JP5992257B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
- Publication number
- JP5992257B2 JP5992257B2 JP2012186700A JP2012186700A JP5992257B2 JP 5992257 B2 JP5992257 B2 JP 5992257B2 JP 2012186700 A JP2012186700 A JP 2012186700A JP 2012186700 A JP2012186700 A JP 2012186700A JP 5992257 B2 JP5992257 B2 JP 5992257B2
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- JP
- Japan
- Prior art keywords
- peg
- ppg
- group
- hair
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- RJECHNNFRHZQKU-RMUVNZEASA-N cholesteryl oleate Chemical compound C([C@@H]12)C[C@]3(C)[C@@H]([C@H](C)CCCC(C)C)CC[C@H]3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)C1 RJECHNNFRHZQKU-RMUVNZEASA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229950010030 dl-alanine Drugs 0.000 description 1
- QQIQMUCZVKBKCS-UHFFFAOYSA-M docosyl-(2-hydroxyethyl)-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CCO QQIQMUCZVKBKCS-UHFFFAOYSA-M 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229960002449 glycine Drugs 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229960001330 hydroxycarbamide Drugs 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000005645 linoleyl group Chemical group 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- ATHMKKBJVNTDQC-UHFFFAOYSA-M methyl sulfate;triethyl(hexadecyl)azanium Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCC[N+](CC)(CC)CC ATHMKKBJVNTDQC-UHFFFAOYSA-M 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- WTWSHHITWMVLBX-DKWTVANSSA-M sodium;(2s)-2-aminobutanedioate;hydron Chemical compound [Na+].[O-]C(=O)[C@@H](N)CC(O)=O WTWSHHITWMVLBX-DKWTVANSSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000003871 white petrolatum Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Description
本発明は、毛髪化粧料に関し、詳しくは、毛髪にべたつきを与えることなく、柔らかでしっとりとした仕上がり感を与える事ができ、かつ濯ぎ時に指通り良く、柔らかで仕上がりへの期待感を与える毛髪化粧料に関する。 The present invention relates to a hair cosmetic, and more specifically, hair that can give a soft and moist finish without giving the hair stickiness, and is easy to pass through when rinsing, giving a soft and expectation to the finish. Regarding cosmetics.
女性のヘアスタイルの流行に伴って、求められる髪の仕上がりや感触も並行して変化している。最近では、シャギーやレイヤーカットなどの毛先のボリュームを落としたヘアスタイルが一般的であり、また一方、カラーリングやパーマ等の施術により、パサツキや髪の硬さが問題となっている。そのような背景から、しっとりしながら、べたつかず、柔らかな仕上がり感が求められている。また、カラーリングやパーマ等の施術によって傷んだ髪は、コンディショナーの濯ぎ時においても、絡み引っ掛かりなど不快な感触につながる。この濯ぎ時の不快な感触は、仕上がり感の満足度にも大きな影響を与える。従って、満足度の高い仕上がりを得る為には、しっとりとしながら、べたつかず、柔らかな仕上がり感でありながら、さらにコンディショナーの濯ぎ時も、柔らかで指通り良く、仕上がりに期待感を持たせる使用感が望まれる。ヘアリンスやヘアトリートメント等の毛髪化粧料においては、従来、毛髪を柔軟にして櫛通りをよくする目的で、カチオン性界面活性剤やシリコーン等の配合、或いは、しっとりとした感触を与えるために液状や固形状の油剤の配合が試みられているが、これら従来の技術では、近年のヘアスタイルにおいて要求されているニーズを満足させることは困難であり、仕上がりはしっとりとしながらべたつかず柔らかで、かつ使用感としては、濯ぎ時も柔らかで指通り良く、仕上がりに期待感を持たせる使用感を両立することは課題であった。 With the trend of women's hairstyles, the required finish and feel of hair are changing in parallel. Recently, hair styles with a reduced volume of hair ends such as shaggy and layer cut are common, and on the other hand, treatments such as coloring and perm have become a problem of softness and hair hardness. From such a background, there is a need for a moist, non-sticky and soft finish. In addition, hair damaged by treatments such as coloring and perm leads to an unpleasant feel such as entanglement and catching even when the conditioner is rinsed. This unpleasant feeling at the time of rinsing has a great influence on the satisfaction of the finished feeling. Therefore, in order to obtain a highly satisfying finish, it is moist, non-sticky, and has a soft finish, but it is also soft and easy to use when rinsing the conditioner, and it gives a sense of expectation to the finish. Is desired. In hair cosmetics such as hair rinses and hair treatments, conventionally, for the purpose of softening the hair and improving the combing, it is possible to add a cationic surfactant, silicone, etc., or to give a moist feel. Attempts have been made to formulate solid oils, but with these conventional technologies, it is difficult to satisfy the needs required in recent hairstyles, and the finish is moist but soft and non-sticky. As a feeling, it was a challenge to achieve both a feeling of use that gives a feeling of expectation to the finish, and is soft and easy to follow even when rinsing.
これらの課題を解決する方法として、例えば、脂肪酸アミドアミン化合物やヒドロキシエーテルアミン化合物を用いることにより、毛髪に滑らかさや柔軟性を付与する毛髪化粧料が提案されている(例えば、特許文献1〜4参照。)。これらの技術は、いずれも一定の改善がなされているが、仕上がりは良くとも、濯ぎ時に仕上がりへの十分な期待感を持つことなく消費者を十分に満足させてはいない。 As a method for solving these problems, for example, a hair cosmetic that imparts smoothness and flexibility to hair by using a fatty acid amidoamine compound or a hydroxyetheramine compound has been proposed (see, for example, Patent Documents 1 to 4). .) Although all of these techniques have been improved to some extent, even if the finish is good, they do not fully satisfy consumers without having a sufficient expectation for the finish when rinsing.
また、新たな抱水性の高い油剤やシリコーン類を配合することによって、毛髪に滑らかさや柔軟性を付与する試みがなされ、例えば、各種シリコーン化合物を配合して、柔らかさとしっとり感を付与する方法(例えば、特許文献5参照。)、ダイマージリノール酸ダイマー酸リノレイルビス(フィトステリル/ベヘニル/イソステアリル)を配合したなじみや伸びに優れべたつきの少ない化粧料(例えば、特許文献6参照。)、分岐脂肪酸コレステリルエステルを配合してしっとり感、さらさら感、柔軟性を付与する毛髪化粧料(例えば、特許文献7参照。)が開示されている。しかしながら、これらの発明においても、しなやかさやしっとり感は実現できるものの、髪がべたつき、重くなり、濯ぎ時には、仕上がりへの十分な期待感を持つことなく消費者を十分に満足させてはいない。 In addition, attempts have been made to impart smoothness and flexibility to hair by blending new oils and silicones with high water-holding properties. For example, a method of blending various silicone compounds to impart softness and moist feeling ( For example, refer to Patent Document 5), dimerinolinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) blended cosmetics with excellent fit and elongation (see Patent Document 6, for example), branched fatty acid cholesteryl. A hair cosmetic (for example, see Patent Document 7) that imparts a moist feeling, a smooth feeling, and flexibility by blending an ester is disclosed. However, even in these inventions, although a supple, moist feeling can be realized, the hair becomes sticky and heavy, and at the time of rinsing, the consumer is not fully satisfied without having a sufficient expectation for the finish.
また、PPG−1/PEG−1ステアラミンを、シリコン類、カチオン活性剤と併用し配合する事によって、塗布時に髪になじみやすく、乾燥後はしっとり柔らかくする技術(例えば、非特許文献1,2参照。)が提案されているが、濯ぎ時のに指通りよく柔らかで、仕上がりへの期待感を与えることには十分ではない。 In addition, PPG-1 / PEG-1 stearamine is used in combination with silicones and a cationic activator, so that it is easy to adjust to hair at the time of application, and softens after drying (for example, see Non-Patent Documents 1 and 2). )) Is proposed, but it is soft enough to follow when rinsing and is not sufficient to give a sense of expectation to the finish.
