, xylose, trehalose, inositol, glucose, mannitol, pentaerythritol, fructose, sucrose and esters thereof, dextrin and derivatives thereof, honey, brown sugar extract and the like. . Examples of the hair lipid component include ceramide and derivatives thereof, 18-methyleicosanoic acid and the like. Examples of phospholipids and their derivatives include phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids, and the like, or compositions containing these, i.e., soy lecithin, egg yolk Examples include lecithin or hydrogenated products thereof, and examples of the phospholipid derivative include a homopolymer of 2-methacryloyloxyethyl phosphorylcholine or a copolymer of 2-methacryloyloxyethyl phosphorylcholine and a hydrophobic monomer. . One or two or more of these may be appropriately selected or combined.

  In the hair styling composition of the present invention, the component (b) gives a harshness, elasticity and hair repair effect at the time of use, and in combination with the component (a) synergistically feels the stiffness due to the hair set agent. It is included for improvement.

  The compounding quantity of the component (b) in the hairdressing material of this invention is 0.001 to 10%, and 0.01 to 5% is more preferable in order to obtain a particularly excellent usability. When the component (b) is blended in this range, a hair styling agent having excellent use time and particularly excellent hair repair effect can be obtained.

  The hair setting agent of component (c) used in the hairdressing material of the present invention is a component for obtaining a setting effect in the hairstyling material, and is a component formulated for the purpose of adjusting and maintaining the hair in the desired shape. These are classified into anionic polymer, amphoteric polymer, nonionic polymer, cationic polymer, etc., depending on the ionicity in the solution. In the present invention, the component (c) is usually not particularly limited as long as it is a polymer that can be used as a set agent in a hairdressing agent, and any of the above ionic ones may be used, and one or two or more may be appropriately selected and used. Can do.

  Examples of the anionic polymer include acrylic acid / ethyl acrylate / N-tert-butylacrylamide copolymer, acrylic resin alkanolamine, vinyl methyl ether / ethyl maleate copolymer, vinyl methyl ether / butyl maleate copolymer Polymers, vinyl acetate / crotonic acid copolymers, etc., Ultrahold series (BASF), plus size L-6330 (Kyoto Chemical Co., Ltd.), Ganzlet ES series (ISP), Ruby Set CA (BASF) Commercially available products such as those manufactured by the company) can be used.

  As amphoteric polymers, N-methacryloylethyl N, N-dimethylammonium / α-N-methylcarboxybetaine / alkyl methacrylate copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide copolymer Examples include acrylic acid / dimethyldiallylammonium chloride / acrylamide copolymer, dimethyldiallylammonium chloride / acrylic acid copolymer, Yuka Former series (Mitsubishi Chemical Co., Ltd.), Amphomer series (National Starch) Commercial products such as Marquat Plus 3330 and Marquat 280 (Calgon) can be used.

  As cationic polymers, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate, diallyldimethylammonium chloride / hydroxyethylcellulose, glycidyltrimethylammonium chloride / hydroxyethylcellulose, dimethyldiallylammonium chloride polymer, dimethyl chloride Examples include diallylammonium acrylamide copolymer, Guffcoat 734, 755 (made by ISP), Polymer JR series (made by Union Carbide), Cellcoat series (made by National Starch), Marcoat 100, 550 (Calgon). H.) C. Commercial products such as polymers (manufactured by Osaka Organic Chemical Industry Co., Ltd.), Gohsenol series (manufactured by Nippon Gosei Co., Ltd.), and Kuraray Poval series (Kuraray) can be used.

  Nonionic polymers include, for example, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, polyvinyl alcohol, and polyurethane. Lubiscol K (manufactured by BASF), PVP / VA (manufactured by ISP), Acorn series Commercial products such as (manufactured by Osaka Organic Chemical Industry Co., Ltd.) can be used.

  The compounding quantity of the component (c) in the hairdressing material of this invention is 0.1 to 20%, and 0.5 to 10% is more preferable in order to obtain the especially outstanding usability. When the component (c) is blended in this range, a hair styling excellent in the finish setting effect and the sustainability of the setting effect can be obtained.

