JP2014009259A - Polyester, and cosmetic using the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a non silicone compound having similar touch and luster improvement effect to silicone compounds, and small in build-up, further having effects to protect hair, improving easiness to comb and suppressing generation of split ends by brushing.SOLUTION: A polyester having a weight average molecular weight of 30 thousand to 1 million containing one or both of a dimer acid and a dimer diol as a constitutional unit is used. Using the polyester provides similar touch and luster improvement effects to silicone compounds and further effects to improve easiness to comb and suppress the generation of split ends. The polyester is small in build-up.

Description

  The present invention relates to a polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of dimer acid and dimer diol as a structural unit, and an oil and a cosmetic containing the polyester.

  Conventionally, a silicone compound has been widely used in cosmetics because it has an effect of imparting a light touch and smoothness to the skin and hair and improving gloss. In hair cosmetics, silicones with a high degree of polymerization and amino-modified silicones are used in particular. Such silicone compounds protect hair, improve combing, and brushing in addition to improving touch and gloss. It is known to suppress the occurrence of split ends caused by. However, since the silicone compound has build-up properties (accumulation on the hair surface), if the silicone-containing hair cosmetic is repeatedly used, the hair gradually becomes wrinkled or squeaked, and chemical hair treatment (waving, There has been a problem that it is difficult for the drug to penetrate into the hair during coloring.

  Against this background, attempts have been made to impart a feel and gloss similar to silicone using non-silicone compounds. As one of them, Patent Document 1 (Japanese Patent Application Laid-Open No. 2004-262783) describes that an oligomer ester containing one or both of dimer acid and dimer diol as a structural unit is used as a silicone-like feel imparting agent. According to this patent, it is disclosed that by using the oligomer ester, the same feel and gloss improvement effect as those of silicone can be obtained and the build-up property is low. The compounds specifically disclosed as silicone-like feel imparting agents in this patent have a weight average molecular weight in the range of 5,000 to 12,000 as described in Table 1 of Patent Document 3. It is. Patent Documents 2 and 3 describe that an ester containing one or both of dimer acid and dimer diol as a constituent unit is excellent in safety, stability, gloss, feeling of use and the like as an oil for cosmetics. However, all the specifically disclosed compounds are oligomer esters having a weight average molecular weight of less than 20,000. That is, in the ester containing one or both of dimer acid and dimer diol as a structural unit, a polyester having a weight average molecular weight of 30,000 or more has not been known yet.

  Oil-based makeup cosmetics such as lipstick and gloss use oil gelling agents such as dextrin derivatives to increase the viscosity of the formulation, but these must be formulated at a high concentration and are uncomfortable such as stickiness. Therefore, it has been desired to reduce or not use the oil gelling agent.

JP 2004-26283A JP 2001-072530 A JP 2002-275020 A

As described above, the oligomer ester containing one or both of the dimer acid and dimer diol of Patent Document 3 as conventionally known as a structural unit is excellent as a silicone-like feel-imparting agent, but has a high degree of polymerization. The effects of protecting hair, improving combing, and suppressing the occurrence of split ends caused by brushing, such as silicone and amino-modified silicone, were not sufficient.
That is, the problem of the present invention is that it is a non-silicone compound, has the same feel and gloss improvement effect as a silicone compound, has a low build-up property, further protects hair, improves combing, and branches by brushing. It is providing the compound which has the effect which suppresses generation | occurrence | production of hair. Another object of the present invention is to provide a compound capable of increasing the viscosity of a makeup cosmetic without impairing the feel of the formulation.

  In view of such a situation, the present inventors have conducted extensive studies and found that a polyester having a weight average molecular weight of 30,000 to 1,000,000 containing one or both of dimer acid and dimer diol as a structural unit can solve the above problems. The present invention has been completed.

  By using the polyester of the present invention, it is possible to obtain the same feel and gloss improvement effect as those of the silicone compound, further improvement of combing property of hair, and suppression of occurrence of split ends by brushing. Therefore, it is possible to obtain a hair cosmetic composition having the same feel and effect by replacing the high polymerization degree silicone or amino-modified silicone in the hair cosmetic composition with the polyester of the present invention as it is. Moreover, since the polyester of this invention has few buildup properties, even if it uses repeatedly the hair cosmetics which mix | blended the oil agent of this invention, the problem which is anxious about a silicone compound does not arise.

  The polyester of the present invention is excellent in feel, compatible with other oil agents, and has a very high viscosity, so that it can thicken makeup cosmetics without impairing the feel, and an oil gelling agent Can be reduced or not used. Further, the present inventors have found that the polyester of the present invention is superior in the effect of imparting flexibility to the skin as compared with the conventional oligomer ester, and such an effect is also one of the effects of the present invention. As mentioned.

  The polyester containing one or both of dimer acid and dimer diol used as a constituent unit in the present invention is produced using dimer acid and dimer diol described below as raw materials.

  Dimer acid is a known dibasic acid obtained by the intermolecular polymerization reaction of unsaturated fatty acids, and its industrial production process is almost standardized in the industry. For example, dimer acid or / and its lower alcohol ester is carbon It is obtained by dimerizing an unsaturated fatty acid having a number of 11 to 22 or a lower alcohol ester thereof with a clay catalyst or the like. The dimer acid obtained industrially is mainly composed of a dibasic acid having about 36 carbon atoms, but contains an arbitrary amount of trimer acid and monomer acid depending on the degree of purification. In general, dimer acid content exceeding 70% by weight and dimer acid content increased to 90% by weight or more by molecular distillation are in circulation. In addition, although a double bond remains after the dimerization reaction, a dimer acid that is further hydrogenated to improve oxidation stability, that is, a hydrogenated dimer acid is also on the market. For the production of the polyester of the present invention, any dimer acid currently in circulation can be used, but hydrogenated dimer acid is more preferable from the viewpoint of oxidation stability. In addition, those derived from animal oils and fats and vegetable oils are distributed among these dimer acids, but those derived from vegetable oils and fats are more preferable. As such dimer acid, for example, PRIPOL 1006, 1009, 1015, 1025 of Croda, etc. are commercially available.

  The dimer diol is mainly composed of a diol having about 36 carbon atoms in which the dimer acid or / and lower alcohol ester thereof is hydrogenated in the presence of a catalyst and the carboxylic acid portion of the dimer acid is an alcohol. Depending on the degree of purification of dimer acid or / and its lower alcohol ester used as a raw material, industrially obtained dimer diol may contain other components such as trimer triol, monomer alcohol and ether compound. Products with dimer diol content exceeding about 70% by weight, and those with further dimer diol content exceeding 90% by weight, etc. are in circulation. Either can be used. Regarding dimer diol, those derived from animal fats and oils and vegetable fats and oils are distributed, but those derived from vegetable fats and oils are more preferable. As such a dimer diol, PRIDO 2033 of Croda etc. can be obtained as a commercial item.

  Polyester containing one or both of dimer acid and dimer diol used as a constituent unit in the present invention is an ester of dimer acid and divalent alcohol other than dimer diol, divalent carboxylic acid other than dimer diol and dimer acid, and And one or more compounds selected from esters of dimer acid and dimer diol.

  As the divalent alcohol other than the dimer diol used in the present invention, a saturated linear, branched, ring-containing or cyclic divalent alcohol having 2 to 24 carbon atoms is preferable. Specifically, ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 1,2-butanediol, 1,5-pentanediol, 1,2- Pentanediol, neopentyl glycol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, 1,2-hexanediol, 2,5-hexanediol, hexylene glycol, 3-methyl-1 , 5-pentanediol, 1,7-heptanediol, 2,2-diethyl-1,3-propanediol, 2,2,4-trimethyl-1,5-pentanediol, 1,8-octanediol, 2- Butyl-2-ethyl-1,3-propanediol, 1,9-nonanediol, 1,8-nonanediol, 2,4-die 1,5-pentanediol, 1,10-decanediol, 1,11-undecanediol, 1,10-undecanediol, 1,12-dodecanediol, 1,2-dodecanediol, 1,13-tridecanedi All, 1,14-tetradecanediol, 1,2-tetradecanediol, 1,16-hexadecanediol, 1,2-hexadecanediol, 1,18-octadecanediol, 1,2-octadecanediol, 1,12-octadecanediol 9-octadecene-1,12-diol, 1,20-icosanediol, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, 1,3-cyclohexanedimethanol, 1,2-cyclohexanedimethanol, Isosorbide, a sorbitol dehydrate Diethylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol, polypropylene glycol, and the like. Among these, ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 1,5-pentanediol from the viewpoint of availability and feel of the resulting ester , Neopentyl glycol, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol, hexylene glycol, 3-methyl-1,5-pentanediol, 2,2-diethyl-1,3- Propanediol, 2,2,4-trimethyl-1,5-pentanediol, 1,8-octanediol, 2-butyl-2-ethyl-1,3-propanediol, 2,4-diethyl-1,5- Pentanediol, 1,10-decanediol, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, iso Rubaido like can be mentioned as preferable.

  As the divalent carboxylic acid other than the dimer acid used in the present invention, a saturated linear, branched or ring-containing divalent carboxylic acid having 4 to 24 carbon atoms is preferable. Specifically, malonic acid, succinic acid, glutaric acid, adipic acid, 3-methylpentanedioic acid, azelaic acid, sebacic acid, 2,4-diethylpentanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid , Hexadecanedioic acid, octadecanedioic acid, icosanedioic acid, dimethylicosanedioic acid, docosanedioic acid, cyclohexanedicarboxylic acid, malic acid, tartaric acid and the like. Among these, succinic acid, glutaric acid, adipic acid, 3-methylpentanedioic acid, azelaic acid, sebacic acid, dodecanedioic acid, tetradecanedioic acid, hexadecanedioic acid from the viewpoint of availability and feel of the resulting ester , Octadecanedioic acid, icosanedioic acid, dimethylicosanedioic acid, cyclohexanedicarboxylic acid and the like are preferable.

  It is most preferable to use a polyester containing both dimer acid and dimer diol as constituent units in terms of exhibiting the effects of the present invention most. Even in such a case, a divalent carboxylic acid other than dimer acid and a divalent alcohol other than dimer diol may be included as a structural unit.

  The polyester of the present invention is a compound whose terminal is an alcohol or a carboxylic acid. The polyester of the present invention may further be esterified with a monovalent carboxylic acid or alcohol at the terminal. Further, when the terminal is a carboxylic acid, it may be in the form of a neutralized salt. Examples of salts include alkali metal salts such as sodium and potassium, alkaline earth metal salts such as calcium and magnesium, metal salts such as aluminum, iron, zinc, copper and cobalt, basic amino acid salts such as lysine and arginine, triethylamine, Examples include organic amine salts such as stearylamine.

