JP6976146B2 - Wax-like composition - Google Patents

Description

The present invention is characterized by containing a polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of the component (A) dimer acid and dimer diol as a constituent unit, and the component (B) wax. The present invention relates to a composition and a cosmetic containing the waxy composition.

Wax is used in a wide range of applications in cosmetics. For example, in make-up cosmetics such as lipsticks and foundations, emulsions, creams, and washings are used for the purposes of solidifying the formulation, adjusting hardness and viscosity, forming a film, and imparting luster. For skin cosmetics such as agents, for the purpose of improving usability and suppressing water evaporation by forming a film, for hair cosmetics such as shampoos, treatments, and hair styling products, the hardness and viscosity of the formulation, hair protection, and hair styling properties It is used for the purpose of granting.

Generally, hair styling products are required to improve resettability (arrangement) in addition to initial settability (keeping power). Further, in make-up cosmetics, it is required to improve the adhesion of powders and the like to the skin to maintain a beautiful finish. Therefore, in hair styling products and make-up cosmetics, it is desired that the wax component also has such a function. Of the wax components commonly used in cosmetics, candelilla wax contains a large amount of resin component compared to other natural waxes, and since this resin component has strong adhesiveness, the above-mentioned settability, resettability, and adhesion are achieved. It is known as a wax that can impart functions such as sex, and is preferably used in hair styling products and make-up cosmetics (Patent Documents 1 to 4). However, candelilla grass, which is a raw material for candelilla wax, has problems such as supply instability and soaring prices due to weather conditions and growing demand, and alternatives to candelilla wax are desired.

Patent Document 5 discloses a cosmetic containing polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of dimer acid and dimer diol as a constituent unit, and as an effect thereof, in hair cosmetics. In make-up cosmetics, oil can be thickened due to the effects of non-build-up, the same feel as silicone compounds, the effect of improving gloss, the improvement of hair combability, and the suppression of split ends due to brushing. It is described that the amount of oil gelling agent can be reduced or not used, and the effects of imparting flexibility to the skin are described. However, the functions such as settability, resettability, and adhesion are not described. Further, since the polyester has a very high viscosity and is difficult to handle, it is described that the polyester is diluted with liquid oil for handling. However, it cannot be said that it is easy to handle because it has a high viscosity even if it is diluted to some extent, and it has a drawback that it is difficult to use it in applications where liquid oil is not desired to be blended.

JP-A-2009-209103 JP-A-2010-270024 Japanese Patent Application Laid-Open No. 2000-327524 JP-A-11-060438 JP 2014-009259

It is an object of the present invention to provide a wax-like composition which is a wax-like composition which imparts settability and resettability in a hair styling product and imparts adhesion in a make-up cosmetic, and which can be a substitute for candelilla wax.

As a result of diligent studies to solve the above problems, the present inventors have contained the following components (A) and (B), the content of (A) is 5 to 50% by weight, and the content of (B). The present invention has been completed by finding that a wax-like composition characterized by having a content of 50 to 95% by weight solves the above-mentioned problems.

(A) Containing one or both of dimer acid and dimer diol as a constituent unit.
Polyester with a weight average molecular weight of 30,000 to 1,000,000 (B) One or more waxes selected from the group consisting of the following (B1) to (B3) (B1) Ester wax (B2) Hydrocarbon wax (B3) ) Solid higher alcohols or higher fatty acids

In addition to the function as a general wax, the wax-like composition of the present invention has the effect of imparting settability and resettability in hair styling products and imparting adhesion in make-up cosmetics. Therefore, it can be preferably used as a substitute for candelilla wax. Moreover, since the wax-like composition of the present invention can be processed into various shapes such as granules, granules, flakes, and plates, it is easy to handle.

The waxy composition of the present invention contains polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of the component (A) dimer acid and dimer diol as a constituent unit, and the component (B) wax. It is a feature.

In the present invention, the wax-like substance is a solid state having no fluidity at room temperature and almost no flexibility, and has a hardness sufficient to be processed into various shapes such as granules, granules, flakes, and plates. Say.

The polyester containing one or both of the dimer acid and the dimer diol of the component (A) used in the present invention as a constituent unit is produced from the dimer acid and the dimer diol described below as raw materials.

Dimer acid is a known dibasic acid obtained by the intermolecular polymerization reaction of unsaturated fatty acids, the industrial production process thereof is almost standardized in the industry, for example, dimer acid and / and its lower alcohol ester are carbon. It is obtained by quantifying an unsaturated fatty acid having a number of 11 to 22 or a lower alcohol ester thereof with a clay catalyst or the like. The industrially obtained dimer acid is mainly composed of a dibasic acid having about 36 carbon atoms, but contains an arbitrary amount of trimer acid and monomeric acid depending on the degree of purification. In general, those having a dimer acid content of more than 70% by weight and those having a dimer acid content increased to 90% by weight or more by molecular distillation are on the market. Further, a dimer acid in which a double bond remains after the dimerization reaction but further hydrogenation is performed to improve the oxidative stability, that is, a hydrogenated dimer acid is also sold. Any of the dimer acids currently on the market can be used for producing the polyester of the present invention, but hydrogenated dimer acid is more preferable from the viewpoint of oxidation stability. Further, although those derived from animal fats and oils and those derived from vegetable fats and oils are distributed as these dimer acids, those derived from vegetable fats and oils are more preferable. As such dimer acids, for example, Croda's PRIPOL 1006, 1009, 1015, 1025 and the like can be obtained as commercial products.

The dimer diol is mainly composed of a diol having about 36 carbon atoms in which the carboxylic acid portion of the dimer acid is used as an alcohol by hydrogenating the dimer acid or / or a lower alcohol ester thereof in the presence of a catalyst. Industrially obtained dimer diols may contain other components such as trimertriol, monomeric alcohols and ether compounds, depending on the degree of purification of dimer acid and / or its lower alcohol ester used as a raw material, and generally. Those having a dimerdiol content of more than about 70% by weight and those having a dimerdiol content of more than 90% by weight after further purification are on the market. Any can be used. As for dimer diols, those derived from animal fats and oils and those derived from vegetable fats and oils are distributed, but those derived from vegetable fats and oils are preferable. As such a dimer diol, Croda's PRIPOL 2033 and the like can be obtained as a commercially available product.

The polyester containing one or both of dimer acid and dimer diol used in the present invention as a constituent unit is an ester of dimer acid and a divalent alcohol other than dimer diol, and a dimer diol and a divalent carboxylic acid other than dimer acid. It is a compound including one or more selected from the ester of and the ester of dimer acid and dimer diol.

As the divalent alcohol other than the dimerdiol used in the present invention, a saturated linear, branched, ring-containing or cyclic divalent alcohol having 2 to 24 carbon atoms is preferable. Specifically, ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 1,2-butanediol, 1,5-pentanediol, 1,2- Pentandiol, neopentyl glycol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, 1,2-hexanediol, 2,5-hexanediol, hexylene glycol, 3-methyl-1 , 5-Pentanediol, 1,7-Heptanediol, 2,2-diethyl-1,3-propanediol, 2,2,4-trimethyl-1,5-pentanediol, 1,8-octanediol, 2- Butyl-2-ethyl-1,3-propanediol, 1,9-nonanediol, 1,8-nonanediol, 2,4-diethyl-1,5-pentanediol, 1,10-decanediol, 1,11 -Undecanediol, 1,10-Undecanediol, 1,12-Dodecanediol, 1,2-Dodecanediol, 1,13-Tridecandiol, 1,14-Tetradecanediol, 1,2-Tetradecanediol, 1,16 -Hexadecanediol, 1,2-hexadecanediol, 1,18-octadecanediol, 1,2-octadecanediol, 1,12-octadecanediol, 9-octadecene-1,12-diol, 1,20-icosandiol, 1,4-Cyclohexanediol, 1,4-Cyclohexanedimethanol, 1,3-Cyclohexanedimethanol, 1,2-Cyclohexanedimethanol, Isosorbide, a dehydrated product of sorbitol, Diethylene glycol, Triethylene glycol, Tetraethylene glycol, Polyethylene Glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol, polypropylene glycol and the like can be mentioned. Of these, from the viewpoint of availability and the feel of the obtained ester, ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, and 1,5-pentanediol , Neopentyl glycol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, hexylene glycol, 3-methyl-1,5-pentanediol, 2,2-diethyl-1,3- Propylenediol, 2,2,4-trimethyl-1,5-pentanediol, 1,8-octanediol, 2-butyl-2-ethyl-1,3-propanediol, 2,4-diethyl-1,5- Pentanediol, 1,10-decanediol, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, isosorbide and the like are preferable.

As the divalent carboxylic acid other than the dimer acid used in the present invention, a saturated linear, branched or ring-containing divalent carboxylic acid having 4 to 24 carbon atoms is preferable. Specifically, malonic acid, succinic acid, glutaric acid, adipic acid, 3-methylpentanedioic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid. , Hexadecanedioic acid, octadecanedioic acid, icosandioic acid, dimethylicosandioic acid, docosanedioic acid, cyclohexanedicarboxylic acid, malic acid, tartrate and the like. Of these, from the viewpoint of availability and the feel of the obtained ester, succinic acid, glutaric acid, adipic acid, 3-methylpentanedioic acid, azelaic acid, sebacic acid, dodecanedioic acid, tetradecanedioic acid, hexadecanedioic acid , Octadecandioic acid, icosandioic acid, dimethylicosandioic acid, cyclohexanedicarboxylic acid and the like are preferable.

It is most preferable to use a polyester containing both dimer acid and dimer diol as a constituent unit from the viewpoint of maximizing the effect of the present invention. Even in such a case, a divalent carboxylic acid other than dimer acid and a divalent alcohol other than dimer diol may be contained as a constituent unit.

The polyester of the component (A) in the present invention is a compound having an alcohol or a carboxylic acid at the end. The polyester of the present invention may be further esterified with a monovalent carboxylic acid or alcohol at the end. Further, when the terminal is a carboxylic acid, it may be in the form of a neutralized salt. Examples of the salt include alkali metal salts such as sodium and potassium, alkaline earth metal salts such as calcium and magnesium, metal salts such as aluminum, iron, zinc, copper and cobalt, basic amino acid salts such as lysine and arginine, and triethylamine. Examples thereof include organic amine salts such as stearylamine.

The polyester of the component (A) in the present invention has a weight average molecular weight of 30,000 to 1,000,000, more preferably 70,000 to 500,000. The weight average molecular weight of the polyester of the present invention can be adjusted by changing the charging ratio of the divalent carboxylic acid and the divalent alcohol to be reacted. As for the reaction ratio of the polyester of the present invention, when the terminal is an alcohol, 0.85 to 1.0 mol, more preferably 0.95 to 1.0 mol of the divalent carboxylic acid is added to 1 mol of the dihydric alcohol. It is 1.0 mol. When the terminal is a carboxylic acid, the amount of the dihydric alcohol is 0.85 to 1.0 mol, more preferably 0.95 to 1.0 mol, with respect to 1 mol of the divalent carboxylic acid.

Since the polyester of the component (A) in the present invention has a very high viscosity and strong adhesiveness, it has an effect of imparting functions such as settability, resettability, and adhesiveness. On the other hand, since it is a glassy substance having almost no fluidity at room temperature, it is difficult to handle subdivision and weighing at room temperature. Since the polyester of the component (A) has excellent compatibility with various oils, it can be uniformly diluted with liquid oil, and by doing so, it can be handled in a fluid state even at room temperature. However, the obtained composition is a highly viscous liquid oil, and it is not always easy to handle. In addition, it is difficult to use in applications where liquid oil is not desired to be blended.

The component (B) in the present invention is one or more waxes selected from the group consisting of the following (B1) to (B3). These may be used alone or in combination of two or more.
(B1) Ester wax (B2) Hydrocarbon wax (B3) Solid higher alcohol or higher fatty acid

The component (B) in the present invention is not particularly limited as long as the composition becomes waxy when mixed with the component (A), but specifically, the component (B1) is carnauba wax. , Sunflower seed wax, rice bran wax, wood wax, beeswax, lanolin, hard lanolin, montan wax, hydrogenated jojoba oil, behenyl behenate, glyceryl tribehenate and the like. Examples of the component (B2) include ceresin, paraffin wax, microcrystalline wax, Fischer-Tropsch wax, polyethylene wax and the like. Examples of the component (B3) include cetyl alcohol, stearyl alcohol, behenyl alcohol, phytosterol, cholesterol, palmitic acid, stearic acid, bechenic acid, 12-hydroxystearic acid, lanolin fatty acid, hard lanolin fatty acid and the like.

The content of the component (A) in the wax-like composition in the present invention is 5 to 50% by weight, more preferably 10 to 40% by weight. If the content of the component (A) is low, the effects of the present invention such as settability, resettability, and adhesion are not sufficiently exhibited, and if the content of the component (A) is high, the composition does not become waxy. The content of the component (B) in the wax-like composition is 50 to 95% by weight, more preferably 60 to 90% by weight. By mixing the component (B) with the component (A) within such a range, the composition becomes waxy and can be processed into various shapes such as granules, granules, flakes, and plates. Easy to handle.