本発明の目的は、毛髪にべたつきをあたえることなく、柔らかでしっとりとした仕上がり感を与える事ができ、かつ濯ぎ時に指通り良く、柔らかで、仕上がりへの期待感を与える毛髪化粧料を提供することにある。 An object of the present invention is to provide a hair cosmetic that can give a soft and moist finish without giving the hair stickiness, is soft and easy to pass when rinsing, and gives a sense of expectation to the finish. There is.
本発明者らは、このような状況に鑑み、鋭意研究した結果、ヒドロキシエチル基、ヒドロキシプロピル基を持った脂肪酸アミンと、アルキル型カチオンと、高級アルコールと、シリコーン誘導体と、メチルポリシロキサンとを含有する毛髪化粧料が、上記課題を解決することを見出し、本発明を完成するに至った。 As a result of diligent research in view of such circumstances, the present inventors have found that a fatty acid amine having a hydroxyethyl group and a hydroxypropyl group, an alkyl cation, a higher alcohol, a silicone derivative, and methylpolysiloxane. It has been found that the hair cosmetics to be contained can solve the above-mentioned problems, and the present invention has been completed.
即ち、本発明の毛髪化粧料は下記成分(A)〜(F)を含有することを特徴としている。(A)PPG−1/PEG−1ステアラミン及びPPG−1/PEG−1ベヘナミンから
選ばれる1種又は2種
(B)下記一般式(II)で表されるアルキル型カチオン
(式中、R4〜R7のうちいずれか1個又は2個は炭素数8〜24のアルキル基、アルケニル基、ヒドロキシアルキル基又はヒドロキシアルケニル基であり、残りは、炭素数1〜3のアルキル基もしくはヒドロキシアルキル基又はベンジル基を表し、Yはハロゲン原子又は炭素数1〜3のアルキル硫酸基を示す。)
(C)炭素数14〜24の長鎖のアルキル基を有する高級アルコール
(D)アミノエチルアミノプロピルメチコン/ジメチコン共重合体、アミノプロピルジメチコン、高重合アミノプロピルジメチコン、アモジメチコン、及びアミノポリエーテルシリコンから選ばれる少なくとも1種のシリコーン誘導体。
(E)25℃での動粘度が50万cs〜3000万csのメチルポリシロキサン
(F)ベヘニルPGトリモニウムクロリド
That is, the hair cosmetic composition of the present invention is characterized by containing the following components (A) to ( F ). (A) From PPG-1 / PEG-1 stearamine and PPG-1 / PEG-1 behenamine
1 type or 2 types selected (B) alkyl type cation represented by the following general formula (II)
(In the formula, any one or two of R 4 to R 7 are an alkyl group, an alkenyl group, a hydroxyalkyl group or a hydroxyalkenyl group having 8 to 24 carbon atoms, and the rest are ones having 1 to 3 carbon atoms. Represents an alkyl group, a hydroxyalkyl group or a benzyl group, and Y represents a halogen atom or an alkyl sulfate group having 1 to 3 carbon atoms.)
(C) a higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms (D) aminoethylaminopropyl methicone / dimethicone copolymer, aminopropyl dimethicone, highly polymerized aminopropyl dimethicone, amodimethicone, and amino polyether silicon At least one silicone derivative selected from:
(E) Methylpolysiloxane having a kinematic viscosity at 25 ° C. of 500,000 cs to 30 million cs
(F) Behenyl PG trimonium chloride
また本発明の毛髪化粧料は、成分(D)のシリコーン誘導体がアミノポリエーテルシリコンであることがより望ましい。
The hair cosmetic composition of the present invention, it is more desirable silicone derivative of Ingredient (D) is an amino polyether silicone.
本発明の毛髪化粧料は、毛髪にべたつきを与えることなく、やわらかでしっとりとした仕上がり感を与える事ができ、かつ、濯ぎ時に指通りよくやわらかで、仕上がりへの期待感を与える効果を付与することができる。 The hair cosmetic composition of the present invention can give a soft and moist finish without giving the hair stickiness, and gives the effect of giving a sense of expectation to the finish that is soft and soft as a finger when rinsing. be able to.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明における成分(A)の脂肪アミンは、例えば、PPG−1/PEG−1ラウラミン、PPG−1/PEG−1ミリスタミン、PPG−1/PEG−1セタミン、PPG−1/PEG−1ステアラミン、PPG−1/PEG−1アラカミン、PPG−1/PEG−1ベヘナミン、PPG−1/PEG−1カルナバミン、PPG−1/PEG−1オレアミン、PPG−1/PEG−1エライザミン、PPG−1/PEG−1リノラミン、PPG−1/PEG−1リノレナル、PPG−1/PEG−2ラウラミン、PPG−1/PEG−2ラウラミン、PPG−1/PEG−2ミリスタミン、PPG−1/PEG−2セタミン、PPG−1/PEG−2ステアラミン、PPG−1/PEG−2アラカミン、PPG−1/PEG−2ベヘナミン、PPG−1/PEG−2カルナバミン、PPG−1/PEG−2オレアミン、PPG−1/PEG−2エライザミン、PPG−1/PEG−2リノラミン、PPG−1/PEG−2リノレナル、PPG−1/PEG−3ラウラミン、PPG−1/PEG−3ラウラミン、PPG−1/PEG−3ミリスタミン、PPG−1/PEG−3セタミン、PPG−1/PEG−3ステアラミン、PPG−1/PEG−3アラカミン、PPG−1/PEG−3ベヘナミン、PPG−1/PEG−3カルナバミン、P
PG−1/PEG−3オレアミン、PPG−1/PEG−3エライザミン、PPG−1/PEG−3リノラミン、PPG−1/PEG−3リノレナル、PPG−2/PEG−1ラウラミン、PPG−2/PEG−1ミリスタミン、PPG−2/PEG−1セタミン、PPG−2/PEG−1ステアラミン、PPG−2/PEG−1アラカミン、PPG−2/PEG−1ベヘナミン、PPG−2/PEG−1カルナバミン、PPG−2/PEG−1オレアミン、PPG−2/PEG−1エライザミン、PPG−2/PEG−1リノラミン、PPG−2/PEG−1リノレナル、PPG−2/PEG−2ラウラミン、PPG−2/PEG−2ミリスタミン、PPG−2/PEG−2セタミン、PPG−2/PEG−2ステアラミン、PPG−2/PEG−2アラカミン、PPG−2/PEG−2ベヘナミン、PPG−2/PEG−2カルナバミン、PPG−2/PEG−2オレアミン、PPG−2/PEG−2エライザミン、PPG−2/PEG−2リノラミン、PPG−2/PEG−2リノレナル、PPG−2/PEG−3ラウラミン、PPG−2/PEG−3ミリスタミン、PPG−2/PEG−3セタミン、PPG−2/PEG−3ステアラミン、PPG−2/PEG−3アラカミン、PPG−2/PEG−3ベヘナミン、PPG−2/PEG−3カルナバミン、PPG−2/PEG−3オレアミン、PPG−2/PEG−3エライザミン、PPG−2/PEG−3リノラミン、PPG−2/PEG−3リノレナル、PPG−3/PEG−1ラウラミン、PPG−3/PEG−1ミリスタミン、PPG−3/PEG−1セタミン、PPG−3/PEG−1ステアラミン、PPG−3/PEG−1アラカミン、PPG−3/PEG−1ベヘナミン、PPG−3/PEG−1カルナバミン、PPG−3/PEG−1オレアミン、PPG−3/PEG−1エライザミン、PPG−3/PEG−1リノラミン、PPG−3/PEG−1リノレナル、PPG−3/PEG−2ラウラミン、PPG−3/PEG−2ミリスタミン、PPG−3/PEG−2セタミン、PPG−3/PEG−2ステアラミン、PPG−3/PEG−