  The method for producing the polyester of the present invention is not particularly limited, and the divalent carboxylic acid and the divalent alcohol to be used may be esterified by a commonly used method. The conditions for the esterification reaction are not particularly limited. For example, paratoluenesulfonic acid, sulfuric acid, hydrochloric acid, methanesulfonic acid, boron trifluoride diethyl ether complex or the like is used as a catalyst, and heptane, hexane, cyclohexane, toluene, xylene is used as a solvent. Etc. can be performed at 50 to 260 ° C. Alternatively, esterification can be carried out at 100 to 260 ° C. even without solvent and without catalyst.

  The polyester of the present invention has a weight average molecular weight of 30,000 to 1,000,000, more preferably 70,000 to 500,000. The weight average molecular weight of the polyester of the present invention can be adjusted by changing the charging ratio of the divalent carboxylic acid to be reacted and the divalent alcohol. As the reaction ratio of the polyester of the present invention, when the terminal is an alcohol, the divalent carboxylic acid is used in an amount of 0.85 to 1.0 mol, more preferably 0.95 to 1 mol of the divalent alcohol. 1.0 mole. When the terminal is a carboxylic acid, the amount of the divalent alcohol is 0.85 to 1.0 mol, more preferably 0.95 to 1.0 mol, with respect to 1 mol of the divalent carboxylic acid.

  Since the polyester of the present invention has a very high viscosity and does not crystallize, it becomes a glassy material having no fluidity at room temperature. Therefore, handling such as subdivision and weighing at room temperature is difficult. On the other hand, since the polyester of the present invention is excellent in compatibility with various oil agents, it can be uniformly diluted with liquid oil, and in this way, it can be handled in a fluid state even at room temperature. . Specific examples of the liquid oil for diluting the polyester of the present invention include polyhydric alcohol fatty acid esters, soybean oil, rice bran oil, etc., which are liquid at room temperature such as tri (caprylic acid / capric acid) glyceryl and neopentyl glycol dicaprate. Such as oils and fats, hydrogenated polyisobutene, isododecane, squalane, etc., liquid hydrocarbons at room temperature, monoalcohol carboxylic acid esters such as isopropyl palmitate, diethylhexyl sebacate, etc., N-lauroyl-L- Examples include acylamino acid diesters such as di-glutamate (phytosteryl / octyldodecyl) and higher alcohols that are liquid at normal temperature such as octyldodecanol. The dilution rate with liquid oil is not particularly limited, and may be diluted to such an extent that fluidity is obtained at room temperature. Specifically, the ratio of polyester may be diluted to 0.1 to 99% by weight, preferably about 1 to 90% by weight.

  The polyester of the present invention and the oil containing the polyester of the present invention are excellent in oxidative stability, but the oxidative stability can be further improved by adding an antioxidant. As antioxidants, those usually added to oils can be used, but the use of vitamin E is particularly desirable. Vitamin E was isolated and purified from d-α-tocopherol, d-δ-tocopherol, d, l-α-tocopherol, d-α-tocopherol acetate, d, l-α-tocopherol acetate, soybean and rapeseed. Tocopherol mixtures and the like can be used. Although there is no restriction | limiting in particular in the addition amount of antioxidant, About 10 ppm-about 10000 ppm are suitable.

  Although the polyester of the present invention and the oil containing the polyester of the present invention can be used by blending in cosmetics, the excellent effects of the present invention can be obtained. However, it is usually 0.01 to 99% by weight, preferably 0.05 to 50% by weight. Moreover, in hair cosmetics, when using the polyester of the present invention as an alternative to high-polymerization silicone and amino-modified silicone, the same amount as high-polymerization silicone and amino-modified silicone may be used, Usually, 0.001 to 50% by weight, preferably about 0.005 to 10% by weight may be blended.

  The cosmetics of the present invention contain water and additive components that are usually added to cosmetics as necessary, such as oil bases, surfactants, alcohols, humectants, polymers, thickeners / gelling agents, antioxidants. Agent, antiseptic, disinfectant, chelating agent, pH adjuster / acid / alkali, UV absorber, whitening agent, solvent, exfoliating / dissolving agent, antipruritic agent, anti-inflammatory agent, antiperspirant, refreshing agent, antihistamine, astringent Agent, stimulant, hair growth agent / blood circulation promoter, reducing agent / oxidant, polymer powder, hydroxy acid, vitamins and derivatives thereof, saccharides and derivatives thereof, organic acids, enzymes, nucleic acids, hormones , Inorganic powders, fragrances, pigments and the like can be blended.

  Examples of oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexa Higher fatty acids such as cannic acid, anteisohenicosanoic acid, long-chain branched fatty acid, dimer acid, hydrogenated dimer acid, and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts, etc. And nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, solid Type hydrocarbons such as candelilla wax, carnauba wax, rice wax, wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, fisher Tropsch wax, polyethylene wax, waxes such as ethylene / propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut Oil, hazelnut oil, cucumber oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran Vegetable oils such as oil, cacao butter, shea fat, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; animal properties such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil Fats and oils; animal waxes such as whale wax, lanolin, orange luffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine, Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids such as sphingomyelin, phospholipids such as phosphatidic acid, lysolecithin; hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, Phospholipid derivatives such as partially hydrogenated egg yolk phospholipids; cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytoster Sterols such as oleol and cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-N-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl) ), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), N Acyl sarcosine alkyl esters such as lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid cholesteryl, macadamia nut oil fatty acid phyto Sterol esters such as steryl, phytosteryl isostearate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; phospholipid / cholesterol complex, phospholipid / phytosterol complex, etc. Lipid complex; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl parmitate, octyldodecyl palmitate, cetyl octanoate, hexyl decyl octanoate, isotridecyl isononanoate, isononyl isononanoate, isononanoate Isotridecyl acid, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octeodecanoate Ludodecyl, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, lanolin fatty acid octyldodecyl, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isostearic acid hydrogenated castor oil, ethyl oleate, ethyl avocado oil, isopropyl myristate , Isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, methyl heptyl laurate, methyl heptyl myristate, methyl heptyl palmitate, methyl heptyl isostearate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, adipine Diisopropyl acid, dibutyl octyl sebacate, diisobutyl adipate, dioctyl succinate Monoalcohol carboxylates such as triethyl citrate; oxyacid esters such as cetyl lactate, diisostearyl malate, hydrogenated castor oil monoisostearate, γ-ercalactone; glyceryl trioctanoate, glyceryl trioleate, Glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (caprylic acid / capric acid), tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester) Gum), glyceryl eicosandioate behenate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentyl glycol dioctanoate, neopentyl dicaprate Coal, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate, (isostearic acid / sebacin Acid) ditrimethylolpropane, pentaerythrityl triethylhexanoate, (hydroxystearic acid / stearic acid / rosin acid) dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl nonaisostearate-10, deca (erucic acid / isostearic acid) / Ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (distea) Polyethylene alcohol fatty acid esters such as ethylene glycol phosphate), dineopentanoic acid 3-methyl-1,5-pentanediol, dineopentanoic acid 2,4-diethyl-1,5-pentanediol; diisopropyl linoleate diisopropyl, dimer Diisostearyl linoleate, dimer dilinoleate di (isostearyl / phytosteryl), dimer dilinoleate (phytosteryl / behenyl), dimer dilinoleate (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleate Dimer acid such as merlinoleyl, diisostearic acid dimerinolinole, dimer linoleyl hydrogenated rosin condensate, dimer linoleic acid hydrogenated castor oil, hydroxyalkyl dimer linoleyl ether or the like Derivatives of imerdiol: coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide Fatty acid alkanolamides such as (lauramide MIPA), palmitic acid monoethanolamide (partamide MEA), palmitic acid diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamide methyl MEA); dimethicone (dimethylpolysiloxane), high polymerization Dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethy , Diphenyldimethicone, phenyldimethicone, (aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, aminopropyl dimethicone and amodimethicone, etc. amino-modified silicone, cation-modified silicone, dimethiconecopolyol Polyether modified silicone, polyglycerin modified silicone, sugar modified silicone, carboxylic acid modified silicone, phosphoric acid modified silicone, sulfuric acid modified silicone, alkyl modified silicone, fatty acid modified silicone, alkyl ether modified silicone, amino acid modified silicone, peptide modified silicone , Fluorine-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether Modified silicones, alkyl-modified and polyether-modified silicones, amidoalkyl-modified silicones, aminoglycol-modified silicones, aminophenyl-modified silicones, silicones such as polysiloxane-oxyalkylene copolymers; perfluorodecane, perfluorooctane, perfluoropoly Fluorine-based oils such as ether are preferred.