Since the wax-like composition of the present invention has the same functions as those peculiar to candelilla wax such as settability, resettability, and adhesion, it can be preferably used as a substitute for candelilla wax. Depending on the type of the component (B), it may be different from the candelilla wax in terms of physical properties such as hardness and melting point, but it can be used without any problem for the purpose of substituting the functional aspect. On the other hand, candelilla wax has a composition of 15 to 25% of resin component, 20 to 30% of ester wax, 40 to 50% of hydrocarbon wax, and 15 to 25% of higher alcohol and higher fatty acid. It is known to contain. Therefore, in the wax-like composition of the present invention, the component (A) is used instead of the resin component, the component (B1) is used instead of the ester wax, and the component (B2) is used instead of the hydrocarbon wax. By using the component (B3) instead of the wax, it is possible to make it similar to candelilla wax not only in terms of function but also in terms of physical properties. Therefore, by using such a wax-like composition of the present invention, it is possible to replace the candelilla wax in the formulation as it is with the wax-like composition of the present invention.

As the wax-like composition of the present invention capable of substituting both functions and physical properties, a wax-like composition containing the following components (A) and (B) is preferable.

(A) Containing one or both of dimer acid and dimer diol as a constituent unit.
Polyester with a weight average molecular weight of 30,000 to 1,000,000 (B) Consists of three or more kinds of waxes selected from the group consisting of the following (B1) to (B3), and at least one kind of each of (B1) to (B3). Wax containing each (B1) Ester wax (B2) Hydrocarbon wax (B3) Solid higher alcohol or higher fatty acid

In the above wax-like composition, those exemplified above can be used as (B1) to (B3). The content of the wax-like compositions (B1) to (B3) is not particularly limited, but the content of the component (A) is 5 to 30 in that it is more similar to candelilla wax in terms of physical properties. The content of the component (B1) may be 5 to 40% by weight, the content of the component (B2) may be 30 to 85% by weight, and the content of the component (B3) may be 5 to 30% by weight. Preferably, the content of the component (A) is 10 to 25% by weight, the content of the component (B1) is 10 to 35% by weight, the content of the component (B2) is 35 to 75% by weight, and the content of the component (B3) is The content may be 5 to 25% by weight.

A component other than the components (A) and (B) can be added to the waxy composition of the present invention as long as the waxy state is maintained and the effect of the present invention is not impaired. The components that can be added are not particularly limited as long as they are components normally used in cosmetics, but for example, components that enhance adhesiveness, antioxidants, oils, oil-soluble moisturizing components, and oil-soluble gelling. Examples thereof include agents, branched fatty acids, branched alcohols, nonionic surfactants and the like. Ingredients that enhance adhesiveness include rosin, hydrogenated rosin, rosin, hydrogenated rosinic acid, glyceryl rosinate, glyceryl hydrogenated rosinate, pentaerythrityl rosinate, pentaerythrityl hydrated rosinate, and trihydrate. Rosin or a derivative thereof such as glyceryl rosinate, (diisostearic acid / hydrogenated rosinate) glyceryl, and dimer dilinoleyl rosin rosin condensate can be preferably used. As the antioxidant, those added to a normal oil-based base such as tocopherols, BHT, and BHA can be preferably used. As oils, hydrocarbon oils such as hydrogenated polyisobutene, polybutene, squalane, vaseline; diisostearyl malate, palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, macadamia nuts. Oil, rose hip oil, meadowfoam oil, persic oil, rapeseed oil, sunflower oil, soybean oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated sunflower oil, jojoba oil, hydrogenated jojoba oil, etc. Vegetable oils and fats; silicones such as low-viscosity dimethylpolysiloxane, high-viscosity dimethylpolysiloxane, cyclic dimethylsiloxane, methylphenylpolysiloxane, and diphenylpolysiloxane can be preferably used. Oil-soluble moisturizing ingredients include macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, phytosteyl isostearate, dimerjilinolate di (phytosteryl / isostearyl), and dimergilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl /). Ester compounds having a sterol skeleton such as behenyl), dimer dilinoleylbis (behenyl / isostearyl / phytosteryl), di lauroyl glutamate (phytosteryl / octyldodecyl), di lauroyl glutamate (phytosteryl / octyldodecyl / behenyl). , Purified lanolin, liquid lanolin, lanolin alcohol, lanolin derivatives such as lanolin fatty acid ester, and the like can be preferably used. Oil-soluble gelling agents include ethylhexanoic acid dextrin, palmitic acid dextrin, myristic acid dextrin, isostearate dextrin, palmitic acid inulin, stearate inulin, higher fatty acid metal soap, silylated silica, and dibutylethylhexanoyl glutamid. , Dibutyllauroylglutamide and the like can be preferably used. As the branched fatty acid, ethylcaproic acid, isodecanoic acid, isotridecanoic acid, isopalmitic acid, isostearic acid, lanolin fatty acid and the like can be preferably used. As the branched alcohol, ethylhexanol, isononyl alcohol, isodecyl alcohol, butyl octanol, isotridecyl alcohol, hexyldecanol, isostearyl alcohol, octyldodecanol, lanolin alcohol and the like can be preferably used. As the nonionic surfactant, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether and the like can be preferably used.

The wax-like composition of the present invention obtained as described above is easy to handle, and in addition to the function as a general wax, the hair styling product has functions such as settability and resettability, and is a make-up cosmetic. In the above, it is possible to impart a function such as adhesion, and it can be preferably used as a substitute for candelilla wax. Further, depending on the composition of the component (B), it can be a substitute for candelilla wax in terms of physical characteristics. Further, it is possible to exert the excellent effect of the component (A) as described in Japanese Patent Application Laid-Open No. 2014-009259, and it can be preferably blended in cosmetics. The amount of the waxy composition of the present invention to be blended in the cosmetic is not particularly limited, but is usually preferably about 0.01 to 60% by weight, more preferably 0.05 to 40% by weight.

The cosmetics containing the waxy composition of the present invention include, if necessary, water and additive components usually added to cosmetics, such as oily bases, surfactants, alcohols, moisturizers, polymers / additions. Viscous / gelling agents, antioxidants, preservatives, bactericides, chelating agents, pH regulators / acids / alkalis, UV absorbers, whitening agents, solvents, keratin peeling / dissolving agents, antipruritic agents, anti-inflammatory agents, antiperspirants Agents, refreshing agents, antihistamines, astringents, stimulants, hair growth agents / blood circulation promoters, reducing agents / oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, saccharides and their derivatives, organic acids , Enzymes, nucleic acids, hormones, inorganic powders, fragrances, dyes and the like may be contained to the extent that the effects of the present invention are not impaired.

Oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, araquil alcohol, behenyl alcohol, jojoba alcohol, chimil alcohol, seraquil alcohol, bacillus alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol, dimerdiol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Higher grades such as palmitooleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, eikosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long chain branched fatty acids, dimer acid, hydrogenated dimer acid, etc. Fatty acids and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium and sodium salts, and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin , Α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalane, vaseline, solid paraffin and other hydrocarbons; candelilla wax, carnauba wax, rice wax, wood wax, honey wax, montan wax , Ozokerite, Celesin, Paraffin wax, Microcrystallin wax, Petrolatum, Fishertropush wax, Polyethylene wax, Ethylene-propylene copolymer and other waxes; Palm oil, Palm oil, Palm kernel oil, Saflower oil, Olive oil, Himasi oil, Avocado Oil, sesame oil, brown oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat Vegetable oils and fats such as germ oil, flaxseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated hojoba oil; beef fat, milk fat, Animal oils and fats such as horse fat, egg yolk oil, mink oil and turtle oil; animal waxes such as whale wax, lanolin and orange raffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption-purified lanolin, lanolin acetate, liquid acetate lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine , Phospholipid ethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin and other sphingophospholipids, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof, phospholipids such as lysolecithin; hydrogenated soybean phospholipids, partially hydrogenated soybeans Phospholipid derivatives such as phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids; sterols such as cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytosterol, cholic acid; sapogenins; saponins; cholesteryl acetate, Cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl), di-lauroyl-L-glutamate (cholesteryl / octyldodecyl), N- Diacylsarcosine alkyl esters such as di-lauroyl-L-glutamate (phytosteryl / behenyl / octyldodecyl), di-lauroyl-L-glutamate (phytosteryl / octyldodecyl), N-lauroyl sarcosin isopropyl, cholesteryl 12-hydroxystearate, macadamia nuts. Phospholipids such as oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, isostearate phytosteryl, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long-chain branched fatty acid cholesteryl, long-chain α-hydroxy fatty acid cholesteryl; -Fatty acid complexes such as cholesterol complex, phospholipid-phytosterol complex; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl parimitinate, octyldodecyl palmitate, cetyl octanate, hexyldecyl octanate, Isotridecyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodesyl neopentanate, ne Isotridecyl operate, isostearyl neopentate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl lysinoreate, octyldodecyl lanolinic acid, dicaprylyl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl ercatate, cured isostearate. Himasi oil, ethyl oleate, ethyl avocado oil fatty acid, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolin fatty acid, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methyl isostearate Monoalcohol carboxylic acid esters such as heptyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate; cetyl lactate, diiso malate Oxyacid esters such as stearyl, hydrogenated castor oil monoisostearate, γ-ercalactone; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, tri (caprylic acid / capric acid) glyceryl, tri (Caprylic acid / capric acid / myristic acid / stearic acid) Glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl beecosanate, glyceryl trioctanoate, triisostearate tri Methylrol propane, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl , Triethylhexanoic acid ditrimethylol propane, (isostearic acid / sebacic acid) ditrimethylol propane, triethylhexanoic acid pentaerythricyl, (hydroxystearic acid / stearic acid / loginic acid) dipentaerythrityl, diisostearate diglyceryl, tetraisostearate polyglyceryl, nona Polyglyceryl-10 isostearate, deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (Hexyldecanoic acid / sebacic acid) Diglyceryl oligoester, glycol distearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopenateate, 2,4-diethyl-1,5-pentanediol dineopanoate, etc. Polyhydric alcohol fatty acid esters; alkyl ethers such as dicaprylyl ether; diisopropyl dimergilinolate, diisostearyl dimergilinolate, dimersilynolate di (isostearyl / phytosteryl), dimergilinoleic acid (phytosteryl /) Behenyl), Dimerglinolic Acid (Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl), Dimerjilinolic Acid Dimergelinoleil, Diisostearate Dimergelinoleil, Dimerjilinoleil Hydrophobic Rodin Condensate, Dimerjilinolic Acid Derivatives of dimeric acid or dimerdiol such as hardened castor oil, hydroxyalkyl dimer dilinoleil ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA). ), Lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA). Fatty acid alkanolamides such as; dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, ( Aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, amino-modified silicones such as aminopropyldimethicone and amodimethicone, cationic-modified silicones, polyether-modified silicones such as dimethiconecopolyol, polyglycerin Modified silicone, sugar-modified silicone, carboxylic acid-modified silicone, phosphate-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone, fatty acid-modified silicone, alkylether-modified silicone, a. Minoic acid-modified silicone, peptide-modified silicone, fluorine-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone, alkyl-modified and polyether-modified silicone, amidoalkyl-modified silicone, aminoglycol-modified silicone, aminophenyl-modified Silicones such as silicones and polysiloxane / oxyalkylene copolymers; fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether are preferable.

Examples of the moisturizing agent / feeling improving agent include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, and the like. Polypolymers such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and its polymers; diethylene glycol monoethyl ether Glycol alkyl ethers such as (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosandioic acid / tetradecanedioic acid) polyglyceryl-10, polyglyceryl-10 tetradecanedioate, cyclohexanedicarboxylic acid Water-soluble esters such as bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, and martitol; Trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylated and hydroxyalkylated), β-glucan, chitin, chitosan, Sugars and derivatives such as heparin and derivatives, pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosylethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate , Caronine sulfate, keratosulfate, dermatane sulfate; white jellyfish extract, white jellyfish polysaccharide; fluctanes such as inulin, levan; fucoidan; tuberose polysaccharide, naturally derived polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and salts thereof. Urea; Salts such as 2-pyrrolidone-5-carboxylic acid and sodium thereof; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threoni Amino acids such as peptide, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen degradation. Peptides, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degraded peptide, keratin-degraded peptide, hydrolyzed keratin, conchiolin-degraded peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean Protein peptides and derivatives thereof such as proteolytic peptides, wheat proteolytic peptides, hydrolyzed wheat proteins, casein-degrading peptides, acylated peptides; acylated peptides such as palmitoyl oligopeptides, palmitoyl pentapeptides, palmitoyl tetrapeptides; silylation. Peptides; Lactobacillus culture, yeast extract, eggshell membrane protein, bovine submandibular gland mutin, hypotaurine, sesame lignan glycoside, glutathione, albumin, lactose; choline chloride, phosphorylcholine; placenta extract, aerastin, collagen, aloe extraction Peptides, Hamamelis water, Hechima water, Camomila extract, Kanzo extract, Comfrey extract, Silk extract, Izayoibara extract, Peptide extract, Eucalyptus extract, Merilot extract and other animal / plant extracts, Natural ceramide (types 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudo-ceramides, sphingoglycolipids, ceramides and ceramides such as sugar ceramide-containing extracts are preferable.

