JP7345325B2 - Cosmetics containing esterified hard lanolin fatty acids - Google Patents

Description

The present invention relates to a cosmetic containing an esterified product of hard lanolin fatty acid and a saturated linear alcohol or/and polyhydric alcohol having 12 to 26 carbon atoms.
Regarding.

Wax is used in a wide range of applications in cosmetics. For example, in makeup cosmetics such as lipstick and foundation, wax is used to solidify the dosage form, adjust hardness and viscosity, form a film, and add shine to emulsions, creams, In skin cosmetics such as detergents, the purpose is to improve the feeling of use and to suppress water evaporation by forming a film, and in hair cosmetics such as shampoos, treatments, and hair styling products, the purpose is to adjust the hardness and viscosity of the dosage form, protect the hair, and hair styling. It is used for purposes such as imparting sex. As waxes used in cosmetics, carnauba wax, candelilla wax, paraffin wax, polyethylene wax, etc. are commonly used, but these are not necessarily insufficient in terms of providing a feeling of use and emollient properties.

Lanolin fatty acid is a general term for fatty acids obtained by saponifying and decomposing lanolin, and its main components are normal fatty acids, iso fatty acids, anteiso fatty acids, α-hydroxy normal fatty acids, α-hydroxy iso fatty acids, etc. It is a fatty acid with a very complex composition with a wide distribution of carbon numbers ranging from 9 to 33. Lanolin fatty acids, which have such a unique composition, have various characteristics and have been incorporated into cosmetics for a long time. In addition, various attempts at derivatization have been made, and examples of ester derivatives include lanolin fatty acid triglyceride (Patent Document 1), lanolin fatty acid polyethylene glycol ester (Patent Document 2), and lanolin fatty acid linear alcohol ester (Patent Document 1). 3), lanolin fatty acid branched alcohol ester (Patent Document 4), etc. are disclosed. However, such conventional esterified products of lanolin fatty acids are not used as wax components because their melting points and hardness are insufficient.

Hard lanolin fatty acids are high melting point lanolin fatty acids obtained by removing relatively low melting point components from lanolin fatty acids or their ester derivatives by distillation or solvent fractionation. Regarding esterified products of hard lanolin fatty acids, attempts have already been made to use them as industrial waxes such as toners and mold release agents (Patent Documents 5 and 6), but their use in the cosmetics field is not known at all. .

Japanese Patent Publication No. 53-018738 Japanese Patent Application Publication No. 53-121945 Japanese Patent Application Publication No. 05-105612 Japanese Patent Application Publication No. 11-171735 JP 2007-057869 JP 2012-192429

An object of the present invention is to provide a wax that has superior feel and emollient properties compared to waxes conventionally used in cosmetics, and cosmetics containing the wax.

The present inventors conducted studies to solve the above problems, and found that an esterified product of hard lanolin fatty acid and a saturated linear alcohol or/and polyhydric alcohol having 12 to 26 carbon atoms solves the above problems. They discovered this and completed the present invention.

The esterified product of hard lanolin fatty acids of the present invention has sufficient melting point and hardness, and can be preferably used as a wax component in cosmetics, and has superior usability compared to waxes conventionally used in cosmetics. It has an excellent emollient effect.

The present invention will be explained in detail below. The present invention relates to a cosmetic containing an esterified product of a hard lanolin fatty acid and a saturated linear alcohol or/and polyhydric alcohol having 12 to 26 carbon atoms.

The hard lanolin fatty acid used in the present invention is a high melting point lanolin fatty acid obtained by removing relatively low melting point components from lanolin fatty acid or its lower alcohol ester by distillation or solvent fractionation. Lanolin fatty acid is a general term for fatty acids obtained by saponifying and decomposing lanolin, and its main components are approximately 7% normal fatty acids, 22% isofatty acids, 29% anteiso fatty acids, 25% α-hydroxynormal fatty acids, and α- It consists of 3% hydroxyisofatty acids and 14% unidentified components, and the number of carbon atoms in these fatty acids ranges widely from 9 to 33. The hard lanolin fatty acids used in the present invention preferably have a melting point of 50°C or higher, more preferably 60°C or higher.

When using a distillation method as a method for obtaining hard lanolin fatty acids, it is advantageous to use lower alcohol esters of lanolin fatty acids as raw materials, since the distillation temperature is lowered and thermal deterioration is prevented. As the distillation apparatus, a thin film vacuum distillation machine, a molecular distillation machine, etc. can be used. Distillation conditions are not particularly limited and can be selected appropriately, and by changing the ratio of distillate to distillation residue, it is possible to change the melting point of the fatty acid obtained. By saponifying and decomposing the distillation residue thus obtained, the desired hard lanolin fatty acid can be obtained. In addition, when using the solvent fractionation method, lanolin fatty acids or their esters can be separated into organic solvents such as hydrocarbon solvents such as hexane, heptane, methylcyclohexane, toluene, and xylene, halogen solvents such as dichloroethane, methanol, ethanol, isopropanol, etc. After heating and dissolving in alcohol solvents, ketone solvents such as acetone, methyl ethyl ketone, and methyl isobutyl ketone, ether solvents such as diethyl ether and tetrahydrofuran, ester solvents such as methyl acetate and ethyl acetate, or mixed solvents thereof, It can be obtained by separating the waxy material that precipitates after cooling using a centrifugal separator, pressure filter, or the like. The type and amount of the solvent to be used may be adjusted as appropriate, and by adjusting these, it is possible to change the melting point of the fatty acid obtained. As the hard lanolin fatty acid used in the present invention, commercially available products may be used, such as lanolin fatty acid SH (Nippon Fine Chemical) and lanolin fatty acid HHW (Nippon Fine Chemical).

Specifically, the saturated linear alcohol having 12 to 26 carbon atoms used in the present invention includes dodecanol, tridecanol, tetradecanol, pentadecanol, hexadecanol, heptadecanol, octadecanol, nonadecanol, Examples include eicosanol, docosanol, tricosanol, and tetracosanol. These may be used alone or in combination of two or more. Among these, saturated linear alcohols having 14 to 22 carbon atoms are preferable from the viewpoint of availability, preferable melting point, and hardness, and specific examples include tetradecanol, pentadecanol, hexadecanol, and heptadecanol. , octadecanol, nonadecanol, eicosanol, and docosanol are preferred.

Specifically, the polyhydric alcohol used in the present invention includes ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol/propylene glycol copolymer, 3-methyl-1 , 3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, propylene glycol, dipropylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene Examples include glycol, hexylene glycol, neopentyl glycol, trimethylolpropane, pentaerythritol, dipentaerythritol, glycerin, diglycerin, and polyglycerin. These may be used alone or in combination of two or more. Among these, from the viewpoint of availability and favorable melting point and hardness, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, 1,3-propanediol, propylene glycol, dipropylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, neopentyl glycol, trimethylolpropane, pentaerythritol, dipentaerythritol, glycerin, diglycerin, and polyglycerin are preferred, and ethylene glycol, diethylene glycol, triethylene glycol, polyethylene More preferred are glycol, propylene glycol, 1,3-butylene glycol, trimethylolpropane, pentaerythritol, dipentaerythritol, and glycerin.

The esterified product of hard lanolin fatty acids of the present invention can be produced by esterifying hard lanolin fatty acids and the various alcohols mentioned above. The esterification method is not particularly limited, and commonly used methods include a method in which raw fatty acids and alcohol are reacted without a solvent at 150 to 260°C, a method in which a catalyst and a solvent are used to react at 50 to 180°C, etc. It can be manufactured by When using a catalyst, common acid catalysts such as paratoluenesulfonic acid, sulfuric acid, hydrochloric acid, phosphoric acid, methanesulfonic acid, boron trifluoride diethyl ether complex, titanium alcoholate, and solid acid catalysts can be used. When using a solvent, commonly used solvents such as heptane, hexane, cyclohexane, toluene, xylene, etc. can be used. After the esterification reaction is completed, the product may be purified by conventional purification methods such as decolorization, deacidification, vacuum distillation, water washing, steam distillation deodorization, and activated carbon treatment.

The amount of the esterified hard lanolin fatty acid of the present invention to be added to cosmetics is not particularly limited as long as it does not impair the effects of the present invention, and is usually 0.01 to 70% by weight, preferably 0.05 to 70% by weight. It is 50% by weight.

Cosmetics containing the esterified product of hard lanolin fatty acids of the present invention may optionally contain water and additive ingredients normally added to cosmetics, such as oily bases, surfactants, alcohols, humectants, polymers, etc.・Thickening/gelling agent, antioxidant, preservative, bactericide, chelating agent, pH adjuster ・Acid/alkali, ultraviolet absorber, whitening agent, solvent, exfoliating/dissolving agent, antipruritic agent, anti-inflammatory agent, Antiperspirants, refreshing agents, antihistamines, astringents, stimulants, hair growth agents/blood circulation promoters, reducing agents/oxidizing agents, polymer powders, hydroxy acids, vitamins and their derivatives, sugars and their derivatives, It may contain organic acids, enzymes, nucleic acids, hormones, inorganic powders, fragrances, pigments, etc. to the extent that they do not impair the effects of the present invention.

Oil bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, arachyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, cerakyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, High-grade products such as palmitooleic acid, oleic acid, linoleic acid, linoleic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexadecanoic acid, anteisoheneicosanoic acid, long chain branched fatty acids, dimer acid, hydrogenated dimer acid, etc. Fatty acids and metal soaps such as their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium salts, sodium salts, etc., and nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin , α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, solid paraffin, and other hydrocarbons; candelilla wax, carnauba wax, rice wax, wood wax, beeswax, montan wax Waxes such as , ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, Fischer-Tropsch wax, polyethylene wax, ethylene-propylene copolymer; coconut oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado Oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat Vegetable oils and fats such as germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, shea butter, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; beef tallow, milk fat, Animal oils and fats such as horse tallow, egg yolk oil, mink oil, and turtle oil; Animal waxes such as spermaceti wax, lanolin, and orange roughy oil; Liquid lanolin, reduced lanolin, adsorption-refined lanolin, acetic acid lanolin, acetic acid liquid lanolin , hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, acetic acid lanolin alcohol, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidyl Sphingophospholipids such as inositol and sphingomyelin, phosphatidic acid, cyclic lysophosphatidic acid or its salts, phospholipids such as lysolecithin; hydrogenated soybean phospholipids, partially hydrogenated soy phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated Phospholipid derivatives such as egg yolk phospholipids; Sapogenins; Saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, di(cholesteryl/behenyl/octyldodecyl) N-lauroyl-L-glutamate ), N-lauroyl-L-glutamate di(cholesteryl/octyldodecyl), N-lauroyl-L-glutamate di(phytosteryl/behenyl/octyldodecyl), N-lauroyl-L-glutamate di(phytosteryl/octyldodecyl), N - Acyl sarcosine alkyl esters such as isopropyl lauroyl sarcosine, cholesteryl 12-hydroxystearate, cholesteryl macadamia nut oil fatty acid, phytosteryl fatty acid macadamia nut oil, phytosteryl fatty acid sunflower seed oil fatty acid, phytosteryl isostearate, cholesteryl soft lanolin fatty acid, cholesteryl hard lanolin fatty acid, long chain Sterol esters such as branched fatty acid cholesteryl and long-chain α-hydroxy fatty acid cholesteryl; lipid complexes such as phospholipid-cholesterol complexes and phospholipid-phytosterol complexes; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate , cetyl palmitate, octyldodecyl palmitate, cetyl octoate, hexyldecyl octoate, isotridecyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, neodecanoic acid Octyldodecyl, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolin fatty acid, dicaprylyl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, hydrogenated castor oil isostearate, ethyl oleate, ethyl avocado oil fatty acid , isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolin fatty acid, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methylheptyl isostearate, diethyl sebacate, diisopropyl sebacate, sebacin Monoalcohol carboxylic acid esters such as dioctyl acid, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl adipate, dioctyl succinate, triethyl citrate; cetyl lactate, diisostearyl malate, hydrogenated monoisostearate Oxyacid esters such as castor oil and γ-ercalactone; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri(caprylic acid/capric acid), glyceryl tri(caprylic acid/capric acid/ myristic acid/stearic acid) glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl eicosanedioate behenate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentyl dioctoate Glycol, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctoate, propylene glycol dioleate, pentaerythrityl tetraoctoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate , (isostearic acid/sebacic acid) ditrimethylolpropane, pentaerythrityl triethylhexanoate, (hydroxystearic acid/stearic acid/rosin acid) dipentaerythrityl, diglyceryl diisostearate, polyglyceryl tetraisostearate, polyglyceryl nonaisostearate-10, Deca (erucic acid/isostearic acid/ricinoleic acid) polyglyceryl-8, (hexyldecanoic acid/sebacic acid) diglyceryl oligoester, glycol distearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopentanoate, dineopentane polyhydric alcohol fatty acid esters such as acid 2,4-diethyl-1,5-pentanediol; alkyl ethers such as dicaprylyl ether; diisopropyl dimer dilinoleate, diisostearyl dimer dilinoleate, dimer dilinoleate (isostearyl/phytosteryl), dimer dilinoleic acid (phytosteryl/behenyl), dimer dilinoleic acid (phytosteryl/isostearyl/cetyl/stearyl/behenyl), dimer dilinoleyl diisostearate, dimer dilinoleyl diisostearate, Dimer acid or dimer diol derivatives such as dimer dilinoleyl hydrogenated rosin condensate, dimer dilinoleic acid hydrogenated castor oil, hydroxyalkyl dimer dilinoleyl ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (Cocamide DEA), Lauric acid monoethanolamide (Lauramide MEA), Lauric acid diethanolamide (Lauramide DEA), Lauric acid monoisopropanolamide (Lauramide MIPA), Palmitic acid monoethanolamide (Paltamid MEA), Palmitic acid diethanolamide ( Fatty acid alkanolamides such as partamide DEA) and coconut oil fatty acid methylethanolamide (cocamide methyl MEA); dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopenta siloxane), phenyl trimethicone, diphenyl dimethicone, phenyl dimethicone, (aminoethylaminopropyl methicone/dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone rubber, amino-modified silicone such as aminopropyl dimethicone and amodimethicone, cation-modified Silicone, polyether-modified silicone such as dimethicone copolyol, polyglycerin-modified silicone, sugar-modified silicone, carboxylic acid-modified silicone, phosphoric acid-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone, fatty acid-modified silicone, alkyl ether-modified silicone, amino acid-modified silicone Silicone, peptide-modified silicone, fluorine-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone, alkyl-modified and polyether-modified silicone, amide alkyl-modified silicone, aminoglycol-modified silicone, aminophenyl-modified silicone, polyester Preferred examples include silicones such as siloxane/oxyalkylene copolymers; fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether.

