JP2018123117A - Waxy composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a waxy composition for providing setting properties and resetting properties in a hair dressing agent and providing adhesiveness in a makeup cosmetic, which can be alternative of candelilla wax.SOLUTION: There is provided a waxy composition which comprises the following components (A) and (B): (A) a polyester having a weight average molecular weight of 30000 to 1000000 which contains one or both of a dimer acid and a dimer diol as a constitutional unit and (B) one or two or more waxes selected from the group consisting of the following (B1) to (B3): (B1) an ester wax, (B2) a hydrocarbon wax and (B3) a solid higher alcohol or a solid higher fatty acid, wherein the content of (A) is 5 to 50 wt.% and the content of (B) is 50 to 95 wt.%.SELECTED DRAWING: None

Description

  The present invention comprises a polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of component (A) dimer acid and dimer diol as a constituent unit, and component (B) wax. The present invention relates to a composition and a cosmetic containing the wax-like composition.

  Waxes are used in a wide range of applications in cosmetics. For example, in makeup cosmetics such as lipsticks and foundations, emulsions, creams, washings are used for the purpose of solidifying dosage forms, adjusting hardness and viscosity, forming films, and imparting gloss. In the case of skin cosmetics such as preparations, for the purpose of improving the feeling of use and suppressing moisture transpiration due to film formation, in the case of hair cosmetics such as shampoos, treatments, and hair styling, the hardness and viscosity of the dosage form, hair protection, and hair styling properties It is used for the purpose of granting.

  In general, hair styling materials are required to improve re-setting (arrangement) in addition to initial setting (keeping force). In addition, makeup cosmetics are required to maintain a beautiful finish by improving the adhesion of powder and the like to the skin. For this reason, in hair styling and makeup cosmetics, it is desired that the wax component also has such a function. Among wax components commonly used in cosmetics, candelilla wax contains more resin components than other natural waxes, and since this resin component has strong adhesiveness, the setability, resettability, and adhesion described above It is known as a wax capable of imparting a function such as sexuality, and is preferably used in hair styling products and makeup cosmetics (Patent Documents 1 to 4). However, candelilla grass, which is a raw material for candelilla wax, has problems such as weather instability, supply instability due to increased demand, and price increases, and the replacement of candelilla wax is desired.

  Patent Document 5 discloses a cosmetic containing a polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of a dimer acid and a dimer diol as a structural unit. In addition, there is no build-up property, the same feel as a silicone compound, the effect of improving gloss, the improvement of combing properties of hair, and the effect of suppressing the occurrence of split ends by brushing can increase the viscosity of oil in makeup cosmetics. It is possible to reduce the amount or not to use the oil gelling agent and to describe the effect of imparting flexibility to the skin. However, functions such as setability, resetability, and adhesion are not described. Further, since the polyester has a very high viscosity and is difficult to handle, it is described that the polyester is diluted with a liquid oil for handling. However, even if diluted to some extent, the viscosity remains the same, so handling is not easy, and there is a drawback that it is difficult to use in applications where liquid oil is not desired.

JP 2009-209103 A JP 2010-270024 A JP 2000-327524 A JP 11-060438 A JP 2014-009259 A

  It is an object of the present invention to provide a wax-like composition that can be used as a substitute for candelilla wax, which is a wax-like composition that imparts setting properties and resetting properties in hairdressing products and adhesion in makeup cosmetics.

As a result of intensive studies to solve the above-mentioned problems, the present inventors contain the following components (A) and (B), the content of (A) is 5 to 50% by weight, and the content of (B) The present invention has been completed by finding that a wax-like composition characterized in that the content of is from 50 to 95% by weight solves the above problems.

(A) including one or both of dimer acid and dimer diol as a structural unit,
Polyester having a weight average molecular weight of 30,000 to 1,000,000 (B) One or more waxes selected from the group consisting of the following (B1) to (B3) (B1) Ester wax (B2) Hydrocarbon wax (B3 ) Solid higher alcohol or higher fatty acid

  The wax-like composition of the present invention has an effect of imparting setting properties and resetting properties in hair styling, and adhesion in makeup cosmetics, in addition to the function as a general wax. For this reason, it can be preferably used as an alternative to candelilla wax. Moreover, since the wax-like composition of this invention can be processed into various shapes, such as a granular form, a granular form, flake shape, and plate shape, handling is easy.

  The wax-like composition of the present invention contains a polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of component (A) dimer acid and dimer diol as a constituent unit, and component (B) wax. Features.

  In the present invention, the wax form is a solid form that is not fluid at room temperature and has almost no flexibility, and has a hardness that can be processed into various forms such as granules, granules, flakes, and plates. Say.

  The polyester containing one or both of the dimer acid and dimer diol of the component (A) used in the present invention as a constituent unit is produced using the dimer acid and dimer diol described below as raw materials.

  Dimer acid is a known dibasic acid obtained by the intermolecular polymerization reaction of unsaturated fatty acids, and its industrial production process is almost standardized in the industry. For example, dimer acid or / and its lower alcohol ester is carbon It is obtained by dimerizing an unsaturated fatty acid having a number of 11 to 22 or a lower alcohol ester thereof with a clay catalyst or the like. The dimer acid obtained industrially is mainly composed of a dibasic acid having about 36 carbon atoms, but contains an arbitrary amount of trimer acid and monomer acid depending on the degree of purification. In general, dimer acid content exceeding 70% by weight and dimer acid content increased to 90% by weight or more by molecular distillation are in circulation. In addition, although a double bond remains after the dimerization reaction, a dimer acid that is further hydrogenated to improve oxidation stability, that is, a hydrogenated dimer acid is also on the market. For the production of the polyester of the present invention, any dimer acid currently in circulation can be used, but hydrogenated dimer acid is more preferable from the viewpoint of oxidation stability. In addition, those derived from animal oils and fats and vegetable oils are distributed among these dimer acids, but those derived from vegetable oils and fats are more preferable. As such dimer acid, for example, PRIPOL 1006, 1009, 1015, 1025 of Croda, etc. are commercially available.

  The dimer diol is mainly composed of a diol having about 36 carbon atoms in which the dimer acid or / and lower alcohol ester thereof is hydrogenated in the presence of a catalyst and the carboxylic acid portion of the dimer acid is an alcohol. Depending on the degree of purification of dimer acid or / and its lower alcohol ester used as a raw material, industrially obtained dimer diol may contain other components such as trimer triol, monomer alcohol and ether compound. Products with dimer diol content exceeding about 70% by weight, and those with further dimer diol content exceeding 90% by weight, etc. are in circulation. Either can be used. Regarding dimer diol, those derived from animal fats and oils and vegetable fats and oils are distributed, but those derived from vegetable fats and oils are preferable. As such a dimer diol, PRIDO 2033 of Croda etc. can be obtained as a commercial item.

  The polyester containing one or both of dimer acid and dimer diol used as a constituent unit in the present invention is an ester of dimer acid and divalent alcohol other than dimer diol, divalent carboxylic acid other than dimer diol and dimer acid. And one or more compounds selected from esters of dimer acid and dimer diol.

  As the divalent alcohol other than the dimer diol used in the present invention, a saturated linear, branched, ring-containing or cyclic divalent alcohol having 2 to 24 carbon atoms is preferable. Specifically, ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 1,2-butanediol, 1,5-pentanediol, 1,2- Pentanediol, neopentyl glycol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, 1,2-hexanediol, 2,5-hexanediol, hexylene glycol, 3-methyl-1 , 5-pentanediol, 1,7-heptanediol, 2,2-diethyl-1,3-propanediol, 2,2,4-trimethyl-1,5-pentanediol, 1,8-octanediol, 2- Butyl-2-ethyl-1,3-propanediol, 1,9-nonanediol, 1,8-nonanediol, 2,4-die 1,5-pentanediol, 1,10-decanediol, 1,11-undecanediol, 1,10-undecanediol, 1,12-dodecanediol, 1,2-dodecanediol, 1,13-tridecanedi All, 1,14-tetradecanediol, 1,2-tetradecanediol, 1,16-hexadecanediol, 1,2-hexadecanediol, 1,18-octadecanediol, 1,2-octadecanediol, 1,12-octadecanediol 9-octadecene-1,12-diol, 1,20-icosanediol, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, 1,3-cyclohexanedimethanol, 1,2-cyclohexanedimethanol, Isosorbide, a sorbitol dehydrate Diethylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol, polypropylene glycol, and the like. Among these, ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 1,5-pentanediol from the viewpoint of availability and feel of the resulting ester , Neopentyl glycol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, hexylene glycol, 3-methyl-1,5-pentanediol, 2,2-diethyl-1,3- Propanediol, 2,2,4-trimethyl-1,5-pentanediol, 1,8-octanediol, 2-butyl-2-ethyl-1,3-propanediol, 2,4-diethyl-1,5- Pentanediol, 1,10-decanediol, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, iso Rubaido like can be mentioned as preferable.

  As the divalent carboxylic acid other than the dimer acid used in the present invention, a saturated linear, branched or ring-containing divalent carboxylic acid having 4 to 24 carbon atoms is preferable. Specifically, malonic acid, succinic acid, glutaric acid, adipic acid, 3-methylpentanedioic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid , Hexadecanedioic acid, octadecanedioic acid, icosanedioic acid, dimethylicosanedioic acid, docosanedioic acid, cyclohexanedicarboxylic acid, malic acid, tartaric acid and the like. Among these, succinic acid, glutaric acid, adipic acid, 3-methylpentanedioic acid, azelaic acid, sebacic acid, dodecanedioic acid, tetradecanedioic acid, hexadecanedioic acid from the viewpoint of availability and feel of the resulting ester , Octadecanedioic acid, icosanedioic acid, dimethylicosanedioic acid, cyclohexanedicarboxylic acid and the like are preferable.

  It is most preferable to use a polyester containing both dimer acid and dimer diol as constituent units in terms of exhibiting the effects of the present invention most. Even in such a case, a divalent carboxylic acid other than dimer acid and a divalent alcohol other than dimer diol may be included as a structural unit.

  The polyester of component (A) in the present invention is a compound whose terminal is an alcohol or a carboxylic acid. The polyester of the present invention may further be esterified with a monovalent carboxylic acid or alcohol at the terminal. Further, when the terminal is a carboxylic acid, it may be in the form of a neutralized salt. Examples of salts include alkali metal salts such as sodium and potassium, alkaline earth metal salts such as calcium and magnesium, metal salts such as aluminum, iron, zinc, copper and cobalt, basic amino acid salts such as lysine and arginine, triethylamine, Examples include organic amine salts such as stearylamine.

  The polyester of component (A) in the present invention has a weight average molecular weight of 30,000 to 1,000,000, more preferably 70,000 to 500,000. The weight average molecular weight of the polyester of the present invention can be adjusted by changing the charging ratio of the divalent carboxylic acid to be reacted and the divalent alcohol. As the reaction ratio of the polyester of the present invention, when the terminal is an alcohol, the divalent carboxylic acid is used in an amount of 0.85 to 1.0 mol, more preferably 0.95 to 1 mol of the divalent alcohol. 1.0 mole. When the terminal is a carboxylic acid, the amount of the divalent alcohol is 0.85 to 1.0 mol, more preferably 0.95 to 1.0 mol, with respect to 1 mol of the divalent carboxylic acid.

  Since the polyester of component (A) in the present invention has a very high viscosity and strong adhesiveness, it has an effect of imparting functions such as setting properties, resetting properties, and adhesiveness. On the other hand, since it becomes a glassy material having almost no fluidity at room temperature, handling such as subdivision and weighing is difficult at room temperature. Since the polyester of component (A) is excellent in compatibility with various oils, it can be uniformly diluted with liquid oil, and in this way, it can be handled in a fluid state even at room temperature. However, the composition obtained is a highly viscous liquid oil, and handling is not necessarily simple. In addition, it is difficult to use in applications where liquid oil is not desired.