Preferred examples of the surfactant include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, and polymer surfactants. The HLB of the surfactant is not particularly limited and can be used from a low HLB of about 1 to a high HLB of about 20, and it is also preferable to combine a low HLB and a high HLB. Examples of preferred surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulphates such as sodium lauryl sulphate, triethanolamine lauryl sulphate and ammonium lauryl sulphate; laureth. Polyoxyethylene alkyl sulfates such as sodium sulphate, triethanolamine laures sulphate; sodium cocoylmethyl taurine, potassium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium myristylmethyl taurine, sodium lauroyl methyl alanine, sodium lauroyl sulcocin, sodium lauroyl sulcocin triethanol. Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroyl glutamate; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine. , Acyl amino acid salts such as lysine Na dilauroyl glutamate; Polyoxyethylene alkyl ether acetates such as sodium laures acetate; Succinic acid ester salts such as sodium lauroyl monoethanolamide succinate; Polyoxyethylene fatty amine sulfate; fatty acid alkanolamide sulfate; hardened coconut oil fatty acid fatty acid glyceride sulfate such as sodium glycerin sulfate; alkylbenzene polyoxyethylene sulfate; olefin sulfonate such as α-olefin sulfonate sodium; Alkyl sulfosuccinates such as lauryl disodium acid, sodium dioctyl sulfosuccinate; alkyl ether sulfosuccinates such as laures disodium sulfosuccinate, monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; tetradecyl Alkyl benzene sulfonates such as sodium benzene sulfonate, triethanolamine tetradecyl benzene sulfonic acid; alkyl naphthalene sulfonate; alkane sulfonate; α-sulfo fatty acid methyl ester salt; acyl isethionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetate; Alkyl ether phosphate such as sodium laures phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooleth phosphate; Alkyl phosphate such as potassium lauryl phosphate; Sodium casein; Alkyl aryl ether Phosphate; fatty acid amide ether phosphate; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; Anionic surfactants, etc .; Among nonionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steares (polyoxyethylene stearyl ether), behenes (polyoxy) Polyoxyethylene alkyl ethers with various polyoxyethylene additions such as (ethylene behenyl ether), isosteares (polyoxyethylene isostearyl ether), octyldodeces (polyoxyethylene octyldodecyl ether); polyoxyethylene alkylphenyl ether; Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, poly Oxyethylene hydrogenated castor oil and castor oil derivatives such as maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholesterolol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxy Polyethylene cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene glycerin ether, etc. Polyoxyethylene / polyoxypropylene alkyl ether; polyoxyethylene / polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; Glyceryl, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, coconut oil fatty acid glyceryl, monocotton oil fatty acid glycerin, glycerin monoerkaate, glycerin sesquioleate, α, α'-glycerin pyroglutamate, monostearate Partial esters of glycerin fatty acids such as acid glycerin malic acid; polyglyceryl-2, 3, 4, 4, 6, 8, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate- 2. Polyglyceryl decastearate-10, polyglyceryl-2 isostearate-2, 3, 4, 4, 5, 6, 8, 10, diisostearate polyglyceryl-2 (diglyceryl diisostearate), 3, 10, , Polyglyceryl-2 triisostearate, Polyglyceryl-2 tetraisostearate, Polyglyceryl-10 decaisostearate, Polyglyceryl-2 oleate, 3, 4, 5, 5, 6, 8, Polyglyceryl dioleate- 6. Polyglycerin fatty acid ester such as polyglyceryl-2 trioleate, polyglyceryl-10 decaurenate; ethylene glycol monofatty acid ester such as ethylene glycol monostearate; propylene glycol monofatty acid ester such as propylene glycol monostearate; pentaerythritol moiety Fatite ester; sorbitol partial fatty acid ester; multitall partial fatty acid ester; martitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan Sorbitane fatty acid esters such as trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; partial esters of sugar derivatives such as sucrose fatty acid ester, methylglucoside fatty acid ester, trehalose undecylate; Alkyl glucosides such as glucosides; alkyl polyglycosides; glycolipids such as mannosylerythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene di Ole Polyoxyethylene fatty acid mono- and diesters such as alcohol; polyoxyethylene / propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate and the like. Polyoxyethylene glycerin fatty acid esters such as monooleate; polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monoolate, and polyoxyethylene sorbitan tetraoleate. Polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, and polyoxyethylene sorbitol monostearate; polyoxyethylene methylglucoside fatty acid esters; poly Oxyethylene alkyl ether fatty acid esters; polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol honey; alkyl glyceryl ethers such as isostearyl glyceryl ethers, chimil alcohols, ceracyl alcohols and bacillic alcohols; polyhydric alcohol alkyl ethers; poly Oxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin and sophorolipid; polyoxyethylene fatty acid amides; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil Fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitate diethanolami Alcohol alkanolamides such as de (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA); alkyldimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, behenamine oxide; alkylethoxydimethylamine Oxide; polyoxyethylene alkyl mercaptan; polye such as dimethicone copolyol -Silicon-based nonionic surfactants such as teller-modified silicones, polysiloxane / oxyalkylene copolymers, polyglycerin-modified silicones, and sugar-modified silicones; Alkyltrimethylammonium chlorides such as cetrimonium chloride and lauryltrimonium chloride; alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; stealamidopropyldimethylamine, Fatty acid amidamines such as stearamid ethyldiethylamine and salts thereof; Alkyl etheramines such as stearoxypropyldimethylamine and salts thereof or quaternary salts; Ethylsulfate long chain branched fatty acids (12-31) aminopropylethyldimethylammonium, lanolin ethylsulfate Fatty acid amide-type quaternary ammonium salts such as fatty acid aminopropylethyldimethylammonium; polyoxyethylene alkylamine and its salts or quaternary salts; alkylamine salts; fatty acid amide guanidium salts; alkyl etheraminemonium salts; alkyltrialkylene glycols Ammonium salt; benzalconium salt; benzethonium salt; pyridinium salt such as cetylpyridinium chloride; imidazolinium salt; alkylisoquinolinium salt; dialkylmoriphonium salt; polyamine fatty acid derivative; aminopropyldimethicone and amodimethicone Silicone-based cationic surfactants such as modified silicones, cationically modified silicones, cationically modified and polyether-modified silicones, amino-modified and polyether-modified silicones; for amphoteric surfactants, lauryl betaine (lauryl dimethylaminoacetic acid betaine) and the like. N-alkyl-N, N-dimethyl amino acid betaine; fatty acid amide alkyl-N, N-dimethylamino acid betaine such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline type betaine such as sodium cocoammonium acetate and sodium lauroammonium acetate; alkyl Alkyl sulfobetaine such as dimethyl taurine; sulfuric acid betaine such as alkyl dimethylaminoethanol sulfate ester; phosphate betaine such as alkyl dimethyl amino ethanol phosphate; phosphatidylcholine, phosphatidylethanola Sphingophospholipids such as min, phosphatidylserine, sphingomyelin, lysolecithin, hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, phospholipids such as hydroxylated lecithin; Silicone-based amphoteric surfactants and the like; As polymer surfactants, polyvinyl alcohol, sodium alginate, starch derivatives, tragant gum, acrylate / alkyl methacrylic acid copolymers; various silicone-based surfactants are preferable.

Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, farcerelan, karaya gum, trolley aoi, cara gum, tragant gum, pectin, pectic acid and sodium. Salts such as salts, salts such as alginic acid and sodium salts, mannan; starches such as rice, corn, potatoes, wheat; xanthan gum, dextran, succinoglucan, curdran, hyaluronic acid and its salts, zansan gum, purulan, gellan gum, chitin , Chitosan, agar, casso extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and salts such as sodium thereof, methyl hydroxypropyl cellulose, sodium cellulose sulfate, dialkyldimethyl. Ammium sulfate cellulose, crystalline cellulose, cellulose such as cellulose powder and derivatives thereof; starch-based polymers such as soluble starch, carboxymethyl starch, methyl hydroxypropyl starch, methyl starch, hydroxypropyltrimonium chloride starch, octenyl succinate corn starch aluminum, etc. Alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), vinylpidridone / vinyl alcohol copolymer, polyvinylmethyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene. Polyoxypropylene copolymer; (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (Acrylate / stearyl acrylate / ethylamine methacrylate) copolymer and other amphoteric methacrylic acid ester copolymers; (dimethicone / vinyldimethicone) cloth Polymers, (alkyl acrylate / diacetone acrylamide) copolymers, (alkyl acrylate / diacetone acrylamide) copolymers AMP; partially saponified polyvinyl acetate, maleic acid copolymers; vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymers; Acrylic resin alkanolamine; polyester, water-dispersible polyester; polya Crylamide; polyacrylic acid ester copolymer such as ethyl polyacrylic acid, carboxyvinyl polymer, salt such as polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; both acrylic acid and alkyl methacrylic acid. Polymers: cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid such as polyquaterium-39. -Diallyldimethylammonium chloride-acrylamide copolymer, acrylic acid-cationized methacrylic acid ester copolymer, acrylic acid-cationized methacrylic acid amide copolymer, polyquaterium-47 and other acrylic acid-methyl acrylate-chloride Methalamide propyltrimethylammonium copolymers, choline chloride ester polymers; cationized oligosaccharides, cationized dextran, cationized polysaccharides such as guarhydroxypropyltrimonium chloride; polyethyleneimine; cationic polymers; polyquaternium-51 and the like. 2-Polymer of methacryloyloxyethyl phosphorylcholine and polymer with butyl methacrylate copolymer, etc .; acrylic resin emulsion, polyacrylic acid ethyl emulsion, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, synthetic Polymer emulsions such as latex; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and The salt; dextrin fatty acid ester such as dextrin palmitate, dextrin myristinate; anhydrous silicic acid, fumes silica (ultrafine anhydrous silicic acid), aluminum magnesium silicate, sodium magnesium silicate, metal soap, dialkylphosphate metal salt, Bentonite, hectrite, organically modified clay minerals, sucrose fatty acid esters, fructo-oligosaccharide fatty acid esters are preferred.

Examples of solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol and isopentyldiol. Kind: Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as; glycol ether esters such as ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate, ethylene glycol dissuccinate; benzyl Preferred examples include propellants such as alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation freon; LPG, dimethyl ether, carbon dioxide gas and the like.

Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; ascorbic acid derivatives such as propyl bisulfate; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; Sodium bisulfite and other sulfites; Sodium bisulfite and other sulfite hydrogen salts; Sodium bisulfite and other thiosulfates; Metahydrosulfite hydrogen salts; Thiotaurine, hypotaurine; Thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride are preferred. Is mentioned as. As the reducing agent, thioglycolic acid, cysteine, cysteamine and the like are preferable. As the oxidizing agent, hydrogen peroxide solution, ammonium persulfate, sodium bromate, percarbonate and the like are preferable.

Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane. 1,2-Alcandiols such as diols; Alkylglyceryl ethers such as 2-ethylhexylglyceryl ether (ethylhexylglycerin); Salicylic acid; Sodium benzoate; Isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; Linium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acidamides, quaternary ammonium salts; trichlorocarbanide, zincpyrythion, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, glucon Chlorhexidine acid acid, halocarban, hexachlorophen, hinokithiol; other phenols such as phenol, isopropylphenol, cresol, timol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolite, silver ion However, when used as an antibacterial agent or an antiseptic for the purpose of antiseptic, from the viewpoint of safety of cosmetics or external skin preparations, phenoxyethanol; 1,2-pentanediol, 1,2-hexane It is more preferable to use 1,2-alkanediols such as diols and 1,2-octanediols; and alkylglyceryl ethers such as 2-ethylhexyl glyceryl ethers.

Examples of the chelating agent include edetates (ethylenediamine tetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediamine triacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; ethidronic acid and the like. Phosphonic acid and salts such as sodium salts thereof; Sodium oxalate; Polypolyamino acids such as polyaspartic acid and polyglutamic acid; Sodium polyphosphate, sodium metaphosphate, phosphate; sodium citrate, citric acid, alanine, dihydroxyethylglycine , Gluconic acid, ascorbic acid, succinic acid, tartrate acid are preferred. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol. Amin, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylated Preferred are sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate and ammonium carbonate.

Powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, white mica, gold mica, synthetic mica, red mica, black mica, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, cay. Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal salt of tungsten acid, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (eg zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, dark blue, carbon black, titanium oxide, fine powder and ultrafine titanium oxide, zinc oxide , Fine particles and ultrafine zinc oxide, alumina, silica, fumigant silica (ultrafine anhydrous silicic acid), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine gold mica, fine particle composite powder, gold, aluminum, etc. Inorganic powders of various sizes and shapes, and these are treated with silicones such as hydrogen silicone and cyclic hydrogen silicone or other surface treatment agents such as silane or titanium coupling agents to make them hydrophobic. Inorganic powder such as hydrophilized powder; starch, cellulose, nylon powder, polyethylene powder, polymethylmethacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate -Polymethylmethacrylate laminated powder, polyethylene terephthalate, aluminum, epoxy laminated powder, etc., urethane powder, silicone powder, Teflon (registered trademark) powder, and other organic powders and surface-treated powders of various sizes and shapes, organic and inorganic Composite powders are preferred. Examples of inorganic salts include sodium chloride-containing salts such as salt, normal salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, ginger, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, etc. Aluminum / potassium sulfate (myoban), aluminum / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na / 2Na / 3Na phosphate, phosphoric acid Potassiums, calcium phosphates and magnesium phosphates are preferred.

