JP2018168141A - Surface-treated powder - Google Patents

Abstract

To provide a surface-treated powder that has a good feeling in use and effectviely inhibits unnatural whiteness, and also has excellent dispersibility in the formula, and cosmetics containing the surface-treated powder.SOLUTION: The present invention provides a surface-treated powder coated with an oligomer ester synthesized from following components (A) and (B): (A) at least one selected from C6-22 bivalent carboxylic acids containing linear, branched, or cyclic structures, and (B) a polyglycerol with an average degree of polymerization of 2-15, calculated in terms of hydroxyl values.SELECTED DRAWING: None

Description

The present invention relates to a surface-treated powder coated with an oligomer ester synthesized from the following components (A) and (B), and a cosmetic containing the surface-treated powder.
(A) One or two or more types selected from divalent carboxylic acids containing a straight chain, branched chain, or cyclic structure having 6 to 22 carbon atoms (B) The average degree of polymerization calculated from the hydroxyl value is 2 to 15 Polyglycerin

  Conventionally, various powders have been used in a wide range of applications in cosmetics. For example, in sunscreen cosmetics, in order to obtain high SPF and PA, inorganic powders such as titanium oxide, zinc oxide, and cesium oxide are blended as an ultraviolet scattering agent. Such an ultraviolet scattering agent shields not only UVB but also UVA, and the load on the skin is small, so there is a demand to mix as much as possible, but when these inorganic powders are blended in cosmetics in large quantities, When applied, it has an adverse effect on the feel, such as poor spreading and squeaking. In addition, there is a problem of “white floating” in which whiteness remains on the skin and a problem that the effect is not sufficiently exhibited because dispersibility in the prescription is deteriorated.

  On the other hand, in makeup cosmetics, powders such as inorganic powders, organic powders, colored pigments, and pearl pigments are blended for the purpose of imparting a desired color, hiding skin, and correcting irregularities. Even with such powders, there are problems such as poor usability, poor dispersibility in the formulation, poor color development, and uneven color.

  In order to solve such problems, attempts have been made to coat the surface of the powder with various compounds (for example, Patent Documents 1 to 5), but these have not always been satisfactory.

Japanese Patent No. 3567335 Japanese Patent No. 2719303 Japanese Patent No. 3707758 Japanese Patent No. 3736848 Japanese Patent No. 4145681

  An object of the present invention is to provide a surface-treated powder having excellent usability and whitening suppression effect and excellent dispersibility in the formulation, and a cosmetic containing the surface-treated powder. is there.

As a result of intensive investigations in view of such circumstances, the present inventors have found that a surface-treated powder coated with an oligomer ester synthesized from the following components (A) and (B) can solve the above problems. The headline and the present invention were completed.
(A) One or two or more types selected from divalent carboxylic acids containing a straight chain, branched chain, or cyclic structure having 6 to 22 carbon atoms (B) The average degree of polymerization calculated from the hydroxyl value is 2 to 15 Polyglycerin

  The surface-treated powder of the present invention is coated with the oligomeric ester of the present invention, so that it has a better feeling of use, whitening is suppressed, and dispersibility in the formulation compared to untreated powder. Excellent. Moreover, when the powder to process is an ultraviolet-ray scattering agent, it has the effect of improving SPF.

The surface-treated powder of the present invention is a surface-treated powder coated with an oligomer ester synthesized from the following components (A) and (B).
(A) One or two or more types selected from divalent carboxylic acids containing a straight chain, branched chain, or cyclic structure having 6 to 22 carbon atoms (B) The average degree of polymerization calculated from the hydroxyl value is 2 to 15 Polyglycerin

  The divalent carboxylic acid of component (A) used in the present invention is a divalent carboxylic acid containing a straight chain, branched chain or cyclic structure having 6 to 22 carbon atoms. Specific examples of divalent carboxylic acids that can be used include adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, undecanedioic acid, dodecanedioic acid, and tridecane. Examples include diacid, tetradecanedioic acid, pentadecanedioic acid, hexadecanedioic acid, octadecanedioic acid, 8-ethyloctadecanedioic acid, eicosane diacid, dimethyleicosane diacid, cyclohexanedicarboxylic acid, and the like. These divalent carboxylic acids may be used alone or in combination of two or more. Among these, preferred are linear or branched divalent carboxylic acids having 14 to 22 carbon atoms, tetradecanedioic acid, pentadecanedioic acid, hexadecanedioic acid, octadecanedioic acid, 8-ethyloctadecanedioic acid, More preferably, it is selected from eicosane diacid and dimethyl eicosane diacid.

As a polyglycerol of the component (B) used for this invention, it is a polyglycerol with an average degree of polymerization computed from the hydroxyl value of 2-15. As such polyglycerin, for example, diglycerin S, polyglycerin # 310, ditto # 500, ditto # 750, etc. manufactured by Sakamoto Pharmaceutical Co., Ltd. are commercially available. Of these, polyglycerin having an average degree of polymerization calculated from the hydroxyl value of 4 to 12 is preferable. Here, the average degree of polymerization calculated from the hydroxyl value is a numerical value obtained by the following formula.
If A = 56.1 × 1000 / hydroxyl value, average polymerization degree = (2 × A-18.0) / (74.1-A)

  Although the manufacturing method of the oligomer ester of the bivalent carboxylic acid and polyglycerol of this invention is not specifically limited, It can obtain by making esterification reaction of a bivalent carboxylic acid and polyglycerol. In the production of the oligomer ester of the present invention, the polymerization degree of the resulting oligomer ester can be adjusted by changing the respective charging ratios of the divalent carboxylic acid and the polyglycerol. The preferable range of the charging ratio is 0.3 to 1.5 molar equivalents of divalent carboxylic acid with respect to 1 molar equivalent of polyglycerin, and more preferably divalent carboxylic acid with respect to 1 molar equivalent of polyglycerol. 0.7 to 1.2 molar equivalents. When the charging ratio of the divalent carboxylic acid to the polyglycerol is large, a large amount of high polymer is generated, resulting in poor fluidity and solubility, which is not preferable because it is out of the range of the oligomer. On the contrary, if the charging ratio of the divalent carboxylic acid to the polyglycerol is small, the effect of the present invention is not sufficiently exhibited. As the molecular weight of the oligomer ester of the present invention, the number average molecular weight measured by GPC is 1,000 to 20,000, preferably 1,400 to 10,000. The conditions for the esterification reaction are not particularly limited, and the reaction is performed by a commonly used method. For example, p-toluenesulfonic acid, sulfuric acid, hydrochloric acid, methanesulfonic acid, boron trifluoride diethyl ether complex or the like can be used as a catalyst, and a suitable solvent can be used at 50 to 260 ° C. Alternatively, the esterification can be carried out at 150 to 260 ° C. even without solvent and without catalyst. The oligomer ester thus obtained may be used as it is, or may be further purified and used by an ordinary method as necessary. Further, it may be diluted with a polyhydric alcohol such as glycerin and used as a diluted polyhydric alcohol. The oligomer ester of the present invention obtained in this way is a complex mixture of various compounds because polyglycerol has a plurality of hydroxyl groups.

  In addition, as the oligomer ester synthesized from the components (A) and (B) of the present invention, a commercial product sold by Nippon Seika Co., Ltd. under the product name Neosole-Aqua or Neosole-AquaS is used. You can also.

  As the powder used in the surface-treated powder of the present invention, conventionally known powders can be used, and their shapes (spherical, rod-like, plate-like, needle-like, indeterminate, scale-like, spindle-like, etc.), particle diameter ( Any material can be used regardless of the form of fumes, fine particles, pigment grade, etc., particle structure (porous, non-porous, etc.) and material (inorganic, organic). Examples thereof include inorganic powders, organic powders, surfactant metal salt powders, colored pigments, pearl pigments, metal powder pigments, tar dyes, natural dyes, and the like. Moreover, these powders may be processed alone or may form a mixture and be processed together.

  Specifically, as the inorganic powder, titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, Muscovite, synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, Tungstic acid metal salt, hydroxyapatite, vermiculite, hydrite, bentonite, montmorillonite, kaolinite, hectorite, zeolite, ceramic powder, calcium phosphate, alumina, aluminum hydroxide, boron nitride, silicon nitride, Boron, silica, silylated silica and the like.

  Organic powders include polyamide powder, polyacrylic acid / acrylate powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane powder, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, polymethyl methacrylate powder , Cellulose powder, silk powder, nylon powder, crosslinked silicone fine powder, crosslinked spherical polymethylsilsesquioxane fine powder, crosslinked spherical organopolysiloxane rubber surface coated with polymethylsilsesquioxane particles Powder, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol resin, fluororesin, silicon resin , Acrylic resins, melamine resins, epoxy resins, polycarbonate resins, or layered powder of resin, microcrystalline fiber powder, starch powder, powder fatty starch derivatives, and lauroyl lysine.

  Surfactant metal salt powders include zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, sodium zinc cetyl phosphate, calcium palmitate, etc. Can be mentioned.

  As colored pigments, iron oxide such as bengara, yellow iron oxide, black iron oxide, iron hydroxide, iron titanate, ocher, carbon black, manganese violet, cobalt violet, chromium hydroxide, chromium oxide, cobalt oxide, titanic acid Examples include cobalt, bitumen, and ultramarine blue.

  Examples of the pearl pigment include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, fish scale foil, and titanium oxide-coated colored mica.

  Examples of the metal powder pigment include aluminum powder, copper powder, and stainless steel powder.

  As tar pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401, Blue 1, Blue 2, Blue 201, Blue 404 , Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207 and the like.

  Examples of natural pigments include carminic acid, laccaic acid, calsamine, bradylin, and crocin.

  Among these powders, inorganic powders or colored pigments are preferable in terms of sufficiently exerting the effects of the present invention. More specifically, titanium oxide, zinc oxide, cerium oxide, talc, kaolin, mica, silica, Iron oxide is preferred. In addition, fine particle titanium oxide, fine particle zinc oxide and the like which are widely used as an ultraviolet scattering agent in sunscreen cosmetics can be preferably used.

  Furthermore, the powder used for the surface-treated powder of the present invention may be one that has been subjected to a conventionally known surface treatment. For example, fluorine compound treatment such as perfluoroalkyl phosphate treatment, perfluoroalkylsilane treatment, perfluoropolyether treatment, fluorosilicone treatment, fluorinated silicone resin treatment; methylhydrogenpolysiloxane treatment, dimethylpolysiloxane treatment, Silicone treatment such as tetramethyltetrahydrogencyclotetrasiloxane treatment; silicone resin treatment such as trimethylsiloxysilicate treatment; pendant treatment; silane coupling treatment; titanium coupling treatment; aluminum coupling treatment; alkylated silane or alkyl Silane treatment such as silazane treatment; oil treatment; N-acylated lysine treatment; polyacrylic acid treatment; metal soap treatment such as stearate and myristate treatment; acrylic resin treatment; Object processing; plasma treatment; mechanochemical treatment. A plurality of these processes may be combined.

  The method of coating the oligomer ester of the present invention on the powder surface is not particularly limited, and generally known processing methods are used. Specifically, direct powder and oligomer ester or polyhydric alcohol dilution of oligomer ester, such as Henschel mixer, ball mill, sand mill, attritor, bag mill, poni mixer, planetary mixer, rakai machine, kneader, roller mill, etc. Examples thereof include a method of mixing using a mixing and dispersing machine, and a method of distilling off the solvent after stirring and mixing using a solvent such as ethanol, isopropyl alcohol, n-hexane, isoparaffin, and toluene.

