JP6883534B2 - Fullerene-containing cosmetic composition - Google Patents

Description

The present invention relates to a composition for cosmetics containing fullerene and a cosmetic using the composition for cosmetics.

In recent years, attempts to use fullerenes in cosmetics have been widely made, and the trend has become stronger and stronger, especially since the active oxygen scavenging ability of fullerenes became known. In addition to the ability to eliminate active oxygen, there are various examples of application of fullerene to cosmetics, such as application as a pigment (Patent Document 1), application as an ultraviolet absorber (Patent Document 2), and application as a melanin inhibitor (Patent Document 1). Document 3), application as a wrinkle inhibitor (Patent Document 4), application as a hair damage inhibitor (Patent Document 5), and the like are known.

On the other hand, fullerenes are poorly soluble substances, and in particular, they are insoluble in water, so it is very difficult to add them as they are to water-based formulations. As a method for solving such a problem, for example, a method of complexing with a water-soluble polymer such as polyvinylpyrrolidone and dispersing it in water is known (Patent Document 6). However, in this method, there is a problem that the water-soluble polymer used may have an unfavorable feel, and the effect of fullerene may not be sufficiently exhibited depending on the application. As another method, a method of encapsulating a liposome using a phospholipid and dispersing it in water is known (Patent Document 7). However, since the preparation of liposomes requires a complicated process, it cannot be said that it is a simple method for preparing an aqueous dispersion of fullerenes. As another method, there is known a method in which fullerenes are once dissolved in hydrocarbon oil or the like and then emulsified using a surfactant (Patent Document 8). However, even in such a method, the preparation is not always simple, and the obtained aqueous dispersion has poor transparency and the dispersion stability is not sufficient.

Japanese Unexamined Patent Publication No. 06-192039 Japanese Unexamined Patent Publication No. 09-278625 Japanese Unexamined Patent Publication No. 2007-131536 International Publication No. 2009/11426 Japanese Unexamined Patent Publication No. 2016-169215 Japanese Unexamined Patent Publication No. 2005-060380 Japanese Unexamined Patent Publication No. 2009-242380 Japanese Unexamined Patent Publication No. 2008-255107

An object of the present invention is to provide a cosmetic composition capable of easily dispersing fullerenes in water.
Another object of the present invention is to provide a cosmetic composition having a transparent appearance and excellent dispersion stability in the fullerene-containing aqueous dispersion prepared by using the composition.

As a result of diligent studies to solve the above problems, the present inventors have made it possible to easily disperse fullerenes in water by using cosmetic compositions containing the following components (A) to (E). The present invention was completed by finding that the above problems could be solved.
(A) Oil containing 0.001 to 0.3% by weight of fullerene (B) Nonionic surfactant (C) Polyhydric alcohol (D) Oil (E) Water Further, the cosmetic composition is biconti. It has been found that the fullerene-containing aqueous dispersion prepared by using the composition has a transparent appearance and is excellent in dispersion stability due to having a nuas structure, and solves the above-mentioned problems. , The present invention has been completed.

By using the cosmetic composition of the present invention, fullerenes can be easily dispersed in water.
Further, since the cosmetic composition has a bicontinuous structure, the obtained aqueous dispersion has a transparent appearance, and its dispersion stability is very good.

FIG. 5 is a graph showing the relationship between the number of damages after hair dyeing and the measured ΔE in Example 51. It is a graph which shows the result of quantifying the amount of cysteic acid in the hair generated by ultraviolet rays about the composition for cosmetics of Example 1. FIG.

The cosmetic composition of the present invention contains the following components (A) to (E) as essential components.
(A) Oil containing 0.001 to 0.3% by weight of fullerene (B) Nonionic surfactant (C) Polyhydric alcohol (D) Oil (E) Water

The component (A) used in the present invention means an oil agent in which fullerene is dissolved at a concentration of 0.001 to 0.3% by weight with respect to the oil agent, and the concentration of fullerene is more preferably 0. It is 01 to 0.28% by weight, most preferably 0.03 to 0.25% by weight. The method for dissolving fullerene in an oil agent is not particularly limited, and the oil agent and fullerene can be prepared by heating and dissolving while stirring. Alternatively, it can be prepared by a method as described in JP-A-2011-256095 in order to dissolve fullerene at a higher concentration. Specifically, it can be prepared by first dissolving fullerene in a solvent such as toluene or cyclohexane, then adding an oil agent so that the fullerene has a predetermined concentration, and distilling off the solvent under reduced pressure.

Fullerene used in the component (A) of the present invention is a general term for spherical shell-shaped molecules composed of carbon atoms, and has C ₆₀ , C ₇₀ , C ₇₆ , C ₇₈ , C ₈₂ , and the number of carbon atoms thereof. Those of C ₈₄ , C ₉₀ , and C ₉₆ are known. Any of such fullerenes can be used in the present invention. These fullerenes may be used alone or in combination of two or more. Of these, from the viewpoint of solubility in oils and availability, _{it is preferable to use C 60} , C ₇₀ , and a mixture thereof.

The oil agent used in the component (A) of the present invention is not particularly limited as long as it is an oil agent that dissolves fullerenes, and specifically, a lactone derivative, an ester oil, a vegetable oil, a hydrocarbon oil, or the like can be used. May be used alone or in combination of two or more. Of these, lactone derivatives and ester oils are preferable, and it is most preferable to use both of them from the viewpoint of dissolving fullerenes in a stable and high concentration.

（式中、ｎは１又は２であり、Ｒは炭素数９〜２２の直鎖又は分岐鎖の飽和又は不飽和炭化水素基を表す）
上記一般式（１）中のＲとしては、具体的には、ノニル基、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基、オクタデシル基、ノナデシル基、エイコシル基、ヘンイコシル基、ドコシル基等が挙げられ、これらのうち、原料の入手しやすさ、合成のしやすさなどの面から、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基、オクタデシル基、エイコシル基、ヘンイコシル基がより好ましく、デシル基、ドデシル基、テトラデシル基、オクタデシル基が最も好ましい。また、式中のｎとしては１の化合物が好ましい。このようなラクトン誘導体の最も好ましいものとしては、γ−テトラデカラクトン、γ−ヘキサデカラクトン、γ−オクタデカラクトン、γ−イコサラクトン、γ−ドコサラクトン等が挙げられる。 More specifically, the lactone derivative used in the component (A) includes a compound represented by the following general formula (1) as the lactone derivative.

(In the formula, n is 1 or 2, and R represents a saturated or unsaturated hydrocarbon group of a linear or branched chain having 9 to 22 carbon atoms.)
Specifically, R in the general formula (1) includes a nonyl group, a decyl group, an undecylic group, a dodecyl group, a tridecylic group, a tetradecyl group, a pentadecyl group, a hexadecyl group, a heptadecyl group, an octadecyl group, and a nonadecil group. Eikosyl group, henicosyl group, docosyl group, etc. are mentioned, and among these, decyl group, undecylic group, dodecyl group, tridecylic group, tetradecyl group, pentadecyl group are mentioned in terms of availability of raw materials and easiness of synthesis. A group, a hexadecyl group, a heptadecyl group, an octadecyl group, an eicosyl group, and a henicosyl group are more preferable, and a decyl group, a dodecyl group, a tetradecylic group, and an octadecyl group are most preferable. Further, as n in the formula, the compound of 1 is preferable. The most preferable of such a lactone derivative is γ-tetradecalactone, γ-hexadecalactone, γ-octadecalactone, γ-icosalactone, γ-docosalactone and the like.

More specifically, the ester oil used in the component (A) is glyceryl triethylhexanate, glyceryl tricaprylate, glyceryl tricaprate, glyceryl tri (capric acid / capric acid), glyceryl trioleate, triisostearic acid. Glyceryl, trimethyl propane triethylhexanoate, pentaerythrityl tetraethylhexanoate, 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoate, cetyl ethylhexanoate, ethyl Hexyldecyl hexanoate, Isononyl isononanoate, Isodecyl isononanoate, Isotridecyl isononanoate, Isodecyl neopentate, Isotridecyl neopentate, Isostearyl neopentate, Octyldodecyl neodecanoate, Isopropyl myristate, Hexyldecyl myristate, Octyldodecyl myristate Isopropyl acid, ethylhexyl palmitate, cetyl palmitate, octyldodecyl palmitate, ethyl oleate, oleyl oleate, octyldodecyl oleate, isopropyl isostearate, octyldodecyl isostearate, octyldodecyl erucate, lanolin fatty acid isopropyl, lanolin fatty acid octyl Examples thereof include dodecyl, dicaprylyl carbonate, diethylhexyl succinate, diisopropyl adipate, diisobutyl adipate, diethyl sebacate, diisopropyl sebacate, diethylhexyl sebacate, triethyl citrate, and diisostearyl malate. Of these, glyceryl triethylhexanoate, tri (caprylic acid / capric acid) glyceryl, cetyl ethylhexanoate, ethylhexyl palmitate, and diethylhexyl sebacate are preferred, and tri (caprylic acid / capric acid) glyceryl, ethyl. Cetyl hexanoate is most preferred.

The nonionic surfactant of the component (B) used in the present invention includes polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene fatty acid ester and polyoxyethylene alkyl ether. One or more selected species can be used. These may be used alone or in combination of two or more.

Specific examples of the polyglycerin fatty acid ester include monoesters, diesters, triesters, and tetraesters of fatty acids having 8 to 22 carbon atoms and polyglycerin having a degree of polymerization of 2 to 20. Of these, the preferred ones are polyglyceryl caprylate, polyglyceryl caprate, polyglyceryl laurate, polyglyceryl myristate, polyglyceryl palmitate, polyglyceryl stearate, polyglyceryl oleate, polyglyceryl isostearate, polyglyceryl behate, polyglyceryl dicaprylate, and polyglyceryl dicaprylate. , Polyglyceryl dilaurate, polyglyceryl dimyristate, polyglyceryl dipalmitate, polyglyceryl distearate, polyglyceryl dioleate, polyglyceryl diisostearate, polyglyceryl dibechenate, polyglyceryl tricaprylate, polyglyceryl tricaprate, polyglyceryl trimyristic Polyglyceryl acid, polyglyceryl tristearate, polyglyceryl trioleate, polyglyceryl triisostearate, polyglyceryl tribechenate, etc. include polyglyceryl laurate, polyglyceryl stearate, polyglyceryl isostearate, polyglyceryl dilaurate, polyglyceryl distearate, polyglyceryl diisostearate. Most preferred.

Specific examples of the polyoxyethylene glycerin fatty acid ester include monoesters and diesters of glycerin polyoxyethylene adduct having 4 to 200 molar additions of polyoxyethylene (EO) and fatty acids having 8 to 22 carbon atoms. Triester and the like can be mentioned. Of these, the preferred ones are polyoxyethylene glycerin caprylate, polyoxyethylene glycerin caprate, polyoxyethylene glycerin laurate, polyoxyethylene glycerin myristate, polyoxyethylene glycerin palmitate, polyoxyethylene glycerin stearate, and olein. Polyoxyethylene glycerin acid, polyoxyethylene glycerin isostearate, polyoxyethylene glycerin dicaprylate, polyoxyethylene glycerin dicaprate, polyoxyethylene glycerin dilaurylate, polyoxyethylene glycerin dimyristate, polyoxyethylene glycerin dipalmitate, Polyoxyethylene glycerin distearate, polyoxyethylene glycerin dioleate, polyoxyethylene glycerin diisostearate, polyoxyethylene glycerin tricaprylate, polyoxyethylene glycerin tricaprate, polyoxyethylene glycerin trilaurylate, polyoxyethylene glycerin trimyristate, Examples thereof include polyoxyethylene glycerin tripalmitate, polyoxyethylene glycerin tristearate, polyoxyethylene glycerin trioleate, polyoxyethylene glycerin triisostearate, polyoxyethylene glycerin laurylate, polyoxyethylene glycerin stearate, and the like. Polyoxyethylene glycerin isostearate is most preferred.

Specific examples of the polyoxyethylene sorbitan fatty acid ester include monoesters and diesters of a sorbitan polyoxyethylene adduct having 4 to 200 moles of polyoxyethylene (EO) and a fatty acid having 8 to 22 carbon atoms. Examples thereof include triesters and tetraesters. Of these, the preferred ones are polyoxyethylene sorbitan caprylate, polyoxyethylene sorbitan caprate, polyoxyethylene sorbitan laurate, polyoxyethylene sorbitan myristate, polyoxyethylene sorbitan palmitate, polyoxyethylene sorbitan stearate, and olein. Polyoxyethylene sorbitan acid, polyoxyethylene sorbitan isostearate, polyoxyethylene sorbitan dicaprylate, polyoxyethylene sorbitan dicaprate, polyoxyethylene sorbitan dilaurylate, polyoxyethylene sorbitan dimyristate, polyoxyethylene sorbitan dipalmitate, Polyoxyethylene sorbitan disstearate, polyoxyethylene sorbitan dioreate, polyoxyethylene sorbitan diisostearate, polyoxyethylene sorbitan tricaprylate, polyoxyethylene sorbitan tricaprate, polyoxyethylene sorbitan trilaurylate, polyoxyethylene sorbitan trimyristate, Examples thereof include polyoxyethylene sorbitan tripalmitate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate, polyoxyethylene sorbitan triisostearate, and polyoxyethylene sorbitan laurate, polyoxyethylene sorbitan stearate, Polyoxyethylene sorbitan isostearate, polyoxyethylene sorbitan trilaurylate, polyoxyethylene sorbitan tristearate, and polyoxyethylene sorbitan triisostearate are most preferred.

Specific examples of the polyoxyethylene fatty acid ester include monoesters and diesters of polyoxyethylene having an addition molar number of 4 to 200 and a fatty acid having 8 to 22 carbon atoms. Of these, preferred are polyoxyethylene caprylate, polyoxyethylene caprate, polyoxyethylene laurylate, polyoxyethylene myristate, polyoxyethylene palmitate, polyoxyethylene stearate, polyoxyethylene oleate, and isostear. Polyoxyethylene Acid, Polyoxyethylene Behenate, Polyoxyethylene Dicaprylate, Polyoxyethylene Dicaprate, Polyoxyethylene Dilaurylate, Polyoxyethylene Dimyristate, Polyoxyethylene Dipalmitate, Polyoxyethylene Distearate, Diorene Examples thereof include polyoxyethylene acid, polyoxyethylene diisostearate, and polyoxyethylene dibechenate, with polyoxyethylene laurate, polyoxyethylene stearate, polyoxyethylene oleate, and polyoxyethylene isostearate being most preferred.

Specific examples of the polyoxyethylene alkyl ether include polyoxyethylene having an addition molar number of 4 to 200, an alkyl group having 8 to 22 carbon atoms, and a monoether. Of these, preferred are polyoxyethylene capryl ether, polyoxyethylene caprylyl ether, polyoxyethylene lauryl ether, polyoxyethylene myristyl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, and polyoxyethylene oleyl ether. Examples thereof include polyoxyethylene isosteyl ether and polyoxyethylene behenyl ether, with polyoxyethylene lauryl ether, polyoxyethylene stearyl ether and polyoxyethylene behenyl ether being the most preferable.