  Furthermore, in the hair styling agent of the present invention, it is also possible to blend component (d) propellant in order to obtain an aerosol type or a spray type. If a component (d) propellant is normally used for cosmetics, it will not be specifically limited. Specifically, liquefied petroleum gas, dimethyl ether, nitrogen, nitrous oxide, carbon dioxide gas and the like can be mentioned.

  The blending amount of the component (d) in the hair styling composition of the present invention is not particularly limited. For example, in the case of an aerosol foam, the amount of foam to form an appropriate foam, and in the case of hair spray, the amount of an appropriate spray pattern, According to prescription, it can adjust and use suitably.

  In the shampoo composition of the present invention, in addition to the above-mentioned components, components that are usually used in preparations such as cosmetics, quasi-drugs, and external medicines, that is, water (purified water) are used within the range not impairing the effects of the present invention. , Hot spring water, deep water, etc.), oil agent, surfactant other than the above, metal soap, gelling agent, powder, alcohol, other water-soluble polymer, film forming agent, resin, inclusion compound, moisture retention Agents, antibacterial agents, fragrances, deodorants, salts, pH adjusters, fresheners, plant extracts, and vitamins.

  As the oil agent, oily components such as higher alcohols, hydrocarbon oils, ester oils, fatty acids, fats and oils, and silicones can be used. For example, lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyldodecanol, octyldodecanol, cetostearyl alcohol, 2-decyltetradecinol, cholesterol, phytosterol , Higher alcohols such as sitosterol, lanosterol, monostearyl glycerol ether (batyl alcohol), hydrocarbons such as ozokerite, squalane, squalene, ceresin, paraffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, microcrystalline wax, petrolatum, etc. , Diisobutyl adipate, 2-hexyldecyl adipate, adipic acid 2-heptylundecyl, monoisostearic acid-alkyl glycol, isocetyl isostearate, trimethylolpropane triisostearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, tri-2-ethylhexanoate tri Methylolpropane, tetra-2-ethylhexanoic acid pentaerythritol, cetyl octoate, octyldodecyl gum ester, oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate , Amyl acetate, ethyl acetate, butyl acetate, isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, milk Myristyl, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, cholesteryl 12-hydroxystearylate, isopropyl myristate, octyldodecyl myristate, 2-hexyldecyl myristate, Ester oils such as myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate, diisostearyl malate, waxes such as beeswax, carnauba wax, candelilla wax, whale wax, beef tallow, beef leg fat, Beef bone fat, hardened beef fat, hardened oil, turtle oil, pork fat, horse fat, mink oil, liver oil, egg yolk oil and other animal oils, lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin fatty acid Lanolin derivatives such as isopropyl, fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, arachidonic acid, docosahexaenoic acid (DHA), isostearic acid, 12-hydroxystearic acid Low-polymerization dimethylpolysiloxane, high-polymerization dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, polyether-modified polysiloxane, polyoxyalkylene, alkylmethylpolysiloxane, methylpoly Siloxane copolymer, alkoxy-modified polysiloxane, alkyl-modified polysiloxane, cross-linked organopolysiloxane, fluorine-modified polysiloxane, amino-modified polysiloxane, glycerin Modified polysiloxane, higher alkoxy-modified silicones, higher fatty acid-modified silicones, silicone resins, silicone rubber, silicone resin and the like.

  As surfactants other than the above, surfactants such as alkylamine salts, amine salts such as polyamines and aminoalcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridium salts, imidazolium salts Etc .; Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether , Polyoxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester , Polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, poly Oxyethylene cholesteryl ether, polyoxyalkylene-modified organopolysiloxane, polyoxyalkylene / alkyl co-modified organopolysiloxane, lauric acid diethanolamide, coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, polyoxyethylene coconut oil fatty acid monoethanol Amide, lauric acid monoisopropanolamide, coconut oil fatty acid monoisopropanolamide, Li oxy prolene coconut oil fatty monoisostearate Pas alkanolamides, alkanolamides, sugar ethers, and sugar amides.

  Metal soaps include: aluminum isostearate, zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, sodium cetyl phosphate, zinc laurate, undecylenate Zinc etc. are mentioned.