  The coating amount of the oligomer ester powder of the present invention on the powder depends on the particle diameter and specific surface area of the powder to be surface-treated, but is usually 0.01 to 25 parts by weight with respect to 100 parts by weight of the powder. Preferably it is the range of 0.1-15 weight part.

  The surface-treated powder of the present invention obtained as described above has excellent usability, whitening is suppressed, and dispersibility in the formulation is excellent compared to untreated powder. Moreover, when the powder to be processed is an ultraviolet scattering agent, it is possible to improve the SPF. The amount of the surface-treated powder of the present invention to be added to the cosmetic is preferably 0.01 to 99% by weight, more preferably based on the total amount of the cosmetic, although it depends on the cosmetic dosage form. Is 0.1 to 90% by weight.

  In addition to the surface-treated powder of the present invention, the cosmetics of the present invention include water and additives added to the normal cosmetics as necessary, such as oily bases, surfactants, alcohols, humectants, high Molecules, thickeners / gelling agents, antioxidants, antiseptics, bactericides, chelating agents, pH adjusters / acids / alkalis, UV absorbers, whitening agents, solvents, exfoliating / dissolving agents, antipruritics, anti-inflammatory agents , Antiperspirants, refreshing agents, antihistamines, astringents, stimulants, hair-restoring agents / blood circulation promoters, reducing agents / oxidants, polymer powders, hydroxy acids, vitamins and derivatives thereof, saccharides and derivatives thereof Organic acids, enzymes, nucleic acids, hormones, inorganic powders, fragrances, pigments and the like can be blended.

  Examples of oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexa Higher fatty acids such as canic acid, antiisohenicosanoic acid, long-chain branched fatty acid, dimer acid, hydrogenated dimer acid, and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium salts, sodium salts, etc. And nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, Hydrocarbons such as solid paraffin; candelilla wax, carnauba wax, rice wax, wax wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, fisher -Tropsch wax, polyethylene wax, waxes such as ethylene propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, Macadamia nut oil, hazelnut oil, cucumber oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, mint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, Vegetable oils such as rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; animals such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil Oils and fats; animal waxes such as whale wax, lanolin, orange luffy oil; liquid lanolin, reduced lano Lanolin, lanolin acetate, lanolin acetate, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, acetic acid lanolin alcohol, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine , Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids such as sphingomyelin, phospholipids such as phosphatidic acid, lysolecithin; hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid Phospholipid derivatives such as partially hydrogenated egg yolk phospholipids; cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytos Sterols such as roll and cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-N-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl) N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), N- Acyl sarcosine alkyl esters such as lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, macadamia nut fatty acid cholesteryl, macadamia nut oil fatty acid Sterol esters such as tosteryl, phytosteryl isostearate, phytosteryl oleate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; phospholipid / cholesterol complex, phospholipid / phytosterol Lipid complexes such as complexes; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl palmitate, octyldodecyl palmitate, cetyl octanoate, hexyldecyl octanoate, isotridecyl isononanoate, isononanoyl isononanoate, isononane Octyl acid, Isotridecyl isononanoate, Isodecyl neopentanoate, Isotridecyl neopentanoate, Iso neopentanoate Tearyl, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, lanolin fatty acid octyldodecyl, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isostearic acid hydrogenated castor oil, ethyl oleate, avocado oil fatty acid Ethyl, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, methyl heptyl laurate, methyl heptyl myristate, methyl heptyl palmitate, methyl heptyl isostearate, diethyl sebacate, diisopropyl sebacate, Dioctyl sebacate, diisopropyl adipate, dibutyl octyl sebacate, dii adipate Monoalcohol carboxylates such as sobutyl, dioctyl succinate, triethyl citrate; oxyesters such as cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate, γ-ercalactone; glyceryl trioctanoate, Glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (caprylic acid / capric acid), tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum) , Rosin triglyceride (ester gum), glyceryl behenate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentyl glycol dioctanoate Neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate, ( Isostearic acid / sebacic acid) ditrimethylolpropane, pentaerythrityl triethylhexanoate, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl nonaisostearate-10, deca (Eruca) Acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, diste Polyhydric alcohol fatty acid esters such as glycolic acid oleate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoate; dimer linoleic acid Diisopropyl, dimer dilinoleate diisostearyl, dimer dilinoleate di (isostearyl / phytosteryl), dimer dilinoleic acid (phytosteryl / behenyl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), die Dimerlinoleic acid dimerinolinoleyl, diisostearic acid dimerinolinoleic acid, dimerinolinoleic hydrogenated rosin condensate, dimerlinoleic acid hydrogenated castor oil, hydroxyalkyl dimerinolinolee Dimer acid or dimer diol derivative such as ter; palm oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA) , Fatty acid alkanolamides such as lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA); Polysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentaci) Xanthine), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, (aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, aminopropyl dimethicone and amodimethicone, cationic modification Polyether modified silicone such as silicone and dimethicone copolyol, polyglycerin modified silicone, sugar modified silicone, carboxylic acid modified silicone, phosphoric acid modified silicone, sulfuric acid modified silicone, alkyl modified silicone, fatty acid modified silicone, alkyl ether modified silicone, amino acid modified Silicone, peptide-modified silicone, fluorine-modified silicone, cation-modified and polyether-modified silicone Silicones such as amino-modified and polyether-modified silicones, alkyl-modified and polyether-modified silicones, amide alkyl-modified silicones, aminoglycol-modified silicones, aminophenyl-modified silicones, polysiloxane / oxyalkylene copolymers; Fluorine oils such as fluorooctane and perfluoropolyether are preferred.

  As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. (Eicosane diacid / tetradecanedioic acid) water-soluble esters such as polyglyceryl-10, tetradecanedioic acid polyglyceryl-10, and cyclohexanedicarboxylic acid bisethoxydiglycol; sugars such as sorbitol, xylitol, erythritol, mannitol, maltitol Alcohols; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ- Cyclodextrins and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabino Sugars and derivatives thereof such as galactan, dextrin, dextran, glycogen, ethyl glucoside, glucosylethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate, caroline sulfate, keratosulfate, dermatan Sulfuric acid; white jellyfish extract; white jellyfish polysaccharide; fucoidan; tuberose polysaccharide, naturally derived polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and their salts; urea; 2-pyrrolidone-5-carboxylic acid and its sodium Salt: betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, aspa Amino acids such as gin, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and the salts thereof; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagenolytic peptide, hydrolyzed collagen, Hydroxypropylammonium chloride hydrolyzed collagen, elastin degrading peptide, keratin degrading peptide, hydrolyzed keratin, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soy proteolytic peptide, wheat protein Degraded peptides, hydrolyzed wheat protein, casein-degraded peptides, acylated peptides and other protein peptides and their derivatives; palmitoyl oligopeptides , Acylated peptides such as palmitoyl pentapeptide, palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesameignan glycoside, glutathione, albumin, milk Chin; choline chloride, phosphorylcholine; placenta extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, Izayoi rose extract, yarrow extract, eucalyptus extract, merirot extract Preferred are ceramides such as animal and plant extract components such as natural ceramides (types 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide, and sugar-ceramide-containing extracts. All It is.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of a surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB. Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium phosphate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine, lysine Na dilauroyl glutamate; sodium laureth acetate, etc. Polyoxyethylene alkyl ether acetates; succinic acid ester salts such as sodium lauroyl monoethanolamide succinate; fatty acid alkanolamide ether carboxylates; acyl lactates; polyoxyethylene fatty amine sulfates; fatty acid alkanolamide sulfates; Fatty acid glyceride sulfate such as coconut oil fatty acid sodium glycerin sulfate; Oxyethylene sulfate; Olefin sulfonate such as sodium α-olefin sulfonate; Alkyl sulfosuccinate such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; Disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sulfosuccinate Alkyl ether sulfosuccinates such as sodium acid, sodium lauryl polypropylene glycol sulfosuccinate; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and triethanolamine tetradecylbenzenesulfonate; alkylnaphthalenesulfonate; alkanesulfonate; α-sulfo fatty acid methyl ester salt; acyl isethionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetates; alkyl ether phosphates such as sodium laureth phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate esters such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphorus Fatty acid amide ether phosphates; Phospholipids such as phosphatidylglycerol, phosphatidylinositol and phosphatidic acid; Silicone anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone and sulfuric acid-modified silicone; Among the ionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether) ), Behenes (polyoxyethylene behenyl ether), isosteares (polyoxyethylene isostearyl ether), octyldecesses (polyoxyethylene octyldodecyl ether), and other polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers Polyoxyethylene alkyl phenyl ether; polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil Castor oil and hydrogenated castor oil derivatives such as monopyroglutamic acid monoisostearic acid diester, polyoxyethylene hydrogenated castor oil maleic acid; polyoxyethylene phytosterol; polio Polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene / polyoxypropylene cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / poly Oxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene alkyl ethers such as polyoxyethylene / polyoxypropylene glycerin ether; polyoxyethylene / polyoxypropylene glycol; PPG-9 di (Poly) glycerin polyoxypropylene glycol such as glyceryl; glyceryl stearate, glyceryl isostearate, Glyceryl mymate, glyceryl myristate, glyceryl oleate, palm oil fatty acid glyceryl, mono cottonseed oil fatty acid glycerin, monoerucic acid glycerin, glyceryl sesquioleate, α, α'-oleic acid pyroglutamate glycerin, monostearic acid glycerin malic acid, etc. Glycerin fatty acid partial esters: polyglyceryl stearate-2, 3, 4, 5, 6, 8, 10, polyglyceryl-6 distearate, 10, polyglyceryl tristearate, polyglyceryl decastearate -10, polyglyceryl isostearate 2, 3, 4, 5, 6, 8, 10, diisostearate polyglyceryl-2 (diglyceryl diisostearate), 3, 10, polyglyceryl triisostearate 2, polyglyceryl-2 tetraisostearate, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, 3, 4, 5, 6, 8, 8, dioleate polyglyceryl-6, trioleate polyglyceryl -2, polyglyceryl fatty acid ester such as polyglyceryl-10 dekaoleate; ethylene glycol mono fatty acid ester such as ethylene glycol monostearate; propylene glycol mono fatty acid ester such as propylene glycol monostearate; pentaerythritol partial fatty acid ester; sorbitol partial fatty acid Maltitol partial fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbita Sorbitan fatty acid esters such as monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; sucrose fatty acid ester, methyl glucoside Sugar ester partial esters such as fatty acid esters and undecylenic acid trehalose; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; lanolin alcohols; reduced lanolins; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene mono Polyoxyethylene fatty acid mono- and diesters such as oleate and polyoxyethylene dioleate; polyoxyethylene propylene glycol Polyoxyethylene glycerol monostearate, polyoxyethylene glycerol monoisostearate, polyoxyethylene glycerol fatty acid esters such as polyoxyethylene monooleate such as polyoxyethylene glycerol triisostearate; polyoxyethylene Polyoxyethylene sorbitan fatty acid esters such as sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate Polyoxyethylene sorbitol pentaoleate, polyoxyethylene sorbitol monostearate, etc. Polyoxyethylene methyl glucoside fatty acid ester; Polyoxyethylene alkyl ether fatty acid ester; Polyoxyethylene animal and vegetable fats and oils such as polyoxyethylene sorbitol beeswax; Isostearyl glyceryl ether, chimyl alcohol, seraalkyl alcohol, batyl Alkyl glyceryl ethers such as alcohols; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acids Amides; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), la Phosphoric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamic acid MEA), palmitic acid diethanolamide (partamic acid DEA), coconut oil Fatty acid alkanolamides such as fatty acid methylethanolamide (cocamidomethyl MEA); alkyldimethylamine oxides such as lauramine oxide, cocamamine oxide, stearamine oxide, and behenamine oxide; alkylethoxydimethylamine oxide; polyoxyethylene alkylmercaptan; Polyether-modified silicone such as dimethicone copolyol, polysiloxane-oxyalkylene copolymer, polyglycerin-modified silicone Silicone-based nonionic surfactants such as corn and sugar-modified silicone; and cationic surfactants such as alkyltrimethylammonium chlorides such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, lauryltrimonium chloride; Alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; fatty acid amidoamines such as stearamidepropyldimethylamine and stearamideethyldiethylamine and salts thereof; stearoxypropyldimethyl Alkyl ether amines such as amines and salts or quaternary salts thereof; ethyl sulfate long chain branched fatty acid (12-31) aminopropylethyl dimethyl Fatty acid amide type quaternary ammonium salts such as ruammonium and ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium; polyoxyethylene alkylamines and salts or quaternary salts thereof; alkylamine salts; fatty acid amidoguanidinium salts; Alkyltrialkylene glycol ammonium salt; Benzalkonium salt; Benzethonium salt; Pyridinium salt such as cetylpyridinium chloride; Imidazolinium salt; Alkylisoquinolinium salt; Dialkyl morpholinium salt; Polyamine fatty acid derivative; Aminopropyl dimethicone And amino-modified silicone such as amodimethicone, cation-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone Cationic surfactants, etc .; in amphoteric surfactants, N-alkyl-N, N-dimethylamino acid betaines such as lauryl betaine (lauryl dimethylaminoacetic acid betaine); cocamidopropyl betaine, lauramidopropyl betaine, etc. Fatty acid amide alkyl-N, N-dimethylamino acid betaines; imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; alkyldimethylamino Phosphate betaines such as ethanol phosphates; sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingomyelin, lysolecithin, water Phospholipids such as raw-added soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, and hydroxylated lecithin; silicone-based amphoteric surfactants; Preferable examples include polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, acrylic acid / alkyl methacrylate copolymers, and various silicone surfactants.

  Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropi Cellulose, carboxymethylcellulose and its salts such as sodium, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch, Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinate corn starch and aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ether Polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymer; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, etc. Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; Kurylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquaternium Acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer such as 47, methacrylic acid choline ester polymer; cationized polysaccharides such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylalkyl ester emulsion, Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, Smoke-like silica (ultrafine silicic anhydride), aluminum magnesium silicate, magnesium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester It is mentioned as preferable.

  Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

  Antibacterial agents or antiseptics include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane 1,2-alkanediols such as diol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); salicylic acid; sodium benzoate; isothiazoline derivatives such as methyl chloroisothiazolinone and methylisothiazolinone; Dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzoyl chloride Luconium, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol , Photosensitizers, antibacterial zeolite, and silver ion are preferable, but when used as an antibacterial agent or antiseptic agent for antiseptic purposes, phenoxyethanol; 1 from the viewpoint of safety of cosmetics or skin external preparations; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol; alkyl glyceres such as 2-ethylhexyl glyceryl ether It is more preferred to use ethers.

  Examples of chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and ultrafine Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), titanium mica, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder Body, gold, aluminum, etc., various sizes and shapes of inorganic powders, and these are treated with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powders such as hydrophobized or hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, Benzoguanamine resin powder, polyethylene terephthalate, polymethyl Organic powders and surface-treated powders of various sizes and shapes, such as methacrylate powder, polyethylene terephthalate / aluminum / epoxy powder, urethane powder, silicone powder, Teflon (registered trademark) powder, organic-inorganic composite powder Is preferable. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

  Examples of ultraviolet absorbers include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester. Benzoic acid-based ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid And salicylic acid-based purple such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate Line absorber: Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), Cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxy Cinnamic acid-based UV absorbers such as namate, ferulic acid and derivatives thereof; 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4′-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone -5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc. Benzophenone purple 3- (4'-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole; 2- (2′-hydroxy-5′-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5- (3 , 3-dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyl triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- ( , 4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentanedione, dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, etc., hydantoin derivatives, phenylbenzimidazolazosulfonic acid, terephthalylidene dicamphsulfone Preference is given to acids, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives.

  Examples of whitening agents include hydroquinone glycosides such as arbutin and α-arbutin and esters thereof; ascorbic acid phosphate salts such as ascorbic acid, sodium ascorbate phosphate and magnesium ascorbate phosphate, ascorbic acid Ascorbic acid fatty acid esters such as tetraisopalmitic acid ester, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside and fatty acid esters thereof, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as kojic acid, ellagic acid, tranexamic acid and its derivatives, ferulic acid and its derivatives, placenta extract, glutathione, oryzanol, butylreso Shinoru, oil-soluble Kamomiraekisu, oil-soluble licorice extract, Nishikawa willow extract, be mentioned as saxifrage extract, and the like plant extracts are preferred.

  Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

  Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable. Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil. Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, α- or such as hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl β-hydroxy acids and derivatives thereof; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosines; caffeine, xanthine and the like; and coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloid, fullerenes, etc. Antioxidant / active oxygen scavengers; catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; rutin and glycosides, etc. Derivatives of hesperidin and glycosides; lignan glycosides; licorice extract-related substances such as grabrizine, glabrene, liquiritin, and isoliquiritin; lactoferrin; shogaol, gingerol; fragrance substances such as menthol, camphor, cedrol, and derivatives thereof Preferred examples include capsaicin, vanillin and the like and derivatives; insect repellents such as diethyltoluamide; and complexes of physiologically active substances and cyclodextrins.

  As plant / animal / microbe extracts, Iris extract, Ashitaba extract, Asunaro extract, Asparagus extract, Avocado extract, Achacha extract, Almond extract, Altea extract, Arnica extract, Aloe extract, Apricot extract, Ginkgo biloba extract, Ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

  Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor, and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.

  As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, vinegar Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damassenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute , Vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian valsum, vetiver oil, vetiverol, peppermint oil, Pepper oil, heliotropin, bergamot oil, benzyl benzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menthol, eucalyptus oil, β-yonone, lime oil, lavender oil, Synthetic and natural fragrances such as D-limonene, linalool, rilal, rireal, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and various blended fragrances It is mentioned as preferred.

  As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230 No. 1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505, red 506, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, orange 401, orange 402, orange 403, yellow 201, yellow 202- No. 1, yellow 202-2, yellow 203, yellow 204, yellow 205, yellow 4, yellow 401, yellow 402, yellow 403-1, yellow 404, yellow 405, yellow 406 Legal dyes such as Yellow No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Base dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4- Nitro dyes such as hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2 and Basic Blue 26; disperse dyes; inorganic white such as titanium dioxide and zinc oxide Pigments: Inorganic red pigments such as iron oxide (Bengara) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and loess; Black iron oxide, low-order titanium oxide, etc. Inorganic pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium oxide coated mica; Titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, pearl pigments such as fish scale foil; aluminum powder, copper powder, gold, etc. Surface treated inorganic and metal powder pigments: Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204 No., Yellow 205, Yellow 401, Blue 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Organic pigments such as zirconium, barium or aluminum lake such as yellow 5, yellow 202, yellow 203, green 3 and blue 1; surface treatment organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene , Catenal, capsanthin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, cochini Natural pigments and dyes such as naphthoquinones such as ru and shikonin, bixin, flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m- Oxidative dye intermediates and couplers such as p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and their salts; Oxidizing dyes; dihydroxyacetone is preferred.

  Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

  In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, Japanese pharmacopoeia, pharmaceutical additives Ingredients listed in standards, official food additives, etc., and Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the ingredients described, in known combinations, blending ratios and blending amounts.

  Examples of cosmetics containing the surface-treated powder of the present invention include hair cosmetics, basic cosmetics, makeup cosmetics, sunscreen cosmetics, aromatic cosmetics, body cosmetics, ointments and the like. Etc. From the viewpoint of exerting the effects of the present invention, it can be preferably used particularly for sunscreen cosmetics and makeup cosmetics. The cosmetic of the present invention can be produced according to a usual method.

  The types of cosmetics of the present invention will be described in more detail. Examples of hair cosmetics include oil shampoos, cream shampoos, conditioning shampoos, dandruff shampoos, hair color shampoos, shampoos with integrated rinses, rinses, and treatments. Conditioners such as hair pack, hair mist, hair foam, hair mousse, hair spray, hair wax, hair gel, hair cream, water grease, set lotion, pomade, tic, etc .; color lotion, hair tonic, hair liquid, hair blow, Split hair coat, hair oil, permanent wave agent, straight permanent agent, oxidative hair dye, hair bleach, hair color pre-treatment, hair color after treatment, permanent pre-treat DOO, permanent after-treatments, hair manicure, and as hair growth agents are preferred.

  Basic cosmetics include soft lotion, astringent lotion, cleansing lotion, multi-layer lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisture, moisturizer -Emulsions such as emulsion, massage lotion, cleansing lotion, protective emulsion, makeup lotion, horny smoother, elbow lotion, hand lotion, body lotion; emollient cream, nourishing cream, nourishing cream, vanishing cream, moisture cream, night cream, Massage cream, cleansing cream, makeup cream, base cream, pre-makeup cream, hair removal cream, deodorant cream Creams such as shaving cream and keratin softening cream; Moisture gel and other gels; Moisturizing essence and whitening essence; Liposome cosmetics such as liposome serum and liposome skin lotion; Peel-off pack, powder pack, washing pack, oil pack, cleansing mask, etc. Cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing oil, cleansing mask, washing powder, face washing powder, etc .; cosmetic soap, transparent soap, medicated soap, liquid soap, shaving soap Soaps such as synthetic cosmetic soaps are preferred.

  As makeup cosmetics, white powder, dusting powder, foundations, lipsticks, lip gloss, blusher, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment are preferable. .

  As sunscreen cosmetics, sunprotect, sun protector, UV care milk, sunscreen emulsion; creams such as sunscreen cream and suntan cream; and UV protection essence are preferable.

  Preferred examples of the aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, eau de cologne, perfumes, fragrance powder, perfume soap, body lotion and bath oil.

  Body cosmetics such as body shampoos; deodorant lotions, deodorant powders, deodorant sprays, deodorant sticks and other deodorant cosmetics; A repeller is preferred.

  As an external preparation for skin, it can be used in dosage forms such as an ointment, a patch, a lotion, a liniment, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

  As the dosage form of the cosmetic or external preparation for skin of the present invention, emulsification such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type, etc. Type cosmetics, oily cosmetics, solid cosmetics, liquid cosmetics, paste cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics, jelly cosmetics, gel cosmetics, pastes Preferred examples include cosmetics, emulsified polymer cosmetics, sheet cosmetics, mist cosmetics, and spray cosmetics.

  EXAMPLES Hereinafter, although this invention is demonstrated in detail using an Example, this invention is not limited to these Examples. The number average molecular weight described below is a value measured by a gel permeation chromatography (GPC) method using a polyethylene oxide having a known molecular weight as a standard in a DMF solvent.