Humectants and feel improvers include glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols and their polymers such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol/propylene glycol copolymer; diethylene glycol monoethyl ether Glycol alkyl ethers such as (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosandioic acid/tetradecanedioic acid) polyglyceryl-10, tetradecanedioic acid polyglyceryl-10, cyclohexanedicarboxylic acid Water-soluble esters such as bisethoxydiglycol; sugar alcohols such as sorbitol, xylitol, erythritol, mannitol, maltitol; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, Trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, Saccharides and their derivatives such as heparin and derivatives, pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosylethyl methacrylate polymers or copolymers; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate , caronine sulfate, keratosulfate, dermatan sulfate; white fungus extract, white fungus polysaccharide; fructans such as inulin and levan; fucoidan; tuberose polysaccharide, naturally derived polysaccharides; organic acids such as citric acid, tartaric acid, lactic acid, and their salts ; Urea; 2-pyrrolidone-5-carboxylic acid and its salts such as sodium; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid , glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine, and other amino acids and their salts; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen-degrading peptide, hydration Degraded collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degraded peptide, keratin-degraded peptide, hydrolyzed keratin, conchiolin-degraded peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, sodium lauroyl hydrolyzed silk, soybean proteolytic peptide , protein peptides such as wheat proteolytic peptide, hydrolyzed wheat protein, caseinolytic peptide, acylated peptide, and derivatives thereof; acylated peptides such as palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetrapeptide; silylated peptides; Lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesame lignan glycoside, glutathione, albumin, whey; choline chloride, phosphorylcholine; placenta extract, aerastin, collagen, aloe extract, Hamamelis Water, animal and plant extracts such as loofah water, chamomilla extract, licorice extract, comfrey extract, silk extract, rose thorn extract, yarrow extract, eucalyptus extract, melilot extract, natural ceramides (types 1, 2, 3, 4) , 5, 6), ceramides such as hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide, and sugar ceramide-containing extracts are preferred.

Preferred examples of the surfactant include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, and polymeric surfactants. The HLB of the surfactant is not particularly limited and can range from as low as about 1 to as high as about 20, and it is also preferable to combine surfactants with low and high HLBs. Preferred examples of surfactants include anionic surfactants such as fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfate salts such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth; Polyoxyethylene alkyl sulfates such as sodium sulfate and triethanolamine laureth sulfate; sodium cocoyl methyl taurate, potassium cocoyl methyl taurate, sodium lauroyl methyl taurate, sodium myristoyl methyl taurate, sodium lauroyl methylalanine, sodium lauroyl sarcosine, and triethanol lauroyl sarcosine. Amine, acyl N-methyl amino acid salts such as sodium lauroyl glutamate methylalanine; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoyl alanine triethanolamine , acylamino acid salts such as dilauroylglutamate lysine Na; polyoxyethylene alkyl ether acetates such as sodium laureth acetate; succinate ester salts such as sodium lauroyl monoethanolamide succinate; fatty acid alkanolamide ether carboxylates; acyl lactates ; Polyoxyethylene fatty amine sulfate; Fatty acid alkanolamide sulfate; Fatty acid glyceride sulfate such as hydrogenated coconut oil fatty acid sodium glycerol sulfate; Alkylbenzene polyoxyethylene sulfate; Olefin sulfonate such as sodium α-olefin sulfonate; Sulfosucci Alkyl sulfosuccinates such as disodium lauryl acid and dioctyl sodium sulfosuccinate; alkyl ether sulfosuccinates such as disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, and sodium lauryl polypropylene glycol sulfosuccinate; tetradecyl Alkylbenzenesulfonates such as sodium benzenesulfonate and triethanolamine tetradecylbenzenesulfonate; alkylnaphthalenesulfonates; alkanesulfonates; α-sulfo fatty acid methyl ester salts; acyl isethionates; alkyl glycidyl ether sulfonates; Alkyl sulfoacetates; alkyl ether phosphate salts such as sodium laureth phosphate, sodium dilaureth phosphate, sodium trilaureth phosphate, sodium monooleth phosphate; alkyl phosphate salts such as potassium lauryl phosphate; sodium caseinate; alkylaryl ether phosphates Acid acid; fatty acid amide ether phosphate; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or its salts; silicone-based compounds such as carboxylic acid-modified silicone, phosphoric acid-modified silicone, and sulfuric acid-modified silicone Ionic surfactants, etc.; Nonionic surfactants include laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether), behenes (polyoxyethylene Polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers such as behenyl ether), isosteareth (polyoxyethylene isostearyl ether), and octyl dodeceth (polyoxyethylene octyl dodecyl ether); polyoxyethylene alkylphenyl ether; Oxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamate monoisostearate diester, polyoxy Castor oil and hydrogenated castor oil derivatives such as ethylene hydrogenated castor oil and maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene/polyoxypropylene Polymers such as cetyl ether, polyoxyethylene/polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene/polyoxypropylene monobutyl ether, polyoxyethylene/polyoxypropylene hydrogenated lanolin, polyoxyethylene/polyoxypropylene glycerin ether, etc. Oxyethylene/polyoxypropylene alkyl ether; polyoxyethylene/polyoxypropylene glycol; (poly)glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; glyceryl stearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, Glyceryl fatty acid partial esters such as glyceryl oleate, glyceryl coconut oil fatty acid, glyceryl monocottonseed oil fatty acid, glyceryl monoerucate, glyceryl sesquioleate, glyceryl pyroglutamate α,α'-oleate, glyceryl monostearate, malic acid; stearic acid Polyglyceryl-2, 3, 4, 5, 6, 8, 10, polyglyceryl-6 distearate, 10, polyglyceryl-2 tristearate, polyglyceryl-10 decastearate, polyglyceryl-2 isostearate , 3, 4, 5, 6, 8, 10, polyglyceryl-2 diisostearate (diglyceryl diisostearate), 3, 10, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate , polyglyceryl decaisostearate-10, polyglyceryl oleate-2, 3, 4, 5, 6, 8, 10, polyglyceryl dioleate-6, polyglyceryl trioleate-2, polyglyceryl decaoleate-10 Polyglycerin fatty acid esters such as; ethylene glycol monofatty acid esters such as ethylene glycol monostearate; propylene glycol monofatty acid esters such as propylene glycol monostearate; pentaerythritol partial fatty acid esters; sorbitol partial fatty acid esters; maltitol partial fatty acid esters; Maltitol ether; sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol pent-2-ethylhexylate, sorbitan, tetra Sorbitan fatty acid esters such as diglycerol sorbitan -2-ethylhexylate; partial esters of sugar derivatives such as sucrose fatty acid esters, methyl glucoside fatty acid esters, and trehalose undecylenate; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; mannosylerythritol lipids, etc. glycolipids; lanolin alcohol; reduced lanolin; polyoxyethylene fatty acid mono- and diesters such as polyoxyethylene distearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate; polyoxy Ethylene/propylene glycol fatty acid ester; polyoxyethylene glycerin fatty acid ester such as polyoxyethylene monooleate such as polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate; Polyoxyethylene sorbitan fatty acid esters such as oxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol Polyoxyethylene sorbitol fatty acid esters such as monooleate, polyoxyethylene sorbitol pentaoleate, and polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid esters; polyoxyethylene alkyl ether fatty acid esters; polyoxyethylene sorbitol beeswax, etc. polyoxyethylene animal and vegetable oils and fats; alkylglyceryl ethers such as isostearylglyceryl ether, chimyl alcohol, serakyl alcohol, butyl alcohol; polyhydric alcohol alkyl ether; polyoxyethylene alkylamine; tetrapolyoxyethylene/tetrapolyoxy Propylene-ethylenediamine condensates; natural surfactants such as saponin and sophorolipid; polyoxyethylene fatty acid amide; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (Lauramide MEA), Lauric acid diethanolamide (Lauramide DEA), Lauric acid monoisopropanolamide (Lauramide MIPA), Palmitic acid monoethanolamide (Palutamide MEA), Palmitic acid diethanolamide (Palutamide DEA), Coconut oil fatty acid methylethanolamide ( Fatty acid alkanolamides such as cocamidomethyl MEA); alkyl dimethyl amine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, and behenamine oxide; alkyl ethoxy dimethyl amine oxides; polyoxyethylene alkyl mercaptans; dimethicone copolyols, etc. Silicone nonionic surfactants such as polyether-modified silicone, polysiloxane/oxyalkylene copolymer, polyglycerin-modified silicone, and sugar-modified silicone; cationic surfactants include behentrimonium chloride and steartrimonium Alkyltrimethylammonium chlorides such as chloride, cetrimonium chloride and lauryltrimonium chloride; Alkyltrimethylammonium bromides such as stearyltrimonium bromide; Dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; stearamidopropyl dimethylamine , fatty acid amide amines and their salts such as stearamide ethyl diethylamine; alkyl ether amines such as stearoxypropyl dimethylamine and their salts or quaternary salts; ethyl sulfate long chain branched fatty acids (12-31) aminopropylethyl dimethyl ammonium, ethyl sulfate Fatty acid amide type quaternary ammonium salts such as lanolin fatty acid aminopropylethyl dimethyl ammonium; polyoxyethylene alkylamine and its salts or quaternary salts; alkyl amine salts; fatty acid amide guanidium salts; alkyl ether amine monoium salts; alkyl trialkylene Glycolammonium salts; benzalkonium salts; benzethonium salts; pyridinium salts such as cetylpyridinium chloride; imidazolinium salts; alkylisoquinolinium salts; dialkylmorphonium salts; polyamine fatty acid derivatives; aminopropyl dimethicone, amodimethicone, etc. Silicone-based cationic surfactants such as amino-modified silicone, cation-modified silicone, cation-modified and polyether-modified silicone, amino-modified and polyether-modified silicone, etc.; Among amphoteric surfactants, lauryl betaine (lauryl dimethylaminoacetic acid betaine) N-alkyl-N,N-dimethylamino acid betaines such as; fatty acid amide alkyl-N,N-dimethylamino acid betaines such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; Alkyl sulfobetaines such as alkyldimethyltaurine; Sulfuric acid betaines such as alkyldimethylaminoethanol sulfates; Phosphate betaines such as alkyldimethylaminoethanol phosphates; Sphingolins such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, and sphingomyelin Phospholipids such as lipids, lysolecithin, hydrogenated soybean phospholipids, partially hydrogenated soybean phospholipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids, and hydroxylated lecithin; silicone-based amphoteric surfactants, etc.; polymer interfaces Preferred active agents include polyvinyl alcohol, sodium alginate, starch derivatives, gum tragacanth, acrylic acid/alkyl methacrylate copolymers, and various silicone surfactants.

Polymers, thickeners, and gelling agents include guar gum, locust bean gum, queen seed, carrageenan, galactan, gum arabic, tara gum, tamarind, farcellan, gum karaya, trolo mallow, carra gum, gum tragacanth, pectin, pectic acid, and sodium. Salts such as salts, salts such as alginic acid and sodium salts, mannan; starches such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salts, xanthan gum, pullulan, gellan gum, chitin , chitosan, agar, Cassow extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose and its sodium salts, methylhydroxypropylcellulose, sodium cellulose sulfate, dialkyl dimethyl Cellulose and its derivatives such as ammonium cellulose sulfate, crystalline cellulose, cellulose powder; soluble starch, starch polymers such as carboxymethyl starch, methylhydroxypropyl starch, methyl starch, hydroxypropyltrimonium chloride starch, corn starch aluminum octenyl succinate, etc. starch derivatives; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinyl pyridone (PVP), polyvinyl alcohol (PVA), vinyl pyridone/vinyl alcohol copolymer, polyvinyl methyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene glycol; Polyoxypropylene copolymer; (methacryloyloxyethyl carboxybetaine/alkyl methacrylate) copolymer, amphoteric methacrylate ester copolymer such as (acrylates/stearyl acrylate/ethylamine oxide methacrylate) copolymer; (dimethicone/vinyl dimethicone) cross Polymer, (alkyl acrylate/diacetone acrylamide) copolymer, (alkyl acrylate/diacetone acrylamide) copolymer AMP; partially saponified polyvinyl acetate, maleic acid copolymer; vinylpyrrolidone/dialkylaminoalkyl methacrylate copolymer; Acrylic resin alkanolamine; polyester, water-dispersible polyester; polyacrylamide; polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its salt such as sodium salt, acrylic acid/methacrylic acid Ester copolymer; acrylic acid/alkyl methacrylate copolymer; cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride/acrylamide copolymer such as polyquaternium-7, acrylic acid/diallyl dimethyl such as polyquaternium-22 Ammonium chloride copolymer, acrylic acid/diallyldimethylammonium chloride/acrylamide copolymer such as polyquaternium-39, acrylic acid/cationized methacrylate ester copolymer, acrylic acid/cationized methacrylic amide copolymer, Acrylic acid/methyl acrylate/methacrylamidopropyltrimethylammonium chloride copolymers such as polyquaternium-47, methacrylic chloride choline ester polymers; cationized polysaccharides such as cationized oligosaccharides, cationized dextran, guar hydroxypropyltrimonium chloride, etc. Saccharides; polyethyleneimine; cationic polymers; copolymers of 2-methacryloyloxyethylphosphorylcholine such as polyquaternium-51 and butyl methacrylate copolymers; acrylic resin emulsions, polyacrylic acid ethyl emulsions, polyacrylic alkyl esters Polymer emulsions such as emulsions, polyvinyl acetate resin emulsions, natural rubber latex, and synthetic latex; Nitrocellulose; Polyurethanes and various copolymers; Various silicones; Various silicone copolymers such as acrylic-silicone graft copolymers Various fluorinated polymers; 12-hydroxystearic acid and its salts; Dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, fumed silica (ultrafine silicic anhydride), aluminum magnesium silicate, silicic acid Preferred examples include sodium magnesium acid, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, and fructooligosaccharide fatty acid ester.

