JP6235214B2 - Hair cosmetics - Google Patents

Description

  The present invention relates to a hair cosmetic, and more specifically, a cationic surfactant, a higher alcohol, a paste oil at 25 ° C., and a polyoxypropylene butyl ether having a polyoxypropylene group polymerization degree of 15 to 60. Hair cosmetics that are easy to wash off during rinsing, have a smooth and supple finish on the hair, and do not substantially contain silicone oil, making them difficult to build up. Regarding fees.

  Hair cosmetics have various items depending on the application such as hair shampoos, hair treatments, hair styling agents, etc., and various functions are required. In particular, it is required to impart moistness, smoothness, smoothness, smoothness, good touch, feeling of unity and gloss to the hair, and this effect is manifested. Therefore, the formulation of various components in hair cosmetics has been studied. For example, water-soluble polymers, surfactants, oils, cosmetic ingredients, and the like. Among these, various oil agents such as silicone oil, hydrocarbon oil, and ester oil are widely used particularly for the purpose of imparting smoothness and suppressing a feeling of roughness. In particular, silicone oil has a technique combined with various components such as being studied for blending into hair cosmetics because it can impart excellent functions such as fingering and smoothness to hair (for example, Patent Documents 1 to 3). 3). On the other hand, there is a hair rinse composition that does not contain silicone oil (see, for example, Patent Documents 4 and 5).

  Moreover, the oil agent mix | blended with hair has used various things, such as liquid form, paste form, and solid form. For example, liquid oil is used for the purpose of providing smoothness and the like, and paste-like oil or solid oil is used for the purpose of styling hair such as hairdressing. In this way, hair cosmetics containing paste oil or solid oil, sodium polyacrylate, liquid oil, anionic or nonionic surfactant as a technology combined with other ingredients using the characteristics of the oil (See, for example, Patent Document 6).

  On the other hand, polyoxypropylene butyl ether having a propylene oxide addition mole number of 15 or more and 60 or less is being studied for blending with a set agent such as a hair styling agent. For example, there is a technique using polyoxypropylene butyl ether and jojoba oil in combination with a propellant (see, for example, Patent Document 7).

JP 2001-181156 A JP 58-116409 A JP 63-190812 A JP 2011-126721 A JP 2010-24169 A JP 2003-252730 A Japanese Examined Patent Publication No. 62-28924

  According to the technology so far, silicone oil has been often blended for the purpose of imparting smoothness to the hair. However, hair cosmetics blended with silicone oil are so-called build-up when used repeatedly. (Accumulation on the surface of the hair) may occur, giving an unpleasant feel such as a feeling of stiffness and a squeak. Furthermore, when a hair dye or a permanent agent is applied, there are cases where the sustainability of effects such as dyeability and wave properties is reduced. On the other hand, oils other than silicone oils in hair cosmetics have problems such as being sticky and heavy depending on the ingredients and amount, and not being excellent in fingering and smoothness. There was a case.

  Accordingly, the present inventors have decided to develop a hair cosmetic composition that is smooth and easy to touch and does not contain silicone oil, which is one of the causes of buildup. Furthermore, another object of the present invention is to provide a hair cosmetic composition that is excellent in ease of rinsing at the time of rinsing and that is excellent in the smoothness and suppleness of the finished hair.

  In view of such circumstances, the present inventors conducted extensive research to solve the above problems, and as a result, when polyoxypropylene butyl ether having a specific polyoxypropylene chain adheres to the hair as a hair cosmetic, it is smooth. I found out that I can get a good feeling of fingering. In order to further enhance this property, as a result of further examination of various ingredients to be blended into hair cosmetics, it has been found that the use of a paste-like oil at 25 ° C. dramatically increases the adhesion to hair. The headline and the hair cosmetic composition of the present invention have been completed. By using this technology, the same effect characteristics as those of conventionally used silicone oil can be obtained, and it has become possible to realize an excellent feel such as goodness and smoothness when rinsing and finishing.