Examples of the ultraviolet absorber include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoate ethyl. Anthranic acid-based UV absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl esters, N, N-dimethylparaaminobenzoic acid ethyl esters; Anthranilic acid-based UV absorbers such as homomentyl-N-acetylanthranilate; salicylic acid. And salicylic acid-based ultraviolet absorbers such as sodium salts, amilsalicylate, menthylsalicylate, homomentylsalicylate, octylsalicylate, phenylsalicylate, benzylsalicylate, p-isopropanolphenylsalicylate; octylcinnamate, ethyl-4-isopropylsinnate, methyl. -2,5-Diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxy cinnamate, isopropyl-p-methoxy cinnamate, isoamyl-p-methoxy Synnamete, 2-Ethylhexyl p-methoxysinamate (octyl paramethoxysilicate), 2-ethoxyethyl-p-methoxysinamate (sinoxate), cyclohexyl-p-methoxysinamate, ethyl-α-cyano-β-phenyl Ceramic acid-based ultraviolet absorbers such as cinnamate, 2-ethylhexyl α-cyano-β-phenyl cinnamate (octocrine), glycerylmono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and its derivatives; 2, 4-Dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2', 4,4'-tetrahydroxybenzophenone, 2-hydroxy- 4-Methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4' Benzophenones such as −phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone System UV absorbers; 3- (4'-methylbenziliden) -d, l-phenyl, 3-benziliden-d, l-phenyl; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 -Methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoilmethane; 5-( 3,3-Dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivative such as 4-t-butylmethoxydibenzoylmethane; octylriazone; urocanic acid derivative such as urocanic acid and ethyl urocanate 2- (2'-Hydroxy-5'-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentandione, dimethoxybenzilidendioxoimidazolidinepropionic acid Preferred examples include hydridein derivatives such as 2-ethylhexyl, phenylbenzimidazole sulfonic acid, terephthalylidenedicanfursulfonic acid, drometrizoletrisiloxane, methyl anthranilate, rutin and its derivatives, orizanol and its derivatives.

Examples of vitamins and derivatives thereof include vitamin A such as retinol, retinol acetate, and retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxin hydrochloride, pyridoxin dioctanoate, pyridoxin dipalmitate, and the like. Flavin adenine dinucleotide, cyanocobalamine, folic acid, nicotinic acids such as nicotinic acid amide and benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin E such as β, γ, δ-tocopherol; Other vitamins such as pantothenic acid and biotin; Ascorbic acid phosphate ester salt such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate ester magnesium salt, ascorbic acid tetra Ascorbic acid fatty acid ester such as isopalmitic acid ester, ascorbic stearate, ascorbic palmitate, ascorbic dipalmitate, ascorbic acid alkyl ether such as ethyl ascorbic acid ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and its fatty acid ester. , Ascorbic acid derivatives such as tocopheryl phosphate ascorbic; vitamin derivatives such as tocopherol derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol linoleic acid, tocopherol ferulate, tocopherol phosphate ester, tocotrienol, and other various vitamin derivatives are preferable. Is mentioned as.

Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokithiol, guaiazulene, allantin, indomethacin, zinc oxide, hydrocortisone acetate, prednison, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract. , Plant extracts such as Honoha extract are preferred. As hair growth agents, blood circulation promoters and stimulants, plant extracts and tinctures such as senburi extract, capsicum tincture, gypsum tincture, gypsum tincture, cantalis tincture; , Borneol, cyclanderate, cinnaridine, trazoline, acetylcholine, verapamil, cepharanthin, γ-orizanol, cepharanthin, vitamin E and derivatives such as tocopherol nicotinate / tocopherol acetate, γ-orizanol, nicotinic acid and nicotinic acid amide / benzyl nicotinate. Derivatives such as ester inositol hexanicotinate and nicotine alcohol, allantin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivative, stigmasterol or stigmasterol and its glycosyl, minoxydil are preferable. Is mentioned as. As the hormones, estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like are preferable. Other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cold sensitizers, warming agents, wound healing promoters, stimulants, painkillers, cell activators, etc. include retinols, retinoic acids, retinoins. Tocopheryl acid; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, hydroxycapric acid, long-chain α-hydroxy fatty acid, long-chain α-hydroxy fatty acid cholesteryl and the like α-or β-Hydroxy acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosin; creatin; ceramides, spingosins; caffeine, xanthin and its derivatives; coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloids, fullerene and other antioxidant / active oxygen scavengers; catechins; kelcetin and other flavones; isoflavones; Polyphenols such as anthocyanidin, chlorogenic acid, apple polyphenol; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; Gyogaol, gingerol; fragrance substances such as menthol, camphor, sedrol and its derivatives; capsaicin, vanillin and the like and derivatives; insect repellents such as diethyl toluamide; complexes of physiologically active substances and cyclodextrins are preferred. Can be mentioned.

Plant / animal / microbial extracts include iris extract, asitaba extract, asnalo extract, asparagus extract, avocado extract, flaxseed extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo biloba extract. , Inchkou extract, Uikyo extract, Ukon extract, Woolong tea extract, Uwaurushi extract, Agetsu extract, Echinashi leaf extract, Enmeisou extract, Ogon extract, Oubaku extract, Ouren extract, Omugi extract, Otaneninjin extract, Otogirisou extract, Odorikosou extract, Ononis extract , Dutch mustard extract, orange extract, dried seawater, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, cucumber extract, chamomile extract, oil-soluble chamomile extract, carrot extract, kawarayomogi Extract, crow wheat extract, karukade extract, kanzo extract, oil-soluble kanzo extract, kiwi extract, kiou extract, kikurage extract, kina extract, cucumber extract, kiri leaf extract, guanosine, guava extract, kujin extract, kuchinashi extract, kumazasa extract, clara extract, walnut Extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, quail extract, gentiana extract, gennoshoco extract, tea extract, yeast extract, koboku extract, coffee extract, gobo extract, rice extract, rice Fermented extract, fermented rice bran extract, rice germ oil, confree extract, collagen, kokemomo extract, saishin extract, psycho extract, saitai extract, saffron extract, salvia extract, sabonsou extract, sasa extract, sanzashi extract, sansha extract, sansho Extract, Shiitake extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shimotsukesou extract, Jatoba extract, Shakuyaku extract, Shokyu extract, Shobu root extract, Shirakaba extract, White chrysanthemum extract, Sugina extract, Stevia extract, Stevia fermented product, Nishikawayanagi extract, Seiyoukizuta extract, Seiyousanzashi extract, Seiyouniwatoko extract, Seiyounokogirisou extract, Seiyouhakka extract, Sage extract, Zeniaoi extract, Senkyu extract, Senburi extract, Souhakuhi extract, Daiou extract, Die Zu extract, Taisou extract, Thyme extract, Dandelion extract, Local clothing extract, Tea extract, Chouji extract, Chigaya extract, Chinpi extract, Tea tree oil, Jincha extract, Togarashi extract, Touki extract, Tokinsenka extract, Tounin extract, Tohi extract, Dokudami extract, Tomato Extract, Natto extract, Carrot extract, Garlic extract, Novara extract, Hibiscus extract, Bakumondou extract, Hass extract, Parsley extract, Birch extract, Honey, Hamamelis extract, Parietaria extract, Hikiokoshi extract, Bisabolol, Hinoki extract, Bifizus bacterium extract, Biwa extract, Fukitanpopo extract, Fukinotou extract, Bukuryo extract, Butcher bloom extract, Grape extract, Grape seed extract, Propolis, Hechima extract, Benibana extract, Peppermint extract, Bodaiju extract, Button extract, Hop extract, Maikaika extract, Pine extract, Maronie extract , Mizubasho extract, Mukuroji extract, Melissa extract, Mozuku extract, Peach extract, Yagurumagiku extract, Eucalyptus extract, Yukinoshita extract, Yuzu extract, Yuri extract, Yokuinin extract, Yomogi extract, Lavender extract, Green tea extract, Eggshell membrane extract, Apple extract, Louis Boss tea extract , Reishi extract, lettuce extract, lemon extract, lotus extract, lotus extract, rose extract, rosemary extract, Roman chamomile extract, royal jelly extract, crackle extract and the like are preferable.

Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, zinc paraphenolsulfonate and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum / potassium sulfate, tannic acid and the like. Examples of the enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease and the like. Preferred examples of nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and disodium adenosine triphosphate.

As fragrances, acetylsedrene, amilcinnamaldehyde, allylamylglycolate, β-ionone, isoe super, isobutylquinoline, iris oil, iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragor, Eugenol, Oak Moss, Opoponax Resinoid, Orange Oil, Eugenol, Oranthiol, Galaxolid, Carbachlor, L-Carbon, Kamfer, Cannon, Carrot Seed Oil, Clove Oil, Methyl Caynate, Geraniol, Geranylnitrile , Isobornyl acetate, Geranyl acetate, Dimethylbenzylcarbyl acetate, Styralyl acetate, Sedrill acetate, Telepinel acetate, pt-butylcyclohexyl acetate, Vetiberyl acetate, benzyl acetate, Linaryl acetate, Isopentyl salicylate, benzyl salicylate, Sandalwood oil, Santa roll, Cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citroneral, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylux Reginoid, Cedarwood Oil, Sedren, Sedrol, Cellory Seed Oil, Thyme Oil, Damascon, Damasenon, Timor, Tuberose Absolute, Decanal, Decalactone, Terpineol, γ-Terpinen, Triplar, Nerol, Nonanar, 2,6-Nonadienor, Nonalactone, Pacholi Alcohol, vanilla absolute, vanillin, basil oil, patcholi oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian balsam, vetiver oil, vetiverol , Peppermint oil, pepper oil, heliotropin, bergamot oil, benzylbenzoate, borneol, millresinoid, muskketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menton, eucalyptus oil, β-yonon, lime oil , Lavender oil, D-limonen, linalol, lylar, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, synthetic fragrances such as various essential oils and natural Fragrances and various blended fragrances are preferred.

Dyes / colorants / dyes / pigments include brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, and blue 204. , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 , Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230-1 , Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505. , Red 506, Orange 201, Orange 203, Orange 204, Orange 205, Orange 206, Orange 207, Orange 401, Orange 402, Orange 403, Yellow 201, Yellow 202-1 , Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow 405, Yellow 406, Yellow Legal dyes such as No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26 and other nitro dyes; Disperse dyes; Titanium dioxide, Zinc oxide Inorganic white pigments such as; Inorganic red pigments such as iron oxide (Bengala) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and ocher; Black iron oxide, low Inorganic black pigments such as secondary titanium oxide; Inorganic purple pigments such as mango violet and cobalt violet; Inorganic green pigments such as dye, chromium hydroxide, cobalt titanate; Inorganic blue pigments such as ultramarine and dark blue; Titanium oxide coated mica, Titanium oxide coated oxybismus chloride, Titanium oxide coated talc, Colored titanium oxide coated mica, Oxy Pearl pigments such as bismuth chloride and fish scale foil; metal powder pigments such as aluminum powder, copper powder and gold; surface-treated inorganic and metal powder pigments; red 201, red 202, red 204, red 205, red 220 , Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, Blue 404, Red 3, Red 104, Red 106, Red 227, Red Organic pigments such as zirconium, barium or aluminum lakes such as 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1. Surface-treated organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsantine, chalcone, calsamine, quercetin, closin, chlorophyll, curcumin, cochineal, ciconin and other naphthoquinones, bixins, flavones, beta Natural pigments / dyes such as cyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5- Oxidation dye intermediates and couplers such as amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and salts thereof; automatic oxidation dyes such as Indolin; dihydroxyacetones are preferred.

As the water, in addition to normal water and purified water, hard water, soft water, natural water, deep ocean water, electrolytic alkaline ionized water, electrolytically acidic ionized water, ionized water, and cluster water are preferable.

In addition to these, cosmetic raw material standards, compounding ingredient standards by cosmetic type, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), non-pharmaceutical raw material standards, Japanese Pharmacy, pharmaceutical additives Ingredients described in standards, official food additives, etc., and Japanese and foreign patent gazettes and patent publication gazettes (including published gazettes and republished gazettes) whose international patent classification IPC belongs to the A61K7 and A61K8 classifications. It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the described ingredients, in known combinations, blending ratios, and blending amounts.

Examples of the type of cosmetics of the present invention include hair cosmetics, basic cosmetics, make-up cosmetics, aromatic cosmetics, body cosmetics, skin external preparations such as ointments, and the like. From the viewpoint of exerting the effect of the present invention, it can be particularly preferably used for hair cosmetics and basic cosmetics. The cosmetic of the present invention can be produced according to a usual method.

To explain the types of cosmetics of the present invention in more detail, hair cosmetics include oil shampoos, cream shampoos, conditioning shampoos, styling shampoos, hair coloring shampoos, rinse-integrated shampoos and other shampoos; rinses, treatments, etc. Conditioners such as hair packs and hair mists; hair styling products such as hair foams, hair mousses, hair sprays, hair waxes, hair gels, hair creams, water greases, set lotions, pomades, tics; color lotions, hair tonics, hair liquids, hair blows, branches Hair coats, hair oils, permanent wave agents, straight perms, oxidative hair dyes, hair bleaches, hair color pretreatments, hair color aftertreatments, perma pretreatments, perma aftertreatments, hair manicures, and hair restorers are preferred. Be done.

Basic cosmetics include soft lotion, astringent lotion, cleaning lotion, multi-layered lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisturizer, moisturizer. -Emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sun screen, make-up lotion, horny smoother, elbow lotion, hand lotion, body lotion and other emulsions; emollient cream, nutrition cream, Nourishing cream, vanishing cream, moisture cream, night cream, massage cream, cleansing cream, make-up cream, base cream, pre-makeup cream, sunscreen cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening Creams such as creams; Gels such as moisture gels; Essences such as moisturizing essences, whitening essences, and UV protection essences; Lipstick cosmetics such as liposome beauty liquids and liposome cosmetics; Peel-off packs, powder packs, washing packs, oil packs, cleansing Packs and masks such as masks; cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing oil, cleansing mask, washing powder, face washing powder and other washing pigments; cosmetic soap, transparent soap, medicated soap, liquid soap, Soaps such as shaving soap and synthetic cosmetic soap are preferable.