2アラカミン、PPG−3/PEG−2ベヘナミン、PPG−3/PEG−2カルナバミン、PPG−3/PEG−2オレアミン、PPG−3/PEG−2エライザミン、PPG−3/PEG−2リノラミン、PPG−3/PEG−2リノレナル、PPG−3/PEG−3ラウラミン、PPG−3/PEG−3ミリスタミン、PPG−3/PEG−3セタミン、PPG−3/PEG−3ステアラミン、PPG−3/PEG−3アラカミン、PPG−3/PEG−3ベヘナミン、PPG−3/PEG−3カルナバミン、PPG−3/PEG−3オレアミン、PPG−3/PEG−3エライザミン、PPG−3/PEG−3リノラミン、PPG−3/PEG−3リノレナル、PPG−1ラウラミン、PPG−1ミリスタミン、PPG−1セタミン、PPG−1ステアラミン、PPG−1アラカミン、PPG−1ベヘナミン、PPG−1カルナバミン、PPG−1オレアミン、PPG−1エライザミン、PPG−1リノラミン、PPG−1リノレナル、PPG−2ラウラミン、PPG−2ミリスタミン、PPG−2セタミン、PPG−2ステアラミン、PPG−2アラカミン、PPG−2ベヘナミン、PPG−2カルナバミン、PPG−2オレアミン、PPG−2エライザミン、PPG−2リノラミン、PPG−2リノレナル、PPG−3ラウラミン、PPG−3ミリスタミン、PPG−3セタミン、PPG−3ステアラミン、PPG−3アラカミン、PPG−3ベヘナミン、PPG−3カルナバミン、PPG−3オレアミン、PPG−3エライザミン、PPG−3リノラミン、PPG−3リノレナル、PEG−1ラウラミン、PEG−1ミリスタミン、PEG−1セタミン、PEG−1ステアラミン、PEG−1アラカミン、PEG−1ベヘナミン、PEG−1カルナバミン、PEG−1オレアミン、PEG−1エライザミン、PEG−1リノラミン、PEG−1リノレナル、PEG−2ラウラミン、PEG−2ミリスタミン、PEG−2セタミン、PEG−2ステアラミン、PEG−2アラカミン、PEG−2ベヘナミン、PEG−2カルナバミン、PEG−2オレアミン、PEG−2エライザミン、PEG−2リノラミン、PEG−2リノレナル、PEG−3ラウラミン、PEG−3ミリスタミン、PEG−3セタミン、PEG−3ステアラミン、PEG−3アラカミン、PEG−3ベヘナミン、PEG−3カルナバミン、PEG−3オレアミン、PEG−3エライザミン、PEG−3リノラミン、PEG−3リノレナル、ラウラミン、ミリスタミン、セタミン、ステアラミン、アラカミン、ベヘナミン、カルナバミン、オレアミ
ン、エライザミン、リノラミン、リノレナル、等の脂肪アミンが挙げられるが、これらは限定するものではない。この中でも、PPG−1/PEG−1ステアラミンと、PPG−1/PEG−1ベヘナミンが特に好ましい。本発明では、これらの脂肪アミンの中から1種又は2種以上を任意に用いることができ、その配合量は、好ましくは0.1〜10質量%(以下、特に記載のあるもの以外は、質量%を単に「%」で示す)、更に好ましくは、0.5〜5%の範囲である。この配合量の範囲であれば、毛髪にべたつきを与えることなく、柔らかでしっとりとした仕上がり感を与える事ができ、かつ、濯ぎ時に指通りよく柔らかで、仕上がりへの期待感を与える効果を付与することができるため好ましい。
Fat 肪A Min component (A) in the present invention, if example embodiment, PPG-1 / PEG-1 lauramine, PPG-1 / PEG-1 Mirisutamin, PPG-1 / PEG-1 Setamin, PPG-1 / PEG- 1 stearamine, PPG-1 / PEG-1 alacamine, PPG-1 / PEG-1 behenamine, PPG-1 / PEG-1 carnabamine, PPG-1 / PEG-1 oleamine, PPG-1 / PEG-1 Elizamin, PPG- 1 / PEG-1 linolamine, PPG-1 / PEG-1 linolenal, PPG-1 / PEG-2 lauramine, PPG-1 / PEG-2 lauramine, PPG-1 / PEG-2 myristamine, PPG-1 / PEG-2 Cetamine, PPG-1 / PEG-2 stearamine, PPG-1 / PEG-2 alacamine, PPG-1 / PEG-2 behenamine PPG-1 / PEG-2 carnabamine, PPG-1 / PEG-2 oleamine, PPG-1 / PEG-2 elizamin, PPG-1 / PEG-2 linolamine, PPG-1 / PEG-2 linolenal, PPG-1 / PEG -3 lauramine, PPG-1 / PEG-3 lauramine, PPG-1 / PEG-3 myristamine, PPG-1 / PEG-3 cetamine, PPG-1 / PEG-3 stearamine, PPG-1 / PEG-3 alacamine, PPG -1 / PEG-3 behenamine, PPG-1 / PEG-3 carnabamine, P
PG-1 / PEG-3 oleamine, PPG-1 / PEG-3 elizamin, PPG-1 / PEG-3 linolamine, PPG-1 / PEG-3 linolenal, PPG-2 / PEG-1 lauramine, PPG-2 / PEG -1 myristamine, PPG-2 / PEG-1 cetamine, PPG-2 / PEG-1 stearamine, PPG-2 / PEG-1 alacamine, PPG-2 / PEG-1 behenamine, PPG-2 / PEG-1 carnabamine, PPG -2 / PEG-1 oleamine, PPG-2 / PEG-1 Elizamin, PPG-2 / PEG-1 linolamine, PPG-2 / PEG-1 linolenal, PPG-2 / PEG-2 lauramine, PPG-2 / PEG- 2 myristamine, PPG-2 / PEG-2 cetamine, PPG-2 / PEG-2 stearamine, PPG-2 / EG-2 alacamine, PPG-2 / PEG-2 behenamine, PPG-2 / PEG-2 carnabamine, PPG-2 / PEG-2 oleamine, PPG-2 / PEG-2 elizamin, PPG-2 / PEG-2 linolamine, PPG-2 / PEG-2 linolenal, PPG-2 / PEG-3 lauramine, PPG-2 / PEG-3 myristamine, PPG-2 / PEG-3 cetamine, PPG-2 / PEG-3 stearamine, PPG-2 / PEG -3 alacamine, PPG-2 / PEG-3 behenamine, PPG-2 / PEG-3 carnabamine, PPG-2 / PEG-3 oleamine, PPG-2 / PEG-3 elizamin, PPG-2 / PEG-3 linolamine, PPG -2 / PEG-3 linolenal, PPG-3 / PEG-1 lauramine, PPG-3 / PEG-1 Listamine, PPG-3 / PEG-1 cetamine, PPG-3 / PEG-1 stearamine, PPG-3 / PEG-1 alacamine, PPG-3 / PEG-1 behenamine, PPG-3 / PEG-1 carnabamine, PPG-3 / PEG-1 oleamine, PPG-3 / PEG-1 Elizamin, PPG-3 / PEG-1 linolamine, PPG-3 / PEG-1 linolenal, PPG-3 / PEG-2 lauramine, PPG-3 / PEG-2 myristamine , PPG-3 / PEG-2 cetamine, PPG-3 / PEG-2 stearamine, PPG-3 / PEG-2 alacamine, PPG-3 / PEG-2 behenamine, PPG-3 / PEG-2 carnabamine, PPG-3 / PEG-2 oleamine, PPG-3 / PEG-2 elizamin, PPG-3 / PEG-2 linolamine , PPG-3 / PEG-2 linolenal, PPG-3 / PEG-3 lauramine, PPG-3 / PEG-3 myristamine, PPG-3 / PEG-3 cetamine, PPG-3 / PEG-3 stearamine, PPG-3 / PEG-3 aracamine, PPG-3 / PEG-3 behenamine, PPG-3 / PEG-3 carnabamine, PPG-3 / PEG-3 oleamine, PPG-3 / PEG-3 elizamin, PPG-3 / PEG-3 linolamine, PPG-3 / PEG-3 linolenal, PPG-1 lauramine, PPG-1 myristamine, PPG-1 cetamine, PPG-1 stearamine, PPG-1 alacamine, PPG-1 behenamine, PPG-1 carnabamine, PPG-1 oleamine, PPG -1 Elizamin, PPG-1 linolamine, PPG-1 linolenal, P G-2 lauramine, PPG-2 myristamine, PPG-2 cetamine, PPG-2 stearamine, PPG-2 alacamine, PPG-2 behenamine, PPG-2 carnabamine, PPG-2 oleamine, PPG-2 elizamin, PPG-2 linolamine, PPG-2 linolenal, PPG-3 lauramine, PPG-3 myristamine, PPG-3 