That is, the present invention
The following components (a) to (d);
(A) Cationic surfactant (b) Higher alcohol (c) Pasty oil at 25 ° C. (d) A polyoxypropylene butyl ether having a polyoxypropylene group polymerization degree of 15 to 60 is blended. The present invention provides a hair cosmetic composition.

  In addition, component (c) is petrolatum, shea butter, N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl), myristyl myristate, cholesteryl hydroxystearate, hexa (hydroxystearic acid / stearic acid / The present invention provides a hair cosmetic characterized by being one or more selected from rosin acid) dipentaerythrityl and dimerlinoleic acid dimerlinoleyl.

  Further, the present invention provides a hair cosmetic characterized in that the mass ratio (d) / (c) of the component (c) and the component (d) is 0.1-1.

  Further, the present invention provides a hair cosmetic characterized by containing an amphoteric polymer and / or a cationic polymer as component (e).

  Further, the present invention provides a hair cosmetic characterized by being an oil-in-water emulsion type.

  And the hair cosmetics characterized by not mix | blending silicone oil substantially further are provided.

  The hair cosmetic composition of the present invention does not have a sticky feeling and has a light finish and a good feeling of use, and is excellent in fingering and smoothness at the time of rinsing and finishing, and has a high conditioning effect.

  Hereinafter, the present invention will be described in detail. In the present specification, “to” means a range including numerical values before and after.

The component (a) cationic surfactant used in the present invention is blended for the purpose of an emulsifier and the like, and is not particularly limited as long as it is a cationic surfactant that can be usually used in cosmetics. Specifically, lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, alkyl trimethyl ammonium chloride such as behenyl trimethyl ammonium chloride, dilauryl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride, Examples thereof include dialkyldimethylammonium chloride such as dibehenyldimethylammonium chloride and dicocoyldimethylammonium chloride, and one or more of these can be appropriately selected and used.
Among these, when one or more selected from alkyltrimethylammonium chlorides such as cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, and behenyltrimethylammonium chloride are used, a hair cosmetic composition that is more excellent in emulsion stability can be obtained. This is preferable.

  The blending amount of the component (a) cationic surfactant used in the present invention is not particularly limited, but is 0.01 to 20.0% by mass (hereinafter simply referred to as “%”), more preferably 0. It is in the range of 5 to 10.0%. When the blending amount of the component (a) cationic surfactant is within this range, a hair cosmetic composition excellent in smoothness and flexibility can be obtained.

  The component (b) higher alcohol used in the present invention is not particularly limited as long as it is a higher alcohol that can be usually used in cosmetics, but preferably has 12 to 22 carbon atoms having a linear or branched hydrocarbon group. . Specifically, myristyl alcohol, cetyl alcohol, cetostearyl alcohol, stearyl alcohol, behenyl alcohol, lanolin alcohol, hydrogenated lanolin alcohol, lauryl alcohol, oleyl alcohol, 2-octyldodecanol, hexadecyl alcohol, iso Examples include stearyl alcohol, jojoba alcohol, and the like, and one or more of them can be appropriately selected and used. Among these, it is preferable to use one or more selected from cetyl alcohol, cetostearyl alcohol, and stearyl alcohol because a hair cosmetic composition that is more excellent in smoothness and flexibility can be obtained.

  Although the compounding quantity of the component (b) higher alcohol used for this invention is not specifically limited, 0.1 to 12% is preferable and 0.5 to 8% is more preferable. If it is this range, the hair cosmetics which are excellent in the smoothness and suppleness of a finish can be obtained.