  As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. (Eicosane diacid / tetradecanedioic acid) water-soluble esters such as polyglyceryl-10, tetradecanedioic acid polyglyceryl-10, and cyclohexanedicarboxylic acid bisethoxydiglycol; sugars such as sorbitol, xylitol, erythritol, mannitol, maltitol Alcohols; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ- Cyclodextrins and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabino Sugars and derivatives thereof such as galactan, dextrin, dextran, glycogen, ethyl glucoside, glucosylethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate, caroline sulfate, keratosulfate, dermatan Sulfuric acid; white jellyfish extract; white jellyfish polysaccharide; fucoidan; tuberose polysaccharide, naturally derived polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and their salts; urea; 2-pyrrolidone-5-carboxylic acid and its sodium Salt: betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, aspa Amino acids such as gin, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and the salts thereof; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagenolytic peptide, hydrolyzed collagen, Hydroxypropylammonium chloride hydrolyzed collagen, elastin degrading peptide, keratin degrading peptide, hydrolyzed keratin, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soy proteolytic peptide, wheat protein Degraded peptides, hydrolyzed wheat protein, casein-degraded peptides, acylated peptides and other protein peptides and their derivatives; palmitoyl oligopeptides , Acylated peptides such as palmitoyl pentapeptide, palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesameignan glycoside, glutathione, albumin, milk Chin; choline chloride, phosphorylcholine; placenta extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, Izayoi rose extract, yarrow extract, eucalyptus extract, merirot extract Preferred are ceramides such as animal and plant extract components such as natural ceramides (types 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide, and sugar-ceramide-containing extracts. All It is.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB. Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium phosphate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine, lysine Na dilauroyl glutamate; sodium laureth acetate, etc. Polyoxyethylene alkyl ether acetates; succinic acid ester salts such as sodium lauroyl monoethanolamide succinate; fatty acid alkanolamide ether carboxylates; acyl lactates; polyoxyethylene fatty amine sulfates; fatty acid alkanolamide sulfates; Fatty acid glyceride sulfate such as coconut oil fatty acid sodium glycerin sulfate; Oxyethylene sulfate; Olefin sulfonate such as sodium α-olefin sulfonate; Alkyl sulfosuccinate such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; Disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sulfosuccinate Alkyl ether sulfosuccinates such as sodium acid, sodium lauryl polypropylene glycol sulfosuccinate; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and triethanolamine tetradecylbenzenesulfonate; alkylnaphthalenesulfonate; alkanesulfonate; α-sulfo fatty acid methyl ester salt; acyl isethionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetates; alkyl ether phosphates such as sodium laureth phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate esters such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphorus Fatty acid amide ether phosphates; Phospholipids such as phosphatidylglycerol, phosphatidylinositol and phosphatidic acid; Silicone anionic surfactants such as carboxylic acid-modified silicone, phosphate-modified silicone and sulfuric acid-modified silicone; Among the ionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether) ), Behenes (polyoxyethylene behenyl ether), isosteares (polyoxyethylene isostearyl ether), octyldecesses (polyoxyethylene octyldodecyl ether), and other polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers Polyoxyethylene alkyl phenyl ether; polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil Castor oil and hydrogenated castor oil derivatives such as monopyroglutamic acid monoisostearic acid diester, polyoxyethylene hydrogenated castor oil maleic acid; polyoxyethylene phytosterol; polio Polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene / polyoxypropylene cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / poly Oxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene alkyl ethers such as polyoxyethylene / polyoxypropylene glycerin ether; polyoxyethylene / polyoxypropylene glycol; PPG-9 di (Poly) glycerin polyoxypropylene glycol such as glyceryl; glyceryl stearate, glyceryl isostearate, Glyceryl mycinate, glyceryl myristate, glyceryl oleate, glyceryl coconut oil fatty acid, mono-cotton oil fatty acid glycerin, glyceryl monoerucate, glyceryl sesquioleate, glycerin α, α'-oleate pyroglutamate, glyceryl monostearate malate, etc. Glycerin fatty acid partial esters: polyglyceryl stearate-2, 3, 4, 5, 6, 8, 10, polyglyceryl-6 distearate, 10, polyglyceryl tristearate, polyglyceryl decastearate -10, polyglyceryl isostearate 2, 3, 4, 5, 6, 8, 10, diisostearate polyglyceryl-2 (diglyceryl diisostearate), 3, 10, polyglyceryl triisostearate 2, polyglyceryl-2 tetraisostearate, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, 3, 4, 5, 6, 8, 8, dioleate polyglyceryl-6, trioleate polyglyceryl -2, polyglyceryl fatty acid ester such as polyglyceryl-10 dekaoleate; ethylene glycol mono fatty acid ester such as ethylene glycol monostearate; propylene glycol mono fatty acid ester such as propylene glycol monostearate; pentaerythritol partial fatty acid ester; sorbitol partial fatty acid Maltitol partial fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbita Sorbitan fatty acid esters such as monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; sucrose fatty acid ester, methyl glucoside Sugar ester partial esters such as fatty acid esters and undecylenic acid trehalose; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; lanolin alcohols; reduced lanolins; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene mono Polyoxyethylene fatty acid mono- and diesters such as oleate and polyoxyethylene dioleate; polyoxyethylene propylene glycol Polyoxyethylene glycerol monostearate, polyoxyethylene glycerol monoisostearate, polyoxyethylene glycerol fatty acid esters such as polyoxyethylene monooleate such as polyoxyethylene glycerol triisostearate; polyoxyethylene Polyoxyethylene sorbitan fatty acid esters such as sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate Polyoxyethylene sorbitol pentaoleate, polyoxyethylene sorbitol monostearate, etc. Polyoxyethylene methyl glucoside fatty acid ester; Polyoxyethylene alkyl ether fatty acid ester; Polyoxyethylene animal and vegetable fats and oils such as polyoxyethylene sorbitol beeswax; Isostearyl glyceryl ether, chimyl alcohol, seraalkyl alcohol, batyl Alkyl glyceryl ethers such as alcohols; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acids Amides; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), la Phosphoric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamic acid MEA), palmitic acid diethanolamide (partamic acid DEA), coconut oil Fatty acid alkanolamides such as fatty acid methylethanolamide (cocamidomethyl MEA); alkyldimethylamine oxides such as lauramine oxide, cocamamine oxide, stearamine oxide, and behenamine oxide; alkylethoxydimethylamine oxide; polyoxyethylene alkylmercaptan; Polyether-modified silicone such as dimethicone copolyol, polysiloxane-oxyalkylene copolymer, polyglycerin-modified silicone Silicone-based nonionic surfactants such as corn and sugar-modified silicone; and cationic surfactants such as alkyltrimethylammonium chlorides such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, lauryltrimonium chloride; Alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; fatty acid amidoamines such as stearamidepropyldimethylamine and stearamideethyldiethylamine and salts thereof; stearoxypropyldimethyl Alkyl ether amines such as amines and salts or quaternary salts thereof; ethyl sulfate long chain branched fatty acid (12-31) aminopropylethyl dimethyl Fatty acid amide type quaternary ammonium salts such as ruammonium and ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium; polyoxyethylene alkylamines and salts or quaternary salts thereof; alkylamine salts; fatty acid amidoguanidinium salts; Alkyltrialkylene glycol ammonium salt; benzalkonium salt; benzethonium salt; pyridinium salt such as cetylpyridinium chloride; imidazolinium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; polyamine fatty acid derivative; And amino-modified silicone such as amodimethicone, cation-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone Cationic surfactants, etc .; in amphoteric surfactants, N-alkyl-N, N-dimethylamino acid betaines such as lauryl betaine (lauryl dimethylaminoacetic acid betaine); cocamidopropyl betaine, lauramidopropyl betaine, etc. Fatty acid amide alkyl-N, N-dimethylamino acid betaines; imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; alkyldimethylamino Phosphate betaines such as ethanol phosphates; sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, sphingomyelin, lysolecithin, water Phospholipids such as raw-added soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, and hydroxylated lecithin; silicone-based amphoteric surfactants; Preferable examples include polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, acrylic acid / alkyl methacrylate copolymers, and various silicone surfactants.

  Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropi Cellulose, carboxymethylcellulose and its salts such as sodium, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch, Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinate corn starch and aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ether Polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymer; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, etc. Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; Kurylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquaternium Acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer such as 47, methacrylic acid choline ester polymer; cationized polysaccharides such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylalkyl ester emulsion, Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, Smoke-like silica (ultrafine silicic anhydride), aluminum magnesium silicate, magnesium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester It is mentioned as preferable.

  Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

  Antibacterial agents or antiseptics include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane 1,2-alkanediols such as diol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); salicylic acid; sodium benzoate; isothiazoline derivatives such as methyl chloroisothiazolinone and methylisothiazolinone; Dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzoyl chloride Luconium, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol , Photosensitizers, antibacterial zeolite, and silver ion are preferable, but when used as an antibacterial agent or antiseptic agent for antiseptic purposes, phenoxyethanol; 1 from the viewpoint of safety of cosmetics or skin external preparations; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol; alkyl glyceres such as 2-ethylhexyl glyceryl ether It is more preferred to use ethers.

  Examples of chelating agents include edetates (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetates such as HEDTA3Na; pentetates (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and ultrafine Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), titanium mica, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder Body, gold, aluminum, etc., various sizes and shapes of inorganic powders, and these are treated with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powders such as hydrophobized or hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, Benzoguanamine resin powder, polyethylene terephthalate, polymethyl Organic powders and surface-treated powders of various sizes and shapes, such as methacrylate powder, polyethylene terephthalate / aluminum / epoxy powder, urethane powder, silicone powder, Teflon (registered trademark) powder, organic-inorganic composite powder Is preferable. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

  Examples of ultraviolet absorbers include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester. Benzoic acid-based ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid And salicylic acid-based purple such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate Line absorber: Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), Cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxy Cinnamic acid-based UV absorbers such as namate, ferulic acid and derivatives thereof; 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4′-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone -5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc. Benzophenone purple 3- (4'-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole; 2- (2′-hydroxy-5′-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5- (3 , 3-dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyl triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- ( , 4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentanedione, dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, etc., hydantoin derivatives, phenylbenzimidazolazosulfonic acid, terephthalylidene dicamphsulfone Preference is given to acids, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives.

  Examples of whitening agents include hydroquinone glycosides such as arbutin and α-arbutin and esters thereof; ascorbic acid phosphate salts such as ascorbic acid, sodium ascorbate phosphate and magnesium ascorbate phosphate, ascorbic acid Ascorbic acid fatty acid esters such as tetraisopalmitic acid ester, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside and fatty acid esters thereof, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as kojic acid, ellagic acid, tranexamic acid and its derivatives, ferulic acid and its derivatives, placenta extract, glutathione, oryzanol, butylreso Shinoru, oil-soluble Kamomiraekisu, oil-soluble licorice extract, Nishikawa willow extract, be mentioned as saxifrage extract, and the like plant extracts are preferred.

  Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

  Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable. Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil. Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, α- or such as hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl β-hydroxy acids and derivatives thereof; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosines; caffeine, xanthine and the like; and coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloid, fullerenes, etc. Antioxidant / active oxygen scavengers; catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; rutin and glycosides, etc. Derivatives of hesperidin and glycosides; lignan glycosides; licorice extract-related substances such as grabrizine, glabrene, liquiritin, and isoliquiritin; lactoferrin; shogaol, gingerol; fragrance substances such as menthol, camphor, cedrol, and derivatives thereof Preferred examples include capsaicin, vanillin and the like and derivatives; insect repellents such as diethyltoluamide; and complexes of physiologically active substances and cyclodextrins.

  As plant / animal / microbe extracts, Iris extract, Ashitaba extract, Asunaro extract, Asparagus extract, Avocado extract, Achacha extract, Almond extract, Altea extract, Arnica extract, Aloe extract, Apricot extract, Ginkgo biloba extract, Ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

  Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor, and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.

  As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, vinegar Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damassenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute , Vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian valsum, vetiver oil, vetiverol, peppermint oil, Pepper oil, heliotropin, bergamot oil, benzyl benzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menthol, eucalyptus oil, β-yonone, lime oil, lavender oil, Synthetic and natural fragrances such as D-limonene, linalool, rilal, rireal, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and various blended fragrances It is mentioned as preferred.

As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230 No. 1, Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505, red 506, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, orange 401, orange 402, orange 403, yellow 201, yellow 202- No. 1, yellow 202-2, yellow 203, yellow 204, yellow 205, yellow 4, yellow 401, yellow 402, yellow 403-1, yellow 404, yellow 405, yellow 406 Legal dyes such as Yellow No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Base dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4- hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-
phenylenediamine, HC Blue 2, Basic
Nitro dyes such as Blue 26; Disperse dyes; Inorganic white pigments such as titanium dioxide and zinc oxide; Inorganic red pigments such as iron oxide (Bengara) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Yellow oxidation Inorganic yellow pigments such as iron and ocher; inorganic black pigments such as black iron oxide and low-order titanium oxide; inorganic purple pigments such as mango violet and cobalt violet; inorganic such as chromium oxide, chromium hydroxide and cobalt titanate Green pigments; inorganic blue pigments such as ultramarine and bitumen; pearl pigments such as titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil; aluminum powder Metal powder pigments such as copper powder and gold; surface-treated inorganic and metal powder pigments; red 201, red 202, Color No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401, Blue No. 404, Red No. 3, Red 104 No., Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3, Blue No. 1, etc. Organic pigments such as zirconium, barium or aluminum lakes; surface-treated organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsanthin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, cochineal, shikonin Naphthoquinones, bixins, flavones, betacyanidine, Natural pigments / dyes such as hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino-2 -Oxidative dye intermediates and couplers such as methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine, and salts thereof; auto-oxidizing dyes such as indoline; and dihydroxyacetone are preferred.

  Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

  In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, Japanese pharmacopoeia, pharmaceutical additives Ingredients listed in standards, official food additives, etc., and Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the ingredients described, in known combinations, blending ratios and blending amounts.

  Examples of the cosmetics containing the polyester of the present invention include hair cosmetics, basic cosmetics, makeup cosmetics, aromatic cosmetics, body cosmetics, and skin external preparations such as ointments. From the viewpoint of exerting the effects of the present invention, it can be preferably used particularly for hair cosmetics and makeup cosmetics. The cosmetic of the present invention can be produced according to a usual method.

  The types of cosmetics of the present invention will be described in more detail. Examples of hair cosmetics include oil shampoos, cream shampoos, conditioning shampoos, dandruff shampoos, hair color shampoos, shampoos with integrated rinses, rinses, and treatments. , Hair pack, hair foam, hair mousse, hair spray, hair mist, hair wax, hair gel, water grease, set lotion, color lotion, hair tonic, hair liquid, pomade, tic, hair cream, hair blow, split hair coat, hair oil, permanent Wave agent, straight perm agent, oxidative hair dye, hair bleach, hair color pre-treatment, hair color after treatment, perm pre-treatment, perm after treatment DOO, hair manicure, and as hair growth agents are preferred.

  Basic cosmetics include soft lotion, astringent lotion, cleansing lotion, multi-layer lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisture, moisturizer -Emulsions such as emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sunscreen, makeup lotion, horny smoother, elbow lotion, hand lotion, body lotion; emollient cream, nutritional cream, Nourishing cream, burnishing cream, moisture cream, night cream, massage cream, cleansing cream, makeup cream, base cream Cream, pre-makeup cream, sunscreen cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening cream, etc .; gel such as moisture gel; essence such as moisturizing essence, whitening essence, UV protection essence; Liposome cosmetics such as liposomal serum and liposome lotion; packs and masks such as peel-off pack, powder pack, washing pack, oil pack, cleansing mask; cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing gel Facial cleansers such as oils, cleansing masks, powders and facial cleansers; cosmetic soaps, transparent soaps, medicated soaps, liquid soaps, shaving soaps, synthetic cosmetic soaps Soap can be mentioned as preferred.

  As makeup cosmetics, white powder, dusting powder, foundations, lipsticks, lip gloss, blusher, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment are preferable. .

  Preferred examples of the aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, eau de cologne, perfumes, fragrance powder, perfume soap, body lotion and bath oil.

  Body cosmetics such as body shampoos; deodorant lotions, deodorant powders, deodorant sprays, deodorant sticks and other deodorant cosmetics; decoloring agents, hair removal / hair removal agents; bathing agents; insect repellents A repeller is preferred.

  As an external preparation for skin, it can be used in dosage forms such as an ointment, a patch, a lotion, a liniment, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

  As the dosage form of the cosmetic or external preparation for skin of the present invention, emulsification such as oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type, etc. Type cosmetics, oily cosmetics, solid cosmetics, liquid cosmetics, paste cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics, jelly cosmetics, gel cosmetics, pastes Preferred examples include cosmetics, emulsified polymer cosmetics, sheet cosmetics, mist cosmetics, and spray cosmetics.

  EXAMPLES Hereinafter, although this invention is demonstrated in detail using an Example, this invention is not limited to these Examples.

In this invention, a weight average molecular weight (Mw) means the numerical value by polystyrene conversion measured by gel permeation chromatography (GPC). In this invention, it is the value measured with the following apparatuses and conditions.

Analysis device: GPC-8020 (manufactured by Tosoh Corporation)
Column: TSK-GEL G3000HHR (7.8 × 300 mm, manufactured by Tosoh Corporation)
TSK-GEL G2000HHR (7.8 × 300 mm, manufactured by Tosoh Corporation)
TSK-GEL GMHHR-M (7.8 × 300 mm, manufactured by Tosoh Corporation)
Detector: RI detector RI-8020 (manufactured by Tosoh Corporation)
Solvent: Tetrahydrofuran Measurement temperature: 40 ° C
Flow rate: 1.0 mL / min

Example 1 Production of Polyester A 500 mL reactor equipped with a stirrer, a thermometer, and a gas introduction tube was charged with 170 g (0.30 mol) of hydrogenated dimer acid (Croda, PRIPOL 1006) and dimer diol (Croda, PRIPOL 2033). ) 162 g (0.30 mol) was charged, heated to 215 to 225 ° C. in a nitrogen stream, and the esterification reaction was carried out for 28 hours while removing the produced water, and the desired polyester (dimer acid: dimer diol = 1.0). : 1.0) 315 g was obtained as a pale yellow glass (yield 98%).

Examples 2-5 Manufacture of polyester Except having changed the ratio of hydrogenation dimer acid and dimer diol into the ratio of Table 1, it esterified similarly to Example 1 and obtained the target polyester, respectively.

Example 6 Production of Polyester Except that PRIPOL 1025 was used instead of PRIPOL 1006 as the hydrogenated dimer acid, and the ratio of dimer acid to dimer diol was changed from 1.0: 1.0 to 0.95: 1.0, An esterification reaction was carried out in the same manner as in Example 1 to obtain the target polyester.

Comparative Example 1 Production of Oligomer Ester The esterification reaction was performed in the same manner as in Example 1 except that the ratio of dimer acid and dimer diol was changed from 1.0: 1.0 to 0.7: 1.0. An oligomeric ester was obtained.

  About the polyester of Examples 1-6 and the oligomer ester of the comparative example 1, the weight average molecular weight, the acid value, and the refractive index were measured. The results are shown in Table 1.

Examples 7 to 10 Production of oil containing polyester 50 g of tri (caprylic acid / capric acid) glyceryl was added to 50 g of the polyester of Example 2 and stirred at 100 ° C. for 1 hour to contain 50% by weight of the polyester of the present invention. An oil was prepared. The resulting oil was a viscous liquid oil at room temperature. Similarly, oil agents having a polyester content of 40, 20, and 10% by weight were prepared. About the obtained oil agent, the viscosity in 25 degreeC was measured and the result was described in Table 2. It has been found that inclusion of the polyester of the present invention greatly increases the viscosity of the oil.

Hair cosmetic evaluation (recovery of surface hydrophobicity, inhibition of split ends, feel)
Using the polyesters of Examples 1 to 6, hair cosmetics (Examples 11 to 16) having the compositions shown in Table 3 were prepared, and surface hydrophobicity recovery effect, split end inhibition effect, and feel of hair were evaluated. . For comparison, hair cosmetics not containing polyester (Comparative Example 2), hair cosmetics containing Comparative Example 1 oligomer esters instead of the polyester of the present invention (Comparative Example 3), high-polymerization silicones were blended. A hair cosmetic (Comparative Example 4) and a hair cosmetic (Comparative Example 5) containing amino-modified silicone were prepared and evaluated in the same manner. The test method was performed as follows, and the results are shown in Tables 3 and 4.

<Surface hydrophobicity evaluation method>
Healthy black hair was subjected to a permanent treatment once with a commercially available permanent treatment agent and twice with a commercially available two-component oxidized bleach agent to produce damaged hair. After washing the damaged hair with a 3% aqueous solution of sodium laureth sulfate, bundle 20 hairs, apply 0.1 g of each hair cosmetic, leave it for 2 minutes, rinse for 30 seconds under running water, % For 12 hours. The contact angle of the obtained hair was measured and used as an index of surface hydrophobicity. The contact angle was measured by placing 1 μL of a fine water droplet on one horizontally stretched hair and observing it from the side with a microscope (manufactured by Keyence Corporation). The measurement was performed 5 times, and the result was shown as an average value. The contact angle of healthy hair was 142 °, and the contact angle of damaged hair before applying the hair cosmetic was 103 °.

<Split hair inhibition evaluation method>
Healthy black-haired human hair was bleached once with a commercially available two-component oxidation bleaching agent and once with a commercially available permanent treating agent, to produce a hair bundle of 1 g having a length of 15 cm cut off at the hair end side. The hair bundle was washed with 3% aqueous laureth sulfate solution, 0.2 g of each hair cosmetic was applied, left for 2 minutes, rinsed under running water for 30 seconds, and dried with a dryer. About the obtained hair | bristle bundle, it brushed for 60 minutes on the conditions of rotation speed 400rpm with the rotating brush linked | linked with the motor. Thereafter, the number of split ends and broken hairs generated in the hair bundle was visually confirmed. The measurement was performed three times, and the result was shown as an average value.

<Hair feel evaluation method>
A healthy black-haired human hair was bleached once with a commercially available two-component oxidation bleaching agent to produce a hair bundle (25 cm × 5 g) of damaged hair. The hair bundle was washed with a 3% aqueous solution of sodium laureth sulfate, 0.5 g of each hair cosmetic was applied, allowed to stand for 2 minutes, rinsed under running water for 30 seconds, and dried with a dryer. About the obtained hair bundle, the touch (moist feeling and smoothness) was evaluated by five professional panelists. The evaluation points were the following five stages, and the hair cosmetics of Comparative Example 2 were compared with other hair cosmetics with 3 points. The results are shown as an average value of 5 panelists.

5 points: very good, 4 points: good, 3 points: same, 2 points: not good, 1 point: not good

  From the results of Tables 3 and 4, the hair cosmetics (Examples 11 to 16) containing the polyester of the present invention were compared with the hair cosmetics (Comparative Example 2) containing no polyester of the present invention. It was found that the hydrophobicity was greatly recovered, the generation of split ends was significantly suppressed, and the feel of the hair was greatly improved. Such an effect was equivalent or better than the hair cosmetics (Comparative Examples 4 and 5) containing a silicone compound. Therefore, the polyester of the present invention has an effect of giving a touch similar to that of a silicone compound and protecting hair and suppressing the occurrence of split ends due to brushing, such as high-polymerization silicone and amino-modified silicone. I understood.

Evaluation of combing property of hair The combing property of hair was evaluated for the hair cosmetics of Example 12 and Comparative Example 4. Evaluation was performed as follows, and the results are shown in Table 5.

(Evaluation method)
Healthy black-haired human hair was subjected to bleach treatment twice with a two-component oxidation bleach and twice with a permanent treatment agent to produce a hair bundle of damaged hair having a length of 25 cm and 15 g. After applying 0.5 g of each hair cosmetic to the hair bundle, it was rinsed for about 2 minutes and dried. For the obtained hair bundle, a combing tester (manufactured by Technohashimoto) was used to measure the load applied to the hair bundle when passed through the comb, and used as an index of combability.