Examples of solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, and isopentyl diol; Class: Diethylene glycol monoethyl ether (ethoxy diglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl Preferred examples include propellants such as alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation fluorocarbons; LPG, dimethyl ether, and carbon dioxide gas.

As antioxidants, tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and/or its derivatives; erythorbic acid and its derivatives; Sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, and cysteine hydrochloride are preferred. It is mentioned as. Preferred examples of the reducing agent include thioglycolic acid, cysteine, and cysteamine. Preferred examples of the oxidizing agent include hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

Antibacterial agents or preservatives include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane 1,2-alkanediols such as diols; alkylglyceryl ethers such as 2-ethylhexylglyceryl ether (ethylhexylglycerin); glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, glyceryl (caprylic acid/capric acid); Salicylic acid; sodium benzoate; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; imidazolinium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary Ammonium salts; trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, Other phenols such as phenylphenol sodium; phenylethyl alcohol, photosensitizers, antibacterial zeolites, and silver ions are preferred; however, when used as antibacterial agents or preservatives for the purpose of preservation, cosmetics or skin From the viewpoint of safety of external preparations, phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol; alkylglyceryls such as 2-ethylhexylglyceryl ether; Ethers: It is more preferable to use glycerin fatty acid esters such as glyceryl caprylate, glyceryl caprate, and glyceryl (caprylic/capric acid).

As chelating agents, edetate salts (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, EDTA4Na; hydroxyethylethylenediamine triacetate such as HEDTA3Na; pentetate salts (diethylenetriaminepentaacetate); phytic acid; etidronic acid, etc. Salts such as phosphonic acid and its sodium salt; Sodium oxalate; Polypolyamino acids such as polyaspartic acid and polyglutamic acid; Sodium polyphosphate, sodium metaphosphate, phosphoric acid; Sodium citrate, citric acid, alanine, dihydroxyethylglycine Preferred examples include , gluconic acid, ascorbic acid, succinic acid, and tartaric acid. Examples of pH adjusters/acids/alkali include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, and monoethanol. Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylated Preferred examples include sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate.

Powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, rhodochite, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica. Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metallic soaps (e.g. zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, deep blue, carbon black, titanium oxide, fine and ultrafine titanium oxide, zinc oxide , fine and ultrafine particles of zinc oxide, alumina, silica, fumed silica (ultrafine silicic acid anhydride), mica titanium, fish scale foil, boron nitride, photochromic pigments, synthetic fluorine phlogopite, fine particle composite powder, gold, aluminum, etc. Inorganic powders of various sizes and shapes, and these are treated with silicone such as hydrogen silicone, cyclic hydrogen silicone, other silanes, or various surface treatment agents such as titanium coupling agents to make them hydrophobic or Inorganic powders such as hydrophilic powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate・Organic powders of various sizes and shapes such as polymethyl methacrylate laminated powder, polyethylene terephthalate/aluminum/epoxy laminated powder, urethane powder, silicone powder, Teflon (registered trademark) powder, etc., and surface-treated powder, organic and inorganic. Composite powder is preferred. Inorganic salts include sodium chloride-containing salts such as common salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum/potassium sulfate (alum), aluminum/ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na, and 3Na phosphate, phosphoric acid Preferred examples include potassium, calcium phosphates, and magnesium phosphates.

As ultraviolet absorbers, para-aminobenzoic acid, para-aminobenzoic acid monoglycerin ester, N,N-dipropoxypara-aminobenzoic acid ethyl ester, N,N-diethoxypara-aminobenzoic acid ethyl ester, N,N-dimethyl para-aminobenzoic acid ethyl ester. Benzoic acid-based UV absorbers such as ester, N,N-dimethylpara-aminobenzoic acid butyl ester, N,N-dimethylpara-aminobenzoic acid ethyl ester; Anthranilic acid-based UV absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid Salicylic acid UV absorbers such as and its sodium salts, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate; octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl -2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxy Cinnamate, 2-ethylhexyl p-methoxycinnamate (octyl para-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (cinoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenyl Cinnamic acid UV absorbers such as cinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, ferulic acid and its derivatives; 2, 4-dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2',4,4'-tetrahydroxybenzophenone, 2-hydroxy- 4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4' - Benzophenone UV absorbers such as phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone; 3-(4'-methylbenzylidene)-d, l-camphor, 3-benzylidene-d,l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2-(2'-hydroxy-5'- t-octylphenyl)benzotriazole; 2-(2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5-(3,3-dimethyl-2-norbornylidene)-3-pentane-2- dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyltriazole; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2-(2'-hydroxy-5'-methylphenyl)benzotriazole , 1-(3,4-dimethoxyphenyl)-4,4-dimethyl-1,3-pentanedione, dimethoxybenzylidene dioxoimidazolidine, hydantoin derivatives such as 2-ethylhexyl propionate, phenylbenzimidasozole sulfonic acid, Preferred examples include phthalylidene dicanfursulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, and oryzanol and its derivatives.

As whitening agents, hydroquinone glycosides and their esters such as arbutin and α-arbutin; ascorbic acid, ascorbic acid phosphate salts such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt, ascorbic acid; Ascorbic acid fatty acid ester such as tetraisopalmitic acid ester, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and its fatty acid esters, ascorbic acid sulfate ester, tocopheryl ascorbyl phosphate Ascorbic acid derivatives such as kojic acid, ellagic acid, tranexamic acid and its derivatives, ferulic acid and its derivatives, placenta extract, glutathione, oryzanol, butylresorcinol, oil-soluble chamomilla extract, oil-soluble licorice extract, saxifrage extract, saxifrage extract Preferred examples include plant extracts such as the following.

Examples of vitamins and their derivatives include vitamin A such as retinol, retinol acetate, and retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acids, nicotinic acids such as nicotinamide and benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its salts such as sodium; vitamin D; α, Vitamin E such as β, γ, δ-tocopherol; Other vitamins such as pantothenic acid and biotin; ascorbic acid phosphate salts such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt, ascorbic acid tetra Ascorbic acid fatty acid esters such as isopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate, ascorbyl dipalmitate, ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucosides such as ascorbic acid-2-glucoside, and their fatty acid esters , ascorbic acid derivatives such as tocopheryl ascorbyl phosphate; vitamin derivatives such as tocopherol derivatives such as tocopherol nicotinate, tocopheryl acetate, tocopherol linoleate, tocopherol ferulate, and tocopherol phosphate, tocotrienols, and other various vitamin derivatives are preferred. It is mentioned as.

Anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, dipedramine hydrochloride, chlorpheniramine maleate; peach leaf extract. Preferred examples include plant extracts such as , mugwort leaf extract and the like. Hair growth drugs, blood circulation promoters, and stimulants include plant extracts and tinctures such as Aspergillus japonica extract, capsicum tincture, ginger tincture, ginger extract, and cantharis tincture; capsaicin, nonylic acid valenylamide, zingerone, ictamol, and tannic acid. , borneol, cyclanderate, cinnarizine, tolazoline, acetylcholine, verapamil, cephalanthine, γ-oryzanol, cephalanthine, vitamin E and derivatives such as tocopherol nicotinate and tocopherol acetate, γ-oryzanol, nicotinic acid and nicotinamide and benzyl nicotinate. Ester inositol hexanicotinate, derivatives such as nicotine alcohol, allantoin, photosensor 301, photosensor 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivatives, stigmasterol or stigmastanol and its glycosides, and minoxidil are preferred. It is mentioned as. Preferred examples of hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, and prednisone. Other medicinal agents such as anti-wrinkle agents, anti-aging agents, tightening agents, cooling agents, warming agents, wound healing promoters, irritation relievers, analgesics, and cell activators include retinols, retinoic acids, and retinoin. Tocopheryl acid: derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and its glycosides and esters, hydroxycapric acid, long chain α-hydroxy fatty acids, α- or long chain α-hydroxy fatty acids such as cholesteryl β-hydroxy acids and their derivatives; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosine; caffeine, xanthine, etc. and their derivatives; coenzyme Q10, carotene, lycopene , astaxanthin, lutein, α-lipoic acid, nanocolloidal platinum, fullerenes and other antioxidants and active oxygen scavengers; catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; tannins, sesamin, proto Polyphenols such as anthocyanidins, chlorogenic acid, and apple polyphenols; derivatives such as rutin and glycosides; derivatives such as hesperidin and glycosides; lignan glycosides; substances related to licorice extract such as glabridin, glabrene, liquiritin, and isoliquiritin; lactoferrin ; gingerol, gingerol; fragrance substances and their derivatives such as menthol, camphor, cedrol; capsaicin, vanillin, etc. and derivatives; insect repellents such as diethyltoluamide; complexes of physiologically active substances and cyclodextrins are preferred. Can be mentioned.

Plant, animal, and microorganism extracts include iris extract, Ashitaba extract, Asunaro extract, asparagus extract, avocado extract, amacha extract, almond extract, althea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, and ginkgo extract. , fenugreek extract, fennel extract, turmeric extract, oolong tea extract, fennel extract, turmeric extract, echidna leaf extract, japonica extract, scutellariae extract, scutellariae extract, scutellariae extract, barley extract, panax ginseng extract, hypericum extract, deadlock root extract, ononis extract , mustard extract, orange extract, dried seawater, seaweed extract, persimmon leaf extract, persimmon extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolyzed silk, cuckoo extract, chamomilla extract, oil-soluble chamomilla extract, carot extract, mugwort Extract, oat extract, karkade extract, licorice extract, oil-soluble licorice extract, kiwi extract, kiosk extract, wood ear extract, cinchona extract, cucumber extract, tungsten leaf extract, guanosine, guava extract, kujin extract, gardenia extract, kumata extract, clara extract, walnut Extract, Chestnut extract, Grapefruit extract, Clematis extract, Black rice extract, Brown sugar extract, Black vinegar, Chlorella extract, Mulberry extract, Gentiana extract, Gennoshouko extract, Black tea extract, Yeast extract, Kouboku extract, Coffee extract, Burdock extract, Rice extract, Rice Fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, collagen, lingonberry extract, saicin extract, saicin extract, rhinoceros extract, saffron extract, salvia extract, soapwort extract, bamboo grass extract, hawthorn extract, sasanya extract, sasanya extract Extract, shiitake extract, rhododendron extract, perilla extract, perilla extract, linden extract, meadow extract, jatoba extract, peony extract, calamus extract, calamus root extract, white birch extract, white wood ear extract, horsetail extract, stevia extract, stevia fermented product, sahe willow extract, Hawthorn Extract, Hawthorn Extract, Sambucus Extract, Yarrow Extract, Mentha Extract, Sage Extract, Mallow Extract, Nebula Extract, Japanese Cucumber Extract, Cucumber Extract, Rhubarb Extract, Soybean Extract, Taishu Extract, Thyme Extract, Dandelion Extract, Ground Clothes extract, tea extract, clove extract, Chigaya extract, chimpi extract, tea tree oil, sweet tea extract, capsicum extract, Japanese ginger extract, Calendula extract, Tonin extract, Spruce extract, Hokutama extract, tomato extract, natto extract, carrot extract, garlic extract, Novara extract , hibiscus extract, bacterium extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietaria extract, hikiokoshi extract, bisabolol, cypress extract, bifidobacterium extract, loquat extract, coltsfoot extract, coltsfoot extract, butterbur extract, butcher Bloom extract, grape extract, grape seed extract, propolis, loofah extract, safflower extract, peppermint extract, bodega extract, button extract, hop extract, mica extract, pine extract, horse chestnut extract, skunk cabbage extract, Sapindium extract, Melissa extract, Mozuku extract , peach extract, cornflower extract, eucalyptus extract, saxifrage extract, yuzu extract, lily extract, yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, reishi extract, lettuce extract, lemon extract, forsythia extract , Astragalus extract, rose extract, rosemary extract, Roman chamomile extract, royal jelly extract, and silver leaf extract are preferred.

Examples of antipruritic agents include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, and substance-P inhibitors. Examples of exfoliating and dissolving agents include salicylic acid, sulfur, resorcinol, selenium sulfide, and pyridoxine. Examples of antiperspirants include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenolsulfonate. Examples of the refreshing agent include menthol, methyl salicylate, and the like. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum/potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, and protease. Preferred examples of the nucleic acids include ribonucleic acid and its salts, deoxyribonucleic acid and its salts, and disodium adenosine triphosphate.