  The component (c) oil in the form of a paste at 25 ° C. used in the present invention is a component that can be expected to be smoother and more unified when used together with the component (d) described later. In addition, the paste form in this invention is defined as a thing whose viscosity of 25 degreeC is 5000-100000 mPa * s. In the present invention, the viscosity was measured using a single cylindrical rotational viscometer bismetron type VS-A1 (manufactured by Shibaura System Co., Ltd.) after the sample was left at 25 ° C. for one day. Such a component (c) will not be specifically limited if it is a paste-form oil which can be normally used for cosmetics. Specifically, petrolatum, shea butter, N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl), myristyl myristate, cholesteryl hydroxystearate, hexa (hydroxystearic acid / stearic acid / rosin acid) Dipentaerythrityl, dimer linoleic acid dimer dilinoleyl, cholesteryl isostearate, lanolin, lanolin derivative, monostearic acid hydrogenated castor oil, tri (capryl / caprin / stearic acid) glyceride, dipentaerythritol 12-hydroxystearic acid ester, partial Examples thereof include hydrogenated coconut oil, partially hydrogenated jojoba oil, tetraisostearic acid pentaerythritol, polybutene, polyisobutylene, and heavy liquid isoparaffin. These are appropriately selected from one or more. Can be used.

  Among these, petrolatum, shea butter, N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl), myristyl myristate, cholesteryl hydroxystearate, hexa (hydroxystearic acid / stearic acid / rosin acid) dipentaerythrityl When one or more selected from dimer linoleic acid dimer linoleyl are used, it is preferable because a hair cosmetic with further excellent smoothness in rinsing and finishing can be obtained.

  The blending amount of component (c) oil that is pasty at 25 ° C. used in the present invention is not particularly limited, but is preferably 0.1 to 15%, and more preferably 0.5 to 10%. If it is this range, the hair cosmetics which are further excellent in the smoothness of the finish and the finish can be obtained.

The polyoxypropylene butyl ether having a degree of polymerization of the component (d) polyoxypropylene group of 15 to 60, used in the present invention, contributes to the goodness and smoothness of rinsing and finishing as per finger. It is a component, and one or more kinds can be appropriately selected and used. Furthermore, when the degree of polymerization of the polyoxypropylene group is in the range of 40 to 60, the remaining smoothness is appropriately imparted to the hair, which is more preferable.
If the degree of polymerization of the polyoxypropylene group is less than 15, sufficient fingering goodness and smoothness cannot be obtained. On the other hand, if it exceeds 60, the hair remains stiff and sticky, and a sufficient feel cannot be obtained. There is a case.

  As the polyoxypropylene butyl ether having a degree of polymerization of the component (d) polyoxypropylene group of 15 or more and 60 or less used in the present invention, Uniluve MB-14, MB-370, MB-700, manufactured by Nippon Oil & Fats Co., Ltd. Commercially available products such as Adekapol M-110, M-250P, M-370, M-700, etc. manufactured by Asahi Denka Kogyo Co., Ltd. can be used.

  The blending amount of the polyoxypropylene butyl ether having a polymerization degree of the component (d) polyoxypropylene group of 15 or more and 60 or less used in the present invention is not particularly limited, but is preferably 0.2 to 8%, 0.4 to 4% is more preferable. If it is this range, the hair cosmetics which are further excellent in the smoothness and smoothness at the time of a rinse and finish can be obtained.

  In the present invention, by blending the above-described component (c) and component (d) at a specific ratio, it is possible to further improve the smoothness of fingering of rinsed hair or finished hair. Such a blending ratio (d) / (c) is not particularly limited, but is more preferably 0.1 to 1.0, and further within a range of 0.3 to 0.7. Can be preferable.

  In addition to the above-mentioned components, a hair cosmetic that is further excellent in fingering and smoothness at the finish is obtained by blending the component (e) amphoteric polymer and / or cationic polymer into the hair cosmetic of the present invention. be able to.

  Specific examples of the component (e) amphoteric polymer include N-methacryloylethyl N, N-dimethylammonium α-N-methylcarboxybetaine / butyl methacrylate copolymer, hydroxypropyl acrylate / butyl methacrylate. Aminoethyl / acrylic acid octylamide copolymer, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer, etc. Can be appropriately selected and used.