Preferred makeup cosmetics include white powder / dusting powder, foundations, lipsticks, lip gloss, blusher, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment. ..

Preferable fragrance cosmetics include perfumes, perfumes, parfum, eau de parfum, eau de toilette, eau de cologne, perfumes, fragrance powders, perfume soaps, body lotions and bath oils.

Body cosmetics include body cleaning agents such as body shampoo, deodorant lotions, deodorant powders, deodorant sprays, deodorant cosmetics such as deodorant sticks, depigmenting agents, depilatory / depilatory agents, bathing agents, insect repellent sprays, etc. Repellers are preferred.

Further, as the external skin preparation, it can be used in a dosage form such as an ointment, a patch, a lotion, a liniment, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

As the dosage form of the cosmetic or skin external preparation of the present invention, emulsification of oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type and the like. Type cosmetics, oil-based cosmetics, solid cosmetics, liquid cosmetics, paste-like cosmetics, stick-like cosmetics, volatile oil-type cosmetics, powder-like cosmetics, jelly-like cosmetics, gel-like cosmetics, paste-like Formulation types such as cosmetics, emulsified polymer type cosmetics, sheet-like cosmetics, mist-like cosmetics, and spray-type cosmetics are preferable.

The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto.

In the present invention, the weight average molecular weight (Mw) means a value in terms of polystyrene measured by gel permeation chromatography (GPC). In the present invention, the values are measured under the following devices and conditions.

Analytical device: GPC-8020 (manufactured by Tosoh)
Column: TSK-GEL G3000HHR (7.8 x 300 mm, manufactured by Tosoh Corporation)
TSK-GEL G2000HHR (7.8 x 300 mm, manufactured by Tosoh Corporation)
TSK-GEL GMHHR-M (7.8 x 300 mm, manufactured by Tosoh Corporation)
Detector: RI detector RI-8020 (manufactured by Tosoh Corporation)
Solvent: Tetrahydrofuran Measurement temperature: 40 ° C
Flow rate: 1.0 mL / min

Synthesis Example 1 Polyester production 170 g (0.30 mol) of hydrogenated dimer acid (PRIPL1006, manufactured by Croda) and dimerdiol (PRIPOL2033, manufactured by Croda) were added to a 500 mL reactor equipped with a stirrer, thermometer, and gas introduction tube. ) 162 g (0.30 mol) was charged, heated to 215 to 225 ° C. in a nitrogen stream, and an esterification reaction was carried out for 28 hours while removing the generated water, and the target polyester (dimeric acid: dimerdiol = 1.0) was carried out. : 1.0) 315 g was obtained as a pale yellow glassy substance (yield 98%).

Synthesis Examples 2 to 5 Production of Polyester The esterification reaction was carried out in the same manner as in Synthesis Example 1 except that the ratio of hydrogenated dimer acid to dimer diol was changed to the ratio shown in Table 1, and the desired polyesters were obtained.

Synthesis Example 6 Production of Polyester As the hydrogenated dimer acid, PRIPOL 1025 was used instead of PRIPOL 1006, except that the ratio of dimer acid to dimer diol was changed from 1.0: 1.0 to 0.95: 1.0. The esterification reaction was carried out in the same manner as in Synthesis Example 1 to obtain the desired polyester.

Comparative Synthesis Example 1 Production of Oligomer Ester The esterification reaction was carried out in the same manner as in Synthesis Example 1 except that the ratio of dimer acid to dimer diol was changed from 1.0: 1.0 to 0.7: 1.0 for comparison. Oligomer ester was obtained.

The weight average molecular weights of the polyesters of Synthesis Examples 1 to 6 and the oligomer esters of Comparative Synthesis Example 1 were measured. The results are shown in Table 1.

Preparation of wax-like composition and feel evaluation 1
Using the polyester corresponding to the component (A) of the present invention, the waxy composition of the present invention was prepared with the composition shown in Table 2 (Examples 1 to 12). All of the obtained wax-like compositions had hardness enough to be processed into various shapes.
The obtained waxy composition was diluted with an oil agent (1: 1 mixed oil of ethylhexyl palmitate and liquid paraffin) to a concentration of 50 w / w%, and a certain amount of the obtained diluted product was applied between the index finger and the pad of the thumb. The feel was evaluated by sandwiching it between the two. The reason for diluting with an oil agent in this evaluation is that the wax-like composition itself is too hard to evaluate the feel. The five evaluation items were adhesiveness, hardness, spread, thickness, and slipperiness, and the following evaluation points were evaluated in comparison with candelilla wax. The scores are shown by the average score of 5 Paraneys, and the results are also shown in Table 2. For comparison, the waxy compositions (Comparative Examples 1 to 12) containing no component (A) of the present invention were also evaluated in the same manner, and the results are shown in Table 3.

Adhesiveness 5 points: considerably stronger than candelilla wax 4 points: slightly stronger than candelilla wax 3 points: almost the same as candelilla wax 2 points: Slightly weaker than candelilla wax 1 point: very weak compared to candelilla wax Hardness 5 points: considerably harder than candelilla wax 4 points: candelilla A little harder than wax 3 points: Almost the same as candelilla wax 2 points: a little softer than candelilla wax 1 point: very soft compared to candelilla wax 5 Point: Very easy to spread compared to candelilla wax 4 points: Slightly easy to spread compared to candelilla wax 3 points: Almost the same as candelilla wax 2 points: Compared to candelilla wax , Slightly difficult to spread 1 point: Very difficult to spread compared to candelilla wax 5 points: considerably thicker than candelilla wax 4 points: slightly thicker than candelilla wax 3 points: Almost the same as candelilla wax 2 points: a little thinner than candelilla wax 1 point: very thin compared to candelilla wax 5 points: can It is considerably slippery compared to Delilah wax 4 points: It is a little slippery compared to Candelilla wax 3 points: Almost the same as Candelilla wax 2 points: It is a little slippery compared to Candelilla wax Difficult 1 point: Very hard to slip compared to candelilla wax

From the results of Tables 2 and 3, the wax containing the component (A) (Comparative Examples 1 to 12) has a weaker adhesiveness than the candelilla wax, whereas the wax of the present invention containing the component (A) is blended. It was found that the state composition showed an adhesiveness equal to or higher than that of the candelilla wax, and was useful for imparting settability, resettability, adhesion and the like.

Preparation of wax-like composition and feel evaluation 2
At least one of the polyester corresponding to the component (A) of the present invention and the wax corresponding to the components (B1) to (B3) of the present invention are blended, and the wax of the present invention has the composition shown in Table 4. A state composition was prepared (Examples 13 to 21). All of the obtained wax-like compositions had hardness enough to be processed into various shapes.
The obtained wax-like composition was subjected to a feel evaluation in the same manner as in Table 2, and the results are also shown in Table 4.

From the results shown in Table 4, the waxy compositions of the present invention of Examples 13 to 21 showed an adhesiveness equal to or higher than that of the candelilla wax, and the component (B) was also used in other evaluations. The result was close to that of candelilla wax as compared with the single Examples 1 to 12. In addition, the wax-like composition using the polyester of Comparative Synthesis Example 1 (molecular weight is smaller than the range of the present invention) had insufficient adhesiveness.

Preparation of wax-like composition and feel evaluation 3
At least one polyester corresponding to the component (A) of the present invention and at least one wax corresponding to the components (B1) to (B3) of the present invention are blended, and the present invention has the compositions shown in Tables 5 and 6. The waxy composition of (Examples 22 to 39) was prepared. All of the obtained wax-like compositions had hardness enough to be processed into various shapes.
The obtained wax-like composition was subjected to a feel evaluation in the same manner as in Table 2, and the results are also shown in Tables 5 and 6.

From the results of Tables 5 and 6, the waxy compositions of the present invention of Examples 22 to 39 showed the same or higher adhesiveness as that of the candelilla wax, and also in other evaluations, the component (B). ) Is single, the result is close to that of candelilla wax as compared with Examples 1 to 12.

Preparation of Hair Wax Containing Wax-like Composition and Evaluation of Setability Using the wax-like composition of the present invention, a hair wax having the composition shown in Table 7 was prepared (Examples 40 to 45). For comparison, a hair wax using candelilla wax or other wax was prepared (Comparative Examples 14 to 16). The obtained hair wax was evaluated for hair settability and resettability by the following method. The results are also shown in Table 7.

<Setability>
A hair bundle having a length of 15 cm and a weight of 5 g was prepared using healthy black-haired human hair, and 1 g of hair wax was evenly applied to the hair bundle up to the tip of the hair, and then lightly squeezed to prepare the hair bundle. The settability of the hair bundles thus obtained was evaluated according to the following criteria based on the adhesiveness between the hairs, the holding power of the hair bundles, and the way the hair bundles were loosened when shaken lightly.

◎: Very strong setting power ○: Strong setting power △: Weak setting power ×: No setting power

<Resetability>
The hair bundle used in the above settability evaluation was left in a room adjusted to 25 ° C./60% humidity for 3 hours, combed with a ring comb 10 times, and then, as in the settability evaluation, the following The evaluation was made according to the criteria of.

◎: Very strong resetting power ○: Strong resetting power △: Weak resetting power ×: No resetting power

From the results shown in Table 7, the hair waxes of Examples 40 to 45 using the wax-like composition of the present invention had settability and resettability equal to or higher than those of the candelilla wax-blended hair wax. ..

Preparation of foundation containing wax-like composition and evaluation of adhesion A foundation having the composition shown in Table 8 was prepared using the wax-like composition of the present invention (Examples 46 to 51). For comparison, a foundation using candelilla wax or other wax was prepared (Comparative Examples 17 to 19). The adhesion of the obtained foundation was evaluated by the following method. The results are also shown in Table 8.

<Adhesion>
Adhesion was evaluated according to the following evaluation criteria based on the feeling of use when the prepared foundation was applied to the skin.

◎: Very adhesive ○: Adhesive △: Weak adhesive ×: No adhesive

From the results shown in Table 8, the foundation using the waxy composition of the present invention had an adhesion equal to or higher than that of candelilla wax.

The waxy composition of the present invention was used to prepare the cosmetics described below. In the obtained cosmetics, the wax-like composition of the present invention exerts functions as a general wax such as solidification of a formulation, adjustment of hardness and viscosity, film formation, gloss imparting, and spreading, and also hair styling. In terms of materials, the operability of hair was improved, excellent settability and resettability were imparted, and in make-up cosmetics, excellent adhesion was imparted.

Example 52 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 8.0
Phytosteryl isostearate 1.0
(Plandol-ISS: Nippon Fine Chemical Co., Ltd.)
Triethylhexanoin (IOTG: Nippon Fine Chemical Co., Ltd.) 1.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandol-G: Nippon Fine Chemical Co., Ltd.) 9.0
Tori Hydrogenated Rosin Lyceryl 1.0
PPG-1 Behenes-15 5.0
Polyurethane-1 2.0
Cholesterol 0.5
Diethyl sebacate 2.0 2.0
Setes-7 1.0
Dimethicone 3.0
Diisopropyl adipate 5.0
Part B Glycerin 5.0
Phenoxyethanol 0.6
Methylparaben 0.2
Amount of purified water totaling 100 parts C (Acrylate / Methacrylic acid steareth-20) copolymer 3.0
Purified water 20.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled (part D). Part C was added to part D and mixed uniformly.

Example 53 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 13.0
Sunflower Seed Oil Fatty Acid Phytosteryl 2.0
(Plandol-SUN: Nippon Fine Chemical Co., Ltd.)
Dimari Linoleic Acid Dimari Linole 2.7
(LUSPLAN DD-DA7: Nippon Fine Chemical Co., Ltd.)
Tori Hydrogenated Rosin Riseryl 0.3
Bisdiglyceryl Polyacyl Adipate-2 5.0
(Plandol-DP: Nippon Fine Chemical Co., Ltd.)
Triethylhexanoin (IOTG: Nippon Fine Chemical Co., Ltd.) 3.0
PEG-40 hydrogenated castor oil 1.0
Stairless-30 1.0
γ-docosalactone, cyclopentasiloxane, diethyl sebacate, ethanol (Elcalactone SIL: Nippon Fine Chemical Co., Ltd.) 1.0
(Alkyl acrylate / Diacetone acrylamide) Copolymer AMP 1.0
Komenukarou 2.0
Hydroxystearic acid 6.0
Glyceryl stearate 1.0
Dimethicone 3.0
Diisopropyl adipic acid (IPSE: Nippon Fine Chemical Co., Ltd.) 5.0
Setes-2 0.5
Setes-20 2.5
BHT0.05
Phenoxyethanol 0.6
Methylparaben 0.2
Part B BG 3.0
Na Hydroxide 0.5
(Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer 0.1
Amount of purified water totaling 100 -------------
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled.