cetamine, PPG-3 stearamine, PPG-3 alacamine, PPG-3 behenamine, PPG-3 carnabamine, PPG-3 oleamine, PPG-3 elizamin, PPG-3 linolamine, PPG-3 linolenal, PEG-1 lauramine, PEG-1 myristamine, PEG-1 cetamine, PEG-1 stearamine, PEG-1 alacamine, PEG-1 behenamine, PEG-1 carnabamine, PEG-1 ole Min, PEG-1 Elizamin, PEG-1 Linolamine, PEG-1 Linolenal, PEG-2 Lauramine, PEG-2 Myristamine, PEG-2 Cetamine, PEG-2 Stearamine, PEG-2 Alacamine, PEG-2 Behenamine, PEG-2 Carnabamine, PEG-2 oleamine, PEG-2 elizamin, PEG-2 linolamine, PEG-2 linolenal, PEG-3 lauramine, PEG-3 myristamine, PEG-3 cetamine, PEG-3 stearamine, PEG-3 alacamine, PEG-3 Behenamine, PEG-3 carnabamine, PEG-3 oleamine, PEG-3 elizamin, PEG-3 linolamine, PEG-3 linolenal, lauramine, myristamine, cetamine, stearamine, alacamine, behenamine, carnabamine, oleami Emissions, Eraizamin, Rinoramin, Rinorenaru, although fat 肪A Min and the like etc., are not intended to be limiting. Among these, a P PG-1 / PEG-1 stearamine, particularly preferably P PG-1 / PEG-1 Behenamin. In the present invention, these can be used from the fat 肪A Min optionally one or two or more, other than the amount thereof, with preferably 0.1 to 10 mass% (hereinafter, described especially Represents mass% simply by “%”), more preferably in the range of 0.5 to 5%. If it is within this range, it can give a soft and moist finish without giving the hair sticky, and it gives the effect of giving a sense of expectation to the finish that is soft and soft to the finger when rinsing. This is preferable because it can be performed.
本発明における成分(B)のアルキル型カチオンは、下記一般式(II) The alkyl cation of component (B) in the present invention is represented by the following general formula (II)
(式中、R4〜R7のうちいずれか1個又は2個は炭素数8〜24のアルキル基、アルケニル基、ヒドロキシアルキル基又はヒドロキシアルケニル基であり、残りは、炭素数1〜3のアルキル基若しくはヒドロキシアルキル基又はベンジル基を表し、Yはハロゲン原子又は炭素数1〜3のアルキル硫酸基を示す。)で表される。上記炭素数8〜24のアルキル基としては、例えばセチル基、ステアリル基、ベヘニル基、12−ヒドロキシステアリル基等が挙げられる。これらの中でも、炭素数16〜22のアルキル基が好ましく、特に好ましいものとしてはベヘニル基が挙げられる。炭素数1〜3のアルキル基若しくはヒドロキシアルキル基又はベンジル基としては、好ましいものとしてメチル基、エチル基、プロピル基、ヒドロキシメチル基及びヒドロキシエチル基が挙げられる。ハロゲン原子としては、好ましくは塩素原子又は臭素原子が挙げられる。 (In the formula, any one or two of R 4 to R 7 is an alkyl group, an alkenyl group, a hydroxyalkyl group or a hydroxyalkenyl group having 8 to 24 carbon atoms, and the rest are those having 1 to 3 carbon atoms. Represents an alkyl group, a hydroxyalkyl group or a benzyl group, and Y represents a halogen atom or an alkyl sulfate group having 1 to 3 carbon atoms. Examples of the alkyl group having 8 to 24 carbon atoms include cetyl group, stearyl group, behenyl group, and 12-hydroxystearyl group. Among these, an alkyl group having 16 to 22 carbon atoms is preferable, and a behenyl group is particularly preferable. As a C1-C3 alkyl group or a hydroxyalkyl group, or a benzyl group, a methyl group, an ethyl group, a propyl group, a hydroxymethyl group, and a hydroxyethyl group are mentioned as a preferable thing. As a halogen atom, Preferably a chlorine atom or a bromine atom is mentioned.
上記一般式(II)で表されるアルキル型カチオンの具体例を示すと、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウム、塩化ベヘニルジメチルヒドロキシエチルアンモニウム、塩化ステアリルジメチルベンジルアンモニウム、塩化ジステアリルジメチルアンモニウム、塩化ジセチルジメチルアンモニウム、及びセチルトリエチルアンモニウムメチルサルフェート等が挙げられる。これらの中でも、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウムが好ましく、更に、塩化ベヘニルトリメチルアンモニウムが特に好ましい。本発明では、これらのアルキル型カチオンの中から1種又は2種以上を任意に用いることができ、その配合量は、好ましくは0.1〜10%、更に好ましくは、0.5〜5%の範囲である。この配合量の範囲であれば、毛髪にべたつきを与えることなく柔らかでしっとりとした仕上がり感を与える事ができ、かつ、濯ぎ時に指通りよく柔らかで、仕上がりへの期待感を与える効果を付与することができるため好ましい。 Specific examples of the alkyl cation represented by the general formula (II) are cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, behenyldimethylhydroxyethylammonium chloride, stearyldimethylbenzylammonium chloride, dichloride chloride. Examples include stearyl dimethyl ammonium, dicetyl dimethyl ammonium chloride, and cetyl triethyl ammonium methyl sulfate. Among these, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, and behenyltrimethylammonium chloride are preferable, and behenyltrimethylammonium chloride is particularly preferable. In this invention, 1 type (s) or 2 or more types can be arbitrarily used from these alkyl type cations, The compounding quantity becomes like this. Preferably it is 0.1-10%, More preferably, it is 0.5-5% Range. If it is within this blending amount, it can give a soft and moist finish without giving the hair sticky, and it gives the effect of giving a sense of expectation to the finish that is soft and easy to follow when rinsing. This is preferable.