Fragrances include acetyl cedrene, amyl cinnamaldehyde, allyl amyl glycolate, β-ionone, isoee super, isobutylquinoline, iris oil, irone, indole, ylang-ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oakmoss, opoponax resinoid, orange oil, eugenol, aurantiol, galaxolide, carvacrol, L-carvone, camphor, canon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranylnitrile , isobornyl acetate, geranyl acetate, dimethylbenzylcarbinyl acetate, styralyl acetate, cedryl acetate, terepinel acetate, p-t-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, linalyl acetate, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, Cyclamen aldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromircenol, jasmine absolute, jasmine lactone, cis-jasmone, citral, citronenol, citronellal, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, styrax Resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascone, damascenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, tripral, nerol, nonanal, 2,6-nonadienol, nonalactone, patchouli Alcohol, vanilla absolute, vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitgrain oil, hexylcinnamaldehyde, cis-3-hexenol, Peruvian balsam, vetiver oil, vetiverol , peppermint oil, pepper oil, heliotropin, bergamot oil, benzyl benzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylionone, menthol, L-menthol, L-menthone, eucalyptus oil, β-ionone, lime oil , lavender oil, D-limonene, linalool, liral, lireal, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and other synthetic and natural fragrances and various blended fragrances are preferred.

Pigments, colorants, dyes, and pigments include Brown No. 201, Black No. 401, Purple No. 201, Purple No. 401, Blue No. 1, Blue No. 2, Blue No. 201, Blue No. 202, Blue No. 203, and Blue No. 204. , Blue No. 205, Blue No. 403, Blue No. 404, Green No. 3, Green No. 201, Green No. 202, Green No. 204, Green No. 205, Green No. 3, Green No. 401, Green No. 402, Red No. 102, Red No. 104-1, Red No. 105-1, Red No. 106, Red No. 2, Red No. 3, Red No. 201, Red No. 202, Red No. 203, Red No. 204, Red No. 205, Red No. 206, Red No. 207 , Red No. 208, Red No. 213, Red No. 214, Red No. 215, Red No. 218, Red No. 219, Red No. 220, Red No. 221, Red No. 223, Red No. 225, Red No. 226, Red No. 227, Red No. 228, Red No. 230-1, Red No. 230-2, Red No. 231, Red No. 232, Red No. 3, Red No. 401, Red No. 404, Red No. 405, Red No. 501, Red No. 502, Red No. 503 , Red No. 504, Red No. 505, Red No. 506, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 205, Orange No. 206, Orange No. 207, Orange No. 401, Orange No. 402, Orange No. 403, Yellow No. 201, Yellow No. 202-1, Yellow No. 202-2, Yellow No. 203, Yellow No. 204, Yellow No. 205, Yellow No. 4, Yellow No. 401, Yellow No. 402, Yellow No. 403-1, Yellow No. 404, Yellow Legal dyes such as No. 405, Yellow No. 406, Yellow No. 407, Yellow No. 5; Other acid dyes such as Acid Red 14; Basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; HC Yellow 2. Nitro dyes such as HC Yellow 5, HC Red 3, 4-hydroxypropylamino-3-nitrophenol, N,N'-bis(2-hydroxyethyl)-2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26; Disperse dyes; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (red iron oxide) and iron titanate; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as yellow iron oxide and ocher Inorganic black pigments such as black iron oxide and low titanium oxide; Inorganic purple pigments such as mango violet and cobalt violet; Inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate; Ultramarine blue and deep blue Inorganic blue pigments such as titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc.; pearl pigments such as aluminum powder, copper powder, gold, etc. Metal powder pigments: anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotenes, catenals, capsanthin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, naphthoquinones such as cochineal and shikonin, bixin, flavones, betacyanidin, Natural pigments and dyes such as henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino- Preferred examples include oxidative dye intermediates and couplers such as 2-methylphenol, resorcinol, 1-naphthol, 2,6-diaminopyridine and their salts; autooxidative dyes such as indoline; and dihydroxyacetone.

Preferred examples of water include regular water, purified water, hard water, soft water, natural water, deep ocean water, electrolyzed alkaline ionized water, electrolyzed acidic ionized water, ionized water, and cluster water.

In addition to these, standards for cosmetic raw materials, standards for combination ingredients by cosmetic type, Japan Cosmetic Industry Federation ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), standards for quasi-drug raw materials, Japanese Pharmacopoeia, and pharmaceutical additives. Ingredients listed in standards, food additive regulations, etc., and international patent classification IPC in Japanese and foreign patent publications and patent publications (including publications and re-publications) that belong to the A61K7 and A61K8 classifications. It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the listed ingredients, in known combinations, blending ratios, and amounts.

Examples of the cosmetics of the present invention include hair cosmetics, skin cosmetics, makeup cosmetics, aromatic cosmetics, body cosmetics, and skin external preparations such as ointments. From the viewpoint of exhibiting the effects of the present invention, it can be particularly preferably used in hair cosmetics, skin cosmetics, and makeup cosmetics. The cosmetic of the present invention can be manufactured according to a conventional method.

To explain the types of cosmetics of the present invention in more detail, hair cosmetics include shampoos such as oil shampoos, cream shampoos, conditioning shampoos, dandruff shampoos, hair coloring shampoos, conditioner-integrated shampoos; conditioners, treatments;
Conditioners such as hair packs and hair mist; Hair products such as hair foam, hair mousse, hair spray, hair wax, hair gel, hair cream, water grease, setting lotion, pomade, and ticks; Color lotion, hair tonic, hair liquid, hair blow-dry, hair twigs, etc. Hair coat, hair oil, permanent wave agent, straight perm agent, oxidative hair dye, hair bleach, hair color pre-treatment, hair color after-treatment, perm pre-treatment, perm after-treatment, hair manicure,
Preferable examples include hair growth agents.

Skin cosmetics include lotions such as softening lotion, astringent lotion, cleaning lotion, and multilayer lotion; emollient lotion, moisture lotion, milky lotion, nourishing lotion, nourishing milk, skin moisture, and moisturizer. - Emulsion, massage lotion, cleansing lotion, protect emulsion, sun protector, UV care milk, sunscreen, makeup lotion, exfoliating smoother, elbow lotion, hand lotion, body lotion, etc.; emollient cream, nutritional cream, Nourishing cream, vanishing cream, moisture cream, night cream, massage cream, cleansing cream, makeup cream, base cream, pre-makeup cream, sunscreen cream, suntan cream, hair removal cream, deodorant cream, shaving cream, keratin softening cream Creams such as creams; Gels such as moisture gels; Essences such as moisturizing essences, whitening essences, and UV protection essences; Liposomal cosmetics such as liposome serums and liposome lotions; Peel-off packs, powder packs, washing packs, oil packs, cleansing Packs and masks such as masks; Facial cleansers such as cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, cleansing oil, cleansing mask, cleansing powder, and facial cleansing powder; Toilet soap, transparent soap, medicated soap, liquid soap, Preferred examples include soaps such as shaving soap and synthetic cosmetic soap.

Preferred examples of makeup cosmetics include white powders, powders, foundations, lipsticks, lip glosses, blushers, eyeliners, mascaras, eyeshadows, eyebrow ink, eyebrows, nail enamel, enamel remover, and nail treatments. .

Preferred examples of aromatic cosmetics include perfume, perfume, parfum, eau de parfum, eau de toilette, eau de cologne, perfume paste, aromatic powder, perfumed soap, body lotion, and bath oil.

Body cosmetics include body cleansing products such as body shampoo, deodorizing cosmetics such as deodorant lotion, deodorant powder, deodorant spray, and deodorant stick, bleaching agents, hair removal agents, bath additives, insect repellent sprays, etc. Repellers are preferred.

Further, as a skin external preparation, it can be used in the form of an ointment, a patch, a lotion, a liniment, a liquid coating, and the like. It can also be used as oral cosmetics such as toothpaste and mouthwash.

The dosage forms of the cosmetics of the present invention include emulsion type cosmetics such as oil-in-water (O/W) type, water-in-oil (W/O) type, W/O/W type, and O/W/O type; Oil-based cosmetics, solid cosmetics, liquid cosmetics, paste cosmetics, stick cosmetics, volatile oil-based cosmetics, powder cosmetics, jelly cosmetics, gel cosmetics, paste cosmetics, emulsions Preferable dosage forms include polymeric cosmetics, sheet cosmetics, mist cosmetics, and spray cosmetics.

EXAMPLES Hereinafter, the present invention will be explained in more detail using Examples, but the present invention is not limited to these Examples.

Synthesis Example 1 Synthesis of hard lanolin fatty acid ethylene glycol monoester 250 g (0.47 mol) of hard lanolin fatty acid (lanolin fatty acid SH, manufactured by Nippon Fine Chemical Co., Ltd.) was placed in a 500 mL reactor equipped with a stirrer, a thermometer, and a gas inlet tube. Then, 29 g (0.47 mol) of ethylene glycol and 0.5 g of 50% phosphoric acid aqueous solution were charged, heated to 140°C in a nitrogen stream, and then heated to 190 to 210°C over 5 hours to remove the water produced. The esterification reaction was carried out for 5 hours. Thereafter, it was diluted with MEK, deoxidized, washed with water, desolventized, and deodorized with steam to obtain the desired esterified product of hard lanolin fatty acid as a waxy product.

Synthesis Example 2 Synthesis of hard lanolin fatty acid ethylene glycol diester The esterification reaction was carried out in the same manner as in Synthesis Example 1, except that the amount of ethylene glycol was changed from 29 g to 14 g, and the desired esterified hard lanolin fatty acid was converted into a waxy product. obtained as.

Synthesis Example 3 Synthesis of hard lanolin fatty acid ethylene glycol/polyethylene glycol ester The esterification reaction was carried out in the same manner as in Synthesis Example 1, except that 29 g of ethylene glycol was changed to 29 g of ethylene glycol and 1 g of polyethylene glycol (average molecular weight 200). An esterified product of hard lanolin fatty acid was obtained as a waxy product.

Synthesis Example 4 Synthesis of hard lanolin fatty acid pentaerythritol ester An esterification reaction was carried out in the same manner as in Synthesis Example 1, except that 29 g of ethylene glycol was changed to 31 g of pentaerythritol, and the desired esterified hard lanolin fatty acid was converted into a waxy product. Obtained.

Synthesis Example 5 Synthesis of hard lanolin fatty acid behenyl alcohol ester An esterification reaction was carried out in the same manner as in Synthesis Example 1, except that 29 g of ethylene glycol was changed to 153 g of behenyl alcohol, and the desired esterified product of hard lanolin fatty acid was obtained as a waxy substance. .

Comparative Synthesis Example 1 Synthesis of lanolin fatty acid ethylene glycol monoester The esterification reaction was carried out in the same manner as in Synthesis Example 1, except that the hard lanolin fatty acid was changed to lanolin fatty acid (Lanolin Fatty Acid W, manufactured by Nippon Fine Chemical Co., Ltd.), and the desired lanolin An esterified fatty acid was obtained as a slightly flexible solid.

Hair cosmetics evaluation 1
Hair waxes (Examples 1 to 5) were prepared using the hard lanolin fatty acid esters of Synthesis Examples 1 to 5 of the present invention with the compositions shown in Table 1. For comparison, hair wax containing the esterified product of Comparative Synthesis Example 1 (Comparative Example 1), hair wax containing carnauba wax (Comparative Example 2), and hair wax containing candelilla wax (Comparative Example 3) were prepared. The resulting hair wax was evaluated for feel on use and hair setting power using the following methods. The results are also listed in Table 1.

<Usability evaluation method>
0.06 g of each hair wax was applied to a bundle of healthy black human hair (length 25 cm, 1 g), and the feeling of use upon application was sensory evaluated using the following criteria.

◎: Very good, ○: Good, △: Somewhat not good, ×: Not good

<Hair setting power evaluation method>
The hair strands coated with the hair wax obtained in the above usability evaluation were combed 20 times and then shaped into a rod shape. One end of this hair bundle was fixed on the ground so that it stood vertically, and after being left for 3 hours at a temperature of 20℃ and humidity of 45%, the state of the hair bundle's shape maintenance was visually observed, and the hair was set according to the following criteria. evaluated the power.

◎: Very good, ○: Good, △: Somewhat not good, ×: Not good

From the results in Table 1, the hair wax containing the esterified hard lanolin fatty acid of the present invention has a setting power equivalent to that of carnauba wax and candelilla wax, which are wax components commonly used in cosmetics, and is superior to these waxes. It was found that the usability was excellent.

Evaluation of skin cosmetics Creams (Examples 6 to 10) were prepared using the hard lanolin fatty acid esters of Synthesis Examples 1 to 5 of the present invention with the compositions shown in Table 2. For comparison, a cream containing the esterified product of Comparative Synthesis Example 1 (Comparative Example 4), a cream containing carnauba wax (Comparative Example 5), and a cream containing Candelilla wax (Comparative Example 6) were prepared. The resulting cream was evaluated for feel (richness, texture, and moist feeling after drying) using the following method. The results are also listed in Table 2.

<Evaluation method>
A certain amount of each cream was applied to the inner side of the upper arm, and the body, texture, and moist feeling after drying were sensually evaluated using the following criteria.

◎: Very good, ○: Good, △: Somewhat not good, ×: Not good

From the results in Table 2, it was found that the cream containing the hard lanolin fatty acid ester of the present invention has the effect of imparting richness as a wax component for cosmetics, similar to carnauba wax and candelilla wax. On the other hand, compared to carnauba wax and candelilla wax, it was found that it blends better into the skin and provides an excellent moisturizing feeling (emollient properties) after drying.

Evaluation of makeup cosmetics Lipsticks (Examples 11 to 15) were prepared using the hard lanolin fatty acid esters of Synthesis Examples 1 to 5 of the present invention with the compositions shown in Table 3. For comparison, a lipstick containing the esterified product of Comparative Synthesis Example 1 (Comparative Example 7), a lipstick containing carnauba wax (Comparative Example 8), and a lipstick containing Candelilla wax (Comparative Example 9) were prepared. The resulting lipstick was evaluated for feel (glossy, moist feel) using the following method. The results are also listed in Table 3.