As the nonionic surfactant of the above component (B), the storage stability of the cosmetic composition and the transparency and dispersion stability of the aqueous dispersion prepared by using the cosmetic composition are exhibited. From the viewpoint of improvement, it is preferable to use a mixture of two or more. The individual HLB of the nonionic surfactant used is not particularly limited, but the HLB of the component (B) as a whole is preferably 5 to 16, and more preferably 7 to 14. Among these nonionic surfactants, polyglycerin fatty acid ester is preferable from the viewpoint of improving the storage stability of fullerene, and polyglyceryl laurate, polyglyceryl stearate, polyglyceryl isostearate, polyglyceryl dilaurate, polyglyceryl distearate, and diisostearate are preferable. Polyglyceryl acid acid is most preferred.

Examples of the polyhydric alcohol of the component (C) used in the present invention include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, and 2-methyl-. 1,3-Propanediol, trimethylolpropane, pentaerythritol, sorbitol, pentylene glycol, hexylene glycol, 1,2-hexanediol, caprylyl glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, Polyethylene glycol and the like can be mentioned. These polyhydric alcohols may be used alone or in combination of two or more. Of these, glycerin and 1,3-butylene glycol are preferable from the viewpoint of stability, and it is more preferable to use both of them.

Examples of the oil agent of the component (D) used in the present invention include hydrocarbon oils such as dodecane, isododecane, hexadecane, isohexadecane, liquid paraffin, heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, squalane, and hydrogenated polyisobutene. ; Palm oil, palm oil, palm kernel oil, saflower oil, olive oil, castor oil, avocado oil, sesame oil, brown oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, argania Spinosa kernel oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, camellia oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, flaxseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, coconut oil, Vegetable oils such as shea butter, hydrogenated coconut oil, hydrogenated coconut oil, jojoba oil, hydrogenated jojoba oil; glyceryl triethylhexanoate, glyceryl tricaprylate, glyceryl tricaprate, tri (capric acid / capric acid) glyceryl, trioleic acid Glyceryl, Glyceryl triisostearate, Trimethylolpropane triethylhexanoate, Pentaerythrityl tetraethylhexanoate, 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoate, ethyl Cetyl hexanoate, hexyldecyl ethylhexanoate, isononyl isononanoate, isodecyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentate, octyldodecyl neodecanoate, isopropyl myristate, hexyldecyl myristine, myristin Octyldodecyl acid, isopropyl palmitate, ethylhexyl palmitate, cetyl palmitate, octyldodecyl palmitate, ethyl oleate, oleyl oleate, octyldodecyl oleate, isopropyl isostearate, octyldodecyl isostearate, octyldodecyl erucate, lanolin fatty acid Isopropyl, lanolin fatty acid octyldodecyl, dicaprylyl carbonate, diethylhexyl succinate, diisopropyl adipate, diisobutyl adipate, diethyl sebacate, diisopropyl sebacate, diethylhexyl sebacate, triethyl citrate, diisostearyl malate, dimer dilinoleic acid Diisostearyl, hydrogenation Ester oils such as dinolate (isostearyl / phytosteryl), di-lauroyl-L-glutamate (phytosteryl / octyldodecyl); (eicosanedioic acid / tetradecanedioic acid) polyglyceryl-10, bisethoxydiglycol succinate, cyclohexane Almogenous ester oils such as bisethoxydiglycol dicarboxylic acid; lactone derivatives such as γ-tetradecalactone, γ-hexadecalactone, γ-octadecalactone, γ-icosalactone, γ-docosalactone; dimethicone, cyclomethicone, Examples thereof include silicone oils such as phenyldimethicone. These oils may be used alone, or may be used in combination of two or more, and may contain the same oils as those used in the component (A). In addition to these, oily components generally used in cosmetics can be added as long as the effects of the present invention are not impaired. Of these, from the viewpoint of stability of the cosmetic composition, it is preferable to contain hydrocarbon oil such as liquid paraffin and squalane as an essential component, and 50% by weight or more of the hydrocarbon oil is contained in the component (D). It is preferable to contain 70% by weight or more.

The water of the component (E) used in the present invention is not particularly limited as long as it can be usually used in cosmetics, and purified water, ion-exchanged water, distilled water, natural water, deep ocean water, hydrogen water and the like can be used. Can be used. Further, the pH may be adjusted with an acid, an alkali, a buffer, a chelating agent or the like, or an antiseptic may be added.

The cosmetic composition of the present invention contains the above-mentioned components (A) to (E), but is prepared by using the cosmetic composition and the storage stability of the cosmetic composition. From the viewpoint of improving the transparency and dispersion stability of the aqueous dispersion, it is more preferable to have a bicontinuous structure. In the present invention, the bicontinuous structure means a state in which both the aqueous phase and the oil phase form a continuous phase, and the oil phase or the aqueous phase is contained in a medium having the aqueous phase or the oil phase as the continuous phase. It means that it is different from the general emulsion form dispersed. When it has a bicontinuous structure, both the aqueous phase and the oil phase form a continuous phase. Therefore, when a liquid in which a water-soluble dye is dissolved in water is added, or when an oil-soluble dye is dissolved in oil. When the liquid is added, in any case, the composition is uniformly colored in the hue of each dye. Such a method can be used to confirm the bicontinuous structure. It is also possible to confirm by a method that combines observation with an electron microscope by a freeze-cutting replica method, observation with an appearance, observation with an optical polarizing microscope, measurement of electrical conductivity, and the like.

The content of each component of the cosmetic composition of the present invention is such that the content of the component (A) is 1 to 20% by weight and the content of the component (B) is 15 from the viewpoint of forming a bicontinuous structure. ~ 45% by weight, the content of the component (C) is 10 to 35% by weight, the content of the component (D) is 5 to 35% by weight, and the content of the component (E) is 10 to 40% by weight. Preferably, more preferably, the content of the component (A) is 5 to 15% by weight, the content of the component (B) is 20 to 40%, the content of the component (C) is 15 to 30% by weight, and the component (D). ) Is 10 to 25% by weight, and the content of the component (E) is 15 to 35% by weight. The method for producing the cosmetic composition of the present invention is not particularly limited, and can be prepared by uniformly stirring each component.

The cosmetic composition of the present invention thus obtained can be easily prepared as an aqueous dispersion containing fullerene by adding it to an aqueous medium and stirring it. At this time, a special device such as a vortex mixer or a homogenizer is not required, and the production can be sufficiently performed with a stirring force such as a propeller or a stirrer. In addition, it does not need to be heated at the time of dispersion, and can be manufactured at room temperature. Further, the fullerene-containing aqueous dispersion thus obtained has a transparent appearance, and its dispersion stability is very good. In the present invention, the term "transparent" means a transparent feeling such that the back of the liquid can be seen through when the sample is placed in a glass bottle having a diameter of 3.5 cm and observed from the side. When the turbidity is measured with a spectrophotometer, the transmittance when the sample is placed in a cell having a thickness of 1 cm and measured at a wavelength of 600 nm is 60% or more.

The amount of the cosmetic composition of the present invention to be blended in the cosmetic is not particularly limited, but is preferably 0.01 to 30% by mass, more preferably 0, from the viewpoint of the appearance and stability of the obtained cosmetic. It is 0.05 to 10% by mass.

Cosmetics containing the cosmetic composition of the present invention include, if necessary, water and additive components usually added to cosmetics, such as oily bases, surfactants, alcohols, moisturizers, polymers, and the like. Thickeners / gelling agents, antioxidants, preservatives, bactericides, chelating agents, pH regulators / acids / alkalis, UV absorbers, whitening agents, solvents, keratin stripping / dissolving agents, antipruritic agents, anti-inflammatory agents, anti-inflammatory agents Sweat agents, refreshing agents, antihistamines, astringents, stimulants, hair growth agents / blood circulation promoters, reducing agents / oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, sugars and their derivatives, organic Acids, enzymes, nucleic acids, hormones, inorganic powders, fragrances, pigments and the like may be contained to the extent that the effects of the present invention are not impaired.

Oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, araquil alcohol, behenyl alcohol, jojoba alcohol, chimil alcohol, seraquil alcohol, bacil alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimerdiol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Higher grades such as palmitooleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, eikosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long chain branched fatty acids, dimer acid, hydrogenated dimer acid, etc. Fatty acids and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium and sodium salts, and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin , Α-Olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalane, vaseline, solid paraffin and other hydrocarbons; candelilla wax, carnauba wax, rice wax, wood wax, honey wax, montan wax , Ozokerite, Celesin, Paraffin wax, Microcrystalin wax, Petrolatum, Fishertroph wax, Polyethylene wax, Ethylene-propylene copolymer and other waxes; Palm oil, Palm oil, Palm kernel oil, Saflower oil, Olive oil, Himasi oil, Avocado Oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rose hip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat Vegetable oils and fats such as germ oil, flaxseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated palm oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef fat, milk fat, Animal oils and fats such as horse fat, egg yolk oil, mink oil and turtle oil; animal waxes such as whale wax, lanolin and orange raffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption-purified lanolin, lanolin acetate, liquid acetate lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine , Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin and other sphingolin lipids, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof, phospholipids such as lysolecithin; hydrogenated soybean phospholipids, partially hydrogenated soybeans Phosphorlipid derivatives such as phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids; sterols such as cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytosterol, cholic acid; sapogenins; saponins; cholesteryl acetate, Cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di-lauroyl-L-glutamate (cholesteryl / behenyl / octyldodecyl), di-lauroyl-L-glutamate (cholesteryl / octyldodecyl), N- Diacylsarcosine alkyl esters such as di-lauroyl-L-glutamate (phytosteryl / behenyl / octyldodecyl), di-lauroyl-L-glutamate (phytosteryl / octyldodecyl), N-lauroyl sarcosin isopropyl, cholesteryl 12-hydroxystearate, macadamia nuts. Sterol esters such as oil fatty acid cholesteryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, isostearate phytosteryl, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; -Fatty acid complexes such as cholesterol complex, phospholipid-phytosterol complex; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl pariminate, octyldodecyl palmitate, cetyl octanate, hexyldecyl octanate, Isotridecyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecil neopentanoate, ne Isotridecyl opentanate, isostearyl neopentate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolinic acid, dicapryryl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl ercatate Himasi oil, ethyl oleate, ethyl avocado oil fatty acid, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolin fatty acid, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methyl isostearate Monoalcoholic carboxylic acid esters such as heptyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate; cetyl lactate, diiso malate Oxyate esters such as stearyl, hydrogenated monoisostearate castor oil, γ-ercalactone; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, tri (caprylic acid / capric acid) glyceryl, tri (Capricic acid / capric acid / myristic acid / stearic acid) Glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl eikosanate behate, trimethylol propane trioctanoate, triisostearate Methylolpropane, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl , Triethylhexanoic acid ditrimethylolpropane, (isostearic acid / sebacic acid) ditrimethylolpropane, triethylhexanoate pentaerythricyl, (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, diisostearate diglyceryl, tetraisostearate polyglyceryl, nona Polyglyceryl isostearate-10, Deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl-8, (Hexyldecanoic acid / sebacic acid) Diglyceryl oligoester, glycol distearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopenate, 2,4-diethyl-1,5-pentanediol dineopenate, etc. Polyhydric alcohol fatty acid esters; alkyl ethers such as dicaprylyl ether; diisopropyl dimergylinolate, diisostearyl dimerserinolate, dimerserylinolate di (isostearyl / phytosteryl), dimergilinolic acid (phytosteryl /) Behenyl), Dimerglinolic Acid (Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl), Dimerglinolic Acid Dimerglinoleil, Diisostearate Dimerglinoleil, Dimerglinoleil Hydrogenated Rosin Condensate, Dimerglinolic Acid Derivatives of dimeric acid or dimerdiol such as hardened castor oil, hydroxyalkyl dimer dichlorinorail ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA). ), Laurate diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolamide (partamide DEA), coconut oil fatty acid methylethanolamide (cocamidomethyl MEA) Fatty acid alkanolamides such as: dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, ( Aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, amino-modified silicones such as aminopropyldimethicone and amodimethicone, cationic-modified silicones, polyether-modified silicones such as dimethiconecopolyol, polyglycerin Modified silicone, sugar-modified silicone, carboxylic acid-modified silicone, phosphate-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone, fatty acid-modified silicone, alkylether-modified silicone, a. Minoic acid-modified silicone, peptide-modified silicone, fluorine-modified silicone, cationic-modified and polyether-modified silicone, amino-modified and polyether-modified silicone, alkyl-modified and polyether-modified silicone, amide alkyl-modified silicone, aminoglycol-modified silicone, aminophenyl-modified Silicones such as silicones and polysiloxane / oxyalkylene copolymers; fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether are preferable.

Examples of the moisturizing agent / feel improving agent include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, and the like. Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymers and their polymers; diethylene glycol monoethyl ether Glycolalkyl ethers such as (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosandioic acid / tetradecanedioic acid) polyglyceryl-10, polyglyceryl-10 tetradecanedioate, cyclohexanedicarboxylic acid Water-soluble esters such as bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, martitol; glucose, fructose, galactose, mannose, treose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, Trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, Heparin and derivatives, saccharides such as pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer and derivatives thereof; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate , Caronine sulfate, keratosulfate, dermatan sulfate; white jellyfish extract, white jellyfish polysaccharide; fluctanes such as inulin, levan; fucoidan; tuberose polysaccharide, naturally occurring polysaccharide; organic acids such as citric acid, tartaric acid, lactic acid and salts thereof. Urea; Salts such as 2-pyrrolidone-5-carboxylic acid and sodium thereof; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threoni Amino acids such as peptides, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen degradation Peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degraded peptide, keratin-degraded peptide, hydrolyzed keratin, conchiolin-degraded peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean Protein peptides and derivatives thereof such as proteolytic peptides, wheat proteolytic peptides, hydrolyzed wheat proteins, casein-degrading peptides, acylated peptides; acylated peptides such as palmitoyl oligopeptides, palmitoyl pentapeptides, palmitoyl tetrapeptides; Peptides; Lactobacillus culture, yeast extract, eggshell membrane protein, submandibular gland mutin, hypotaurine, sesame lignan glycoside, glutathione, albumin, lactose; choline chloride, phosphorylcholine; placenta extract, aerastin, collagen, aloe extraction Peptides, Hamamelis water, Hechima water, Camomila extract, Kanzo extract, Comfrey extract, Silk extract, Izayoi rose extract, Peptide extract, Eucalyptus extract, Melilot extract and other animal / plant extracts, Natural ceramide (Types 1, 2, 3, 4, 5, 6), hydroxyceramides, pseudo-ceramides, sphingoglycolipids, ceramides and ceramides such as sugar ceramide-containing extracts are preferable.