本発明における成分(C)の炭素数14〜22の長鎖のアルキル基を有する高級アルコールは、好ましいものとしては、炭素数16〜22の長鎖高級アルコール、例えばセチルアルコール、ステアリルアルコール、ベヘニルアルコールである。これらの高級アルコールは、1種又は2種以上を組み合わせて用いることができ、その配合量は、好ましくは1〜20%、更に好ましくは、3〜10%の範囲である。この配合量の範囲であれば、毛髪に対して、べたつきを与えることなく、柔らかでしっとりとした仕上がり感を与える事ができ、かつ、濯ぎ時に指通りよく柔らかで、仕上がりへの期待感を与える効果を付与することができるため好ましい。 The higher alcohol having a long-chain alkyl group having 14 to 22 carbon atoms as component (C) in the present invention is preferably a long-chain higher alcohol having 16 to 22 carbon atoms such as cetyl alcohol, stearyl alcohol, or behenyl alcohol. is there. These higher alcohols can be used singly or in combination of two or more, and the blending amount is preferably 1 to 20%, more preferably 3 to 10%. If it is within this range, the hair can be given a soft and moist finish without giving it stickiness, and it is soft and easy to follow when rinsing, giving a sense of expectation to the finish. Since an effect can be provided, it is preferable.
本発明における成分(D)のシリコーン誘導体は、アミノエチルアミノプロピルメチコン/ジメチコン共重合体、アミノプロピルジメチコン、高重合アミノプロピルジメチコン、アモジメチコン、及びアミノポリエーテルシリコンから選ばれる少なくとも1種である。これらの中でも好ましいものは、アミノポリエーテル変性シリコンである。アミノポリエーテル変性シリコンの中でも、さらにより好ましくは、(ビスイソブチルPEG−14/アモジメチコン)コポリマーである。また、これらのシリコーン誘導体は、1種又は2種以上を組み合わせて用いることができ、その配合量は好ましくは、組成物全体に対して0.01〜10%、更に好ましくは0.1〜5%である。この配合量の範囲であれば、毛髪にべたつきを与えることなく、柔らかでしっとりとした仕上がり感を与える事ができ、かつ、濯ぎ時に指通りよく柔らかで、仕上がりへの期待感を与える効果を付与することができるため好ましい。 The silicone derivative of component (D) in the present invention is at least one selected from aminoethylaminopropyl methicone / dimethicone copolymer, aminopropyl dimethicone, highly polymerized aminopropyl dimethicone, amodimethicone, and amino polyether silicon. Among these, aminopolyether-modified silicon is preferable. Even more preferred among aminopolyether-modified silicon is a (bisisobutyl PEG-14 / amodimethicone) copolymer. These silicone derivatives can be used alone or in combination of two or more, and the blending amount thereof is preferably 0.01 to 10%, more preferably 0.1 to 5 with respect to the entire composition. %. If it is within this range, it can give a soft and moist finish without giving the hair sticky, and it gives the effect of giving a sense of expectation to the finish that is soft and soft to the finger when rinsing. This is preferable because it can be performed.
本発明における成分(E)の不揮発性かつ未変性のシリコーンは、好ましいものとしては、ジメチルポリシロキサン:メチルシロキサン構造を持ち、25℃における粘度が6〜5000,0000mPa・sである重合度ものが挙げられる。より好ましくは、10000〜4000,0000mPa・sである重合度のもの、さらにより好ましくは、500000〜3000,0000である重合度のものが挙げられる。 The non-volatile and unmodified silicone of component (E) in the present invention preferably has a polymerization degree having a dimethylpolysiloxane: methylsiloxane structure and a viscosity at 25 ° C. of 6 to 5,000,000 mPa · s. Can be mentioned. More preferably, the degree of polymerization is 10,000 to 4,000,000 mPa · s, and still more preferably, the degree of polymerization is 500,000 to 3,000,0000.
さらに本発明においては使用時の感触を高める目的で、成分(F)のベヘニルPGトリモニウムクロリドを配合することができる。ベヘニルPGトリモニウムクロリドは、下記一般式(III)
R8−(OCH2CH(OH)CH2)m−N+(R9)3・X- … (III)
(式中、R8は炭素数22のベヘニル基、R9はメチル基、Xは塩素を示す。)
その配合量は、好ましくは0.1〜10%、更に好ましくは、0.5〜5%の範囲である。
Further, in the present invention, the component (F) behenyl PG trimonium chloride can be blended for the purpose of enhancing the feel during use. Behenyl PG trimonium chloride is represented by the following general formula (III)
R 8 - (OCH 2 CH ( OH) CH 2) m-N + (R 9) 3 · X - ... (III)
(In the formula, R 8 represents a behenyl group having 22 carbon atoms, R 9 represents a methyl group, and X represents chlorine.)
The blending amount is preferably 0.1 to 10%, and more preferably 0.5 to 5%.
本発明の毛髪化粧料は、PPG−1/PEG−1ステアラミン及びPPG−1/PEG−1ベヘナミンから選ばれる1種又は2種の脂肪アミン、一般式(II)で表されるようなアルキル型カチオン、高級アルコール、上記記載のシリコーン誘導体、ジメチコン、ベヘニルPGトリモニウムクロリドを必須成分とし、これらを水又は水に適宜な溶剤などを加えた液に含有させることによって調製されるが、これらの必須成分以外にも、本発明の効果を損なわない範囲で通常毛髪化粧料に一般的に配合される他の成分を目的に応じて配合することができる。
The hair cosmetic composition of the present invention, as represented by one or two lipid 肪A Min, general formula selected from PPG-1 / PEG-1 stearamine and PPG-1 / PEG-1 Behenamin (II) Alkyl cation, higher alcohol, silicone derivative as described above, dimethicone , behenyl PG trimonium chloride is an essential component, and these are prepared by adding them in water or a solution obtained by adding an appropriate solvent to water. In addition to the essential components, other components generally blended in hair cosmetics can be blended according to the purpose within a range not impairing the effects of the present invention.
そのような成分としては、例えば、ラウリル硫酸塩、ポリオキシエチレンラウリルーテル硫酸塩、ラウリルベンゼンスルホン酸塩、ラウロイルメチ−β−アラニンナトリウム等のアニオン性界面活性剤;2−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾニウムベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ヤシ油アルキルN−カルボキシエチル−N−ヒドロキシエチルイミダゾリニウムベタインナトリウム等の両性界面活性剤:ポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリン脂肪酸エステル等の非イオン界面活性剤;カチオン化セルロース、ヒドロキシエチルセルロース、ポリ(塩化ジアリルジメチルアンモニウム)、高重合ポリエチレングリコール等の高分子化合物;グリセリン、プロピレングリコール、ブチレングリコール、ジプロピレングリコール等の湿潤剤;ステアリン酸、ベヘニン酸、オレイン酸等の高級脂肪酸;ミリスチン酸イソプロピル等のエステル油;流動イソパラフィン、ワセリン、スクワラン等の炭化水素;ジメチルポリシロキサン、高重合シリコーン、ポリエーテル変性シリコーン等のシリコン類;ジンクピリチオン、塩化ベンザルコニウム等の抗フケ成分;エタノール、メタノール、プロピルアルコール、イソプロピルアルコール等の低級アルコール;L−アスパラギン酸、L−アスパラギン酸ナトリウム、DL−アラニン、L−アルギニン、グリシン、L−グルタミン酸、L−システイン、Lスレオニン等のアミノ酸;その他紫外線吸収剤、防腐剤、糖類、香料、色剤、金属イオン封鎖剤、酸化防止剤、各種薬剤等が挙げられる。 Examples of such components include anionic surfactants such as lauryl sulfate, polyoxyethylene lauryl sulfate, lauryl benzene sulfonate, sodium lauroylmethy-β-alanine; 2-alkyl-N-carboxymethyl -Amphoteric surfactants such as N-hydroxyethyl imidazolium betaine, coconut oil fatty acid amidopropyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethyl imidazolinium betaine sodium: polyoxyethylene alkyl ether, polyoxyethylene sorbitan Nonionic surfactants such as fatty acid esters and glycerin fatty acid esters; polymers such as cationized cellulose, hydroxyethyl cellulose, poly (diallyldimethylammonium chloride), and highly polymerized polyethylene glycol Compound: Wetting agent such as glycerin, propylene glycol, butylene glycol, dipropylene glycol; higher fatty acid such as stearic acid, behenic acid, oleic acid; ester oil such as isopropyl myristate; hydrocarbon such as liquid isoparaffin, petrolatum, squalane Silicones such as dimethylpolysiloxane, highly polymerized silicone and polyether-modified silicone; antidandruff components such as zinc pyrithione and benzalkonium chloride; lower alcohols such as ethanol, methanol, propyl alcohol and isopropyl alcohol; L-aspartic acid, L -Amino acids such as sodium aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, L-threonine; other UV absorbers, preservatives, sugars, fragrances, colorants, metals Examples include ion sequestering agents, antioxidants, and various drugs.