<Usability evaluation method>
A fixed amount of each lipstick was applied to the lips, and the feeling (glossy, moist feeling) after application was sensually evaluated using the following criteria.

◎: Very good, ○: Good, △: Somewhat not good, ×: Not good

From the results in Table 3, it was found that the lipstick of the present invention containing an esterified product of hard lanolin fatty acid had superior moisturizing feel (emollient properties) compared to carnauba wax and candelilla wax. Note that the lipstick containing the esterified product of hard lanolin fatty acids of the present invention and the lipstick containing carnauba wax or candelilla wax had sufficient hardness to form a stick shape, but Comparative Synthesis Example 1 The esterified product was insufficient.

Evaluation of hair cosmetics 2
Using the hard lanolin fatty acid esters of Synthesis Examples 1 to 5 of the present invention, hair conditioners (Examples 16 to 20) were prepared with the compositions shown in Table 4. For comparison, a hair conditioner containing the esterified product of Comparative Synthesis Example 1 (Comparative Example 10), a hair conditioner containing carnauba wax (Comparative Example 11), and a hair conditioner containing Candelilla wax (Comparative Example 12) were prepared. The feeling of use of the obtained hair conditioner was evaluated using the following method. The results are also listed in Table 4.

<Usability evaluation method>
Healthy black human hair was bleached once with a two-part bleaching agent to prepare 5 g of damaged hair bundles. 0.5 g of each hair conditioner was applied to the prepared hair bundles, left for 2 minutes, rinsed under running water for 30 seconds, and dried with a hair dryer. The resulting hair bundles were evaluated for feel (reduction in damage feeling, smoothness, and moist feeling) based on the following criteria.

◎: Very good, ○: Good, △: Somewhat not good, ×: Not good

From the results in Table 4, the hair conditioner of the present invention containing an esterified product of hard lanolin fatty acid has the effect of reducing the feeling of damage and imparting smoothness as a wax component for cosmetics, similar to carnauba wax and candelilla wax. That's what I found out. On the other hand, it was found to have superior moisturizing properties (emollient properties) compared to carnauba wax and candelilla wax.

The cosmetics described below were prepared using the esterified product of hard lanolin fatty acids of the present invention. The resulting cosmetics perform the functions of a general wax, such as solidifying the formulation, adjusting hardness and viscosity, forming a film, imparting gloss, and spreading, and in hair styling products, it provides excellent setting properties. In makeup cosmetics, it provided excellent adhesion, and in skin cosmetics, it provided excellent feel and emollient properties.

Example 21 Hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 8.0
Plandool-ISS (Nippon Fine Chemical) 1.0
Triethylhexanoin (Nippon Fine Chemical) 1.0
Plandool-G (Nippon Fine Chemical) 9.0
Tri-hydrogenated rosin glyceryl 1.0
PPG-1 Behenes-15 5.0
Polyurethane-1 2.0
Cholesterol 0.5
Diethyl sebacate 2.0
Seteth-7 1.0
Dimethicone 3.0
Diisopropyl adipate (Nippon Fine Chemical) 5.0
Part B Glycerin 5.0
Phenoxyethanol 0.6
Methylparaben 0.2
Purified water Amount to make a total of 100 Part C (acrylates/steareth methacrylate-20) copolymer 3.0
Purified water 20.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and B were each taken, heated to about 80°C, and mixed uniformly. Part B was gradually added to Part A with stirring, mixed uniformly, and then cooled (Part D). Part C was added to Part D and mixed uniformly.

Example 22 Hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 13.0
Plandool-SUN (Nippon Fine Chemical) 2.0
LUSPLAN DD-DA7 (Nippon Fine Chemical) 2.7
Tri-hydrogenated rosin glyceryl 0.3
Plandool-DP (Nippon Fine Chemical) 5.0
Triethylhexanoin (Nippon Fine Chemical) 3.0
PEG-40 hydrogenated castor oil 1.0
Steerless-30 1.0
Ercalactone MCT (Nippon Fine Chemical) 1.0
(Alkyl acrylate/diacetone acrylamide) copolymer AMP 1.0
Komenukarou 2.0
Hydroxystearic acid 6.0
Glyceryl stearate 1.0
Dimethicone 3.0
Diisopropyl sebacate (Nippon Fine Chemical) 5.0
Seteth-2 0.5
Seteth-20 2.5
BHT 0.05
Phenoxyethanol 0.6
Methylparaben 0.2
Part B BG 3.0
Na hydroxide 0.5
(Acrylates/Alkyl acrylate (C10-30)) Crosspolymer 0.1
Purified water Amount that makes a total of 100----------------------
(Preparation method)
Parts A and B were each taken, heated to about 80°C, and mixed uniformly. Part B was gradually added to Part A with stirring, mixed uniformly, and then cooled.

Example 23 Hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 1 13.0
Plandool-ISS (Nippon Fine Chemical) 1.0
Plandool-G (Nippon Fine Chemical) 2.7
Tri-hydrogenated rosin glyceryl 0.3
Dimethicone 6cs 10.0
Ecolano DP-50 (Nippon Fine Chemical) 0.5
Jojoba seed oil 4.0
Glyceryl stearate 2.0
Seteth-10 2.0
Tocopherol 0.05
paraffin wax 2.0
PEG-20 hydrogenated castor oil 1.3
Beeswax 1.5
Ethylhexyl methoxycinnamate 1.8
PEG-90M 3.0
Part B Phenoxyethanol 0.6
Methylparaben 0.15
PG 3.0
Purified water Amount that makes a total of 100----------------------
(Preparation method)
Parts A and B were each taken, heated to about 80°C, and mixed uniformly. Part B was gradually added to Part A with stirring, mixed uniformly, and then cooled.

Example 24 Hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 6.0
LUSPLAN DD-IS (Nippon Fine Chemical) 2.5
Cetyl palmitate 2.5
Dimethicone 100cs 8.0
olive oil 2.0
Squalane 3.0
Theopromagrange Florum Seed Oil 0.3
Stearic acid 2.0
Glyceryl stearate 0.8
Seteth-7 1.0
Tocopherol 0.05
Microcrystalline wax 2.0
Rice Bran 2.5
PEG-40 hydrogenated castor oil 1.3
Seteth-20 1.5
Beeswax 1.5
Part B Phenoxyethanol 0.4
Methylparaben 0.15
Carbomer 0.1
EDTA-4Na 0.05
TEA 0.2
PG 3.0
Purified water Amount that makes a total of 100----------------------
(Preparation method)
Parts A and B were each taken, heated to about 80°C, and mixed uniformly. Part B was gradually added to Part A with stirring, mixed uniformly, and then cooled.

Example 25 Hair cream wax Component Amount (weight%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 6.0
Fatty acid (C18-35) glycol 6.0
Dioleate PEG-120 Methylglucose 5.0
Lanolin fatty acid octyldodecyl 5.0
Stearic acid 4.0
LUSPLAN DD-DHR (Nippon Fine Chemical) 2.7
carnauba wax 3.0
Diethyl sebacate 2.0
Ercalactone DES 2.0
Dimethicone (100,000 cs) 1.0
Cyclopentasiloxane 1.0
Seteth-2 2.0
Seteth-7 2.0
Seteth-20 1.0
Dicocodimonium chloride (75%) 1.0
Propylparaben 0.1
Part B Triethanolamine 0.3
Methylparaben 0.2
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was heated to about 80°C to dissolve it. Part B was placed in a separate container and heated to about 80°C to uniformly dissolve it (Part B). Part B was gradually added to Part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 26 Hair styling wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 4.0
Plandool-G (Nippon Fine Chemical) 2.7
Octyldodecyl myristate 6.0
Rapeseed oil 5.0
Squalane 5.0
Stearic acid 2.0
Beeswax 3.0
LUSPLAN SR-DM4 (Nippon Fine Chemical) 2.0
PEG-60 hydrogenated castor oil 1.0
Glyceryl stearate (SE) 1.0
Lauroyl lysine 0.5
Seteth-7 2.0
Glyceryl caprate 1.0
Part B Triethanolamine 0.3
Propanediol 5.0
Pentylene glycol 3.0
Hexylene glycol 0.8
Neosolue-AquaS (Nippon Fine Chemical) 0.4
Purified water Amount for a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was heated to about 80°C and dissolved. Part B was placed in a separate container and heated to about 80°C to uniformly dissolve it (Part B). Part B was gradually added to Part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 27 Matte hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 9.0
hard lanolin 6.0
Hydrogenated polyisobutene 6.0
Cetyl ethylhexanoate (Nippon Fine Chemical) 5.0
Microcrystalline wax 5.0
Hydroxystearic acid 3.0
Setanol 2.0
Tocopherol 0.05
Silica 1.0
Polymethyl acrylate 0.5
Ethylhexyltriazone 2.0
Steares-20 1.0
Propylparaben 0.1
Part B: Na hydroxide 0.8
Methylparaben 0.20
Purified water Amount for a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was heated to about 80°C to dissolve it. Part B was placed in a separate container and heated to about 80°C to uniformly dissolve it. Part B was gradually added to Part A and mixed uniformly. After cooling to room temperature, the pH was adjusted.

Example 28 Stick balm Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Esterified product of Synthesis Example 2 4.0
Diisostearyl malate Amount that adds up to 100 Isotridecyl isononanoate 3.0
Pentaerythrityl tetraisostearate 3.0
Plandool-S (Nippon Fine Chemical) 0.2
Trioctanoin (Nippon Fine Chemical) 6.0
Ascorbyl tetraethylhexanoate 2.0
polyethylene 5.0
Polyglyceryl-2 triisostearate 0.5
Dimethicone 2.0
Stearyl glycyrrhetinate 0.05
Phenoxyethanol 0.6
Titanium oxide 0.5
Microcrystalline wax 0.8
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All ingredients were heated to about 80° C., mixed uniformly, and then cooled to room temperature.

Example 29 Hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 4 10.0
Beeswax 3.0
Cellulose acetate 2.0
Ethylhexyl palmitate 5.0
Cetyl ethylhexanoate 2.0
Vaseline 1.5
mineral oil 2.0
Stearic acid 1.0
Stearyl alcohol 1.0
Seteth-20 2.0
Sorbitan stearate 2.0
Polysorbate 60 1.0
PEG-250 distearate 1.0
Talc 1.0
Part B Carboxyvinyl polymer 0.1
Vinylpyrrolidone-N,N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Purified water 10.0
Part C Polyethylene glycol 1.0
diglycerin 1.0
glycerin 2.0
Caprylyl glycol 0.5
Triethanolamine 0.2
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was mixed uniformly at 80° C. with stirring. Part B was taken into a separate container and made into a viscous liquid. Part C was taken into a separate container and uniformly dissolved. Part C was added to part A at 80°C with stirring and emulsified. After emulsification, the mixture was cooled to about 50°C, and then part B was mixed to make it homogeneous.

Example 30 Hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 5 8.0
Sunflower seed wax 3.0
Cellulose acetate 2.0
Ethylhexyl palmitate 5.0
Isononyl isononanoate 2.0
Isopropyl myristate 2.0
Vaseline 1.5
Squalane 2.0
Hydroxystearic acid 1.0
Myristyl alcohol 1.0
Seteth-20 2.0
Sorbitan stearate 2.0
PEG-60 hydrogenated castor oil 1.0
PEG-250 distearate 1.0
Ethylhexylglycerin 0.5
Part B Carboxyvinyl polymer 0.1
Vinylpyrrolidone-N,N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate 0.1
Tremoist-TP (Nippon Fine Chemical) 0.1
Purified water 10.0
Part C Polyethylene glycol 1.0
BG 5.0
glycerin 2.0
Caprylyl glycol 0.5
Triethanolamine 0.2
Purified water Amount that makes a total of 100----------------------
(Preparation method)
Part A was mixed uniformly at 80° C. with stirring. Part B was taken into a separate container and made into a viscous liquid. Part C was taken into a separate container and uniformly dissolved. Part C was added to part A at 80°C with stirring and emulsified. After emulsification, the mixture was cooled to about 50°C, and then part B was mixed to make it homogeneous.

Example 31 Hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 3 10.0
Beeswax 3.0
Microcrystalline wax 2.0
Cetyl ethylhexanoate 5.0
Cyclopentasiloxane 8.0
Dimethicone 1.5
mineral oil 2.0
Stearic acid 1.0
Stearyl alcohol 1.0
Seteth-20 2.0
Glyceryl stearate 2.0
Polysorbate-60 1.0
Dilauroylglutamate lysine Na 0.3
Crystalline cellulose 1.0
Part B Carboxyvinyl polymer 0.1
Acrylic acid/alkyl acrylate (C10-30) copolymer 0.1
Purified water 10.0
Part C Polyethylene glycol 1.0
Ethanol 5.0
glycerin 2.0
Dextrin 0.2
Caprylyl glycol 0.5
Hydrolyzed soy protein 0.2
Triethanolamine 0.2
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was mixed uniformly at 80° C. with stirring. Part B was taken into a separate container and made into a viscous liquid. Part C was taken into a separate container and uniformly dissolved. Part C was added to part A at 80°C with stirring and emulsified. After emulsification, the mixture was cooled to about 50°C, and then part B was mixed to make it homogeneous.

