JP2020158400A - O/w emulsion composition - Google Patents

Abstract

To provide an O/W emulsion composition which is used as a raw material for a cosmetic or an external preparation for skin having excellent stability and contains one or two or more oil agents selected from a dimer acid ester, a fatty acid sterol ester and an N-acylamino acid ester in a high concentration.SOLUTION: There is provided an O/W emulsion composition which comprises the following components (A) to (C) as essential components: (A) a polyglycerol fatty acid ester having an HLB of 12 to 18, (B) an oily component containing the following components (B1) and (B2), (B1) one or two or more selected from a dimer acid ester, a fatty acid sterol ester and an N-acylamino acid ester and (B2) a liquid oil having a viscosity at 25°C of 200 mPa s or less and (C) water.SELECTED DRAWING: None

Description

The present invention relates to an O / W type emulsified composition having excellent stability, which is used as a raw material for cosmetics or skin external preparations containing a high concentration of an oil agent.

In cosmetics, oils are one of the main ingredients in most types of formulations. Its main purpose is to impart flexibility and emollientity to the skin and hair, and depending on the characteristics of each oil, it has a feeling of use, moisturizing property, glossiness, cleansing property, pigment dispersibility, and adhesion. It is used for the purpose of improving solubility. Among the oils used in cosmetics, there are oils having special functions that are not found in oils such as hydrocarbon oils, vegetable oils, and silicone oils that are generally used. For example, dimer acid esters (Patent Documents 1 to 4). ), Fatty acid sterol esters (Patent Documents 5 to 6), N-acylamino acid esters (Patent Documents 7 to 8) and the like are used as cosmetic oils. Compared with ordinary general-purpose oils, these oils are superior in functions such as emollientity, moisturizing property, glossing property for skin, feel improvement and damage improvement for hair. However, since these esters have a larger molecular weight and a higher viscosity than general-purpose oils, they have problems that they take a long time to prepare and need to be preheated and dissolved, which makes them complicated to handle as raw materials. there were. Therefore, it has been desired that such an oil agent can be easily added to cosmetics.

As a method of easily blending an oil agent into a cosmetic, a method of preparing a composition emulsified to a high concentration in advance and adding such a high-concentration emulsified composition to the cosmetic as a raw material is known. In such a method, the emulsion stability of the high-concentration emulsion itself is important, but the emulsion stability after being mixed with cosmetics and diluted is also very important. Since various ingredients other than oils are blended in cosmetics, maintaining a stable emulsified state without being affected by such blended ingredients is a high-concentration emulsified composition used as a raw material for cosmetics. Is very important in. Further, when such a high-concentration emulsified composition is used as a raw material for cosmetics, it is preferable that the number of types of components in the composition is small in order to make it easy to blend in as wide a range of types of cosmetics as possible. It is desirable that components generally blended in cosmetics, such as polyhydric alcohols and thickeners that improve the stability of emulsified compositions, are not blended as much as possible. This is because some cosmetics do not want to contain ingredients such as polyhydric alcohols and thickeners, so that they can be preferably used for such cosmetics.

As a composition obtained by emulsifying an oil agent at a high concentration, Patent Documents 9 to 10 disclose a composition using a polyglycerin fatty acid ester and a polyhydric alcohol, but a dimer acid ester, a fatty acid sterol ester, and N- It has not been suggested at all that acyl amino acid esters and the like can be emulsified at high concentrations.

Japanese Patent No. 4573383 Japanese Patent No. 3826057 Japanese Patent No. 4331584 Japanese Patent No. 6033587 Japanese Patent No. 3035554 Japanese Unexamined Patent Publication No. 09-132512 Japanese Patent No. 2831800 Japanese Patent No. 5805466 Japanese Unexamined Patent Publication No. 2008-094811 JP-A-2008-195689

The subject of the present invention is stability used as a raw material for cosmetics or skin external preparations, which contains a high concentration of one or more oils selected from dimer acid ester, fatty acid sterol ester and N-acylamino acid ester. An object of the present invention is to provide an O / W type emulsified composition having excellent properties. In addition, the present inventors use only one or more oils selected from dimer acid ester, fatty acid sterol ester and N-acylamino acid ester to prepare a high-concentration emulsified composition for stable emulsification. Since it has been found that the composition cannot be obtained, it is also an object of the present invention to improve such a point.

As a result of diligent studies to solve the above problems, the present inventors have contained the following components (A) to (C), and the content of the component (B) is 10 to 70% by weight. We have found that an O / W type emulsified composition for cosmetics or external preparations for skin, characterized in that the content of (B1) in B) is 20 to 80% by weight, solves the above problems. Completed the invention.
(A) Polyglycerin fatty acid ester having an HLB of 12 to 18 (B) An oily component containing the following components (B1) and (B2) (B1) Dimeric acid ester, fatty acid sterol ester, and
One or more selected from N-acylamino acid esters (B2) Liquid oil (C) water with a viscosity of 200 mPa · s or less at 25 ° C.

The O / W type emulsified composition of the present invention contains one or more oils selected from dimer acid ester, fatty acid sterol ester and N-acylamino acid ester in high concentration, and has excellent stability and cosmetics. It can maintain a stable emulsified state even after being mixed with an ester and diluted. Further, the O / W type emulsified composition of the present invention can be obtained as having excellent stability even without components such as a polyhydric alcohol and a thickener that generally improve the stability of the emulsified composition. is there.

The O / W type emulsified composition of the present invention contains the following components (A) to (C) as essential components.
(A) Polyglycerin fatty acid ester having an HLB of 12 to 18 (B) An oily component containing the following components (B1) and (B2) (B1) Dimeric acid ester, fatty acid sterol ester, and
One or more selected from N-acylamino acid esters (B2) Liquid oil (C) water with a viscosity of 200 mPa · s or less at 25 ° C.

The component (A) used in the present invention is a polyglycerin fatty acid ester having an HLB of 12 to 18. In the present invention, the polyglycerin fatty acid ester having such an HLB is not particularly limited, but is preferably a polyglycerin fatty acid ester having an HLB of 14 to 16. Specific examples of such polyglycerin fatty acid esters include polyglyceryl-6 caprylate, polyglyceryl caprylate-10, polyglyceryl laurate-6, polyglyceryl laurate-10, polyglyceryl myristate-10, polyglyceryl palmitate-10, and stearic acid. Examples thereof include polyglyceryl-10 acid, polyglyceryl isostearate-10, and polyglyceryl oleate-10. From the viewpoint of the stability of the obtained emulsified composition and the stability over time when blended in cosmetics, polyglyceryl laurate-6, polyglyceryl laurate-10, polyglyceryl myristate-10, and polyglyceryl palmitate-10 are more preferable. Preferably, polyglyceryl laurate-10 and polyglyceryl myristate-10 are most preferable. These may be used alone or in combination of two or more.

HLB is an abbreviation for "Hydrophile-Lipophile Balance" and indicates the balance between hydrophilicity and lipophilicity. In the present invention, the HLB calculated from Griffin's formula shown below can be used as an index.

HLB = 20 × (1-S / A)
S: Saponification value of polyglycerin fatty acid ester A: Neutralization value of raw material fatty acid

The component (B) used in the present invention is an oily component containing the following components (B1) and (B2).
(B1) Dimer acid ester, fatty acid sterol ester, and
One or more selected from N-acylamino acid esters (B2) Liquid oil with a viscosity of 200 mPa · s or less at 25 ° C.

The amount of the component (B) to be blended in the O / W type emulsified composition is 10% by weight or more, preferably 20% by weight or more, and more preferably 30% by weight or more. If it is less than this, the effect of imparting the excellent function of the component (B1) when blended in cosmetics is reduced. Further, it may be blended in an amount of 70% by weight or less, preferably 65% by weight or less. If it is more than this, it becomes difficult to obtain a stable emulsified composition. The blending ratio of the components (A) and (B) is preferably (B) / (A) = 1 to 10, preferably 2 to 7, in terms of weight ratio, from the viewpoint of obtaining a stable emulsified composition. ..

Among the components (B1) used in the present invention, specific examples of the dimer acid ester include dimer dilinoleic acid dimer dilinoleyl, dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl), and die. Examples thereof include dimer dilinoleic acid (isostearyl / phytosteryl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid hydrogenated castor oil, diglycerin isostearate dimerginoleic acid, and the like. .. Of these, from the viewpoint of obtaining a more stable emulsified composition, dimer dilinoleyl dimer dilinoleate, dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl), dimer dilinoleate di (isostearyl). / Phytosteryl) and dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) are mentioned as preferable, and dimer dilinoleic acid dimer dilinoleic acid is most preferable. Dimer dilinoleic acid Since dimer dilinoleyl is an esterified product of a dicarboxylic acid and a diol, those having different molecular weights can be obtained depending on the reaction ratio, but in the present invention, any molecular weight can be used. Usually, one having a weight average molecular weight (Mw) of 10 to 1,000,000, preferably 2,000 to 500,000, and more preferably 3,000 to 200,000 is preferable. The weight average molecular weight (Mw) means a polystyrene-equivalent value measured by gel permeation chromatography (GPC).
Specific examples of fatty acid sterol esters include phytosteryl oleate, phytosteryl hydroxystearate, phytosteryl isostearate, lanolin fatty acid phytosteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, rice bran oil fatty acid phytosteryl, cholesteryl oleate, cholesteryl hydroxystearate. , Isostearate cholesteryl, lanolin fatty acid cholesteryl, macadamia nut oil fatty acid cholesteryl, sunflower seed oil fatty acid cholesteryl, rice bran oil fatty acid cholesteryl. Of these, phytosteryl oleate, phytosteryl isostearate, macadamia nut oil fatty acid phytosteryl, and sunflower seed oil fatty acid phytosteryl are more preferable from the viewpoint of obtaining a more stable emulsified composition.
Specific examples of the N-acylamino acid ester include dioctyldodecyl N-lauroyl-L-glutamic acid, di (phytosteryl / octyldodecyl) N-lauroyl-L-glutamic acid, and di (cholesteryl / octyldodecyl) N-lauroyl-L-glutamic acid. , N-lauroyl-L-glutamic acid di (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamic acid di (phytosteryl / behenyl / octyldodecyl). Of these, di (phytosteryl / octyldodecyl) N-lauroyl-L-glutamic acid and di (phytosteryl / behenyl / octyldodecyl) N-lauroyl-L-glutamic acid are more preferable from the viewpoint of obtaining a more stable emulsified composition.

In the present invention, the component (B1) may be blended in the component (B) in an amount of 20% by weight or more, preferably 40% by weight or more. If it is less than this, the effect of imparting the excellent function of the component (B1) when blended in cosmetics is reduced. Further, the component (B1) may be blended in the component (B) in an amount of 80% by weight or less, preferably 75% by weight or less. If it is more than this, it becomes difficult to obtain a stable emulsified composition.

Specific examples of the component (B2) used in the present invention include hydrocarbon oils such as dodecane, isododecane, hexadecane, isohexadecan, (C13-15) alkane, liquid paraffin, and squalane; coconut oil, palm oil, palm kernel. Oil, saflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, Argania spinosa kernel oil, meadowfoam oil, persic Vegetable oils such as oil, tea tree oil, peppermint oil, camellia oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, flaxseed oil, cotton seed oil, soybean oil, peanut oil, rice bran oil, cacao fat, jojoba oil; triethylhexanoic acid Glyceryl, Glyceryl tricaprylate, Glyceryl tricaprate, Tri (caprylic / capric acid) glyceryl, Glyceryl trioleate, Glyceryl triisostearate, Trimethylolpropane triethylhexanoate, Pentaerythrityl tetraethylhexanoate, 3-Methyl dineopentanoate 1,5-pentanediol, dineopentanoic acid 2,4-diethyl-1,5-pentanediol, cetyl ethylhexanate, hexyldecyl ethylhexanate, isononyl isononanoate, isodecyl isononanoate, isotolideyl isononanoate, isodecyl neopentane, neopentane Isotridecyl acid, isostearyl neopentate, octyldodecyl neodecanoate, isopropyl myristate, hexyldecyl myristate, octyldodecyl myristate, isopropyl palmitate, ethylhexyl palmitate, cetyl palmitate, octyldodecyl palmitate, ethyl oleate, oleate Oleyl, octyldodecyl oleate, isopropyl isostearate, octyldodecyl isostearate, octyldodecyl erucate, isopropyl lanolin fatty acid, octyldodecyl lanolin fatty acid, dicaprylyl carbonate, diethylhexyl succinate, diisopropyl adipate, diisobutyl adipate, diethylhexyl adipate , Ester oils such as diethyl sebacate, diisopropyl sebacate, diethylhexyl sebacate, triethyl citrate, diisostearyl malate (methyl branched); parents such as bisethoxydiglycol succinate, bisethoxydiglycol cyclohexanedicarboxylic acid Medicinal ester oil; Dimethico Silicone oils such as dimethicone, cyclomethicone and phenyldimethicone. These oils may be used alone or in combination of two or more.