Preferred examples of the surfactant include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, and polymer surfactants. The HLB of the surfactant is not particularly limited and can be used from a low HLB of about 1 to a high HLB of about 20, and it is also preferable to combine a low HLB and a high HLB. Examples of preferred surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulphates such as sodium lauryl sulphate, triethanolamine lauryl sulphate and ammonium lauryl sulphate; laureth. Polyoxyethylene alkyl sulfates such as sodium sulphate and triethanolamine laures sulphate; sodium cocoyl methyl taurine, potassium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium myristyl methyl taurine, sodium lauroyl methyl alanine, sodium lauroyl sarcosin, lauroyl sarcosin triethanol. Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroyl glutamate; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine. , Acylamino acid salts such as lysine Na dilauroyl glutamate; Polyoxyethylene alkyl ether acetates such as sodium laureth acetate; Sulfonic acid ester salts such as sodium lauroyl monoethanolamide succinate; Polyoxyethylene fatty amine sulfate; fatty acid alkanolamide sulfate; hardened coconut oil fatty acid fatty acid glyceride sulfate such as sodium glycerin sulfate; alkylbenzene polyoxyethylene sulfate; olefin sulfonate such as α-olefin sulfonate; Alkyl sulfosuccinates such as lauryl disodium acid, sodium dioctyl sulfosuccinate; alkyl ether sulfosuccinates such as laures disodium sulfosuccinate, monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; tetradecyl Alkyl benzene sulfonates such as sodium benzene sulfonate, triethanolamine tetradecyl benzene sulfonic acid; alkyl naphthalene sulfonate; alkane sulfonate; α-sulfo fatty acid methyl ester salt; acyl icethionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetate; Alkyl phosphate ester salts such as sodium laures phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooleth phosphate; Alkyl phosphate ester salts such as potassium lauryl phosphate; Sodium caseinate; Alkyl aryl ether Phosphate; fatty acid amide ether phosphate; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; Anionic surfactants, etc .; Among nonionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steares (polyoxyethylene stearyl ether), behenes (polyoxy) Polyoxyethylene alkyl ethers with various polyoxyethylene additions such as ethylene behenyl ether), isosteares (polyoxyethylene isostearyl ether), octyldodeces (polyoxyethylene octyldodecyl ether); polyoxyethylene alkylphenyl ether; Polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, poly Oxyethylene hydrogenated castor oil and castor oil derivatives such as maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxy Polyethylene cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene glycerin ether, etc. Polyoxyethylene / polyoxypropylene alkyl ether; polyoxyethylene / polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; Glyceryl, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, coconut oil fatty acid glyceryl, monocotton oil fatty acid glycerin, glycerin monoercaate, glycerin sesquioleate, α, α'-glycerin oleate, monostearic acid Glycerin fatty acid partial esters such as acid glycerin malic acid; polyglyceryl-2, 3, 4, 4, 6, 8, 8, 10, polyglyceryl distearate-6, 10, polyglyceryl tristearate- 2. Polyglyceryl decastearate-10, polyglyceryl-2 isostearate-2, 3, 4, 4, 5, 6, 8, 10, diisostearate polyglyceryl-2 (diglyceryl diisostearate), 3, 10, 10 , Polyglyceryl-2 triisostearate, Polyglyceryl-2 tetraisostearate, Polyglyceryl-10 decaisostearate, Polyglyceryl-2 oleate, 3, 4, 5, 5, 6, 8, Polyglyceryl dioleate- 6. Polyglycerin fatty acid ester such as polyglyceryl-2 trioleate, polyglyceryl-10 decaoleate; ethylene glycol monofatty acid ester such as ethylene glycol monostearate; propylene glycol monofatty acid ester such as propylene glycol monostearate; pentaerythritol moiety Fatite ester; sorbitol partial fatty acid ester; martitol partial fatty acid ester; martitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan Solbitan fatty acid esters such as trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; partial esters of sugar derivatives such as sucrose fatty acid ester, methylglucoside fatty acid ester, trehalose undecylate; Alkyl glucosides such as glucosides; alkyl polyglycosides; glycolipids such as mannosyl erythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene distearate, polytylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene di Ole Polyoxyethylene fatty acid mono and diesters such as alcohol; polyoxyethylene / propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate, etc. Polyoxyethylene glycerin fatty acid esters such as monooleate; polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, and polyoxyethylene sorbitan tetraoleate. Polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, and polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid esters; poly Oxyethylene alkyl ether fatty acid esters; polyoxyethylene animal and vegetable oils and fats such as polyoxyethylene sorbitol honey; alkyl glyceryl ethers such as isostearyl glyceryl ethers, chimil alcohols, ceracyl alcohols and batyl alcohols; polyhydric alcohol alkyl ethers; poly Oxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin and sophorolipid; polyoxyethylene fatty acid amides; coconut oil fatty acids monoethanolamide (cocamide MEA), coconut oil Fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitate monoethanolamide (partamide MEA), palmitate diethanolami Alcohol alkanolamides such as do (partamide DEA) and coconut oil fatty acid methylethanolamide (cocamidomethyl MEA); alkyldimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, behenamine oxide; alkylethoxydimethylamine Oxide; polyoxyethylene alkyl mercaptan; polyether such as dimethicone copolypoly Silicone-based nonionic surfactants such as cell-modified silicones, polysiloxane / oxyalkylene copolymers, polyglycerin-modified silicones, and sugar-modified silicones; among cationic surfactants, betaine trimonium chloride and stealtrimonium chloride. Alkyltrimethylammonium chlorides such as cetrimonium chloride and lauryltrimonium chloride; alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; stearamidepropyldimethylamine, Fatty acid amidoamines such as stearamide ethyldiethylamine and salts thereof; alkyletheramines such as stearoxypropyldimethylamine and salts thereof or quaternary salts; long-chain ethylsulfate branched fatty acids (12-31) aminopropylethyldimethylammonium, lanolin ethylsulfate Fatty acid amide type quaternary ammonium salt such as fatty acid aminopropyl ethyl dimethyl ammonium; polyoxyethylene alkylamine and its salt or quaternary salt; alkylamine salt; fatty acid amide guanidium salt; alkyl etheraminemonium salt; alkyltrialkylene glycol Ammonium salt; benzalconium salt; benzethonium salt; pyridinium salt such as cetylpyridinium chloride; imidazolinium salt; alkylisoquinolinium salt; dialkylmoriphonium salt; polyamine fatty acid derivative; aminopropyldimethicone and amodimethicone Silicone-based cationic surfactants such as modified silicones, cationically modified silicones, cationically modified and polyether-modified silicones, amino-modified and polyether-modified silicones; among amphoteric surfactants, lauryl betaine (lauryldimethylaminoacetic acid betaine) and the like. N-alkyl-N, N-dimethyl amino acid betaine; fatty acid amide alkyl-N, N-dimethyl amino acid betaine such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline type betaine such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkyl Alkyl sulfobetaine such as dimethyl taurine; sulfuric acid betaine such as alkyl dimethylaminoethanol sulfate ester; phosphoric acid betaine such as alkyl dimethyl amino ethanol phosphate; Sphingomyelin lipids such as min, phosphatidylserine, sphingomyelin, lysolecithin, hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, phospholipids such as lecithin hydroxide; Silicone-based amphoteric surfactants and the like; As polymer surfactants, polyvinyl alcohol, sodium alginate, starch derivatives, tragant gum, acrylate / alkyl methacrylic acid copolymers; various silicone-based surfactants are preferable.

Examples of the polymer / thickener / gelling agent include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, farcerelan, karaya gum, trolley aoi, cara gum, tragant gum, pectin, pectic acid and sodium. Salts such as salts, salts such as alginic acid and sodium salts, mannan; starches such as rice, corn, potatoes, wheat; xanthan gum, dextran, succinoglucan, curdran, hyaluronic acid and its salts, zansan gum, purulan, gellan gum, chitin , Chitosan, agar, casso extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and salts such as sodium thereof, methyl hydroxypropyl cellulose, sodium cellulose sulfate, dialkyldimethyl Ammonium sulfate cellulose, crystalline cellulose, cellulose powder and other cellulose and derivatives thereof; starch-based polymers such as soluble starch, carboxymethyl starch, methylhydroxypropyl starch, methyl starch, hydroxypropyltrimonium chloride starch, corn starch aluminum octenyl succinate, etc. Alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), vinylpidridone / vinyl alcohol copolymer, polyvinylmethyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene Polyoxypropylene copolymer; amphoteric methacrylate copolymer such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrelites / stearyl acrylate / ethylamine methacrylate) copolymer; (dimethicone / vinyldimethicone) cloth Polymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; polyvinyl acetate partially saponified product, maleic acid copolymer; vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; Acrylic resin alkanolamine; polyester, water-dispersible polyester; polya Crylamide; polyacrylic acid ester copolymer such as ethyl polyacrylate, carboxyvinyl polymer, salt such as polyacrylic acid and sodium salt thereof, acrylic acid / methacrylic acid ester copolymer; acrylate / alkyl methacrylic acid Polymers: cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid such as polyquaternium-39. -Diallyldimethylammonium chloride-acrylamide copolymer, acrylic acid-cationized metaacrylic acid ester copolymer, acrylic acid-cationized metaacrylic acid amide copolymer, polyquaterium-47 and other acrylic acid-methyl acrylate-chloride Methacylamide propyltrimethylammonium copolymer, choline chloride methacrylate polymer; cationized oligosaccharide, cationized dextran, cationized polysaccharide such as guarhydroxypropyltrimonium chloride; polyethyleneimine; cationic polymer; polyquaternium-51 and the like. 2-Polymer of methacryloyloxyethyl phosphorylcholine, polymer with butyl methacrylate copolymer, etc .; acrylic resin emulsion, ethyl polyacrylate emulsion, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, synthetic Polymer emulsions such as latex; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and Its salts; dextrin fatty acid esters such as dextrin palmitate, dextrin myristinate; silicic anhydride, fuming silica (ultrafine anhydrous silicic acid), aluminum magnesium silicate, sodium magnesium silicate, metal soap, metal dialkyl phosphate, Bentonite, hectrite, organically modified clay minerals, sucrose fatty acid esters, fructo-oligosaccharide fatty acid esters are preferred.

Examples of solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, and isopentyldiol. Kind: Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as: ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, glycol ether esters such as propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate and ethylene glycol disuccinate; benzyl Preferables include propellants such as alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation freon; LPG, dimethyl ether, and carbon dioxide.

Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; bisulfite derivatives such as propyl bisulfite; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; Sulfites such as sodium sulfite; hydrogen sulfites such as sodium hydrogen sulfite; thiosulfites such as sodium thiosulfite; metahydrosulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride are preferable. Is listed as. As the reducing agent, thioglycolic acid, cysteine, cysteamine and the like are preferable. As the oxidizing agent, hydrogen peroxide solution, ammonium persulfate, sodium bromate, percarbonate and the like are preferable.

Examples of antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane. 1,2-Alcandiols such as diols; Alkylglyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); Salicylic acid; Sodium benzoate; Isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; Linium urea; Dehydroacetic acid and its salts; Phenols; Halogenized bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zincpyrythion, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, glucon Chlorhexidine acid, halocarban, hexachlorophenol, hinokithiol; other phenols such as phenol, isopropylphenol, cresol, timol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolite, silver ion However, when used as an antibacterial agent or an antiseptic for the purpose of antiseptic, from the viewpoint of safety of cosmetics or external preparations for skin, phenoxyethanol; 1,2-pentanediol, 1,2-hexane It is more preferable to use 1,2-alkanediols such as diols and 1,2-octanediols; and alkylglyceryl ethers such as 2-ethylhexyl glyceryl ethers.

Examples of the chelating agent include edetates (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytate; ethidroic acid and the like. Phosphonic acid and salts such as sodium salts thereof; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphate; sodium citrate, citric acid, alanine, dihydroxyethylglycine , Gluconic acid, ascorbic acid, succinic acid, tartrate acid are preferred. As pH adjusters / acids / alkalis, citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxide Preferred are sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate and ammonium carbonate.

Powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, white mica, gold mica, synthetic mica, red mica, black mica, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, cay. Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (eg zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, dark blue, carbon black, titanium oxide, fine and ultrafine titanium oxide, zinc oxide , Fine and ultrafine zinc oxide, alumina, silica, fumigant silica (ultrafine anhydrous silicic acid), mica titanium, fish scale foil, boron nitride, photochromic pigment, synthetic fluorine gold mica, fine particle composite powder, gold, aluminum, etc. Inorganic powders of various sizes and shapes, and these are treated with silicones such as hydrogen silicone and cyclic hydrogen silicone or other surface treatment agents such as silane or titanium coupling agents to make them hydrophobic or Inorganic powder such as hydrophilized powder; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate -Polymethylmethacrylate laminated powder, polyethylene terephthalate, aluminum, epoxy laminated powder, etc., urethane powder, silicone powder, Teflon (registered trademark) powder, and other organic powders and surface treatment powders of various sizes and shapes, organic and inorganic Composite powders are preferred. Inorganic salts include sodium chloride-containing salts such as salt, normal salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, ginger, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, etc. Aluminum / potassium sulfate (myoban), aluminum / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na / 2Na / 3Na phosphate, phosphoric acid Potassiums, calcium phosphates and magnesium phosphates are preferred.

Examples of the ultraviolet absorber include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoate ethyl. An benzoic acid-based ultraviolet absorber such as ester, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; anthranilic acid-based ultraviolet absorber such as homomentyl-N-acetylanthranilate; salicylic acid And salicylic acid-based ultraviolet absorbers such as sodium salt, amylsalicylate, menthylsalicylate, homomentylsalicylate, octylsalicylate, phenylsalicylate, benzylsalicylate, p-isopropanol phenylsalicylate; octylcinnamate, ethyl-4-isopropylcinnamate, methyl. -2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxy cinnamate, isopropyl-p-methoxy cinnamate, isoamyl-p-methoxy Synnamete, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (synoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenyl Cyraxic acid-based ultraviolet absorbers such as cinnamate, 2-ethylhexyl α-cyano-β-phenyl cinnamate (octocrine), glycerylmono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and derivatives thereof; 2, 4-Dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2', 4,4'-tetrahydroxybenzophenone, 2-hydroxy- 4-Methoxybenzophenone (oxybenzon-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4' Benzophenones such as −phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone UV absorbers; 3- (4'-methylbenziliden) -d, l-phenyl, 3-benziliden-d, l-phenyl; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 -Methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoilmethane; 5-( 3,3-Dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octylriazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate 2- (2'-Hydroxy-5'-methylphenyl) benzotriazole, 1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentandione, dimethoxybenzilidendioxoimidazolidine propionic acid Hydantin derivatives such as 2-ethylhexyl, phenylbenzimidazole sulfonic acid, terephthalylidene dicanfursulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives are preferred.