Example 54 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 13.0
Phytosteryl isostearate 1.0
(Plandol-ISS: Nippon Fine Chemical Co., Ltd.)
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandol-G: Nippon Fine Chemical Co., Ltd.) 2.7
Tori Hydrogenated Rosin Riseryl 0.3
Cyclopentasiloxane 10.0
Cetyl ethylcaproate (NS-CIO: Nippon Fine Chemical Co., Ltd.) 8.0
Jojoba Ester 4.0
Glyceryl stearate 2.0
Setes-10 2.0
Tocopherol 0.05
Paraffin wax 2.0
PEG-20 hydrogenated castor oil 1.3
Beeswax 1.5
Ethylhexyl methoxycinnamate 1.8
PEG-90M 3.0
Part B Phenoxyethanol 0.6
Methylparaben 0.15
PG 3.0
Amount of purified water totaling 100 -------------
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled.

Example 55 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 1 6.0
Pentaerythrityl tetraethylhexanoate 4.5
(NS-408: Nippon Fine Chemical Co., Ltd.)
Dimethicone 8.0
Olive oil 2.0
Squalene 3.0
Theopromagrange Florum Seed Fat 0.3
Stearic acid 2.0
Glyceryl stearate 0.8
Setes-7 1.0
Tocopherol 0.05
Microcrystalline wax 2.0
Come Nukarou 2.5
PEG-40 hydrogenated castor oil 1.3
Setes-20 1.5
Beeswax 1.5
Part B Phenoxyethanol 0.4
Methylparaben 0.15
Carbomer 0.1
EDTA-4Na 0.05
TEA 0.2
PG 3.0
Amount of purified water totaling 100 -------------
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled.

Example 56 Hair Cream Wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 9 6.0
Fatty Acid (C18-35) Glycol 6.0
PEG-120 Methyl Glucose Dioleate 5.0
Lanolin fatty acid octyldodecyl 5.0
Stearic acid 4.0
Carnauba wax 3.0
Diethyl sebacate 2.0 2.0
Elcalactone 2.0
Dimethicone (100,000 cs) 1.0
Cyclopentasiloxane 1.0
Setes-2 2.0
Setes-7 2.0
Setes-20 1.0
Dicocodimonium chloride (75%) 1.0
Propylparaben 0.1
Part B Triethanolamine 0.3
Methylparaben 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was placed in a separate container and heated to about 80 ° C. to uniformly dissolve it (part B). Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 57 Hair Care Styling Milk

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 23 4.0
Jojoba Seed Oil 6.0
Glyceryl stearate (SE) 2.0
Polyglyceryl-10 2.0 myristate
Squalene 4.0
Olive oil 3.0
Bisdiglyceryl Polyacyl Adipate-2 2.0
(Plandol-DP: Nippon Fine Chemical Co., Ltd.)
Part B Carbomer 0.1
Purified water 20.0
PVP 0.05
Modified cornstarch 0.1
Part C Glycerin 4.0
(Icosanedioic acid / tetradecanedioic acid) Polyglyceryl-10, glycerin (Neosolue-AquaS: Nippon Fine Chemical Co., Ltd.) 1.0
BG 2.0
Betaine 1.0
Sorbitol 0.5
Pentylene Glycol 3.0
Arginine 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part C was placed in a separate container and heated to about 80 ° C. to uniformly dissolve it. Part B was placed in a separate container to prepare a viscous liquid. Part C was added to part A at about 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 58 Hair Styling Wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 24 4.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandol-G: Nippon Fine Chemical Co., Ltd.) 2.7
Octyldodecyl myristate 6.0
Rapeseed oil 5.0
Squalene 5.0
Stearic acid 2.0
Beeswax 3.0
Dimer dilinoleic acid Dimer dilinoleil, tri (caprylic acid / capric acid) glyceryl (LUSPLAN SR-DM4: Nippon Fine Chemical Co., Ltd.) 2.0
PEG-60 hydrogenated castor oil 1.0
Glyceryl stearate (SE) 1.0
Lauroyl lysine 0.5
Setes-7 2.0
Glyceryl caprate 1.0
Part B Triethanolamine 0.3
Propane Glycol 5.0
Pentylene Glycol 3.0
Hexylene glycol 0.8
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was placed in a separate container and heated to about 80 ° C. to uniformly dissolve it (part B). Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 59 Matte Hair Wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 12.0
Hydrogenated polyisobutene 6.0
Cetyl ethylcaproate (NS-CIO: Nippon Fine Chemical Co., Ltd.) 5.0
Microcrystalline wax 5.0
Hydroxystearic acid 3.0
Cetanol 2.0
Tocopherol 0.05
Silica 1.0
Methyl polyacrylate 0.5
Ethylhexyltriazone 2.0
Setes-20 1.0
Propylparaben 0.1
Part B Na Hydroxide 0.8
Methylparaben 0.20
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was placed in a separate container and heated to about 80 ° C. to uniformly dissolve it. Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 60 Styling Balm

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Wax-like composition of Example 15 3.0
Tri (caprylic acid / capric acid) glyceryl Amount totaling 100 (Neosolve-MCT: Nippon Fine Chemical Co., Ltd.)
Pentaerythrityl tetraethylhexanoate 6.0
(NS-408: Nippon Fine Chemical Co., Ltd.)
Polyethylene 5.0
Celesin 1.0
Diisostearyl malate 2.0
Squalene 3.0
Camellia seed oil 5.0
Phenoxyethanol 1.0
Glyceryl stearate (SE) 1.0
Setes-25 2.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All components were heated to about 80 ° C., mixed uniformly and then cooled to room temperature.

Example 61 Hair mist wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 3.0
Setes-20 1.0
Propylene glycol 4.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(Neosolue-Aquio: Nippon Fine Chemical Co., Ltd.)
Part B Carbomer 0.1
Purified water 20.0
Part C Arginine 0.2
Hydrolyzed keratin 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was heated to about 80 ° C. and uniformly dissolved. Part C was placed in a separate container and heated to about 80 ° C. to uniformly dissolve it. Part B was placed in a separate container to prepare a viscous liquid. Part A was mixed while stirring part C with a homomixer at about 80 ° C. After quenching to about 30 ° C., part B was mixed and made uniform.

Example 62 Hair Conditioner

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 23 4.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandol-G: Nippon Fine Chemical Co., Ltd.) 1.0
Stearyl alcohol 3.0
Behenyl alcohol 1.0
Behentrimonium chloride 2.0
Stearamidopropyldimethylamine 0.5
Dimer dilinoleic acid Dimer dilinoleil, tri (caprylic acid / capric acid) glyceryl (LUSPLAN SR-DM4: Nippon Fine Chemical Co., Ltd.) 2.0
Cetyl ethylcaproate (NS-CIO: Nippon Fine Chemical Co., Ltd.) 1.0
Glyceryl caprate 1.0
Part B Lactic acid 0.3
Glycerin 3.0
Amount of purified water totaling 100 Part C Phenoxyethanol 0.3
Amodimethicone 3.0
Snow fungus polysaccharide (Tremost-TP: Nippon Fine Chemical Co., Ltd.) 0.1
Purified water 10.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was placed in a separate container and heated to about 80 ° C. to uniformly dissolve it (part B). Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, part C was added to make it uniform.

Example 63 Stick Balm

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Wax-like composition of Example 15 4.0
Diisostearyl malate A total amount of 100 Isotridecyl isononanoate 3.0
Pentaerythrityl tetraisostearate 3.0
Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl /
Behenil) (Plandol-S: Nippon Fine Chemical Co., Ltd.) 0.2
Triethylhexanoin (IOTG: Nippon Fine Chemical Co., Ltd.) 6.0
Ascorbyl Tetraethyl Caproate 2.0 2.0
Polyethylene 5.0
Polyglyceryl triisostearate-2 0.5
Dimethicone 2.0
Stearyl glycyrrhetinate 0.05
Phenoxyethanol 0.6
Titanium oxide 0.5
Microcrystalline wax 0.8
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All components were heated to about 80 ° C., mixed uniformly and then cooled to room temperature.

Example 64 Lipstick

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Wax-like composition of Example 15 4.0
Hydrogenated polyisobutene 6.0
Dimari Linoleic Acid Dimari Linole 3.0
(LUSPLAN DD-DA7: Nippon Fine Chemical Co., Ltd.)
Polybutene 8.0
Polyethylene 5.0
Ethyl cellulose 0.2
Synthetic wax 1.2
Shea butter 3.0
Iron oxide 2.3
Mica 1.5
Titanium oxide 2.5
Red 202 1.5
Cetyl ethylcaproate (NS-CIO: Nippon Fine Chemical Co., Ltd.) 5.0
Sorbitan sesquioleate 1.0
Tocopherol 0.05
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All components were heated to about 80 ° C., mixed uniformly and then cooled to room temperature.

Example 65 Lipstick

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Wax-like composition of Example 15 7.5
(Diphenylmethylsiloxyphenylmethicone / phenylsilsesquioxane)
Cross polymer 15.0
Cetyl ethylhexanoate (NS-CIO: Nippon Fine Chemical Co., Ltd.) A total amount of 100 Trimethylolpropane triethylhexanoate 10.0
(NS-308: Nippon Fine Chemical Co., Ltd.)
Isohexadecane 8.0
Tritridecyl trimeritoate 8.0
Beeswax 8.0
Celesin 3.0
Stearic acid 2.0
Japan wax 2.0
Dimari Linoleic Acid Dimari Linole 3.0
(LUSPLAN DD-DA5: Nippon Fine Chemical Co., Ltd.)
Vaseline 2.5
Lanolin (Purified Lanolin: Nippon Fine Chemical Co., Ltd.) 2.0
Di (phytosteryl / octyldodecyl) lauroyl glutamate 6.0
(Plandol-LG2: Nippon Fine Chemical Co., Ltd.)
Diisostearyl malate 5.0
Mineral oil 5.0
Sorbitan sesquiisostearate 0.1
(Icosanedioic acid / tetradecanedioic acid) Polyglyceryl-10, glycerin (Neosolue-Aqua: Nippon Fine Chemical Co., Ltd.) 0.1
Diethylpentanediol dineopentanoate 0.5
(Neosolve-DE: Nippon Fine Chemical Co., Ltd.)
Ethylhexyl stearate 0.2
(Neosolve-IOS: Nippon Fine Chemical Co., Ltd.)
Isopropyl palmitate 0.1
(Neosolve-IPP: Nippon Fine Chemical Co., Ltd.)
Octyl methoxycinnamate 0.01
Tocopherol 0.1
Propinyl iodide butylcarbamate 0.01
Titanium oxide Appropriate amount Zinc oxide Appropriate amount Safflower Red Appropriate amount Red 226 Appropriate amount Yellow 5 Appropriate amount Borosilicate (Ca / Al) Appropriate amount Silica Appropriate amount Tin oxide Appropriate amount －－－－－－－－－－－－－－
(Preparation method)
All components were heated to about 80 ° C., mixed uniformly and kneaded, and then cooled to room temperature.

Example 66 Lipstick

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Wax-like composition of Example 23 3.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandol-G: Nippon Fine Chemical Co., Ltd.) 1.0
Di-lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
(Plandol-LG1: Nippon Fine Chemical Co., Ltd.) 7.0
Dimer dilinoleate di (isostearyl / phytosteryl) 5.0
(LUSPLAN PI-DA: Nippon Fine Chemical Co., Ltd.)
Trimethylolpropane triethylhexanoate (NS-308: Nippon Fine Chemical Co., Ltd.) 10.0
Diisostearyl malate Amount totaling 100 Tri (caprylic acid / capric acid) glyceryl 10.0
(Neosolve-MCT: Nippon Fine Chemical Co., Ltd.)
Triethylhexanoin (IOTG: Nippon Fine Chemical Co., Ltd.) 5.0
Squalene 7.0
Isotridecyl isononanoate 8.0
Triethylhexyl trimeritoate 3.0
Diisobutyl adipate 3.0
Diethyl sebacate 3.0
Ethylhexyl palmitate (Neosolue-IOP: Nippon Fine Chemical Co., Ltd.) 2.0
Microcrystalline wax 5.0
Polyethylene, Microcrystalline Wax Mixture 8.0
Methylparaben Appropriate amount Dehydroacetic acid Appropriate amount Titanium oxide Appropriate amount Red 214 Appropriate amount Red 214 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca / Al), titanium oxide, silica, tin oxide Appropriate amount －－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All components were heated to about 80 ° C., mixed uniformly and kneaded, and then cooled to room temperature.