Example 32 Hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 8.0
Ecolano MAC (Nippon Fine Chemical) 1.0
polyethylene 3.0
paraffin 3.0
Microcrystalline wax 2.0
Beeswax 2.0
Komenukarou 2.0
indodecane 5.0
mineral oil 5.0
Ethylhexyl palmitate 3.0
Dodecane 2.0
Dimethicone 1.0
Stearic acid 2.0
Seteth-10 2.0
Seteth-15 3.0
Seteth-6 2.0
Glyceryl stearate (SE) 2.0
Part B Inulin (Nippon Fine Chemical) 0.5
Hydroxyethylcellulose 0.1
(Acrylates/Alkyl acrylate (C1-18)/Alkyl (C1-8)
Acrylamide) copolymer AMP 0.1
Purified water 10.0
C part BG 3.0
Ethanol 5.0
EDTA-2Na 0.02
Phenoxyethanol 0.25
Methylparaben 0.05
Na hydroxide 0.25
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was mixed uniformly at 80° C. with stirring. Part B was taken into a separate container and made into a viscous liquid. Part C was taken into a separate container and uniformly dissolved. Part C was added to part A at 80°C with stirring and emulsified. After emulsification, the mixture was cooled to about 50°C, and then part B was mixed to make it homogeneous.

Example 33 Gel-like hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 4.0
Fischer-Tropsch wax 1.0
Cetearyl alcohol 1.0
Ecolano DP-50 (Nippon Fine Chemical) 0.5
PPG-1 Behenes-15 6.0
Sodium lauroamphoacetate 3.0
Laureth-7 citric acid 2.0
Polyoxyethylene (60) phytosterol 1.0
Part B Polyurethane-14 acrylates copolymer AMP 0.1
Acrylates/steareth methacrylate-20 crosspolymer 0.1
(vinylpyrrolidone/VA) copolymer 0.1
Vinyl acetate/vinylpyrrolidone copolymer 0.05
(Sodium acrylate/Na acryloyldimethyltaurine) copolymer 0.05
Hydroxyethylcellulose 0.05
Xanthan gum 0.05
Purified water 10.0
C part BG 8.0
Ethanol 5.0
Neosolue-Aqulio (Nippon Fine Chemical) 1.0
Phytopresome MEL (Nippon Fine Chemical) 1.0
Isostearoyl hydrolyzed silk 0.1
Na hydroxide 0.3
Phenoxyethanol 0.2
Methylparaben 0.05
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was mixed uniformly at 80° C. with stirring. Part B was taken into a separate container and made into a viscous liquid. Part C was taken into a separate container and uniformly dissolved. Part C was added to part A at 80°C with stirring and emulsified. After emulsification, the mixture was cooled to about 50°C, and then part B was mixed to make it homogeneous.

Example 34 Gel hair wax Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 4.0
Cetearyl alcohol 1.0
Diethylhexyl succinate (Nippon Fine Chemical) 2.0
Neosolue-DiSM (Nippon Fine Chemical) 2.0
Glyceryl stearate 2.0
Polyoxyethylene (60) phytosterol 1.0
Polysorbate-60 6.0
Part B Polyurethane-14 acrylates copolymer AMP 0.1
Acrylates/steareth methacrylate-20 crosspolymer 0.1
(vinylpyrrolidone/VA) copolymer 0.1
Vinyl acetate/vinylpyrrolidone copolymer 0.05
(Sodium acrylate/Na acryloyldimethyltaurine) copolymer 0.05
(Alkyl acrylate/diacetone acrylamide) copolymer AMP 0.1
Hydroxyethylcellulose 0.05
Xanthan gum 0.05
Purified water 10.0
C part BG 8.0
Ethanol 5.0
Neosolue-Aqulio (Nippon Fine Chemical) 2.0
Isostearoyl hydrolyzed silk 0.1
Na hydroxide 0.3
Phenoxyethanol 0.2
Methylparaben 0.05
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was mixed uniformly at 80° C. with stirring. Part B was taken into a separate container and made into a viscous liquid. Part C was taken into a separate container and uniformly dissolved. Part C was added to part A at 80°C with stirring and emulsified. After emulsification, the mixture was cooled to about 50°C, and then part B was mixed to make it homogeneous.

Example 35 Styling milk Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 1.0
LUSPLAN SR-DM4 (Nippon Fine Chemical) 1.0
Stearyl alcohol 1.7
Cetyl ethylhexanoate (Nippon Fine Chemical) 1.2
Stearamidopropyldimethylamine 1.0
Plandool-H (Nippon Fine Chemical) 0.2
Plandool-DP (Nippon Fine Chemical) 0.2
hard lanolin 1.0
Glyceryl stearate 0.3
Ecolano DC-30 (Nippon Fine Chemical) 0.5
PEG-25 hydrogenated castor oil 1.0
Seteth-20 0.3
Part B Inulin (Nippon Fine Chemical) 0.5
Lactic acid 0.4
Purified water Amount that makes the total 100 Part C Hydroxyethylcellulose 0.4
BG 2.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Parts A and B were mixed at about 80°C. Part B was added to part A and emulsified, and after cooling to about 60°C, part C was added.

Example 36 Shampoo Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 0.2
Isopropyl palmitate (Nippon Fine Chemical) 0.2
Diethylhexyl sebacate (Nippon Fine Chemical) 1.0
Oleic acid 0.2
Part B Ammonium laureth sulfate 5.0
Sodium laureth sulfate (25%) 10.0
Cocoyl glutamic acid TEA (30%) 3.0
Lauryl hydroxysultaine (30%) 7.0
Lauric acid K 1.0
Glycol distearate 0.5
Stearoxypropyldimethylamine 0.5
PPG-17 0.3
Neopentyl glycol diethylhexanoate 0.4
Lanolin fatty acid 0.3
Isodecyl glyceryl ether 0.4
Cocamide MEA 1.0
Laures-4 0.3
Laures-16 0.2
Steerless-6 0.2
Miconazole nitrate 0.75
Phenoxyethanol 0.3
Part C Sorbitol 1.6
Methylparaben 0.2
EDTA-2Na 0.05
Phosphoric acid 0.03
Sodium benzoate 0.3
Purified water Amount for a total of 100 Part D Polyquaternium-10 0.2
Guar hydroxypropyltrimonium chloride 0.1
Tremoist-TP (Nippon Fine Chemical) 0.02
Purified water 6.7
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A and Part B, which had been mixed in advance, were uniformly mixed at about 80°C (Part E). Part C, which had been set aside, was heated to about 60° C. to make it uniform. Part C was gradually added to Part E with stirring, mixed uniformly, and then cooled to about 50°C. Furthermore, part D was added and mixed uniformly.

Example 37 Shampoo Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 2.0
Lanolin fatty acid 0.1
Isostearic acid 0.1
Laureth 2Na sulfosuccinate (26%) 10.0
Sodium lauroamphoacetate (30%) 7.0
Lauryl sulfate TEA (40%) 6.0
Laures-2 1.0
Dioleate PEG-120 Methylglucose 1.0
Sorbeth Tetraoleate-60 3.5
Caprylyl glucoside 0.3
Glycol distearate 0.5
PEG-2 cocamine 1.2
PEG-60 hydrogenated castor oil 0.5
Neopentyl glycol diheptanoate 0.3
Glyceryl oleate 0.8
Phenoxyethanol 0.3
Part B EDTA-2Na 0.05
Methylparaben 0.15
Purified water Amount to make a total of 100 Part C Polyquaternium-10 0.1
Guar hydroxypropyltrimonium chloride 0.3
Na chloride 0.3
Ascorbic acid 0.3
Hyaluronate Na 0.3
Purified water 19.3
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80°C to uniformly dissolve it. Part A was placed in a separate container, heated, and dissolved. Part B was gradually added to Part A, mixed uniformly, and Part C was added at about 60°C.

Example 38 Shampoo Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 4 2.0
Isostearic acid 0.1
Sodium cocoyl methyltaurate (30%) 8.0
Cocamidopropyl betaine (30%) 5.0
Sodium laureth sulfate (25%) 6.0
Laures-2 1.0
Sorbeth Tetraoleate-60 3.5
Caprylyl glucoside 0.3
Cocamide DEA 3.0
PEG-20 hydrogenated castor oil 0.5
Neopentyl glycol diheptanoate 0.3
Ethyl oleate 0.3
Part B EDTA-2Na 0.05
Methylparaben 0.15
Propanediol 0.5
Purified water Amount to make a total of 100 Part C Polyquaternium-10 0.1
Guar hydroxypropyltrimonium chloride 0.3
Na chloride 0.3
Ascorbic acid 0.3
Suizenjinori polysaccharide 0.1
Purified water 19.3
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80°C to uniformly dissolve it. Part A was placed in a separate container, heated, and dissolved. Part B was gradually added to Part A, mixed uniformly, and Part C was added at about 60°C.

Example 39 Non-silicone shampoo Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Esterified product of Synthesis Example 2 0.2
Plandool-LG2 (Nippon Fine Chemical) 0.03
Neosolue-AquaS (Nippon Fine Chemical) 0.1
Inulin (Nippon Fine Chemical) 0.5
Sodium laureth-4 carboxylate (28%) 10.0
Laureth-6 carboxylic acid 4.0
Cocamidopropyl betaine (30%) 10.0
Lauroyl methylalanine Na (30%) 5.0
Isostearic acid 0.3
Cocamide methyl MEA 3.0
Na hydroxide 1% solution 0.5
Polyquaternium-10 0.8
Glycol distearate 0.5
Polyquaternium-7 0.5
Sodium benzoate 0.3
EDTA-2Na 0.05
Phenoxyethanol 0.4
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All components were heated to about 80° C. and mixed uniformly with stirring.

Example 40 Hair Treatment Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 4 0.5
Neosolue-Aqulio (Nippon Fine Chemical) 0.2
Dimethicone 0.3
Cetyl ethylhexanoate 1.0
Ercalactone MCT (Nippon Fine Chemical) 2.0
Cetearyl alcohol 3.5
Palmitic acid dextrin 0.2
PEG-200 0.5
Ecolano DP-50 (Nippon Fine Chemical) 0.5
Behenic acid dimethylaminopropylamide 0.2
Cetrimonium chloride (30%) 1.0
Behentrimonium chloride (80%) 1.0
Trideceth-6 0.3
BHT 0.03
Part B NanoRepair-CMC5 (Nippon Fine Chemical) 5.0
Hydroxyethylcellulose 0.4
Tremoist-TP (Nippon Fine Chemical) 0.02
(Acryloyldimethyltaurine ammonium/VP) copolymer 0.02
BG 1.8
Glycerin 4.0
Methylparaben 0.2
Citric acid 0.05
Purified water Amount that makes total 100 Part C Isododecane 0.2
PPG-3 caprylyl ether 0.5
Panthenol 0.1
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80°C and dissolved. Part A was added to a separate container, heated, and dissolved. Part B was gradually added to Part A and mixed uniformly. At about 50° C., Part C was added with stirring until homogeneous.

Example 41 Hair treatment that does not wash away
Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 1 0.2
Polyquaternium-37 2.0
Squalane 2.0
PPG-3 caprylyl ether 2.0
Ecolano CA-NH (Nippon Fine Chemical) 0.5
Microcrystalline wax 0.1
Lanolin alcohol 0.2
paraffin wax 0.1
Polyethylene wax 0.1
Beeswax 0.1
Mokuro 0.2
Ceresin 0.1
Dicapric acid PG 1.0
Cholesterol 0.2
Cetyl ethylhexanoate 1.0
Candelilla wax extract 0.1
Octyldodecyl erucate 4.5
Tocopherol acetate 0.02
Ercalactone MCT (Nippon Fine Chemical) 2.0
Dipentaerythrityl tripolyhydroxystearate 1.5
PPG-5 phytosteryl 0.5
Glycerin 4.0
Sorbitol 2.0
Phenoxyethanol 0.5
Part B Hydrolyzed conchiolin 0.1
Hydrolyzed keratin 0.1
Panthenol 0.1
Hydroxypropyltrimonium hyaluronate 0.01
Polyquaternium-11 0.2
Glycosyltrehalose 0.1
Glyceryl glucoside 0.3
Arginine 0.1
Part C Purified water Amount to make a total of 100 Hydroxypropyl starch phosphate 1.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part C was uniformly dispersed and heated to about 80°C. Next, part A was heated to about 80°C to dissolve it. Part A was added to part C while stirring, and after uniformly mixing, the mixture was cooled to about 40°C. Part B was then added and mixed uniformly.

Example 42 Hair Treatment Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 5 0.2
Plandool-LG2 (Nippon Fine Chemical) 0.5
Propanediol 3.0
Behenamidopropyldimethylamine 1.5
Setanol 2.2
Stearyl alcohol 0.8
Hydrogenated rapeseed oil alcohol 0.5
Neopentyl glycol diethylhexanoate 0.8
Jojoba seed oil 1.0
Glyceryl stearate 0.4
Propylparaben 0.1
Cocamide MEA 0.8
Behentrimonium chloride 0.5
Rice bran wax 0.5
glycerin 1.0
Part B NanoRepair-CMC5 1.0
Miconazole nitrate 0.2
Lactic acid 0.4
Purified water Amount that makes a total of 100 Part C Amodimethicone 3.0
Diethylhexyl sebacate (Nippon Fine Chemical) 1.0
Polyquaternium-7 0.15
Myristic acid PPG-3 benzyl ether 0.5
D part Tremoist-TP (Nippon Fine Chemical) 0.01
Purified water 10.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was uniformly mixed at about 80°C. Part B, which had been set aside, was heated to about 60° C. to make it uniform. Part B was gradually added to Part A with stirring, mixed uniformly, and then cooled to about 50°C. Furthermore, Part C and Part D were added and mixed uniformly.

