JP6538346B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
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- JP6538346B2 JP6538346B2 JP2014259112A JP2014259112A JP6538346B2 JP 6538346 B2 JP6538346 B2 JP 6538346B2 JP 2014259112 A JP2014259112 A JP 2014259112A JP 2014259112 A JP2014259112 A JP 2014259112A JP 6538346 B2 JP6538346 B2 JP 6538346B2
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- peg
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- hair
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- stearamine
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- 239000003676 hair preparation Substances 0.000 title claims description 6
- -1 Fatty acid amine Chemical class 0.000 claims description 21
- 229920001296 polysiloxane Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 2
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 2
- 150000004670 unsaturated fatty acids Chemical group 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 101000611641 Rattus norvegicus Protein phosphatase 1 regulatory subunit 15A Proteins 0.000 description 26
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 26
- 239000002537 cosmetic Substances 0.000 description 13
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 13
- ZENZJGDPWWLORF-UHFFFAOYSA-N (Z)-9-Octadecenal Natural products CCCCCCCCC=CCCCCCCCC=O ZENZJGDPWWLORF-UHFFFAOYSA-N 0.000 description 12
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 12
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 11
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 11
- FWWQKRXKHIRPJY-UHFFFAOYSA-N octadecyl aldehyde Natural products CCCCCCCCCCCCCCCCCC=O FWWQKRXKHIRPJY-UHFFFAOYSA-N 0.000 description 11
- 229940105131 stearamine Drugs 0.000 description 11
- 238000012360 testing method Methods 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 6
- DENWXVJCXRNUNB-UHFFFAOYSA-N 2-[dodecyl-[2-(2-hydroxyethoxy)ethyl]amino]ethanol Chemical compound CCCCCCCCCCCCN(CCO)CCOCCO DENWXVJCXRNUNB-UHFFFAOYSA-N 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- XLQKQWFHQUWKPL-KTKRTIGZSA-N 2-[2-(2-hydroxyethoxy)ethyl-[(z)-octadec-9-enyl]amino]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCN(CCO)CCOCCO XLQKQWFHQUWKPL-KTKRTIGZSA-N 0.000 description 4
- ODBCUKKSMRQNCL-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethyl-octadecylamino]ethanol Chemical compound CCCCCCCCCCCCCCCCCCN(CCO)CCOCCO ODBCUKKSMRQNCL-UHFFFAOYSA-N 0.000 description 4
- WOGKWSUSGNOHRJ-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethyl-tetradecylamino]ethanol Chemical compound CCCCCCCCCCCCCCN(CCO)CCOCCO WOGKWSUSGNOHRJ-UHFFFAOYSA-N 0.000 description 4
- NDLNTMNRNCENRZ-UHFFFAOYSA-N 2-[2-hydroxyethyl(octadecyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCCCN(CCO)CCO NDLNTMNRNCENRZ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- QMGAJHYFGBHHRR-UHFFFAOYSA-M trimethyl(3-octadecoxypropyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCOCCC[N+](C)(C)C QMGAJHYFGBHHRR-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical compound CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 229960000735 docosanol Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- AKWFJQNBHYVIPY-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO AKWFJQNBHYVIPY-UHFFFAOYSA-N 0.000 description 1
- PNLGRMWXGJVEAV-UHFFFAOYSA-N 2-[hexadecyl-[2-(2-hydroxyethoxy)ethyl]amino]ethanol Chemical compound CCCCCCCCCCCCCCCCN(CCO)CCOCCO PNLGRMWXGJVEAV-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- NBDYSLCMCUDINP-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)N(C)CCC(O)=O NBDYSLCMCUDINP-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- VSNHCAURESNICA-UHFFFAOYSA-N Hydroxyurea Chemical compound NC(=O)NO VSNHCAURESNICA-UHFFFAOYSA-N 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-N L-arginine Chemical compound OC(=O)[C@@H](N)CCCN=C(N)N ODKSFYDXXFIFQN-BYPYZUCNSA-N 0.000 description 1
- 229930064664 L-arginine Natural products 0.000 description 1
- 235000014852 L-arginine Nutrition 0.000 description 1
- 125000000010 L-asparaginyl group Chemical class O=C([*])[C@](N([H])[H])([H])C([H])([H])C(=O)N([H])[H] 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000004473 Threonine Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
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- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- XMXOIHIZTOVVFB-JIZZDEOASA-L disodium;(2s)-2-aminobutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CC([O-])=O XMXOIHIZTOVVFB-JIZZDEOASA-L 0.000 description 1
- 229950010030 dl-alanine Drugs 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
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- 238000011156 evaluation Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- 229960002449 glycine Drugs 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
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- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
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- 235000014655 lactic acid Nutrition 0.000 description 1
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- 235000019388 lanolin Nutrition 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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- KSCKTBJJRVPGKM-UHFFFAOYSA-N octan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-] KSCKTBJJRVPGKM-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
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- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
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- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 229960002898 threonine Drugs 0.000 description 1
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- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Description
本発明は、毛髪化粧料に関し、詳しくは、すすぎ時に指通りよくやわらかで、かつ毛髪にべたつきをあたえることなく、やわらかでしっとりとまとまる仕上がり感を与える毛髪化粧料に関する。 The present invention relates to a hair cosmetic, and more particularly, to a hair cosmetic which gives a feeling of softness and moistness without being sticky as it is finger-washed well when rinsing.