Synthesis Example 1 (Eicosanedioic acid / Tetradecanedioic acid) Polyglyceryl-10
292 g (0.35) of polyglycerin 90% aqueous solution (polyglycerin # 750, manufactured by Sakamoto Pharmaceutical Co., Ltd.) having an average degree of polymerization calculated from the hydroxyl value of 10 in a 1 L reactor equipped with a stirrer, a thermometer and a gas introduction tube. Mole), and after dehydration under reduced pressure, 71.8 g (0.21 mol) of eicosandioic acid (manufactured by Okamura Oil Co., Ltd., SL-20), 36.1 g (0.14 mol) of tetradecanedioic acid (manufactured by Cognis, EMEROX114) Was heated to 210-220 ° C. in a nitrogen stream, and the esterification reaction was carried out for 24 hours while distilling off the generated water to obtain 341 g of a solid compound at room temperature. 2. The number average molecular weight was 3900.

Synthesis Example 2 (Eicosanedioic acid / Tetradecanedioic acid) Polyglyceryl-4
In a 1 L reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 392 g (1.2%) of a polyglycerin 95% aqueous solution (polyglycerin # 310, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) having an average degree of polymerization calculated from the hydroxyl value of 4 was obtained. Mole) and after dehydration under reduced pressure, 123 g (0.36 mol) of eicosandioic acid (manufactured by Okamura Oil Co., Ltd., SL-20), 61.9 g (0.24 mol) of tetradecanedioic acid (manufactured by Kognis, EMEROX114) The mixture was heated to 210-220 ° C. in a nitrogen stream, and the esterification reaction was carried out for 24 hours while distilling off the generated water, to obtain 504 g of a solid compound at room temperature. The acid value of the obtained compound was 0.3, and the number average molecular weight was 1700.

Synthesis Example 3 Polyglyceryl-10 sebacate
In a 1 L reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 415 g (0.5%) of a polyglycerin 90% aqueous solution (polyglycerin # 750, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) having an average degree of polymerization calculated from the hydroxyl value of 10 was obtained. Mol), dehydrated under reduced pressure, and then charged with 101 g (0.5 mol) of sebacic acid, heated to 210-220 ° C. in a nitrogen stream, and subjected to an esterification reaction for 24 hours while distilling off the generated water. 440 g of pasty compound was obtained. The acid value of the obtained compound was 0.2, and the number average molecular weight was 3,800.

Synthesis Example 4 Polyglyceryl sebacate-6.5
In a 1 L reactor equipped with a stirrer, a thermometer, and a gas introduction tube, 556 g (1) of a polyglycerin 90% aqueous solution (polyglycerin # 500, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) having an average polymerization degree of 6.5 calculated from the hydroxyl value. 0.0 mol), dehydrated under reduced pressure, charged with 101 g (0.5 mol) of sebacic acid, heated to 210-220 ° C. in a nitrogen stream, and subjected to esterification reaction for 24 hours while distilling off the generated water. 550 g of a paste-like compound was obtained at room temperature. The acid value of the obtained compound was 0.3, and the number average molecular weight was 1600.

Preparation / Evaluation of Surface Treated Powder of the Present Invention Surface treated powders were prepared by coating various powders with oligomer esters with the compositions shown in Tables 1 and 2. First, the oligomer ester was dissolved in 2-fold weight isopropyl alcohol with respect to the powder, and the powder was put into this solution. After stirring and mixing, isopropyl alcohol was distilled off under reduced pressure, dried, and pulverized in a mortar to obtain the surface-treated powder of the present invention. The resulting surface-treated powder was evaluated for feel and dispersibility by the following methods, and the results are shown in Tables 1 and 2.

<Feel evaluation>
A certain amount of each surface-treated powder was applied to the skin, and sensory evaluation was performed by five specialist panelists on the four items of spread, no creaking, familiarity, and adhesion. The evaluation was performed in the following five stages based on the powder not coated with the oligomer ester (Comparative Examples 1 to 4), and the results were shown as average points.

Rating 5 points: Good 4 points: Somewhat good 3 points: Same 2 points: Somewhat bad 1 point: Bad

<Dispersibility evaluation>
1 g of each surface-treated powder was dispersed in 9 g of each oil in a test tube, and the state of dispersion immediately after dispersion and after standing at 25 ° C. for 1 hour was visually confirmed. Evaluation was based on the following judgment criteria based on powders (Comparative Examples 1 to 4) not coated with oligomer ester.

○: Dispersibility is good △: Dispersibility is slightly good ×: Same

  From the results of Tables 1 and 2, the surface-treated powder of the present invention is superior in use feeling when applied to the skin, compared to the powder not coated with the oligomer ester (Comparative Examples 1 to 4). It was found that the sex was improved.

Evaluation of sunscreen cosmetics Using the surface-treated powders of Examples 5, 9, and 11, sunscreen cosmetics having the compositions shown in Table 3 were prepared (Examples 14, 15, and 16). For comparison, sunscreen cosmetics (Comparative Examples 6, 8, and 10) containing untreated powder not coated with the oligomer ester of the present invention, and the untreated powder and the oligomer ester of the present invention, respectively. Blended sunscreen cosmetics (Comparative Examples 5, 7, 9) were prepared. About the obtained sunscreen cosmetics, the feeling when applied to the skin, the degree of whitening, and the dispersibility were evaluated, and the results are also shown in Table 3. Moreover, about the sunscreen cosmetics of Example 14 and the sunscreen cosmetics of Comparative Examples 5 and 6, SPF was measured by the following method, and the results are also shown in Table 3.

<Feel evaluation>
A certain amount of each sunscreen cosmetic was applied to the skin, and sensory evaluation was conducted by five expert panelists on two items, no spread and creaking. The evaluation was performed in the following five stages based on the sunscreen cosmetics (Comparative Examples 6, 8, and 10) prepared using powder not coated with the oligomer ester, and the results are shown as average points.

Rating 5 points: Good 4 points: Somewhat good 3 points: Same 2 points: Somewhat bad 1 point: Bad

<Evaluation of degree of white float>
After applying a certain amount of each sunscreen cosmetic to the back of the hand and spreading it evenly, the degree of whitening was visually confirmed. The evaluation was based on the following judgment criteria based on the sunscreen cosmetics (Comparative Examples 6, 8, and 10) prepared using powder not coated with the oligomer ester.

○: Whitening is suppressed △: Whitening is slightly suppressed ×: Same

<Dispersibility evaluation>
The appearance of each sunscreen cosmetic after standing at 25 ° C. for 1 day was visually confirmed to evaluate dispersibility. Evaluation was based on the following criteria based on sunscreen cosmetics (Comparative Examples 6, 8, 10) prepared using powder not coated with oligomer ester.

○: Dispersibility is good △: Dispersibility is slightly good ×: Same

<SPF evaluation>
About the sunscreen cosmetics of Example 14 and the sunscreen cosmetics of Comparative Examples 5 and 6, SPF was measured with an SPF analyzer (UV-1000S manufactured by Labsphere). A plate obtained by uniformly applying 0.03 mL of sunscreen cosmetics to a PMMA plate and drying for 15 minutes was used as a measurement sample. After measuring 7 points per plate and measuring 3 plates per sample, the average value obtained by deleting the upper limit value and lower limit value of the measured value was defined as SPF.

  From the results of Table 3, the sunscreen cosmetics produced using the surface-treated powder of the present invention are more comfortable to use than the sunscreen cosmetics produced using a powder not coated with the oligomer ester. It was found that there was no white floating, dispersibility, and SPF were improved. Even when compared with sunscreen cosmetics in which the oligomer ester is not coated on the powder and the oligomer ester and the powder are blended separately, the feeling of use, no whitening, dispersibility, and SPF are good. It has been found that an excellent effect is exhibited by performing a coating treatment in advance.

Evaluation in Makeup Cosmetics A foundation having the composition shown in Table 4 was prepared using the surface-treated powder of the present invention (Example 17). For comparison, a foundation in which an untreated powder not coated with the oligomer ester of the present invention was blended (Comparative Example 12), and a foundation in which each of the untreated powder and the oligomer ester of the present invention was blended (Comparative Example 11). ) Was produced. The feel and color developability of the obtained foundation were evaluated by the following methods. The results are shown in Table 4.

<Feel evaluation>
A certain amount of each foundation was applied to the skin, and sensory evaluation was performed by five expert panelists on three items: spread, no creaking, and familiarity. The evaluation was performed in the following five stages based on a foundation (Comparative Example 12) prepared using a powder not coated with the oligomer ester, and the results are shown as average points.

Rating 5 points: Good 4 points: Somewhat good 3 points: Same 2 points: Somewhat bad 1 point: Bad

<Color development evaluation>
A certain amount of each foundation was applied to the skin, and the appearance after drying was visually observed. The bottom evaluation was based on the foundation (Comparative Example 12) prepared using a powder not coated with the oligomer ester and evaluated according to the following criteria.

○: Little color unevenness △: Little color unevenness ×: Same

  From the results of Table 4, the foundation produced using the surface-treated powder of the present invention has improved usability and color development compared to the foundation produced using a powder not coated with the oligomer ester. I found out. In addition, even when compared with a foundation in which oligomer ester and powder are blended separately, the oligomer ester is not coated on the powder, the feeling of use and color development are good, and the effect is excellent by performing the coating treatment in advance. It was found that

  The cosmetics described below were prepared using the surface-treated powder of the present invention. Each of the obtained cosmetics has an excellent feeling of use, and sunscreen cosmetics have good spreading, suppress creaking and whitening, and makeup cosmetics have good spreading and familiarity. Was to suppress.

Example 18 Sunscreen cosmetic
Component Blending amount (% by weight)
------------------------------------
Part A Cetanol 1.0
Mineral oil 5.0
Phenyltrimethicone 5.0
Part B Surface-treated powder of Example 1 5.0
Surface treated powder of Example 11 1.0
Dimethicone 5.0
Decaglyceryl pentastearate1.0
Decaglyceryl tristearate1.0
Part C Glycerin 10.0
Xanthan gum 0.5
Purified water Total amount of 100 ------------------------------------
(Preparation method)
Part A and part B were mixed, heated to 80 ° C., and then uniformly stirred with a homomixer. This was mixed with part C and emulsified. Cooled to about 50 ° C. with stirring.

Example 19 Sunscreen Cosmetic
Component Blending amount (% by weight)
------------------------------------
Part A Cetanol 1.0
Squalane 5.0
Phenyltrimethicone 5.0
Part B Surface-treated powder of Example 5 5.0
Surface treated powder of Example 11 1.0
Dimethicone 5.0
Hexaglyceryl pentastearate1.0
Sucrose stearate 1.0
Stearic acid-treated fine particle titanium oxide 1.0
Part C Glycerin 10.0
Neosolute-AquaS (Nippon Seika) 0.5
Xanthan gum 0.5
Purified water Total amount of 100 ------------------------------------
(Preparation method)
Part A and part B were mixed, heated to 80 ° C., and stirred uniformly with a homomixer. This was mixed with part C and emulsified. Cooled to about 50 ° C. with stirring.

Example 20 Sunscreen Cosmetic
Component Blending amount (% by weight)
------------------------------------
Part A Ethylhexyl methoxycinnamate 5.0
Diethylaminohydroxybenzoyl hexyl benzoate 5.0
Isotridecyl isononanoate 10.0
Bisethylhexyloxyphenol methoxyphenyl triazine 1.0
Polysilicone-15 0.2
Diphenylsiloxyphenyl trimethicone 0.2
PEG-30 phytosterol 0.3
PEG-5 phytosterol 1.0
Sorbitan oleate 1.5
Tocopherol 0.1
BHT 0.05
Part B Surface-treated powder of Example 5 1.0
(Dimethicone / Vinyl Dimethicone) Cross Polymer 2.0
(Dimethicone / Phenyl Vinyl Dimethicone) Cross Polymer 2.0
(Vinyl Dimethicone / Methicon Silsesquioxane) Cross Polymer 1.5
Part C Carbomer 0.1
Glycerin 5.0
Phenoxyethanol 0.2
Methylparaben 0.15
Dicapric acid PG 1.0
BG 5.0
DPG 2.0
Ethanol 5.0
Water Amount D totaling 100 parts (Na acrylate / acryloyldimethyltaurine Na) copolymer 1.0
(Acrylates / alkyl acrylate (C10-30)) cross polymer
0.5
Part E Hydroxide K Appropriate amount Water 5.0
------------------------------------
(Preparation method)
Part B was dispersed in part A. This was heated to 80 ° C., part C heated to 80 ° C. was added, and the mixture was uniformly stirred with a homomixer. While stirring, the mixture was cooled to about 50 ° C., and parts D and E were mixed.