  Gelling agents include amino acid derivatives such as α, γ-di-n-butylamine, dextrin palmitate, dextrin stearate, dextrin fatty acid ester such as dextrin 2-ethylhexanoate palmitate, sucrose palmitate Sucrose fatty acid esters such as sucrose stearate, benzylidene derivatives of sorbitol such as monobenzylidene sorbitol, dibenzylidene sorbitol, organically modified clay minerals such as dimethylbenzyl dodecyl ammonium montmorillonite clay, dimethyl dioctadecyl ammonium montmorillonite clay, etc. .

  If the powder is used in ordinary cosmetics, its shape (spherical, needle-like, plate-like, etc.), particle size (smoke-like, fine particles, pigment grade, etc.), particle structure (porous) Any inorganic powder can be used, for example, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, synthetic mica. , Mica, kaolin, sericite, muscovite, synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, aluminum magnesium silicate, calcium silicate, Barium silicate, strontium silicate, metal tungstate, hydroxyapatite, vermiculite, hydrite, montmorillonite, z Light, ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, etc .; organic powders include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethyl Benzoguanamine powder, tetrafluoroethylene powder, polymethyl methacrylate powder, cellulose, silk powder, nylon powder, 12 nylon, 6 nylon, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol Resin, fluororesin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, microcrystalline fiber powder, Lauro Luridine, etc .; as colored pigments, inorganic red pigments such as iron oxide, iron hydroxide and iron titanate, inorganic brown pigments such as γ-iron oxide, yellow inorganic oxides such as yellow iron oxide and loess, black iron oxide, Inorganic black pigments such as carbon black, inorganic purple pigments such as manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate, inorganic blue pigments such as bitumen and ultramarine blue, tar-based Dye raked, natural dye raked, and composite powders made by combining these powders; pearl pigments include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide Coated bismuth oxychloride, titanium oxide coated talc, fish scale foil, titanium oxide coated colored mica, etc .; -Powder, stainless steel powder, etc. As tar pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227 , Red 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401, Blue 1, Blue 2, Blue No. 201, Blue No. 404, Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207, etc .; A powder selected from acids, laccaic acid, calsamine, bradylin, crocin, etc., and these powders are compounded or surface treated with oils, silicones, or fluorine compounds It may be carried out powder.

  Examples of alcohols include lower alcohols such as ethanol and isopropanol, polyhydric alcohols such as glycerin, diglycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, and polyethylene glycol. Etc.

  Examples of water-soluble polymers include chondroitin sulfate, hyaluronic acid, mucin, dermatan sulfate, heparin and keratan sulfate other than component (c) and their salts, gum arabic, tragacanth, galactan, carob gum, guar gum, caraya gum , Plant polymers such as carrageenan, pectin, agar, quince seed, algae colloid, tortue gum, locust bean gum, galactomannan, microbial polymers such as xanthan gum, dextran, succinoglucan, pullulan, starch, carboxymethyl starch, Starch polymers such as methylhydroxypropyl starch, methylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose Cellulose cellulose sulfate, sodium carboxymethyl cellulose, crystalline cellulose, cellulose-based cellulose polymers, sodium alginate, alginic acid polymers such as propylene glycol alginate, vinyl polymers such as carboxyvinyl polymers and alkyl-modified carboxyvinyl polymers, Examples include polyoxyethylene polymers, polyoxyethylene polyoxypropylene copolymer polymers, inorganic water-soluble polymers such as sodium polyacrylate, polyethyleneimine, bentonite, laponite, and hectorite.

  Antibacterial agents include benzoic acid, sodium benzoate, salicylic acid, coalic acid, sorbic acid, potassium sorbate, paraoxybenzoic acid ester, parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitive Element, bis (2-pyridylthio-1-oxide) zinc, phenoxyethanol, isopropylmethylphenol and the like.

  Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, malic acid, potassium carbonate, sodium bicarbonate, ammonium bicarbonate, sodium hydroxide, potassium hydroxide, triethanolamine, monoethanolamine, Examples of the refreshing agent include l-menthol and camphor.

  Vitamins such as vitamin A and derivatives thereof, vitamin B and derivatives thereof, vitamin C and derivatives thereof, vitamin E and derivatives thereof, linolenic acid and derivatives thereof, and vitamins such as phytonadione, menaquinone, menadione, menadiol Ks; vitamin Ps such as eriocitrin and hesperidin; and biotin, carcinine, ferulic acid and the like.