Examples of vitamins and derivatives thereof include vitamin A such as retinol, retinol acetate, and retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxin hydrochloride, pyridoxin dioctanoate, pyridoxin dipalmitate, etc. Vitamin B group such as flavin adenin dinucleotide, cyanocobalamine, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin E such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphate ester salt such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate ester magnesium salt, tetra ascorbic acid Ascorbic acid fatty acid ester such as isoparmic acid ester, ascorbic stearate, ascorbic palmitate, ascorbic dipalmitate, alkyl ether ascorbic acid such as ethyl ether ascorbic acid, ascorbic acid glucoside such as -2-glucoside ascorbic acid and its fatty acid ester , Ascorbic acid derivatives such as tocopheryl ascorbic acid; tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, tocopherol ferulate, tocopherol derivatives such as tocopherol phosphate, and other vitamin derivatives, tocotrienol, and other various vitamin derivatives are preferable. Is listed as.

Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokithiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract. , Plant extracts such as Honoha extract are preferred. As hair growth agents, blood circulation promoters, and stimulants, plant extracts and tinctures such as senburi extract, togarashi tincture, ginger tincture, ginger extract, and cantarist tincture; capsaicin, nonylate valenylamide, gingerone, ictamol, and tannic acid. , Borneol, cyclanderate, cinnaridine, trazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol, cepharanthin, vitamin E and derivatives such as tocopherol nicotinate and tocopherol acetate, γ-orizanol, nicotinic acid and nicotinic acid amide benzyl nicotinate Derivatives such as ester inositol hexanicotinate and nicotine alcohol, allantin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivative, stigmasterol or stigmasterol and its glycoside, minoxidil are preferable. Is listed as. As the hormones, estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like are preferable. Other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cold sensitizers, warming agents, wound healing promoters, stimulant relievers, analgesics, cell activators, etc. include retinols, retinoic acids, retinoins. Tocopheryl acid; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and its glycosides / esterified products, hydroxycapric acid, long-chain α-hydroxy fatty acid, long-chain α-hydroxy fatty acid cholesteryl and other α- or β-Hydroxy acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosin; creatin; ceramides, spingosins; caffeine, xanthin and its derivatives; coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloids, fullerene and other antioxidant / active oxygen scavengers; catechins; quercetin and other flavones; isoflavones; gallic acid and ester sugar derivatives; tannins, sesamine, proto Polyphenols such as anthocyanidin, chlorogenic acid, apple polyphenols; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; Glycoside, gingerol; fragrance substances such as menthol, camphor, sedrol and derivatives thereof; capsaicin, vanillin and derivatives; insect repellents such as diethyl toluamide; complexes of physiologically active substances and cyclodextrins are preferred. Can be mentioned.

Plant / animal / microbial extracts include iris extract, acitaba extract, asunaro extract, asparagus extract, avocado extract, flaxseed extract, almond extract, altea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract. , Inchikou extract, Uikyo extract, Ukon extract, Woolong tea extract, Uwaurushi extract, Agetsu extract, Echinashi leaf extract, Enmeisou extract, Ogon extract, Oubaku extract, Ouren extract, Omugi extract, Otanenjinjin extract, Otogirisou extract, Odori kosou extract, Ononis extract , Dutch mustard extract, orange extract, dried seawater, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, cucumber extract, chamomile extract, oil-soluble chamomile extract, carrot extract, kawarayomogi Extract, crow wheat extract, calcade extract, kanzo extract, oil-soluble kanzo extract, kiwi extract, kiou extract, kikurage extract, kina extract, cucumber extract, kiri leaf extract, guanosine, guava extract, kujin extract, cutinashi extract, kumazasa extract, clara extract, walnut Extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, quail extract, gentiana extract, gennoshouko extract, tea extract, yeast extract, koboku extract, coffee extract, gobo extract, rice extract, rice Fermented extract, fermented rice bran extract, rice germ oil, comfrey extract, collagen, moss peach extract, saishin extract, psycho extract, saitai extract, saffron extract, salvia extract, sabonsou extract, sasa extract, sanzashi extract, sansha extract, sansho Extract, Shiitake extract, Jio extract, Shikon extract, Shiso extract, Shinanoki extract, Shimotsukesou extract, Jatoba extract, Shakuyaku extract, Shokyu extract, Shobu root extract, Shirakaba extract, White chrysanthemum extract, Sugina extract, Stevia extract, Stevia fermented product, Nishikawayanagi extract, Seiyoukizuta extract, Seiyousanzashi extract, Seiyouniwatoko extract, Seiyounokogirisou extract, Seiyouhakka extract, Sage extract, Zeniaoi extract, Senkyu extract, Senburi extract, Souhakuhi extract, Daiou extract, Dai Zu extract, Taisou extract, Thyme extract, Dandelion extract, Local clothing extract, Tea extract, Chouji extract, Chigaya extract, Chinpi extract, Tea tree oil, Jincha extract, Togarashi extract, Touki extract, Tokinsenka extract, Tounin extract, Tohi extract, Dokudami extract, Tomato Extract, Natto extract, Carrot extract, Carrot extract, Novara extract, Hibiscus extract, Bakumondou extract, Hass extract, Parsley extract, Birch extract, Honey, Hamamelis extract, Paris etalia extract, Hikiokoshi extract, Bisaborol, Hinoki extract, Bifizus bacterium extract, Biwa extract, Fukitanpopo extract, Fukinotou extract, Bukuryo extract, Butcher bloom extract, Grape extract, Grape seed extract, Propolis, Hechima extract, Benibana extract, Peppermint extract, Bodaiju extract, Button extract, Hop extract, Maikaika extract, Pine extract, Maronie extract , Mizubasho extract, Mukuroji extract, Melissa extract, Mozuku extract, Peach extract, Yagurumagiku extract, Eucalyptus extract, Yukinoshita extract, Yuzu extract, Yuri extract, Yokuinin extract, Yomogi extract, Lavender extract, Green tea extract, Eggshell membrane extract, Apple extract, Louis Boss tea extract , Reishi extract, lettuce extract, lemon extract, lotus extract, lotus extract, rose extract, rosemary extract, roman chamomile extract, royal jelly extract, crackle extract and the like are preferable.

Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, and pyridoxine. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, zinc paraphenol sulfonate and the like. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum / potassium sulfate, tannic acid and the like. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease and the like. Preferred examples of nucleic acids include ribonucleic acid and a salt thereof, deoxyribonucleic acid and a salt thereof, and disodium adenosine triphosphate.

As fragrances, acetylsedrene, amylcinnamaldehyde, allylamylglycolate, β-ionone, isoe super, isobutylquinolin, iris oil, iron, indol, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragor, Eugenol, Oak Moss, Opoponax Resinoid, Orange Oil, Eugenol, Oranthiol, Galaxolid, Carbachlor, L-Carbon, Kamfer, Cannon, Carrot Seed Oil, Clove Oil, Methyl Cylate, Geraniol, Geranyl nitrile , Isobornyl acetate, Geranyl acetate, Dimethylbenzylcarbinate acetate, Styralyl acetate, Cedril acetate, Telepinel acetate, pt-butylcyclohexyl acetate, Vetiberyl acetate, benzyl acetate, Linaryl acetate, Isopentyl salicylate, benzyl salicylate, Sandalwood oil, Santa roll, Cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citroneral, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylux Reginoid, Cedarwood Oil, Sedren, Sedrol, Celori Seed Oil, Thyme Oil, Damascon, Damasenon, Timor, Tuberose Absolute, Decanal, Decalactone, Terpineol, γ-Terpinen, Triplar, Nerol, Nonanar, 2,6-Nonadienor, Nonalactone, Pachori Alcohol, vanilla absolute, vanillin, basil oil, patcholi oil, hydroxycitroneral, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian balsam, vetiver oil, vetiverol , Peppermint oil, pepper oil, heliotropin, bergamot oil, benzylbenzoate, borneol, milresinoid, muskketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menton, eucalyptus oil, β-yonone, lime oil , Lavender oil, D-limonen, linalol, lylar, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, synthetic fragrances such as various essential oils and natural Fragrances and various blended fragrances are preferred.

Dyes / colorants / dyes / pigments include brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, and blue 204. , Blue 205, Blue 403, Blue 404, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1 , Red 105-1, Red 106, Red 2, Red 201, Red 202, Red 203, Red 204, Red 205, Red 206, Red 207, Red 208, Red 213 , Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 228, Red 230-1 , Red 230-2, Red 231, Red 232, Red 3, Red 401, Red 404, Red 405, Red 501, Red 502, Red 503, Red 504, Red 505 , Red 506, Orange 201, Orange 203, Orange 204, Orange 205, Orange 206, Orange 207, Orange 401, Orange 402, Orange 403, Yellow 201, Yellow 202-1 , Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow 405, Yellow 406, Yellow Legal dyes such as No. 407 and Yellow No. 5; Other acidic dyes such as Acid Red 14; Basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p- phenylenediamine, HC Blue 2, Basic Blue 26 and other nitro dyes; Disperse dyes; Titanium dioxide, Zinc oxide Inorganic white pigments such as; Inorganic red pigments such as iron oxide (Bengala) and iron titanate; Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and ocher; Black iron oxide, low Inorganic black pigments such as next titanium oxide; Inorganic purple pigments such as mango violet and cobalt violet; Inorganic green pigments such as dye, chromium hydroxide, cobalt titanate; inorganic blue pigments such as ultramarine and dark blue; titanium oxide coated mica, titanium oxide coated oxybismus chloride, titanium oxide coated talc, colored titanium oxide coated mica, oxy Pearl pigments such as bismuth chloride and fish scale foil; metal powder pigments such as aluminum powder, copper powder and gold; surface-treated inorganic and metal powder pigments; red 201, red 202, red 204, red 205, red 220 , Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, Blue 404, Red 3, Red 104, Red 106, Red 227, Red Organic pigments such as zirconium, barium or aluminum lakes such as 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1. Surface-treated organic pigments; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsantin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, cochineal, naphthoquinones such as ciconin, bixin, flavones, beta Natural pigments and dyes such as cyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5- Oxidation dye intermediates and couplers such as amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine and salts thereof; auto-oxidation dyes such as indolin; dihydroxyacetones are preferred.

As the water, in addition to normal water and purified water, hard water, soft water, natural water, deep ocean water, electrolytic alkaline ionized water, electrolytically acidic ionized water, ionized water, and cluster water are preferable.

In addition to these, cosmetic raw material standards, compounding ingredient standards by cosmetic type, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), pharmaceutical non-pharmaceutical raw material standards, Japanese Pharmacy, pharmaceutical additives Ingredients described in standards, official food additive official documents, etc., and Japanese and foreign patent gazettes and patent publication gazettes (including publication gazettes and republishing) whose international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the described ingredients, in known combinations, blending ratios, and blending amounts.

Examples of the type of cosmetics of the present invention include hair cosmetics, basic cosmetics, make-up cosmetics, aromatic cosmetics, body cosmetics, skin external preparations such as ointments, and the like. From the viewpoint of exerting the effects of the present invention, it can be particularly preferably used for hair cosmetics and basic cosmetics. The cosmetic of the present invention can be produced according to a usual method.

Explaining the types of the cosmetics of the present invention in more detail, the hair cosmetics include oil shampoos, cream shampoos, conditioning shampoos, shampoos for indulgence, shampoos for hair coloring, shampoos such as rinse-integrated shampoos; rinses, treatments, Conditioners such as hair packs and hair mists; hair styling products such as hair foams, hair mousses, hair sprays, hair waxes, hair gels, hair creams, water greases, set lotions, pomades, tics; color lotions, hair tonics, hair liquids, hair blows, branches Hair coats, hair oils, permanent wave agents, straight perms, oxidative hair dyes, hair bleaches, hair color pretreatments, hair color aftertreatments, perma pretreatments, perma aftertreatments, hair manicures, and hair restorers are preferred. Be done.

Basic cosmetics include softening lotion, astringent lotion, cleansing lotion, multi-layered lotion, etc .; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisturizer, moisturizer. -Emulsion, massage lotion, cleansing lotion, protect emulsion, sun protect, sun protector, UV care milk, sun screen, make-up lotion, horny smoother, elbow lotion, hand lotion, body lotion and other emulsions; emollient cream, nutrition cream, Nourishing cream, vanishing cream, moisture cream, night cream, massage cream, cleansing cream, make-up cream, base cream, pre-makeup cream, sunscreen cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening Creams such as creams; Gels such as moisture gels; Essences such as moisturizing essences, whitening essences, and UV protection essences; Lipstick cosmetics such as liposome beauty liquids and liposome cosmetics; Peel-off packs, powder packs, washing packs, oil packs, cleansing Packs and masks such as masks; cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing oil, cleansing mask, cleansing powder, facial cleansing powder, etc.; cosmetic soap, transparent soap, medicated soap, liquid soap, Soaps such as shaving soaps and synthetic cosmetic soaps are preferred.

Preferred makeup cosmetics include white powder / dusting powder, foundations, lipsticks, lip gloss, blusher, eyeliner, mascara, eye shadow, eyebrow, eyebrow, nail enamel, enamel remover, and nail treatment. ..

Preferable aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, cologne, perfume paste, fragrance powder, perfume soap, body lotion, and bath oil.

Body cosmetics include body cleaners such as body shampoo, deodorant lotions, deodorant powders, deodorant sprays, deodorant cosmetics such as deodorant sticks, depigmenting agents, depilatory / depilatory agents, bathing agents, insect repellent sprays, etc. Repellers are preferred.

Further, as the external preparation for skin, it can be used in a dosage form such as an ointment, a patch, a lotion, a liniment, and a liquid coating agent. It can also be used as an oral cosmetic such as toothpaste and mouthwash.

As the dosage form of the cosmetic or skin external preparation of the present invention, emulsification of oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, O / W / O type and the like. Molded cosmetics, oil-based cosmetics, solid cosmetics, liquid cosmetics, paste-like cosmetics, stick-shaped cosmetics, volatile oil-based cosmetics, powdered cosmetics, jelly-like cosmetics, gel-like cosmetics, paste-like Pharmaceutical types such as cosmetics, emulsified polymer type cosmetics, sheet-like cosmetics, mist-like cosmetics, and spray-type cosmetics are preferable.

The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto.

Preparation of Fullerene Dissolved Oil of Component (A) _{300 g of toluene was added to 0.3 g of fullerene (mixture of C 60} and C ₇₀ ), and the mixture was stirred and dissolved at room temperature for 2 hours and then filtered through a 0.2 μm PTFE membrane filter. After adding 99.7 g of each oil having the composition shown in Table 1 to the obtained filtrate, toluene was distilled off under reduced pressure with a rotary evaporator (80 ° C., 0.1 MPa, 2 hours), and the mixture was further filtered with a 1 μm PTFE membrane filter. , The component (A) fullerene-dissolved oil of the present invention was obtained. The fullerene-dissolved oils thus obtained were all brown solutions. The obtained fullerene dissolved oil, the concentration of fullerene C ₆₀ was analyzed by HPLC under the following conditions, the results are also shown in the lower column of Table 1.
<HPLC fullerene analysis conditions>
Detector: Ultraviolet absorptiometer 340 nm
Column: Inertsil ODS-2 4.6 × 250mm GL Science Co., Ltd.
Column temperature: 40 ° C
Mobile phase: Weigh 420 mL of methanol and add toluene to make 1000 mL.