In the present invention, a stable emulsified composition cannot be obtained only by the component (B1) as the component (B), but a stable emulsified composition can be obtained by blending the component (B1) and the component (B2) in combination. It becomes possible. In the present invention, the component (B2) may be blended in the component (B) in an amount of 20% by weight or more, preferably 25% by weight or more, and 80% by weight or less, preferably 60% by weight or less. Further, the component (B2) of the present invention contains one or more hydrocarbon oils selected from dodecane, isododecane, hexadecane, isohexadecane, (C13-15) alkane, liquid paraffin, and squalane as essential components. It is preferable to contain it. It is preferable that such a hydrocarbon oil is contained in the component (B2) in an amount of 30% by weight or more, more preferably 50% by weight or more. By containing the hydrocarbon oil, the polarity of the entire oily component can be adjusted, and the stability of the emulsified composition itself and the stability over time when the cosmetic is blended can be improved.

The component (B) of the present invention may contain an oily component other than the components (B1) and (B2) described above as long as the effects of the present invention are not impaired. For example, oils such as semi-solid oils, solid oils, and highly viscous oils for the purpose of imparting usability and moisturizing properties; oil-soluble antioxidants such as vitamin E for the purpose of improving oxidative stability; For the purpose, an oil-soluble ultraviolet absorber, an oil-soluble physiologically active ingredient, or the like may be added.

The water of the component (C) of the present invention is not particularly limited as long as it can be usually used for cosmetics, and purified water, ion-exchanged water, distilled water, natural water, deep ocean water, hydrogen water and the like can be used. .. Further, the pH may be adjusted with an acid, an alkali, a buffer, a chelating agent or the like, or an antiseptic may be added. The blending amount of the component (C) of the present invention into the O / W type emulsified composition may be appropriately adjusted according to the blending amounts of the components (A) and (B), and is usually 15 to 85% by weight, preferably 20. ~ 75% by weight.

In the O / W type emulsified composition of the present invention, it is possible to obtain a stable emulsified composition using only the components (A) to (C) of the present invention, and generally, a polyhydric alcohol or an increase that improves emulsification stability. Does not require ingredients such as thickeners. Further, in the O / W type emulsified composition of the present invention, it is preferable not to mix components other than the essential components of the present invention, even if they are components generally used in cosmetics, as much as possible. This is because the O / W type emulsified composition of the present invention can be easily used as a raw material for cosmetics in a wide variety of cosmetics as much as possible. However, when the type, composition, etc. of the cosmetic containing the O / W type emulsification composition of the present invention have been determined and the components to which the composition is permitted are clear, the O / W type emulsification of the present invention The composition may also contain various ingredients generally used in cosmetics.

The blending amount of the O / W type emulsified composition of the present invention into a cosmetic or external preparation for skin varies depending on the type and composition of the cosmetic or external preparation for skin to be blended, but is generally 0.01 to 50 mass. %, preferably 0.05 to 30% by mass.

<Method for producing O / W type emulsified composition of the present invention>
When producing an O / W type emulsified composition, generally, oil and a surfactant are first heated and mixed to dissolve them, and then warmed water is added thereto with stirring, and the mixture is continuously added. A method is used in which the phase is changed from the oil phase to the aqueous phase to obtain an O / W type emulsified composition (phase inversion emulsification method). However, in the production of the O / W type emulsified composition of the present invention, a stable emulsified composition cannot be obtained by such a phase inversion emulsification method. In the present invention, it can be produced by adding water while stirring to a mixture in which a surfactant, oil and a small amount of water are uniformly stirred and mixed. A small amount of water is 5 to 90 parts by weight, preferably 10 to 60 parts by weight, based on 100 parts by weight of the surfactant. All of these steps can be performed at room temperature and do not require heating. That is, the method for producing an O / W type emulsified composition of the present invention is characterized by including the following steps (1) and (2).
(1): With respect to 100 parts by weight of component (A), component (B), and component (A)
Step of adding 5 to 90 parts by weight of component (C) and uniformly stirring and mixing (2): Add the rest of component (C) to the mixture of step (1) with stirring.
Step to uniformly stir and mix

The O / W type emulsified composition of the present invention can be produced by either a batch type or a continuous type, and the devices that can be used include a paddle mixer, an anchor mixer, a ribbon mixer, a turbine mixer, a dispenser mixer, a homogenizing mixer, and now. Examples include a turbine mixer and a planetary mixer. These devices may be a composite device in which a plurality of stirring blades are combined. It is preferably a combination of a dispar mixer and a planetary mixer.

The cosmetics containing the O / W type emulsified composition of the present invention include water and additive components generally contained in cosmetics, such as oily bases, surfactants, alcohols, moisturizers, polymers and thickening agents.・ Gelling agent, antioxidant, preservative, bactericidal agent, chelating agent, pH adjuster ・ Acid / alkali, UV absorber, whitening agent, solvent, keratin peeling / dissolving agent, antipruritic agent, anti-inflammatory agent, antiperspirant , Cooling agents, antihistamines, astringents, stimulants, hair growth agents / blood circulation promoters, reducing agents / oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, sugars and their derivatives, organic acids, It may be a mixture of enzymes, nucleic acids, hormones, inorganic powders, fragrances, pigments and the like.

Oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, araquil alcohol, behenyl alcohol, jojoba alcohol, chimil alcohol, seraquil alcohol, bacil alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimerdiol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Higher grades such as palmitooleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, eikosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long-chain branched fatty acids, dimer acids, hydrogenated dimer acids, etc. Fatty acids and their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts and other metal soaps, and amides and other nitrogen-containing derivatives; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin , Α-Olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalane, vaseline, solid paraffin and other hydrocarbons; candelilla wax, carnauba wax, rice wax, wood wax, honey wax, montan wax , Ozokerite, Celesin, Paraffin Wax, Microcrystalin Wax, Petrolatum, Fisher Tropsch Wax, Polyethylene Wax, Ethylene-propylene Copolymer and other Waxes; Palm Oil, Palm Oil, Palm Core Oil, Saflower Oil, Olive Oil, Himasi Oil, Avocado Oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat Vegetable fats and oils such as germ oil, flaxseed oil, cotton seed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, Animal fats and oils such as horse fat, egg yolk oil, mink oil, turtle oil; animal waxes such as whale wax, lanolin, orange raffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption-purified lanolin, lanolin acetate, liquid acetate lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine , Phospholipid ethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin and other sphingophospholipids, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof, phospholipids such as lysolecithin; hydrogenated soybean phospholipids, partially hydrogenated soybeans Phospholipid derivatives such as phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, N-lauroyl -L-Glutamate di (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl- Di (phytosteryl / octyldodecyl) L-glutamate, acylsarcosine alkyl esters such as N-lauroyl sarcosin isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, isostearyl Sterol esters such as soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long-chain branched fatty acid cholesteryl, long-chain α-hydroxy fatty acid cholesteryl; phospholipid / cholesterol complex, phospholipid / phytosterol complex and other lipid complexes; myristic acid Octyldodecyl, hexyldecyl myristate, octyldodecyl isostearate, cetyl parimitinate, octyldodecyl palmitate, cetyl octanoate, hexyldecyl octanoate, isotridesyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate , Isotridecyl neopentate, Isostearyl neopentate, Octyldodecyl neodecanoate, Oleyl oleate, Octi oleate Ludodecyl, octyldodecyl ricinoleate, octyldodecyl lanolin fatty acid, dicaprylic carbonate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, hardened isostearic acid castor oil, ethyl oleate, ethyl avocado oil fatty acid, isopropyl myristate, isopropyl palmitate, palmitin Octyl acid, isopropyl isostearate, isopropyl lanolin fatty acid, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methylheptyl isostearate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyl sebacate Monoalcoholic carboxylic acid esters such as octyl, diisobutyl adipate, dioctyl adipate, dioctyl succinate, triethyl citrate; oxy such as cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate, γ-ercalactone Acid esters; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (caprylic acid / capric acid), tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl, hydrogenated Rozin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl benoic acid, glyceryl trioctanoate, trimethylolpropane triisostearate, neopentylglycol dioctanoate, neopentyl glycol dicaprate, dioctanoic acid 2-Butyl-2-ethyl-1,3-propanediol, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate, ditrimethylol (isostearic acid / sebacic acid) Propane, pentaerythricyl triethylhexanoate, (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl nonaisostearate-10, deca (erucic acid / isostearic acid / ricinoleic acid) Polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (d. distearate) Polyhydric alcohol fatty acid esters such as (tyrene glycol), 3-methyl-1,5-pentanediol dineopenate, 2,4-diethyl-1,5-pentanediol dineopenate; alkyl ethers such as dicaprylyl ether; die Diisopropyl dimersinolate, diisostearyl dimerserinolate, dimerselyl dimerglinolate (isostearyl / phytosteryl), dimerglinolic acid (phytosteryl / behenyl), dimerserinolic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) ), Dimerdilinoleic acid Dimerdilinoleil, Diomadylinorail diisostearate, Dimersylinoleyl hydrogenated rosin condensate, Dimergylinoleic acid-cured castor oil, Dimericicic dimeric acid or Dimerdiol such as hydroxyalkyl Dimergylinoleil ether Derivatives of: Palm oil fatty acid monoethanolamide (cocamide MEA), palm oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide). MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA) and other fatty acid alkanolamides; dimethicone (dimethylpolysiloxane), highly polymerized dimethicone ( Highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, (aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin , Amino-modified silicones such as silicone rubber, aminopropyl dimethicone and amodimethicone, polyether-modified silicones such as cation-modified silicones and dimethicone copolyols, polyglycerin-modified silicones, sugar-modified silicones, carboxylic acid-modified silicones, phosphate-modified silicones, sulfuric acid. Modified silicones, alkyl-modified silicones, fatty acid-modified silicones, alkyl ether-modified silicones, amino acid-modified silicones, peptide-modified silicones, fluorine-modified silicones, cation-modified and polyether-modified compounds. Silicones such as licone, amino-modified and polyether-modified silicones, alkyl-modified and polyether-modified silicones, amidoalkyl-modified silicones, aminoglycol-modified silicones, aminophenyl-modified silicones, polysiloxane / oxyalkylene copolymers; perfluorodecane, Fluoro-based oils such as perfluorooctane and perfluoropolyether are preferred.

Examples of the moisturizing agent / feel improving agent include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, and the like. Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymers and their polymers; diethylene glycol monoethyl ether Glycolalkyl ethers such as (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosandioic acid / tetradecanedioic acid) polyglyceryl-10, polyglyceryl-10 tetradecanedioate, cyclohexanedicarboxylic acid Water-soluble esters such as bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, martitol; glucose, fructose, galactose, mannose, treose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, Trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, Heparin and derivatives, saccharides such as pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer and derivatives thereof; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate , Caronine sulfate, keratosulfate, dermatan sulfate; white jellyfish extract, white jellyfish polysaccharide; inulin (Nippon Seisei), levan and other fluctanes; fucoidan; tuberose polysaccharide, naturally occurring polysaccharide; citric acid, tartaric acid, lactic acid, etc. Organic acids and salts thereof; ureas; 2-pyrrolidone-5-carboxylic acids and salts such as sodium thereof; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β- Ara Amino acids such as nin, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, Collagen-degrading peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degrading peptide, keratin-degrading peptide, hydrolyzed keratin, conchiolin-degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium , Soybean proteolytic peptides, wheat proteolytic peptides, hydrolyzed wheat proteins, casein-degrading peptides, acylated peptides and other protein peptides and their derivatives; palmitoyl oligopeptides, palmitoyl pentapeptides, palmitoyl tetrapeptides and other acylated peptides; Cyrilized peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mutin, hypotaurine, sesame lignan glycoside, glutathione, albumin, lactose; choline chloride, phosphorylcholine; placenta extract, aerastin, collagen, Animal / plant extracts such as aloe extract, hamamelis water, hechima water, chamomile extract, kanzo extract, comfrey extract, silk extract, isayoibara extract, sycamore extract, eucalyptus extract, melilot extract, natural ceramide (type 1, type 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudo-ceramides, sphingoglycolipids, ceramides and ceramides such as sugar ceramide-containing extracts are preferable.

Preferred examples of the surfactant include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, and polymer surfactants. The HLB of the surfactant is not particularly limited and can be used from a low HLB of about 1 to a high HLB of about 20, and it is also preferable to combine a low HLB and a high HLB. Examples of preferred surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate and ammonium lauryl sulfate; laureth. Polyoxyethylene alkyl sulfates such as sodium sulfate and triethanolamine laureth sulfate; sodium cocoyl methyl taurine, potassium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium myristyl methyl taurine, sodium lauroyl methyl alanine, sodium lauroyl sarcosin, and lauroyl sarcosin triethanol. Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroyl glutamate; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine. , Acyl amino acid salts such as lysine Na dilauroyl glutamate; Polyoxyethylene alkyl ether acetate salts such as sodium laures acetate; Sulfonic acid ester salts such as sodium lauroyl monoethanolamide succinate; Fatty acid alkanolamide ether carboxylates; Acyl lates Polyoxyethylene fatty amine sulfate; fatty acid alkanolamide sulfate; hardened coconut oil fatty acid fatty acid glyceride sulfate such as sodium glycerin sulfate; alkylbenzene polyoxyethylene sulfate; olefin sulfonate such as α-olefin sulfonate; sulfosuccin Alkyl sulfosuccinates such as sodium lauryl sulphate, sodium dioctyl sulfosuccinate; alkyl ether sulfosuccinates such as sodium laures sulfosuccinate, monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; tetradecyl Alkyl benzene sulfonates such as sodium benzene sulfonate, triethanolamine tetradecyl benzene sulfonic acid; alkyl naphthalene sulfonate; alkane sulfonate; α-sulfo fatty acid methyl ester salt; acyl acetylionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetate; Alkyl ether phosphate such as sodium laureth phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monoolesphosphate; Alkyl phosphate such as potassium lauryl phosphate; Sodium caseinate; Alkyl aryl ether Phosphate; fatty acid amide ether phosphate; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; silicone-based such as carboxylic acid-modified silicone, phosphoric acid-modified silicone, sulfate-modified silicone Anionic surfactants, etc .; Among nonionic surfactants, laures (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steares (polyoxyethylene stearyl ether), behenes (polyoxy) Polyoxyethylene alkyl ethers with various polyoxyethylene additions such as ethylene behenyl ethers), isosteares (polyoxyethylene isostearyl ethers), octyldodeces (polyoxyethylene octyldodecyl ethers); polyoxyethylene alkylphenyl ethers; Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene cured castor oil monoisostearate, polyoxyethylene cured castor oil triisostearate, polyoxyethylene cured castor oil monopyroglutamic acid monoisostearic acid diester, poly Oxyethylene hardened bean oil and hardened bean oil derivatives such as maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxy Protinic cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene glycerin ether, etc. Polyoxyethylene / polyoxypropylene alkyl ether; polyoxyethylene / polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; Glycerin such as ceryl, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, coconut oil fatty acid glyceryl, monocotton oil fatty acid glycerin, monoercaate glycerin, sesquioleate glycerin, α, α'-pyroglutamate oleate Partial fatty acid esters; polyglyceryl-2, 3, 4, 5, 6, 6, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate-2, polyglyceryl decastearate- 10, Polyglyceryl-2 isostearate-2, 3, 4, 5, 6, 8, 8, 10, Polyglyceryl diisostearate-2 (diglyceryl diisostearate), 3, 10, Polyglyceryl triisostearate-2 , Polyglyceryl-2 tetraisostearate, Polyglyceryl-10 decaisostearate, Polyglyceryl-2 oleate 3, 3, 4, 5, 5, Polyglyceryl dioleate-6, Polyglyceryl trioleate- 2. Polyglycerin fatty acid ester such as polyglyceryl-10 decaoleate; ethylene glycol monofatty acid ester such as ethylene glycol monostearate; propylene glycol monofatty acid ester such as propylene glycol monostearate; pentaerythritol partial fatty acid ester; sorbitol partial fatty acid ester Glyceride partial fatty acid ester; Glyceride ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, penta-2- Solbitan fatty acid esters such as diglycerol sorbitan ethylhexylate and diglycerol sorbitan tetra-2-ethylhexylate; sugar derivative partial esters such as sucrose fatty acid ester, methyl glucoside fatty acid ester and trehalose undecylate; alkyl glucosides such as caprylyl glucoside; alkyl Polyglycoside; glycolipids such as mannosyl erythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate, etc. Glyceride mono Diester; polyoxyethylene / propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate, etc. Glycerin fatty acid ester; polyoxyethylene sorbitan fatty acid ester such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate , Polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, polyoxyethylene sorbitol monostearate and other polyoxyethylene sorbitol fatty acid esters; polyoxyethylene methyl glucoside fatty acid esters; polyoxyethylene alkyl ether fatty acid esters; poly Polyoxyethylene animal and vegetable oils and fats such as oxyethylene sorbitol mitsuro; alkyl glyceryl ethers such as isostearyl glyceryl ethers, chimyl alcohols, ceracyl alcohols and batyl alcohols; polyhydric alcohol alkyl ethers; polyoxyethylene alkyl amines; tetrapolyoxy Ethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin and sophorolipid; polyoxyethylene fatty acid amide; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), Lauric acid monoethanolamide (lauramide MEA), laurate diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA), palm oil Fatty acid alkanolamides such as fatty acid methylethanolamide (cocamidomethyl MEA); alkyldimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, behenamine oxide; alkylethoxydimethylamine oxide; polyoxyethylene alkyl mercaptan; Polyether-modified silicones such as dimethicone copolyols, polysiloxanes -Silicone-based nonionic surfactants such as oxyalkylene copolymers, polyglycerin-modified silicones, and sugar-modified silicones; among cationic surfactants, behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, and lauryl. Alkyltrimethylammonium chloride such as trimonium chloride; Alkyltrimethylammonium bromide such as stearyltrimonium bromide; Dialkyldimethylammonium chloride such as distearyldimonium chloride and dicocodimonium chloride; stearamidepropyldimethylamine, stearamideethyldiethylamine and the like Fatty acid amidoamine and its salts; alkyl ether amines such as stearoxypropyl dimethylamine and its salts or quaternary salts; ethyl sulfate long chain branched fatty acids (12-31) aminopropyl ethyl dimethyl ammonium, ethyl sulfate lanolin fatty acids aminopropyl ethyl dimethyl ammonium Such as fatty acid amide type quaternary ammonium salt; polyoxyethylene alkylamine and its salt or quaternary salt; alkylamine salt; fatty acid amide guanidium salt; alkyl etheraminemonium salt; alkyltrialkylene glycol ammonium salt; benzalconium Salts; benzethonium salts; pyridinium salts such as cetylpyridinium chloride; imidazolinium salts; alkylisoquinolinium salts; dialkylmoriphonium salts; polyamine fatty acid derivatives; amino-modified silicones such as aminopropyldimethicone and amodimethicone, cation-modified silicones , Cationic-modified and polyether-modified silicones, Amino-modified and polyether-modified silicones and other silicone-based cationic surfactants; among amphoteric surfactants, N-alkyl-N such as lauryl betaine (lauryldimethylaminoacetic acid betaine) , N-dimethyl amino acid betaine; fatty acid amide alkyl-N, N-dimethyl amino acid betaine such as cocamidopropyl betaine and lauramide propyl betaine; imidazoline type betaine such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfo such as alkyldimethyltaurine Betaine; Sulfate-type betaine such as alkyldimethylaminoethanol sulfate ester; Phosphate-type betaine such as alkyldimethylaminoethanol phosphate; Phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphine Sphingo phospholipids such as gomelin, lysolecithin, hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, phospholipids such as lecithin hydroxide; Etc .; As the polymer surfactant, polyvinyl alcohol, sodium alginate, starch derivative, tragant gum, acrylic acid / alkyl methacrylic acid copolymer; various silicone-based surfactants are preferable.

Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, farcerelan, karaya gum, trolley aoi, cara gum, tragant gum, pectin, pectic acid and sodium. Salts such as salts, salts such as alginic acid and sodium salts, mannan; starches such as rice, corn, potatoes, wheat; xanthan gum, dextran, succinoglucan, curdran, hyaluronic acid and its salts, zansan gum, purulan, gellan gum, chitin , Chitosan, agar, casso extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and salts such as sodium thereof, methyl hydroxypropyl cellulose, sodium cellulose sulfate, dialkyldimethyl Cellulose sulfate, crystalline cellulose, cellulose powder and other cellulose and derivatives thereof; starch-based polymers such as soluble starch, carboxymethyl starch, methylhydroxypropyl starch and methyl starch, hydroxypropyltrimonium chloride starch, corn starch aluminum octenyl succinate and the like. Alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), vinylpidridone / vinyl alcohol copolymer, polyvinylmethyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene Polyoxypropylene copolymer; amphoteric methacrylate copolymer such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrelites / stearyl acrylate / ethylamine methacrylate) copolymer; (dimethicone / vinyldimethicone) cloth Polymers, (alkyl acrylate / diacetone acrylamide) copolymers, (alkyl acrylate / diacetone acrylamide) copolymers AMP; partially saponified polyvinyl acetate, maleic acid copolymers; vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymers; Acrylic resin alkanolamine; polyester, water-dispersible polymer; polya Crylamide; polyacrylic acid ester copolymer such as ethyl polyacrylic acid, carboxyvinyl polymer, salt such as polyacrylic acid and sodium salt thereof, acrylic acid / methacrylic acid ester copolymer; acrylate / alkyl methacrylic acid Polymers: cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid such as polyquaternium-39. -Diallyldimethylammonium chloride-acrylamide copolymer, acrylic acid-cationized methacrylic acid ester copolymer, acrylic acid-cationized methacrylic acid amide copolymer, polyquaterium-47 and other acrylic acid-methyl acrylate-chloride Methacylamide propyltrimethylammonium copolymer, choline chloride methacrylate polymer; cationized oligosaccharide, cationized dextran, cationized polysaccharide such as guarhydroxypropyltrimonium chloride; polyethyleneimine; cationic polymer; polyquaternium-51 and the like. 2-Polymer of methacryloyloxyethyl phosphorylcholine and polymer with butyl methacrylate copolymer, etc .; acrylic resin emulsion, ethyl polyacrylate emulsion, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, synthetic Polymer emulsions such as latex; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and Its salts; dextrin fatty acid esters such as dextrin palmitate, dextrin myristinate; silicic anhydride, fuming silica (ultrafine anhydrous silicic acid), aluminum magnesium silicate, sodium magnesium silicate, metal soap, metal dialkyl phosphate, Bentonite, hectrite, organically modified clay minerals, sucrose fatty acid esters, fructo-oligosaccharide fatty acid esters are preferred.

Examples of solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, and isopentyldiol. Kind: Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as: ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, glycol ether esters such as propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate and ethylene glycol disuccinate; benzyl Preferables include propellants such as alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation freon; LPG, dimethyl ether, and carbon dioxide.

Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; bisulfite derivatives such as propyl bisulfite; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; Sulfites such as sodium sulfite; hydrogen sulfites such as sodium hydrogen sulfite; thiosulfites such as sodium thiosulfite; metahydrosulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride are preferable. Is listed as. As the reducing agent, thioglycolic acid, cysteine, cysteamine and the like are preferable. As the oxidizing agent, hydrogen peroxide solution, ammonium persulfate, sodium bromate, percarbonate and the like are preferable.

Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane. 1,2-Alcandiols such as diols; Alkylglyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); Salicylic acid; Sodium benzoate; Isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; Imidazo Linium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zincpyrythion, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, glucon Chlorhexidine acid, halocarban, hexachlorophenol, hinokithiol; other phenols such as phenol, isopropylphenol, cresol, timol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolite, silver ion However, when used as an antibacterial agent or an antiseptic for the purpose of antiseptic, from the viewpoint of safety of cosmetics or external preparations for skin, phenoxyethanol; 1,2-pentanediol, 1,2-hexane It is more preferable to use 1,2-alkanediols such as diols and 1,2-octanediols; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ethers.

Examples of the chelating agent include edetates (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytate; ethidroic acid and the like. Phosphonic acid and salts such as sodium salts thereof; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphate; sodium citrate, citric acid, alanine, dihydroxyethylglycine , Gluconic acid, ascorbic acid, succinic acid, tartrate acid are preferred. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol. Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylated Preferred are sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate.

As powders, mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, white mica, gold mica, synthetic mica, red mica, black mica, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, kay Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (eg zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, navy blue, carbon black, titanium oxide, fine particles and ultrafine titanium oxide, zinc oxide , Fine and ultrafine zinc oxide, alumina, silica, fumigant silica (ultrafine anhydrous silicic acid), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine gold mica, fine particle composite powder, gold, aluminum, etc. Inorganic powders of various sizes and shapes, and these are treated with silicones such as hydrogen silicone and cyclic hydrogen silicone or other surface treatment agents such as silane or titanium coupling agents to make them hydrophobic or Inorganic powder such as hydrophilized powder; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate -Polymethylmethacrylate laminated powder, polyethylene terephthalate, aluminum, epoxy laminated powder, etc., urethane powder, silicone powder, Teflon (registered trademark) powder, and other organic powders and surface treatment powders of various sizes and shapes, organic and inorganic Composite powders are preferred. Inorganic salts include sodium chloride-containing salts such as salt, normal salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, ginger, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, etc. Aluminum / potassium sulfate (myoban), aluminum / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na / 2Na / 3Na phosphate, phosphate Potassiums, calcium phosphates and magnesium phosphates are preferred.

Examples of the ultraviolet absorber include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, N, N-dimethylparaaminobenzoate ethyl. An benzoic acid-based ultraviolet absorber such as ester, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; anthranilic acid-based ultraviolet absorber such as homomentyl-N-acetylanthranilate; salicylic acid And salicylic acid-based ultraviolet absorbers such as sodium salt, amylsalicylate, menthylsalicylate, homomentylsalicylate, octylsalicylate, phenylsalicylate, benzylsalicylate, p-isopropanol phenylsalicylate; octylcinnamate, ethyl-4-isopropylcinnamate, methyl. -2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxy cinnamate, isopropyl-p-methoxy cinnamate, isoamyl-p-methoxy Synnamete, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenyl Ceramic acid-based ultraviolet absorbers such as cinnamate, 2-ethylhexyl α-cyano-β-phenyl cinnamate (octocrine), glycerylmono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and derivatives thereof; 2, 4-Dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2', 4,4'-tetrahydroxybenzophenone, 2-hydroxy- 4-Methoxybenzophenone (oxybenzon-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4' Benzophenones such as −phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone UV absorbers; 3- (4'-methylbenziliden) -d, l-phenyl, 3-benziliden-d, l-phenyl; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 -Methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoilmethane; 5-( 3,3-Dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octylriazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate 2- (2'-Hydroxy-5'-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentandione, dimethoxybenzilidendioxoimidazolidine propionic acid Hydantin derivatives such as 2-ethylhexyl, phenylbenzimidazole sulfonic acid, terephthalilidene dicanfursulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives are preferred.

Examples of vitamins and their derivatives include vitamin A such as retinol, retinol acetate, and retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxin hydrochloride, pyridoxin dioctanoate, and pyridoxin dipalmitate. Flavin adenine dinucleotide, cyanocobalamine, folic acids, nicotinic acids such as nicotinic acid amide and benzyl nicotinate, vitamin B group such as choline; vitamin Cs such as salts of ascorbic acid and its sodium; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as sodium ascorbic acid phosphate and magnesium ascorbic acid ester, tetra ascorbic acid Ascorbic acid fatty acid esters such as isoparmic acid ester, ascorbyl stearate, ascorvir palmitate, ascorvir dipalmitate, alkyl ascorbic acid ethers such as ethyl ascorbic acid, ascorbic acid glucosides such as ascorbic acid-2-glucoside, and their fatty acid esters. , Ascorbic acid derivatives such as tocopheryl ascorbyl phosphate; vitamin derivatives such as tocopherols such as tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, tocopherol ferrate, tocopherol phosphate, tocotrienol, and various other vitamin derivatives are preferable. Is listed as.

Anti-inflammatory and anti-inflammatory agents include glycyrrhizinic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokithiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract. , Plant extracts such as Honoha extract are preferred. As hair growth agents, blood circulation promoters, and stimulants, plant extracts and tinctures such as senburi extract, togarashi tincture, ginger tincture, ginger extract, and cantarist tincture; capsaicin, nonylate valenylamide, gingerone, ictamol, and tannic acid. , Borneol, cyclanderate, cinnaridine, trazoline, acetylcholine, verapamil, cepharanthin, γ-orizanol, cepharanthin, vitamin E and derivatives such as tocopherol nicotinate / tocopherol acetate, γ-orizanol, nicotinic acid and nicotinic acid amide / benzyl nicotinate. Derivatives such as ester inositol hexanicotinate and nicotine alcohol, allantin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivative, stigmasterol or stigmasterol and its glycoside, minoxidil are preferable. Is listed as. As the hormones, estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like are preferable. Other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cold sensitizers, warming agents, wound healing promoters, stimulants, analgesics, cell activators, etc. include retinols, retinoic acids, retinoins. Tocopheryl acid; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and its glycosides / esterified products, hydroxycapric acid, long-chain α-hydroxy fatty acid, long-chain α-hydroxy fatty acid cholesteryl and other α- or β-Hydroxy acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosin; creatin; ceramides, spingosins; caffeine, xanthin and its derivatives; coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloids, fullerene and other antioxidants and active oxygen scavengers; catechins; quercetin and other flavones; isoflavones; gallic acid and ester sugar derivatives; tannins, sesamine, proto Polyphenols such as anthocyanidin, chlorogenic acid, apple polyphenols; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; kanzo extract-related substances such as glabridin, glabrene, liquilithin, isoliquiritin; lactoferrin Glycoside, gingerol; fragrance substances such as menthol, camphor, sedrol and its derivatives; capsaicin, vanillin and the like and derivatives; insect repellents such as diethyl toluamide; complexes of physiologically active substances and cyclodextrins are preferred. Can be mentioned.

Plant / animal / microbial extracts include iris extract, acitaba extract, asunaro extract, asparagus extract, avocado extract, flaxseed extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract. , Inchikou extract, Uikyo extract, Ukon extract, Woolong tea extract, Uwaurushi extract, Agetsu extract, Echinashi leaf extract, Enmeisou extract, Ogon extract, Oubaku extract, Ouren extract, Omugi extract, Otanenjinjin extract, Otogirisou extract, Odori kosou extract, Ononis extract , Dutch mustard extract, orange extract, dried seawater, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, cucumber extract, chamomile extract, oil-soluble chamomile extract, carrot extract, kawarayomogi Extract, crow wheat extract, calcade extract, kanzo extract, oil-soluble kanzo extract, kiwi extract, kiou extract, kikurage extract, kina extract, cucumber extract, kiri leaf extract, guanosine, guava extract, kujin extract, kuchinashi extract, kumazasa extract, clara extract, walnut Extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, quail extract, gentiana extract, gennoshouko extract, tea extract, yeast extract, koboku extract, coffee extract, gobo extract, rice extract, rice Fermented extract, fermented rice bran extract, rice germ oil, comfrey extract, collagen, moss peach extract, saishin extract, psycho extract, saitai extract, saffron extract, salvia extract, sabonsou extract, sasa extract, sanzashi extract, sansha extract, sansho Extract, Shiitake extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shimotsukesou extract, Jatoba extract, Shakuyaku extract, Shokyu extract, Shobu root extract, Shirakaba extract, White chrysanthemum extract, Sugina extract, Stevia extract, Stevia fermented product, Nishikawayanagi extract, Seiyoukizuta extract, Seiyousanzashi extract, Seiyouniwatoko extract, Seiyounokogirisou extract, Seiyouhakka extract, Sage extract, Zeniaoi extract, Senkyu extract, Senburi extract, Souhakuhi extract, Daiou extract, Dai Zu extract, Taisou extract, Thyme extract, Dandelion extract, Local clothing extract, Tea extract, Chouji extract, Chigaya extract, Chinpi extract, Tea tree oil, Jincha extract, Togarashi extract, Touki extract, Tokinsenka extract, Tounin extract, Tohi extract, Dokudami extract, Tomato Extract, Natto extract, Carrot extract, Carrot extract, Novara extract, Hibiscus extract, Bakumondou extract, Hass extract, Parsley extract, Birch extract, Honey, Hamamelis extract, Paris etalia extract, Hikiokoshi extract, Bisaborol, Hinoki extract, Bifizus bacterium extract, Biwa extract, Fukitanpopo extract, Fukinotou extract, Bukuryo extract, Butcher bloom extract, Grape extract, Grape seed extract, Propolis, Hechima extract, Benibana extract, Peppermint extract, Bodaiju extract, Button extract, Hop extract, Maikaika extract, Pine extract, Maronie extract , Mizubasho extract, Mukuroji extract, Melissa extract, Mozuku extract, Peach extract, Yagurumagiku extract, Eucalyptus extract, Yukinoshita extract, Yuzu extract, Yuri extract, Yokuinin extract, Yomogi extract, Lavender extract, Green tea extract, Eggshell membrane extract, Apple extract, Louis Boss tea extract , Reishi extract, lettuce extract, lemon extract, lotus extract, lotus extract, rose extract, rosemary extract, roman chamomile extract, royal jelly extract, crackle extract and the like are preferable.

Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, zinc paraphenol sulfonate and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum / potassium sulfate, tannic acid and the like. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease and the like. Preferred examples of nucleic acids include ribonucleic acid and a salt thereof, deoxyribonucleic acid and a salt thereof, and disodium adenosine triphosphate.

As fragrances, acetylsedrene, amylcinnamaldehyde, allylamylglycolate, β-ionone, isoe super, isobutylquinolin, iris oil, iron, indol, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragor, Eugenol, Oak Moss, Opoponax Resinoid, Orange Oil, Eugenol, Oranthiol, Galax Solid, Carbachlor, L-Carbon, Camper, Cannon, Carrot Seed Oil, Clove Oil, Methyl Caynate, Geraniol, Geranyl nitrile , Isobornyl acetate, Geranyl acetate, Dimethylbenzylcarbinate acetate, Styralyl acetate, Cedril acetate, Telepinel acetate, pt-butylcyclohexyl acetate, Vetiberyl acetate, benzyl acetate, Linalyl acetate, Isopentyl salicylate, benzyl salicylate, Sandalwood oil, Santalol, Cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citroneral, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylux Resinoid, cedarwood oil, sedren, sedrol, celery seed oil, thyme oil, damascon, damasenon, timol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinen, triplar, nerol, nonanaal, 2,6-nonazienol, nonalactone, pachori Alcohol, vanilla absolute, vanillin, basil oil, patcholi oil, hydroxycitroneral, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian balsam, vetiver oil, vetiverol , Peppermint oil, pepper oil, heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, muskketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menton, eucalyptus oil, β-yonone, lime oil , Lavender oil, D-limonone, linalool, lylar, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, synthetic fragrances such as various essential oils and natural Fragrances and various blended fragrances are preferred.