  The hair styling composition of the present invention may be any of liquid, emulsion, cream, gel, and solid as a dosage form, and it is an out of hair lotion, split hair coat agent, hair milk, hair cream, hair foam, hair treatment, etc. It can be used for hair styling for bath hair products, rinses, hair packs, etc. Moreover, it can also be implemented as an aerosol foam or hair spray by blending a propellant.

  Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.

Invention products 1 to 10 and comparative products 1 to 6: Styling foams The styling foams shown in Tables 1 and 2 were prepared by the following manufacturing method, and the feeling of use (no stiffness at the time of finishing, flexibility, setting power), hair Each item of the repair effect (elasticity) was evaluated and determined by the following evaluation method and criteria, and the results are shown in Table 1 and Table 2.

Note 1: DEHYQUAL L80 (manufactured by Cognis; listed as pure quantity)
Note 2: DEHYQUART F75 (manufactured by Cognis; listed as pure quantity)
Note 3: DEHYQUAT AU56 / G (manufactured by Cognis; described as a pure quantity)
Note 4: PVP / VA E-735 (manufactured by ISP; described as a pure resin amount)
Note 5: Plus size L6330 (manufactured by Kyoyo Chemical Co., Ltd .; described as a pure resin amount)
Note 6: Yuka Former SM (Diachemco Co., Ltd .; described as a pure resin amount)
Note 7: Lipidure-HM-500 (Nippon Yushi Co., Ltd.)

(Production method)
A: Components 1 to 17 are uniformly mixed to obtain a stock solution.
The aerosol can was filled so that the mass ratio of B: A (raw solution) and the propellant (liquefied petroleum gas) was 97: 3 to obtain styling foam.

[Evaluation method of feeling of use]
Have 10 panelists specializing in cosmetics use the styling foams of the present invention and comparative products, and for each item of feeling of use (no wrinkles at the finish, flexibility, set power) Five levels were evaluated according to the evaluation criteria, and the average score of all panels was determined according to the following criteria.
Evaluation criteria:
[Evaluation Result]: [Score]
Very good: 5 points Good: 4 points Normal: 3 points Somewhat bad: 2 points Bad: 1 point Criteria:
[Average score]: [Judgment]
4.5 or more: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than 1.5: ×

[Evaluation method of hair repair effect (elasticity)]
A hair bundle of Asian hair subjected to hair bleach treatment having a length of 5 cm and 10 bundles was washed with a commercially available shampoo and then naturally dried. Further, the styling foams shown in Tables 1 and 2 were uniformly applied, and further dried with a drier to prepare evaluation hair bundles. The load value change rate when the stress load value when this hair bundle is bent is measured with a hair elasticity measuring machine (see Japanese Patent Laid-Open No. 2000-32186) and compared with the stress load value of the hair bundle not coated with styling foam. Thus, the hair repair effect (elasticity) was determined using the following criteria.
Judgment criteria:
[Evaluation]: [Judgment]
Load value change rate + 20% or more: ◎
Load value change rate + 10% or more and less than 20%: ○
Load value change rate + 5% or more and less than 10%: △
Load value change rate + 5% or less: ×

  As is apparent from the results of Tables 1 and 2, the styling foams of the present invention products 1 to 10 are excellent in feeling of use (no stiffness at the finish, flexibility, setting power) and hair repair effect (elasticity). It was. On the other hand, the comparative products 1 to 6 could not satisfy all the items.

Example 2: Hair styling point mist (component) (%)
1. Dicocoylethylhydroxyethylmonium methosulfate (Note 1) 1
2. Polyvinylpyrrolidone (Note 8) 8
3. Vinylpyrrolidone / vinyl acetate copolymer (Note 4) 1
4). Behenyltrimethylammonium chloride 0.1
5. Creatine 0.5
6). L-proline 0.5
7). Creatinine 0.5
8). Diglycerin 0.1
9. Sorbitol 0.1
10. Ethanol 40
11. Dipropylene glycol 0.1
12.1,3-butylene glycol 0.2
13. Fragrance 0.3
14 Purified water remaining amount Note 8: LUVISKOL K90 (made by Badish)

(Production method)
A: Components 1 to 14 were mixed and dissolved uniformly to obtain a hair styling point mist.
The hair styling point mist of Example 2, which is a product of the present invention, was excellent in feeling of use (no stiffness at the time of finishing, flexibility, setting power) and hair repair effect (elasticity).