  From the results in Table 5, the hair bundle treated with the hair cosmetic composition containing the polyester of the present invention (Example 12) is equivalent to the hair composition containing the highly polymerized silicone used as a comparison (Comparative Example 4). It turns out that it improves the street.

Evaluation of accumulation in hair The accumulation in hair was evaluated for the hair cosmetic of Example 12 and the hair cosmetics of Comparative Examples 2 to 4. Evaluation was performed as follows, and the results are shown in Table 6.

(Evaluation method)
Healthy black hair human hair was treated with a commercially available bleach agent three times to produce a hair bundle of damaged hair. Each hair cosmetic 0.3 g was applied to 3 g of the damaged damaged hair bundle, allowed to stand for 2 minutes, and then rinsed for 30 seconds under running water. Then, it was washed with 3% aqueous laureth sulfate solution and dried. This treatment was repeated 10 times, and a hair bundle was prepared by repeating the application of the hair cosmetic and washing with 3% aqueous laureth sulfate solution 10 times. The resulting hair bundle, measuring the infrared absorption spectrum (ATR method), a peak around 1750 cm ^-1 derived from an ester bond, or the presence or absence of a peak around 1250 cm ^-1 and 1110 cm ^-1 derived from a silicone compound It was confirmed.

  From the results in Table 6, in the hair bundle treated with the hair cosmetic composition (Comparative Example 4) containing highly polymerized silicone, a peak derived from the silicone compound was confirmed, whereas the polyester of the present invention (Example 12). ), No peak derived from the ester was confirmed as in the conventional oligomer ester (Comparative Example 3). Therefore, it was considered that the polyester of the present invention was easily washed off from the hair surface by washing and less accumulated on the hair surface even after repeated use, as compared with the silicone compound.

Lip cosmetic evaluation (viscosity, feel)
Lip cosmetics (Examples 17 and 18) were prepared with the composition described in Table 7 using the polyester of Example 2. For comparison, a lip cosmetic (Comparative Example 6) containing the oligomer ester of Comparative Example 1 and a lip cosmetic not containing the polyester of the present invention (Comparative Example 7) were prepared. The lip cosmetics of Examples 17 and 18 and Comparative Example 6 were adjusted in the blending amount of dextrin palmitate as an oil gelling agent so that the viscosities were comparable (viscosity of lip cosmetics is shown in Table 7). Described in). About the obtained lip cosmetic, the touch was evaluated as follows, and the obtained results are shown in Table 7.

(Evaluation method)
A certain amount of each lip cosmetic was applied to the lips, and the touch (softness of the skin) after application was evaluated by 5 expert panelists. The evaluation score was the following five stages, and the score of the lip cosmetic of Comparative Example 7 was set to 3 to compare with other lip cosmetics. The results are shown as an average value of 5 panelists.

5 points: very good 4 points: good 3 points: the same 2 points: not good 1 point: not good

  From the results of Table 7, it was found that the lip cosmetic containing the polyester of the present invention can increase the viscosity of the formulation with a smaller amount of dextrin palmitate. Moreover, it turned out that it has the effect which provides the outstanding softness | flexibility with respect to lips, and the effect was superior to the conventional oligomer ester.

Skin cosmetic evaluation (feel)
A skin cosmetic (Example 19) was prepared with the composition described in Table 8 using the polyester of Example 2. For comparison, a skin cosmetic (Comparative Example 8) containing the oligomer ester of Comparative Example 1 and a skin cosmetic not containing the polyester of the present invention were prepared. About the obtained skin cosmetics, the touch was evaluated as follows, and the obtained results are shown in Table 8.
(Evaluation method)
A certain amount of each skin cosmetic was applied to the inner side of the forearm, and the touch (softness of the skin) after application was evaluated by five professional panelists. The evaluation score was the following five stages, and the score of the skin cosmetic of Comparative Example 7 was set to 3 and compared with other skin cosmetics. The results are shown as an average value of 5 panelists.

5 points: very good 4 points: good 3 points: the same 2 points: not good 1 point: not good

From the results of Table 8, it was found that the skin cosmetic containing the polyester of the present invention had an effect of imparting flexibility to the skin, and the effect was superior to the conventional oligomer ester.

Example 20 Hair Treatment A treatment having the following formulation was prepared using the oily base of the present invention. This treatment was a treatment capable of improving the feeling of hair damage without using silicone, and providing a moist feeling, smoothness and a lasting feeling. Further, after washing with shampoo, no residual feeling on the hair was felt.

Component Blending amount (% by weight)
-------------------------------
Part A Oil for Example 8 5.00
Neosole-Aquilio (Nihon Seika) 0.50
Glyceryl stearate (SE) 4.50
Steerless-10 4.00
Cetanol 4.00
Steartrimonium chloride (63%) 1.80
Behentrimonium chloride (80%) 1.00
Part B Methylparaben 0.20
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved. Part A was added to a separate container, heated and dissolved. Part B was gradually added to part A and mixed uniformly.

Example 21 Hair Treatment A treatment having the following formulation was prepared. This treatment was able to improve the hair damage feeling and give a moist feeling and smoothness.

Component Blending amount (% by weight)
--------------------------------
Part A Oil for Example 7 3.00
Behentrimonium chloride (80%) 2.40
Cetanol 5.20
Glyceryl stearate 1.20
Neosolute-EHS (Nippon Seika) 0.40
Cyclopentasiloxane 0.80
Dimethiconol 0.10
Part B Methylparaben 0.10
Propylparaben 0.10
Purified water Total amount of 100 parts C Aminoethylaminopropylsiloxane
Dimethylsiloxane copolymer emulsion 2.00
--------------------------------
(Preparation method)
Part A and part B were taken and heated to about 80 ° C. and mixed uniformly. The part B was gradually added to the part A with stirring and mixed uniformly, and then cooled (part D). C part was added to D part and mixed uniformly.

Example 22 Hair Treatment A treatment having the following formulation was prepared. This treatment was able to improve the hair damage feeling and give a moist feeling and smoothness.

Component Blending amount (% by weight)
------------------------------
Part A Oil for Example 10 10.00
Cetanol 6.00
Dimethicone (1000cs) 2.00
Aminopropyl dimethicone 0.40
Behentrimonium chloride (80%) 2.40
Distearyldimonium chloride (75%) 0.80
Glyceryl stearate 0.80
Part B Phenoxyethanol 0.50
Purified water Amount to be 100 in total C part Hydrolyzed keratin (20%) 1.50
------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 40 ° C. and mixed uniformly.

Example 23 Hair Treatment A treatment having the following formulation was prepared. This treatment was excellent in feel when washed off, kept the moisture of the hair, and was able to impart gloss, moist and smooth feel to the hair.

Component Blending amount (% by weight)
--------------------------------
Part A Polyester of Example 5 0.50
Behenyl alcohol 4.00
Cetanol 2.00
Behentrimonium chloride 2.00
Stearamidopropyldimethylamine 1.00
Glyceryl stearate 0.40
PPG-9 Diglyceryl 0.20
Polyglyceryl-2 diisostearate 0.10
Hydrogenated lecithin 0.10
Dimethicone 1.00
Adsorbed purified lanolin 0.20
Neopentyl glycol dioctanoate 0.50
Neosolute-EHS (Nippon Seika) 0.50
Tocopherol 0.05
Part B Glycerin 0.20
DPG 0.20
Hydrolyzed collagen 0.10
Panthenol 0.10
Hydroxycellulose 0.02
Polyquaternium-10 0.05
Phenoxyethanol 0.20
Citric acid appropriate amount Edetic acid 3Na 0.01
Pentethic acid 0.02
Purified water Total amount of 100 parts C Arginine 0.10
--------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. B was taken in another container, heated to about 80 ° C., and dissolved uniformly. Part C was taken in another container, a part of purified water was added and dissolved, and then added to part A and stirred to form the polyester and salt of Example 5. Further, part B was gradually added to part A and mixed uniformly to cool.

Example 24 Leave-On Hair Treatment A non-washing hair treatment having the following formulation was prepared. This hair treatment improved the feeling of hair damage without using silicone, and improved the feeling of slipping and moistening. Further, after washing with shampoo, no residual feeling on the hair was felt.

Component Blending amount (% by weight)
---------------------------------
Part A Oil of Example 10 0.10
Cyclohexanedicarboxylic acid bisethoxydiglycol 2.00
Cetrimonium chloride (25%) 3.80
Caprylyl glucoside (50%) 0.80
Glycerin 4.00
Phenoxyethanol 0.50
Part B Ethanol 5.00
Part C Polyquaternium-6 0.60
Polyquaternium-7 0.40
Polyquaternium-39 0.50
Purified water Total amount of 100 ---------------------------------
(Preparation method)
Part C was heated to about 80 ° C. and dissolved. Next, part A was heated to about 80 ° C. and dissolved. Part A was added with stirring, part A was mixed uniformly, and then cooled to about 40 ° C. Next, part B was added and mixed uniformly.

Example 25 Leave-on treatment A leave-on treatment having the following formulation was prepared. This leave-on treatment has a moist feel and can impart a moist and slippery feel to the hair.

Component Blending amount (% by weight)
---------------------------------
Part A Polyester of Example 6 1.00
Diethyl sebacate 2.00
Myristyl alcohol 5.00
Behenyl alcohol 1.00
Oleyl alcohol 1.00
Stearamidopropyldimethylamine 2.00
Cocoamphoacetate Na (30%) 2.00
Glyceryl stearate 0.40
Myristic acid 0.60
Phenyltrimethicone 1.00
Diphenyl dimethicone 0.10
PEG-10 Dimethicone 1.00
PEG-12 methyl ether lauroxy PEG-5 amidopropyl dimethicone 0.05
Biscetearyl amodimethicone 0.10
(Aminoethylaminopropyl methicone /
Dimethicone) copolymer 0.10
Phenoxyethanol 0.40
Part B Lactic acid 0.60
Purified water Total amount of 100 ---------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. Part B was heated to about 80 ° C. and dissolved. Part B was gradually added to part A and mixed uniformly.

Example 26 Hair rinse A hair rinse having the following formulation was prepared. Although this rinse was not using silicone, it was a rinse that gave good fingering during washing, and was able to give a moist feeling and gloss after washing, giving a smooth fingering.

Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 2 1.00
2 YOFCO MAS (Nippon Seika) 0.50
3 Cetrimonium chloride 5.20
4 Octyldecanol 4.70
5 Cetanol 2.80
6 Stealtrimonium chloride 0.60
7 Cetyl ethylhexanoate 0.30
8 Squalane 0.30
9 Myristyl sulfate Na 0.20
10 POE (40) cetyl ether 0.10
11 Ores-5 0.10
12 Nacetyl sulfate 0.10
13 Citric acid 0.10
14 Methylparaben 0.10
15 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 12 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 14 to 15 were heated to about 80 ° C. and dissolved (Part B). While stirring Part B into Part A, gradually add and mix uniformly. After 13 was added and stirred, it was quenched.

Example 27 Hair cream wax A hair cream wax having the following formulation was prepared. When this hair cream wax was applied to the hair, it was glossy, non-sticky, did not dislodge even when moved, had an appropriate hair bundle feeling, and had excellent hairstyle retention.