Component (B) in the present invention is one or more waxes selected from the group consisting of the following (B1) to (B3). These may be used alone or in combination of two or more.
(B1) Ester wax (B2) Hydrocarbon wax (B3) Solid higher alcohol or higher fatty acid

  The component (B) in the present invention is not particularly limited as long as the composition becomes waxy when mixed with the component (A). Specifically, the component (B1) includes carnauba wax. Sunflower seed wax, rice bran wax, tree wax, beeswax, lanolin, hard lanolin, montan wax, hydrogenated jojoba oil, behenyl behenate, glyceryl tribehenate, and the like. Examples of the component (B2) include ceresin, paraffin wax, microcrystalline wax, Fischer-Tropsch wax, and polyethylene wax. Examples of the component (B3) include cetyl alcohol, stearyl alcohol, behenyl alcohol, phytosterol, cholesterol, palmitic acid, stearic acid, behenic acid, 12-hydroxystearic acid, lanolin fatty acid, and hard lanolin fatty acid.

  The content of the component (A) in the wax-like composition in the present invention is 5 to 50% by weight, more preferably 10 to 40% by weight. If the content of the component (A) is small, the effects of the present invention such as setting property, resetting property and adhesion will not be sufficiently achieved, and if the content of the component (A) is large, the composition will not be waxy. The content of the component (B) in the waxy composition is 50 to 95% by weight, more preferably 60 to 90% by weight. By mixing component (B) with component (A) in such a range, the composition becomes waxy and can be processed into various shapes such as granules, granules, flakes, and plates, Handling becomes easy.

  Since the wax-like composition of the present invention has functions similar to the functions unique to the candelilla wax, such as setting properties, resetting properties, and adhesion, it can be preferably used as an alternative to the candelilla wax. Depending on the type of component (B), it may be different from candelilla wax in terms of physical properties such as hardness and melting point, but it can be used without any problem for the purpose of substituting functional aspects. On the other hand, the composition of candelilla wax is 15 to 25% resin component, 20 to 30% ester wax, 40 to 50% hydrocarbon wax, 15 to 25% higher alcohol and higher fatty acid. It is known to contain. Accordingly, as the waxy composition of the present invention, the component (A) is substituted for the resin component, the component (B1) is substituted for the ester wax, the component (B2) is substituted for the hydrocarbon wax, the higher alcohol and the higher fatty acid. By using component (B3) instead of, it is possible to resemble the candelilla wax not only in terms of function but also in terms of physical properties. Therefore, if such a wax-like composition of the present invention is used, the candelilla wax in the formulation can be replaced with the wax-like composition of the present invention as it is.

As the wax-like composition of the present invention that can replace both functions and physical properties, a wax-like composition containing the following components (A) and (B) is preferable.

(A) including one or both of dimer acid and dimer diol as a structural unit,
Polyester having a weight average molecular weight of 30,000 to 1,000,000 (B) consisting of three or more waxes selected from the group consisting of the following (B1) to (B3), wherein (B1) to (B3) are each at least one or more (B1) ester wax (B2) hydrocarbon wax (B3) solid higher alcohol or higher fatty acid

In the above waxy composition, (B1) to (B3) may be those exemplified above. Further, the content of the (B1) to (B3) in the wax-like composition is not particularly limited, but the content of the component (A) is 5 to 30 in that it is more similar to the candelilla wax in terms of physical properties. The content of component (B1) is 5 to 40 wt%, the content of component (B2) is 30 to 85 wt%, and the content of component (B3) is 5 to 30 wt%. Preferably, the content of the component (A) is 10 to 25% by weight, the content of the component (B1) is 10 to 35% by weight, the content of the component (B2) is 35 to 75% by weight, and the component (B3) The content may be 5 to 25% by weight.

  Components other than components (A) and (B) can be added to the wax-like composition of the present invention within a range that maintains the wax-like shape and does not impair the effects of the present invention. The component that can be added is not particularly limited as long as it is a component that is usually used in cosmetics. For example, components that enhance adhesion, antioxidants, oil agents, oil-soluble moisturizing components, oil-soluble gelation Agents, branched fatty acids, branched alcohols, nonionic surfactants and the like. Examples of components that enhance adhesion include rosin, hydrogenated rosin, rosin acid, hydrogenated rosin acid, glyceryl rosin acid, glyceryl hydrogenated rosin acid, pentaerythrityl rosin acid, hydrogenated pentaerythrityl rosin acid, trihydrogenated A rosin such as glyceryl rosinate, (diisostearic acid / hydrogenated rosin acid), dimer dilinoleyl hydrogenated rosin condensate or a derivative thereof can be preferably used. As antioxidant, what is normally added to oily bases, such as tocopherols, BHT, BHA, can be used preferably. Oils include hydrogenated polyisobutene, polybutene, squalane, petrolatum and other hydrocarbon oils; diisostearyl malate, palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, macadamia nut Oil, rosehip oil, meadow foam oil, persic oil, rapeseed oil, sunflower oil, soybean oil, rice bran oil, cocoa butter, shea fat, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil, etc. Vegetable oils and fats; silicones such as low-viscosity dimethylpolysiloxane, high-viscosity dimethylpolysiloxane, cyclic dimethylsiloxane, methylphenylpolysiloxane, and diphenylpolysiloxane can be preferably used. Oil-soluble moisturizing ingredients include macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, isostearic acid phytosteryl, dimer dilinoleic acid di (phytosteryl / isostearyl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / Ester compounds having a sterol skeleton such as behenyl), dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl), lauroyl glutamate di (phytosteryl / octyldodecyl), lauroyl glutamate di (phytosteryl / octyldodecyl / behenyl) In addition, lanolin derivatives such as purified lanolin, liquid lanolin, lanolin alcohol, and lanolin fatty acid ester can be preferably used. Oil-soluble gelling agents include: ethylhexanoic acid dextrin, palmitic acid dextrin, myristic acid dextrin, isostearic acid dextrin, palmitic acid inulin, stearic acid inulin, higher fatty acid metal soap, silylated silica, dibutylethylhexanoylglutamide Dibutyllauroylglutamide can be preferably used. As the branched fatty acid, ethylhexanoic acid, isodecanoic acid, isotridecanoic acid, isopalmitic acid, isostearic acid, lanolin fatty acid and the like can be preferably used. As the branched alcohol, ethylhexanol, isononyl alcohol, isodecyl alcohol, butyl octanol, isotridecyl alcohol, hexyl decanol, isostearyl alcohol, octyldodecanol, lanolin alcohol and the like can be preferably used. As the nonionic surfactant, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether and the like can be preferably used.

  The wax-like composition of the present invention obtained as described above is easy to handle and has functions such as setting properties and re-setting properties in hairdressing products as well as functions as general waxes. Can impart functions such as adhesion, and can be preferably used as an alternative to candelilla wax. Further, depending on the composition of the component (B), it can be a substitute for candelilla wax in terms of physical properties. Furthermore, it is also possible to exhibit the excellent effect of the component (A) as described in JP-A-2014-009259, and it can be preferably blended in cosmetics. The blending amount of the waxy composition of the present invention in the cosmetic is not particularly limited, but is usually preferably about 0.01 to 60% by weight, more preferably 0.05 to 40% by weight.

  Cosmetics containing the wax-like composition of the present invention include water and additives added to normal cosmetics as necessary, such as oil bases, surfactants, alcohols, moisturizers, polymers and additives. Viscous / gelling agent, antioxidant, antiseptic, bactericidal agent, chelating agent, pH adjuster / acid / alkali, UV absorber, whitening agent, solvent, exfoliating / dissolving agent, antipruritic agent, anti-inflammatory agent, antiperspirant Agent, refreshing agent, antihistamine, astringent, stimulant, hair-growth agent / blood circulation promoter, reducing agent / oxidant, polymer powder, hydroxy acid, vitamins and derivatives thereof, saccharides and derivatives thereof, organic acids In addition, enzymes, nucleic acids, hormones, inorganic powders, fragrances, pigments and the like may be contained to such an extent that the effects of the present invention are not impaired.

  Examples of oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexa Higher fatty acids such as cannic acid, anteisohenicosanoic acid, long-chain branched fatty acid, dimer acid, hydrogenated dimer acid, and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts, etc. And nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, solid Hydrocarbons such as paraffin; candelilla wax, carnauba wax, rice wax, wax wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, fisher Tropsch wax, polyethylene wax, waxes such as ethylene / propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut Oil, hazelnut oil, cucumber oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran Vegetable oils such as oil, cacao butter, shea fat, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; animal properties such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil Fats and oils; animal waxes such as whale wax, lanolin, orange luffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine, Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids such as sphingomyelin, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof, phospholipids such as lysolecithin; hydrogenated soybean phospholipid, partially hydrogenated soybean phospho Phospholipid derivatives such as lipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids; cholesterol, dihydrocholesterol, lanostero , Sterols such as dihydrolanosterol, phytosterol and cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, N-lauroyl-L-glutamate di (cholesteryl / behenyl) / Octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl) ), Acyl sarcosine alkyl esters such as N-lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid choles Steryl esters such as teryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, phytosteryl isostearate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; phospholipids / cholesterol Complexes, lipid complexes such as phospholipid / phytosterol complexes; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl parimilate, octyldodecyl palmitate, cetyl octanoate, hexyldecyl octanoate, isononanoic acid Isotridecyl, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, ne Isotridecyl pentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, lanolin fatty acid octyldodecyl, dicaprylyl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isostearic acid cure Castor oil, ethyl oleate, avocado oil fatty acid ethyl, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, methyl heptyl laurate, methyl heptyl palmitate, methyl heptyl palmitate, methyl isostearate Heptyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, Monoalcohol carboxylic acid esters such as diisopropyl pinate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate; cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate, γ-ercalactone Oxyesters such as: glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (caprylic acid / capric acid), tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl , Hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate, trimethylolpropane trioctanoate, triisostearate Trimethylol propane acid, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin Pentaerythrityl, triethylhexanoic acid ditrimethylolpropane, (isostearic acid / sebacic acid) ditrimethylolpropane, triethylhexanoic acid pentaerythrityl, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, diisostearate diglyceryl, tetraisostearic acid Polyglyceryl, polyglyceryl-10 nonaisostearate, deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, ( Hexyl decanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoate, etc. Polyhydric alcohol fatty acid esters; alkyl ethers such as dicaprylyl ether; diisopropyl dimerolinolate diisostearyl, dimerdilinoleate diisostearyl, dimerdilinoleate di (isostearyl / phytosteryl), dimerdilinoleic acid (phytosteryl / behenyl) ), Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleic acid dimer dilinoleyl, diisostearic dimer dilinoleyl, die -Dimerinoyl hydrogenated rosin condensate, dimer linoleic acid hydrogenated castor oil, dimer acid or dimer diol derivative such as hydroxyalkyl dimer linoleyl ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide) DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA) , Fatty acid alkanolamides such as coconut oil fatty acid methylethanolamide (cocamidomethyl MEA); dimethicone (dimethylpolysiloxane), high polymerization Methicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, (aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, Silicone resin, silicone rubber, amino-modified silicone such as aminopropyl dimethicone and amodimethicone, polyether-modified silicone such as cation-modified silicone and dimethicone copolyol, polyglycerin-modified silicone, sugar-modified silicone, carboxylic acid-modified silicone, phosphoric acid-modified silicone , Sulfuric acid modified silicone, alkyl modified silicone, fatty acid modified silicone, alkyl ether modified silicone, amino Non-acid modified silicone, peptide modified silicone, fluorine modified silicone, cation modified and polyether modified silicone, amino modified and polyether modified silicone, alkyl modified and polyether modified silicone, amide alkyl modified silicone, amino glycol modified silicone, aminophenyl modified Preferable examples include silicones such as silicone and polysiloxane / oxyalkylene copolymer; and fluorine-based oils such as perfluorodecane, perfluorooctane and perfluoropolyether.