Example 3: Styling milk (component) (%)
1. Dicocoylethylhydroxyethylmonium methosulfate (Note 1) 0.5
2. Distearoylethylhydroxyethylmonium methosulfate (Note 2) 0.2
3. Distearyldimethylammonium chloride 0.2
4). Stearyltrimethylammonium chloride 0.1
5. Cetostearyl alcohol 2
6). Behenyl alcohol 1
7). Glyceryl tri-2-ethylhexanoate 3
8). Liquid paraffin 1.5
9. Octyl palmitate 1
10. Cetyl palmitate 1
11. Octild decanol 1
12 N-lauroyl-L-glutamate di (phytosteryl, 2-octyldodecyl) 0.5
13. Polyvinylpyrrolidone (Note 8) 5
14 Propylene glycol 3
15. Polyethylene glycol 400 1
16. Hydroxyethyl cellulose 0.1
17. PEG-60 Butylamodimethicone Emulsion (Note 9) 1
18. Cysteine 0.1
19. Glutamic acid 0.1
20. Sucrose 0.1
21. Phenoxyethanol 0.2
22. Fragrance 0.5
23. Purified water remaining amount Note 9: SILSTLE 401 (Nippon Unicar)

(Production method)
A: Components 1 to 12 are mixed and dissolved at 70 ° C.
B: Components 13 to 16 and 23 are mixed and dissolved at 70 ° C.
C: A is added to B and emulsified.
D: C was cooled, and components 17 to 22 were uniformly added and mixed to obtain styling milk.
The styling milk of Example 3, which is an embodiment of the present invention, was excellent in feeling of use (no stiffness at the finish, flexibility, setting power) and hair repair effect (elasticity).

Example 4: Hair wax (component) (%)
1. Dicocoylethylhydroxyethylmonium methosulfate (Note 1) 0.3
2. Dipalmitoylethylhydroxyethylmonium methosulfate (Note 3) 0.5
3. Cetyltrimethylammonium chloride 0.1
4). Stearyltrimethylammonium chloride 0.5
5. Cetyl alcohol 5
6). Stearyl alcohol 3
7). Paraffin wax 9
8). Candelilla wax 5
9. Microcrystalline wax 1
10. Hardened oil 1
11. Cetyl palmitate 1
12 N-lauroyl-L-glutamate di (2-octyl dodecyl) 1
13. Vinylpyrrolidone / vinyl acetate copolymer (Note 4) 7
14 Dipropylene glycol 3
15. Highly polymerized polyethylene glycol 0.1
16. Cationized cellulose 0.1
17. Highly polymerized silicone emulsion 3
18. L-serine 0.1
19. Aspartic acid 0.1
20. Hydrolyzed collagen 0.1
21. Methylparaben 0.2
22. Fragrance 0.5
23. Purified water remaining

(Production method)
A: Components 1 to 12 are mixed and dissolved at 70 ° C.
B: Components 13 to 16 and 23 are mixed and dissolved at 70 ° C.
C: A is added to B and emulsified.
D: C was cooled, and components 17 to 22 were uniformly added and mixed to obtain a hair wax.
The hair wax of Example 4, which is an embodiment of the present invention, was excellent in feeling of use (no stiffness at the finish, flexibility, setting power), and hair repair effect (elasticity).

Example 5: Hair styling gel (component) (%)
1. Dicocoylethylhydroxyethylmonium methosulfate (Note 1) 0.3
2. Dipalmitoylethylhydroxyethylmonium methosulfate (Note 3) 0.1
3. Hydroxypropyl methylcellulose 0.5
4). Carboxyvinyl polymer 0.5
5. Polyvinylpyrrolidone (Note 8) 3
6). Sodium hydroxide 0.1
7). Ethanol 20
8). Propylene glycol 3
9. Theanine 0.1
10. Hydroxyproline 0.1
11. Hydrolyzed silk 0.1
12 Butylparaben 0.2
13. Fragrance 0.5
14 Purified water remaining

(Production method)
A: Components 1 to 6 and 14 are mixed uniformly.
B: Components 7 to 13 were added to A to obtain a hair styling gel.
The hair styling gel of Example 5, which is an embodiment of the present invention, was excellent in feeling of use (no stiffness at the time of finishing, flexibility, setting power) and hair repair effect (elasticity).