Component Blending amount (% by weight)
--------------------------------
Part A Polyester of Example 1 4.00
Fatty acid (C18-35) glycol 6.00
Dioleic acid PEG-120 methyl glucose 5.00
Lanolin fatty acid octyldodecyl 5.00
Stearic acid 4.00
Candelilla Row 3.00
Diethyl sebacate 2.00
Dimethicone (100,000 cs) 1.00
Cyclopentasiloxane 1.00
Setes-2 2.00
Setes-7 2.00
Ceteth-20 1.00
Dicocodimonium chloride (75%) 1.00
Propylparaben 0.10
Part B Triethanolamine 0.30
Methylparaben 0.20
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was taken in a separate container, heated to about 80 ° C. and uniformly dissolved (part B). Part B was gradually added to part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 28 Hair Shampoo A shampoo having the following formulation was prepared. This shampoo was a shampoo capable of imparting a moist feeling and gloss to the hair without using silicone and providing a smooth finger passage.

Component Blending amount (% by weight)
--------------------------------
1 Oil of Example 9 0.30
2 Cocoyl methyl methyl taurine Na (30%) 30.00
3 Cocamidopropyl betaine (30%) 20.00
4 Laureth-12 Na acetate (30%) 5.00
5 1,3-butylene glycol 1.00
6 Cocamide MEA 2.00
7 Glycol distearate 1.50
8 Polyquaternium-10 0.50
9 Polyquaternium-7 0.30
10 Cationic NH (Nippon Seika) 0.50
11 Sodium benzoate 0.40
12 Phenoxyethanol 0.20
13 Methylparaben 0.20
14 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 7 were heated to about 80 ° C. and dissolved (part A). No. in a separate container. 8 to 14 were heated to about 80 ° C. and dissolved (Part B). While stirring Part B into Part A, they were gradually added and mixed uniformly, and then rapidly cooled.

Example 29 Hair Shampoo A hair shampoo having the following formulation was prepared. This shampoo was capable of imparting a smooth sliding feeling while suppressing hairiness while increasing the volume of the hair.

Component Blending amount (% by weight)
---------------------------------
Part A Polyester of Example 4 0.10
Plandool-H (Nippon Seika) 0.20
Cocoyl glutamic acid (30%) 40.00
Olefin (C14-16) sulfonic acid Na liquid (30%) 10.00
Lauramide MIPA 4.50
Dioleic acid PEG-120 methyl glucose 2.00
SIMULGEL EG (SEPPIC) 3.00
PEG-12 Dimethicone 1.00
PEG10 methyl ether dimethicone 0.30
Dimethiconol 0.30
Dimethicone (10cs) 0.10
Part B Methylparaben 0.20
Purified water Amount C part (bisisobutyl PEG-14 / amodimethicone) copolymer totaling 100
0.50
Aminopropylphenyl trimethicone 0.10
Bis (C13-15alkoxy) PG dimethicone 0.10
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 30 Hair Depigmenting Agent (2 agent type)
A hair bleaching agent (two-part formulation) having the following formulation was prepared. This hair bleaching agent (two-component type) was a bleaching agent capable of suppressing damage to the hair and giving the hair a good feel such as flexibility and slipping when applied to the hair.

(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 6 0.10
2 Polyoxyethylene oleyl ether 50.00
3 Ammonia water (25%) 20.00
4 Cetyltrimethylammonium chloride 10.00
5 Ethanol 10.00
6 Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.

(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide 19.00
2 Cetyltrimethylammonium chloride (25%) 7.00
3 Setanol 3.50
4 Polyoxyethylene (2) cetyl ether 1.00
5 Polyoxyethylene (20) cetyl ether 1.00
6 Na pyrophosphate 0.10
7 Diethylenetriaminepentaacetic acid 0.10
8 Citric acid (50%) Appropriate amount 9 Purified water Amount to be 100 in total --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.
(Mixing ratio)
1 agent: 2 agents = 1: 1

Example 31 Hair depigmenting agent (3-agent type)
A hair bleaching agent (three-part formulation) having the following formulation was prepared. In addition, 1 agent and 2 agents of Example 30 were used for 1 agent and 2 agents. This hair bleaching agent (three-component type) was a bleaching agent that can suppress hair damage and give a good feel such as flexibility and slipping to the hair by applying to the hair.

(3 agents)
Component Blending amount (% by weight)
--------------------------------
1 Ammonium persulfate 65.00
2 Sodium carbonate 35.00
--------------------------------
(Preparation method)
Each component was mixed uniformly.
(Mixing ratio)
1 agent: 2 agents: 3 agents = 3: 6: 1

Example 32 Oxidative hair dye An oxidative hair dye having the following formulation was prepared. This oxidative hair dye was an oxidative hair dye which can suppress the feeling of damage to the hair and give a good feeling such as moist feeling and slipperiness by applying to the hair.

(1 agent)
Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 2 0.50
2 Cetyltrimethylammonium chloride (25%) 24.00
3 Cetanol 9.00
4 Octyldecanol 9.00
5 Monoethanolamine 3.80
6 Ammonia water 2.00
7 Myristyl sulfate Na 1.50
8 Polyoxyethylene (20) oleyl ether 1.40
9 Toluene hydrochloride, 2,5-diamine 1.00
10 Resorcin 1.00
11 Metaaminophenol 0.50
12 Paraaminophenol 0.20
13 Orthoaminophenol 0.10
14 Ascorbic acid 0.20
15 Fragrance 0.10
16 Purified water 45.70
--------------------------------
(Preparation method)
Each component was mixed uniformly.

(2 agents)
Component Blending amount (% by weight)
--------------------------------
1 Hydrogen peroxide solution 17.00
2 Cetyltrimethylammonium chloride (25%) 10.00
3 Cetanol 3.00
4 Polyoxyethylene (2) cetyl ether 1.00
5 Polyoxyethylene (20) cetyl ether 1.00
6 Na pyrophosphate 0.10
7 Diethylenetriamine 0.10
8 Citric acid (50%) Appropriate amount 9 Purified water Amount to be 100 in total --------------------------------
(Preparation method)
Each component was mixed uniformly, and the pH was adjusted to 3.5 to 4.0 with citric acid.
(Mixing ratio)
1 agent: 2 agents = 1: 1

Example 33 Acid hair dye The acid hair dye of the following prescription was prepared. This acidic hair dye was an acidic hair dye capable of imparting a good feel such as flexibility and slipperiness to the hair by performing treatment on the hair.

Component Blending amount (% by weight)
--------------------------------
Oil of Example 8 0.50
N-methylpyrrolidone 15.00
Benzyl alcohol 8.50
Dimethicone (1000cs) 2.00
Citric acid 1.00
Brown 201 0.13
Black 401 No. 0.05
Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was mixed uniformly.

Example 34 Cysteine permanent agent A cysteine permanent agent having the following formulation was prepared. This cysteine-based permanent agent was a permanent agent capable of imparting a good feel such as flexibility and a slipping feeling to the hair, and sustaining wave formation when applied to the hair.

(1 liquid)
Component Blending amount (% by weight)
--------------------------------
Oil of Example 10 0.50
Monoethanolamine 4.50
L-cysteine hydrochloride 3.20
Acetylcysteine 2.50
Ores-20 2.00
Ammonium thioglycolate solution (50%) 1.90
PEG-20 sorbitan cocoate 1.00
Ammonia water (28%) 0.30
Purified water Total amount of 100 --------------------------------
(Preparation method)
Each component was stirred and mixed uniformly.

(2 liquids)
Component Blending amount (% by weight)
--------------------------------
Part A Emmacol TS-703 (Sanei Chemical) 2.00
Steartrimonium chloride (50%) 2.00
Bromate Na 10.00
Emma Coal NZ (Sanei Chemical) 4.00
Ores-20 3.00
Oil of Example 7 0.50
Part B: Benzoic acid Na 0.20
Edetic acid 2Na 0.10
Diammonium phosphate 0.10
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part B was heated to about 60 ° C. and dissolved. Subsequently, A part was added to B part in order, and it mixed and cooled uniformly.

Example 35 Thioglycolic acid-based permanent agent A thioglycolic acid-based permanent agent having the following formulation was prepared. This thioglycolic acid-based permanent agent is a permanent agent that gives hair a feeling of slipping and moistness when applied to the hair.

(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 3 0.10
2 Polyoctanium-22 2.00
3 Monoethanolamine 1.00
4 Ammonia water 1.00
5 PEG-50 hydrogenated castor oil 0.20
6 Ammonium bicarbonate 2.00
7 Phosphoric acid 2Na 0.50
8 Ammonium thioglycolate aqueous solution 11.40
9 Cysteine 1.50
10 EDTA-4Na 0.15
11 Hydroxide Na 0.25
12 Polyquaternium-10 0.10
13 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. No. 13 in the majority of No. 13 11 is dissolved and then No. 11 is dissolved. No. 12 was added in small portions and dissolved. 8-10 were added and dissolved (part A). No. in a separate container. Take the rest of 13 6 and 7 were added, and it heated and dissolved (part B). No. in a separate container. 1-5 was added, it heated at about 50 degreeC, and it was made to melt | dissolve (part C). Part B was added to part A and mixed uniformly, then part C was gradually added and mixed uniformly.
(2 liquids)
Two liquids of Example 34 were used.

Example 36 Straight Perm Agent (Cation Type)
One part and two parts of a straight perm agent (cation type) having the following formulation were prepared. This straight perm agent was able to hold the hair firmly during the treatment, and was excellent in slipperiness after washing.

(1 liquid)
Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 2 1.00
2 Cetanol 5.00
3 Stealtrimonium chloride 2.40
4 Seths-20 2.40
5 Tribehenine PEG-20 2.00
6 Seths-6 0.80
7 Lauric acid monoisopropanolamide 0.80
8 PEG-60 hydrogenated castor oil 0.40
9 Ammonium thioglycolate (50%) 13.50
10 Monoethanolamine 1.70
11 Polyquaternium-6 1.30
12 Hydrolyzed soy protein 1.00
13 EDTA-4Na 0.10
14 Ammonia water (28%) 1.10
15 Purified water 66.50
--------------------------------
(Preparation method)
No. Most of 15 were heated to about 80 ° C. (Part A). No. in a separate container. 1-8 were added and it heated and dissolved (part B). No. in a separate container. No.15, no. 9 to 13 were added and dissolved uniformly (part C). Part B was added to part A, mixed and stirred, and part C was added at about 45 ° C. and mixed uniformly. After cooling to room temperature, no. 14 was added.