Example 21 Sunscreen cosmetic
Component Blending amount (% by weight)
------------------------------------
Part A IPSE (Nippon Seika) 5.0
NS-408 (Nippon Seika) 5.0
Plandool-MAS (Nippon Seika) 1.0
Part B (Dimethicone / Vinyl Dimethicone) Cross Polymer 5.0
(Vinyl Dimethicone / Methicon Silsesquioxane) Cross Polymer 5.0
Silica-treated fine particle titanium oxide 1.0
Surface treated powder of example 11 5.0
Part C Cyclomethicone Total amount of 100 Isododecane 10.0
Diethylaminohydroxybenzoyl hexyl benzoate,
Ethyl hexyl methoxycinnamate (Ubinal A Plus B: BASF) 10.0
Ethyl hexyl methoxycinnamate 3.0
Octocrylene 3.0
Cetyl diglyceryl tris (trimethylsiloxy) silylethyl dimethicone
1.0
PEG / PPG-19 / 19 dimethicone, cyclomethicone mixture 0.25
Bisethylhexyloxyphenol methoxyphenyl triazine 1.0
Part D Tremoist-SL (Nippon Seika) 0.5
VC ethyl (Nippon Seika) 0.1
Sodium citrate appropriate amount Citric acid appropriate amount water 10.0
Ethanol 10.0
Glycerin 3.0
------------------------------------
(Preparation method)
After dissolving part A at 80 ° C., part B was added and dispersed. After adding part C, part D was added while stirring with a homomixer.

Example 22 Sunscreen cosmetics
Component Blending amount (% by weight)
------------------------------------
Part A cyclopentasiloxane 20.0
Dimethicone 2.0
PEG-10 Dimethicone 1.0
Polyglyceryl-3 polydimethylsiloxyethyl dimethicone 5.0
Olefin oligomer 1.0
Part B Surface-treated powder of Example 5 5.0
Silica-treated fine particle zinc oxide 1.0
Iron oxide appropriate amount (dimethicone / (PEG-10 / 15)) cross polymer 0.5
(Dimethicone / Vinyl Dimethicone) Cross Polymer 2.0
Polymethylsilsesquioxane 1.0
Silica 0.5
(Hydroxylation / carbonic acid) (Mg / Al / zinc) 0.5
Methyl methacrylate cross polymer 1.0
Part C Methylparaben appropriate amount Na citrate appropriate amount Na chloride appropriate amount PEG-45M 0.2
Phenoxyethanol 0.2
Water total amount 100 DPG 5.0
Glycerin 3.0
Ethanol 3.0
------------------------------------
(Preparation method)
Part B was added to part A and dispersed. Part C was added while stirring with a homomixer.

Example 23 Sunscreen cosmetics
Component Blending amount (% by weight)
------------------------------------
Part A Glyceryl stearate (SE) 1.0
Stearic acid PG (SE) 1.0
Octocrylene 4.0
Octyl salicylate 4.0
Diethylaminohydroxybenzoyl hexyl benzoate 2.25
t-Butylmethoxydibenzoylmethane 1.0
Bisethylhexyloxyphenol methoxyphenyl triazine 0.1
Diethylaminohydroxybenzoyl hexyl benzoate 0.1
Ethylhexyl triazone 0.1
Homosalate 0.1
4- (2-β-Glucopyranosiloxane) propoxy-2-hydroxybenzophenone 0.1
2-Hydroxy-4-methoxybenzophenone 0.1
Dimethyldiethylbenzalmalonate 0.1
Oxybenzone-3 0.1
Neosolute-EHS (Nippon Seika) 3.0
Dimethicone 5.0
Myristyl alcohol 2.0
Cetearyl alcohol 2.0
Isononyl isononanoate 6.0
Plandool-S (Nippon Seika) 1.0
BHT 0.02
Part B Carbomer 0.1
Hydroxide K 0.07
Cellulose gum 0.1
Kangten 0.1
Tremoist-SL (Nippon Seika) 10.0
Part C Methylparaben 0.15
EDTA-2Na 0.1
Neosolu-Aquilio (Nippon Seika) 1.0
Purified water Total amount of 100 parts D VC ethyl (Nihon Seika) 0.1
2-0-ethylascorbic acid 0.1
Cetyl tranexamate 0.1
Tranexamic acid 1.0
Placenta extract 0.1
Part E Surface-treated powder of Example 5 5.0
------------------------------------
(Preparation method)
Part A, part B and part C were mixed, heated to about 80 ° C., and uniformly dissolved and dispersed. While stirring Part A, Part C was added and emulsified. After cooling, at about 50 ° C., parts B, D, and E were added and stirred to cool to about 40 ° C.

Example 24 Sunscreen Cosmetic
Component Blending amount (% by weight)
--------------------------------------
Part A Quotanium-18 Hectorite 1.00
Part B Cyclomethicone 13.70
Diphenyl dimethicone 7.00
Dimethicone copolyol 5.50
Plandool-MAS (Nippon Seika) 1.00
Part C Methylhydrogenpolysiloxane treated fine particle titanium oxide 3.90
Surface-treated powder of Example 11 2.10
D part Al stearate 0.70
Hydroxide Al 0.50
Isononyl isononanoate 2.50
Isodecyl neopentanoate 2.50
Part E Trimethylsiloxysilicate 1.20
Dimethicone 0.80
Meticon 0.10
Stearyl glycyrrhetinate 0.02
Sorbitan sesquioleate 2.00
Tocopherol 0.02
Part F Tranexamic acid 2.00
Phytic acid 0.04
(Acryloyldimethyltaurine ammonium / VP) copolymer 0.30
Na chloride 1.00
Hydroxyethane diphosphonic acid solution (60%) 0.07
Lactic acid 0.05
Lactic acid Na appropriate amount Hyaluronic acid Na 0.20
Isopropyl methylphenol 0.05
EDTA-3Na 0.10
Methylparaben 0.15
Purified water Total amount of 100 --------------------------------------
(Production method)
Part A was added to part B and stirred. Further, part C was added and dispersed using a roller mill. Part D was heated and melted to the mixture of parts A to C, and further part E was added and heated to about 70 ° C. Part F was heated and gradually emulsified with stirring into the mixture from part A to part E.

Example 25 Sunscreen cosmetics
Component Blending amount (% by weight)
----------------------------------
Part A Quotanium-18 Hectorite 1.0
Part B Cyclomethicone 13.7
Diphenyl dimethicone 7.0
Dimethicone copolyol 5.5
Part C: Hydroxylated Al hydroxide treated fine particles Titanium oxide 3.9
Surface-treated powder of Example 11 2.1
D part Al stearate 0.7
Hydroxide Al 0.5
Isononyl isononanoate 2.5
Isodecyl neopentanoate 1.5
Neosolute-DE (Nippon Seika) 1.0
Part E Trimethylsiloxysilicate 1.2
Dimethicone 0.8
Methicone 0.1
Polymethylsilsesquioxane 0.1
Trifluoroalkyldimethyltrimethylsiloxysilicate 0.1
Cetearyl dimethicone cross polymer 0.1
Stearyl glycyrrhetinate 0.02
Sorbitan sesquioleate 2.0
Tocopherol 0.02
Part F Na chloride 1.0
Methylparaben 0.15
Purified water Total amount of 100 ----------------------------------
(Production method)
Part A was added to part B and stirred. Further, part C was added and dispersed using a roller mill. Part D was added to the mixture of A, B, and C while being heated and melted, and further part E was added and heated to about 70 ° C. Part F was heated, gradually added to the mixture of parts A to E with stirring and emulsified, and then cooled to 40 ° C. with stirring.

Example 26 Sunscreen Cosmetic
Component Blending amount (% by weight)
----------------------------------
Part A Phytocopo-PP (Nippon Seika) 1.0
BG 8.0
Glycerin 5.0
Part B Ethylhexyl methoxycinnamate 5.0
Dimethicone 5.0
Part C Surface-treated powder of Example 5 1.0
Part D Carbomer 0.2
Hydroxide K Appropriate amount Purified water 20.0
Part E Tremoist-SL (Nippon Seika) 10.0
Methylparaben 0.15
Purified water Total amount of 100 ----------------------------------
(Preparation method)
Part A, part B and part E were mixed, heated to about 70 ° C., and uniformly dissolved and dispersed. Part D was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homodisper, part E was added and emulsified. After adding part C and dispersing, it was cooled and at about 50 ° C., part D was added, stirred and cooled to about 40 ° C.

Example 27 Sunscreen cosmetics
Component Blending amount (% by weight)
----------------------------------
Part A Phytocopo-PP (Nippon Seika) 1.0
BG 10.0
Glycerin 9.0
Neosolu-Aculio (Nihon Seika) 0.5
Part B Shea Fat 8.0
Plandool-MAS (Nippon Seika) 2.0
Part C Surface-treated powder of Example 5 1.0
Part D Carbomer 0.2
Hydroxide K Appropriate amount Purified water 20.0
Part E Tremoist-SL (Nippon Seika) 10.0
Methylparaben 0.15
Purified water Total amount of 100 ----------------------------------
(Preparation method)
Part A, part B and part E were mixed, heated to about 70 ° C., and uniformly dissolved and dispersed. Part D was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homodisper, part E was added and emulsified. After adding part C and dispersing, it was cooled and at about 50 ° C., part D was added, stirred and cooled to about 40 ° C.

Example 28 Sunscreen Cosmetic
Component Blending amount (% by weight)
----------------------------------
Part A Phytocopo-PP (Nippon Seika) 1.0
BG 10.0
Glycerin 9.0
Part B Octocrylene 4.0
Octyl salicylate 4.0
Diethylaminohydroxybenzoyl hexyl benzoate 2.25
t-Butylmethoxydibenzoylmethane 1.0
Neosolute-EHS (Nippon Seika) 3.0
Dimethicone 5.0
Behenyl alcohol 2.0
Cetearyl alcohol 2.0
Plandool-MAS (Nippon Seika) 1.0
Tocopherol 0.05
Part C Surface-treated powder of Example 5 1.0
Part D Carbomer 0.1
Hydroxide K Appropriate amount Purified water 20.0
Part E Tremoist-SL (Nippon Seika) 10.0
Methylparaben 0.15
Purified water Total amount of 100 ----------------------------------
(Preparation method)
Part A, part B and part E were mixed, heated to about 70 ° C., and uniformly dissolved and dispersed. Part D was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homodisper, part E was added and emulsified. After adding part C and dispersing, it was cooled and at about 50 ° C., part D was added, stirred and cooled to about 40 ° C.