  As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. (Eicosane diacid / tetradecanedioic acid) water-soluble esters such as polyglyceryl-10, tetradecanedioic acid polyglyceryl-10, and cyclohexanedicarboxylic acid bisethoxydiglycol; sugars such as sorbitol, xylitol, erythritol, mannitol, maltitol Alcohols; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ- Cyclodextrins and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabino Sugars and derivatives thereof such as galactan, dextrin, dextran, glycogen, ethyl glucoside, glucosylethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate, caroline sulfate, keratosulfate, dermatan Sulfuric acid; white jellyfish extract; white jellyfish polysaccharide; fructans such as inulin and levan; fucoidan; tuberose polysaccharide, naturally occurring polysaccharide; organic acids such as citric acid, tartaric acid and lactic acid and salts thereof; urea; 2-pyrrolidone-5 -Carboxylic acid and salts thereof such as sodium; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine Amino acids and salts thereof such as glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagenolytic peptide, Hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin degrading peptide, keratin degrading peptide, hydrolyzed keratin, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean proteolytic Peptides, wheat proteolytic peptides, hydrolyzed wheat proteins, casein degrading peptides, acylated peptides and other protein peptides and their Derivatives; acylated peptides such as palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesameignan glycoside, Glutathione, albumin, whey; choline chloride, phosphorylcholine; placental extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, Izayobara extract, yarrow extract Animal / plant extract components such as eucalyptus extract and merirot extract, natural ceramide (type 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide and sugar ceramide-containing extract Ceramides can be mentioned as preferred.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB. Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acylamino acid salts such as sodium phosphate, triethanolamine cocoylglutamate, sodium lauroylglutamate, sodium myristoylglutamate, sodium stearoylglutamate, ditriethanolamine palmitoylaspartate, cocoylalaninetriethanolamine, lysine Nadilauroylglutamate; sodium laureth acetate, etc. Polyoxyethylene alkyl ether acetates; succinic acid ester salts such as sodium lauroyl monoethanolamide succinate; fatty acid alkanolamide ether carboxylates; acyl lactates; polyoxyethylene fatty amine sulfates; fatty acid alkanolamide sulfates; Fatty acid glyceride sulfate such as coconut oil fatty acid sodium glycerin sulfate; Oxyethylene sulfate; Olefin sulfonate such as sodium α-olefin sulfonate; Alkyl sulfosuccinate such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; Disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sulfosuccinate Alkyl ether sulfosuccinates such as sodium acid, sodium lauryl polypropylene glycol sulfosuccinate; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and triethanolamine tetradecylbenzenesulfonate; alkylnaphthalenesulfonate; alkanesulfonate; α-sulfo fatty acid methyl ester salt; acyl isethionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetates; alkyl ether phosphates such as sodium laureth phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate esters such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphorus Acid salts; fatty acid amide ether phosphates; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; silicone-based shades such as carboxylic acid-modified silicone, phosphate-modified silicone, and sulfate-modified silicone Nonionic surfactants such as ionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steale Various polyoxyethylene addition numbers such as bis (polyoxyethylene stearyl ether), behenes (polyoxyethylene behenyl ether), isosteares (polyoxyethylene isostearyl ether), octyldecesses (polyoxyethylene octyldodecyl ether) Polyoxyethylene alkyl ethers; polyoxyethylene alkyl phenyl ethers; polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, Castor oil and hardened castor oil derivatives such as polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, polyoxyethylene hardened castor oil maleic acid; Polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene polyoxypropylene 2-decyltetradecyl ether; Polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene alkyl ethers such as polyoxyethylene / polyoxypropylene glycerin ether; polyoxyethylene / polyoxypropylene glycol ; (Poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; Glyceryl isostearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, glyceryl coconut fatty acid, mono-cotton oil fatty acid glycerin, glyceryl monoerucate, glyceryl sesquioleate, glycerin α, α'-pyroglutamate oleate, monostearin Glycerin fatty acid partial esters such as glyceryl malic acid; polyglyceryl stearate-2, 3, 4, 5, 6, 8, 8, disglyceryl-6, 10, polyglyceryl tristearate 2, polyglyceryl-10 decastearate, polyglyceryl-2 isostearate, 3, 4, 5, 6, 6, 8, diisostearate polyglyceryl-2 (diglyceryl diisostearate), 3, 1 Polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, 3, 4, 5, 6, 8, 10, dioleate polyglyceryl- 6, polyglyceryl fatty acid ester such as polyglyceryl-2 trioleate, polyglyceryl-10 decaoleate; ethylene glycol mono fatty acid ester such as ethylene glycol monostearate; propylene glycol mono fatty acid ester such as propylene glycol monostearate; pentaerythritol moiety Fatty acid ester; sorbitol partial fatty acid ester; maltitol partial fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate Sorbitan fatty acid esters such as sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; Sugar derivatives partial esters such as sucrose fatty acid ester, methyl glucoside fatty acid ester and undecylenic acid trehalose; alkyl glucoside such as caprylyl glucoside; alkyl polyglycoside; glycolipid such as mannosyl erythritol lipid; lanolin alcohol; reduced lanolin; Stearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate, etc. Polyoxyethylene fatty acid mono- and diesters; polyoxyethylene propylene glycol fatty acid esters; polyoxyethylene monooleates such as polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate Polyoxyethylene glycerin fatty acid esters such as polyoxyethylene sorbitan monooleate; polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monooleate, and other polyoxyethylene sorbitan fatty acid esters; poly Oxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene Polyoxyethylene sorbitol fatty acid esters such as bitol pentaoleate and polyoxyethylene sorbitol monostearate; Polyoxyethylene methyl glucoside fatty acid ester; Polyoxyethylene alkyl ether fatty acid ester; Polyoxyethylene animal and vegetable oils such as polyoxyethylene sorbitol beeswax Alkyl glyceryl ethers such as isostearyl glyceryl ether, chimyl alcohol, ceralkyl alcohol and batyl alcohol; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; Natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acid amides; coconut oil fatty acid monoethano Luamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide Fatty acid alkanolamides such as (partamide MEA), palmitic acid diethanolamide (partamide DEA), and palm oil fatty acid methylethanolamide (cocamidomethyl MEA); alkyl such as lauramine oxide, cocamamine oxide, stearamine oxide, and behenamine oxide Polydimethyl ether oxide; alkyl ethoxy dimethyl amine oxide; polyoxyethylene alkyl mercaptan; polyether such as dimethicone copolyol Silicone-based nonionic surfactants such as silicone-modified silicones, polysiloxane / oxyalkylene copolymers, polyglycerin-modified silicones, sugar-modified silicones, etc .; for cationic surfactants, behentrimonium chloride, steartrimonium chloride Alkyltrimethylammonium chloride such as cetrimonium chloride and lauryltrimonium chloride; alkyltrimethylammonium bromide such as stearyltrimonium bromide; dialkyldimethylammonium chloride such as distearyldimonium chloride and dicocodimonium chloride; stearamidepropyldimethylamine; Fatty acid amidoamines such as stearamide ethyl diethylamine and salts thereof; alkyl ether amines such as stearoxypropyldimethylamine; and Salt or quaternary salt of fatty acid amide type quaternary ammonium salt such as ethyl sulfate long chain branched fatty acid (12-31) aminopropylethyldimethylammonium, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium; polyoxyethylene alkylamine and its Alkylamine salt; fatty acid amidoguanidinium salt; alkyl etheraminemonium salt; alkyltrialkylene glycol ammonium salt; benzalkonium salt; benzethonium salt; pyridinium salt such as cetylpyridinium chloride; imidazolinium salt Alkyl isoquinolinium salts; dialkyl morpholinium salts; polyamine fatty acid derivatives; amino-modified silicones such as aminopropyl dimethicone and amodimethicone; cation-modified silicones; And silicone-based cationic surfactants such as polyether-modified silicone, amino-modified and polyether-modified silicone; and amphoteric surfactants such as N-alkyl-N, N- Dimethylamino acid betaine; fatty acid amide alkyl-N, N-dimethylamino acid betaine such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline type betaine such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkyl sulfobetaine such as alkyldimethyltaurine; alkyl Sulfate-type betaines such as dimethylaminoethanol sulfate; phosphate-type betaines such as alkyldimethylaminoethanol phosphate; phosphatidylcholine, phosphatidylethanolamine , Sphingophospholipids such as phosphatidylserine and sphingomyelin, lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, and phospholipids such as hydroxylated lecithin; silicone Preferred examples of the polymeric surfactant include polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, acrylic acid / alkyl methacrylate copolymer; and various silicone surfactants.

  Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropi Cellulose, carboxymethylcellulose and its salts such as sodium, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch, Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinate corn starch and aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ether Polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymer; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, etc. Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; Kurylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquaternium Acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer such as 47, methacrylic acid choline ester polymer; cationized polysaccharides such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylalkyl ester emulsion, Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, Smoke-like silica (ultrafine silicic anhydride), aluminum magnesium silicate, magnesium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester It is mentioned as preferable.

  Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

  Antibacterial agents or antiseptics include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane 1,2-alkanediols such as diol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); salicylic acid; sodium benzoate; isothiazoline derivatives such as methyl chloroisothiazolinone and methylisothiazolinone; Dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzoyl chloride Luconium, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol , Photosensitizers, antibacterial zeolite, and silver ion are preferable, but when used as an antibacterial agent or antiseptic agent for antiseptic purposes, phenoxyethanol; 1 from the viewpoint of safety of cosmetics or skin external preparations; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol; alkyl glyceres such as 2-ethylhexyl glyceryl ether It is more preferred to use ethers.

  Examples of chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and ultrafine Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), titanium mica, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder Body, gold, aluminum, etc., various sizes and shapes of inorganic powders, and these are treated with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powders such as hydrophobized or hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, Benzoguanamine resin powder, polyethylene terephthalate, polymethyl Organic powders and surface-treated powders of various sizes and shapes, such as methacrylate powder, polyethylene terephthalate / aluminum / epoxy powder, urethane powder, silicone powder, Teflon (registered trademark) powder, organic-inorganic composite powder Is preferable. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

  Examples of ultraviolet absorbers include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester. Benzoic acid-based ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid And salicylic acid-based purple such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate Line absorber: Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), Cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxy Cinnamic acid-based UV absorbers such as namate, ferulic acid and derivatives thereof; 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4′-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone -5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc. Benzophenone purple 3- (4'-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole; 2- (2′-hydroxy-5′-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5- (3 , 3-dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyl triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- ( , 4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentanedione, dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, etc., hydantoin derivatives, phenylbenzimidazolazosulfonic acid, terephthalylidene dicamphsulfone Preference is given to acids, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives.

  Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

  Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable. Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil. Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, α- or such as hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl β-hydroxy acids and derivatives thereof; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosines; caffeine, xanthine and the like; and coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloid, fullerenes, etc. Antioxidant / active oxygen scavengers; catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; rutin and glycosides, etc. Derivatives of hesperidin and glycosides; lignan glycosides; licorice extract-related substances such as grabrizine, glabrene, liquiritin, and isoliquiritin; lactoferrin; shogaol, gingerol; fragrance substances such as menthol, camphor, cedrol, and derivatives thereof Preferred examples include capsaicin, vanillin and the like and derivatives; insect repellents such as diethyltoluamide; and complexes of physiologically active substances and cyclodextrins.