(2 liquids)
Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 2 0.10
2 Cetanol 5.00
3 Emacol VT-20 (Sanei Chemical) 5.00
4 Trioctanoin 2.00
5 Octyldodecanol 0.60
6 Seths-20 0.50
7 Diammonium phosphate 0.20
8 Benzoic acid Na 0.15
9 Na bromate 8.00
10 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1-6 were added, it heated at about 70 degreeC, and it was made to melt | dissolve (A part). No. in a separate container. 10 was taken and heated to about 70 ° C. 7 and 8 were added and dissolved (part B). No. in a separate container. Take the remainder of 10 and heat to about 60 ° C. 9 was added and dissolved (part C). At about 70 ° C., part B was added to part A and stirred until the viscosity increased. The mixture was cooled to 60 ° C., and part C was added with stirring and mixed uniformly. After the temperature dropped to about 50 ° C., it was rapidly cooled.

Example 37 Moose A mousse having the following formulation was prepared. This mousse suppressed the feeling of hair damage, was not sticky, and had excellent hairstyle retention.

Component Blending amount (% by weight)
--------------------------------
Polyester of Example 3 0.20
Ethanol 5.00
Polyethylene glycol oleyl ether (20) 1.00
Acrylic resin alkanolamine solution 3.00
Stearic acid diethylaminopropylamide 0.50
Pyrrolidone carboxylic acid 0.20
Preservatives, fragrance 1.00
Purified water Total amount of 100 --------------------------------
(Preparation method)
The above components were mixed, and the obtained base and LPG were mixed at a ratio of base: LPG = 92: 8 to obtain an injection-type mousse.

Example 38 Hair Cream A hair cream having the following formulation was prepared. This hair cream suppressed the feeling of hair damage, was not sticky, and was excellent in touch.

Component Blending amount (% by weight)
--------------------------------
Part A Stearic acid 2.00
Lanolin 3.00
Paraffin wax 2.00
Liquid paraffin 38.00
Polyester of Example 5 0.20
Glycerol monostearate (SE) 1.00
Sorbitan monostearate 1.00
Polyoxyethylene cetyl ether 1.50
Preservative appropriate amount Part B Triethanolamine 1.00
Part C 1,3-butylene glycol 3.00
(HEMA glucoside / ethyltrimonium methacrylate chloride) copolymer (20%, Nippon Seika) 2.50
Perfume Appropriate amount Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A was mixed at 80 ° C. Part B is diluted with a portion of purified water, heated to 80 ° C. and added to Part A (Part D). C part excluding fragrance is mixed, heated to 80 ° C., mixed with Part A, and uniformly did. After cooling to 50 ° C., a fragrance was added for production.

Example 39 Cleansing Foam A cleansing foam having the following formulation was prepared. This cleansing foam had good foaming, and it was rinsed from the time of cleansing and maintained a moist feel until washed up.

Component Blending amount (% by weight)
--------------------------------
Stearic acid K 10.00
Palmitic acid K 10.00
Myristic acid K 10.00
Lauric acid K 4.00
Lanolin 2.00
PEG 1500 10.00
Glycerin 15.00
Glyceryl monostearate2.00
POE (20) sorbitan monostearate 2.00
Oil of Example 9 1.50
Preservatives, fragrances Trace amount Purified water Total amount of 100 --------------------------------
(Preparation method)
All ingredients were mixed uniformly.

Example 40 Cleansing Gel A cleansing gel having the following formulation was prepared. This cleansing gel had a good foundation, makeup and the like, had a moderate thickness and was not sticky, and had an effect of giving a refreshing feel.

Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 4 8.00
2 Plandool-H (Nippon Seika) 2.00
3 Bell Paul DC-30 (Japan Seika) 2.00
4 LUSPLAN DD-IS (Nippon Seika) 15.00
5 PEG-25 hydrogenated castor oil 20.00
6 Glycerin 16.00
7 BG 5.00
8 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1-No. 7 is weighed and dissolved by heating to about 80 ° C. (A). No. 8 is weighed and heated to about 80 ° C. (B). While stirring, gradually add B to A, and cool to 40 ° C. after emulsification.

Example 41 Cleansing Cream A cleansing cream having the following formulation was prepared. This cleansing cream had good familiarity with makeup cosmetics and was excellent in cleansing effect.

Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 6 5.00
2 Ceresin 6.00
3 Mineral oil 35.00
4 Sorbitan sesquioleate 1.50
5 Oleic acid polyoxyethylene sorbitan 0.30
6 Paraffin 2.00
7 Butylparaben 0.10
8 Methylparaben 0.20
9 Trisodium edetate 0.02
10 Phenoxyethanol 0.20
11 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1 to 7 were heated to about 80 ° C. and dissolved (part A). No. 8-11 were added and heated to about 80 ° C. to dissolve (Part B). The part B was gradually added to the part A with stirring and emulsified, and then cooled to about 40 ° C. with stirring.

Example 42 Face Wash Foam A face wash foam having the following formulation was prepared. This face-washing foam had good foaming, and it was possible to obtain effects such as providing a smooth and smooth feel to the skin.

Component Blending amount (% by weight)
--------------------------------
1 Polyester of Example 3 0.30
2 (coconut fatty acid / hydrogenated beef tallow fatty acid) glutamic acid Na 20.00
3 Plandool-G (Nippon Seika) 0.50
4 Lauric acid diethanolamide 2.00
5 PEG-8 5.00
6 PEG-32 10.00
7 BG 14.00
8 Propylparaben 0.10
9 Methylparaben 0.20
10 Lipidure PMB (Japanese fat) 1.00
11 Crystalline cellulose 10.00
12 Tocopherol 0.20
13 Purified water Total amount of 100 --------------------------------
(Preparation method)
No. 1-9, no. 12 was heated to about 80 ° C. and dissolved. After dissolution, no. 13 was added and dissolved. While stirring at about 60 ° C., no. 10 and 11 were added and cooled.

Example 43 Body Shampoo A body shampoo having the following formulation was prepared. This body shampoo was foamy, moisturized and moistened, and the skin was soft.

Component Blending amount (% by weight)
--------------------------------
Polyester of Example 1 0.50
Cocoyl Methyl Taurine Na 10.00
Lauroyl hydrolyzed silk Na 6.00
Lauroylmethylalanine Na 10.00
Cocoamphoacetate Na (30%) 4.00
Cocamidopropyl betaine (30%) 10.00
Cocamide DEA 3.00
1,3-butylene glycol 5.00
Methylparaben 0.20
Purified water Total amount of 100 --------------------------------
(Production method)
All components were heated at about 80 ° C. and stirred and mixed uniformly.

Example 44 Hand Soap A hand soap having the following formulation was prepared. This hand soap had good foaming, moisturized, and soft skin.

Component Blending amount (% by weight)
-------------------------------
Part A Isethionate Na 1.00
Glycerin 50.00
Part B Lauroyl sarcosine salt 12.00
Myristoyl methyl taurine sodium 2.00
Polyglyceryl laurate-6 2.00
Palm oil fatty acid diethanolamide 2.00
Synthetic latex 0.10
Nitrocellulose 0.10
Sorbitol 8.00
Conchiolin-degrading peptide 0.10
Oil of Example 8 2.50
1,3-butylene glycol 8.00
Presome OR (Nippon Seika)
(Phospholipid / cholesterol / γ-oryzanol complex) 0.10
Phenoxyethanol 0.80
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A is heated to about 80 ° C. and dissolved. Add Part B to Part A, heat to about 80 ° C. to dissolve uniformly, and then cool.

Example 45 Lipstick A lipstick having the following formulation was prepared. This lipstick had a good feeling when applied and gave gloss to the lips and a soft feeling.

Component Blending amount (% by weight)
--------------------------------
Part A Polyester of Example 2 15.00
Triethylhexanoin 20.00
Cetyl ethylhexanoate Total amount of 100 cyclomethicone 16.00
Jojoba oil 1.00
Ceresin 9.00
Candelilla wax 5.00
Sorbitan sesquiisostearate 4.00
Diisostearyl malate 1.00
Dextrin palmitate 1.00
Stearyl dimethicone 0.05
Meadow Foam Oil 1.00
Tocopherol 0.50
Part B Iron oxide 2.25
Mica 1.50
Titanium oxide 2.25
Red 202 1.50
--------------------------------
(Preparation method)
Part A was heated to about 100 to 110 ° C. and dissolved uniformly. Next, part B was added and mixed with a roll mill. Part A and part B were added, heated to about 80 ° C., uniformly stirred and mixed, then filled into a mold and rapidly cooled.

Example 46 Lip Gloss A lip gloss having the following formulation was prepared. This lip gloss has a good feeling when applied, has an appropriate viscosity, and gives gloss to the lips and a soft feeling.

Component Blending amount (% by weight)
--------------------------------
Oil agent of Example 8 55.00
Polyethylene wax 0.20
Plandool-G (Nippon Seika) 2.00
12-hydroxystearic acid 1.50
Shea fat 0.10
Cyclopentasiloxane 1.00
Tocopherol Appropriate amount Liquid paraffin Amount to be 100 in total Part B Silylated ultrafine silica 2.00
(Aerosil R972 manufactured by Nippon Aerosil Co., Ltd.)
Mica titanium 12.00
--------------------------------
(Preparation method)
After all the ingredients were uniformly heated and mixed, part B was added and mixed uniformly.

Example 47 Foundation A foundation having the following formulation was prepared. This foundation had good adhesion to the skin and gave the skin a soft feeling.

Component Blending amount (% by weight)
--------------------------------
Polyester of Example 6 5.00
Cyclomethicone 3.50
Dimethicone (5cs) 2.00
YOFCO MAS (Nippon Seika) 1.00
Trimethylsiloxysilicate 1.50
Octyl methoxycinnamate 1.00
Phenoxyethanol 0.40
Tocopherol 0.10
Mica 39.60
Talc Total amount of 100 Titanium oxide 20.00
Iron oxide 1.90
--------------------------------
(Preparation method)
All ingredients were stirred at high speed and mixed uniformly.

Example 48 Eye Shadow An eye shadow having the following formulation was produced. This eye shadow had good adhesion and good usability.

Component Blending amount (% by weight)
--------------------------------
1 Talc 10.00
2 Kaolin 2.00
3 facial 5.00
4 Oil of Example 9 1.00
5 Stearic acid 3.00
6 Isopropyl myristate 8.00
7 Liquid paraffin 8.00
8 Propylene glycol monolaurate 5.00
9 Antioxidant appropriate amount 10 fragrance proper amount 11 1,3-butylene glycol 5.00
12 Glycerin 1.00
13 Preservative Appropriate amount 14 Triethanolamine 1.20
15 Metal ion sequestering agent Appropriate amount 16 Purified water Amount to be 100 in total -------------------------------
(Preparation method)
No. 1-3 were mixed with a blender and then processed with a pulverizer (powder part). No. 11 to 16 were heated and dissolved at 70 to 75 ° C. (aqueous phase part). No. 4 to 10 were dissolved by heating at 70 to 80 ° C. (oil phase part). The powder part was added to the aqueous phase part and mixed with stirring. The oil phase was added to this while stirring, dispersed with a homomixer, and stirred and cooled to room temperature to obtain the desired eye shadow.

Example 49 Mascara A mascara having the following formulation was produced. This mascara had good adhesion, good usability, and good stability.