Example 29 Foundation
Component Blending amount (% by weight)
-----------------------------------
Part A Glyceryl stearate (SE) 1.00
Stearic acid PG (SE) 1.00
Cetyl octanoate 6.00
Cyclopentasiloxane 9.0
Mineral oil 4.0
Ethyl hexyl methoxycinnamate 3.0
Plandool-H (Nippon Seika) 1.0
Plandool-G (Nippon Seika) 1.0
Plandool-MAS (Nippon Seika) 1.0
Vaseline 1.0
Phenyltrimethicone 2.0
Sorbitan isostearate 1.5
Tribehenine 0.5
(Butyl acrylate / dimethacrylate glycol) cross polymer,
Silica, (Methyl methacrylate / Dimethacrylate glycol)
Cross-polymer mixture 2.0
Boron nitride 1.0
PEG / PPG-19 / 19 dimethicone,
Cyclopentasiloxane mixture 4.0
Distemalimonium Hectorite (20%) 2.5
Polypropylsilsesquioxane,
Cyclopentasiloxane mixture 1.0
Mica 15.0
Talc 4.0
Surface treated powder of example 11 5.0
Surface treated powder of Example 13 10.0
Iron oxide 1.5
Part B Water Total amount of 100 DPG 4.0
Maltitol (75% solution) 1.0
Na chloride 1.0
BG 1.0
Tremoist-SL (Nippon Seika) 1.0
Polypropylsilsesquioxane, cyclopentasiloxane mixture 1.0
Phenoxyethanol 0.3
-----------------------------------
(Preparation method)
Part A was heated to about 70 ° C., stirred well and dispersed uniformly. Part B was heated to about 70 ° C. and homogenized, then part B was added to part A, stirred and emulsified at about 70 ° C., and cooled to about 40 ° C.

Example 30 Lipstick
Component Blending amount (% by weight)
------------------------------------
Diisostearyl malate 27.2
LUSPLAN SR-DP4 (Nippon Seika) 7.0
Hydrogenated polyisobutene 5.0
IOTG (Japan Seika) 10.0
Neosolute-MCT (Nippon Seika) Total amount of 100 Dialkyl carbonate (C14, 15) 3.0
Dextrin palmitate 0.9
Stearoyl lactate Na 0.9
Cetyl octanoate 24.0
Dimethicone 5.0
Plandool-MAS (Nippon Seika) 2.0
Ceresin 8.5
Candelilla Row 4.0
Sorbitan sesquioleate 0.15
Hydrogen Dimethicone 2.0
Ethanol 0.1
Tocopherol 0.5
Nylon-12 2.0
(Ethylene / Propylene) Copolymer 0.5
Sulfuric acid Ba 1.0
Iron oxide 2.0
Mica 2.0
Surface treated powder of Example 13 1.0
------------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 31 Lipstick
Component Blending amount (% by weight)
------------------------------------
Plandool-S (Nippon Seika) 10.0
Pentaerythrityl tetraisostearate Total amount of 100 Prandool-MAS (Nippon Seika) 3.0
Cyclomethicone 10.0
LUSPLAN DD-DA5 (Nippon Seika) 7.0
Dimethylsilylated silica 5.0
Synthetic wax 10.0
Candelilla Row 5.0
Sorbitan sesquiisostearate 4.0
Tocopherol 0.5
Iron oxide 2.0
Surface treated powder of example 13 2.0
Mica 1.0
------------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 32 Lipstick
Component Blending amount (% by weight)
------------------------------------
Hydrogenated polyisobutene 15.0
Plandool-G (Nippon Seika) 15.0
Plandool-DP (Nippon Seika) 10.0
IOTG (Japan Seika) Total amount of 100 Vaseline 1.5
Isododecane 10.0
Cyclomethicone 6.0
Polyethylene wax 9.0
Microcrystalline wax 5.0
LUSPLAN PI-DA (Nippon Seika) 5.0
Sorbitan sesquiisostearate 4.0
Macadamia nut oil 1.0
Tocopherol 0.5
Iron oxide 2.25
Surface-treated powder of Example 13 2.25
Mica 1.5
Red 202 1.5
------------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 33 Lipstick
Component Blending amount (% by weight)
------------------------------------
Plandool-ISS (Nippon Seika) 15.0
Plandool-SUN (Nippon Seika) 15.0
Hydrogenated polyisobutene Total amount of 100 LUSPLAN DD-DA7 (Nippon Seika) 3.0
YOFCO CLC-678 (Nippon Seika) 1.5
YOFCO MAC (Nippon Seika) 3.0
Shea fat 1.0
Candelilla Row 5.5
Ceresin 9.0
Dimethicone copolyol 0.5
Sorbitan sesquiisostearate 2.0
Tocopherol 0.1
Iron oxide 1.2
Surface treated powder of Example 13 1.2
Mica 1.5
Red 202 0.3
Purified water 6.0
------------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 34 Lipstick
Component Blending amount (% by weight)
------------------------------------
Plandool-H (Nippon Seika) 15.0
Dimerlinoleic acid hydrogenated castor oil 10.0
Purified lanolin (Nippon Seika) 10.0
Hexa (behenic acid / benzoic acid / ethylhexanoic acid) dipentaerythrityl
5.0
Benzyldimethylstearylammonium bentonite 0.36
POE (20) hydrogenated castor oil 0.12
Hydrogenated polyisobutene Total amount of 100 Neosole-EHS (Nippon Seika) 10.0
NS-CIO (Nippon Seika) 10.0
Plandool-SUN (Nippon Seika) 5.0
Sunflower oil 1.0
Cellulose 1.0
Polyethylene wax 5.0
Microcrystalline wax 4.0
Candelilla wax 1.0
Hydrogenated jojoba oil 1.0
Beeswax 1.0
Squalane from olive oil 1.0
Sorbitan isostearate 0.1
Ascorbyl dipalmitate 0.1
N-stearoyl-L-glutamic acid 2Na 0.15
d-δ-tocopherol 0.1
Red 201 No. 2.4
Red No. 202 0.8
Black iron oxide 0.3
Synthetic mica 0.47
Surface treated powder of Example 13 0.5
Bengala coated mica titanium 3.0
Acyl peptide mixture (Maxilip manufactured by Zederma) 0.5
------------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 35 Lipstick
Component Blending amount (% by weight)
------------------------------------
Plandool-G (Nippon Seika) 20.0
Plandool-MAS (Nippon Seika) 10.0
YOFCO MAC (Nippon Seika) 1.0
Plandool-LG1 (Nippon Seika) 1.0
Plandool-LG2 (Nippon Seika) 1.0
Plandool-LG3 (Nippon Seika) 1.0
Plandool-LG4 (Nippon Seika) 1.0
Hydrogenated polyisobutene Total amount of 100 LUSPLAN DD-DHR (Nippon Seika) 3.0
IPSE (Japan Seika) 19.0
Candelilla Row 4.0
Ceresin 5.0
Paraffin 3.0
Dimethicone copolyol 0.5
Sorbitan sesquiisostearate 2.0
Tocopherol 0.1
Iron oxide 1.2
Surface treated powder of Example 13 1.2
Mica 1.5
Red 218 0.1
Red 223 0.1
Orange 201 No.0.1
Glycerin 1.0
BG 1.0
Purified water 2.0
------------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 36 Lipstick
Component Blending amount (% by weight)
--------------------------------------
Plandool-G (Nippon Seika) 10.0
Plandool-LG2 (Nippon Seika) 10.0
Mineral oil 10.0
IOTG (Japan Seika) 10.0
Octilde decanol 5.0
Amount of diisostearyl malate totaling 100 Phytocompo-PP (Nippon Seika) 5.0
Phytopresom Cera-236 (Nippon Seika) 0.5
2-ethylhexyl hydroxystearate 3.0
(Polyglyceryl-2 isostearate / dimerlinoleic acid) copolymer
1.0
Neopentyl glycol dicaprate 1.0
Candelilla Row 4.0
Rice wax 8.0
Polyethylene wax 2.0
Tribehenine 1.0
Sorbitan sesquiisostearate 2.0
Rosehip oil 0.1
VC ethyl (Nippon Seika) 0.01
Tocopherol 0.1
Iron oxide 2.0
Surface treated powder of Example 13 1.2
Mica 1.5
Red No. 202 0.1
Purified water 2.0
--------------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 37 Lipstick
Component Blending amount (% by weight)
------------------------------------
(Diphenylmethylsiloxyphenyl methicone /
Phenylsilsesquioxane) Crosspolymer 15.0
Neosolute-MCT (Nippon Seika) 10.0
IOTG (Nippon Seika) Total amount of 100 NS-308 (Nippon Seika) 3.0
Neosolute-DE (Nippon Seika) 0.2
Neosolute-MP (Nippon Seika) 0.2
Isohexadecane 8.0
Isotridecyl isononanoate 8.0
Microcrystalline wax 8.0
Polyethylene 4.0
Candelilla Row 2.0
Carnavalo 2.0
Plandool-G (Nippon Seika) 5.0
LUSPLAN DD-DHR (Nippon Seika) 7.5
Plandool-LG2 (Nippon Seika) 6.0
Squalane 5.0
Ascorbyl tetrahexyldecanoate 0.01
Hyaluronic acid Na 0.05
Sorbitan isostearate 0.1
Tremoist-SL (Nippon Seika) 0.05
Plandool-DP (Nippon Seika) 0.01
Plandool-LG1 (Nippon Seika) 0.01
Plandool-LG3 (Nippon Seika) 0.01
Plandool-LG4 (Nippon Seika) 0.01
Plandool-S (Nippon Seika) 0.01
Tocopherol 0.1
BHT 0.01
Methylparaben 0.1
Dimethylpolysiloxane-treated titanium oxide 0.2
Surface-treated powder of Example 11 0.5
Red 202 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca / Al) Appropriate amount Silica Appropriate amount Tin oxide Appropriate amount --------------------- -----------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 38 Lipstick
Component Blending amount (% by weight)
------------------------------------
Plandool-G (Nippon Seika) 15.0
Plandool-LG2 (Nippon Seika) 12.0
LUSPLAN DD-IS (Nippon Seika) 1.0
NS-408 (Nippon Seika) 5.0
Amount of diisostearyl malate totaling 100 Neosolue-MCT (Nippon Seika) 10.0
Squalane 10.0
Isotridecyl isononanoate 8.0
Microcrystalline wax 4.0
Polyethylene 4.0
Sorbitan isostearate 0.1
Surface-treated powder of Example 11 0.5
Surface treated powder of Example 13 0.5
BHT Appropriate amount Methylparaben Appropriate amount Red 202 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca / Al) Appropriate amount Silica Appropriate amount Tin oxide Appropriate amount ----------------------- --------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 39 Pasty Lipstick
Component Blending amount (% by weight)
--------------------------------
LUSPLAN DD-DA5 (Nippon Seika) 40.0
Plandool-H (Nihon Seika) 30.0
Organically modified clay mineral (Benton 38 by National Head) 2.0
Pigment appropriate amount Surface-treated powder of Example 13 0.4
Hydrogenated polyisobutene Total amount of 100 --------------------------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 40 Pasty Lipstick
Component Blending amount (% by weight)
--------------------------------
LUSPLAN PI-DA (Nippon Seika) 40.0
Plandool-S (Nihon Seika) 30.0
Dimethylsilylated silica 5.0
Dextrin palmitate 1.0
Surface-treated powder of Example 13 0.3
Pigment Appropriate amount Diisostearyl malate Total amount of 100 --------------------------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 41 Pasty Lipstick
Component Blending amount (% by weight)
--------------------------------
Plandool-H (Nihon Seika) 40.0
12-hydroxystearic acid 8.0
Mineral oil Total amount of 100 Isododecane 8.0
IOTG (Nippon Seika) 8.0
Hydrogenated polyisobutene 15.0
Dimethylsilylated silica 0.3
Surface treated powder of Example 13 0.1
Red No. 202 appropriate amount Yellow No. 4 appropriate amount --------------------------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 42 Lip Gloss
Component Blending amount (% by weight)
--------------------------------
Hydrogenated polyisobutene 55.0
LUSPLAN DD-DA7 (Nippon Seika) 7.0
LUSPLAN SR-DP4 (Nippon Seika) 7.0
Cyclopentasiloxane 10.0
Phenyltrimethicone 5.0
Polyethylene wax 0.2
12-hydroxystearic acid 1.5
Neosolue-IOP (Nippon Seika) Total amount of 100 Tocopherol Appropriate amount Dimethylsilylated silica 5.0
Mica titanium 12.0
Surface treated powder of Example 13 1.0
--------------------------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 43 Lip Gloss
Component Blending amount (% by weight)
--------------------------------
Plandool-H (Nippon Seika) 5.0
Plandool-G (Nippon Seika) 5.0
Plandool-MAS (Nippon Seika) 5.0
LUSPLAN PI-DA (Nippon Seika) 10.0
Hydrogenated polyisobutene Total amount of 100 IOTG (Nippon Seika) 5.0
Dextrin palmitate 4.0
Dimethylsilylated silica 2.0
Surface-treated powder of Example 13 0.2
Dimethicone 5.0
Mica 9.0
Sulfuric acid Ba 25.0
Red 104 (1) 0.5
Yellow 203 0.8
--------------------------------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 44 Lip Gloss
Component Blending amount (% by weight)
--------------------------------
Plandool-G (Nippon Seika) 20.0
Plandool-SUN (Japan Seika) 1.0
Plandool-MAS (Nippon Seika) 1.0
Plandool-ISS (Nippon Seika) 1.0
YOFCO MAC (Nippon Seika) 1.0
Plandool-LG1 (Nippon Seika) 1.0
Plandool-LG2 (Nippon Seika) 1.0
Plandool-LG3 (Nippon Seika) 1.0
Plandool-LG4 (Nippon Seika) 1.0
LUSPLAN PI-DA (Nippon Seika) 18.0
Hydrogenated polyisobutene Total amount of 100 dextrin palmitate 3.0
Quaternium-18 hectorite 0.5
Quotanium-18 bentonite 1.0
Tocopherol 0.5
Surface treated powder of example 13 1.1
Iron oxide, mica 0.5
(Timiron MP-24 manufactured by Merck)
Iron oxide 0.1
Red 104 (1) 0.1
--------------------------------
(Preparation method)
All components were heated and melted and mixed uniformly. After uniformly dissolving, it was cooled to about 40 ° C.