  Specific examples of the component (e) cationic polymer include cationized cellulose derivatives, cationic starch, cationized fenugreek gum derivatives, cationized guar gum derivatives, cationized tara gum derivatives, cationized locust bean gum derivatives, diallyl quaternary derivatives. Quaternary ammonium salt / acrylamide copolymer, vinyl imidazolium trichloride / vinyl pyrrolidone copolymer, hydroxyethyl cellulose / dimethyl diallylammonium chloride copolymer, vinyl pyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer, polyvinyl pyrrolidone / alkyl Amino acrylate copolymer, polyvinyl pyrrolidone / alkyl amino acrylate / vinyl caprolactam copolymer, vinyl pyrrolidone / methacrylamide propyl salt Trimethylammonium copolymer, alkylacrylamide / acrylate / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer, adipic acid / dimethylaminohydroxypropylethylenetriamine copolymer, diallyl quaternary ammonium salt / vinyl polypyrrolidone / vinyl imidazole copolymer Examples include coalescence. In the present invention, a cationized cellulose derivative is more preferably used.

  The above-mentioned component (e) amphoteric polymer and / or cationic polymer used in the present invention is a marcoat 550PR, 7SPR, 3330PR, 3331PR manufactured by NALCO, a ruby cut sensation manufactured by BASF, or a Ucare polymer JR manufactured by Amercor. -30M, JR-125, JR-400, Ucare polymer LR-30M manufactured by the company, Poise C-150L, C-60H manufactured by Kao Corporation, JAGUAR C-13S, C-14S, C-17 manufactured by Rhodia, EXCEL , C-500, SANCARE 2000, HP-8, HP-105, HP-120, Kathonal HC-100, HC-200, LC-100, LC-200, CG-100, CG-100S, manufactured by Toho Chemical Co., Ltd. CTR-100, CLB-100, CF-100, MEPO Commercially available products such as Limar 09W, H40W, Yuka Former R205, SM, 301, AMOPHOSE, 202, Akzo Nobel Amphomer 28-4910, LV-71, SH30 manufactured by Mitsubishi Chemical Corporation can be used.

  In the hair cosmetic composition of the present invention, the component (a) cationic surfactant, component (b) higher alcohol, component (c) paste oil at 25 ° C., component (d) propylene oxide addition mole number is 15 or more and 60 It is prepared by containing the following polyoxypropylene butyl ether as an essential component and adding them to water or a solution obtained by adding an appropriate solvent to water. The water used in the hair cosmetic composition of the present invention is not particularly limited, and examples thereof include various kinds of water such as purified water, distilled water, hot spring water, deep ocean water, lavender flower water, and the like. Accordingly, one or a combination of two or more of these can be used. Moreover, although the compounding quantity of water can be suitably determined according to each above-mentioned component, it can be used in 20 to 95% of range in general.

  In addition to these essential components, other components generally blended in hair cosmetics can be blended depending on the purpose within a range not impairing the effects of the present invention. Specifically, for example, anionic surfactants such as lauryl sulfate, polyoxyethylene lauryl ether sulfate, lauryl benzene sulfonate, sodium lauroylmethyl-β-alanine; 2-alkyl-N-carboxymethyl-N -Amphoteric surfactants such as hydroxyethyl imidazolium betaine, coconut oil fatty acid amidopropyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethyl imidazolinium betaine sodium; polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester , Nonionic surfactants such as glycerin fatty acid esters; polymer compounds such as highly polymerized polyethylene glycol; wetting agents such as glycerin, propylene glycol, butylene glycol, dipropylene glycol; Higher fatty acids such as phosphoric acid, behenic acid and oleic acid; ester oils such as isopropyl myristate; hydrocarbons such as liquid isoparaffin, petrolatum and squalane; lower alcohols such as ethanol, methanol, propyl alcohol and isopropyl alcohol; L-aspartic acid , Amino acids such as sodium L-aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, L-threonine; other UV absorbers, preservatives, sugars, fragrances, colorants, sequestering metals Agents, antioxidants, various drugs and the like.