本発明の毛髪化粧料は、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック、ヘアローション、ヘアリキッド、ヘアクリーム、ヘアフォーム、リーブオントリートメント、パーマ剤、ヘアカラー等に用いることができる。また本発明の毛髪化粧料は、常法により製造することができる。 The hair cosmetic composition of the present invention can be used for hair rinses, hair conditioners, hair treatments, hair packs, hair lotions, hair liquids, hair creams, hair foams, leave-on treatments, permanent agents, hair colors, and the like. The hair cosmetic composition of the present invention can be produced by a conventional method.
次に本発明の毛髪化粧料について、実施例を用いて詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価基準を説明する。 Next, although the hair cosmetics of this invention are demonstrated in detail using an Example, this invention is not limited by this. Prior to the examples, test methods and evaluation criteria employed in each example will be described.
(1)使用後の毛髪の仕上がり感試験法
20名のパネルが試料を使用し、使用後の毛髪のしっとり感、べたつきのなさ、柔らかさについて「良い」、「普通」、「悪い」の3段階で判定し、判定結果を「良い」と回答した人数により判断した。
判断基準は以下の通りである。
◎:大変優れている・・・「良い」が16名以上
○:優れている ・・・「良い」が11〜15名
△:劣っている ・・・「良い」が6〜10名
×:大変劣っている・・・「良い」が5名以下
(1) Hair finish feeling test method after use 20 panels use samples, and the hair feels moist, non-sticky and soft after use. “Good”, “Normal”, “Bad” 3 Judgment was made at the stage, and the judgment result was judged by the number of people who answered “good”.
Judgment criteria are as follows.
◎: Very good ... "Good" is more than 16 people ○: Excellent ... "Good" is 11-15 people △: Inferior ... "Good" is 6-10 people ×: Very inferior ... "Good" is less than 5
(2)使用時の感触試験法
20名のパネルが試料を使用し、使用時の濯ぎ時の指通り、柔らかさについて「良い」、「普通」、「悪い」の3段階で判定し、仕上がりへの期待感について「ある」、「普通」、「ない」の3段階で判定し、判定結果を「良い」又は「ある」と回答した人数により判断した。
判断基準は以下の通りである。
◎:大変優れている・・・「良い」又は「ある」が16名以上
○:優れている ・・・「良い」又は「ある」が11〜15名
△:劣っている ・・・「良い」又は「ある」が6〜10名
×:大変劣っている・・・「良い」又は「ある」が5名以下
(2) Feeling test method during use 20 panels use samples, and follow the fingers when rinsing during use, and determine the softness in three stages: “good”, “normal” and “bad”, and finish As for the sense of expectation, the judgment was made in three stages, “Yes”, “Normal”, and “None”, and the judgment result was judged by the number of people who answered “Good” or “Yes”.
Judgment criteria are as follows.
◎: Very good ... “Good” or “Yes” is 16 or more people ○: Excellent ... “Good” or “Yes” is 11 to 15 people △: Inferior ... “Good” ”Or“ A ”is 6 to 10 people ×: Very inferior ...“ Good ”or“ A ”is 5 or less
表1〜3に示す処方の毛髪化粧料を常法にて調製し、仕上がり感試験及び感触試験を実施した。評価結果を表1〜3に合わせて示す。 Hair cosmetics having the formulations shown in Tables 1 to 3 were prepared by a conventional method, and finished feeling test and feel test were performed. The evaluation results are shown in Tables 1 to 3.
表1〜3より明らかなように、本発明による毛髪化粧料は比較例の組成物に比べて、優れた性能を示していた。 As is apparent from Tables 1 to 3, the hair cosmetic composition according to the present invention exhibited superior performance as compared with the composition of the comparative example.
以下、本発明毛髪化粧料のその他の処方例を実施例として挙げる。なお、これらの実施例の毛髪化粧料についても、仕上がりのしっとり感、べたつきのなさ、軟らかさ、濯ぎ時の指通りの良さ、柔らかさ、仕上がりへの期待感の各項目を評価したところ、いずれの実施例においても、優れた特性を有しており良好であった。 Hereinafter, other formulation examples of the hair cosmetic composition of the present invention will be given as examples. The hair cosmetics of these examples were evaluated for the moist feeling of finish, non-stickiness, softness, goodness of fingering during rinsing, softness, and expectation for the finish. This example also had excellent characteristics and was good.
実施例23(ヘアコンディショナー)
配合量(%)
(1)PPG−1/PEG−1ステアラミン 1.0
(2)塩化ベヘニルトリメチルアンモニウム 0.5
(3)セトステアリルアルコール 6.5
(4)ベヘニルアルコール 0.5
(5)アモジメチコン 1.0
(6)アミノポリエーテルシリコン 0.5
(7)メチルポリシロキサン(300cs) 1.0
(8)高重合メチルポリシロキサン(50万cs) 3.0
(9)べヘニルPGトリモニウムクロリド 1.0
(10)ステアリルPGトリモニウムクロリド 1.0
(11)コメヌカ油脂肪酸フィトステリル 2.0
(12)乳酸 0.4
(13)パラフィン 1.0
(14)プロピレングリコール 0.5
(15)ソルビトール 3.0
(16)グリセリン 0.5
(17)アンズ核油 0.1
(18)セラミド2 0.1
(19)トウモロコシ由来スフィンゴ脂質 0.1
(20)ヒドロキシエチルセルロース 0.4
(21)フェノキシエタノール 0.2
(22)サリチル酸 0.1
(23)香料 0.5
(24)精製水 全量を100とする
Example 23 (hair conditioner)
Compounding amount (%)
(1) PPG-1 / PEG-1 stearamine 1.0
(2) Behenyltrimethylammonium chloride 0.5
(3) Cetostearyl alcohol 6.5
(4) Behenyl alcohol 0.5
(5) Amodimethicone 1.0
(6) Aminopolyether silicon 0.5
(7) Methyl polysiloxane (300 cs) 1.0
(8) Highly polymerized methylpolysiloxane (500,000 cs) 3.0
(9) Behenyl PG trimonium chloride 1.0
(10) Stearyl PG trimonium chloride 1.0
(11) Rice bran oil fatty acid phytosteryl 2.0
(12) Lactic acid 0.4
(13) Paraffin 1.0
(14) Propylene glycol 0.5
(15) Sorbitol 3.0
(16) Glycerin 0.5
(17) Apricot kernel oil 0.1
(18) Ceramide 2 0.1
(19) Corn-derived sphingolipid 0.1
(20) Hydroxyethyl cellulose 0.4
(21) Phenoxyethanol 0.2
(22) Salicylic acid 0.1
(23) Fragrance 0.5
(24) 100% purified water
(製法)(1)〜(19)を80℃にて均一に混合溶解し、80℃に加温した(24)に(20)〜(22)を分散したものをプロペラで攪拌しながら加え、乳化を行う。徐々に冷却を行い、60℃にて(23)を添加し、室温まで冷却して、ヘアコンディショナーを調製した。 (Production method) (1) to (19) were uniformly mixed and dissolved at 80 ° C, and (24) heated to 80 ° C and (20) to (22) dispersed therein were added while stirring with a propeller. Emulsify. The hair conditioner was prepared by gradually cooling, adding (23) at 60 ° C., and cooling to room temperature.