Component Blending amount (% by weight)
--------------------------------
1 Iron oxide (black) 10.00
2 Light isoparaffin 30.00
3 Polyacrylate emulsion 30.00
4 Solid paraffin 8.00
5 Oil of Example 7 7.00
6 Sorbitan sesquioleate 4.00
7 Preservatives Appropriate amount 8 Perfume Appropriate amount 9 Purified water Total amount of 100 ----------------------------
(Preparation method)
No. No. 9 no. No. 1 was added and dispersed with a homomixer. 3 was added and heated to 70 ° C (aqueous phase). The other ingredients were mixed and heated to 70 ° C. (oil phase). The aqueous phase was added to the oil phase, and the mixture was uniformly emulsified and dispersed with a homomixer to obtain the desired mascara.

Example 50 Skin Care Cream A cream having the following formulation was prepared. This cream is excellent in feeling of use, softens the skin, and the skin after use is moist and moist, and these effects last for a long time.

Component Blending amount (% by weight)
--------------------------------
Part A BG 8.00
Glycerin 5.00
Phytocompo-PP (Nippon Seika) 0.50
Phytopresome Q10 (Nippon Seika) 0.50
Phytopresome Cera-2 (Nippon Seika) 0.20
Part B Macadamia nut oil fatty acid phytosteryl (Nippon Seika) 2.00
Glyceryl amidomethacrylate /
Stearyl methacrylate copolymer 0.05
Diethylhexyl sebacate 2.10
Hardened oil 4.50
Stearyl alcohol 1.20
Behenyl alcohol 1.80
Lipophilic glyceryl monostearate 1.80
POE (60) glyceryl isostearate 1.10
Stearic acid PG (SE) 1.00
Methyl polysiloxane (10cs) 1.50
Polyglyceryl-3disiloxane dimethicone 0.20
Laurylpolyglyceryl-3polydimethylsiloxyethyl dimethicone 0.20
Ethyl hexyl methoxycinnamate 0.15
Oil agent of Example 10 1.00
Ethylparaben 0.15
Part C Cyclohexanedicarboxylic acid bisethoxydiglycol 1.00
(Eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10
2.00
Methylparaben 0.10
Oxybenzone-4 0.10
Phenoxyethanol 0.20
Carbomer 0.25
Hydroxide K 0.20
Tranexamic acid 0.50
Purified water Total amount of 100 ---------------------------------
(Preparation method)
Part A is heated to about 70 ° C. and dispersed uniformly. Part B is heated to about 80 ° C. and dissolved uniformly. Add part C and stir well to make uniform. Add Part B to Part A and emulsify at about 80 ° C. using a homomixer. Then cool with stirring and add part C at about 60 ° C. Stir and cool to about 40 ° C.

Example 51 Cream A cream having the following formulation was prepared. This cream softens the skin after use and is moist and moist, and these effects last for a long time.

Component Blending amount (% by weight)
--------------------------------
Part A Plandool-G (Nihon Seika) 7.00
Plandool-H (Nippon Seika) 1.00
Diisopropyl sebacate 2.00
Diethylhexyl sebacate 1.00
CIO (Nippon Seika) 5.00
Batyl isostearate 2.00
PEG-60 glyceryl isostearate 1.50
Polyester of Example 6 0.50
Shea fat 0.10
Cyclopentasiloxane 1.00
Meadow Foam Oil 1.00
Ceramide 2 0.01
Ceramide 3 0.01
Ceramide 6 0.01
Isostearyl pivalate 0.10
Tetraethylhexanoic acid pentaerythritol 0.10
Ethylparaben 0.20
Stearyl alcohol 3.50
Glyceryl stearate (SE) 1.00
Triisostearic acid hydrogenated castor oil 1.00
Steerless-6 1.50
Distearic acid PEG-8 1.00
Cetanol 1.00
Dimethicone 1.00
Polyglycerin-modified silicone 0.50
Tocopherol 0.10
Part B white jellyfish polysaccharide 0.05
Tuberose polysaccharide 0.01
Water-soluble collagen 0.05
Hydrolyzed collagen 0.05
2-Methacryloyloxyethyl phosphorylcholine
Butyl methacrylate copolymer solution 0.05
(HEMA glucoside / ethyltrimonium methacrylate methacrylate) copolymer (20%, Nippon Seika) 0.40
Part C Cyclohexanedicarboxylic acid bisethoxydiglycol 1.00
(Eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10
1.00
Pyrosulfite Na 0.10
Imidazolinium urea 0.10
Polyvinylpyrrolidone 0.10
Pullulan 0.10
Polyvinyl alcohol 0.10
Dehydroacetic acid 0.10
BG 2.00
PEG 1.00
Glycerin 1.00
Diglycerin 1.00
Polyglycerin 1.00
Pentate acid 0.05
Phosphoric acid, Na phosphate appropriate amount Na hydroxide proper amount Purified water Amount that will be 100 in total ------------------------------ −−
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. Part C was heated to about 80 ° C. and dissolved. While stirring with a homomixer at about 80 ° C., part C was gradually added to part A, mixed uniformly after emulsification, cooled to about 40 ° C., part B was added and mixed uniformly. Phosphoric acid and phosphoric acid Na were added to adjust the pH to 4.5 to 5.5.

Example 52 Hand Cream A hand cream having the following formulation was prepared. This hand cream was non-sticky and water-repellent hand cream.

Component Blending amount (% by weight)
--------------------------------
Part A Plandool-G (Nippon Seika) 0.30
Dimethicone 2.00
(Dimethicone / vinyl dimethicone) Cross polymer 0.10
(Vinyl Dimethicone / Lauryl Dimethicone) Cross Polymer 0.10
(Dimethicone / PEG-10 / 15) Crosspolymer 0.10
(PEG-15 / Lauryl Dimethicone) Crosspolymer 0.10
(Alkyl acrylate / dimethicone) copolymer 0.10
Behenyl alcohol 2.50
CIO (Nippon Seika) 3.00
Oil of Example 7 3.70
Propylparaben 0.10
Dimethicone 4.00
Mineral oil 1.00
Part B Hydrogenated lecithin 1.00
BG 5.00
Methylparaben 0.20
Part C Xanthan gum (2% aqueous solution) 15.00
Water Total amount of 100 --------------------------------
(Preparation method)
After part B is dissolved, part A is added and heated to about 70 ° C. (part D). Bring Part C to about 70 ° C. Add Part C to Part D with stirring and stir and mix with a homomixer for about 3 minutes. After mixing uniformly, cool to about 40 ° C.

Example 53 Hand Cream A hand cream having the following formulation was prepared. This hand cream was non-sticky and water-repellent hand cream.

Component Blending amount (% by weight)
--------------------------------
Part A liquid paraffin 20.00
Vaseline 20.00
Microcrystalline wax 4.00
Stearic acid Al 1.50
Mg stearate 1.00
Stearic acid Ca 0.10
Part B Polyester of Example 5 2.00
Lanolin Fatty Acid Cholesteryl 2.00
Propylparaben 0.10
Tocopherol 0.05
Cyclopentasiloxane 5.00
Dimethicone 5.00
Part C Methylparaben 0.10
Water Total amount of 100 --------------------------------
(Preparation method)
Part C is heated to about 80 ° C. and dissolved. Take part A in another container, heat to 100-120 ° C., turn into a transparent gel, and cool to 80 ° C. The polyester of Example 5 is added to A part among B parts, and is stirred. Further, the remaining part B is added and dissolved by heating at about 80 ° C. (part D). Add Part C to Part D with stirring and emulsify. After mixing uniformly, cool to about 40 ° C.

Example 54 Sunscreen Agent A sunscreen agent having the following formulation was prepared. This sunscreen agent was excellent in water repellency, was not sticky, and gave a moist and soft feeling to the skin.

Component Blending amount (% by weight)
--------------------------------
Part A Quotanium-18 Hectorite 1.00
Part B Cyclomethicone 13.70
Diphenyl dimethicone 7.00
Dimethicone copolyol 5.50
Part C Silicone-treated fine particle titanium oxide 3.90
Silicone-treated zinc oxide 2.10
D part Al stearate 0.70
Hydroxide Al 0.50
Isononyl isononanoate 2.50
Isodecyl neopentanoate 1.50
Neosolue-DE (Nippon Seika) 1.00
Polyester of Example 5 2.00
Part E Trimethylsiloxysilicate 1.20
Dimethicone 0.80
Meticon 0.10
Polymethylsilsesquioxane 0.10
Trifluoroalkyldimethyltrimethylsiloxysilicate 0.10
Cetearyl dimethicone crosspolymer 0.10
Stearyl glycyrrhetinate 0.02
Sorbitan sesquioleate 2.00
Tocopherol 0.02
Part F Na chloride 1.00
Methylparaben 0.15
Purified water Total amount of 100 --------------------------------
(Production method)
Add Part A to Part B and stir. Further, part C was added and dispersed using a roller mill. Part D was heated and melted, added to the mixture of A, B, and C, and further part E was added to about 70 ° C. Part F was heated, gradually added to the mixture of A to E with stirring and emulsified, and then cooled to 40 ° C. with stirring.

Example 55 Hair Oil A hair oil having the following formulation was prepared. This hair oil was glossy, non-sticky and smooth when applied to hair.

Component Blending amount (% by weight)
--------------------------------
Oil of Example 8 10.00
Dimethiconol 2.00
Dimethicone 2.00
Neosolue-DE (Nippon Seika) 10.00
Neosolute-EHS (Nippon Seika) 10.00
Neosolute-MCT (Nippon Seika) 20.00
Tocopherol 0.10
Propylparaben 0.10
Cyclopentasiloxane Total amount of 100 --------------------------------
(Preparation method)
All ingredients were dissolved by heating and mixed.

Example 56 Cleansing Oil This cleansing oil had a refreshed feel and was well-familiar with foundations, makeup, etc., and could be quickly removed.

Component Blending amount (% by weight)
--------------------------------
Oil agent of Example 10 60.00
Laureth-4 7.00
Tocopherol Appropriate amount Propylparaben Appropriate amount Cetyl octanoate Total amount of 100 Mineral oil 10.00
--------------------------------
(Preparation method)
All ingredients were dissolved by heating and mixed.

Claims (8)

  A polyester used in cosmetics having a weight average molecular weight of 30,000 to 1,000,000, comprising one or both of dimer acid and dimer diol as a constituent unit.   A polyester used in cosmetics having a weight average molecular weight of 30,000 to 1,000,000, comprising both dimer acid and dimer diol as constituent units.   The polyester according to claim 1 or 2, having a weight average molecular weight of 70,000 to 500,000.   The polyester according to any one of claims 1 to 3, wherein the dimer acid is a hydrogenated dimer acid.   Cosmetic oil containing the polyester according to any one of claims 1 to 4.   Cosmetics containing the polyester according to any one of claims 1 to 4.   A hair cosmetic containing the polyester according to any one of claims 1 to 4. A makeup cosmetic comprising the polyester according to claim 1.