  The manufacturing method of the hair cosmetics of this invention is not specifically limited, It prepares by a conventional method. That is, it can manufacture by processing the said component (a)-(e) and the said arbitrary component as needed according to a conventional method.

  The hair cosmetic composition of the present invention can be implemented in various forms such as liquid, emulsion, cream, oil, gel, mousse, etc., depending on the combination with other components and the mechanism of the container. . In particular, the component (a) is the main emulsifier, the component (b) is the emulsification aid, the component (c) is the oil to be emulsified, and the emulsified type in which the component (d) is further blended into an oil-in-water emulsified type. From the viewpoint of obtaining the effects of the present invention such as ease of washing during rinsing, smoothness of finish, and flexibility.

  In the present invention, by combining a polyoxypropylene butyl ether having a polymerization degree of a polyoxypropylene group of 15 or more and 60 or less and a paste-like oil at 25 ° C., it is possible to obtain a smooth finger feeling when attached to the hair. Therefore, the same effect characteristics as those of conventionally used silicone oil can be obtained. For this reason, it is possible to make the finish smooth and supple without any particular compounding of silicone oil, and not to build up. For these reasons, it is not necessary to add silicone oil in the present invention. In the present invention, “substantially not blended” means that the blending amount relative to the total amount of the hair cosmetic is 1% or less, more preferably 0.1%, even if not blended or blended at all. It means the following.

  Specifically, the hair cosmetic composition of the present invention can be used as a hair product such as shampoo, hair rinse, hair conditioner, hair pack, hair cream, hair lotion, hair gel, hair styling mousse, hair spray and the like. The method of use can be used for any product such as a type that is applied to hair and then washed away, or a type that is applied to dry hair, but is not limited thereto.

  EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited at all by these.

Invention products 1 to 19 and comparative products 1 to 5: Hair conditioners Prepare hair conditioners according to the formulations shown in Tables 1 to 4 and the following production method, and “Ease of washing when rinsing”, “Smoothness of finish”, “Finish flexibility” and “not build-up” were evaluated and determined by the following evaluation methods and criteria, and the results are shown in Table 1.

(Production method)
A: Components (1) to (19) are heated to 80 ° C. and uniformly mixed.
B: Components (20) to (26) are heated to 80 ° C.
C: A is added to B, and the mixture is uniformly emulsified and cooled.
D: Component (27) was added to C and mixed, and the mixture was filled in a container to obtain a hair conditioner.

(Evaluation method)
Have 10 panelists specializing in cosmetics use the hair conditioners of the present invention products 1-19 and comparative products 1-5, and “Ease of washing when rinsing”, “Smoothness of finish”, “Flexibility of finish” The following evaluation criteria (a) were evaluated for "", and the following evaluation criteria (b) for "no build-up" were evaluated. Thereafter, the average score of all panels was determined according to the following criteria.
<Evaluation criteria (a)>: Ease of washing during rinsing
[Evaluation Result]: [Score]
Very easy to wash away: 5 points easy to wash away: 4 points somewhat easy to wash away: 3 points somewhat difficult to wash away: 2 points difficult to wash away: 1 point

<Evaluation criteria (a)>: Smooth finish
[Evaluation Result]: [Score]
Very smooth: 5 points Smooth: 4 points Somewhat smooth: 3 points Somewhat inferior: 2 points Inferior smooth: 1 point

<Evaluation criteria (a)>: Finished flexibility
[Evaluation Result]: [Score]
Very supple: 5 points supple: 4 points supple: 3 points inferior to supple: 2 points inferior to supple: 1 point