As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 3, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1, Red 105-1, Red 106, Red 2, Red 3, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207 , Red 208, Red 213, Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230-1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503 , Red No. 504, Red No. 505, Red No. 506, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 205, Orange No. 206, Orange No. 207, Orange No. 401, Orange No. 402, Orange No. 403, Yellow 201, Yellow 202-1, Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow Legal dyes such as 405, Yellow 406, Yellow 407, Yellow 5; Other acidic dyes such as Acid Red 14; Basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26 and other nitro dyes; Disperse dyes; Inorganic white pigments such as titanium dioxide and zinc oxide; Inorganic red pigments such as iron oxide (Bengala) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow such as yellow iron oxide and yellow clay System pigments: Inorganic black pigments such as black iron oxide and low-order titanium oxide; Inorganic substances such as mango violet and cobalt violet Purple pigments; Inorganic green pigments such as chromium oxide, chromium hydroxide, cobalt titanate; Inorganic blue pigments such as ultramarine and dark blue; Titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored oxidation Pearl pigments such as titanium coated mica, bismuth oxychloride, fish scale foil; metal powder pigments such as aluminum powder, copper powder, and gold; anthracinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsantin, chalcone, calsamine, Naftquinones such as quercetin, crosin, chlorophyll, curcumin, cochineal and ciconin, bixins, flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, natural pigments and dyes such as rutin; p-phenylenediamine, toluene-2,5 Oxidizing dyes such as -diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and salts thereof. Body and couplers; auto-oxidizing dyes such as indolin; dihydroxyacetones are preferred.

As the water, in addition to normal water and purified water, hard water, soft water, natural water, deep ocean water, electrolytic alkaline ionized water, electrolytically acidic ionized water, ionized water, and cluster water are preferable.

In addition to these, cosmetic ingredient standards, compounding ingredient standards by cosmetic type, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), non-pharmaceutical ingredient standard, Japanese pharmacy, pharmaceutical additives Ingredients described in standards, food additive official regulations, etc., and Japanese and foreign patent gazettes and patent publication gazettes (including publication gazettes and republishing) whose international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the described ingredients, in known combinations, blending ratios, and blending amounts.

The types of cosmetics or skin external preparations containing the O / W type emulsifying composition of the present invention include hair cosmetics, skin cosmetics, make-up cosmetics, aromatic cosmetics, body cosmetics, ointments and the like. Examples include skin external preparations. These can be manufactured according to conventional methods.

Explaining the types of the cosmetics or external preparations for skin of the present invention in more detail, the hair cosmetics include shampoos such as oil shampoo, cream shampoo, styling shampoo, indulgence shampoo, hair coloring shampoo, and rinse-integrated shampoo. Rinse, treatment, hair pack, hair foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair tonic, hair liquid, pomade, tic, hair cream, hair blow, split hair coat , Hair oil, permanent wave agent, straight perm agent, oxidative hair dye, hair bleach, hair color pretreatment, hair color after treatment, perma pretreatment, perma after treatment, hair manicure, hair restorer are preferable.

As skin cosmetics, softening lotion, astringent lotion, cleansing lotion, multi-layered lotion and other lotions; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisturizer, moisturizer -Emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sun screen, make-up lotion, horny smoother, elbow lotion, hand lotion, body lotion and other emulsions; emollient cream, nutrition cream, Nourishing Cream, Vanishing Cream, Moisture Cream, Night Cream, Massage Cream, Cleansing Cream, Makeup Cream, Base Cream, Pre-Makeup Cream, Sunscreen Cream, Suntan Cream, Hair Removal Cream, Deodorant Cream, Shaving Cream, Keratin Softening Creams such as creams; Gels such as moisture gels; Essences such as moisturizing essences, whitening essences, and UV protection essences; Lipstick cosmetics such as liposome beauty liquids and liposome cosmetics; Peel-off packs, powder packs, washing packs, oil packs, cleansing Packs and masks such as masks; cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing oil, cleansing mask, cleansing powder, facial cleansing powder, etc.; cosmetic soap, transparent soap, medicated soap, liquid soap, Soaps such as shaving soaps and synthetic cosmetic soaps are preferred.

Preferable makeup cosmetics include white powder / dusting powder, foundations, lipsticks, lip gloss, blusher, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment. ..

Preferred examples of the aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, eau de cologne, perfume paste, fragrance powder, perfume soap, body lotion, and bath oil.

Body cosmetics include body cleaners such as body shampoo, deodorant lotions, deodorant powders, deodorant sprays, deodorant cosmetics such as deodorant sticks, depigmenting agents, depilatory / depilatory agents, bathing agents, insect repellent sprays, etc. Repellers are preferred.

Further, as the external preparation for skin, it can be used in a dosage form such as an ointment, a patch, a lotion, a liniment, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

The dosage form of the cosmetic or skin external preparation containing the O / W type emulsified composition of the present invention includes oil-in-water (O / W) type, water-in-oil (W / O) type, and W / O / W. Emulsified cosmetics such as molds, O / W / O types, oil-based cosmetics, solid cosmetics, liquid cosmetics, paste cosmetics, stick-shaped cosmetics, volatile oil-based cosmetics, powdered cosmetics, jelly Dosage forms such as liquid cosmetics, gel cosmetics, paste cosmetics, emulsified polymer type cosmetics, sheet cosmetics, mist cosmetics, and spray cosmetics can be mentioned. Of these, those having a continuous phase in the aqueous phase can be particularly preferably used.

The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto.

O / W type emulsified compositions containing the components (A) to (C) of the present invention having the compositions shown in Tables 1 to 5 were prepared by the following preparation methods. The initial emulsifying property and emulsifying stability of the obtained O / W type emulsified composition were evaluated by the following methods. The results are also shown in Tables 1-5.

<Preparation method>
A surfactant solution was prepared by mixing the component (A) and 25 parts by weight of the component (C) with respect to 100 parts by weight of the component (A). The component (B1) and the component (B2) were stirred and mixed in a separate container to prepare a mixed solution of an oil phase. The obtained mixed solution of the oil phase was gradually added to the surfactant solution and mixed until a uniform gel was formed. The remaining component (C) was added to the obtained gel with stirring to obtain a uniform O / W type emulsified composition. All these steps were performed at room temperature.

<Initial emulsifying property>
The obtained O / W type emulsifying composition was observed with a microscope, and the initial emulsifying property was evaluated according to the following evaluation criteria.

○ ・ ・ ・ Uniformly emulsified △ ・ ・ ・ Large oil droplets are slightly observed, but almost uniformly emulsified × ・ ・ ・ Many large oil droplets are observed and not uniformly emulsified

<Emulsification stability>
The obtained O / W emulsified composition was allowed to stand at 25 ° C. for 4 weeks and then observed under a microscope to evaluate the emulsification stability according to the following evaluation criteria.

○ ・ ・ ・ Uniformly emulsified △ ・ ・ ・ Large oil droplets are slightly observed, but almost uniformly emulsified × ・ ・ ・ Many large oil droplets are observed and not uniformly emulsified

The O / W type emulsified compositions shown in Tables 1 to 5 were added to the cosmetics, and the stability over time of the obtained cosmetics was evaluated by the following method. The results are also shown in Tables 1-5.

<Stability over time after blending cosmetics>
Two kinds of cosmetics (toner, hair treatment) were prepared by the following prescription. 5 parts by weight of the O / W type emulsified composition was added to 100 parts by weight of the obtained cosmetic, and the appearance after standing at 25 ° C. for 4 weeks was observed, and the stability over time was evaluated according to the following evaluation criteria. did.

(Toner prescription)
1,3-butylene glycol 5% by weight, glycerin 5% by weight, carboxyvinyl polymer 0.1% by weight, phenoxyethanol 0.4% by weight, potassium hydroxide 0.04% by weight, purified water residue

(Hair treatment prescription)
Stealtrimonium chloride 3.5% by weight, cetearyl alcohol 4% by weight, propylene glycol 3% by weight. 1.2% by weight of ethanol, 0.3% by weight of phenoxyethanol, residual purified water

○ ・ ・ ・ No change in appearance from the beginning △ ・ ・ ・ The appearance changed slightly from the beginning × ・ ・ ・ The appearance changed significantly from the beginning

From the results in Tables 1 to 5, it was found that the O / W type emulsified composition containing the components (A) to (C) of the present invention within the blending ratio of the present invention is excellent in initial emulsifying property and emulsifying stability. It was. It was also found that the O / W type emulsified composition of the present invention exhibits good stability even after being blended in a cosmetic and diluted. On the other hand, a composition outside the blending ratio of the present invention, for example, the compositions of Comparative Examples 1 and 2 having a large content of (B1) in the component (B), and a comparison having a large content of the component (B) in the composition. With the composition of Example 3, a stable emulsified composition could not be obtained.

The cosmetics described below were prepared. When used on the skin, the obtained cosmetics had excellent moisturizing and penetrating sensations, prevented fine wrinkles and rough skin, and made the skin look plump and bright. In addition, it was excellent in moisturizing, smoothness, and smoothness when used for hair.

Example 22 Moisturizing Toner Composition Amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Composition of Example 19 5.0
Composition of Example 20 3.0
Part B purified water 40.0
Part C BG 2.0
Glycerin 3.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Glucosylceramide 0.5
1,2-Pentanediol 1.0
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.1
EDTA-2Na 0.05
Phenoxyethanol 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were stirred and mixed with a propeller mixer (500 rpm) to prepare an aqueous dispersion. Further, part C mixed in advance was added to obtain a uniform liquid.

Example 23 Moisturizing lotion
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Composition of Example 18 5.0
Composition of Example 20 3.0
Part B purified water 50.0
Polyglycerin-10 1.0
Diglycerin 2.0
Glycerin 8.0
Part C maltitol liquid 1.0
Betaine 0.5
α-Glucan oligosaccharide 0.1
Na 0.5 hyaluronate
Hydrolyzed hyaluronic acid 0.1
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Phytopresome Cera23 (Nippon Fine Chemical Co., Ltd.) 1.0
Tuberose polysaccharide 0.01
Hydroxypropyl Methyl Cellulose Stearoxy Ether 0.05
(Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer 0.05
Arginine 0.05
Phenoxyethanol 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were stirred and mixed with a propeller mixer (500 rpm) to prepare an aqueous dispersion. Further, part C mixed in advance was added to obtain a uniform liquid.

Example 24 Moisturizing Toner Composition Amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Phytopresome MEL (Nippon Fine Chemical Co., Ltd.) 1.5
BG 5.0
Glycerin 10.0
Part B purified water 40.0
Part C Composition of Example 21 8.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
PEG / PPG / Polybutylene Glycol-8 / 5/3 Glycerin 0.5
Xanthan gum 0.05
Glucosyl trehalose 0.5
Polyquaternium-51 0.5
Hydrolyzed yeast extract 1.0
Licorice extract 0.05
Aloe extract 0.05
Souhakuhi extract 0.2
Willow extract 0.2
Pentetic acid 5Na 0.05
Phenoxyethanol 0.4
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were each heated to 70 ° C., and A part was added while stirring part B with a homomixer (7000 rpm) to prepare an aqueous dispersion. Further, after cooling, part C mixed in advance was added to obtain a uniform liquid.