  As plant / animal / microbe extracts, Iris extract, Ashitaba extract, Asunaro extract, Asparagus extract, Avocado extract, Achacha extract, Almond extract, Altea extract, Arnica extract, Aloe extract, Apricot extract, Ginkgo biloba extract, Ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

  Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor, and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.

  As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, vinegar Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damassenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute , Vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian valsum, vetiver oil, vetiverol, peppermint oil, Pepper oil, heliotropin, bergamot oil, benzyl benzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menthol, eucalyptus oil, β-yonone, lime oil, lavender oil, Synthetic and natural fragrances such as D-limonene, linalool, rilal, rireal, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and various blended fragrances It is mentioned as preferred.

  As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230 No. 1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505, red 506, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, orange 401, orange 402, orange 403, yellow 201, yellow 202- No. 1, yellow 202-2, yellow 203, yellow 204, yellow 205, yellow 4, yellow 401, yellow 402, yellow 403-1, yellow 404, yellow 405, yellow 406 Legal dyes such as Yellow No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Base dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4- Nitro dyes such as hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2 and Basic Blue 26; disperse dyes; inorganic white such as titanium dioxide and zinc oxide Pigments: Inorganic red pigments such as iron oxide (Bengara) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and loess; Black iron oxide, low-order titanium oxide, etc. Inorganic pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium oxide coated mica; Titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, pearl pigments such as fish scale foil; aluminum powder, copper powder, gold, etc. Surface treated inorganic and metal powder pigments: Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204 No., Yellow 205, Yellow 401, Blue 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Organic pigments such as zirconium, barium or aluminum lake such as yellow 5, yellow 202, yellow 203, green 3 and blue 1; surface treatment organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene , Catenal, capsanthin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, cochini Natural pigments and dyes such as naphthoquinones such as ru and shikonin, bixin, flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m- Oxidative dye intermediates and couplers such as p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and their salts; Oxidizing dyes; dihydroxyacetone is preferred.

  Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

  In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, Japanese pharmacopoeia, pharmaceutical additives Ingredients listed in standards, official food additives, etc., and Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the ingredients described, in known combinations, blending ratios and blending amounts.

  Examples of the cosmetics of the present invention include hair cosmetics, basic cosmetics, makeup cosmetics, aromatic cosmetics, body cosmetics, skin external preparations such as ointments, and the like. From the viewpoint of exerting the effects of the present invention, it can be preferably used particularly for hair cosmetics and basic cosmetics. The cosmetic of the present invention can be produced according to a usual method.

  The types of cosmetics of the present invention will be described in more detail. Examples of hair cosmetics include oil shampoos, cream shampoos, conditioning shampoos, dandruff shampoos, hair color shampoos, shampoos with integrated rinses, rinses, treatments, Conditioners such as hair packs, hair mists, hair foams, hair mousses, hair sprays, hair waxes, hair gels, hair creams, water greases, set lotions, pomades, tics, etc .; color lotions, hair tonics, hair liquids, hair blows, branches Hair coat, hair oil, permanent wave agent, straight permanent agent, oxidation hair dye, hair bleach, hair color pre-treatment, hair color after treatment, permanent pre-treat DOO, permanent after-treatments, hair manicure, and as hair growth agents are preferred.

  Basic cosmetics include soft lotion, astringent lotion, cleansing lotion, multi-layer lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisture, moisturizer -Emulsions such as emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sunscreen, makeup lotion, horny smoother, elbow lotion, hand lotion, body lotion; emollient cream, nutritional cream, Nourishing cream, burnishing cream, moisture cream, night cream, massage cream, cleansing cream, makeup cream, base cream Cream, pre-makeup cream, sunscreen cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening cream, etc .; gel such as moisture gel; essence such as moisturizing essence, whitening essence, UV protection essence; Liposome cosmetics such as liposomal serum and liposome lotion; packs and masks such as peel-off pack, powder pack, washing pack, oil pack, cleansing mask; cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing gel Facial cleansers such as oils, cleansing masks, powders and facial cleansers; cosmetic soaps, transparent soaps, medicated soaps, liquid soaps, shaving soaps, synthetic cosmetic soaps Soap can be mentioned as preferred.

  As makeup cosmetics, white powder, dusting powder, foundations, lipsticks, lip gloss, blusher, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment are preferable. .

  Preferred examples of the aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, eau de cologne, perfumes, fragrance powder, perfume soap, body lotion and bath oil.

  Body cosmetics include body shampoos and other body cleansers, deodorant lotions, deodorant powders, deodorant sprays, deodorant sticks and other deodorant cosmetics, depigmenting agents, depilation / hair removal agents, bathing agents, insect repellents, etc. A repeller is preferred.

  Moreover, as a skin external preparation, it can be used with dosage forms, such as an ointment, a patch, a lotion agent, a liniment agent, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

  As the dosage form of the cosmetic or external preparation for skin of the present invention, emulsification such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type, etc. Type cosmetics, oily cosmetics, solid cosmetics, liquid cosmetics, paste cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics, jelly cosmetics, gel cosmetics, pastes Preferred examples include cosmetics, emulsified polymer cosmetics, sheet cosmetics, mist cosmetics, and spray cosmetics.

  The following examples further illustrate the present invention in detail but are not to be construed to limit the scope thereof.

In this invention, a weight average molecular weight (Mw) means the numerical value by polystyrene conversion measured by gel permeation chromatography (GPC). In this invention, it is the value measured with the following apparatuses and conditions.

Analysis device: GPC-8020 (manufactured by Tosoh Corporation)
Column: TSK-GEL G3000HHR (7.8 × 300 mm, manufactured by Tosoh Corporation)
TSK-GEL G2000HHR (7.8 × 300 mm, manufactured by Tosoh Corporation)
TSK-GEL GMHHR-M (7.8 × 300 mm, manufactured by Tosoh Corporation)
Detector: RI detector RI-8020 (manufactured by Tosoh Corporation)
Solvent: Tetrahydrofuran Measurement temperature: 40 ° C
Flow rate: 1.0 mL / min

Synthesis Example 1 Production of Polyester A 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube was charged with 170 g (0.30 mol) of hydrogenated dimer acid (Cropa, PRIPOL 1006) and dimer diol (Croda, PRIPOL 2033). ) 162 g (0.30 mol) was charged, heated to 215 to 225 ° C. in a nitrogen stream, and the esterification reaction was carried out for 28 hours while removing the produced water, and the desired polyester (dimer acid: dimer diol = 1.0) was obtained. : 1.0) 315 g was obtained as a pale yellow glass (yield 98%).

Synthesis Examples 2 to 5 Production of Polyester An esterification reaction was carried out in the same manner as in Synthesis Example 1 except that the ratio of hydrogenated dimer acid and dimer diol was changed to the ratio shown in Table 1 to obtain the target polyester.

Synthesis Example 6 Production of Polyester A hydrogenated dimer acid, except that PRIPOL 1025 was used instead of PRIPOL 1006 and the ratio of dimer acid to dimer diol was changed from 1.0: 1.0 to 0.95: 1.0, An esterification reaction was carried out in the same manner as in Synthesis Example 1 to obtain the target polyester.

Comparative Synthesis Example 1 Production of oligomeric ester The esterification reaction was performed in the same manner as in Synthesis Example 1 except that the ratio of dimer acid and dimer diol was changed from 1.0: 1.0 to 0.7: 1.0. The oligomer ester was obtained.

  For the polyesters of Synthesis Examples 1 to 6 and the oligomer ester of Comparative Synthesis Example 1, the weight average molecular weight was measured. The results are shown in Table 1.

Preparation of waxy composition and feel evaluation 1
Using the polyester corresponding to the component (A) of the present invention, the waxy composition of the present invention was produced with the composition of Table 2 (Examples 1 to 12). All of the obtained waxy compositions had such a hardness that they could be processed into various shapes.
The obtained waxy composition was diluted with an oil agent (1: 1 mixed oil of ethylhexyl palmitate and liquid paraffin) to a concentration of 50 w / w%, and a certain amount of the obtained dilution was placed between the index finger and the thumb belly. The touch was evaluated. In this evaluation, the reason why the oily agent was diluted is that the wax-like composition itself is hard and the touch cannot be evaluated. As evaluation items, five items of adhesiveness, hardness, spread, thickness, and slipperiness were evaluated, and the following evaluation points compared with the candelilla wax were evaluated. The score is shown as the average score of five Parane players, and the results are shown in Table 2. For comparison, the wax-like compositions not containing the component (A) of the present invention (Comparative Examples 1 to 12) were similarly evaluated, and the results are shown in Table 3.

Adhesiveness 5 points: Strongly sticky compared to candelilla wax 4 points: A little stronger than candelilla wax 3 points: Almost the same as candelilla wax 2 points: 1 point: very weak compared to candelilla wax Hardness 5 points: considerably harder than candelilla wax 4 points: candelilla 3 points: almost the same compared to candelilla wax 2 points: slightly softer than candelilla wax 1 point: very soft compared to candelilla wax 5 Point: Easier to extend than candelilla wax 4 points: Easier to extend than candelilla wax 3 points: Candelilla wax 2 points: Compared to candelilla wax, slightly harder than 1 point: Very difficult to extend compared to candelilla wax Thickness 5: Compared to candelilla wax, considerably thicker 4 points: Slightly thicker compared to candelilla wax 3 points: Almost the same as candelilla wax 2 points: Not slightly thicker compared to candelilla wax 1 point: Candelilla Compared with wax, it is very thin. 5 points: Compared with candelilla wax. 4 points: Compared with candelilla wax. 3 points: Compared with candelilla wax. Almost the same 2 points: Slightly less slippery than candelilla wax 1 point: Very slippery compared to candelilla wax Difficult

  From the results of Tables 2 and 3, the wax (Comparative Examples 1 to 12) not containing the component (A) is weaker than the candelilla wax, whereas the wax of the present invention containing the component (A) is used. It has been found that the composition in the form of adhesive exhibits the same or higher tackiness as compared with the candelilla wax, and is useful for imparting setting property, resetting property, adhesion and the like.

Preparation and feel evaluation of waxy composition 2
At least one or more of the polyesters corresponding to the component (A) of the present invention and the waxes corresponding to the components (B1) to (B3) of the present invention are blended, and the wax of the present invention having the composition shown in Table 4 A composition was prepared (Examples 13 to 21). All of the obtained waxy compositions had such a hardness that they could be processed into various shapes.
About the obtained wax-like composition, touch evaluation was performed similarly to Table 2, and the result was written together in Table 4.

  From the results shown in Table 4, the wax-like compositions of the present invention of Examples 13 to 21 showed the same or higher tackiness as compared with the candelilla wax, and the component (B) was also evaluated in other evaluations. Compared to the single Examples 1 to 12, the result was close to the candelilla wax. Further, the wax-like composition using the polyester of Comparative Synthesis Example 1 (having a molecular weight smaller than the range of the present invention) was insufficient in tackiness.

Preparation and feel evaluation of waxy composition 3
At least one or more of the polyesters corresponding to the component (A) of the present invention and the waxes corresponding to the components (B1) to (B3) of the present invention are blended, and the compositions of Tables 5 and 6 are used. A waxy composition was prepared (Examples 22 to 39). All of the obtained waxy compositions had such a hardness that they could be processed into various shapes.
About the obtained wax-like composition, touch evaluation was performed similarly to Table 2, and the result was written together in Table 5,6.