<Evaluation Criteria (b)>: It was evaluated as the number of times of use until the hair feels stiff while it was used for 1 month at a frequency of use once a day without build-up.
[Evaluation Result]: [Grade]
I feel no worries even after 1 month of continuous use: 5 points I feel a little stiff after 1 month of continuous use: I feel a little stiff after 4 points of 3 weeks of continuous use I feel slightly stiff after 1 week of continuous use: 1 point

Based on the above evaluation criteria, the average value of the evaluated scores was determined based on the following criteria.
<Criteria>
[Average score]: [Judgment]
4.5 or more: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than 1.5: ×

As is apparent from the results of Tables 1 to 4, all of the hair conditioners 1 to 19 of the present invention products are “ease of washing when rinsing”, “smoothness of the finish”, “smoothness of the finish” and It was proved to show an extremely excellent effect in “no build-up”.
On the other hand, Comparative Product 1 in which mineral oil was blended instead of component (c) was inferior to “easy to wash off during rinsing” and “smoothness of finish”, and component (d) However, Comparative products 2 to 4 which are not within the range of the number of moles of propylene oxide added according to the present invention were inferior in “smoothness of the finish” and comparative product 3 in “no build-up”. Further, Comparative Product 5 in which dimethylpolysiloxane was blended instead of blending component (d) was inferior to “no build-up”.

Hair milk (ingredient) (%)
1. Behenyltrimethylammonium chloride 0.2
2. Dicocoylethylhydroxyethylmonium methosulfate 0.2
3. Cetostearyl alcohol 2
4). 2-ethylhexyl palmitate 1
5. Vaseline 1
6). Shea fat (Note 1) 1
7). Hardened castor oil 1
8). Jojoba alcohol 1
9. Paramethoxycinnamic acid-2-ethylhexyl 0.1
10. Polyoxypropylene (52) butyl ether (Note 4) 3
11. Dipropylene glycol 3
12.1,3-butylene glycol 2
13. Chloride [2-hydroxy-3- (trimethylammonio)
Propyl] hydroxyethyl cellulose (Note 7) 0.2
14 Phenoxyethanol 0.2
15. Glycosyl trehalose 0.1
16. Citric acid 0.1
17. Sodium citrate 0.1
18. Fragrance 0.5
19. Purified water remaining (manufacturing method)
A: Components 1 to 10 are heated and dissolved uniformly.
B: Components 11 to 17 and 19 are heated and dissolved uniformly.
C: A is added to B, and the mixture is uniformly emulsified and cooled.
D. Ingredient 18 was added to C and mixed, and then filled into a container to obtain hair milk.

The hair milk of Example 2 obtained as described above was an excellent hair cosmetic composition with smooth finish, suppleness, lack of build-up and the like.

Hair lotion (hair mist)
(Ingredient) (%)
1. 1,3-butylene glycol 1
2. Vaseline 0.1
3. Dicocoyldimethylammonium chloride 0.5
4). Cetostearyl alcohol 0.05
5. Polyoxypropylene (52) butyl ether (Note 4) 1
6). Ethanol 10
7). Hydroxyethyl cellulose 0.1
8). Purified water remaining amount 9. Rose extract 0.1
10. Isostearoyl hydrolyzed collagen / aminomethyl propanediol salt 0.1
11. Methylparaben 0.1
12.1,2-Pentanediol 2
13. Fragrance 0.5
(Production method)
A: Heat components 1 to 5 and mix uniformly.
B: Components 6 to 14 are added to A and mixed uniformly.
C: B was filled into an atomizer container to obtain a hair lotion.

The hair lotion (hair mist) of Example 3 obtained as described above was a hair cosmetic that had no stickiness and was excellent in smoothness, flexibility, and build-up.