Example 43 Hair Treatment Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 1 0.5
Dodecane 1.5
Neosolue-Aqulio (Nippon Fine Chemical) 0.2
Neosolue-DiSM (Nippon Fine Chemical) 0.2
LUSPLAN SR-DM4 (Nippon Fine Chemical) 0.5
Candelilla wax 0.2
Isopropyl palmitate 1.0
Cetyl ethylhexanoate 1.0
Cetearyl alcohol 3.5
PEG-200 0.5
Hydroxyethylcellulose 0.4
Cetrimonium chloride (30%) 1.0
Behentrimonium chloride (80%) 1.0
Trideceth-6 0.3
BHT 0.03
Part B Methylparaben 0.01
Citric acid 0.05
Purified water Amount that makes a total of 100 Part C Dimethicone (4 million cs) 1.0
Dimethicone (100cs) 3.0
Cyclomethicone 3.0
PPG-3 Myristyl 0.5
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 80°C and dissolved. Part A was added to a separate container, heated, and dissolved. Part B was gradually added to Part A and mixed uniformly. At about 50° C., Part C was added with stirring until homogeneous.

Example 44 Non-silicone hair treatment Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 1 0.2
LUSPLAN SR-DM4 (Nippon Fine Chemical) 0.8
Neosolue-DiSM (Nippon Fine Chemical) 0.3
Neosolue-MP (Nippon Fine Chemical) 0.2
Stearyl alcohol 2.0
Setanol 1.2
Steartrimonium chloride 1.0
Ecolano CA-NH (Nippon Fine Chemical) 0.3
PEG-45M 0.8
Plandool-LG1 (Nippon Fine Chemical) 0.3
Erucalactone DES (Nippon Fine Chemical) 1.0
Camellia seed oil 0.4
Hydroxyethylurea 0.5
Dicaprylyl carbonate 2.0
PPG-1/PEG-1 stearamine 1.0
Squalane 0.1
Isocetes-10 0.5
sunflower wax 0.8
Cocoyl arginine ethyl PCA 0.2
Phenoxyethanol 0.2
Tocopherol 0.05
Part B DPG 2.2
Glycerin 1.3
Sorbitol 3.5
BG 1.0
Hydroxycellulose 0.07
NanoRepair-EL (Nippon Fine Chemical) 1.0
Citric acid appropriate amount EDTA-2Na 0.01
Purified water Amount that makes the total 100 Part C Polyquaternium-61 0.3
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was uniformly mixed at about 80°C. Part B, which had been set aside, was heated to about 60° C. to make it uniform. Part B was gradually added to Part A with stirring, mixed uniformly, and then cooled to about 50°C. Part C was further added and mixed uniformly.

Example 45 Emulsion Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 1 2.0
Plandool-LG3 (Nippon Fine Chemical) 2.0
Plandool-H (Nippon Fine Chemical) 2.0
Plandool-DP (Nippon Fine Chemical) 1.0
Plandool-MAS (Nippon Fine Chemical) 1.0
Isopropyl palmitate (Nippon Fine Chemical) 5.0
Setanol 1.2
Phenyltrimethicone 3.0
Ethylparaben 0.1
Isopropyl myristate (Nippon Fine Chemical) 3.0
mineral oil 2.0
Hydrogenated polyisobutene 1.0
Part B Stearoxyhydroxypropyl methylcellulose 0.1
Xanthan gum 0.1
Purified water 20.0
Part C Phytocompo-PP (Nippon Fine Chemical) 1.0
Pentylene glycol 3.0
Glycerin 8.0
D part VC ethyl (Nippon Fine Chemical) 1.0
Arbutin (Nippon Fine Chemical) 1.0
Purified water 5.0
Part E Phenoxyethanol 0.2
Methylparaben 0.15
Phytic acid 0.5
Citric acid 0.1
Sodium citrate Amount to bring the pH to 4.5 Purified water Amount to bring the total to 100 －－－－－
(Preparation method)
Part A and Part E were each heated to about 70°C to uniformly dissolve them. Part B was stirred to form a viscous liquid. Part C was heated to about 70°C and uniformly dispersed. Part A was added to part C while stirring with a homodisper, and then part E was added while stirring. Part D and Part B were added at about 50°C and stirred to uniformly dissolve.

Example 46 Whitening emulsion Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 0.2
Plandool-H (Nippon Fine Chemical) 1.0
Diethylhexyl sebacate (Nippon Fine Chemical) 5.0
Diethylhexyl succinate (Nippon Fine Chemical) 5.0
Setanol 1.2
Phenyltrimethicone 3.0
Ethylparaben 0.1
Myristyl alcohol 2.0
Oleyl alcohol 1.0
Part B Stearoxyhydroxypropyl methylcellulose 0.1
Xanthan gum 0.1
Purified water 20.0
Part C Phytocompo-PP (Nippon Fine Chemical) 1.0
Pentylene glycol 2.0
1,2-hexanediol 1.0
BG 5.0
Glycerin 8.0
Part D Arbutin (Nippon Fine Chemical) 1.0
Tranexamic acid (Nippon Fine Chemical) 1.0
Purified water 5.0
Part E Sodium sulfite 0.05
Phytic acid 0.5
Citric acid 0.1
Sodium citrate Amount to bring the pH to 4.5 Purified water Amount to bring the total to 100 －－－－－
(Preparation method)
Part A and Part E were each heated to about 70°C to uniformly dissolve them. Part B was stirred to form a viscous liquid. Part C was heated to about 70°C and uniformly dispersed. Part A was added to part C while stirring with a homodisper, and then part E was added while stirring. Part D and Part B were added at about 50°C and stirred to uniformly dissolve.

Example 47 Emulsion Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Glycerin 3.0
diglycerin 1.0
BG 7.0
Phytocompo-C (Nippon Fine Chemical) 1.0
Hydrogenated lysophospholipid (Nippon Fine Chemical) 0.1
Part B Esterified product of Synthesis Example 2 1.0
Trioctanoin (Nippon Fine Chemical) 3.0
LUSPLAN SR-DM4 (Nippon Fine Chemical) 0.5
Hydrogenated polyisobutene 3.5
Isododecane 1.5
Cetostearyl alcohol 1.0
Arachyl alcohol 0.1
Jojoba alcohol 3.0
Chimyl alcohol 0.3
Serakyl alcohol 0.1
Hexyldecanol 0.5
Part C (Hydroxyethyl acrylate/Na acryloyldimethyltaurine) copolymer
0.2
Tremoist-TP (Nippon Fine Chemical) 0.03
Carbomer 0.1
Purified water 20.0
D part Neosolue-AquaS (Nippon Fine Chemical) 0.5
Polyquaternium-51 1.0
Ascorbyl glucoside 1.0
Potassium hydroxide 0.2
Phenoxyethanol 0.05
Methylparaben 0.01
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A, Part B, and Part D were mixed and heated to about 70°C to uniformly dissolve and disperse. Part C was mixed and stirred to form a viscous liquid. Part B was added to part A while stirring with a homodisper, and then part D was added and emulsified. After cooling to about 50°C, Part C was added, stirred and cooled to about 40°C.

Example 48 Skin care cream Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 5 0.3
Squalane 5.0
Stearic acid 1.0
Plandool-ISS (Nippon Fine Chemical) 1.0
Macadamia nut oil 3.0
Hydrogenated jojoba oil 2.0
Vaseline 2.0
Olive oil fatty acid cetearyl 1.0
Olive oil fatty acid sorbitan 0.8
Lanolin fatty acid arginine salt 1.5
Polyglyceryl oleate-10 1.0
Part B Acrylic acid/alkyl methacrylate copolymer 0.1
Hydroxide K 0.07
(Acryloyldimethyltaurate ammonium/
Methacrylic acid beheneth-25) Crosspolymer 0.2
Tremoist-SL (Nippon Fine Chemical) 1.0
Purified water 10.0
Hydrolyzed polyγ-glutamic acid K 0.1
Sodium polyglutamate 0.1
Oligopeptide-24 0.05
Part C Inulin (Nippon Fine Chemical) 1.0
Glycerin 9.0
Propanediol 10.0
PEG-8 5.0
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A and Part C were mixed and heated to about 70°C to uniformly dissolve and disperse. Part B was mixed and stirred to form a viscous liquid. While stirring part C with a homomixer, part A was added and emulsified. After cooling to about 50°C, Part B was added, stirred and cooled to about 40°C.

Example 49 Skin care cream Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Glycerin 12.0
BG 6.0
Phytocompo-PP (Nippon Fine Chemical) 2.5
Part B Esterified product of Synthesis Example 1 0.2
olive oil 1.5
Shea butter 1.0
Neosolue-DiSM (Nippon Fine Chemical) 5.0
Sucrose stearate 0.8
Cetearyl glucoside 1.2
Behenyl alcohol 1.5
Ceramide 2 0.01
Ceramide 3 0.01
Ceramide 5 0.01
Ceramide 6 0.01
Ascorbyl tetrahexyldecanoate 7.0
Lauroylsarcosine isopropyl 2.0
Hydrogenated cocoglyceryl 3.0
Setanol 2.5
Sorbitan stearate 0.8
Part C Xanthan gum 0.05
Tremoist-SL (Nippon Fine Chemical) 1.0
Tuberose polysaccharide 0.01
Water-soluble collagen 0.05
Hydrolyzed collagen 0.5
Sodium pyrosulfite 0.03
Arbutin (Nippon Fine Chemical) 1.0
Tranexamic acid (Nippon Fine Chemical) 1.0
D part Neosolue-Aqulio (Nippon Fine Chemical) 1.0
Propanediol 3.0
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A, Part B, and Part D were mixed and heated to about 70°C to uniformly dissolve and disperse. Part C was mixed and stirred to form a viscous liquid. Part B was added to part A while stirring with a homodisper, and then part D was added and emulsified. After cooling to about 50°C, Part C was added, stirred and cooled to about 40°C.

Example 50 Skin care cream Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 4 2.0
Plandool-LG2 (Nippon Fine Chemical) 2.0
Plandool-H (Nippon Fine Chemical) 2.0
Squalane 8.0
Stearic acid 1.0
Plandool-ISS (Nippon Fine Chemical) 1.0
Macadamia nut oil 3.0
Hydrogenated jojoba alcohol 2.0
Olive oil fatty acid cetearyl 1.0
Olive oil fatty acid sorbitan 0.8
Polyglyceryl oleate-10 1.0
Polyglyceryl laurate-10 0.5
Part B Acrylic acid/alkyl methacrylate copolymer 0.1
Hydroxide K 0.07
Hydroxyethyl acrylate/acryloyl dimethyltaurine (Na) copolymer 0.05
(Acryloyldimethyltaurine ammonium/methacrylic acid beheneth-25)
Crosspolymer 0.05
Tremoist-TP (Nippon Fine Chemical) 0.02
Purified water 10.0
Hydrolyzed polyγ-glutamic acid K 0.1
Sodium polyglutamate 0.1
Oligopeptide-24 0.05
C part Neosolue-Aqua (Nippon Fine Chemical) 1.0
Tranexamic acid (Nippon Fine Chemical) 1.0
Mannosylester Lipid 0.2
diglycerin 5.0
Propanediol 3.0
PEG-8 2.0
Sodium pyrosulfite 0.03
Methylparaben 0.1
Phenoxyethanol 0.3
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A and Part C were mixed and heated to about 70°C to uniformly dissolve and disperse. Part B was mixed and stirred to form a viscous liquid. While stirring part C with a homomixer, part A was added and emulsified. After cooling to about 50°C, Part B was added, stirred and cooled to about 40°C.

Example 51 Cleansing cream Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 5.0
Plandool-LG2 (Nippon Fine Chemical) 2.0
Plandool-S (Nippon Fine Chemical) 2.0
Neosolue-Aqulio (Nippon Fine Chemical) 2.0
Diisostearyl malate 6.0
Diethylhexyl succinate (Nippon Fine Chemical) 2.0
Neosolue-DiSM (Nippon Fine Chemical) 2.0
Mineral oil 23.0
Diethylhexyl sebacate 10.0
PEG-25 Hydrogenated Castor Oil 3.0
PEG-20 Glyceryl Triisostearate 4.0
PEG-12 isostearate 3.0
Sorbitan sesquioleate 1.5
Polyoxyethylene sorbitan oleate 0.3
Polyglyceryl-6 stearate 0.5
Glyceryl stearate 1.0
Microcrystalline wax 2.0
Tocopherol 0.05
Propylparaben 0.05
Part B Neosolue-Aqulio (Nippon Fine Chemical) 1.0
diglycerin 3.0
DPG 5.0
Methylparaben 0.05
Edetate trisodium 0.02
Phenoxyethanol 0.2
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was weighed out and heated to about 80°C to dissolve it. Weigh part B and heat it to about 80°C. Part B was gradually added to part A while stirring, and after mixing, the mixture was cooled to 40°C.

Example 52 Facial cleansing foam Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 0.5
Plandool-LG2 (Nippon Fine Chemical) 2.0
K stearate 10.0
Palmitic acid K 10.0
Myristic acid K 10.0
Lauric acid K 4.0
Lauroylsarcosine isopropyl 0.8
PEG1500 10.0
Glycerin 15.0
Glyceryl monostearate 1.0
POE (20) Sorbitan Monostearate 2.0
Part B Tremoist-TP (Nippon Fine Chemical) 0.02
Hydroxypropyl methylcellulose 0.05
Tuberose polysaccharide 0.05
Cationized guar gum 0.05
Polyquaternium-7 0.5
Polyquaternium-39 0.5
Methylparaben 0.1
Purified water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was weighed out and heated to about 80°C to dissolve it. Weigh part B and heat it to about 80°C. Part B was gradually added to part A while stirring, and after mixing, the mixture was cooled to 40°C.

Example 53 Hand cream Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 1.0
Neosolue-DiSM (Nippon Fine Chemical) 8.0
Ecolano CLE-S (Nippon Fine Chemical) 5.0
LUSPLAN DD-DA7 (Nippon Fine Chemical) 0.5
Squalane 8.0
Macadamia nut oil 0.5
rosehip oil 1.0
meadowfoam oil 1.0
Vaseline 15.0
Microcrystalline wax 2.0
Glyceryl stearate 2.0
Setanol 2.0
Cetyl phosphate 1.0
Lanolin alcohol 3.0
Propylparaben 0.1
Tocopherol 0.05
Perfluoropolyether 1.0
Part B Glycerin 8.0
Propanediol 5.0
Methylparaben 0.1
Ethylhexylglycerin 0.5
Na hydroxide 0.5
Water Amount that makes a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part B was heated to about 70°C and dissolved. Part A was placed in a separate container and heated to about 80°C to dissolve it. Part A was added to part B while stirring with a homomixer and emulsified. After emulsification, it was cooled to about 40°C.