_{From the results in Table 1, the content of fullerene C 60} in the fullerene dissolved oil obtained by the above-mentioned preparation method was 0.03 to 0.15% by weight. It was found that the fullerene content was particularly high in the oil agent to which γ-docosalactone was added.

Preparation and Evaluation of Cosmetic Composition of the Present Invention The cosmetic composition of the present invention containing the components (A) to (E) was prepared by uniformly stirring and mixing each component with the composition shown in Table 2 ( Examples 1-6). Similarly, a cosmetic composition was prepared with the composition shown in Table 3 (Reference Examples 1 to 6). The obtained cosmetic composition was evaluated for its appearance, presence / absence of formation of bicontinuous structure, and storage stability by the following method, and the results are shown in the lower columns of Tables 2 and 3.
<Confirmation of bi-continuous structure>
20 g of the cosmetic composition was placed in a glass screw bottle, and 0.1 g of an aqueous solution containing a water-soluble pigment (purple No. 401) having a concentration of 0.01% was added. Similarly, in another container, 0.1 g of a squalane solution containing an oil-soluble dye (Red No. 225) having a concentration of 0.01% was added. By visually observing the appearance of the composition to which these dyes are added, a bicontinuous structure is formed when the entire composition is uniformly colored and transparent regardless of whether the dye is water-soluble or oil-soluble. I decided that I was doing it. On the other hand, if either or both of the dyes do not uniformly color or become turbid, it is judged that they are not formed.
○ ・ ・ ・ All pigments are uniformly colored and transparent × ・ ・ ・ Not uniformly colored with either or both pigments, or the liquid becomes turbid <Storage stability of cosmetic composition>
The obtained cosmetic composition was subjected to a storage stability test at 50 ° C./1 month and evaluated according to the following evaluation criteria.
○ ・ ・ ・ The appearance does not change from the initial stage even after storage × ・ ・ ・ After storage, it is cloudy from the initial stage or separated into two phases.

As a result of Tables 2 and 3, fullerenes could be easily dispersed in the cosmetic compositions of Examples 1 to 6 and Reference Examples 1 to 6. Among them, the cosmetic compositions of Examples 1 to 6, which had formed a bicontinuous structure, had a transparent appearance and were excellent in storage stability. On the other hand, the cosmetic compositions of Reference Examples 1 to 6 which did not form a bicontinuous structure had a turbid appearance from the initial stage, resulting in poor storage stability.

Preparation and Evaluation of Fullerene-Containing Water Dispersion A fullerene-containing water dispersion was prepared with the compositions shown in Tables 4 and 5 using the cosmetic compositions of Examples 1 to 6 and Reference Examples 1 to 6. The preparation was carried out by putting 49 g of water in which methylparaben was previously dissolved in a 100 mL beaker, slowly adding 1 g of each cosmetic composition while stirring with a stirrer (600 rpm), and stirring at room temperature for 5 minutes. The obtained aqueous dispersion was evaluated for initial dispersibility, transparency / transmittance, and dispersion stability by the following methods, and the results are also shown in the lower columns of Tables 4 and 5.
<Initial dispersibility of aqueous dispersion>
With respect to the obtained aqueous dispersion, the dispersion state immediately after preparation was visually observed, and the initial dispersibility was evaluated according to the following evaluation criteria.
○ ・ ・ ・ Uniformly dispersed × ・ ・ ・ Not uniformly dispersed <Transparency / transmittance of water dispersion>
The obtained aqueous dispersion was placed in a glass bottle having a diameter of 3.5 cm, the appearance was visually observed from the side, and the transparency was evaluated according to the following evaluation criteria. In addition, the transmittance of the aqueous dispersion was measured using a spectrophotometer (cell thickness 1 cm, wavelength 600 nm).
○ ・ ・ ・ The back of the liquid can be seen through × ・ ・ ・ The back of the liquid cannot be seen through <Dispersion stability of the aqueous dispersion>
The obtained aqueous dispersion was subjected to a storage stability test at 50 ° C./1 month, and the dispersion stability was evaluated according to the following evaluation criteria.
○ ・ ・ ・ Uniformly dispersed even after storage × ・ ・ ・ Not uniformly dispersed or precipitated after storage

From the results in Tables 4 and 5, the aqueous dispersion prepared using the cosmetic composition of the present invention (forming a bicontinuous structure) can easily disperse fullerenes in water and has initial dispersibility. It was very excellent in transparency and dispersion stability. On the other hand, in the aqueous dispersion prepared using the cosmetic composition of the reference example (which does not form a bicontinuous structure), fullerenes tend to be able to be dispersed in water, but those that cannot be dispersed from the beginning Even if it could be dispersed, the transparency and dispersion stability were insufficient.

The cosmetic composition described below was prepared using the cosmetic composition of the present invention. All of the obtained cosmetics can easily and stably mix fullerenes, have excellent moisturizing properties with skin cosmetics, improve the spread of pores, improve hair damage with hair cosmetics, and give elasticity. It was something to do.

Example 13 Hair mist
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 2.5
Purified water 20.0
Part B NanoRepair-V (Nippon Fine Chemical Co., Ltd.) 2.0
Hydrolyzed keratin 0.5
Methylparaben 0.2
Betaine 0.5
Citric acid 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A and B were weighed and mixed uniformly, and then the two agents were mixed to make them uniform.

Example 14 Hair treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A isostearic acid 0.8
Polyricino-acidic acid 0.5
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.5
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 1.0
Part B Cosmetic composition of Example 1 0.2
Propanediol 3.0
Stealtrimonium chloride (70%) 1.5
Behenamide propyl dimethylamine 0.5
Cetanol 2.2
Stearyl alcohol 0.8
Hydrogenated rapeseed oil alcohol 0.5
Neopentyl glycol diethylcaproate 0.8
Myristic acid PPG-3 benzyl ether 0.5
Jojoba seed oil 1.0
Glyceryl stearate 0.4
Propylparaben 0.1
Cocamide MEA 0.8
Caesarpinia Spinosa Hydroxypropyltrimonium Chloride 0.1
Rice bran wax 0.5
Glycerin 1.0
Part C methylparaben 0.1
Lactic acid 0.18
Hydrolyzed conchiolin 0.1
Panthenol 0.1
Polyquaternium-7 0.15
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A, which had been mixed and dissolved in advance, was added to part B, and the mixture was uniformly mixed at about 80 ° C. (part D). Part C, which was set aside separately, was heated to 80 ° C. to make it uniform. Part D was gradually added to part C with stirring, mixed uniformly, and then cooled to about 50 ° C.

Example 15 Hair treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 0.2
Lanolin fatty acid 0.5
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.2
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 1.0
Ceramide 2 0.001
Ceramide 6 0.001
Part B Stearoxypropyltrimonium chloride 1.0
Setrimonium chloride 0.3
Dialkyl (C12-18) Dimonium Chloride 0.3
Stearyl alcohol 2.0
Cetanol 1.0
DPG 0.5
BG 1.0
Lactic acid 0.12
Hexa (hydroxystearic acid / stearic acid / rosin acid)
Dipentaerythrityl 0.2
Polyglyceryl polyricinoleate-6 1.0
Naphthalene Sulfonic Acid Na 0.5
Benzyl alcohol 0.4
Stearoxypropyl Dimethylamine 0.4
Behendimonium Stearyl Ethyl Phosphate 0.05
Tristearin 0.5
Ceteares-7 0.8
Ceteares-25 0.3
Part C Purified water Total amount of 100 Phenoxyethanol 0.5
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A, which had been mixed and dissolved in advance, was added to part B, and the mixture was uniformly mixed at about 80 ° C. (part D). Part C, which was set aside separately, was heated to 80 ° C. to make it uniform. Part D was gradually added to part C with stirring, mixed uniformly, and then cooled to about 50 ° C.

Example 16 Hair treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Hydroxystearic Acid 0.5
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.3
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 0.6
Neosolue-IOP (Nippon Fine Chemical Co., Ltd.) 3.0
Dextrin palmitate 0.5
Isostearoyl hydrolyzed collagen 0.2
Part B Stearyl Alcohol 2.0
Cetanol 1.2
Behentrimonium chloride 1.0
PEG-45M 0.8
Totsubaki Seed Oil 0.4
Hydroxyethylurea 0.5
Dicaprilyl Carbonate 2.0
Squalene 0.1
Isosetes-10 0.5
Sunflower wax 0.8
Cocoyl Arginine Ethyl PCA 0.2
Phenoxyethanol 0.2
Tocopherol 0.05
Glycerin 1.3
DPG 2.2
Part C Cosmetic composition of Example 1 0.2
Sorbitol 3.5
BG 1.0
Hydroxycellulose 0.07
Phenoxyethanol 0.2
Appropriate amount of citric acid EDTA-2Na 0.01
Amount of purified water totaling 100 Part D Polyquaternium-61 0.3
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A, which had been mixed and dissolved in advance, was added to part B, and the mixture was uniformly mixed at about 80 ° C. (part E). Part C, which was set aside separately, was heated to 80 ° C. to make it uniform. Part E was gradually added to part C with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part D was added and mixed uniformly.

Example 17 Hair treatment
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 1.0
Cetearyl alcohol 3.0
PPG-1 / PEG-1 stearamine 0.8
Behenamide propyl dimethylamine 1.0
Setrimonium chloride (25%) 5.3
Ethylhexyl palmitate 1.0
Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 1.0
Dimethicone (1 million cs) 1.0
Dimethicone (100cs) 3.0
Amodimethicone 1.0
Neopentyl glycol diheptate 2.0
Ethylhexyl isononanoate 1.0
Hybrid sunflower oil 1.0
DPG 1.8
Glycerin 4.0
Phytosterols 0.1
Mineral oil 0.5
PEG-160M 0.5
Part B Cosmetic composition of Example 1 0.2
Lactic acid 0.3
Hydrolyzed starch 0.4
Hydroxypropyl Methyl Cellulose 0.1
Hyaluronic acid Na 0.01
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and cooled.

Example 18 Treatment component compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A NS-CIO (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-IOP (Nippon Fine Chemical Co., Ltd.) 3.0
Stearyl alcohol 3.0
Behentrimonium chloride 1.0
Stealtrimonium chloride 0.5
Stearamidopropyl dimethylamine 0.1
Hydrogenated polyisobutene 1.0
Hydrogenated polydecene 0.6
Camellia seed oil 0.5
PPG-3 myristil 0.5
Dextrin palmitate 0.3
Dicaprilyl ether 3.0
Dilauroyl lysine Na 0.1
Ascorbyl dipalmitate 0.1
BG 3.0
Tocopherol 0.1
Phenoxyethanol 0.4
Part B Cosmetic composition of Example 1 0.2
Bicarbonate Na 0.4
Amount of purified water totaling 100 Locust Bean Hydroxypropyltrimonium Chloride 0.1
Lactic acid 0.05
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to another container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and cooled.

Example 19 Treatment component compounding amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-H (Nippon Fine Chemical Co., Ltd.) 0.5
DUB VCI-10 (Nippon Fine Chemical Co., Ltd.) 0.5
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 0.7
Dimethicone (300cs) 2.0
Part B Behentrimonium metosulfate 1.3
Setrimonium chloride 0.3
Paraffin 1.0
Hydroxypropyltrimonium hyaluronate 0.2
Isostearic acid hydrogenated castor oil 1.0
Squalene 2.0
Tocopherol acetate 0.05
Diethyl sebacate 2.0
Candelilla wax 0.3
Apricot kernel oil 1.0
DPG 2.0
Propanediol 1.0
Benzyl alcohol 0.5
Glycerin 1.0
PEG-7 propyl heptyl ether 0.8
PEG-180M 0.3
Part C Cosmetic composition of Example 1 0.2
Na benzoate 0.3
EDTA-2Na 0.03
Amount of purified water totaling 100 Polyquaternium-10 0.2
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A and part B, which had been mixed and dissolved in advance, were heated to about 80 ° C. and mixed uniformly (part D). Part C, which was set aside, was heated to about 60 ° C. to make it uniform. Part C was gradually added to part D with stirring, mixed uniformly, and then cooled to about 50 ° C.

Example 20 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Neosolue-IOP (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-MAS: (Nippon Fine Chemical Co., Ltd.) 0.1
Inulin stearate 1.0
Part B Sodium Laureth Sulfate (27%) 20.0
Hydrogenated palm oil fatty acid PEG-200 glyceryl 1.0
Coco Betaine (25%) 8.0
Glycerin 1.0
Polysorbate 20 0.5
Coconut oil fatty acid PEG-7 glyceryl 0.4
PPG-2 cocamide 0.3
PEG-60 hydrogenated castor oil 1.0
Bisabolol 0.01
Part C Na benzoate 0.4
Na chloride 0.5
Arginine 0.2
Amount of purified water totaling 100 Part D Cosmetic composition of Example 1 0.2
Polyquaternium-10 0.3
Purified water 9.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A and part B, which had been mixed and dissolved in advance, were uniformly mixed at about 80 ° C. (part E). Part C, which was set aside, was heated to about 60 ° C. to make it uniform. Part C was gradually added to part E with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part D was added and mixed uniformly.

Example 21 Shampoo for dandruff
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 0.2
Lauroylmethylalanine Na (30%) 13.0
Cocamidopropyl Betaine (30%) 20.0
Cocoyl Glutamic Acid TEA (30%) 5.0
Cocamide DEA 1.0
Glycerin 1.0
Glyceryl caprylate 0.4
Glyceryl undecylenic acid 0.1
Isostearoyl hydrolyzed collagen 0.5
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Glycol distearate 1.5
Part B Na benzoate 0.4
Na chloride 0.2
Amount of purified water totaling 100 Part C Polyquaternium-7 0.3
Swertia japonica extract 3.0
Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Polyquaternium-47 0.1
Piroctone olamine 0.1
Purified water 9.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was placed in a separate container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 22 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 0.2
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 1.0
Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 1.0
Dextrin palmitate 0.5
Part B Ammonium Laureth Sulfate 5.0
Sodium Laureth Sulfate (25%) 10.0
Lauryl hydroxysultaine (30%) 10.0
Lauric acid K 1.0
Glycol distearate 0.5
Toluenesulfonic acid 0.3
Stearoxypropyl dimethylamine 0.5
PPG-17 0.3
Neopentyl glycol diethylcaproate 0.4
Isodecyl glyceryl ether 0.4
Cocamide MEA 1.0
Laureth-4 0.3
Laureth-16 0.2
Stairless-6 0.2
Phenoxyethanol 0.3
Part C malic acid 0.02
Methylparaben 0.2
Phosphoric acid 0.03
Na benzoate 0.3
Amount of purified water totaling 100 Part D Polyquaternium-10 0.2
Guar Hydroxypropyltrimonium Chloride 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 3.0
Purified water 6.7
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A and part B, which had been mixed and dissolved in advance, were uniformly mixed at about 80 ° C. (part E). Part C, which was set aside, was heated to about 60 ° C. to make it uniform. Part C was gradually added to part E with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part D was added and mixed uniformly.