Stick hair cosmetics (ingredients) (%)
1. Fischer-Tropsch wax 5
2. Behenyl alcohol 4
3. Microcrystalline wax 6
4). Glyceryl tri-2-ethylhexanoate 5
5. 5. Diglyceryl triisostearate remaining amount Alkyltrimethylammonium chloride 6
7). Shea fat (note 1) 2
8). Liquid paraffin 10
9. Vaseline 30
10. Stearyl glycyrrhetinate 1
11. Methylsiloxane network polymer (Note 2) 0.1
12 Polyoxypropylene (40) butyl ether (Note 5) 2
13. Silylation-treated silicic acid 0.1
14 Dibutylhydroxytoluene 0.1
15. Phenoxyethanol 0.1
16.1,2-Pentanediol 0.1
17. Perfume Appropriate amount (Note 2) Tospearl 2000B * (Momentive Performance Materials Japan)
(Production method)
A: Components 1 to 12 are heated and mixed uniformly.
B: Components 13 to 16 are added to A and mixed uniformly.
C: Component 17 was added to and mixed with B, and then filled into a container to obtain a stick-like hair cosmetic.

The stick-like hair cosmetic of Example 4 obtained as described above was a hair cosmetic that had no stickiness and was excellent in finish smoothness, suppleness, build-up, and the like.

Hair treatment (ingredient) (%)
1. Cetostearyl alcohol 2.5
2. Behenyl alcohol 2.5
3. Polyoxyethylene (40) hydrogenated castor oil 0.5
4). Glyceryl monostearate 0.2
5. N-lauroyl-L-glutamate di (phytosteryl, behenyl,
2-octyldodecyl) 1
6). Isopropyl myristate 3
7). Astaxanthin 0.01
8). Hematococcus spur beari extract (Note 8) 0.01
9. Polyoxypropylene (40) butyl ether (Note 5) 2
10. Purified water remaining amount 11. Propylene glycol 10
12.1,2-Pentanediol 0.1
13. Stearyltrimethylammonium chloride 0.5
14 Chloride [2-hydroxy-3- (trimethylammonio)
Propyl] hydroxyethyl cellulose (Note 7) 0.2
15. Phenoxyethanol 0.1
16. Fragrance Appropriate amount (Note 8) Astaxanthin-5C (Oryza Oil Chemical Co., Ltd.)
(Production method)
A: Components 1 to 9 are heated and dissolved uniformly.
B: Components 10 to 15 are uniformly dissolved by heating.
C: A is added to B, and the mixture is uniformly emulsified and cooled.
D. After component 16 was added to C and mixed, the container was filled to obtain a hair treatment.

  The hair treatment of Example 5 obtained as described above was an excellent hair cosmetic composition with a smooth finish, a suppleness, and a lack of build-up.

Claims (5)

The following components (a) to (d);
(A) 0.01-20.0 mass% of cationic surfactant
(B) 0.1 to 12% by mass of a higher alcohol having 12 to 22 carbon atoms having a linear or branched hydrocarbon group
(C) Oil having a viscosity at 25 ° C. of 5,000 to 100,000 mPa · s 0.1 to 15% by mass
(D) Polyoxypropylene group having a degree of polymerization of 15 to 60 and having a degree of polymerization of 0.2 to 8% by mass
A hair cosmetic characterized by comprising 1% by mass or less of silicone oil based on the total amount of the hair cosmetic, or not blended at all .     The component (c) is petrolatum, shea butter, N-lauroyl-L-glutamate di (phytosteryl, behenyl, 2-octyldodecyl), myristyl myristate, cholesteryl hydroxystearate, hexa (hydroxystearic acid / stearic acid / rosin) The hair cosmetic composition according to claim 1, wherein the hair cosmetic composition is one or more selected from (acid) dipentaerythrityl and dimerlinoleic acid dimer dilinoleyl.     3. The hair makeup according to claim 1, wherein the blending mass ratio (d) / (c) of the component (c) and the component (d) is 0.1-1. Fee.     Furthermore, amphoteric polymer and / or cationic polymer are contained as a component (e), The hair cosmetics in any one of Claims 1-3 characterized by the above-mentioned.     The hair cosmetic composition according to any one of claims 1 to 4, which is an oil-in-water emulsion type.