Example 67 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 10.0
Microcrystalline wax 3.0
Paraffin 2.0
Ethylhexyl palmitate 5.0
Cyclopentasiloxane 2.0
Dimethicone 1.5
Mineral oil 2.0
Stearic acid 1.0
Stearyl alcohol 1.0
Setes-20 3.0
Sorbitan stearate 3.0
Polyoxypropylene sorbitol 3.0
Part B carboxyvinyl polymer 0.1
Vinylpyrrolidone-N, N-Dimethylaminoethyl Methacrylic Acid Copolymer Diethyl Sulfate 0.1
Purified water 10.0
Part C Polyethylene Glycol 90M 1.0
BG 2.0
Ethanol 2.0
Caprylyl glycol 0.5
Etidronic acid 0.1
Triethanolamine 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 68 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 10.0
Beeswax 3.0
Polyethylene wax 2.0
Ethylhexyl palmitate 5.0
Cetyl ethylcaproate 2.0
Vaseline 1.5
Mineral oil 2.0
Stearic acid 1.0
Stearyl alcohol 1.0
Setes-20 2.0
Sorbitan stearate 2.0
Polysorbate 60 1.0
PEG-250 1.0 distearate
Talc 1.0
Part B carboxyvinyl polymer 0.1
Vinylpyrrolidone-N, N-Dimethylaminoethyl Methacrylic Acid Copolymer Diethyl Sulfate 0.1
Purified water 10.0
Part C Polyethylene Glycol 1.0
Diglycerin 1.0
Glycerin 2.0
Caprylyl glycol 0.5
Triethanolamine 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 69 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 8.0
Sunflower seed wax 3.0
Polyethylene wax 2.0
Ethylhexyl palmitate 5.0
Isononyl isononanoate 2.0
Isopropyl myristate 2.0
Vaseline 1.5
Squalene 2.0
Hydroxystearic acid 1.0
Myristyl Alcohol 1.0
Setes-20 2.0
Sorbitan stearate 2.0
PEG-60 hydrogenated castor oil 1.0
PEG-250 1.0 distearate
Ethylhexyl glycerin 0.5
Part B carboxyvinyl polymer 0.1
Vinylpyrrolidone-N, N-Dimethylaminoethyl Methacrylic Acid Copolymer Diethyl Sulfate 0.1
Snow fungus polysaccharide (Tremost-TP: Nippon Fine Chemical Co., Ltd.) 0.1
Purified water 10.0
Part C Polyethylene Glycol 1.0
BG 5.0
Glycerin 2.0
Caprylyl glycol 0.5
Triethanolamine 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 70 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 10.0
Microcrystalline wax 3.0
Paraffin 2.0
Isododecane 5.0
Cyclopentasiloxane 2.0
12-Hydroxystearic acid 1.5
Didimethylsilylated silica 1.0
Dextrin palmitate 1.0
Mineral oil 2.0
Isostearic acid 1.0
Trimethylsiloxysilicic acid 1.0
Mica 3.0
Talc 1.0
Kaolin 1.0
Setes-20 3.0
Sorbitan stearate 3.0
Polysorbate-60 3.0
PEG-20 glyceryl isostearate 1.0
Part B carboxyvinyl polymer 0.1
Alkyl Methacrylic Acid Copolymer Acrylic Acid 0.1
Hyaluronic acid 0.1
Dimethyldiallyl ammonium chloride / acrylamide copolymer 0.1
Purified water 10.0
Part C Polyethylene Glycol 1.0
BG 2.0
Ethanol 2.0
Caprylyl glycol 0.5
Triethanolamine 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 71 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 23 10.0
Beeswax 3.0
Microcrystalline wax 2.0
Cetyl ethylcaproate 5.0
Cyclopentasiloxane 8.0
Dimethicone 1.5
Mineral oil 2.0
Stearic acid 1.0
Stearyl alcohol 1.0
Setes-20 2.0
Glyceryl stearate 2.0
Polysorbate -60 1.0
Lysine dilauroyl glutamate Na 0.3
Crystalline cellulose 1.0
Part B carboxyvinyl polymer 0.1
Acrylic Acid / Alkyl Acrylic Acid (C10-30) Copolymer 0.1
Purified water 10.0
Part C Polyethylene Glycol 1.0
Ethanol 5.0
Glycerin 2.0
Dextrin 0.2
Caprylyl glycol 0.5
Hydrolyzed soy protein 0.2
Triethanolamine 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 72 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 24 8.0
Polyethylene 3.0
Paraffin 3.0
Microcrystalline wax 2.0
Beeswax 2.0
Komenukarou 2.0
India Decane 5.0
Mineral oil 5.0
Ethylhexyl palmitate 3.0
Dodecane 2.0
Dimethicone 1.0
Stearic acid 2.0
Setes-10 2.0
Setes-15 3.0
Setes-6 2.0
Glyceryl stearate (SE) 2.0
Part B Hydroxyethyl Cellulose 0.1
(Acrylate / Alkyl acrylate (C1-18) / Alkyl (C1-8))
Acrylamide) Copolymer AMP 0.1
Purified water 10.0
Part C BG 3.0
Ethanol 5.0
EDTA-2Na 0.02
Phenoxyethanol 0.25
Methylparaben 0.05
Na hydroxide 0.25
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 73 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 24 10.0
Microcrystalline wax 5.0
Lanolin fatty acid octyldodecyl 2.0
Shea butter 1.0
Liquid lanolin 1.0
Meadowfoam oil 0.5
Dimethicone 3.0
Cetearyl alcohol 3.0
Glyceryl stearate 8.0
Polysorbate 80 4.0
Part B (alkyl acrylate / diacetone acrylamide) copolymer AMP 0.1
(Dimethylacrylamide / hydroxyethyl acrylate / methoxyethyl acrylate)
Copolymer 0.1
Hydroxyethyl cellulose 0.05
Carboxyvinyl polymer 0.05
Purified water 10.0
Part C Propylene Glycol 8.0
Ethanol 5.0
Aminomethyl propanol 2.0
Phenoxyethanol 0.2
Methylparaben 0.05
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 74 Gel-like hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 4.0
Fischer-Tropsch Wax 1.0
Cetearyl alcohol 1.0
PPG-1 Behenes-15 6.0
Lauroamphoacetate Na 3.0
Laureth-7 citric acid 2.0
Polyoxyethylene (60) Phytosterol 1.0
Part B Polyurethane-14 Acrylate Copolymer AMP 0.1
Acrylate / Methacrylic Acid Steareth-20 Cross Polymer 0.1
(Vinylpyrrolidone / VA) Copolymer 0.1
Vinyl acetate / vinylpyrrolidone copolymer 0.05
(Na acrylate / Na acryloyl dimethyl taurine) Copolymer 0.05
Hydroxyethyl cellulose 0.05
Xanthan gum 0.05
Purified water 10.0
Part C BG 8.0
Ethanol 5.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(Neosolue-Aquio: Nippon Fine Chemical Co., Ltd.)
Isostearoyl hydrolyzed silk 0.1
Na hydroxide 0.3
Phenoxyethanol 0.2
Methylparaben 0.05
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 75 Hair Treatment

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 0.5
Cyclohexanedicarboxylic acid bisethoxydiglycol 0.2
(Neosolue-Aquio: Nippon Fine Chemical Co., Ltd.)
Dimethicone 0.3
Cetyl ethylhexanoate 1.0
γ-docosalactone, tri (caprylic acid / capric acid) glyceryl (Elcalactone MCT: Nippon Fine Chemical Co., Ltd.) 2.0
Cetearyl alcohol 3.5
Dextrin palmitate 0.2
PEG-200 0.5
Behenic acid dimethylaminopropylamide 0.2
Setrimonium chloride (30%) 1.0
Behentrimonium chloride (80%) 1.0
Trideces-6 0.3
BHT 0.03
Part B Ceramide 1, Ceramide 2, Ceramide 3, Ceramide 5, Ceramide 6, Cholesterol,
Quotanium-33-containing composition (NanoRepair-CMC5: Nippon Fine Chemical Co., Ltd.)
5.0 5.0
Hydroxyethyl cellulose 0.4
Snow fungus polysaccharide (Tremost-TP: Nippon Fine Chemical Co., Ltd.) 0.02
(Acryloyldimethyltaurine ammonium / VP) copolymer 0.02
BG 1.8
Glycerin 4.0
Methylparaben 0.2
Citric acid 0.05
Amount of purified water totaling 100 Part C Isododecan 0.2
PPG-3 Caprylyl Ether 0.5
Panthenol 0.1
Isodecyl neopentate 1.0
(DUB VIC-10: Nippon Fine Chemical Co., Ltd.)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A and mixed uniformly. Part C was added with stirring at about 50 ° C. to make it uniform.

Example 76 Shampoo

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 0.2
Ethylhexyl palmitate (Neosolue-IOP: Nippon Fine Chemical Co., Ltd.) 0.2
Ethylhexyl sebacate (Neosolue-EHS: Nippon Fine Chemical Co., Ltd.) 1.0
Oleic acid 0.2
Part B Ammonium Laureth Sulfate 5.0
Sodium Laureth Sulfate (25%) 10.0
Cocoyl Glutamic Acid TEA (30%) 3.0
Lauryl hydroxysultaine (30%) 7.0
Lauric acid K 1.0
Glycol distearate 0.5
Stearoxypropyl dimethylamine 0.5
PPG-17 0.3
Neopentyl glycol diethylcaproate 0.4 0.4
Lanolin fatty acid 0.3
Isodecyl glyceryl ether 0.4
Cocamide MEA 1.0
Laureth-4 0.3
Laureth-16 0.2 0.2
Stairless-6 0.2
Miconazole nitrate 0.75
Phenoxyethanol 0.3
Part C Sorbitol 1.6
Methylparaben 0.2
EDTA-2Na 0.05
Phosphoric acid 0.03
Na 0.3 benzoate
Amount of purified water totaling 100 Part D Polyquaternium-10 0.2
Guar hydroxypropyltrimonium chloride 0.1
Snow fungus polysaccharide (Tremost-TP: Nippon Fine Chemical Co., Ltd.) 0.02
Purified water 6.7
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A and part B, which had been mixed in advance, were uniformly mixed at about 80 ° C. (part E). Part C, which was set aside separately, was heated to about 60 ° C. to make it uniform. Part C was gradually added to part E with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part D was added and mixed uniformly.

Example 77 Emulsion

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 2.0
Di-lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
(Plandol-LG3: Nippon Fine Chemical Co., Ltd.) 2.0
Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
(Plandol-H: Nippon Fine Chemical Co., Ltd.) 2.0
Bisdiglyceryl Polyacyl Adipate-2 1.0
(Plandol-DP: Nippon Fine Chemical Co., Ltd.)
Macademia nut oil fatty acid phytosteryl 1.0
(Plandol-MAS: Nippon Fine Chemical Co., Ltd.)
Cetyl ethylcaproate (NS-CIO: Nippon Fine Chemical Co., Ltd.) 5.0
Cetanol 1.2
Phenyltrimethicone 3.0
Ethylparaben 0.1
Isopropyl myristate 3.0
Mineral oil 2.0
Hydrogenated polyisobutene 1.0
Part B Stearoxy hydroxypropyl Methyl Cellulose 0.1
Xanthan gum 0.1
Purified water 20.0
Part C Hydrogenated Lecithin, Phytosterols 1.0
(Phytocompo-PP: Nippon Fine Chemical Co., Ltd.)
Pentylene Glycol 3.0
Glycerin 8.0
Part D 3-O-ethylascorbic acid (VC ethyl: Nippon Fine Chemical Co., Ltd.) 1.0
Arbutin (Nippon Fine Chemical Co., Ltd.) 1.0
Purified water 5.0
Part E Phenoxyethanol 0.2
Methylparaben 0.15
Phytic acid 0.5
Citric acid 0.1
Amount of sodium citrate pH 4.5 Amount of purified water totaling 100 ------------- −−−−−−
(Preparation method)
Parts A and E were each heated to about 70 ° C. and uniformly dissolved. Part B was stirred to obtain a viscous liquid. Part C was heated to about 70 ° C. and uniformly dispersed. After adding the A part while stirring the C part with a homodisper, the E part was added while stirring. Parts D and B were added at about 50 ° C., and the mixture was stirred and uniformly dissolved.

Example 78 Skin care cream

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 2.0
Di lauroyl glutamate (phytosteryl / octyldodecyl)
(Plandol-LG2: Nippon Fine Chemical Co., Ltd.) 2.0
Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
(Plandol-H: Nippon Fine Chemical Co., Ltd.) 2.0
Squalene 8.0
Stearic acid 1.0
Phytosteryl isostearate 1.0
(Plandol-ISS: Nippon Fine Chemical Co., Ltd.)
Macademia nut oil 3.0
Hydrogenated jojoba alcohol 2.0
Olive oil fatty acid cetearyl 1.0
Olive oil fatty acid sorbitan 0.8
Polyglyceryl oleate-10 1.0
Polyglyceryl laurate-10 0.5
Part B Acrylic acid / alkyl methacrylate copolymer 0.1
Hydroxide K 0.07
Hydroxyethyl Acrylate / Acryloyl Dimethyl Taurine Na) Copolymer 0.05
(Acryloyldimethyltaurine ammonium /
Behenes Methacrylic Acid-25) Cross Polymer 0.05
Snow fungus polysaccharide (Tremost-TP: Nippon Fine Chemical Co., Ltd.) 0.02
Purified water 10.0
Hydrolyzed polyγ-glutamic acid K 0.1
Sodium polyglutamate 0.1
Oligopeptide-24 0.05
Part C (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, glycerin (Neosolue-Aqua: Nippon Fine Chemical Co., Ltd.) 1.0
Tranexamic acid (Nippon Fine Chemical Co., Ltd.) 1.0
Mannosyl Erythritol Lipid 0.2
Diglycerin 5.0
Propane Glycol 3.0
PEG-8 2.0
Sodium metabisulfite 0.03
Methylparaben 0.1
Phenoxyethanol 0.3
Amount of purified water totaling 100 -------------
(Preparation method)
Parts A and C were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part B was mixed and stirred to obtain a viscous liquid. Part C was added while stirring with a homomixer, and part A was emulsified. After cooling, part B was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 79 Cleansing Cream

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 5.0
Di lauroyl glutamate (phytosteryl / octyldodecyl)
(Plandol-LG2: Nippon Fine Chemical Co., Ltd.) 2.0
Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl /
Behenil) (Plandol-S: Nippon Fine Chemical Co., Ltd.) 2.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(Neosolue-Aquio: Nippon Fine Chemical Co., Ltd.)
Diisostearyl malate 6.0
Mineral oil 23.0
Diethylhexyl sebacate 10.0
PEG-25 hydrogenated castor oil 3.0
PEG-20 glyceryl triisostearate 4.0
PEG-12 isostearate 3.0
Sorbitan sesquioleate 1.5
Polyoxyethylene sorbitan oleate 0.3
Polyglyceryl stearate-6 0.5
Glyceryl stearate 1.0
Microcrystalline wax 2.0
Tocopherol 0.05
Propylparaben 0.05
Part B (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, glycerin (Neosolue-Aqua: Nippon Fine Chemical Co., Ltd.) 1.0
Diglycerin 3.0
DPG 5.0
Methylparaben 0.05
Edetonic acid 3Na 0.02
Phenoxyethanol 0.2
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was weighed and heated to about 80 ° C. to dissolve. Weigh part B and heat to about 80 ° C. Part B was gradually added to part A with stirring, and after mixing, the mixture was cooled to 40 ° C.