Example 23 Non-silicone shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A PPG-3 Caprylyl Ether 2.0
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 0.3
Ceramide 3 0.001
Ceramide 5 0.004
Part B Cocoyl Methyl Taurine Na 3.0
Sodium Laureth Sulfate (27%) 9.0
Lauryl hydroxysulfobetaine (30%) 7.0
Cocamide MEA 1.0
Polyquaternium-61 0.5
Neopentyl glycol diheptate 1.0
Glycol distearate 0.5
Polyglyceryl oleate-10 0.25
PEG-150 1.0 stearate
DPG 2.0
Phenoxyethanol 0.6
Part C Cosmetic composition of Example 1 0.2
EDTA-2Na 0.05
Methylparaben 0.2
Na benzoate 0.3
Amount of purified water totaling 100 Part D Polyquaternium-10 0.5
Polyquaternium-7 0.2
Purified water 9.3
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A and part B, which had been mixed and dissolved in advance, were uniformly mixed at about 80 ° C. (part E). Part C, which was set aside, was heated to about 60 ° C. to make it uniform. Part C was gradually added to part E with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part D was added and mixed uniformly.

Example 24 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.3
Cocoyl methyl taurine Na 3.0
Cocamidopropyl Betaine (30%) 8.0
Sodium Laureth Sulfate (27%) 10.0
Sodium cocoamphoacetate (30%) 5.0
Cocamidomethyl MEA 1.0
Glycol distearate 0.5
DPG 1.3
Cocoyl threonine Na 1.0
Lysine dilauroyl glutamate Na 0.05
PPG-70 glyceryl 0.7
PEG-10 Dimethicone 1.0
Cocoyl Arginine Ethyl PCA 0.2
Phenoxyethanol 0.3
Part B Cosmetic composition of Example 1 0.2
EDTA-2Na 0.05
Methylparaben 0.2
Na benzoate 0.3
Amount of purified water totaling 100 Part C Polyquaternium-10 0.3
Polyquaternium-7 0.2
Locust Bean Hydroxypropyltrimonium Chloride 0.1
Na chloride 0.3
Purified water 9.4
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was placed in a separate container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 25 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 0.5
Lauroyl sarcosine TEA (30%) 3.0
Cocoyl Glutamic Acid TEA (30%) 8.0
Sodium Laureth Sulfate (27%) 10.0
Palm kernel fatty acid amide propyl betaine (30%) 5.0
Cocamidomethyl MEA 1.0
Glycol distearate 0.5
Coconut oil fatty acid PEG-7 glyceryl 0.3
Ascorbyl dipalmitate 0.2
Laurate PEG-2 1.3
Cocoyl arginine ethyl PCA 0.1
Phenoxyethanol 0.3
Part B Cosmetic composition of Example 1 0.2
EDTA-2Na 0.05
Methylparaben 0.2
Dehydroacetic acid 0.2
Na benzoate 0.3
Amount of purified water totaling 100 Part C Polyquaternium-10 0.5
Polyquaternium-49 0.1
Ethanol 3.0
Purified water 4.8
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was placed in a separate container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 26 Non-silicone shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cetanol 0.3
Myristic acid 0.1
PEG-2 caprylyl amine 1.0
Ammonium xylene sulfonate 1.0
Sodium lauroamphoacetate (30%) 7.0
Sodium Laureth Sulfate (27%) 10.0
Glycol distearate 0.5
Coconut oil fatty acid PEG-7 glyceryl 0.3
PPG-3 Caprylyl Ether 1.5
Myristic acid PPG-3 benzyl ether 0.5
Dodecylbenzene Sulfonate Na 2.0
Sunflower wax 0.01
Polyquaternium-64 0.5
Dimethicone (100cs) 0.1
Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.3
PPG-7 0.5
Setrimonium chloride (30%) 1.0
Porokisama-407 0.8
Hydrogenated polydecene 0.2
Phenoxyethanol 0.3
Part B Cosmetic composition of Example 1 0.2
EDTA-2Na 0.05
Ethylenediamine disuccinic acid 3Na 0.1
Na benzoate 0.3
Polyquaternium-10 0.1
Guar Hydroxypropyltrimonium Chloride 0.3
Hydroxypropyltrimonium hyaluronate 0.3
Amount of purified water totaling 100 Part C xanthan gum 0.1
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.05
Carbomer 0.1
Arginine 1.0
Na hydroxide 0.05
Na chloride 0.7
Purified water 10.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was placed in a separate container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 27 Shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 0.2
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.1
Lanolin fatty acid 0.1
Laureth sulfosuccinate 2Na (26%) 10.0
Sodium lauroamphoacetate (30%) 7.0
Lauryl Sulfate TEA (40%) 6.0
Laureth-2 1.0
PEG-120 Methyl Glucose Dioleate 1.0
Solves Tetraoleate-60 3.5
Caprylyl glucoside 0.3
Glycol distearate 0.5
PEG-2 cocamine 1.2
PEG-30 hydrogenated castor oil 0.5
Coconut oil alkyl glucoside 1.0
Glyceryl oleate 0.8
Phenoxyethanol 0.3
Part B EDTA-2Na 0.05
Methylisothiazolinone 0.005
Amount of purified water totaling 100 Part C Polyquaternium-10 0.1
Guar Hydroxypropyltrimonium Chloride 0.3
Na chloride 0.3
Ascorbic acid 0.3
Hyaluronate Na 0.3
Purified water 19.3
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was placed in a separate container and heated to dissolve it. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 28 Hair treatment that does not wash away
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-G (Nippon Fine Chemical Co., Ltd.) 0.1
DUB VCI-10 (Nippon Fine Chemical Co., Ltd.) 1.0
Part B Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
Setrimonium chloride (25%) 1.1
Cation NH (Nippon Fine Chemical Co., Ltd.) 0.3
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 2.0
Neopentyl glycol diheptate 2.0
Glycerin 4.0
Phenoxyethanol 0.3
Part C hydrolyzed keratin 0.1
Keratin 0.1
Hydrolyzed conchiolin 0.1
Panthenol 0.1
Hydroxypropyltrimonium hyaluronate 0.01
Hyaluronic Acid Cross Polymer Na 0.01
Polyquaternium-51 0.5
Part D Cosmetic composition of Example 1 2.5
Amount of purified water totaling 100 Hydroxyethyl cellulose 0.1
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A, which had been uniformly mixed in advance, was added to part B and heated to about 80 ° C. to dissolve it (part E). Part D was heated to about 80 ° C. in another container to dissolve it. While stirring the D part in the E part, the mixture was gradually added and uniformly mixed, and then rapidly cooled (F part). Part C was added to part F at about 40 ° C. to make it uniform.

Example 29 Hair wax
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-DP (Nippon Fine Chemical Co., Ltd.) 2.0
Microcrystalline wax 4.0
Hydrogenated polyisobutene 5.0
Rice bran wax 3.0
Hydroxystearic acid 6.0
Glyceryl stearate 1.0
Isohexadecane 5.0
Dimethicone (10,000 cs) 1.0
PPG-3 Caprylyl Ether 2.0
Diisopropyl adipate 5.0
Setes-2 6.0
Setes-20 0.5
BHT 0.05
Phenoxyethanol 0.6
Methylparaben 0.2
BG 3.0
Part B Cosmetic composition of Example 1 0.2
Na hydroxide 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Heat parts A and B to about 80 ° C. and mix them uniformly. Part B is gradually added to part A with stirring, mixed uniformly, and then cooled.

Example 30 Hair wax
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Triethylhexanoin 1.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 3.0
Tori Hydrogenated Glyceryl Rosinate 1.0
Ethylhexyl methoxycinnamate 2.0
Lanolin 1.0
Elcalactone MCT (Nippon Fine Chemical Co., Ltd.) 3.0
Ceramide 1 0.0001
Ceramide 2 0.01
Part B Candelilla Wax 1.0
DUB VCI-10 (Nippon Fine Chemical Co., Ltd.) 2.5
PPG-1 Behenes-15 5.0
Carnauba wax 4.0
Polyurethane-1 2.0
Glycerin 5.0
Silica 2.0
Na hydroxide (50% solution) 0.3
Part C Phenoxyethanol 0.6
Methylparaben 0.2
Amount of purified water totaling 100 Part D Cosmetic composition of Example 1 1.0
(Acrylate / Methacrylic Acid Steareth-20) Copolymer 1.0
PEG-240 / decyltetradeceth-20 / HMDI) copolymer 0.75
Purified water 30.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A, which had been mixed and dissolved in advance, was added to part B and mixed uniformly at about 80 ° C. (part E). Part C, which was set aside, was heated to about 60 ° C. to make it uniform. Part C was gradually added to part E with stirring, mixed uniformly, and then cooled to about 50 ° C. Further, part D was added and mixed uniformly.

Example 31 Moose
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
The cosmetic composition of Example 1 0.2
NS-CIO (Nippon Fine Chemical Co., Ltd.) 1.0
Ethanol 5.0
Polyethylene glycol oleyl ether (20) 1.0
Acrylic resin alkanolamine solution 3.0
Diethylaminopropylamide stearate 0.5
Pyrrolidone carboxylic acid 0.2
Preservatives, fragrances 1.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
The above components were mixed, and the obtained base and LPG were mixed at a ratio of base: LPG = 92: 8 to obtain an injection type mousse.

Example 32 Hair cream
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 0.2
PPG-3 Caprylyl Ether 1.5
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 0.6
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-Aqua (Nippon Fine Chemical Co., Ltd.) 0.8
Cetyl palmitate 3.0
Candelilla wax 4.0
Beeswax 2.0
Cetyl ethylcaproate 2.0
Setes-7 2.0
Ceramide 0.1
Stearyl alcohol 1.5
PEG-8 0.8
Part B (Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer
0.2
AMP 0.2
Hydrolyzed keratin 0.5
Purified water 10.0
Part C Hydroxide K 0.3
PG 0.5
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was mixed at 80 ° C. Part C was heated to 80 ° C. and added to part A for emulsification (part D). After cooling to 50 ° C., part B was added to make it uniform.

Example 33 Hair treatment that does not wash away
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 1.4
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 1.0
Hydrolyzed keratin 0.01
Dextrin palmitate 2.0
Part B Stearamidopropyl Dimethylamine 0.5
Stearyl alcohol 1.5
Myristyl alcohol 0.3
Phytocompo-pp (Nippon Fine Chemical Co., Ltd.) 0.2
Glycerin 4.0
Phenoxyethanol 0.2
Part C Cosmetic composition of Example 1 0.2
Cetearamid ethyldiethonium hydrolyzed rice protein 0.2
Hydrolyzed conchiolin 0.1
Part D Lactic acid 0.1
Glycerin 2.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A, which had been mixed and dissolved in advance, was added to part B, and the mixture was heated to about 80 ° C. to dissolve it (part E). In another container, part D was heated to about 80 ° C. to make it uniform. While stirring the D part in the E part, the mixture was gradually added and uniformly mixed, and then rapidly cooled (F part). The C part was added to the F part at about 40 ° C. to make it uniform.

Example 34 Hair oil
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
The cosmetic composition of Example 1 0.2
Elcalactone DES (Nippon Fine Chemical Co., Ltd.) 2.0
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 10.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 20.0
PPG-3 Caprylyl Ether 2.0
Tocopherol 0.1
Propylparaben 0.05
Carnauba wax 0.1
Amount of isododecane totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
All ingredients were heated and dissolved and mixed.

Example 35 Whitening lotion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 2.0
Purified water 10.0
Part B xanthan gum 0.05
BG 3.0
Purified water 20.0
Part C VC Ethyl (Nippon Fine Chemical Co., Ltd.) 1.0
Purified water 5.0
Part D Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.01
BG 4.0
Innocitol 0.5
Glycyrrhizinate 2K 0.05
Ethanol 3.0
Phenoxyethanol 0.2
Methylparaben 0.15
Citric acid 0.1
Amount of sodium citrate pH 4.5 Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− −−−−−−−
(Preparation method)
Part B was mixed to prepare a viscous liquid. Part A was heated to 50 ° C. and slowly added to part B with stirring. Further, parts C and D mixed in advance were added to obtain a uniform liquid.

Example 36 Whitening lotion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 3.0
DPG 3.0
Glycerin 1.0
Part B purified water 20.0
Part C tranexamic acid (Nippon Fine Chemical Co., Ltd.) 2.0
Purified water 20.0
Part D Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
Niacinamide 0.3
Betaine 1.0
Phenoxyethanol 0.2
Methylparaben 0.15
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was mixed and slowly added to part B at about 50 ° C. with stirring to adjust the dispersion. Further, parts C and D mixed in advance were added to obtain a uniform liquid.

Example 37 Moisturizing lotion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 1.0
Diglycerin 3.0
Hydrolyzed hyaluronic acid 0.01
Arginine 0.05
Part B purified water 20.0
Part C Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
Betaine 0.5
Pullulan 0.5
Hyaluronic acid Na 0.01
Hydroxyethyl cellulose 0.03
Carbomer 0.05
Arginine 0.05
Phenoxyethanol 0.2
Methylparaben 0.15
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was mixed and slowly added to part B with stirring to adjust the dispersion. Further, it was added to the C part mixed in advance to obtain a uniform liquid.

Example 38 Moisturizing Toner
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 2.0
Diglycerin 3.0
Astaxanthin 0.01
Ubiquinone 0.05
Part B purified water 20.0
Part C Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 1.0
PEG / PPG / Polybutylene Glycol-8 / 5/3 Glycerin 0.5
Glucosyl ceramide 0.5
Glucosylrutin 0.01
Polyquaternium-51 0.5
Acetyl Hexapeptide-8 0.001
Hydrolyzed collagen 0.05
Carbomer 0.05
Arginine 0.05
Phenoxyethanol 0.2
Methylparaben 0.15
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was mixed and part B was added slowly with stirring to adjust the dispersion. Further, it was added to the C part mixed in advance to obtain a uniform liquid.