Example 25 Moisturizing Toner
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Glycerin 8.0
Hexylene glycol 2.0
Hydrogenated lysolecithin (Nippon Fine Chemical Co., Ltd.) 0.05
Phytopresome Cera23 (Nippon Fine Chemical Co., Ltd.) 0.05
PrimeLipid PI (Nippon Fine Chemical Co., Ltd.) 0.2
PEG-30 Phytosterol 0.2
Part B purified water 60.0
Part C Composition of Example 20 2.0
Composition of Example 21 2.0
Hydrolyzed collagen 0.05
Hydrolyzed Na 0.05 hyaluronate
Citric acid 0.01
Na citrate 0.09
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Ectoine 0.3
Na pyrrolidone carboxylate 0.1
Inositol 0.2
Arginine 0.1
Alanine 0.1
Betaine 0.1
EDTA-2Na 0.05
Phenoxyethanol 0.4
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were each heated to 70 ° C., and A part was added while stirring part B with a propeller (500 rpm) to prepare an aqueous dispersion. Further, after cooling, part C mixed in advance was added to obtain a uniform liquid.

Example 26 Moisturizing Toner
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Propane Diol 5.0
Glycerin 10.0
Glyceryl caprylate 0.5
Phytopresome Lipo-Q (Nippon Fine Chemical Co., Ltd.) 0.25
Phytopresome Asta (Nippon Fine Chemical Co., Ltd.) 0.05
LUSPLAN PI-DA (Nippon Fine Chemical Co., Ltd.) 0.05
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 0.05
Lanolin fatty acid cholesteryl (Nippon Fine Chemical Co., Ltd.) 0.05
Tocopherol 0.02
Part B purified water 60.0
Inulin-SC (Nippon Fine Chemical Co., Ltd.) 2.0
Part C Composition of Example 20 1.0
Composition of Example 15 1.0
Mannitol 1.0
PEG-30 1.0
Hydrolyzed collagen 0.1
Urea 0.1
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Na 0.05 hyaluronate
Hydroxyethyl cellulose 0.03
Carboxyvinyl polymer 0.05
Sorbitol 0.5
Phenoxyethanol 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were each heated to 70 ° C., and A part was added while stirring part B with a homomixer (7000 rpm) to prepare an aqueous dispersion. Further, the mixture was dispersed by a high-pressure emulsifier (Mizuho Industrial Microfluidizer). After cooling, part C mixed in advance was added to obtain a uniform liquid.

Example 27 Whitening lotion compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A PrimeLipid PI (Nippon Fine Chemical Co., Ltd.) 0.5
Glycerin 8.0
Part B Composition of Example 17 3.0
Composition of Example 20 1.0
3-O-Ethyl ascorbic acid (Nippon Fine Chemical Co., Ltd.) 1.0
Tranexamic acid (Nippon Fine Chemical Co., Ltd.) 2.0
Arbutin (Nippon Fine Chemical Co., Ltd.) 1.0
Purified water 30.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Inulin-SC (Nippon Fine Chemical Co., Ltd.) 2.0
Ethanol 3.0
Methylgluces-10 2.0
Glycyrrhizinate 2K 0.05
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.02
Xanthan gum 0.03
Hydroxyethyl cellulose 0.05
Gellan gum 0.03
Phenoxyethanol 0.2
Glyceryl caprylate 0.5
Na edetate 0.1
Citric acid 0.1
Na citrate Amount at which pH becomes 4.5 Part C Amount at which the total amount of purified water becomes 100 ----------------- −−−−−−−−−−
(Preparation method)
Part B was mixed to prepare a viscous liquid. A part and C part were each heated to 70 ° C., and A part was added while stirring part C with a homomixer (7000 rpm) to prepare an aqueous dispersion. Further, after cooling, part B mixed in advance was added to obtain a uniform liquid.

Example 28 Whitening lotion compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Composition of Example 18 10.0
Part B tranexamic acid (Nippon Fine Chemical Co., Ltd.) 2.0
Ascorbic acid 2-glucoside 1.0
Phytic acid 0.30
Purified water 20.0
Scutellaria extract 0.2
Peony extract 0.2
Tripropylene glycol 2.0
Glyceryl laurate 0.5
DPG 2.0
Maltose 1.0
Carbomer 0.01
Glutamic acid 0.2
Phenoxyethanol 0.4
Citric acid 0.05
Appropriate amount of Na citrate C part Purified water Amount that makes a total of 100 ------------------------------------------------------------------------------------------------------------ −−−−
(Preparation method)
Part B was mixed to prepare a viscous liquid. Part A was added while stirring the parts with a propeller mixer (700 rpm) to prepare an aqueous dispersion. Further, part B mixed in advance was added to obtain a uniform liquid.

Example 29 Gel lotion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Glycerin 10.0
Composition of Example 18 15.0
Niacinamide 1.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Diglycerin 3.0
Tripropylene glycol 3.0
PPG-9 glyceryl 1.0
PEG-150 3.0
Purified water 10.0
Part B Pullulan 0.2
Ethylhexyl glycerin 0.2
Polymethacryloyl lysine 0.05
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Locust bean gum 0.03
Hydroxyethyl cellulose 0.05
(Acrylic acid / Perfluorohexyl ethyl acrylate) Cross polymer 0.05
Xanthan gum 0.05
Hyaluronate Na 0.01
Carbomer 0.06
Hydroxide K 0.08
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was uniformly dispersed at room temperature. Part B was mixed and stirred to obtain a viscous liquid. Part A was added to part B to make a uniform liquid.

Example 30 Transparent gel
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Glycerin 5.0
PPG-6 decyltetradeceth-30 0.2
Sucrose laurate 0.3
Phytopresome MEL (Nippon Fine Chemical Co., Ltd.) 0.8
Purified water 40.0
Part B PEG-4M 0.2
Phenoxyethanol .3
Methylgluces-10 1.0
Pyridoxine hydrochloride 0.05
Ethylhexyl glycerin 0.2
Phenoxyethanol 0.4
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.01
Hydrolyzed collagen 0.01
Pentetic acid 5Na 0.05
Amount of purified water totaling 100 Part C Composition of Example 20 1.0
Composition of Example 2 5.0
(Dimethyltaurine ammonium acrylate / vinylpyrrolidone) Copolymer 0.05
(Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer 0.15
Arginine 0.25
Purified water 20.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was stirred with a propeller to prepare a nanovesicle solution. Part C was mixed to obtain a viscous liquid. Part B was mixed to obtain a uniform liquid. A part and B part were added to C part to make them uniform.

Example 31 Skull lotion
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Composition of Example 20 3.0
Glycerin 6.0
Purified water 50.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Tocopherol acetate 0.05
Menthol 0.1
Betaine 0.2
Swertia japonica extract 0.1
Sinomenium acutum root extract 0.003
Hinokitiol 0.1
Phenoxyethanol 0.3
PCA-Na 0.1
Carbomer 0.01
Hydroxide K 0.01
Pentetic acid 5Na 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were mixed to make a uniform solution.

Example 32 Hair restorer
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A PrimeLipid PI (Nippon Fine Chemical Co., Ltd.) 0.25
1,2-Pentanediol 5.0
Phytopresome MEL (Nippon Fine Chemical Co., Ltd.) 1.0
Part B Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
DPG 2.0
Lactic acid 0.1
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.01
Purified water 50.0
Part C Composition of Example 19 5.0
Ethanol 10.0
Menthol 0.1
Mentil Lactate 0.2
Mentyl glyceryl ether 0.15
Panthenyl ethyl ether 0.2
Camphor 0.1
Cordyceps extract 1.0
Swertia japonica extract 1.0
Eriobotrya leaf extract 1.0
Hydrolyzed hyaluronic acid 0.02
Cyclic lysophosphatidic acid Na 0.001
Capsicum extract 0.01
Betaine 0.3
Trehalose 0.2
Cymene-5-all 0.1
Tocopherol acetate 0.05
β-Glycyrrhetinic acid 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
A part and B part were each heated to 70 ° C., and A part was added while stirring part B with a propeller (500 rpm) to prepare a nanovesicle solution. Further, after cooling, part C mixed in advance was added to obtain a uniform liquid.

Example 33 Whitening emulsion
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Plandoll-LG3 (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 1.0
LUSPLAN DD-DA5 (Nippon Fine Chemical Co., Ltd.) 0.2
LUSPLAN DD-DA7 (Nippon Fine Chemical Co., Ltd.) 0.2
Cetyl ethylhexanoate (Nippon Fine Chemical Co., Ltd.) 7.0
Ethylhexyl succinate (Nippon Fine Chemical Co., Ltd.) 3.0
Cetanol 1.2
Myristyl Alcohol 2.0
Oleyl alcohol 1.0
Part B Stearoxy hydroxypropyl Methyl Cellulose 0.1
Xanthan gum 0.1
Purified water 20.0
Part C Phytocompo-C (Nippon Fine Chemical Co., Ltd.) 1.0
DPG 3.0
Glycerin 8.0
Part D 3-O-ethylascorbic acid (Nippon Fine Chemical Co., Ltd.) 1.0
Tranexamic acid (Nippon Fine Chemical Co., Ltd.) 2.0
Composition of Example 19 1.0
BG 7.0
Purified water 5.0
Part E Phenoxyethanol 0.2
Methylparaben 0.15
Phytic acid 0.5
Citric acid 0.1
Amount of Na citrate pH of 4.5 Amount of purified water totaling 100 ---------------------------------------------------------------------------- −−−−−
(Preparation method)
Parts A and E were each heated to about 70 ° C. and dissolved uniformly. Part B was stirred to obtain a viscous liquid. Part C was heated to about 70 ° C. and dispersed uniformly. After adding part A while stirring part C with a homodisper, part E was added while stirring. Parts D and B were added at about 50 ° C., and the mixture was stirred and uniformly dissolved.

Example 34 Skin care cream
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Sugar Squalene 10.0
Stearic acid 1.0
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 1.0
Jojoba oil 3.0
Behenyl alcohol 2.0
PEG-20 glyceryl isostearate 1.0
Olive oil fatty acid sorbitan 0.8
Polyglyceryl oleate-10 1.0
Part B Acrylic acid / alkyl methacrylate copolymer 0.1
Hydroxide K 0.07
(Acryloyldimethyltaurine ammonium /
Behenes Methacrylic Acid-25) Cross Polymer 0.2
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Purified water 20.0
Composition of Example 20 5.0
Hydrolyzed polyγ-glutamic acid K 0.1
Na 0.1 polyglutamate
Oligopeptide-24 0.05
Part C Glycerin 9.0
PEG-8 5.0
PEG-2M 2.0
Ethylhexyl glycerin 0.8
DPG 1.5
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and C were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part B was mixed and stirred to give a viscous liquid. Part C was added while stirring with a homomixer to emulsify part A. After cooling, part B was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 35 Facial cleansing foam
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Composition of Example 19 8.0
Stearic acid K 10.0
Palmitic acid K 10.0
Myristic acid K 10.0
Lauric acid K 4.0
Lauroyl sarcosine isopropyl 0.8
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.05
LUSPLAND DD-DHR (Nippon Fine Chemical Co., Ltd.) 0.05
PEG-150 10.0
Glyceryl monostearate 1.0
PEG-40 hydrogenated castor oil 0.5
Part B Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Inulin-SC ((Nippon Fine Chemical Co., Ltd.) 1.0
Polyquaternium-7 0.5
Polyquaternium-39 0.5
Methylparaben 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was heated to about 80 ° C. Part B was gradually added to part A with stirring, and after mixing, the mixture was cooled to 40 ° C.

Example 36 Body shampoo
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Composition of Example 3 3.0
Cocoyl methyl taurine Na 10.0
Lauroyl hydrolyzed silk Na 6.0
Lauroylmethylalanine Na 10.0
Na cocoamphoacetate (30%) 4.0
Cocamidopropyl Betaine (30%) 10.0
Olefin (C14-16) Na Sulfonate 5.0
Polyquaternium-10 0.8
Hydroxypropyl Methyl Cellulose 0.3
Acetyl hyaluronic acid Na 0.02
Cocamide DEA 3.0
PPG-9 diglyceryl 1.0
Glycerin 5.0
Phenoxyethanol 0.6
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were heated at about 80 ° C. and uniformly stirred and mixed.