Example 80 Facial cleansing foam

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 0.5
Di lauroyl glutamate (phytosteryl / octyldodecyl)
(Plandol-LG2: Nippon Fine Chemical Co., Ltd.) 2.0
Stearic acid K 10.0
Palmitic acid K 10.0
Myristic acid K 10.0
Lauric acid K 4.0
Lauroyl sarcosine isopropyl 0.8
PEG1500 10.0
Glycerin 15.0
Glyceryl monostearate 1.0
POE (20) Sorbitan Monostearate 2.0
Part B White fungus polysaccharide (Tremost-TP: Nippon Fine Chemical Co., Ltd.) 0.02
Hydroxypropyl Methyl Cellulose 0.05
Tuberose polysaccharide 0.05
Cationized guar gum 0.05
Polyquaternium-7 0.5
Polyquaternium-39 0.5
Methylparaben 0.1
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was weighed and heated to about 80 ° C. to dissolve. Weigh part B and heat to about 80 ° C. Part B was gradually added to part A with stirring, and after mixing, the mixture was cooled to 40 ° C.

Example 81 Hair manicure

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 0.8
Ethanol 10.0
Setes-10 1.0
γ-Docosalactone, diethyl sebacate (Elcalactone DES: Nippon Fine Chemical Co., Ltd.) 2.5
Hydrogenated polyisobutene 1.0
Behenes-10 1.0
Trideces-9 0.5
Dicapric acid PG 0.5
Dicaprilyl Carbonate 0.5
Part B Purple 401 0.2
Black 401 0.1
Orange 205 0.1
Red 102 0.1
Citric acid 2.0
Benzyl alcohol 8.0
Ethanol 10.0
Part C Purified water Amount totaling 100 (hydroxyethyl acrylate / acryloyldimethyltaurine Na) copolymer
0.2 0.2
(Acryloyldimethyltaurine ammonium / VP) copolymer 0.3
Glycolic acid 2.0
Hydroxypropyl xanthan gum 0.2
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and C were mixed and made uniform. After adding to the B part with stirring and adding to the C part and mixing uniformly, the A part was added at about 60 ° C. and mixed uniformly.

Example 82 Lipstick

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Wax-like composition of Example 15 10.0
Dimari Linoleic Acid Dimari Linole 5.0
(LUSPLAN DD-DA7: Nippon Fine Chemical Co., Ltd.)
Pentaerythrityl tetraisostearate A total amount of 100 di (phytosteryl / octyldodecyl) lauroyl glutamate
(Plandol-LG2: Nippon Fine Chemical Co., Ltd.) 2.0
Macademia nut oil fatty acid phytostile (Plandol-PM: Nippon Fine Chemical Co., Ltd.) 3.0
Isopropyl myristate 3.0
Cyclomethicone 10.0
Methyl Phenyl Polysiloxane 9.0
Didimethylsilylated silica 5.0
Synthetic wax 5.0
Sorbitan sesquiisostearate 4.0
Tocopherol 0.5
Iron oxide 2.0
Titanium oxide 2.0
Mica 1.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All the components were uniformly heated, stirred and mixed, then filled in a mold and rapidly cooled.

Example 83 Solid powder foundation

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 15 5.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandol-G: Nippon Fine Chemical Co., Ltd.) 1.0
Di-lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
(Plandol-LG1: Nippon Fine Chemical Co., Ltd.) 7.0
Dimer dilinoleate di (isostearyl / phytosteryl) 5.0
(LUSPLAN PI-DA: Nippon Fine Chemical Co., Ltd.)
Sunflower Seed Oil Fatty Acid Phytosteryl 2.0
(Plandol-SUN: Nippon Fine Chemical Co., Ltd.)
Hydrogenated polyisobutene 5.0
(Icosanedioic acid / tetradecanedioic acid) Polyglyceryl-10, glycerin (Neosolue-Aqua: Nippon Fine Chemical Co., Ltd.) 1.0
Perfluoropolyether 5.0
Part B Silicone treated sericite 60.0
Titanium oxide 10.0
Powdered synthetic hydrocarbon wax 1.0
Yellow iron oxide 1.0
Bengala 0.5
Methylparaben 0.5
Black iron oxide 0.05
Amount of talc totaling 100 －－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
A part is heated and mixed. Take part B in a separate container and mix and disperse (part B). Add part A to part B and mix evenly.

Example 84 Sunscreen cosmetics

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 1.0
BG 10.0
Glycerin 9.0
Part B Wax-like composition of Example 15 1.0
Octocrylene 4.0
Octyl salicylate 4.0
Diethylaminohydroxybenzoyl hexyl benzoate 2.25
t-Butylmethoxydibenzoylmethane 1.0
Ethylhexyl sebacate (Nippon Fine Chemical Co., Ltd.) 3.0
Pentaerythrityl tetraethylhexanoate (Nippon Fine Chemical Co., Ltd.) 2.0
Isopropyl sebacate (IPSE: Nippon Fine Chemical Co., Ltd.) 1.0
Behenyl alcohol 2.0
Cetearyl alcohol 2.0
Macademia Nut Oil Fatty Acid Phytostile 3.0
(Plandol-MAS: Nippon Fine Chemical Co., Ltd.)
Tocopherol 0.05
Part C (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, glycerin (Neosolue-Aqua: Nippon Fine Chemical Co., Ltd.) 1.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 1.0
(Neosolue-Aquio: Nippon Fine Chemical Co., Ltd.)
Methylparaben 0.2
Amount of water totaling 100 Part D Carbomer (2%) 5.0
Na Hydroxide 0.05
Snow fungus polysaccharide (Tremost-TP: Nippon Fine Chemical Co., Ltd.) 0.02
Water dispersion titanium oxide 5.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Disperse part A evenly. Parts B and C are each heated and dissolved at about 70 ° C. After gradually adding the B part to the A part, the C part is gradually added and emulsified. Cool while stirring, add part D at 45 ° C, and stir.

Example 85 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 33 8.0
Phytosteryl isostearate 1.0
(Plandol-ISS: Nippon Fine Chemical Co., Ltd.)
Siethylhexyl succinate 1.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandol-G: Nippon Fine Chemical Co., Ltd.) 9.0
Tori Hydrogenated Rosin Lyceryl 1.0
Ethylhexyl methoxycinnamate 5.0
Cholesterol 0.5
Diethyl sebacate 2.0 2.0
Setes-7 1.0
Dimethicone 3.0
Glycol distearate PEG-150 5.0
Part B Glycerin 5.0
Polyethylene glycol 5.0
Phenoxyethanol 0.6
Methylparaben 0.2
Hydrolyzed keratin 0.02
Amount of purified water totaling 100 parts C (Acrylate / Methacrylic acid steareth-20) copolymer 2.0
(Alkyl acrylate / Diacetone acrylamide) Copolymer AMP0.1
Carbomer 0.1
Purified water 20.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled (part D). Part C was added to part D and mixed uniformly.

Example 86 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 33 13.0
Sunflower Seed Oil Fatty Acid Phytosteryl 2.0
(Plandol-SUN: Nippon Fine Chemical Co., Ltd.)
Dimari Linoleic Acid Dimari Linole 2.7
(LUSPLAN DD-DA7: Nippon Fine Chemical Co., Ltd.)
Tori Hydrogenated Rosin Riseryl 0.3
Bisdiglyceryl Polyacyl Adipate-2 5.0
(Plandol-DP: Nippon Fine Chemical Co., Ltd.)
Triethylhexanoin (IOTG: Nippon Fine Chemical Co., Ltd.) 3.0
PEG-40 hydrogenated castor oil 1.0
Stairless-30 1.0
γ-docosalactone, cyclopentasiloxane, diethyl sebacate, ethanol (Elcalactone SIL: Nippon Fine Chemical Co., Ltd.) 1.0
Komenukarou 2.0
Glyceryl stearate 1.0
Dimethicone 3.0
Siethylhexyl succinate 5.0
Setes-2 0.5
Setes-20 2.5
BHT 0.05
Phenoxyethanol 0.6
Methylparaben 0.2
Part B BG 3.0
Na Hydroxide 0.5
(Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer 0.1
(Alkyl acrylate / Diacetone acrylamide) Copolymer AMP 0.1
Carbomer 0.5
Amount of purified water totaling 100 -------------
(Preparation method)
Parts A and B were taken, heated to about 80 ° C., and mixed uniformly. Part B was gradually added to part A with stirring, mixed uniformly, and then cooled.

Example 87 Hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 33 10.0
Microcrystalline wax 5.0
Lanolin fatty acid octyldodecyl 2.0
Shea butter 1.0
Liquid lanolin 1.0
Meadowfoam oil 0.5
Dimethicone 3.0
Cetearyl alcohol 3.0
Glyceryl stearate 8.0
Polysorbate 80 4.0
Part B (alkyl acrylate / diacetone acrylamide) copolymer AMP 0.1
(Dimethylacrylamide / hydroxyethyl acrylate / methoxyethyl acrylate)
Copolymer 0.1
Hydroxyethyl cellulose 0.05
Carboxyvinyl polymer 0.05
Purified water 10.0
Part C Propylene Glycol 8.0
Ethanol 5.0
Aminomethyl propanol 2.0
Phenoxyethanol 0.2
Methylparaben 0.05
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Example 88 Gel-like hair wax

Composition amount (% by weight)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Wax-like composition of Example 33 4.0
Fischer-Tropsch Wax 1.0
Cetearyl alcohol 1.0
Diethylhexyl succinate 2.0
Glyceryl stearate 2.0
Polyoxyethylene (60) Phytosterol 1.0
Polysorbate-60 6.0
Part B Polyurethane-14 Acrylate Copolymer AMP 0.1
Acrylate / Methacrylic Acid Steareth-20 Cross Polymer 0.1
(Vinylpyrrolidone / VA) Copolymer 0.1
Vinyl acetate / vinylpyrrolidone copolymer 0.05
(Na acrylate / Na acryloyl dimethyl taurine) Copolymer 0.05
(Alkyl acrylate / Diacetone acrylamide) Copolymer AMP 0.1
Hydroxyethyl cellulose 0.05
Xanthan gum 0.05
Purified water 10.0
Part C BG 8.0
Ethanol 5.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(Neosolue-Aquio: Nippon Fine Chemical Co., Ltd.)
Isostearoyl hydrolyzed silk 0.1
Na hydroxide 0.3
Phenoxyethanol 0.2
Methylparaben 0.05
Amount of purified water totaling 100 -------------
(Preparation method)
Part A was uniformly mixed while stirring at 80 ° C. Part B was placed in a separate container to prepare a viscous liquid. Part C was placed in a separate container and dissolved uniformly. Part C was added to part A at 80 ° C. with stirring and emulsified. After emulsification, it was cooled to about 50 ° C., and then the B part was mixed and made uniform.

Claims (6)

The following components (A) and (B);
(A) including both dimer acid and dimer diol as a constituent unit,
Polyester with a weight average molecular weight of 30,000 to 1,000,000 (B) One or more waxes selected from the group consisting of the following (B1) to (B3) (B1) Carnauba wax, sunflower seed wax, rice bran wax, wood wax , Honey wax, lanolin, hard lanolin, montan wax, hydrogenated jojoba oil, behenyl behenate, ester wax selected from glyceryl tribechenate (B2) Celesin, paraffin wax, microcrystallin wax, Fishertropsh wax, polyethylene wax The hydrocarbon wax (B3) is a solid higher alcohol or higher fatty acid selected from cetyl alcohol, stearyl alcohol, behenyl alcohol, phytosterol, cholesterol, palmitic acid, bechenic acid, 12-hydroxystearic acid, lanolin fatty acid, and hard lanolin fatty acid. A wax-like composition for cosmetics containing <br />, wherein the content of (A) is 5 to 50% by weight, and the content of (B) is 50 to 95% by weight. The component (B) is composed of three or more kinds of waxes selected from the group consisting of (B1) to (B3), and is characterized by being a wax containing at least one kind of each of (B1) to (B3). The waxy composition according to claim 1. The content of the component (A) is 5 to 30% by weight, the content of the component (B1) is 15 to 40% by weight, the content of the component (B2) is 30 to 75% by weight, and the content of the component (B3) is. The waxy composition according to claim 2 , wherein the waxy composition is 5 to 30% by weight. A cosmetic comprising the waxy composition according to any one of claims 1 to 3. A hair styling product containing the waxy composition according to any one of claims 1 to 3. A make-up cosmetic comprising the waxy composition according to any one of claims 1 to 3.