実施例24(ヘアトリートメント)
配合量(%)
(1)PPG−1/PEG−1ステアラミン 2.0
(2)塩化ベヘニルトリメチルアンモニウム 1.0
(3)セトステアリルアルコール 7.5
(4)ベヘニルアルコール 0.5
(5)アモジメチコン 2.0
(6)アミノポリエーテルシリコン 0.5
(7)メチルポリシロキサン(300cs) 5.0
(8)高重合メチルポリシロキサン(50万cs) 2.0
(9)べヘニルPGトリモニウムクロリド 1.0
(10)ステアリルPGトリモニウムクロリド 1.0
(11)コメヌカ油脂肪酸フィトステリル 3.0
(12)乳酸 0.6
(13)パラフィン 1.0
(14)白色ワセリン 1.0
(15)1,3−ブチレングリコール 3.0
(16)ヒドロキシステアリン酸コレステリル 0.5
(17)セレブロシド 0.1
(18)ヒオウギエキス 0.5
(19)加水分解コムギ末 1.0
(20)LIPIDURE−C(日本油脂社製) 1.0
(21)プロピレングリコール 0.5
(22)ソルビトール 3.0
(23)グリセリン 0.5
(24)アンズ核油 0.1
(25)セラミド2 0.1
(26)トウモロコシ由来スフィンゴ脂質 0.1
(27)ヒドロキシエチルセルロース 0.5
(28)フェノキシエタノール 0.2
(29)サリチル酸 0.1
(30)防腐剤(ケーソンCG) 0.1
(31)香料 0.5
(32)精製水 全量を100とする
Example 24 (hair treatment)
Compounding amount (%)
(1) PPG-1 / PEG-1 stearamine 2.0
(2) Behenyltrimethylammonium chloride 1.0
(3) cetostearyl alcohol 7.5
(4) Behenyl alcohol 0.5
(5) Amodimethicone 2.0
(6) Aminopolyether silicon 0.5
(7) Methyl polysiloxane (300 cs) 5.0
(8) Highly polymerized methylpolysiloxane (500,000 cs) 2.0
(9) Behenyl PG trimonium chloride 1.0
(10) Stearyl PG trimonium chloride 1.0
(11) Rice bran oil fatty acid phytosteryl 3.0
(12) Lactic acid 0.6
(13) Paraffin 1.0
(14) White petrolatum 1.0
(15) 1,3-butylene glycol 3.0
(16) Cholesteryl hydroxystearate 0.5
(17) Cerebroside 0.1
(18) Hinogi extract 0.5
(19) Hydrolyzed wheat powder 1.0
(20) LIPIDURE-C (manufactured by NOF Corporation) 1.0
(21) Propylene glycol 0.5
(22) Sorbitol 3.0
(23) Glycerin 0.5
(24) Apricot kernel oil 0.1
(25) Ceramide 2 0.1
(26) Corn-derived sphingolipid 0.1
(27) Hydroxyethyl cellulose 0.5
(28) Phenoxyethanol 0.2
(29) Salicylic acid 0.1
(30) Preservative (Caisson CG) 0.1
(31) Fragrance 0.5
(32) Total amount of purified water is 100
(製法)(1)〜(16)、(24)〜(26)を80℃にて均一に混合溶解し油相とす
る。(32)に(21)〜(23)及び(27)を60℃にて均一に混合攪拌し水相とする。水相に油相を加えて乳化したのち、(28)及び(29)加えて、ホモミキサーを用いて均一に混合する。混合しながら徐々に冷却を行い、40℃にて(17)〜(20)、(30)(31)を添加し、室温まで冷却して、ヘアトリートメントを調製した。
(Production method) (1) to (16) and (24) to (26) are uniformly mixed and dissolved at 80 ° C. to obtain an oil phase. (32) (21) to (23) and (27) are uniformly mixed and stirred at 60 ° C. to obtain an aqueous phase. After the oil phase is added to the aqueous phase and emulsified, (28) and (29) are added and mixed uniformly using a homomixer. The mixture was gradually cooled while mixing, (17) to (20), (30) and (31) were added at 40 ° C. and cooled to room temperature to prepare a hair treatment.
実施例25(アウトバストリートメント)
配合量(%)
(1)PPG−1/PEG−1ステアラミン 0.5
(2)塩化ステアリルトリメチルアンモニウム 0.5
(3)セトステアリルアルコール 4.0
(4)ベヘニルアルコール 0.5
(5)アモジメチコン 1.0
(6)アミノポリエーテルシリコン 0.5
(7)べヘニルPGトリモニウムクロリド 0.5
(8)ステアリルPGトリモニウムクロリド 0.5
(9)シリコーン水性エマルジョン 2.0
(XS65−B7116、GE東芝シリコン社製)
(10)コメヌカ油脂肪酸フィトステリル 3.0
(11)オレイン酸コレステリル 1.0
(12)1,3−ブチレングリコール 2.0
(13)セバシン酸ジエチル 3.0
(14)海苔タンパク質加水分解物 2.0
(ピュアポルフィラPE、株式会社白子社製)
(15)グリコール酸 0.2
(16)フェノキシエタノール 0.2
(17)香料 微 量
(18)精製水 全量を100とする
Example 25 (out bath treatment)
Compounding amount (%)
(1) PPG-1 / PEG-1 stearamine 0.5
(2) Stearyltrimethylammonium chloride 0.5
(3) Cetostearyl alcohol 4.0
(4) Behenyl alcohol 0.5
(5) Amodimethicone 1.0
(6) Aminopolyether silicon 0.5
(7) Behenyl PG trimonium chloride 0.5
(8) Stearyl PG trimonium chloride 0.5
(9) Silicone aqueous emulsion 2.0
(XS65-B7116, manufactured by GE Toshiba Silicon Corporation)
(10) Rice bran oil fatty acid phytosteryl 3.0
(11) Cholesteryl oleate 1.0
(12) 1,3-butylene glycol 2.0
(13) Diethyl sebacate 3.0
(14) Nori protein hydrolyzate 2.0
(Pure Porphyra PE, manufactured by Shiroko Co., Ltd.)
(15) Glycolic acid 0.2
(16) Phenoxyethanol 0.2
(17) Fragrance fine amount (18) Purified water Total amount is 100
(製法)(1)〜(8)及び(10)〜(13)を80℃にて均一に混合溶解させ、(14)〜(16)及び(18)を70℃にて混合したものを加えて乳化し、ホモミキサーで混合分散を行いながら、60℃にて(9)及び(17)を加え、室温まで冷却して、アウトバストリートメントを調製した。 (Production method) (1) to (8) and (10) to (13) are uniformly mixed and dissolved at 80 ° C., and (14) to (16) and (18) are mixed at 70 ° C. (9) and (17) were added at 60 ° C. while mixing and dispersing with a homomixer, and the mixture was cooled to room temperature to prepare an out bath treatment.