女性のヘアスタイルの流行に伴って、求められる髪の仕上がりや感触も並行して変化している。最近では、シャギーやレイヤーカットなどの毛先のボリュームを落としたヘアスタイルが一般的であるが、一方では、カラーリングやパーマ等の施術により、パサツキや髪の硬さが問題となっている。そのような背景から、仕上がりとして、しっとりまとまりながら、べたつかず、やわらかな仕上がり感が求められている。また、カラーリングやパーマ等の施術によって傷んだ髪は、ヘアトリートメントのすすぎ時においても、絡みや引っ掛かりなど不快な感触につながる。このすすぎ時の不快な感触は、仕上がり感の満足度にも大きな影響を与える。従って、満足度の高い仕上がりをえる為には、柔らかでしっとりまとまり、かつべたつかない仕上がりでありながら、さらにヘアトリートメントのすすぎ時も、柔らかで指通り良い使用感が望まれる。ヘアトリートメント等の毛髪化粧料においては、従来、毛髪を柔軟にして櫛通りをよくする目的で、カチオン性界面活性剤やシリコーン等の配合、或いは、しっとりとした感触を与えるために液状や固形状の油剤の配合が試みられているが、これら従来の技術では、近年のヘアスタイルにおいて要求されているニーズを満足させることは困難であり、仕上がりはしっとりまとまりながらべた付かずやわらかで、かつ使用時は、すすぎ時もやわらかで指通りの良い使用感を両立することは課題であった。 With the trend of women's hairstyles, the finish and feel of the required hair are changing in parallel. In recent years, although the hairstyle which dropped the volume of the hair tips, such as shaggy and a layer cut, is common, on the other hand, the treatment of coloring etc. and a perm, the hardness of the pasatsuki and the hair has become a problem. From such a background, as a finish, while feeling moist and non-greasy, a soft finish feeling is required. In addition, hair damaged by treatments such as coloring and perming leads to an unpleasant feeling such as entanglement and sticking even when rinsing hair treatment. The unpleasant feel at the time of rinsing greatly affects the degree of satisfaction with the finish. Therefore, in order to obtain a highly satisfactory finish, it is desirable to have a soft, finger-like good feeling of use while rinsing the hair treatment while being soft and moist, and not sticky. In hair cosmetic products such as hair treatments, conventionally, in order to soften the hair and improve combing, a composition such as a cationic surfactant or silicone, or a liquid or solid to give a moist feeling In these conventional techniques, it is difficult to satisfy the needs required in recent hairstyles, and the finish is soft and non-sticky and soft. At the same time, it was a challenge to have a good feeling of use that is soft and good at the time of rinsing.