Example 37 Non-silicone shampoo

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Composition of Example 18 3.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.03
Diethylhexyl succinate (Nippon Fine Chemical Co., Ltd.) 0.01
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.5
Laures-4 Na Carboxylic Acid (28%) 10.0
Laures-6 Carboxylic Acid 4.0
Cocamidopropyl Betaine (30%) 10.0
Lauroylmethylalanine Na (30%) 5.0
Cocamidomethyl MEA 3.0
Coconut oil fatty acid PEG-7 glyceryl 5.0
Na hydroxide 1% solution 0.5
Polyquaternium-10 0.8
Glycol distearate 0.5
Polyquaternium-7 0.5
EDTA-2Na 0.05
1,2-Pentanediol 5.0
Phenoxyethanol 0.4
Na benzoate 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All components were heated at about 80 ° C. and uniformly stirred and mixed.

Example 38 shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Ammonium Laureth Sulfate 10.0
Na laureth sulfate (25%) 10.0
Lauryl hydroxysultaine (30%) 10.0
Lauric acid K 1.0
Glycol distearate 0.5
Toluene sulfonic acid 0.3
Stearoxypropyl dimethylamine 0.5
PPG-17 0.3
Neopentyl glycol diethylhexanoate 0.4
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.2
Isodecyl glyceryl ether 0.4
Cocamide MEA 1.0
Laures-4 0.3
Laures-16 0.2
Stairless-6 0.2
Sorbitol 1.0
Phenoxyethanol 0.3
Part B malic acid 0.02
Phosphoric acid 0.03
Na benzoate 0.4
Amount of purified water totaling 100 Part C Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 3.0
Purified water 6.7
Part D Composition of Example 20 1.0
Composition of Example 19 3.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A and part B were uniformly mixed at about 80 ° C. Part C was heated to about 60 ° C. to make it uniform, gradually added with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part D was added and mixed uniformly.

Example 39 Hair treatment that does not wash away
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Polyquaternium-37 2.0
Squalene 2.0
PPG-3 Caprilyl Ether 2.0
Microcrystalline wax 0.1
Lanolin alcohol 0.2
Sunflower seed wax 0.1
Polyethylene wax 0.1
Japan wax 0.2
Celesin 0.1
Dicapric acid PG 1.0
Almond oil 0.5
Ethylhexyl ethylhexanoate 1.0
Candelilla low extract 0.1
Octyldodecyl erucate 4.5
LUSPLAN DD-IS (Nippon Fine Chemical Co., Ltd.) 0.1
Neosolue-DP (Nippon Fine Chemical Co., Ltd.) 0.2
Tocopherol acetate 0.02
Elcalactone MCT (Nippon Fine Chemical Co., Ltd.) 2.0
Dipentaerythrityl tripolyhydroxystearate 1.5
PPG-5 Phytosteryl 0.5
1,2-Pentanediol 5.0
Glycerin 4.0
Sorbitol 2.0
Phenoxyethanol 0.5
Part B Hydrolyzed hyaluronic acid 0.1
Panthenol 0.1
Hydroxypropyltrimonium hyaluronate 0.01
Polyquaternium-11 0.2
Glycosyl trehalose 0.1
Carboxyvinyl polymer 0.3
Glyceryl glucoside 0.3
Arginine 0.1
Purified water 10.0
Composition of Example 2 5.0
Amodimethicone 0.5
Part C Purified water Amount totaling 100 Hydroxypropyl starch phosphoric acid 1.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part C was uniformly dispersed and heated to about 80 ° C. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, part B was added and mixed uniformly.

Example 40 Non-silicone hair treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.5
Propanediol 3.0
Behenamide propyl dimethylamine 1.5
Cetanol 2.2
Stearyl alcohol 0.8
Hydrogenated rapeseed oil alcohol 0.5
Shea fat 0.3
Neopentyl glycol diethylhexanoate 0.8
Jojoba seed oil 1.0
Isododecane 1.0
Glyceryl stearate 0.4
Cocamidomethyl MEA 0.8
Caesar Pineia Spinosa Hydroxypropyltrimonium Chloride 0.1
Rice bran wax 0.5
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 2.0
Glycerin 1.0
Part B Composition of Example 3 20.0
Part C Phenoxyethanol 0.4
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Lactic acid 0.4
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and C were uniformly mixed at about 80 ° C., respectively. Part C was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Part B was added and mixed uniformly.

Example 41 Hair treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A oleic acid 1.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.2
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 0.2
Ethylhexyl palmitate (Nippon Fine Chemical Co., Ltd.) 1.0
PPG-3 myristil 0.5
Cetyl Esters 0.3
Dimethicone (100cs) 2.0
Dimethicone (1 million CS) 1.0
Stearyl ethylhexanoate 1.0
Isostearoyl lactate Na 0.2
Cetearyl alcohol 3.5
PEG-200 0.5
Hydroxyethyl cellulose 0.4
Setrimonium chloride (30%) 1.0
Behentrimonium chloride (80%) 1.0
Trideces-6 0.3
Ceramide 2 0.01
Ceramide 3 0.01
BHT 0.03
Part B Hydrolyzed Keratin 0.5
Na benzoate 0.4
Lactic acid 0.05
Amount of purified water totaling 100 Part C Composition of Example 14 3.0
Composition of Example 3 7.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. After cooling, part C was added to make it uniform.

Example 42 Hair Treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A isostearic acid 0.8
Polyricino-acidic acid 0.5
Diethylhexyl sebacate (Nippon Fine Chemical Co., Ltd.) 1.0
Propanediol 3.0
Stealtrimonium chloride (70%) 1.5
Behenamide propyl dimethylamine 0.5
Cetanol 2.2
Stearyl alcohol 0.8
Hydrogenated rapeseed oil alcohol 0.5
Neopentyl glycol diethylhexanoate 0.8
Myristic acid PPG-3 benzyl ether 0.5
Jojoba seed oil 1.0
Glyceryl stearate 0.4
Cocamide MEA 0.8
Caesar Pineia Spinosa Hydroxypropyltrimonium Chloride 0.1
Rice bran wax 0.5
Glycerin 1.0
Part B Lactic acid 0.18
Hydrolyzed conchiolin 0.1
Panthenol 0.1
Polyquaternium-7 0.15
Amount of purified water totaling 100 Part C Composition of Example 3 5.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A and part B were uniformly mixed at about 80 ° C. Part A was gradually added to part B with stirring, mixed uniformly, and then cooled to about 50 ° C. Part C was added to make it uniform.

Example 43 Hair Treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A linolenic acid 0.5
Lanolin fatty acid 0.5
Diethylhexyl succinate (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 1.0
Ceramide 2 0.001
Ceramide 6 0.001
Stearoxypropyltrimonium chloride 1.0
Setrimonium chloride 0.3
Dialkyl (C12-18) Dimonium Chloride 0.3
Stearyl alcohol 2.0
Cetanol 1.0
DPG 0.5
BG 1.0
Lactic acid 0.12
Hexa (hydroxystearic acid / stearic acid / rosin acid)
Dipentaerythrityl 0.2
Polyglyceryl polyricinoleate-6 1.0
Naphthalene Sulfonic Acid Na 0.5
Benzyl alcohol 0.4
Stearoxypropyl Dimethylamine 0.4
Behendimonium stearyl ethyl phosphate 0.05
Tristearin 0.5
Ceteares-7 0.8
Ceteares-25 0.3
Part B Purified water Total amount of 100 Phenoxyethanol 0.5
Part C
Composition of Example 5 10.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A and part B were uniformly mixed at about 80 ° C. Part A was gradually added to part B with stirring, mixed uniformly, and then cooled to about 50 ° C. Part C was added to make it uniform.

Example 44 Hair Treatment
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A hydroxystearic acid 0.5
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.3
Tri (caprylic acid / capric acid) glyceryl (Nippon Fine Chemical Co., Ltd.) 0.6
Ethylhexyl palmitate (Nippon Fine Chemical Co., Ltd.) 3.0
Dextrin palmitate 0.5
Isostearoyl hydrolyzed collagen 0.2
Stearyl alcohol 2.0
Cetanol 1.2
Behentrimonium chloride 1.0
PEG-45M 0.8
Totsubaki Seed Oil 0.4
Hydroxyethyl urea 0.5
Dicaprilyl Carbonate 2.0
Squalene 0.1
Isosetes-10 0.5
Sunflower wax 0.8
Cocoyl Arginine Ethyl PCA 0.2
Phenoxyethanol 0.2
Tocopherol 0.05
Glycerin 1.3
DPG 2.2
Part B Sorbitol 3.5
BG 1.0
Hydroxycellulose 0.07
Cellulose 0.02
Phenoxyethanol 0.2
Appropriate amount of citric acid EDTA-2Na 0.01
Amount of purified water totaling 100 Part C Polyquaternium-61 0.3
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Composition of Example 18 5.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A and part B were uniformly mixed at about 80 ° C. Part A was gradually added to part B with stirring, mixed uniformly, and then cooled to about 50 ° C. Part C was added to make it uniform.

Example 45 Treatment compound content (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Polyhydroxystearic acid 0.2
Palmitoleic acid 0.5
Cetyl ethylhexanoate (Nippon Fine Chemical Co., Ltd.) 1.0
Ethylhexyl palmitate (Nippon Fine Chemical Co., Ltd.) 3.0
Stearyl alcohol 3.0
Behentrimonium chloride 1.0
Stealtrimonium chloride 0.5
Stearamidopropyl dimethylamine 0.1
Hydrogenated polyisobutene 1.0
Hydrogenated polydecene 0.6
Camellia seed oil 0.5
PPG-3 myristil 0.5
Dextrin palmitate 0.3
Zika fever ether 3.0
Dilauroyl lysine Na 0.1
Ascorbyl dipalmitate 0.1
BG 3.0
Tocopherol 0.1
Phenoxyethanol 0.4
Part B Composition of Example 3 1.0
Na 0.4 hydrogen carbonate
Amount of purified water totaling 100 Locust Bean Hydroxypropyltrimonium Chloride 0.1
Lactic acid 0.05
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled.

Example 46 Treatment compound content (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Diethylhexyl sebacate (Nippon Fine Chemical Co., Ltd.) 0.7
Behentrimonium metosulfate 1.3
Setrimonium chloride 0.3
Paraffin 1.0
Hydroxypropyltrimonium hyaluronate 0.2
Isostearic acid hydrogenated castor oil 1.0
Squalene 2.0
Dimethicone (300cs) 1.0
Dimethicone (500,000 cs) 1.5
Tocopherol acetate 0.05
Diethyl sebacate 2.0
Candelilla wax 0.3
Apricot kernel oil 1.0
DPG 2.0
Propanediol 1.0
Benzyl alcohol 0.5
Glycerin 1.0
PEG-7 propyl heptyl ether 0.8
PEG-180M 0.3
Part B Na benzoate 0.3
EDTA-2Na 0.03
Amount of purified water totaling 100 Polyquaternium-10 0.2
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
Part C Composition of Example 5 8.0
Composition of Example 18 3.0
Amodimethicone 3.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was mixed and then added to make it uniform.

Example 47 Hair color treatment compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Polyricinoleic Acid 0.3
Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 1.0
Cetearyl alcohol 3.0
Behentrimonium metosulfate 2.0
Benzyl alcohol 1.0
Setrimonium chloride (25%) 5.3
Ethylhexyl palmitate 1.0
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 1.0
Neopentyl glycol diheptate 2.0
Ethylhexyl isononanoate 1.0
Hybrid sunflower oil 1.0
DPG 1.8
Glycerin 4.0
Phytosterols 0.1
Mineral oil 0.5
PEG-160M 0.5
Part B Lactic acid 0.3
Hydrolyzed starch 0.4
Hydroxypropyl methylcellulose 0.1
Hyaluronate Na 0.01
Basic red 76 0.1
Basic tea 17 0.2
Basic blue 99 0.1
HC Blue 16 0.1
HC Blue 2 0.05
HC Red 10 0.1
HC red 11 0.05
Purple 401 0.05
Red 227 0.1
Black 401 0.1
Yellow 4 0.05
Amount of purified water totaling 100 parts C
Composition of Example 3 10.0
Setrimonium chloride (30%) 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container, and the mixture was heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was mixed and then added to make it uniform.