Example 6: curl lotion (component) (%)
1. Dicocoylethylhydroxyethylmonium methosulfate (Note 1) 0.2
2. Distearoylethylhydroxyethylmonium methosulfate (Note 2) 0.3
3. Behenyltrimethylammonium bromide 0.1
4). Stearyltrimethylammonium bromide 0.1
5. N-methacryloylethyl N, N-dimethylammonium / α-N-methylcarboxybetaine / alkyl methacrylate copolymer (Note 6) 3
6). Ethanol 10
7). L-cysteine 0.1
8). Threonine 0.1
9. Hydrolyzed soy protein 0.1
10. Phenoxyethanol 0.2
11. Fragrance 0.5
12 Purified water remaining

(Production method)
A: Components 1 to 12 were mixed and dissolved uniformly to obtain a curl lotion.
The curl lotion of Example 6, which is a product of the present invention, was excellent in feeling of use (no stiffness at the finish, flexibility, setting power) and hair repair effect (elasticity).

Example 7: Foam hair conditioner aerosol concentrate formulation (component) (%)
1. Dicocoylethylhydroxyethylmonium methosulfate (Note 1) 0.3
2. Behenyltrimethylammonium chloride 0.1
3. Cetostearyl alcohol 0.3
4). Octyl palmitate 1
5. Dimethylpolysiloxane (100 mPa · s) 1
6). Decamethylcyclopentasiloxane 1
7). N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl) 1
8). Propylene glycol 10
9. Vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate (Note 10) 1.5
10. Glycerin 3
11. Hydroxyethyl cellulose 0.1
12 Amodimethicone Emulsion 0.5
13. Creatine 0.1
14 Creatinine 0.1
15. Fish-derived water-soluble collagen 0.1
16. Phenoxyethanol 0.2
17. Fragrance 0.5
18. Purified water remaining amount Note 10: C. Polymer-2L (manufactured by Osaka Organic Chemical Industry Co., Ltd .; described as a pure resin amount)

(Production method)
A: Components 1 to 18 were mixed and dissolved uniformly to obtain an aerosol stock solution.
The aerosol can was filled so that the mass ratio of B: A (aerosol stock solution) and propellant (liquefied petroleum gas) was 97: 3 to obtain a foamy hair styling agent.
The foam hair styling material of Example 7 which is an embodiment of the present invention was excellent in feeling of use (no stiffness at the time of finishing, flexibility, setting power) and hair repair effect (elasticity).

Example 8: Hair spray stock solution formulation (component) (%)
1. Dicocoylethylhydroxyethylmonium methosulfate (Note 1) 0.1
2. Hydroxypropyl acrylate / butylamino methacrylate / octylamide acrylate copolymer (Note 13) 5
3. N-methacryloylethyl N, N-dimethylammonium / α-N-methylcarboxybetaine / alkyl methacrylate copolymer (Note 6) 0.5
4). Isopropyl myristate 0.1
5. Phenyltrimethicone 0.1
6). Dimethylpolysiloxane (6 mPa · s) 0.1
7). N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl) 0.2
8). Aminomethylpropanol 1
9. Ethanol remaining amount Note 13: Amphomer (National Starch)

(Production method)
A: Components 1 to 9 are uniformly dissolved to obtain a stock solution.
B: 20 parts of liquefied petroleum gas and 20 parts of dimethyl ether were added as propellants to 60 parts of the stock solution to obtain a hair spray.
The hair spray of Example 8, which is an embodiment of the present invention, was excellent in feeling of use (no stiffness at the finish, flexibility, setting power) and hair repair effect (elasticity).

Claims (2)

The following components (a) to (c);
(A) The following general formula (1)
Wherein R ² is an aliphatic acyl group having 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, n = 2 or 3, and X is a halogen compound, methosulfate or metho 0.001 to 10% by mass of a cationic surfactant represented by phosphate)
(B) Hair repair component 0.001-10 mass%
(C) Hair setting agent 0.1-20% by mass
A hair styling characterized by blending.   Furthermore, a propellant is mix | blended as a component (d), The hairdressing material of Claim 1 characterized by the above-mentioned.