Example 45 Lip Gloss
Component Blending amount (% by weight)
--------------------------------
Hydrogenated polyisobutene Total amount of 100 LUSPLAN DD-DA7 (Nippon Seika) 25.0
Triethylhexyl trimellitate 10.6
IOTG (Japan Seika) 10.0
Plandool-G (Nippon Seika) 3.2
Dimethylsilylated silica 3.2
Dextrin palmitate 1.0
Neosolute-IOP (Nippon Seika) 1.6
Surface-treated powder of Example 11 0.5
Surface treated powder of Example 13 0.5
BHT Appropriate amount Methylparaben Appropriate amount Red 202 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca / Al) Appropriate amount Silica Appropriate amount Tin oxide Appropriate amount ----------------------- -----------
(Preparation method)
All components were heated and melted and mixed uniformly.

Example 46 Water-containing gloss
Component Blending amount (% by weight)
--------------------------------
Part A Octildodecanol 27.0
Ethylcellulose 2.5
Diisostearyl malate 10.0
IOTG (Japan Seika) 3.0
LUSPLAN PI-DA (Nippon Seika) 2.0
LUSPLAN DD-DHR (Nippon Seika) 2.0
Plandool-MAS (Nippon Seika) 0.1
Plandool-H (Nippon Seika) 0.1
Dimethylsilylated silica 0.2
Inulin stearate 0.3
PEG-60 hydrogenated castor oil 1.0
Red No. 202 appropriate amount Yellow No. 4 appropriate amount Surface-treated powder of Example 13 0.5
Sorbitan stearate and coconut fatty acid sucrose mixture (ALACEL 2121 by Croda) 3.0
Part B Glycerin 7.0
Maltose 2.0
Phenoxyethanol 0.2
Water Amount that totals 100 ---------------------------------
(Preparation method)
A part and B part were heated and dissolved, respectively, and B part was mixed with A part.

Example 47 Mascara
Component Blending amount (% by weight)
--------------------------------
Part A Surface-treated powder of Example 13 0.5
Iron oxide (black) 10.0
Amount of purified water A total of 100 parts B Polyacrylate emulsion 30.0
Part C Light isoparaffin 30.0
Solid paraffin 8.0
Plandool-G (Nippon Seika) 0.5
Sorbitan sesquioleate 4.0
Preservative Appropriate amount Perfume Appropriate amount ---------------------------------
(Preparation method)
After part A was dispersed with a homomixer, part B was added and mixed by heating (aqueous phase). Part C was heated and mixed, the aqueous phase was added, and the mixture was uniformly emulsified and dispersed with a homomixer.

Example 48 Eyeshadow
Component Blending amount (% by weight)
--------------------------------
Part A Talc 10.0
Kaolin 2.0
Facial department 5.0
Surface treated powder of Example 13 1.0
Part B Plandool-H (Nippon Seika) 3.0
Stearic acid 3.0
Neosolute-IPM (Nippon Seika) 5.0
Hydrogenated polyisobutene 5.0
Propylene glycol monolaurate 3.0
Tocopherol proper amount fragrance department proper amount part C BG 5.0
Glycerin 1.0
Preservative Appropriate amount Triethanolamine 1.2
Metal sequestering agent Appropriate amount Purified water Amount to be 100 in total -------------------------------
(Preparation method)
Part A was mixed with a blender and then processed with a pulverizer (powder part). Part B and part C were mixed and dissolved by heating. Part A was added to part C and mixed with stirring. Part B was added to this with stirring, dispersed with a homomixer, and stirred and cooled to room temperature.

Example 49 Eyeshadow
Component Blending amount (% by weight)
--------------------------------
Hydrogenated polyisobutene 5.0
Plandool-H (Nippon Seika) 0.6
Mica Total amount of 100 Talc 24.0
Surface-treated powder of Example 13 20.0
Silicone-treated iron oxide 1.9
Cyclomethicone 3.5
Trimethylsiloxysilicate 1.5
Octyl methoxycinnamate 1.0
Dimethicone (10cs) 0.5
Tocopherol 0.1
BHT 0.1
Phenoxyethanol 0.4
Dye Appropriate amount Perfume Appropriate amount --------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 50 Foundation
Component Blending amount (% by weight)
--------------------------------
Mineral oil 6.0
Cyclomethicone 3.5
Dimethicone (5cs) 2.0
Trimethylsiloxysilicate 1.5
Octyl methoxycinnamate 1.0
Octocrylene 1.0
t-Butylmethoxybenzoylmethane 0.5
Phenoxyethanol 0.4
Tocopherol 0.1
Mica 39.6
Talc 24.0
Surface-treated powder of Example 13 20.0
Iron oxide 1.9
--------------------------------
(Preparation method)
Each component was stirred at high speed and mixed uniformly.

Example 51 Foundation
Component Blending amount (% by weight)
--------------------------------
Plandool-S (Nippon Seika) 1.0
Plandool-G (Nippon Seika) 0.1
Plandool-SUN (Nippon Seika) 0.1
Plandool-MAS (Nippon Seika) 0.1
Plandool-ISS (Nippon Seika) 0.1
Neosolute-AquaS (Nippon Seika) 0.3
Hydrogenated polyisobutene 5.0
Cyclomethicone 3.5
Trimethylsiloxysilicate 1.5
Talc 24.0
Iron oxide 1.9
Surface-treated powder of Example 13 20.0
Tocopherol 0.1
Ethylhexyl methoxycinnamate 1.0
Phenoxyethanol 0.4
Mica Total amount of 100 ----------------------------------
(Preparation method)
All ingredients were stirred at high speed and mixed uniformly.

Example 52 Solid powder foundation
Component Blending amount (% by weight)
--------------------------------
Part A Hydrogenated polyisobutene 10.0
Plandool-MAS (Nippon Seika) 2.0
Plandool-G (Nippon Seika) 1.0
Perfluoropolyether 5.0
Part B Silicone-treated sericite 60.0
Surface treated powder of Example 9 10.0
Powdered synthetic hydrocarbon wax 1.0
Yellow iron oxide 1.0
Bengala 0.5
Methylparaben 0.5
Black iron oxide 0.05
Talc Total amount of 100 --------------------------------
(Preparation method)
Part A was warmed and mixed. Part B was placed in a separate container and mixed and dispersed. Part A was added to part B and mixed uniformly.

Example 53 Solid powder foundation
Component Blending amount (% by weight)
--------------------------------
Part A Plandool-H (Nippon Seika) 2.0
YOFCO MAC (Nippon Seika) 0.1
Plandool-LG1 (Nippon Seika) 0.1
Plandool-LG2 (Nippon Seika) 0.1
Plandool-LG3 (Nippon Seika) 0.1
Plandool-LG4 (Nippon Seika) 0.1
LUSPLAN PI-DA (Nippon Seika) 3.0
NS-CIO (Nippon Seika) 3.0
Dimethicone 2.0
Mineral oil 1.6
Part B lecithin-treated sericite 20.0
Boron nitride 10.0
Mica 3.0
Silica 2.0
Dimethicone 3.0
Nylon-12 3.0
Talc 10.0
Surface-treated powder of Example 5 10.0
Iron oxide Amount that totals 100 --------------------------------
(Preparation method)
Part A was warmed and mixed. Part B was placed in a separate container and mixed and dispersed. Part A was added to part B and mixed uniformly.

Example 54 Liquid Foundation
Component Blending amount (% by weight)
--------------------------------
Part A Plandool-G (Nippon Seika) 5.0
Glyceryl stearate (SE) 1.0
Stearic acid PG (SE) 1.0
Hydrogenated polyisobutene 12.0
Tocopherol 0.1
Propylparaben 1.0
Part B Titanium oxide / iron oxide mixture (FDP-W-007: manufactured by Toyo Pigment) 15.0
Surface treated powder of example 11 3.0
Mica 7.0
BG 5.0
Methylparaben 0.2
Purified water Total amount of 100 parts C Neosol-AquaS (Nippon Seika) 0.5
Cellulose gum (2% aqueous dispersion) 5.0
Xanthan gum (2% aqueous dispersion) 5.0
--------------------------------
(Preparation method)
Part A, part B and part C were heated and mixed. Part B was added to part A and emulsified, then cooled to about 50 ° C., part C was added and stirred until uniform.

Example 55 Liquid Foundation
Component Blending amount (% by weight)
--------------------------------
Part A Purified water Amount to be 100 in total Aqueous dispersion fine particles Titanium oxide 1.0
Carboxyvinyl polymer 0.1
Potassium hydroxide appropriate amount DPG 5.0
Preservative appropriate amount Part B Polyoxyethylene-modified dimethylpolysiloxane 1.0
Trimethylsiloxysilicate 3.0
Phenylmethicone 1.0
Cyclomethicone 9.0
Hydrogenated polyisobutene 5.0
Part C Zinc Hana 10.0
Sericite 0.36
Surface-treated powder of Example 13 8.32
Iron oxide yellow 0.8
Iron oxide red 0.36
Iron oxide black 0.16
----------------------------------
(Preparation method)
After part A was heated and stirred at 70 ° C., part C was added and dispersed. This was added to part B which had been heated to 70 ° C. in advance and emulsified and dispersed. Then it was cooled to room temperature.