Example 54 Facial cleansing foam Component Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 4 0.2
K stearate 10.0
Palmitic acid K 10.0
Myristic acid K 10.0
Lauric acid K 4.0
Lanolin fatty acid arginine salt 3.0
Lauroylsarcosine isopropyl 0.8
PEG1500 10.0
Glycerin 15.0
Plandool-SUN (Nippon Fine Chemical) 0.2
Glyceryl monostearate 1.0
POE (20) Sorbitan Monostearate 2.0
Part B Inulin (Nippon Fine Chemical) 1.0
Tremoist-TP (Nippon Fine Chemical) 0.02
Phytopresome MEL (Nippon Fine Chemical) 1.0
Polyquaternium-7 0.5
Polyquaternium-39 0.5
Methylparaben 0.01
Purified water Amount for a total of 100－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was heated to about 80°C and dissolved. Part B was heated to about 80°C. Part B was gradually added to part A while stirring, and after mixing, the mixture was cooled to 40°C.

Example 55 Lipstick Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Esterified product of Synthesis Example 2 4.0
Hydrogenated polyisobutene 6.0
LUSPLAN DD-DA7 (Nippon Fine Chemical) 3.0
Polybutene 8.0
polyethylene 5.0
Ethylcellulose 0.2
Synthetic wax 1.2
Shea butter 3.0
Iron oxide 2.3
mica 1.5
Titanium oxide 2.5
Red 202 1.5
Cetyl ethylhexanoate (Nippon Fine Chemical) 5.0
Sorbitan sesquioleate 1.0
Tocopherol 0.05
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All ingredients were heated to about 80° C., mixed uniformly, and then cooled to room temperature.

Example 56 Lipstick Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Esterified product of Synthesis Example 2 7.5
(diphenylmethylsiloxyphenylmethicone/phenylsilsesquioxane)
Crosspolymer 15.0
Cetyl ethylhexanoate (Nippon Fine Chemical) Amount that adds up to 100 Trimethylolpropane triethylhexanoate (Nippon Fine Chemical) 10.0
Isohexadecane 8.0
Tritridecyl trimellitate 8.0
Beeswax 8.0
Ceresin 3.0
Stearic acid 2.0
Mokuro 2.0
LUSPLAN DD-DA5 (Nippon Fine Chemical) 3.0
Vaseline 2.5
Purified lanolin (Nippon Fine Chemical) 2.0
Plandool-LG2 (Nippon Fine Chemical) 6.0
Diisostearyl malate 5.0
Neosolue-DiSM (Nippon Fine Chemical) 5.0
mineral oil 5.0
Sorbitan sesquiisostearate 0.1
Neosolue-Aqua (Nippon Fine Chemical) 0.1
Neosolue-DE (Nippon Fine Chemical) 0.5
Isopropyl palmitate (Nippon Fine Chemical) 0.1
Octyl methoxycinnamate 0.01
Tocopherol 0.1
Butylcarbamate propynyl iodide 0.01
Titanium oxide (appropriate amount) Zinc oxide (appropriate amount) Safflower red (appropriate amount) Red 226 (appropriate amount) Yellow 5 (appropriate amount) Borosilicate (Ca/Al) (appropriate amount) Silica (appropriate amount) Tin oxide (appropriate amount) －－－－－－－－－－－－－－
(Preparation method)
All components were heated to about 80° C., uniformly mixed and kneaded, and then cooled to room temperature.

Example 57 Lipstick Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Esterified product of Synthesis Example 1 3.0
Plandool-G (Nippon Fine Chemical) 1.0
Plandool-LG1 (Nippon Fine Chemical) 7.0
LUSPLAN PI-DA (Nippon Fine Chemical) 5.0
Pentaerythrityl tetraethylhexanoate (Nippon Fine Chemical) 10.0
Diisostearyl malate Amount that adds up to 100 Tri(capric acid/caprylic acid) glyceryl (Nippon Fine Chemical) 10.0
Squalane 7.0
Isotridecyl isononanoate 8.0
Triethylhexyl trimellitate 3.0
Diisobutyl adipate 3.0
Diethyl sebacate 3.0
Microcrystalline wax 5.0
Polyethylene, microcrystalline wax mixture 8.0
Methylparaben Appropriate amount Dehydroacetic acid Appropriate amount Titanium oxide Appropriate amount Red 218 Appropriate amount Red 214 Appropriate amount Red 202 Appropriate amount Iron oxide Appropriate amount Yellow 4 Appropriate amount Borosilicate (Ca/Al), Titanium oxide, Silica, Tin oxide Appropriate amount －－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
All components were heated to about 80° C., uniformly mixed and kneaded, and then cooled to room temperature.

Example 58 Foundation Ingredients Blending amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Esterified product of Synthesis Example 2 1.0
Isododecane 10.0
Tri(capric acid/caprylic acid) glyceryl (Nippon Fine Chemical) 4.0
Ethylhexyl methoxycinnamate 3.0
Plandool-SUN (Nippon Fine Chemical) 1.0
Plandool-LG2 (Nippon Fine Chemical) 1.0
Plandool-LG4 (Nippon Fine Chemical) 1.0
Vaseline 1.0
Isotridecyl isononanoate 2.0
Ascorbyl tetrahexyldecanoate 0.1
Palmitic acid dextrin 0.3
Sorbitan Isostearate 1.5
Tribehenin 0.5
(butyl acrylate/glycol dimethacrylate) crosspolymer,
Silica, (methyl methacrylate/glycol dimethacrylate) crosspolymer mixture
2.0
Boron nitride 1.0
Polysorbate 20 2.0
PEG-60 hydrogenated castor oil 1.0
Disteardimonium hectorite (20%) 2.5
Polypropylsilsesquioxane cyclopentasiloxane mixture 1.0
Mica 15.0
Talc 4.0
Zinc oxide 5.0
Titanium oxide 10.0
Iron oxide 1.5
Part B DPG 4.0
Maltitol (75% liquid) 1.0
Neosolue-AquaS (Nippon Fine Chemical) 0.4
Na chloride 1.0
BG 1.0
Tremoist-SL (Nippon Fine Chemical) 1.0
Ethanol 0.5
Purified water Amount that makes a total of 100----------------------
(Preparation method)
Part A was heated to about 70°C and stirred well to uniformly disperse the mixture. After heating Part B to about 70°C and making it uniform, Part B was added to Part A, stirred and emulsified at about 70°C, and cooled to about 40°C.

Example 59 Sunscreen cosmetics Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Phytocompo-PP (Nippon Fine Chemical) 1.0
BG 10.0
Glycerin 9.0
Part B Esterified product of Synthesis Example 2 0.5
Ethylhexyl methoxycinnamate 7.0
Diethylaminohydroxybenzoyl hexyl benzoate 7.0
Behenyl alcohol 4.0
Plandool-LG1 (Nippon Fine Chemical) 0.5
Plandool-MAS (Nippon Fine Chemical) 1.0
Part C Inulin (Nippon Fine Chemical) 0.3
Purified water Amount to make a total of 100 Part D Xanthan gum 0.2
Hyaluronate Na 0.01
Purified water 10.0
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A was uniformly dispersed. Part B and Part C were each dissolved by heating to about 70°C. After gradually adding Part B to Part A, Part C was gradually added and emulsified. The mixture was cooled while stirring, and Part D and Part E were added at 45° C. and mixed uniformly.

Example 60 Sunscreen cosmetics Ingredients Amount (wt%)
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
Part A Ultrafine titanium oxide 5.0
Purified water Amount that makes a total of 100 BG 7.0
Edetate disodium 0.05
Triethanolamine 1.0
Part B Esterified product of Synthesis Example 2 0.2
Oxybenzone 3.0
Octyl paramethoxycinnamate 5.0
t-Butylmethoxybenzoylmethane 3.0
Diethylhexyl sebacate (Nippon Fine Chemical) 8.0
Plandool-H (Nippon Fine Chemical) 2.0
Plandool-SUN (Nippon Fine Chemical) 2.0
Plandool-MAS (Nippon Fine Chemical) 0.1
Plandool-LG1 (Nippon Fine Chemical) 0.1
Plandool-LG2 (Nippon Fine Chemical) 0.1
Plandool-LG3 (Nippon Fine Chemical) 0.1
Plandool-LG4 (Nippon Fine Chemical) 0.1
LUSPLAN PI-DA (Nippon Fine Chemical) 3.0
Cetyl ethylhexanoate (Nippon Fine Chemical) 3.0
Diisopropyl sebacate (Nippon Fine Chemical) 5.0
Stearyl alcohol 3.0
Batyl alcohol 1.0
Stearic acid 3.0
Glyceryl monostearate 3.0
Polyethyl acrylate 1.0
Lanolin fatty acid 0.5
Antioxidant, fragrance appropriate amount－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
(Preparation method)
Part A is heated to melt and thoroughly dispersed. A heating solution of Part B was added to this, emulsified and dispersed using a homogenizer, and the mixture was stirred and cooled to room temperature.

In the above formulation, the details of the ingredients listed in the product name are as follows.
〇Ecolano DP-50: Quaternium-33, DPG
〇Ecolano CA-NH (former cation NH): Quaternium-33, BG
〇Ecolano DC-30 (formerly Bellpol DC-50): Dihydrocholes-30
〇Ecolano MAC (formerly YOFCO MAC): Macadamia nut oil fatty acid cholesteryl 〇Ecolano CLE-S (formerly YOFCO CLE-S): Lanolin fatty acid cholesteryl 〇LUSPLAN DD-IS: Dimer dilinoleyl diisostearate〇LUSPLAN PI-D A: Dimer dilinol Di(isostearyl/phytosteryl) acid
〇 LUSPLAN DD-DHR: Dimer dilinoleyl hydrogenated rosin condensate 〇 LUSPLAN DD-DA5: Dimer dilinoleyl dimer dilinoleic acid 〇 LUSPLAN DD-DA7: Dimer dilinoleyl dimer dilinoleic acid 〇 LUSPLAN SR-DM4: Dimer dilinoleyl Mardilinoleic acid dimer dilinoleyl, tri(caprylic acid/capric acid) glyceryl 〇 Neosolue-DiSM: diisostearyl malate 〇 Neosolue-Aqulio: cyclohexanedicarboxylic acid bisethoxydiglycol 〇 Neosolue-Aqua: (eicosandioic acid/tetradecane diacid) polyglyceryl-10, glycerin Neosolue-AquaS: (eicosanedioic acid/tetradecanedioic acid) polyglyceryl-10, glycerin Neosolue-MP: methylpentanediol dineopentanoate Neosolue-DE: diethylpentanediol dineopentanoate Plandool - H: Dimer dilinoleic acid (phytosteryl/isostearyl/cetyl/stearyl/behenyl)
〇Plandool-S: Dimer dilinoleic acid (phytosteryl/isostearyl/cetyl/stearyl/behenyl)
〇Plandool-G: Dimer dilinoleic acid Dimer dilinoleyl bis(behenyl/isostearyl/phytosteryl)
〇Plandool-DP: Bisdiglyceryl polyacyl adipate-2
〇Plandool-ISS: Phytosteryl isostearate 〇Plandool-SUN: Sunflower seed oil fatty acid phytosteryl 〇Plandool-MAS: Macadamia nut oil fatty acid phytosteryl 〇Plandool-LG1: Lauroylglutamate di(phytosteryl/octyldodecyl/behenyl)
〇Plandool-LG2: Lauroylglutamic acid di(phytosteryl/octyldodecyl)
〇Plandool-LG3: Lauroylglutamic acid di(phytosteryl/octyldodecyl/behenyl)
〇Plandool-LG4: Lauroylglutamic acid di(phytosteryl/octyldodecyl/behenyl)
〇Phytocompo-PP: Hydrogenated lecithin, phytosterols 〇Phytocompo-C: Hydrogenated lecithin, phytosterols, ceramide 2, ceramide 3, ceramide 6II
〇Phytopresome MEL: Glycolipid, hydrogenated lecithin, BG, purified water 〇Erucalactone MCT: γ-docosalactone, tri(caprylic acid/capric acid) glyceryl 〇Erucalactone DES: γ-docosalactone, diethyl sebacate 〇Tremoist- TP: White fungus polysaccharide 〇 Tremoist-SL: White fungus polysaccharide aqueous solution (1%)
〇NanoRepair-CMC5: Composition containing ceramide 1, ceramide 2, ceramide 3, ceramide 5, ceramide 6, cholesterol, quaternium-33 〇NanoRepair-EL: Composition containing γ-docosalactone, soybean sterol 〇VC ethyl: 3-O -Ethyl ascorbic acid

Claims (5)

Hard lanolin fatty acids, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, 1,3-propanediol, propylene glycol, dipropylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene A cosmetic containing an esterified product with one or more polyhydric alcohols selected from glycol, neopentyl glycol, trimethylolpropane, pentaerythritol, dipentaerythritol, glycerin, diglycerin, and polyglycerin. Hard lanolin fatty acids and one or more saturated straight chain carbon atoms of 12 to 26 selected from lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol, lignoceryl alcohol, and ceryl alcohol. Cosmetics containing esterified products with alcohol. 3. The cosmetic according to claim 1, wherein the cosmetic is for hair. 3. The cosmetic according to claim 1, wherein the cosmetic is for skin use. 3. The cosmetic according to claim 1, wherein the cosmetic is for make-up.