  From the results of Tables 5 and 6, the wax-like compositions of the present invention of Examples 22 to 39 showed the same or higher tackiness as compared with the candelilla wax, and in other evaluations, the component (B Compared with Examples 1 to 12 in which) is single, the result was close to that of candelilla wax.

Preparation of hair wax blended with wax-like composition and evaluation of set properties Hair waxes having the compositions shown in Table 7 were prepared using the wax-like composition of the present invention (Examples 40 to 45). For comparison, hair waxes using candelilla wax or other waxes were prepared (Comparative Examples 14 to 16). About the obtained hair wax, the setting property of hair and the resetting property were evaluated by the following method. The results are also shown in Table 7.

<Setability>
A healthy black-haired human hair was used to prepare a hair bundle having a length of 15 cm and a weight of 5 g, and 1 g of hair wax was evenly applied to the hair tip to this hair bundle, and then lightly gripped and arranged. With respect to the hair bundles thus obtained, the setability was evaluated according to the following criteria from the adhesiveness between the hairs, the holding power of the hair bundles, how to disperse when lightly shaken, and the like.

◎: Very good set power ○: Set power △: Low set power ×: No set power

<Resetability>
The hair bundle used in the above set property evaluation was left in a room adjusted to 25 ° C./humidity 60% for 3 hours, and after combing 10 times with a ring comb, Evaluation was performed according to the criteria.

◎: Very reset power ○: Reset power △: Reset power is weak ×: No reset power

  From the results shown in Table 7, the hair waxes of Examples 40 to 45 using the wax-like composition of the present invention had the same or better setting properties and resetting properties as the candelilla wax-containing hair waxes. .

Preparation of foundation containing wax-like composition and evaluation of adhesion Using the wax-like composition of the present invention, foundations having the compositions shown in Table 8 were prepared (Examples 46 to 51). For comparison, foundations using candelilla wax or other waxes were prepared (Comparative Examples 17 to 19). About the obtained foundation, adhesiveness was evaluated by the following method. The results are also shown in Table 8.

<Adhesion>
The adhesion was evaluated according to the following evaluation criteria based on the feeling of use when the prepared foundation was applied to the skin.

◎: Very adhesive ○: Adhesive △: Poor adhesive ×: No adhesive

  From the results in Table 8, the foundation using the wax-like composition of the present invention had adhesiveness equivalent to or higher than that of candelilla wax.

  The following cosmetics were produced using the wax-like composition of the present invention. In the obtained cosmetic, the wax-like composition of the present invention exhibits functions as a general wax such as solidifying the dosage form, adjusting hardness and viscosity, forming a film, imparting gloss, and spreading. In the preparation, the operability of the hair was improved, and excellent setting properties and resetting properties were imparted. In the makeup cosmetics, excellent adhesion was imparted.

Example 52 Hair Wax

Component Blending amount (% by weight)
--------------------------------------
Part A waxy composition of Example 15 8.0
Phytosteryl isostearate 1.0
(Plandool-ISS: Nippon Seika)
Triethylhexanoin (IOTG: Nippon Seika) 1.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandool-G: Nippon Seika) 9.0
Tri-hydrogenated rosin glyceryl 1.0
PPG-1 Behenez-15 5.0
Polyurethane-1 2.0
Cholesterol 0.5
Diethyl sebacate 2.0
Setes-7 1.0
Dimethicone 3.0
Diisopropyl adipate5.0
Part B Glycerin 5.0
Phenoxyethanol 0.6
Methylparaben 0.2
Purified water Total amount of 100 parts C (Acrylates / Stearless Methacrylate) Copolymer 3.0
Purified water 20.0
--------------------------------------
(Preparation method)
Part A and part B were taken and heated to about 80 ° C. and mixed uniformly. The part B was gradually added to the part A with stirring and mixed uniformly, and then cooled (part D). C part was added to D part and mixed uniformly.

Example 53 Hair Wax

Component Blending amount (% by weight)
---------------------------------------
Part A waxy composition of Example 15 13.0
Sunflower seed oil fatty acid phytosteryl 2.0
(Plandool-SUN: Nippon Seika)
Dimer linoleic acid Dimer linoleil 2.7
(LUSPLAN DD-DA7: Nippon Seika)
Tri-hydrogenated rosin glyceryl 0.3
Bisdiglyceryl polyacyl adipate-2 5.0
(Plandool-DP: Nippon Seika)
Triethylhexanoin (IOTG: Nippon Seika) 3.0
PEG-40 hydrogenated castor oil 1.0
Steerless-30 1.0
γ-docosalactone, cyclopentasiloxane, diethyl sebacate, ethanol (Elcalactone SIL: Nippon Seika) 1.0
(Alkyl acrylate / diacetone acrylamide) copolymer AMP 1.0
Rice bran 2.0
Hydroxystearic acid 6.0
Glyceryl stearate 1.0
Dimethicone 3.0
Diisopropyl adipate (IPSE: Nippon Seika) 5.0
Seteth-2 0.5
Setes-20 2.5
BHT 0.05
Phenoxyethanol 0.6
Methylparaben 0.2
Part B BG 3.0
Hydroxide Na 0.5
(Acrylates / alkyl acrylate (C10-30)) Crosspolymer 0.1
Purified water Total amount of 100 ---------------------------------------
(Preparation method)
Part A and part B were taken and heated to about 80 ° C. and mixed uniformly. The part B was gradually added to the part A with stirring and mixed uniformly, and then cooled.

Example 54 Hair Wax

Component Blending amount (% by weight)
--------------------------------------
Part A waxy composition of Example 15 13.0
Phytosteryl isostearate 1.0
(Plandool-ISS: Nippon Seika)
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandool-G: Nippon Seika) 2.7
Tri-hydrogenated rosin glyceryl 0.3
Cyclopentasiloxane 10.0
Cetyl ethylhexanoate (NS-CIO: Nippon Seika) 8.0
Jojoba ester 4.0
Glyceryl stearate 2.0
Setes-10 2.0
Tocopherol 0.05
Paraffin wax 2.0
PEG-20 hydrogenated castor oil 1.3
Beeswax 1.5
Ethyl hexyl methoxycinnamate 1.8
PEG-90M 3.0
Part B Phenoxyethanol 0.6
Methylparaben 0.15
PG 3.0
Purified water Total amount of 100 ------------------------------------
(Preparation method)
Part A and part B were taken and heated to about 80 ° C. and mixed uniformly. The part B was gradually added to the part A with stirring and mixed uniformly, and then cooled.

Example 55 Hair Wax

Component Blending amount (% by weight)
--------------------------------------
Part A waxy composition of Example 1 6.0
Pentaerythrityl tetraethylhexanoate 4.5
(NS-408: Nippon Seika)
Dimethicone 8.0
Olive oil 2.0
Squalane 3.0
Theoprogrange florum seed fat 0.3
Stearic acid 2.0
Glyceryl stearate 0.8
Setes-7 1.0
Tocopherol 0.05
Microcrystalline wax 2.0
Rice bran 2.5
PEG-40 hydrogenated castor oil 1.3
Setes-20 1.5
Beeswax 1.5
Part B Phenoxyethanol 0.4
Methylparaben 0.15
Carbomer 0.1
EDTA-4Na 0.05
TEA 0.2
PG 3.0
Purified water Total amount of 100 ------------------------------------
(Preparation method)
Part A and part B were taken and heated to about 80 ° C. and mixed uniformly. The part B was gradually added to the part A with stirring and mixed uniformly, and then cooled.

Example 56 Hair Cream Wax

Component Blending amount (% by weight)
--------------------------------
Part A waxy composition of Example 9 6.0
Fatty acid (C18-35) glycol 6.0
Dioleic acid PEG-120 methylglucose 5.0
Lanolin fatty acid octyldodecyl 5.0
Stearic acid 4.0
Carnauba Arrow 3.0
Diethyl sebacate 2.0
Elcalactone 2.0
Dimethicone (100,000 cs) 1.0
Cyclopentasiloxane 1.0
Seteth-2 2.0
Setes-7 2.0
Setes-20 1.0
Dicocodimonium chloride (75%) 1.0
Propylparaben 0.1
Part B Triethanolamine 0.3
Methylparaben 0.2
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was taken in a separate container, heated to about 80 ° C. and uniformly dissolved (part B). Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 57 Hair Care Styling Milk

Component Blending amount (% by weight)
----------------------------------
Part A waxy composition of Example 23 4.0
Jojoba seed oil 6.0
Glyceryl stearate (SE) 2.0
Polyglyceryl myristate-10 2.0
Squalane 4.0
Olive oil 3.0
Bisdiglyceryl polyacyl adipate-2 2.0
(Plandool-DP: Nippon Seika)
Part B Carbomer 0.1
Purified water 20.0
PVP 0.05
Modified corn starch 0.1
Part C Glycerin 4.0
(Eicosanedioic acid / tetradecanedioic acid) Polyglyceryl-10, Glycerin (Neosolue-AquaS: Nippon Seika) 1.0
BG 2.0
Betaine 1.0
Sorbitol 0.5
Pentylene glycol 3.0
Arginine 0.2
Purified water Total amount of 100 ----------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part C was taken in a separate container and heated to about 80 ° C. to dissolve uniformly. Part B was placed in a separate container to obtain a viscous liquid. At about 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 58 Hair Styling Wax

Component Blending amount (% by weight)
-----------------------------------
Part A waxy composition of Example 24 4.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandool-G: Nippon Seika) 2.7
Octyldodecyl myristate 6.0
Rapeseed oil 5.0
Squalane 5.0
Stearic acid 2.0
Beeslow 3.0
Dimer dilinoleic acid dimer dilinoleyl, tri (caprylic acid / capric acid) glyceryl (LUSPLAN SR-DM4: Nippon Seika) 2.0
PEG-60 hydrogenated castor oil 1.0
Glyceryl stearate (SE) 1.0
Lauroyl lysine 0.5
Setes-7 2.0
Glyceryl caprate 1.0
Part B Triethanolamine 0.3
Propanediol 5.0
Pentylene glycol 3.0
Hexylene glycol 0.8
Purified water Total amount of 100 -----------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was taken in a separate container, heated to about 80 ° C. and uniformly dissolved (part B). Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 59 Matte Hair Wax

Component Blending amount (% by weight)
---------------------------------
Part A waxy composition of Example 15 12.0
Hydrogenated polyisobutene 6.0
Cetyl ethylhexanoate (NS-CIO: Nippon Seika) 5.0
Microcrystalline wax 5.0
Hydroxystearic acid 3.0
Cetanol 2.0
Tocopherol 0.05
Silica 1.0
Polymethyl acrylate 0.5
Ethylhexyl triazone 2.0
Setes-20 1.0
Propylparaben 0.1
Part B Hydroxide Na 0.8
Methylparaben 0.20
Purified water Total amount of 100 ---------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was taken in a separate container and heated to about 80 ° C. to dissolve uniformly. Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 60 Styling Balm

Component Blending amount (% by weight)
--------------------------------
The waxy composition of Example 15 3.0
Tri (caprylic acid / capric acid) glyceryl Total amount of 100 (Neosolu-MCT: Nippon Seika)
Pentaerythrityl tetraethylhexanoate 6.0
(NS-408: Nippon Seika)
Polyethylene 5.0
Ceresin 1.0
Diisostearyl malate 2.0
Squalane 3.0
Camellia seed oil 5.0
Phenoxyethanol 1.0
Glyceryl stearate (SE) 1.0
Setes-25 2.0
--------------------------------
(Preparation method)
All components were heated to about 80 ° C., mixed uniformly, and then cooled to room temperature.