Example 56 Liquid Foundation
Component Blending amount (% by weight)
--------------------------------
Part A Hydrogenated polyisobutene 7.0
Octyl rearzone 1.5
Ethylhexyl methoxycinnamate 1.0
Quaternium-18 hectorite 0.5
Part B Cyclomethicone 25.0
Polyether-modified silicone mixture 5.0
(BY22-008M manufactured by Toray Dow Corning Silicone)
Polyglyceryl-2 isostearate 1.0
Titanium oxide / iron oxide mixture 12.5
(FDP-C111S: Eastern Pigment)
Mica 6.0
Surface treated powder of Example 11 1.0
Part C Glycerin 5.0
Methylparaben 0.2
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A was heated and dissolved, and part B was heated and uniformly dispersed in part A (part D). Part C was heated and dissolved, part C was added to part D with stirring, emulsified, and then cooled to about 40 ° C.

Example 57 Foundation
Component Blending amount (% by weight)
-----------------------------------
Part A mineral oil 5.0
Cyclopentasiloxane 4.0
Ethyl hexyl methoxycinnamate 3.0
Plandool-H (Nippon Seika) 1.0
Plandool-G (Nippon Seika) 1.0
Plandool-MAS (Nippon Seika) 1.0
Vaseline 1.0
Phenyltrimethicone 2.0
Sorbitan isostearate 1.5
Tribehenine 0.5
(Butyl acrylate / dimethacrylate glycol) cross polymer,
Silica, (Methyl methacrylate / Dimethacrylate glycol)
Cross-polymer mixture 2.0
Boron nitride 1.0
PEG / PPG-19 / 19 dimethicone,
Cyclopentasiloxane mixture 4.0
Distemalimonium Hectorite (20%) 2.5
Polypropylsilsesquioxane,
Cyclopentasiloxane mixture 1.0
Mica 15.0
Talc 4.0
Silica-treated zinc oxide 5.0
Surface treated powder of Example 13 10.0
Iron oxide 1.5
Part B Water Total amount of 100 DPG 4.0
Maltitol (75% solution) 1.0
Na chloride 1.0
BG 1.0
Tremoist-SL (Nippon Seika) 1.0
Hyaluronic acid (1% solution) 0.1
Phenoxyethanol 0.3
-----------------------------------
(Preparation method)
Part A was heated to about 70 ° C., stirred well and dispersed uniformly. Part B was heated to about 70 ° C. and homogenized, then part B was added to part A, stirred and emulsified at about 70 ° C., and cooled to about 40 ° C.

Example 58 foundation
Component Blending amount (% by weight)
-----------------------------------
Part A Hydrogenated polyisobutene 20.0
Isododecane 10.0
Neosolute-MCT (Nippon Seika) 4.0
Ethyl hexyl methoxycinnamate 3.0
Plandool-SUN (Japan Seika) 1.0
Plandool-LG2 (Nippon Seika) 1.0
Plandool-LG4 (Nippon Seika) 1.0
Vaseline 1.0
Isotridecyl isononanoate 2.0
Ascorbyl tetrahexyldecanoate 0.1
Dextrin palmitate 0.3
Sorbitan isostearate 1.5
Tribehenine 0.5
(Butyl acrylate / dimethacrylate glycol) cross polymer,
Silica, (Methyl methacrylate / Dimethacrylate glycol)
Cross-polymer mixture 2.0
Boron nitride 1.0
Polysorbate 20 2.0
PEG-60 hydrogenated castor oil 1.0
Distemalimonium Hectorite (20%) 2.5
Polypropylsilsesquioxane Cyclopentasiloxane mixture 1.0
Mica 15.0
Talc 4.0
Methyl hydrogen polysiloxane treated zinc oxide 5.0
Surface-treated powder of Example 5 10.0
Iron oxide 1.5
Part B Water Total amount of 100 Neosolu-Aquolio (Japan Seika) 0.5
DPG 4.0
Maltitol (75% solution) 1.0
Na chloride 1.0
BG 1.0
Tremoist-SL (Nippon Seika) 1.0
Ethanol 0.5
Phenoxyethanol 0.3
-----------------------------------
(Preparation method)
Part A was heated to about 70 ° C., stirred well and dispersed uniformly. Part B was heated to about 70 ° C. and homogenized, then part B was added to part A, stirred and emulsified at about 70 ° C., and cooled to about 40 ° C.

Example 59 Amphibious Foundation
Component Blending amount (% by weight)
----------------------------------
Part A Metal soap treatment talc 19.0
Metal soap treated mica Total amount of 100 Metal soap treated Bengala 1.0
Metal soap treated yellow iron oxide 3.0
Metal soap treated black iron oxide 0.2
Surface treated powder of Example 13 5.0
Zinc flower 15.0
Zinc stearate 0.1
Nylon powder 2.0
Boron nitride 5.0
Tremoist-TP (Nippon Seika) 0.01
Part B Hydrogenated polyisobutene 4.0
YOFCO MAC (Nippon Seika) 0.2
Plandool-LG2 (Nippon Seika) 4.0
Dextrin palmitate 0.1
Tetradecene 0.5
Diisostearyl malate 5.0
Octyl methoxycinnamate 1.0
Preservative Appropriate amount Antioxidant Appropriate amount Perfume Appropriate amount --------------------------------
(Preparation method)
After mixing part A with a Henschel mixer, the part B heated and dissolved was added, mixed and pulverized, and molded into an inner dish.

Example 60 Oil Foundation
Component Blending amount (% by weight)
----------------------------------
Part A Cyclopentasiloxane Total amount of 100 Phenyltrimethicone 15.0
Hydrogenated polyisobutene 10.0
Plandool-G (Nippon Seika) 5.0
LUSPLAN DD-DHR (Nippon Seika) 5.0
Microcrystalline wax 5.0
NS-CIO (Nippon Seika) 2.0
Plandool-LG2 (Nippon Seika) 2.0
Candelilla wax 0.5
Carnauba 0.5
Methylparaben appropriate amount B part talc 2.7
Surface-treated powder of Example 13 20.0
Perfluoroalkylsilane-treated zinc oxide 0.5
Iron oxide 4.15
Nylon-12 3.0
----------------------------------
(Preparation method)
Part A was heated to about 90 ° C. and dissolved uniformly. Part B was added to part A and dispersed using a roller mill. The mixture was heated to 90 ° C, defoamed, and then cooled to 40 ° C.

Example 61 Base Cream
Component Blending amount (% by weight)
--------------------------------
Part A LUSPLAN DD-DA7 (Nippon Seika) 5.0
LUSPLAN SR-DM4 (Nippon Seika) 2.0
Hydrogenated polyisobutene 2.5
Argania spinosa kernel oil 0.1
Cyclomethicone 14.0
Trimethylsiloxysilicate 3.0
Glyceryl stearate (SE) 2.0
Stearic acid PG (SE) 2.0
Plandool-MAS (Nippon Seika) 0.5
Stearic acid 0.5
Palmitic acid 0.5
Ethyl hexyl methoxycinnamate 0.5
Tocopherol 0.2
Part B BG 10.0
Neosolu-Aculio (Nihon Seika) 0.5
Ethanol 1.0
Mica 8.0
Talc 7.0
Phenoxyethanol 0.8
Dimethylpolysiloxane treated zinc oxide 0.2
Surface-treated powder of Example 5 0.2
Purified water Total amount of 100 parts C Dextrin (1%) 1.0
Tremoist-SL (Nippon Seika) 1.0
Xanthan gum (10%) 1.0
Cellulose gum (10%) 1.0
--------------------------------
(Preparation method)
Part A and part B were each heated and dissolved in separate containers. After adding part B to part A and emulsifying, part C was added and mixed uniformly. It cooled to 40 degreeC after stirring.

In the above formulation, details of the components described by the product name are as follows.

○ IOTG: Triethylhexanoin ○ IPSE: Diisopropyl sebacate ○ LUSPLAN DD-IS: Diisostearate dimer dilinoleyl ○ LUSPLAN PI-DA: Dimer dilinoleate di (isostearyl / phytosteryl)
O LUSPLAN DD-DHR: Dimer dilinoleic hydrogenated rosin condensate O LUSPLAN DD-DA5: Dimer dilinoleic acid dimer dilinole O LUSPLAN DD-DA7: Dimer dilinoleic acid dimer dilinole O LUSPLAN SR-DM4: Dai Dimerlinoleyl merlinoleate, tri (caprylic acid / capric acid) glyceryl o LUSPLAN SR-DP4: dimerlinoleic acid dimerinolinoleyl, tetraisostearate pentaerythrityl Neosolue-AquaS: (eicosanedioic acid / tetradecane diacid) Acid) polyglyceryl-10, glycerol o Neosolue-Aculio: cyclohexanedicarboxylic acid bisethoxydiglycol o Neosolue-EHS: diethyl sebacate Sil * Neosolue-IOP: ethylhexyl palmitate * Neosolue-IPM: isopropyl myristate * Neosolue-MP: dineopentanoic acid methylpentanediol * Neosolue-DE: dineopentanoic acid diethylpentanediol * NS-CIO: cetyl ethylhexanoate * NS-408 : Pentaerythrityl tetraethylhexanoate O Plandool-H: Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
* Plandool-S: Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
* Plandool-G: Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl)
O Plandool-DP: Bisdiglyceryl polyacyl adipate-2
O Plandool-ISS: Phytosteryl isostearate O Plandool-SUN: Sunflower seed oil fatty acid phytosteryl O Plandool-MAS: Macadamia nut oil fatty acid phytosteryl O Plandool-LG1: Dilauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
○ Plandool-LG2: dilauroyl glutamate (phytosteryl / octyldodecyl)
○ Plandool-LG3: dilauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
O Plandool-LG4: dilauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
* Phytocompo-PP: hydrogenated lecithin, phytosterols * Tremoist-TP: white jellyfish polysaccharide * Tremoist-SL: white jellyfish polysaccharide aqueous solution (1%)
O YOFCO MAC: Macadamia nut oil fatty acid cholesteryl o YOFCO CLC-678: dihydrocholesteryl oleate, cholesteryl nonate, dihydrocholesteryl butyrate, cholesteryl butyrate, phytosteryl oleate o VC ethyl: 3-O-ethylascorbic acid

Claims (7)

A surface-treated powder coated with an oligomer ester synthesized from the following components (A) and (B).
(A) One or two or more types selected from divalent carboxylic acids containing a straight chain, branched chain, or cyclic structure having 6 to 22 carbon atoms (B) The average degree of polymerization calculated from the hydroxyl value is 2 to 15 Polyglycerin   Component (A) is adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, pentadecanedioic acid, The surface-treated powder according to claim 1, wherein the surface-treated powder is selected from hexadecanedioic acid, octadecanedioic acid, 8-ethyloctadecanedioic acid, eicosanedioic acid, dimethyleicosanedioic acid, and cyclohexanedicarboxylic acid.   The surface-treated powder according to claim 1 or 2, wherein the component (B) is a polyglycerin having an average degree of polymerization calculated from a hydroxyl value of 4 to 12.   The surface-treated powder according to claim 1, wherein the powder is an inorganic powder.   Cosmetics containing the surface-treated powder according to any one of claims 1 to 4.   Sunscreen cosmetics containing the surface-treated powder according to any one of claims 1 to 4. A makeup cosmetic containing the surface-treated powder according to claim 1.