Example 48 Shampoo for dandruff
Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Lauroylmethylalanine Na (30%) 13.0
Cocamidopropyl Betaine (30%) 20.0
Cocoyl Glutamic Acid TEA (30%) 5.0
Cocamide DEA 1.0
Glycerin 1.0
Glyceryl caprylate 0.4
Glyceryl undecylenate 0.1
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
BG 1.6
PPG-3 Caprilyl Ether 0.2
Miconazole nitrate 0.75
Glycol distearate 1.5
Polyquaternium-7 0.3
Part B Na benzoate 0.4
Na chloride 0.2
Amount of purified water totaling 100 Part C Swertia japonica extract 3.0
Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Polyquaternium-47 0.1
Piroctone olamine 0.1
Purified water 9.7
Composition of Example 16 3.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was placed in a separate container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 49 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Diethylhexyl succinate (Nippon Fine Chemical Co., Ltd.) 0.2
Composition of Example 3 1.0
Composition of Example 10 1.0
Cocoyl sarcosine Na 10.0
Na cocoyl glutamate (30%) 10.0
Lauryl hydroxysultaine (30%) 10.0
Glycol distearate 0.5
Stearoxypropyl dimethylamine 0.5
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.5
Isostearic acid 0.3
Glyceryl undecylenic acid 0.5
DPG 0.1
Cocamidomethyl MEA 3.0
Phenoxyethanol 0.6
Part B citric acid 0.1
Methylparaben 0.2
EDTA-2Na 0.1
Amount of purified water totaling 100 Part C Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 3.0
Purified water 6.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was uniformly mixed at about 80 ° C. Part B, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part C was added and mixed uniformly.

Example 50 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A oleic acid 0.3
PPG-3 Caprilyl Ether 2.0
Ceramide 3 0.001
Ceramide 5 0.004
Cocoyl methyl taurine Na 3.0
Na laureth sulfate (27%) 9.0
Lauryl hydroxysulfobetaine (30%) 7.0
Cocamide MEA 1.0
Polyquaternium-61 0.5
Neopentyl glycol diheptate 1.0
Glycol distearate 0.5
Polyglyceryl oleate-10 0.25
PEG-150 1.0 stearate
DPG 2.0
Phenoxyethanol 0.6
Part B EDTA-2Na 0.05
Methylparaben 0.2
Na benzoate 0.3
Amount of purified water totaling 100 Part C Polyquaternium-10 0.5
Polyquaternium-7 0.2
Purified water 9.3
Composition of Example 16 1.0
Composition of Example 17 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A and part B, which had been mixed and dissolved in advance, were uniformly mixed at about 80 ° C. (part E). Part C, which was set aside, was heated to about 60 ° C. to make it uniform. Part C was gradually added to part E with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part D was added and mixed uniformly.

Example 51 Leave on Hair Treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 2.0
Setrimonium chloride (25%) 3.8
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 1.0
Caprylyl glucoside (50%) 0.8
Part B Composition of Example 3 10.0
Hydrolyzed keratin 0.2
Hydrolyzed silk 0.1
Hydrolyzed conchiolin 0.1
Polyquaternium-6 0.6
Polyquaternium-7 0.4
Polyquaternium-39 0.5
Part C Glycerin 4.0
Phenoxyethanol 0.5
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part C was heated to about 80 ° C. and dissolved. Next, part A was heated to about 80 ° C. to dissolve it. Part C was added while stirring, and after mixing uniformly, the mixture was cooled to about 40 ° C. Then, part B was added and mixed uniformly.

Example 52 Sunscreen Cosmetics
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 1.0
BG 10.0
Glycerin 9.0
Part B Octocrylene 4.0
Octyl salicylate 4.0
Diethylaminohydroxybenzoyl hexyl benzoate 2.25
t-Butylmethoxydibenzoylmethane 1.0
Diethylhexyl sebacate (Nippon Fine Chemical Co., Ltd.) 2.0
Diethylhexyl adipate (Nippon Fine Chemical Co., Ltd.) 2.0
Behenyl alcohol 2.0
Cetearyl alcohol 2.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-LG4 (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-S (Nippon Fine Chemical Co., Ltd.) 0.5
Tocopherol 0.05
Part C Neosolue-Aqua (Nippon Fine Chemical Co., Ltd.) 1.0
Methylparaben Appropriate amount Water Amount that totals 100 Part D Carbomer (2%) 5.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 10.0
Composition of Example 20 5.0
Water-dispersed titanium oxide 5.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Disperse part A evenly. Parts B and C are each heated and dissolved at about 70 ° C. After gradually adding the B part to the A part, the C part is gradually added and emulsified. Cool while stirring, add part D at 45 ° C, and stir.

Example 53 O / W type emulsified composition
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Polyglyceryl myristate-10 5.0
Glyceryl caprylate 0.6
Purified water 1.5
Part B Plandoll-H (Nippon Fine Chemical Co., Ltd.) 3.0
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 2.0
Ethylhexyl methoxycinnamate 2.0
Octocrylene 2.0
Dimethicone 1.0
Diethylaminohydroxybenzoyl hexyl benzoate 2.0
Diethylhexyl sebacate (Nippon Fine Chemical Co., Ltd.) 2.0
Squalene 5.0
Tocopherol 0.05
Part C Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.0
Phenoxyethanol 0.5
Amount of water totaling 100 Part D Carbomer (2% liquid KOH neutralization) 5.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 5.0
Hyaluronate Na 0.01
Scutellaria extract 0.1
Aloe extract 0.1
Licorice extract 0.1
Cha extract 0.1
Sorbitol 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A is uniformly dispersed with a planetary mixer. Parts B and C are mixed and dissolved, respectively. After gradually adding part B to part A and making it uniform with a planetary mixer, part C is gradually added while stirring with a dispar mixer and a planetary mixer to emulsify. Add part D with stirring to make it uniform.

Example 54 O / W type emulsified composition
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Part A Polyglyceryl isostearate-10 5.0
Polyglyceryl myristate-10 3.0
Glyceryl caprate 0.6
Purified water 1.5
Part B Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 3.0
Plandoll-G (Nippon Fine Chemical Co., Ltd.) 2.0
Vaseline 2.0
Tristearin 2.0
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 5.0
Hyaluronate Na 0.01
Brown algae extract 0.3
Souhakuhi extract 0.1
Mango seed extract 0.1
Licorice extract 0.1
Cha extract 0.1
Carambola leaf extract 0.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A is uniformly dispersed with a planetary mixer. Parts B and C are mixed and dissolved, respectively. After gradually adding part B to part A and making it uniform with a planetary mixer, part C is gradually added while stirring with a dispar mixer and a planetary mixer to emulsify. Add part D with stirring to make it uniform.

In the above formulation, the details of the ingredients described by the product names are as follows.
〇Inulin-SC: Inulin 〇Plandol-H: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-S: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-G: Dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl)
〇Plandol-DP: Bisdiglyceryl polyacyl adipate-2
〇Plandol-ISS: Phytosteryl isostearate 〇Plandol-SUN: Sunflower seed oil fatty acid phytosteryl 〇Plandol-MAS: Macadamia nut oil fatty acid phytosteryl 〇Plandol-LG1: Di (phytosteryl / octyldodecyl) lauroyl glutamate
〇Plandol-LG2: Di-lauroyl glutamate (phytosteryl / octyldodecyl)
〇Plandol-LG3: Di-lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇Plandol-LG4: Di lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇LUS PLAN DD-IS: Dimer dilinoleyl diisostearate 〇LUS PLAN PI-DA: Dimer dilinoleate di (isostearyl / phytosteryl)
〇LUSPLAN DD-DHR: Diomerlinoleyl hydrogenated rosin condensate 〇LUSPLAN DD-DA5: Diomerlinoleic acid Diomerlinoleil 〇LUSPLAN DD-DA7: Diomerlinoleic acid dimersolinoleyl 〇Neosolue-Aqualio: Cyclohexanedicarboxylic acid Bisethoxydiglycolic acid 〇 Neosolue-Aqua: (eicosandioic acid / tetradecanedioic acid) polyglyceryl-10, glycerin 〇Neosolue-AquaS: (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, glycerin 〇Neosolue-MP: Methylpentanediol 〇 Neosolue-DE: Dioxypentanediol dineopentanoate 〇Phytocompo-PP: Hydrohydrated lecithin, phytosterols 〇Phytocompo-C: Hypochlorite, phytosterols, ceramide 2, ceramide 3, ceramide 6II
〇Phytopresome Asta: Hydrogenated lecithin, phytosterols, astaxanthin 〇Phytopresome Lipo-Q: Hydrogenated lecithin, phytosterols, lipoic acid, coenzyme Q10
〇 Phytopresome Cera23: Hydrogenated lecithin, phytosterols, ceramide 2, ceramide 3
〇Phytopresome MEL: Glycolipid, hydrogenated lecithin, BG, purified water 〇Elcalactone MCT: γ-docosalactone, tri (caprylic acid / capric acid) glyceryl 〇Elcalactone DES: γ-docosalactone, diethyl sebacate 〇Tremoist- TP: White jellyfish polysaccharide 〇 Tremoist-SL: White jellyfish polysaccharide aqueous solution (1%)
〇PrimeLipid PI: Hydrogenated lecithin, phosphatidylinositol, soybean sterol

Claims (6)

It contains the following components (A) to (C), the content of the component (B) is 10 to 70% by weight, and the content of (B1) in the component (B) is 20 to 80% by weight. An O / W type emulsifying composition for cosmetics or external preparations for skin.
(A) Polyglycerin fatty acid ester having an HLB of 12 to 18 (B) An oily component containing the following components (B1) and (B2) (B1) Dimeric acid ester, fatty acid sterol ester, and
One or more selected from N-acylamino acid esters (B2) Liquid oil (C) water with a viscosity of 200 mPa · s or less at 25 ° C. The O / W type emulsified composition according to claim 1, wherein the weight ratio of the components (A) to (B) is (B) / (A) = 1-10. The dimer acid ester of the component (B1) is dimer dilinoleic acid dimer dilinoleyl, dimer dilinoleic acid dimer dinorail bis (behenyl / isostearyl / phytosteryl), dimer dilinoleic acid di (isostearyl / phytosteryl), die. Selected from marginoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid hydrogenated castor oil, diglycerin isostearate dimerginoleic acid;
Fatty acid sterol esters are phytosteryl oleate, phytosteryl hydroxystearate, phytosteryl isostearate, lanolin fatty acid phytosteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, rice bran oil fatty acid phytosteryl, cholesteryl olesteryl olesteryl hydroxystearate. , Lanolin fatty acid cholesteryl, macadamia nut oil fatty acid cholesteryl, sunflower seed oil fatty acid cholesteryl, rice bran oil fatty acid cholesteryl;
N-acylamino acid esters are N-lauroyl-L-glutamic acid dioctyldodecyl, N-lauroyl-L-glutamic acid di (phytosteryl / octyldodecyl), N-lauroyl-L-glutamic acid di (cholesteryl / octyldodecyl), N-lauroyl. The O / W according to claim 1 or 2, wherein it is selected from di-L-glutamic acid (cholesteryl / behenyl / octyldodecyl) and di-lauroyl-L-glutamic acid (phytosteryl / behenyl / octyldodecyl). Molded emulsion composition. A cosmetic or skin external preparation containing the O / W type emulsified composition according to any one of claims 1 to 3. The method for producing an O / W type emulsified composition according to any one of claims 1 to 3, which comprises the following steps (1) and (2). Manufacturing method.
(1): A step of adding 5 to 90 parts by weight of the component (C) to 100 parts by weight of the component (A), the component (B), and the component (A), and uniformly stirring and mixing (2): Add the rest of component (C) to the mixture of step (1) with stirring.
Step to uniformly stir and mix The method for producing an O / W type emulsified composition according to claim 5, wherein the steps (1) and (2) are carried out at room temperature.