Example 61 Heamist wax

Component Blending amount (% by weight)
--------------------------------
Part A waxy composition of Example 15 3.0
Setes-20 1.0
Propylene glycol 4.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(Neosolu-Aquorio: Nippon Seika)
Part B Carbomer 0.1
Purified water 20.0
Part C Arginine 0.2
Hydrolyzed keratin 0.2
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. Part C was taken in a separate container and heated to about 80 ° C. to dissolve uniformly. Part B was placed in a separate container to obtain a viscous liquid. Part A was mixed while stirring part C with a homomixer at about 80 ° C. After rapidly cooling to about 30 ° C., part B was mixed and made uniform.

Example 62 Hair Conditioner

Component Blending amount (% by weight)
-----------------------------------
Part A waxy composition of Example 23 4.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandool-G: Nippon Seika) 1.0
Stearyl alcohol 3.0
Behenyl alcohol 1.0
Behentrimonium chloride 2.0
Stearamidopropyldimethylamine 0.5
Dimer dilinoleic acid dimer dilinoleyl, tri (caprylic acid / capric acid) glyceryl (LUSPLAN SR-DM4: Nippon Seika) 2.0
Cetyl ethylhexanoate (NS-CIO: Nippon Seika) 1.0
Glyceryl caprate 1.0
Part B Lactic acid 0.3
Glycerin 3.0
Purified water Amount to be 100 in total C part Phenoxyethanol 0.3
Amodimethicone 3.0
White jellyfish polysaccharide (Tremoist-TP: Nippon Seika) 0.1
Purified water 10.0
-----------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was taken in a separate container, heated to about 80 ° C. and uniformly dissolved (part B). Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, part C was added and made uniform.

Example 63 Stick Balm

Component Blending amount (% by weight)
-----------------------------------
The waxy composition of Example 15 4.0
Diisostearyl malate Total amount of 100 Isotridecyl isononanoate 3.0
Pentaerythrityl tetraisostearate3.0
Dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl /
Behenyl) (Plandool-S: Nippon Seika) 0.2
Triethylhexanoin (IOTG: Nippon Seika) 6.0
Ascorbyl tetraethylhexanoate 2.0
Polyethylene 5.0
Polyglyceryl triisostearate-2 0.5
Dimethicone 2.0
Stearyl glycyrrhetinate 0.05
Phenoxyethanol 0.6
Titanium oxide 0.5
Microcrystalline wax 0.8
-----------------------------------
(Preparation method)
All components were heated to about 80 ° C., mixed uniformly, and then cooled to room temperature.

Example 64 Lipstick

Component Blending amount (% by weight)
--------------------------------
The waxy composition of Example 15 4.0
Hydrogenated polyisobutene 6.0
Dimer dilinoleic acid Dimer dilinoleil 3.0
(LUSPLAN DD-DA7: Nippon Seika)
Polybutene 8.0
Polyethylene 5.0
Ethylcellulose 0.2
Synthetic wax 1.2
Shea fat 3.0
Iron oxide 2.3
Mica 1.5
Titanium oxide 2.5
Red 202 1.5
Cetyl ethylhexanoate (NS-CIO: Nippon Seika) 5.0
Sorbitan sesquioleate 1.0
Tocopherol 0.05
--------------------------------
(Preparation method)
All components were heated to about 80 ° C., mixed uniformly, and then cooled to room temperature.

Example 65 Lipstick

Component Blending amount (% by weight)
-----------------------------------
The waxy composition of Example 15 7.5
(Diphenylmethylsiloxyphenyl methicone / phenylsilsesquioxane)
Cross polymer 15.0
Cetyl ethylhexanoate (NS-CIO: Nippon Seika) Total amount of 100 Trimethylhexanoic acid trimethylolpropane 10.0
(NS-308: Nippon Seika)
Isohexadecane 8.0
Tritridecyl trimellitate 8.0
Bees Wax 8.0
Ceresin 3.0
Stearic acid 2.0
Owl 2.0
Dimer dilinoleic acid Dimer dilinoleil 3.0
(LUSPLAN DD-DA5: Nippon Seika)
Vaseline 2.5
Lanolin (Purified Lanolin: Nippon Seika) 2.0
Lauroyl glutamate di (phytosteryl / octyldodecyl) 6.0
(Plandool-LG2: Nippon Seika)
Diisostearyl malate 5.0
Mineral oil 5.0
Sorbitan sesquiisostearate 0.1
(Eicosanedioic acid / tetradecanedioic acid) Polyglyceryl-10, Glycerin (Neosolue-Aqua: Nippon Seika) 0.1
Dienepentanoic acid diethylpentanediol 0.5
(Neosol-DE: Nippon Seika)
Ethyl hexyl stearate 0.2
(Neosolute-IOS: Nippon Seika)
Isopropyl palmitate 0.1
(Neosolute-IPP: Nippon Seika)
Octyl methoxycinnamate 0.01
Tocopherol 0.1
Butylcarbamic acid propynyl iodide 0.01
Titanium oxide Appropriate amount Zinc oxide Appropriate amount Safflower red Appropriate amount Red 226 Appropriate amount Yellow 5 Appropriate amount Borosilicate (Ca / Al) Appropriate amount Silica Appropriate amount Tin oxide Appropriate amount --------------------- ---------------
(Preparation method)
All components were heated to about 80 ° C., uniformly mixed and kneaded, and then cooled to room temperature.

Example 66 Lipstick

Component Blending amount (% by weight)
------------------------------------
The waxy composition of Example 23 3.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandool-G: Nippon Seika) 1.0
Lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
(Plandool-LG1: Nippon Seika) 7.0
Dimer dilinoleic acid di (isostearyl / phytosteryl) 5.0
(LUSPLAN PI-DA: Nippon Seika)
Trimethylhexanoic acid triethylhexanoate (NS-308: Nippon Seika) 10.0
Diisostearyl malate Total amount of 100 Tri (Caprylic / Capric) glyceryl 10.0
(Neosolu-MCT: Nippon Seika)
Triethylhexanoin (IOTG: Nippon Seika) 5.0
Squalane 7.0
Isotridecyl isononanoate 8.0
Triethylhexyl trimellitate 3.0
Diisobutyl adipate 3.0
Diethyl sebacate 3.0
Ethylhexyl palmitate (Neosolue-IOP: Nippon Seika) 2.0
Microcrystalline wax 5.0
Polyethylene, microcrystalline wax mixture 8.0
Methyl paraben Appropriate amount Dehydroacetic acid Appropriate amount Titanium oxide Appropriate amount Red 218 Appropriate amount Red 214 Appropriate amount Red 202 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca / Al), Titanium oxide, Silica, Tin oxide Appropriate amount --------------------------
(Preparation method)
All components were heated to about 80 ° C., uniformly mixed and kneaded, and then cooled to room temperature.

Example 67 Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 15 10.0
Microcrystalline wax 3.0
Paraffin 2.0
Ethylhexyl palmitate 5.0
Cyclopentasiloxane 2.0
Dimethicone 1.5
Mineral oil 2.0
Stearic acid 1.0
Stearyl alcohol 1.0
Setes-20 3.0
Sorbitan stearate 3.0
Polyoxypropylene sorbit 3.0
Part B Carboxyvinyl polymer 0.1
Vinylpyrrolidone-N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water 10.0
Part C Polyethylene glycol 90M 1.0
BG 2.0
Ethanol 2.0
Caprylyl glycol 0.5
Etidronic acid 0.1
Triethanolamine 0.2
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 68 Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 15 10.0
Beeslow 3.0
Polyethylene wax 2.0
Ethylhexyl palmitate 5.0
Cetyl ethylhexanoate 2.0
Vaseline 1.5
Mineral oil 2.0
Stearic acid 1.0
Stearyl alcohol 1.0
Setes-20 2.0
Sorbitan stearate 2.0
Polysorbate 60 1.0
Distearic acid PEG-250 1.0
Talc 1.0
Part B Carboxyvinyl polymer 0.1
Vinylpyrrolidone-N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water 10.0
Part C Polyethylene glycol 1.0
Diglycerin 1.0
Glycerin 2.0
Caprylyl glycol 0.5
Triethanolamine 0.2
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 69 Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 15 8.0
Sunflower seed wax 3.0
Polyethylene wax 2.0
Ethylhexyl palmitate 5.0
Isononyl isononanoate 2.0
Isopropyl myristate 2.0
Vaseline 1.5
Squalane 2.0
Hydroxystearic acid 1.0
Myristyl alcohol 1.0
Setes-20 2.0
Sorbitan stearate 2.0
PEG-60 hydrogenated castor oil 1.0
Distearic acid PEG-250 1.0
Ethylhexyl glycerin 0.5
Part B Carboxyvinyl polymer 0.1
Vinylpyrrolidone-N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
White jellyfish polysaccharide (Tremoist-TP: Nippon Seika) 0.1
Purified water 10.0
Part C Polyethylene glycol 1.0
BG 5.0
Glycerin 2.0
Caprylyl glycol 0.5
Triethanolamine 0.2
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 70 Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 15 10.0
Microcrystalline wax 3.0
Paraffin 2.0
Isododecane 5.0
Cyclopentasiloxane 2.0
12-hydroxystearic acid 1.5
Dimethylsilylated silica 1.0
Dextrin palmitate 1.0
Mineral oil 2.0
Isostearic acid 1.0
Trimethylsiloxysilicate 1.0
Mica 3.0
Talc 1.0
Kaolin 1.0
Setes-20 3.0
Sorbitan stearate 3.0
Polysorbate-60 3.0
PEG-20 glyceryl isostearate 1.0
Part B Carboxyvinyl polymer 0.1
Acrylic acid alkyl methacrylate copolymer 0.1
Hyaluronic acid 0.1
Dimethyldiallylammonium chloride / acrylamide copolymer 0.1
Purified water 10.0
Part C Polyethylene glycol 1.0
BG 2.0
Ethanol 2.0
Caprylyl glycol 0.5
Triethanolamine 0.2
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 71 Hair wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 23 10.0
Beeslow 3.0
Microcrystalline wax 2.0
Cetyl ethylhexanoate 5.0
Cyclopentasiloxane 8.0
Dimethicone 1.5
Mineral oil 2.0
Stearic acid 1.0
Stearyl alcohol 1.0
Setes-20 2.0
Glyceryl stearate 2.0
Polysorbate-60 1.0
Dilauroyl glutamate lysine Na 0.3
Crystalline cellulose 1.0
Part B Carboxyvinyl polymer 0.1
Acrylic acid / alkyl acrylate (C10-30) copolymer 0.1
Purified water 10.0
Part C Polyethylene glycol 1.0
Ethanol 5.0
Glycerin 2.0
Dextrin 0.2
Caprylyl glycol 0.5
Hydrolyzed soy protein 0.2
Triethanolamine 0.2
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 72 Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 24 8.0
Polyethylene 3.0
Paraffin 3.0
Microcrystalline wax 2.0
Beeswax 2.0
Rice bran 2.0
Indian decane 5.0
Mineral oil 5.0
Ethylhexyl palmitate 3.0
Dodecane 2.0
Dimethicone 1.0
Stearic acid 2.0
Setes-10 2.0
Seteth-15 3.0
Seteth-6 2.0
Glyceryl stearate (SE) 2.0
Part B Hydroxyethylcellulose 0.1
(Acrylates / alkyl acrylate (C1-18) / alkyl (C1-8)
Acrylamide) copolymer AMP 0.1
Purified water 10.0
Part C BG 3.0
Ethanol 5.0
EDTA-2Na 0.02
Phenoxyethanol 0.25
Methylparaben 0.05
Hydroxide Na 0.25
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 73 Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 24 10.0
Microcrystalline wax 5.0
Lanolin fatty acid octyldodecyl 2.0
Shea fat 1.0
Liquid lanolin 1.0
Meadow foam oil 0.5
Dimethicone 3.0
Cetearyl alcohol 3.0
Glyceryl stearate 8.0
Polysorbate 80 4.0
Part B (alkyl acrylate / diacetone acrylamide) copolymer AMP 0.1
(Dimethylacrylamide / Hydroxyethyl acrylate / Methoxyethyl acrylate)
Copolymer 0.1
Hydroxyethyl cellulose 0.05
Carboxyvinyl polymer 0.05
Purified water 10.0
Part C Propylene glycol 8.0
Ethanol 5.0
Aminomethylpropanol 2.0
Phenoxyethanol 0.2
Methylparaben 0.05
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 74 Gel Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 15 4.0
Fischer-Tropsch Wax 1.0
Cetearyl alcohol 1.0
PPG-1 Behenez-15 6.0
Lauroamphoacetate Na 3.0
Laureth-7 citric acid 2.0
Polyoxyethylene (60) phytosterol 1.0
Part B Polyurethane-14 acrylate copolymer AMP 0.1
Acrylates / Stearless Methacrylate-20 Cross Polymer 0.1
(Vinylpyrrolidone / VA) copolymer 0.1
Vinyl acetate / vinyl pyrrolidone copolymer 0.05
(Na acrylate / acryloyl dimethyl taurine Na) copolymer 0.05
Hydroxyethyl cellulose 0.05
Xanthan gum 0.05
Purified water 10.0
Part C BG 8.0
Ethanol 5.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(Neosolu-Aquorio: Nippon Seika)
Isostearoyl hydrolyzed silk 0.1
Hydroxide Na 0.3
Phenoxyethanol 0.2
Methylparaben 0.05
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 75 Hair Treatment