実施例26(ヘアパック)
配合量(%)
(1)PPG−1/PEG−1ステアラミン 2.0
(2)塩化ベヘニルトリメチルアンモニウム 1.0
(3)セトステアリルアルコール 5.0
(4)ベヘニルアルコール 1.0
(5)アモジメチコン 1.0
(6)アミノポリエーテルシリコン 0.5
(7)べヘニルPGトリモニウムクロリド 0.5
(8)ステアリルPGトリモニウムクロリド 0.5
(9)シリコーン水性エマルジョン 5.0
(XS65−B7116、GE東芝シリコン社製)
(10)ヒドロキシウレア 1.0
(11)PG 3.0
(12)セバシン酸ジエチル 1.0
(13)乳酸 0.5
(14)フェノキシエタノール 0.2
(15)香料 0.6
(16)精製水 全量を100とする
Example 26 (hair pack)
Compounding amount (%)
(1) PPG-1 / PEG-1 stearamine 2.0
(2) Behenyltrimethylammonium chloride 1.0
(3) cetostearyl alcohol 5.0
(4) Behenyl alcohol 1.0
(5) Amodimethicone 1.0
(6) Aminopolyether silicon 0.5
(7) Behenyl PG trimonium chloride 0.5
(8) Stearyl PG trimonium chloride 0.5
(9) Silicone aqueous emulsion 5.0
(XS65-B7116, manufactured by GE Toshiba Silicon Corporation)
(10) Hydroxyurea 1.0
(11) PG 3.0
(12) Diethyl sebacate 1.0
(13) Lactic acid 0.5
(14) Phenoxyethanol 0.2
(15) Fragrance 0.6
(16) Total amount of purified water is 100
(製法)(1)〜(8)を80℃にて均一に混合溶解させ、(11)〜(16)を50℃にて混合したものを加えて乳化し、ホモミキサーで混合分散を行いながら、50℃で(9)〜(10)を加えて、室温まで冷却して、ヘアパックを調製した。 (Manufacturing method) (1) to (8) are uniformly mixed and dissolved at 80 ° C, and (11) to (16) mixed at 50 ° C are added and emulsified, and mixed and dispersed with a homomixer. (9) to (10) were added at 50 ° C. and cooled to room temperature to prepare a hair pack.
参考例27(トリートメントフォーム)
配合量(%)
(1)PPG−1/PEG−1ステアラミン 0.3
(2)塩化ステアリルトリメチルアンモニウム 0.2
(3)セトステアリルアルコール 1.0
(4)ベヘニルアルコール 0.1
(5)アミノポリエーテルシリコン 0.1
(6)べヘニルPGトリモニウムクロリド 0.2
(7)メチルポリシロキサン(300cs) 0.5
(8)コメヌカ油脂肪酸フィトステリル 1.0
(9)マカデミアナッツ油脂肪酸コレステリル 0.2
(10)セラミド1・セラミド5混合物(1:1) 0.1
(11)乳酸 0.2
(12)ポリオキシエチレン(20)セチルエーテル 1.0
(13)ポリオキシエチレン(60)硬化ヒマシ油 0.5
(14)1,3−ブチレングリコール 0.5
(15)フェノキシエタノール 0.5
(16)精製水 全量を100とする
Reference Example 27 (treatment form)
Compounding amount (%)
(1) PPG-1 / PEG-1 stearamine 0.3
(2) Stearyltrimethylammonium chloride 0.2
(3) cetostearyl alcohol 1.0
(4) Behenyl alcohol 0.1
(5) Amino polyether silicon 0.1
(6) Behenyl PG trimonium chloride 0.2
(7) Methyl polysiloxane (300 cs) 0.5
(8) Rice bran oil fatty acid phytosteryl 1.0
(9) Macadamia nut oil fatty acid cholesteryl 0.2
(10) Ceramide 1 / ceramide 5 mixture (1: 1) 0.1
(11) Lactic acid 0.2
(12) Polyoxyethylene (20) cetyl ether 1.0
(13) Polyoxyethylene (60) hydrogenated castor oil 0.5
(14) 1,3-butylene glycol 0.5
(15) Phenoxyethanol 0.5
(16) Total amount of purified water is 100
(製法)(1)〜(13)を80℃にて均一に混合溶解し、80℃に加温した(16)にプロペラで攪拌しながら加えて乳化する。徐々に冷却を行い、60℃にて(14)及び(15)を添加し、室温まで冷却して、原液とした。次にエアゾール耐圧容器に原液:LPGガスを92:8の比率で充填し、トリートメントフォームを調製した。 (Production Method) (1) to (13) are uniformly mixed and dissolved at 80 ° C., and added to (16) heated to 80 ° C. while stirring with a propeller to emulsify. The solution was gradually cooled, (14) and (15) were added at 60 ° C., and cooled to room temperature to obtain a stock solution. Next, the aerosol pressure vessel was filled with stock solution: LPG gas at a ratio of 92: 8 to prepare a treatment foam.
以上記載のごとく、本発明は、毛髪にべたつきをあたえることなく、柔らかでしっとりとした仕上がり感を与える事ができ、かつ、濯ぎ時に指通りよく柔らかで、仕上がりへの期待感を与える毛髪化粧料を提供することができる。 As described above, the present invention is a hair cosmetic that can give a soft and moist finish without giving the hair stickiness, and is soft and easy to follow when rinsing, giving a sense of expectation to the finish. Can be provided.
Claims (2)
(A)PPG−1/PEG−1ステアラミン及びPPG−1/PEG−1ベヘナミンから選ばれる1種又は2種
(B)下記一般式(II)で表されるアルキル型カチオン
(式中、R4〜R7のうちいずれか1個又は2個は炭素数8〜24のアルキル基、アルケニル基、ヒドロキシアルキル基又はヒドロキシアルケニル基であり、残りは、炭素数1〜3のアルキル基もしくはヒドロキシアルキル基又はベンジル基を表し、Yはハロゲン原子又は炭素数1〜3のアルキル硫酸基を示す。)
(C)炭素数14〜24の長鎖のアルキル基を有する高級アルコール
(D)アミノエチルアミノプロピルメチコン/ジメチコン共重合体、アミノプロピルジメチコン、高重合アミノプロピルジメチコン、アモジメチコン、及びアミノポリエーテルシリコンから選ばれる少なくとも1種のシリコーン誘導体
(E)25℃での動粘度が50万cs〜3000万csのメチルポリシロキサン
(F)ベヘニルPGトリモニウムクロリド A hair cosmetic comprising the following components (A) to ( F ).
(A) One or two selected from PPG-1 / PEG-1 stearamine and PPG-1 / PEG-1 behenamine (B) Alkyl cation represented by the following general formula (II)
(In the formula, any one or two of R 4 to R 7 are an alkyl group, an alkenyl group, a hydroxyalkyl group or a hydroxyalkenyl group having 8 to 24 carbon atoms, and the rest are ones having 1 to 3 carbon atoms. Represents an alkyl group, a hydroxyalkyl group or a benzyl group, and Y represents a halogen atom or an alkyl sulfate group having 1 to 3 carbon atoms.)
(C) a higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms (D) aminoethylaminopropyl methicone / dimethicone copolymer, aminopropyl dimethicone, highly polymerized aminopropyl dimethicone, amodimethicone, and amino polyether silicon At least one silicone derivative (E) selected from: methylpolysiloxane having a kinematic viscosity at 25 ° C. of 500,000 cs to 30 million cs
(F) Behenyl PG trimonium chloride
The hair cosmetic according to claim 1, wherein the component (D) is amino polyether silicon.
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JP6538346B2 (en) * | 2014-12-22 | 2019-07-03 | クラシエホームプロダクツ株式会社 | Hair cosmetics |
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