Example 39 Gel lotion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 1.0
Glycerin 5.0
Sorbitol solution (70%) 5.0
Glyceryl behenate 0.8
Stearic acid 0.3
PEG-10 Dimethicone 0.4
Part B Cosmetic Composition of Example 1 3.0
Purified water 20.0
Part C Phenoxyethanol 0.3
Pullulan 0.2
Ethylhexyl glycerin 0.2
Poly HEMA Glucoside 0.05
Polymethacryloyl lysine 0.05
Crystalline cellulose powder 0.1
Locust bean gum 0.03
Hydroxyethyl cellulose 0.05
Hyaluronic acid Na 0.01
Carbomer 0.06
Hydroxide K 0.05
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 70 ° C. and dispersed uniformly. Part C was mixed, stirred well, made uniform, and then heated to about 70 ° C. Part B was stirred with a propeller to prepare a dispersion. Part C was added to part A, stirred at about 70 ° C. using a homomixer, cooled to about 40 ° C., and the mixed solution of part B was added.

Example 40 Transparent gel
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 3 0.5
Glycerin 3.0
Purified water 30.0
Part B PEG-4000 0.2
Methylgluces-10 1.0
Phenoxyethanol 0.3
Pyridoxine hydrochloride 0.05
Ethylhexyl glycerin 0.2
Hydroxyethyl cellulose 0.05
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.01
Hydrolyzed collagen 0.01
Amount of purified water totaling 100 parts C
(Dimethyltaurine ammonium acrylate / vinylpyrrolidone) Copolymer 0.05
(Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer 0.15
Arginine 0.25
Purified water 30.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was stirred with a propeller to prepare a dispersion. Part C was made into a viscous liquid when mixed. Part B was mixed to obtain a uniform liquid. A part and B part were added to C part to make them uniform.

Example 41 Moisturizing emulsion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 3.0
Diglycerin 1.0
BG 7.0
Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 1.0
Hydrogenated lysolecithin (main purification) 0.1
Part B IOTG (Nippon Fine Chemical Co., Ltd.) 3.0
LUSPLAN SR-DM4 (Nippon Fine Chemical Co., Ltd.) 0.5
Dimethicone (100CS) 5.0
Hydrogenated polyisobutene 3.5
Setostearyl alcohol 1.0
Arachidyl alcohol 0.1
Jojoba Alcohol 3.0
Kimil alcohol 0.3
Ceraquil Alcohol 0.1
Hexildecanol 0.5
Part C Cosmetic Composition of Example 1 2.0
Purified water 20.0
Part D (Hydroxyethyl Acrylate / Acryloyl Dimethyl Taurine Na) Copolymer 0.2
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.03
Carbomer 0.1
Purified water 30.0
Part E Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.5
Polyquaternium-51 1.0
Ascorbyl Glucoside 1.0
Potassium hydroxide 0.2
Phenoxyethanol 0.2
Methylparaben 0.15
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Parts A, B, and E were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part C was mixed with a propeller (room temperature) to prepare a dispersion. Part D was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homodisper, part E was added and emulsified. After cooling, parts C and D were added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 42 UV emulsion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 3.0
Diglycerin 1.0
BG 7.0
Phytocompo-C5 (Nippon Fine Chemical Co., Ltd.) 1.0
Cosmetic Composition of Example 2 1.5
Part B Neosolue-DE (Nippon Fine Chemical Co., Ltd.) 5.0
Neosolue-MP (Nippon Fine Chemical Co., Ltd.) 2.0
DUB VCI-10 (Nippon Fine Chemical Co., Ltd.) 2.0
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 0.8
Dimethicone 5.0
Ethylhexyl methoxycinnamate 5.0
Dimethoxybenzyl dioxoimidazolidine propionate ethylhexyl 0.5
t-Butylmethoxydibenzoylmethane 0.5
Cinoxate 1.0
Dihydroxydimethoxybenzophenone 0.5
Tetrahydroxybenzophenone 0.1
Methylbis trimethoxycinnamate (trimethylsiloxy)
Cyril isopentyl 0.5
2-Ethylhexyl paradimethylaminobenzoate 1.0
Bisethylhexyloxyphenol methoxyphenyl triazine 1.0
Diethylaminohydroxybenzoyl hexyl benzoate 1.0
Ethylhexyltriazone 1.0
3- (4'-methylbenzylidene) -d, l-camphor 1.0
Methyl 2,5-diisopropylcinnamic acid 1.0
Octyl salicylate 2.0
Homomentyl salicylate 1.5
1- (3,4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentandion 1.0
Amyl paradimethylaminobenzoate 0.5
Polyglyceryl pentastearate-10 1.0
N-lauroyl sarcosine isopropyl 2.0
Isostearyl alcohol 1.0
Stearyl alcohol 0.5
2-Octyldodecanol 1.0
Dimerdiol 0.5
Benzyl alcohol 0.5
Isostearic acid 1.0
Erucic acid 1.0
Rice wax 0.1
Celesin 0.1
Paraffin wax 0.1
Microcrystalline wax 0.1
Polyethylene 0.1
Safflower oil 0.5
Olive oil 0.5
Castor oil 0.3
Tea oil 0.3
Evening primrose oil 0.3
Wheat germ oil 0.3
Part C Hydroxyethyl Cellulose 0.2
Stearoxy hydroxypropyl methylcellulose 0.8
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.03
Purified water 20.0
Part D Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.5
VC Ethyl (Nippon Fine Chemical Co., Ltd.) 0.5
Arbutin (Nippon Fine Chemical Co., Ltd.) 0.5
Phenoxyethanol 0.2
Methylparaben 0.15
Sodium dihydroxydimethoxybenzophenone disulfonate 0.5
Phenylbenzimidazole sulfonic acid 1.0
Na hydroxide 1.0
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Parts A, B, and D were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part C was mixed and stirred to give a viscous liquid. After adding part B while stirring part A with a homomixer, part D was added and emulsified. After cooling, part C was added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 43 UV emulsion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 3.0
Diglycerin 1.0
BG 7.0
Phytocompo-PP (Nippon Fine Chemical Co., Ltd.) 1.0
Part B Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 1.0
Dimethicone 10.0
Ethylhexyl methoxycinnamate 7.0
t-Butylmethoxydibenzoylmethane 1.5
Bisethylhexyloxyphenol methoxyphenyl triazine 1.0
Diethylaminohydroxybenzoyl hexyl benzoate 0.5
Ethylhexyltriazone 1.0
Homo salate 0.5
4- (2-β-Glucopyranosiloxane) propoxy-2-hydroxybenzophenone 0.7
2-Hydroxy-4-methoxybenzophenone 0.3
Dimethyldiethylbenzalmalonate 0.5
Part C Hydroxyethyl Cellulose 0.2
Stearoxy hydroxypropyl methylcellulose 0.8
Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.03
Purified water 20.0
Part D Cosmetic composition of Example 4 1.0
Purified water 15.0
Part E Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.5
VC Ethyl (Nippon Fine Chemical Co., Ltd.) 1.0
Tranexamic acid 1.0
Glyceryl ascorbic acid 0.5
Arbutin 0.5
Phenoxyethanol 0.2
Methylparaben 0.15
Amount of purified water totaling 100 Part F Titanium oxide (silica treatment) 1.0
Zinc oxide (silica treatment) 2.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Parts A, B, and E were mixed and heated to about 70 ° C. to uniformly dissolve and disperse them. Part C was mixed and stirred to give a viscous liquid. Part D was mixed by propeller stirring to prepare a dispersion liquid. After adding part B while stirring part A with a homodisper, part E was added and emulsified. After cooling, parts D and F were added at about 50 ° C., and the mixture was stirred and cooled to about 40 ° C.

Example 44 Skin care cream
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 1.0
Jojoba oil 2.0
Plandoll-H (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) 5.0
LUSPLAN DD-DHR (Nippon Fine Chemical Co., Ltd.) 3.0
Propylene glycol monostearate 0.6
Behenyl alcohol 2.0
Ethylparaben 0.1
Liquid isoparaffin 0.5
Carnauba wax 0.3
Corn oil 0.3
Canola oil 1.0
Sunflower oil 1.0
Wheat germ oil 1.0
Flaxseed oil 0.1
Cottonseed oil 0.1
Soybean oil 0.1
Cholesteryl nonanoate 0.1
Cholesteryl stearate 0.1
Cholesteryl isostearate 1.0
Cholesteryl oleate 0.1
Cholesteryl 12-hydroxystearate 0.1
Long-chain branched fatty acid cholesteryl 0.3
Octyldodecyl myristate 1.0
Dimeric linoleic acid hardened castor oil 1.0
Hydroxyalkyl dimer dilinoleyl ether 1.0
Phenyltrimethicone 1.0
Diphenyldimethicone 1.0
Methyl Hydrogen Polysiloxane 1.0
Polyglyceryl-3 polydimethylsiloxyethyl dimethicone 0.5
Polyoxyethylene / methylpolysiloxane copolymer 1.0
Tannin 0.01
Sesamin 0.01
Proanthocyanidins 0.01
Gravlysin 0.01
Grablen 0.01
Liquiritin 0.01
Isoliquilithin 0.01
Lactoferrin 0.01
Shogaol 0.01
Gingerol 0.01
Part B (acryloyl dimethyl taurine /
Behenes methacrylic acid-25) Copolymer 0.2
(Acryloyl dimethyl taurine ammonium / VP) copolymer Purified water 20.0
Part C Cosmetic composition of Example 2 0.5
Composite-PC (Nippon Fine Chemical Co., Ltd.) 1.5
LP70H (Nippon Fine Chemical Co., Ltd.) 0.05
Hydrogenated egg yolk lecithin 0.1
Stigmasterol 1.0
Stannole 1.0
Dihydrocholesterol 0.1
Lanosterol 0.1
Dihydrolanosterol 0.1
Glycerin 7.0
DPG 7.0
Menthol 0.1
Camphor 0.1
Tocopherol ferulate 0.1
Tocopherol phosphate 0.1
Polyglyceryl laurate-10 0.5
Tocotrienols 0.1
Part D Citric acid 0.07
Appropriate amount of Na citrate EDTA-2Na 0.1
Tranexamic acid (Nippon Fine Chemical Co., Ltd.) 2.0
Methylparaben 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was mixed and heated to about 70 ° C. to uniformly dissolve. Part B was mixed and stirred to give a viscous liquid. Part C was mixed and heated to about 70 ° C. to uniformly disperse. Part D was mixed and heated to about 70 ° C. to uniformly dissolve. Part A was added to part C with stirring with a homogenizer, and then part D was added for emulsification. After cooling, part B was added at about 50 ° C., and the mixture was stirred and uniformly dissolved.

Example 45 Skin care cream
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 1.0
Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 1.5
Neosolue-EHS (Nippon Fine Chemical Co., Ltd.) 8.0
Plandoll-ISS (Nippon Fine Chemical Co., Ltd.) 1.0
Diisopropyl sebacate (IPSE: Nippon Fine Chemical Co., Ltd.) 2.0
Bacil isostearate 2.0
Shea butter 3.0
Cyclopentasiloxane 5.0
Isostearyl pivalate 0.1
NS-408 (Nippon Fine Chemical Co., Ltd.) 0.1
Ethylparaben 0.2
Stearyl alcohol 3.5
Dimethicone 1.0
Cyclomethicone 3.0
Tocopherol 0.1
Ascorbyl tetrahexyl decanoate 3.0
Tocopheryl phosphate ascorbyl 2.0
Placenta extract 1.0
Oryzanol 0.3
Phytosphingosine 0.0001
Ubiquinone 0.03
Carotene 0.05
Lycopene 0.01
Astaxanthin 0.01
Lutein 0.01
Peanut oil 0.1
Rice bran oil 1.0
Hydrogenated castor oil 0.3
Jojoba oil 2.0
Orange roughy oil 1.0
Liquid lanolin (Nippon Fine Chemical Co., Ltd.) 1.0
Purified lanolin (Nippon Fine Chemical Co., Ltd.) 1.0
Belpole L-50 (Nippon Fine Chemical Co., Ltd.) 1.0
Lanolin alcohol (Nippon Fine Chemical Co., Ltd.) 0.3
Lanolin acetate alcohol 0.1
Cholesteryl acetate 0.1
Polyglyceryl triisostearate-2 1.0
PEG-60 glyceryl isostearate 1.5
Stearic acid PG (SE) 1.0
Glyceryl stearate (SE) 1.0
Octocrylene 0.05
Part B Tremoist-TP (Nippon Fine Chemical Co., Ltd.) 0.05
Tuberose polysaccharide 0.01
Water-soluble collagen 0.05
Hydrolyzed collagen 0.5
2-Methylloyloxyethyl phosphorylcholine
Butyl methacrylate copolymer solution 0.05
(HEMA Glucoside / Ethyl Trimonium Methacrylate) Copolymer (20%, Nippon Fine Chemical Co., Ltd.) 0.4
Glutathione 0.3
4- (4-Hydroxyphenyl) -2-butanol 1.5
Butyl resorcinol 1.5
Arbutin (Nippon Fine Chemical Co., Ltd.) 3.0
Ascorbyl Phosphate Mg 1.0
Part C BG 5.0
Glycerin 7.0
DPG 2.0
Sodium metabisulfite 0.1
Imidazolenium urea 0.1
Polyvinylpyrrolidone 0.1
Pullulan 0.1
Polyvinyl alcohol 0.1
Dehydroacetic acid 0.1
PEG-30 1.0
Diglycerin 1.0
Polyglycerin 1.0
Pentetic acid 5Na 0.05
Appropriate amount of phosphoric acid and sodium phosphate Purified water Amount totaling 100 Part D Cosmetic composition of Example 1 1.0
Purified water 15.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was heated to about 70 ° C. and dissolved uniformly. Part C was heated to about 70 ° C. and dispersed. Part D was well stirred with a propeller to prepare a dispersion. While stirring with a homomixer at about 70 ° C., part A was gradually added to part C, emulsified and mixed uniformly, cooled to about 40 ° C., parts B and D were added, and the mixture was uniformly mixed.