Component Blending amount (% by weight)
-----------------------------------
Part A The waxy composition of Example 15 0.5
Cyclohexanedicarboxylic acid bisethoxydiglycol 0.2
(Neosolu-Aquorio: Nippon Seika)
Dimethicone 0.3
Cetyl ethylhexanoate 1.0
γ-docosalactone, tri (caprylic acid / capric acid) glyceryl (Elcalactone MCT: Nippon Seika) 2.0
Cetearyl alcohol 3.5
Dextrin palmitate 0.2
PEG-200 0.5
Behenic acid dimethylaminopropylamide 0.2
Cetrimonium chloride (30%) 1.0
Behentrimonium chloride (80%) 1.0
Trideceth-6 0.3
BHT 0.03
Part B Ceramide 1, Ceramide 2, Ceramide 3, Ceramide 5, Ceramide 6, Cholesterol,
Quotanium-33-containing composition (NanoRepair-CMC5: Nippon Seika)
5.0
Hydroxyethyl cellulose 0.4
White jellyfish polysaccharide (Tremoist-TP: Nippon Seika) 0.02
(Acryloyldimethyltaurate ammonium / VP) copolymer 0.02
BG 1.8
Glycerin 4.0
Methylparaben 0.2
Citric acid 0.05
Purified water Total amount of 100 parts C Isododecane 0.2
PPG-3 caprylyl ether 0.5
Panthenol 0.1
Isodecyl neopentanoate 1.0
(DUB VIC-10: Nippon Seika)
-----------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Part A was added to a separate container, heated and dissolved. Part B was gradually added to part A and mixed uniformly. Part C was added with stirring at about 50 ° C. to make it uniform.

Example 76 Shampoo

Component Blending amount (% by weight)
------------------------------------
Part A The waxy composition of Example 15 0.2
Ethylhexyl palmitate (Neosolue-IOP: Nippon Seika) 0.2
Ethylhexyl sebacate (Neosol-EHS: Nippon Seika) 1.0
Oleic acid 0.2
Part B ammonium laureth sulfate 5.0
Laureth sulfate Na (25%) 10.0
Cocoa glutamic acid TEA (30%) 3.0
Lauryl hydroxysultain (30%) 7.0
Lauric acid K 1.0
Distearate glycol 0.5
Stearoxypropyldimethylamine 0.5
PPG-17 0.3
Neopentyl glycol diethylhexanoate 0.4
Lanolin fatty acid 0.3
Isodecyl glyceryl ether 0.4
Cocamide MEA 1.0
Laureth-4 0.3
Laureth-16 0.2
Steerless-6 0.2
Miconazole nitrate 0.75
Phenoxyethanol 0.3
Part C Sorbitol 1.6
Methylparaben 0.2
EDTA-2Na 0.05
Phosphoric acid 0.03
Benzoic acid Na 0.3
Purified water Total amount of 100 parts D
Guar hydroxypropyltrimonium chloride 0.1
White jellyfish polysaccharide (Tremoist-TP: Nippon Seika) 0.02
Purified water 6.7
------------------------------------
(Preparation method)
Part A and part B, which had been mixed in advance, were uniformly mixed at about 80 ° C. (part E). The part C set aside was heated to about 60 ° C. and made uniform. C. Part C was gradually added to part E with stirring and mixed uniformly, and then cooled to about 50.degree. Furthermore, D part was added and mixed uniformly.

Example 77 Latex

Component Blending amount (% by weight)
--------------------------------------
Part A waxy composition of Example 15 2.0
Lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
(Plandool-LG3: Nippon Seika) 2.0
Dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
(Plandool-H: Nippon Seika) 2.0
Bisdiglyceryl polyacyl adipate-2 1.0
(Plandool-DP: Nippon Seika)
Macadamia nut oil fatty acid phytosteryl 1.0
(Plandool-MAS: Nippon Seika)
Cetyl ethylhexanoate (NS-CIO: Nippon Seika) 5.0
Cetanol 1.2
Phenyltrimethicone 3.0
Ethylparaben 0.1
Isopropyl myristate 3.0
Mineral oil 2.0
Hydrogenated polyisobutene 1.0
Part B stearoxyhydroxypropylmethylcellulose 0.1
Xanthan gum 0.1
Purified water 20.0
Part C Hydrogenated lecithin, phytosterols 1.0
(Phytocompo-PP: Nippon Seika)
Pentylene glycol 3.0
Glycerin 8.0
Part D 3-O-ethylascorbic acid (VC ethyl: Nippon Seika) 1.0
Arbutin (Nippon Seika) 1.0
Purified water 5.0
Part E Phenoxyethanol 0.2
Methylparaben 0.15
Phytic acid 0.5
Citric acid 0.1
Amount of Na citrate pH 4.5 Purified water Amount of total 100 100 -------------------------------- -------
(Preparation method)
Part A and part E were each heated to about 70 ° C. and dissolved uniformly. Part B was stirred to obtain a viscous liquid. Part C was heated to about 70 ° C. and dispersed uniformly. After adding part A while stirring part C with a homodisper, part E was added with stirring. Part D and part B were added at about 50 ° C. and stirred to dissolve uniformly.

Example 78 Skin Care Cream

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 15 2.0
Lauroyl glutamate di (phytosteryl / octyldodecyl)
(Plandool-LG2: Nippon Seika) 2.0
Dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
(Plandool-H: Nippon Seika) 2.0
Squalane 8.0
Stearic acid 1.0
Phytosteryl isostearate 1.0
(Plandool-ISS: Nippon Seika)
Macadamia nut oil 3.0
Hydrogenated jojoba alcohol 2.0
Olive oil fatty acid cetearyl 1.0
Olive oil fatty acid sorbitan 0.8
Polyglyceryl oleate-10 1.0
Polyglyceryl laurate-10 0.5
Part B Acrylic acid / alkyl methacrylate copolymer 0.1
Hydroxide K 0.07
Hydroxyethyl acrylate / acryloyl dimethyltaurine Na) copolymer 0.05
(Ammonium acryloyldimethyltaurate /
Methenic acid behenes-25) Crosspolymer 0.05
White jellyfish polysaccharide (Tremoist-TP: Nippon Seika) 0.02
Purified water 10.0
Hydrolyzed polyγ-glutamic acid K 0.1
Polyglutamate Na 0.1
Oligopeptide-24 0.05
Part C (eicosandioic acid / tetradecandioic acid) polyglyceryl-10, glycerin (Neosol-Aqua: Nippon Seika) 1.0
Tranexamic acid (Nippon Seika) 1.0
Mannosyl Elistor Rapid 0.2
Diglycerin 5.0
Propanediol 3.0
PEG-8 2.0
Pyrosulfite Na 0.03
Methylparaben 0.1
Phenoxyethanol 0.3
Purified water Total amount of 100 ------------------------------------
(Preparation method)
Part A and part C were mixed, heated to about 70 ° C., and uniformly dissolved and dispersed. Part B was mixed and stirred to give a viscous liquid. While stirring part C with a homomixer, part A was added and emulsified. Cooled to about 50 ° C., part B was added, stirred and cooled to about 40 ° C.

Example 79 Cleansing Cream

Component Blending amount (% by weight)
----------------------------------
Part A waxy composition of Example 15 5.0
Lauroyl glutamate di (phytosteryl / octyldodecyl)
(Plandool-LG2: Nippon Seika) 2.0
Dimerlinoleic acid (phytosteryl / isostearyl / cetyl / stearyl /
Behenyl) (Plandool-S: Nippon Seika) 2.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(Neosolu-Aquorio: Nippon Seika)
Diisostearyl malate 6.0
Mineral oil 23.0
Diethylhexyl sebacate 10.0
PEG-25 hydrogenated castor oil 3.0
PEG-20 glyceryl triisostearate 4.0
PEG-12 isostearic acid 3.0
Sorbitan sesquioleate 1.5
Oleic acid polyoxyethylene sorbitan 0.3
Polyglyceryl stearate-6 0.5
Glyceryl stearate 1.0
Microcrystalline wax 2.0
Tocopherol 0.05
Propylparaben 0.05
Part B (eicosandioic acid / tetradecanedioic acid) polyglyceryl-10, glycerin (Neosol-Aqua: Nippon Seika) 1.0
Diglycerin 3.0
DPG 5.0
Methylparaben 0.05
Edetic acid 3Na 0.02
Phenoxyethanol 0.2
Purified water Total amount of 100 ----------------------------------
(Preparation method)
Part A was weighed and dissolved by heating to about 80 ° C. Part B is weighed and heated to about 80 ° C. While stirring, part B was gradually added to part A, and cooled to 40 ° C. after mixing.

Example 80 Face Wash Foam

Component Blending amount (% by weight)
----------------------------------
Part A The waxy composition of Example 15 0.5
Lauroyl glutamate di (phytosteryl / octyldodecyl)
(Plandool-LG2: Nippon Seika) 2.0
Stearic acid K 10.0
Palmitic acid K 10.0
Myristic acid K 10.0
Lauric acid K 4.0
Lauroyl sarcosine isopropyl 0.8
PEG 1500 10.0
Glycerin 15.0
Glyceryl monostearate1.0
POE (20) sorbitan monostearate 2.0
Part B White Jellyfish Polysaccharide (Tremoist-TP: Nippon Seika) 0.02
Hydroxypropyl methylcellulose 0.05
Tuberose polysaccharide 0.05
Cationized guar gum 0.05
Polyquaternium-7 0.5
Polyquaternium-39 0.5
Methylparaben 0.1
Purified water Total amount of 100 ----------------------------------
(Preparation method)
Part A was weighed and dissolved by heating to about 80 ° C. Part B is weighed and heated to about 80 ° C. While stirring, part B was gradually added to part A, and cooled to 40 ° C. after mixing.