これらの課題を解決する方法として、例えば、脂肪酸アミドアミン化合物やヒドロキシエーテルアミン化合物を用いることにより、または各種シリコーンを配合して毛髪に滑らかさや柔らかさを付与する毛髪化粧料（例えば、特許文献１〜５参照）が開示されている。更にはカチオン性界面活性剤の研究が進み、ヒドロキシエーテル型カチオンのような構造を有するカチオンに、エーテル型アミンや分岐脂肪酸を配合してべたつきや重さを与ることなくしなやかでしっとりした仕上がり感を与える毛髪化粧料（例えば特許文献６、７参照）が開示されるなど、毛髪にしなやかさを与える技術は年々進歩しているものの、毛髪化粧料の使用感、特にべたつきや重さを低減したいという要求も拡大し続けており、更なる進歩が望まれている。 As a method for solving these problems, for example, a hair cosmetic which imparts smoothness and softness to hair by using a fatty acid amidoamine compound or a hydroxyetheramine compound, or blending various silicones (for example, Patent Documents 1 to 4) 5) is disclosed. Furthermore, research on cationic surfactants has progressed, and ether type amines and branched fatty acids are mixed with cations having a structure like hydroxyether type cations to give a soft and moist finish without giving stickiness and weight. Although techniques for imparting softness to hair have been advanced year by year, such as hair cosmetics that give hair (see, for example, Patent Documents 6 and 7), it is desirable to reduce the feeling of use of hair cosmetics, in particular stickiness and weight. The demand is also expanding, and further progress is desired.
また、（非特許文献１、２）ＰＰＧ−１／ＰＥＧ−１ステアラミンを、シリコーン類、カチオン活性剤と併用し配合する事によって、塗布時に髪になじみやすく、乾燥後にまで優れたコンディショニング効果を維持する技術が提案されているが、柔らかさを付与しながら乾燥後のしっとりまとまる仕上がり感において十分ではない。また、４級アルキル型カチオンと組み合わせることにより一定の改善がなされているが（特許文献８）まとまりの点でまだ十分に消費者を満足させていない。 In addition, (non-patent documents 1 and 2) PPG-1 / PEG-1 stearamine is used in combination with silicones and a cationic surfactant to make it easy to conform to the hair at the time of application and maintain excellent conditioning effect until after drying Technology is proposed, but it is not sufficient in the feeling of finish that is moist and dry after drying while imparting softness. Further, although a certain improvement is achieved by combining with the quaternary alkyl type cation (Patent Document 8), the consumer has not yet been satisfied sufficiently in terms of the unity.
本発明の目的は、すすぎ時に指通りよくやわらかで、かつ毛髪にべたつきをあたえることなく、やわらかでしっとりとまとまる仕上がり感を与える毛髪化粧料を提供することにある。 An object of the present invention is to provide a hair cosmetic which gives a soft and moist finish feeling without being sticky to the hair as it is finger softly when rinsing.
本発明者は、このような状況に鑑み、鋭意研究した結果、特定の脂肪酸アミンと、特定のカチオン性界面活性剤と、アミノポリエーテル変性シリコーンを含有する毛髪化粧料が、上記課題を解決することを見出し、本発明を完成するに至った。 In view of such circumstances, the present inventors have intensively studied and as a result, a hair cosmetic containing a specific fatty acid amine, a specific cationic surfactant, and an aminopolyether-modified silicone solves the above problems. The present invention has been completed.
本発明の毛髪化粧料は、すすぎ時に指通りよくやわらかで、かつ毛髪にべたつきをあたえることなく、やわらかでしっとりとまとまる仕上がり感を与える効果を付与することができる。 The hair cosmetic composition of the present invention can impart an effect of giving a soft and moist finish feeling without being sticky and being soft and soft as a finger rinse.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明における（Ａ）成分の脂肪酸アミンは、例えば下記一般式（１）で表される。 The fatty acid amine of the component (A) in the present invention is represented, for example, by the following general formula (1).