Example 46 Skin care cream
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 5.0
PG 2.0
Phytocompo-C (Nippon Fine Chemical Co., Ltd.) 1.0
Part B Plandoll-LG2 (Nippon Fine Chemical Co., Ltd.) 0.5
Plandoll-LG1 (Nippon Fine Chemical Co., Ltd.) 0.5
LUSPLAN DD-DA7 (Nippon Fine Chemical Co., Ltd.) 0.1
Plandoll-MAS (Nippon Fine Chemical Co., Ltd.) 0.5
Glyceryl amide ethyl methacrylate
Stearyl Methacrylate Copolymer 0.05
Olive oil 3.5
Macadamia nut oil 4.5
Hydrogenated vegetable oil 3.0
Dimethicone (100cs) 0.5
Ethylhexyl methoxycinnamate 2.0
Ethylparaben 0.15
Lanolin fatty acid octyldodecyl 1.0
Isostearic acid hardened castor oil 0.5
Ethyl oleate 3.0
Avocado Oil Fatty Acid Ethyl 2.0
Isopropyl palmitate 2.0
Isopropyl isostearate 1.0
Methyl heptyl laurate 3.0
Methyl heptyl myristate 3.0
Methyl heptyl palmitate 3.0
Methyl heptyl isostearate 3.0
Diethyl sebacate 1.0
Diisopropyl sebacate 1.0
Diisopropyl adipate 1.0
Diisobutyl adipate 1.0
Dioctyl succinate 1.0
Triethyl citrate 1.0
Cetyl lactate 1.0
Diisostearyl malate 5.0
γ-docosalactone 0.2
Glyceryl triolein 0.1
Glyceryl triisostearate 0.1
Glyceryl diisostearate 0.1
Tri (caprylic acid / capric acid / myristic acid /
Stearic acid) glyceryl 0.1
(Behenic acid / icosane diacid) Glyceryl 0.1
Trimethylolpropane trioctanoate 0.5
Neopentyl glycol dicaprate 1.0
Perfluorodecane 1.0
Perfluorooctane 1.0
5,5'-Dipropyl-biphenyl-2,2'-diol 0.3
Oil-soluble chamomile extract 0.3
Oil-soluble licorice extract 0.05
Retinol 0.1
Retinyl acetate 0.1
Retinol palmitate 0.1
Pyridoxine dioctanoate 0.1
Pyridoxine dipalmitate 0.1
Tocopherol nicotinate 0.1
Tocopherol acetate 0.1
Tocopherol linoleate 0.1
Glycyrrhetinic acid 0.05
Hinokitiol 0.05
Indomethacin 0.05
Hydrocortisone acetate 0.1
Prednisolone 0.1
Diphedramine hydrochloride 0.1
Borneol 0.1
Cepharanthine 0.001
Photosensitizer 301 0.001
Photosensitizer 401 0.001
Cetyl tranexamic acid 2.0
Part C Cosmetic composition of Example 1 2.5
Ascorbyl tetrahexyl decanoate 1.0
Purified water 10.0
Part D Methylparaben 0.1
Phenoxyethanol 0.2
Xanthan gum 0.1
(Acrylate / Alkyl Acrylate (C10-30)) Cross Polymer 0.2
(Hydroxyethyl acrylate /
Acryloyl dimethyl taurine Na) copolymer 0.2
Arginine 0.3
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was heated to about 70 ° C. and dispersed uniformly. Part B was heated to about 80 ° C. and dissolved uniformly. Part C was stirred well to prepare a dispersion. Part A was added and dispersed while stirring part A with a homodisper (part E). Further, the D part was added to the E part with stirring. The mixture was stirred and cooled to about 40 ° C.

Example 47 Skull Lotion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Pentylene Glycol 2.0
Glycyrrhetinic acid 0.05
PPG-5 Phytosterol 0.1
Cosmetic Composition of Example 2 2.5
Part B Methylparaben 0.1
Purified water 50.0
Part C Glycerin 4.0
Maltitol liquid 0.5
Ethanol 10.0
Neosolue-Aquolio (Nippon Fine Chemical Co., Ltd.) 1.0
Tocopherol acetate 0.05
Menthol 0.1
Mentoxipropanediol 0.05
Betaine 0.2
Carrot extract 0.1
Swertia japonica extract 0.1
Menispermaceae root extract 0.003
Pyridoxine hydrochloride 0.05
Panthenol 0.1
PCA-Na 0.1
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Each component was measured and mixed uniformly. Part A was added to part B to prepare a dispersion. Further, part C was added with stirring to make it uniform.

Example 48 Skull Lotion
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Glycerin 2.0
The cosmetic composition of Example 5 0.3
Purified water 10.0
Part B Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.5
Nicotinamide 1.0
Dipotassium glycyrrhizinate 0.1
VC Ethyl (Nippon Fine Chemical Co., Ltd.) 0.3
Hyaluronic acid Na 0.01
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.5
Caprilyl proline 0.3
Raffinose 0.2
Arginine 0.5
Serine 0.1
Glycine 0.1
Purified water 50.0
Part C ethanol 10.0
Methylparaben 0.1
Menthol 0.1
Mentoxipropanediol 0.1
Ethyl dicarboethoxypantothenate 0.2
Camphor 0.1
Carrot extract 1.0
Swertia japonica extract 1.0
Glycosyl trehalose 0.5
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
(Preparation method)
Part A was stirred with a propeller to prepare a dispersion. The components of parts B and C were measured and mixed uniformly. After adding part B to part A to make it uniform, part C was added to make it uniform.

Example 49 Body shampoo
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 2 0.3
Purified water 10.0
Part B Neosolue-AquaS (Nippon Fine Chemical Co., Ltd.) 0.5
Cocoyl methyl taurine Na 10.0
Lauroyl hydrolyzed silk Na 6.0
Lauroylmethylalanine Na 10.0
Sodium cocoamphoacetate (30%) 4.0
Cocamidopropyl Betaine (30%) 10.0
Olefin (C14-16) Na Sulfonate 5.0
Polyquaternium-10 1.3
Guar Hydroxypropyltrimonium Chloride 0.8
Acetyl hyaluronic acid Na 0.02
Cocamide DEA 3.0
Glycerin 5.0
Methylparaben 0.2
Amount of purified water totaling 100 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Part A was stirred and mixed with a propeller to prepare a dispersion. Part B was weighed and heated to about 80 ° C. and mixed uniformly. Part B was cooled with stirring, and part A was added at 40 ° C.

Example 50 Hair mist
Composition amount (% by weight)
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
Part A Cosmetic Composition of Example 1 2.5
Purified water 20.0
Part B Neosolue-Aquilio (Nippon Fine Chemical Co., Ltd.) 0.5
Betaine 0.5
Sea salt 0.1
Tremoist-SL (Nippon Fine Chemical Co., Ltd.) 0.3
Amount of purified water totaling 50 Part C Squalene 25.0
Neosolue-MCT (Nippon Fine Chemical Co., Ltd.) A total amount of 50 Olive oil 5.0
Tocopherol 0.05
Plandoll-SUN (Nippon Fine Chemical Co., Ltd.) 1.0
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−–
(Preparation method)
Parts A and B were weighed and mixed uniformly, and then the two agents were mixed to make them uniform. Further, a uniformly mixed part C was added to prepare a liquid for separating into two phases.

In the above formulation, the details of the ingredients described by the product names are as follows.
〇Plandol-H: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-S: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
〇Plandol-G: Dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl)
〇Plandol-DP: Bisdiglyceryl polyacyl adipate-2
〇Plandol-ISS: Phytosteryl isostearate 〇Plandol-SUN: Sunflower seed oil fatty acid phytosteryl 〇Plandol-MAS: Macadamia nut oil fatty acid phytosteryl 〇Plandol-LG1: Di (phytosteryl / octyldodecyl) lauroyl glutamate
〇Plandol-LG2: Di lauroyl glutamate (phytosteryl / octyldodecyl)
〇Plandol-LG3: Di lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇Plandol-LG4: Di-lauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇LUS PLAN DD-IS: Dimersylinoleyl diisostearate 〇LUSPLAN PI-DA: Dimergelinoleate di (isostearyl / phytosteryl)
〇LUSPLAN DD-DHR: Dimerge linoleic acid hydrogenated rosin condensate 〇LUSPLAN DD-DA5: Dimerge linoleic acid Dimerge linoleyl 〇LUSPLAN DD-DA7: Dimerge linoleic acid Dimerge linoleyl 〇LUSPLAN SR-DM4: Die Dimer dilinoleic acid dimer dilinoleic acid, tri (caprylic acid / capric acid) glyceryl 〇LUS PLAN SR-DP4: dimer dilinoleic acid dimer dilinoleic acid, pentaerythrityl tetraisostearate 〇 Neosolue-Aquilio: bisethoxydiglycol cyclohexanedicarboxylic acid 〇 Neosolue-Aqua: (eicosane linoleic acid / tetradecanedioic acid) polyglyceryl-10, glycerin 〇 Neosolue-Aqua S: (eicosane diacid / tetradecanedioic acid) polyglyceryl-10, glycerin 〇 Neosolue-MP: dineopentane methylpentanediol 〇 -DE: Diethylpentanediol dineopentanoate 〇 Neosolue-IOP: Ethylhexyl palmitate 〇 Neosolue-EHS: Diethylhexyl sevacinate 〇Composite-PC: Hydrohydrated lecithin, cholesterol 〇Phytocompo-PP: Hydrophilic lecithin, phytosterols 〇Phyto : Hydrophobic lecithin, phytosterols, ceramide 2, ceramide 3, ceramide 6II
〇 Phytocompo-C5: Hydrogenated lecithin, phytosterols, ceramide 2, ceramide 3, ceramide 6II
〇Phytocompo-SP: Hydrogenated lecithin, phytosterols, BG, glycerin 〇LP70H: Hydrogenated lysolecithin (Nippon Fine Chemical Co., Ltd.)
〇 Tremoist-TP: Snow fungus polysaccharide 〇 Tremoist-SL: Snow fungus polysaccharide aqueous solution (1%)
〇YOFCO MAC: Macadamia nut oil fatty acid cholesteryl 〇Cation NH: Quotanium-33
〇 Elcalactone DES: γ-docosalactone, diethyl sebacate 〇Elcalactone MCT: γ-docosalactone, tri (caprylic acid / capric acid) glyceryl 〇NanoRepair-CMC5: ceramide 1, ceramide 2, ceramide 3, ceramide 5, ceramide 6, Ceramide, Quotanium-33, etc. 〇 NS-408: Pentaerythrityl tetraethylhexanoate 〇 Belpole L-50: PEG-50 lanolin

値が大きいほど、色が変化していることを示しており、実施例１の製剤１は、製剤１を塗布しないものと比較して髪の色の退色を防ぐことが明らかとなった。特に10回のダメージ処理後の退色抑制効果は、無処置及びフラーレンを除いた製剤２と比較して顕著であった。 Example 51
Regarding the cosmetic composition of Example 1, the effect of suppressing hair fading was confirmed.
(Materials used, etc.)
・ Human hair: White hair (Bulux Co., Ltd.)
・ Hair dyeing: Wella Reach Cream, Choleston Perfect 14/45, Wella Welloxon Perfect (above, made by P & G)
-A preparation prepared from the cosmetic composition of Example 1 excluding fullerene-A preparation prepared from the cosmetic composition of Example 1 (preparation of preparation)
<Preparation of Formula 1 of Example 1>
0.5 g of the cosmetic composition of Example 1 was dissolved in 49.5 g of water to obtain Formula 1.
<Preparation of preparation 2 excluding fullerene from Example 1>
0.5 g of the composition obtained by removing fullerene from the cosmetic composition of Example 1 was dissolved in 49.5 g of water to obtain the pharmaceutical product 2.
(Processing method)
-Bleach treatment The bleach treatment was performed twice for 3 bundles of gray hair.
Wella Welloxon Perfect was mixed 1: 2 and applied to the hair. After application, it was left for about 40 minutes, rinsed with hot water, and then shampooed twice.
-Hair dyeing treatment Choleston Perfect 14/45 and Weroxon Perfect were mixed well at a ratio of 1: 2 and then applied to the bleached hair bundle. After leaving it for 30 minutes, it was shampooed and dried with a dryer.
・ Damage treatment Hair bundles were washed, towel-dried, sprayed with a formulation, completely dried with a dryer, lightly sprayed with water, and then UVB (about 5 mW / cm ² ) was repeated for 10 minutes to dye the hair. Damaged the hair bundle. For no treatment, towel drying was followed by direct dryer drying.
・ Measurement (Spectro Photometer SE-7700, Nippon Denshoku Kogyo)
Colors were measured at 6 points (root, middle, and tip of hair on both sides) for one hair bundle, and the average value was used.
After hair dyeing, the damage was measured at the 1st, 5th, and 10th times. ΔE was measured from the Lab value immediately after hair dyeing and the Lab after damage, and the degree of color change was observed.
The results are shown in Table 6 and FIG.

The larger the value, the more the color changed, and it was clarified that the pharmaceutical product 1 of Example 1 prevented the fading of the hair color as compared with the one to which the pharmaceutical product 1 was not applied. In particular, the effect of suppressing fading after 10 times of damage treatment was remarkable as compared with the untreated and the preparation 2 excluding fullerene.

Example 52
It is known that when hair is damaged by oxidation, the SS bond of cystine is oxidized to produce cysteic acid. Therefore, for the cosmetic composition of Example 1, the amount of cysteic acid in the hair generated by ultraviolet rays was quantified. Human black hair (Bulux Co., Ltd.) was washed with a 1% aqueous sodium lauryl sulfate solution, washed with water, and air-dried. After that, it was cut to about 5 cm and fixed in a holder, and then the infrared absorption spectrum was measured to calculate the ratio ^{of the absorption wavelength (1040 cm -1} ) of the cysteic acid residue to the absorption wavelength of ^{the amide (1634 cm -1) (Affinity).} -1, DuraSamplIR II, Shimadzu Corporation). Then, water or an aqueous solution of Example 1 diluted to 5% was applied, and the mixture was completely dried with a dryer. The hair was irradiated with ultraviolet rays (about 300 J / cm ² , 70 hours) under a UVB lamp. Then, it was washed and dried, and the infrared absorption spectrum was measured again. It was confirmed in advance that this condition did not affect the spectrum due to the application of the pharmaceutical product of Example 1.
As a result, as shown in FIG. 2, in the case of only water treatment, the absorption of S = O showing cysteic acid increased after irradiation with ultraviolet rays, whereas in the aqueous solution (5%) treated hair of Example 1, the amount of cysteic acid was increased. It was confirmed that there was no change in. From this result, it was clarified that the formulation of Example 1 can effectively suppress the oxidative damage of hair due to ultraviolet rays.

Claims (5)

The following components (A) to (E):
(A) An oil containing 0.001 to 0.3% by weight of fullerene dissolved in an oil containing one or more selected from ester oils (B) Polyglycerin fatty acid ester and polyoxyethylene glycerin fatty acid ester. Containing one or more nonionic surfactants (C) glycerin, or polyhydric alcohol (D) oil (E) water which is glycerin and 1,3-butylene glycol,
The content of the component (A) is 1 to 20% by weight, the content of the component (B) is 15 to 45% by weight, the content of the component (C) is 10 to 35% by weight, and the content of the component (D) is. A cosmetic composition having a bicontinuous structure having 10 to 30% by weight and a content of the component (E) of 10 to 40% by weight. A claim characterized by uniformly coloring the hue of each dye in both the case of adding a liquid in which a water-soluble dye is dissolved in water and the case of adding a liquid in which an oil-soluble dye is dissolved in oil. The cosmetic composition according to 1. Component oil (A) in the cosmetic composition according to claim 1 or 2, wherein the containing over 1 or more kinds selected lactone derived material or et al., Which is represented by the following general formula (1) Stuff.

(In the formula, n is 1 or 2, and R represents a saturated or unsaturated hydrocarbon group of a linear or branched chain having 9 to 22 carbon atoms.) A cosmetic in which the cosmetic composition according to any one of claims 1 to 3 is dispersed in an aqueous medium. A hair cosmetic in which the cosmetic composition according to any one of claims 1 to 3 is dispersed in an aqueous medium.

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