Example 81 Hair Nail Polish

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 15 0.8
Ethanol 10.0
Setes-10 1.0
γ-docosalactone, diethyl sebacate (Erucalactone DES: Nippon Seika) 2.5
Hydrogenated polyisobutene 1.0
Behenez-10 1.0
Torides-9 0.5
Dicapric acid PG 0.5
Dicaprylyl carbonate 0.5
B part purple 401 0.2
Black 401 0.1
Orange 205 0.1
Red 102 0.1
Citric acid 2.0
Benzyl alcohol 8.0
Ethanol 10.0
Part C Purified water Total amount of 100 (hydroxyethyl acrylate / acryloyldimethyltaurine Na) copolymer
0.2
(Acryloyldimethyltaurate ammonium / VP) copolymer 0.3
Glycolic acid 2.0
Hydroxypropyl xanthan gum 0.2
------------------------------------
(Preparation method)
A part and C part were mixed and made uniform. After stirring to part B and adding to part C and mixing uniformly, part A was added at about 60 ° C. and mixed uniformly.

Example 82 Lipstick

Component Blending amount (% by weight)
----------------------------------
The waxy composition of Example 15 10.0
Dimer dilinoleic acid Dimer dilinoleil 5.0
(LUSPLAN DD-DA7: Nippon Seika)
Pentaerythrityl tetraisostearate Total amount of 100 dilauroyl glutamate (phytosteryl / octyldodecyl)
(Plandool-LG2: Nippon Seika) 2.0
Macadamia nut oil fatty acid phytostil (Plandool-PM: Nippon Seika) 3.0
Isopropyl myristate 3.0
Cyclomethicone 10.0
Methylphenylpolysiloxane 9.0
Dimethylsilylated silica 5.0
Synthetic wax 5.0
Sorbitan sesquiisostearate 4.0
Tocopherol 0.5
Iron oxide 2.0
Titanium oxide 2.0
Mica 1.0
----------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, they were filled in a mold and rapidly cooled.

Example 83 Solid powder foundation

Component Blending amount (% by weight)
-----------------------------------
Part A waxy composition of Example 15 5.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandool-G: Nippon Seika) 1.0
Lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
(Plandool-LG1: Nippon Seika) 7.0
Dimer dilinoleic acid di (isostearyl / phytosteryl) 5.0
(LUSPLAN PI-DA: Nippon Seika)
Sunflower seed oil fatty acid phytosteryl 2.0
(Plandool-SUN: Nippon Seika)
Hydrogenated polyisobutene 5.0
(Eicosanedioic acid / tetradecanedioic acid) Polyglyceryl-10, Glycerin (Neosolue-Aqua: Nippon Seika) 1.0
Perfluoropolyether 5.0
Part B Silicone-treated sericite 60.0
Titanium oxide 10.0
Powdered synthetic hydrocarbon wax 1.0
Yellow iron oxide 1.0
Bengala 0.5
Methylparaben 0.5
Black iron oxide 0.05
Talc Total amount of 100 -----------------------------------
(Preparation method)
Mix part A warm. Take part B in a separate container and mix and disperse (part B). Add part A to part B and mix evenly.

Example 84 Sunscreen Cosmetic

Component Blending amount (% by weight)
----------------------------------
Part A Phytocompo-PP (Nippon Seika) 1.0
BG 10.0
Glycerin 9.0
Part B The waxy composition of Example 15 1.0
Octocrylene 4.0
Octyl salicylate 4.0
Diethylaminohydroxybenzoyl hexyl benzoate 2.25
t-Butylmethoxydibenzoylmethane 1.0
Ethylhexyl sebacate (Nippon Seika) 3.0
Pentaerythrityl tetraethylhexanoate (Nippon Seika) 2.0
Isopropyl sebacate (IPSE: Nippon Seika) 1.0
Behenyl alcohol 2.0
Cetearyl alcohol 2.0
Macadamia nut oil fatty acid phytostil 3.0
(Plandool-MAS: Nippon Seika)
Tocopherol 0.05
Part C (eicosandioic acid / tetradecandioic acid) polyglyceryl-10, glycerin (Neosol-Aqua: Nippon Seika) 1.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 1.0
(Neosolu-Aquorio: Nippon Seika)
Methylparaben 0.2
Amount of water totaling 100 parts D Carbomer (2%) 5.0
Hydroxide Na 0.05
White jellyfish polysaccharide (Tremoist-TP: Nippon Seika) 0.02
Water-dispersed titanium oxide 5.0
----------------------------------
(Preparation method)
Disperse part A uniformly. Part B and part C are each heated to about 70 ° C. and dissolved. After part B is gradually added to part A, part C is gradually added and emulsified. Cool with stirring, add part D at 45 ° C. and stir.

Example 85 Hair Wax

Component Blending amount (% by weight)
--------------------------------------
Part A waxy composition of Example 33 8.0
Phytosteryl isostearate 1.0
(Plandool-ISS: Nippon Seika)
Cethylhexyl succinate 1.0
Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl /
Phytosteryl) (Plandool-G: Nippon Seika) 9.0
Tri-hydrogenated rosin glyceryl 1.0
Ethyl hexyl methoxycinnamate 5.0
Cholesterol 0.5
Diethyl sebacate 2.0
Setes-7 1.0
Dimethicone 3.0
Distearic acid PEG-150 5.0
Part B Glycerin 5.0
Polyethylene glycol 5.0
Phenoxyethanol 0.6
Methylparaben 0.2
Hydrolyzed keratin 0.02
Purified water Total amount of 100 parts C (Acrylates / Stearless Methacrylate) Copolymer 2.0
(Alkyl acrylate / diacetone acrylamide) copolymer AMP0.1
Carbomer 0.1
Purified water 20.0
--------------------------------------
(Preparation method)
Part A and part B were taken and heated to about 80 ° C. and mixed uniformly. The part B was gradually added to the part A with stirring and mixed uniformly, and then cooled (part D). C part was added to D part and mixed uniformly.

Example 86 Hair Wax

Component Blending amount (% by weight)
---------------------------------------
Part A waxy composition of Example 33 13.0
Sunflower seed oil fatty acid phytosteryl 2.0
(Plandool-SUN: Nippon Seika)
Dimer linoleic acid Dimer linoleil 2.7
(LUSPLAN DD-DA7: Nippon Seika)
Tri-hydrogenated rosin glyceryl 0.3
Bisdiglyceryl polyacyl adipate-2 5.0
(Plandool-DP: Nippon Seika)
Triethylhexanoin (IOTG: Nippon Seika) 3.0
PEG-40 hydrogenated castor oil 1.0
Steerless-30 1.0
γ-docosalactone, cyclopentasiloxane, diethyl sebacate, ethanol (Elcalactone SIL: Nippon Seika) 1.0
Rice bran 2.0
Glyceryl stearate 1.0
Dimethicone 3.0
Cethylhexyl succinate 5.0
Seteth-2 0.5
Setes-20 2.5
BHT 0.05
Phenoxyethanol 0.6
Methylparaben 0.2
Part B BG 3.0
Hydroxide Na 0.5
(Acrylates / alkyl acrylate (C10-30)) Crosspolymer 0.1
(Alkyl acrylate / diacetone acrylamide) copolymer AMP 0.1
Carbomer 0.5
Purified water Total amount of 100 ---------------------------------------
(Preparation method)
Part A and part B were taken and heated to about 80 ° C. and mixed uniformly. The part B was gradually added to the part A with stirring and mixed uniformly, and then cooled.

Example 87 Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 33 10.0
Microcrystalline wax 5.0
Lanolin fatty acid octyldodecyl 2.0
Shea fat 1.0
Liquid lanolin 1.0
Meadow foam oil 0.5
Dimethicone 3.0
Cetearyl alcohol 3.0
Glyceryl stearate 8.0
Polysorbate 80 4.0
Part B (alkyl acrylate / diacetone acrylamide) copolymer AMP 0.1
(Dimethylacrylamide / Hydroxyethyl acrylate / Methoxyethyl acrylate)
Copolymer 0.1
Hydroxyethyl cellulose 0.05
Carboxyvinyl polymer 0.05
Purified water 10.0
Part C Propylene glycol 8.0
Ethanol 5.0
Aminomethylpropanol 2.0
Phenoxyethanol 0.2
Methylparaben 0.05
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Example 88 Gel Hair Wax

Component Blending amount (% by weight)
------------------------------------
Part A waxy composition of Example 33 4.0
Fischer-Tropsch Wax 1.0
Cetearyl alcohol 1.0
Diethylhexyl succinate 2.0
Glyceryl stearate 2.0
Polyoxyethylene (60) phytosterol 1.0
Polysorbate-60 6.0
Part B Polyurethane-14 acrylate copolymer AMP 0.1
Acrylates / Stearless Methacrylate-20 Cross Polymer 0.1
(Vinylpyrrolidone / VA) copolymer 0.1
Vinyl acetate / vinyl pyrrolidone copolymer 0.05
(Na acrylate / acryloyl dimethyl taurine Na) copolymer 0.05
(Alkyl acrylate / diacetone acrylamide) copolymer AMP 0.1
Hydroxyethyl cellulose 0.05
Xanthan gum 0.05
Purified water 10.0
Part C BG 8.0
Ethanol 5.0
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.0
(Neosolu-Aquorio: Nippon Seika)
Isostearoyl hydrolyzed silk 0.1
Hydroxide Na 0.3
Phenoxyethanol 0.2
Methylparaben 0.05
Purified water Total amount of 100 -------------------------------------
(Preparation method)
Part A was mixed uniformly at 80 ° C. with stirring. Part B was placed in a separate container to obtain a viscous liquid. Part C was taken in a separate container and dissolved uniformly. At 80 ° C., part C was added to part A with stirring and emulsified. After emulsification, after cooling to about 50 ° C., part B was mixed and made uniform.

Claims (8)

The following components (A) and (B);
(A) including one or both of dimer acid and dimer diol as a structural unit,
Polyester having a weight average molecular weight of 30,000 to 1,000,000 (B) One or more waxes selected from the group consisting of the following (B1) to (B3) (B1) Ester wax (B2) Hydrocarbon wax (B3 A wax for cosmetics containing a solid higher alcohol or higher fatty acid, the content of (A) being 5 to 50% by weight, and the content of (B) being 50 to 95% by weight Composition.   The wax-like composition according to claim 1, wherein the polyester of component (A) contains both dimer acid and dimer diol as structural units. The waxy composition (B1) according to claim 1 or 2, wherein the components (B1) to (B3) are the following components: carnauba wax, sunflower seed wax, rice bran wax, tree wax, beeswax, Ester wax (B2) selected from lanolin, hard lanolin, montan wax, hydrogenated jojoba oil, behenyl behenate, glyceryl tribehenate; carbonization selected from ceresin, paraffin wax, microcrystalline wax, Fischer-Tropsch wax, polyethylene wax Hydrogen wax (B3); selected from cetyl alcohol, stearyl alcohol, behenyl alcohol, phytosterol, cholesterol, palmitic acid, stearic acid, behenic acid, 12-hydroxystearic acid, lanolin fatty acid, hard lanolin fatty acid Solid higher alcohol or higher fatty acid   The component (B) is composed of three or more waxes selected from the group consisting of (B1) to (B3), and is a wax containing at least one or more of each of (B1) to (B3). The wax-like composition according to any one of claims 1 to 3   The content of the component (A) is 5 to 30% by weight, the content of the component (B1) is 15 to 40% by weight, the content of the component (B2) is 30 to 75% by weight, and the content of the component (B3) is The wax-like composition according to claim 4, which is 5 to 30% by weight.   Cosmetics containing the wax-like composition in any one of Claims 1-5.   A hair styling comprising the wax-like composition according to any one of claims 1 to 5. A makeup cosmetic comprising the wax-like composition according to claim 1.