このような脂肪酸アミンを具体的に示すとＰＰＧ−１／ＰＥＧ−１ラウラミン、ＰＰＧ−１／ＰＥＧ−１ミリスタミン、ＰＰＧ−１／ＰＥＧ−１セタミン、ＰＰＧ−１／ＰＥＧ−
１ステアラミン、ＰＰＧ−１／ＰＥＧ−１アラカミン、ＰＰＧ−１／ＰＥＧ−１ベヘナミン、ＰＰＧ−１／ＰＥＧ−１カルナバミン、ＰＰＧ−１／ＰＥＧ−１オレアミン、ＰＰＧ−１／ＰＥＧ−１エライザミン、ＰＰＧ−１／ＰＥＧ−１リノラミン、ＰＰＧ−１／ＰＥＧ−１リノレナル、ＰＰＧ−１／ＰＥＧ−２ラウラミン、ＰＰＧ−１／ＰＥＧ−２ラウラミン、ＰＰＧ−１／ＰＥＧ−２ミリスタミン、ＰＰＧ−１／ＰＥＧ−２セタミン、ＰＰＧ−１／ＰＥＧ−２ステアラミン、ＰＰＧ−１／ＰＥＧ−２アラカミン、ＰＰＧ−１／ＰＥＧ−２ベヘナミン、ＰＰＧ−１／ＰＥＧ−２カルナバミン、ＰＰＧ−１／ＰＥＧ−２オレアミン、ＰＰＧ−１／ＰＥＧ−２エライザミン、ＰＰＧ−１／ＰＥＧ−２リノラミン、ＰＰＧ−１／ＰＥＧ−２リノレナル、ＰＰＧ−１／ＰＥＧ−３ラウラミン、ＰＰＧ−１／ＰＥＧ−３ラウラミン、ＰＰＧ−１／ＰＥＧ−３ミリスタミン、ＰＰＧ−１／ＰＥＧ−３セタミン、ＰＰＧ−１／ＰＥＧ−３ステアラミン、ＰＰＧ−１／ＰＥＧ−３アラカミン、ＰＰＧ−１／ＰＥＧ−３ベヘナミン、ＰＰＧ−１／ＰＥＧ−３カルナバミン、ＰＰＧ−１／ＰＥＧ−３オレアミン、ＰＰＧ−１／ＰＥＧ−３エライザミン、ＰＰＧ−１／ＰＥＧ−３リノラミン、ＰＰＧ−１／ＰＥＧ−３リノレナル、ＰＰＧ−２／ＰＥＧ−１ラウラミン、ＰＰＧ−２／ＰＥＧ−１ミリスタミン、ＰＰＧ−２／ＰＥＧ−１セタミン、ＰＰＧ−２／ＰＥＧ−１ステアラミン、ＰＰＧ−２／ＰＥＧ−１アラカミン、ＰＰＧ−２／ＰＥＧ−１ベヘナミン、ＰＰＧ−２／ＰＥＧ−１カルナバミン、ＰＰＧ−２／ＰＥＧ−１オレアミン、ＰＰＧ−２／ＰＥＧ−１エライザミン、ＰＰＧ−２／ＰＥＧ−１リノラミン、ＰＰＧ−２／ＰＥＧ−１リノレナル、ＰＰＧ−２／ＰＥＧ−２ラウラミン、ＰＰＧ−２／ＰＥＧ−２ミリスタミン、ＰＰＧ−２／ＰＥＧ−２セタミン、ＰＰＧ−２／ＰＥＧ−２ステアラミン、ＰＰＧ−２／ＰＥＧ−２アラカミン、ＰＰＧ−２／ＰＥＧ−２ベヘナミン、ＰＰＧ−２／ＰＥＧ−２カルナバミン、ＰＰＧ−２／ＰＥＧ−２オレアミン、ＰＰＧ−２／ＰＥＧ−２エライザミン、ＰＰＧ−２／ＰＥＧ−２リノラミン、ＰＰＧ−２／ＰＥＧ−２リノレナル、ＰＰＧ−２／ＰＥＧ−３ラウラミン、ＰＰＧ−２／ＰＥＧ−３ミリスタミン、ＰＰＧ−２／ＰＥＧ−３セタミン、ＰＰＧ−２／ＰＥＧ−３ステアラミン、ＰＰＧ−２／ＰＥＧ−３アラカミン、ＰＰＧ−２／ＰＥＧ−３ベヘナミン、ＰＰＧ−２／ＰＥＧ−３カルナバミン、ＰＰＧ−２／ＰＥＧ−３オレアミン、ＰＰＧ−２／ＰＥＧ−３エライザミン、ＰＰＧ−２／ＰＥＧ−３リノラミン、ＰＰＧ−２／ＰＥＧ−３リノレナル、ＰＰＧ−３／ＰＥＧ−１ラウラミン、ＰＰＧ−３／ＰＥＧ−１ミリスタミン、ＰＰＧ−３／ＰＥＧ−１セタミン、ＰＰＧ−３／ＰＥＧ−１ステアラミン、ＰＰＧ−３／ＰＥＧ−１アラカミン、ＰＰＧ−３／ＰＥＧ−１ベヘナミン、ＰＰＧ−３／ＰＥＧ−１カルナバミン、ＰＰＧ−３／ＰＥＧ−１オレアミン、ＰＰＧ−３／ＰＥＧ−１エライザミン、ＰＰＧ−３／ＰＥＧ−１リノラミン、ＰＰＧ−３／ＰＥＧ−１リノレナル、ＰＰＧ−３／ＰＥＧ−２ラウラミン、ＰＰＧ−３／ＰＥＧ−２ミリスタミン、ＰＰＧ−３／ＰＥＧ−２セタミン、ＰＰＧ−３／ＰＥＧ−２ステアラミン、ＰＰＧ−３／ＰＥＧ−２アラカミン、ＰＰＧ−３／ＰＥＧ−２ベヘナミン、ＰＰＧ−３／ＰＥＧ−２カルナバミン、ＰＰＧ−３／ＰＥＧ−２オレアミン、ＰＰＧ−３／ＰＥＧ−２エライザミン、ＰＰＧ−３／ＰＥＧ−２リノラミン、ＰＰＧ−３／ＰＥＧ−２リノレナル、ＰＰＧ−３／ＰＥＧ−３ラウラミン、ＰＰＧ−３／ＰＥＧ−３ミリスタミン、ＰＰＧ−３／ＰＥＧ−３セタミン、ＰＰＧ−３／ＰＥＧ−３ステアラミン、ＰＰＧ−３／ＰＥＧ−３アラカミン、ＰＰＧ−３／ＰＥＧ−３ベヘナミン、ＰＰＧ−３／ＰＥＧ−３カルナバミン、ＰＰＧ−３／ＰＥＧ−３オレアミン、ＰＰＧ−３／ＰＥＧ−３エライザミン、ＰＰＧ−３／ＰＥＧ−３リノラミン、ＰＰＧ−３／ＰＥＧ−３リノレナル、ＰＰＧ−１ラウラミン、ＰＰＧ−１ミリスタミン、ＰＰＧ−１セタミン、ＰＰＧ−１ステアラミン、ＰＰＧ−１アラカミン、ＰＰＧ−１ベヘナミン、ＰＰＧ−１カルナバミン、ＰＰＧ−１オレアミン、ＰＰＧ−１エライザミン、ＰＰＧ−１リノラミン、ＰＰＧ−１リノレナル、ＰＰＧ−２ラウラミン、ＰＰＧ−２ミリスタミン、ＰＰＧ−２セタミン、ＰＰＧ−２ステアラミン、ＰＰＧ−２アラカミン、ＰＰＧ−２ベヘナミン、ＰＰＧ−２カルナバミン、ＰＰＧ−２オレアミン、ＰＰＧ−２エライザミン、ＰＰＧ−２リノラミン、ＰＰＧ−２リノレナル、ＰＰＧ−３ラウラミン、ＰＰＧ−３ミリスタミン、ＰＰＧ−３セタミン、ＰＰＧ−３ステアラミン、ＰＰＧ−３アラカミン、ＰＰＧ−３ベヘナミン、ＰＰ
Ｇ−３カルナバミン、ＰＰＧ−３オレアミン、ＰＰＧ−３エライザミン、ＰＰＧ−３リノラミン、ＰＰＧ−３リノレナル、ＰＥＧ−１ラウラミン、ＰＥＧ−１ミリスタミン、ＰＥＧ−１セタミン、ＰＥＧ−１ステアラミン、ＰＥＧ−１アラカミン、ＰＥＧ−１ベヘナミン、ＰＥＧ−１カルナバミン、ＰＥＧ−１オレアミン、ＰＥＧ−１エライザミン、ＰＥＧ−１リノラミン、ＰＥＧ−１リノレナル、ＰＥＧ−２ラウラミン、ＰＥＧ−２ミリスタミン、ＰＥＧ−２セタミン、ＰＥＧ−２ステアラミン、ＰＥＧ−２アラカミン、ＰＥＧ−２ベヘナミン、ＰＥＧ−２カルナバミン、ＰＥＧ−２オレアミン、ＰＥＧ−２エライザミン、ＰＥＧ−２リノラミン、ＰＥＧ−２リノレナル、ＰＥＧ−３ラウラミン、ＰＥＧ−３ミリスタミン、ＰＥＧ−３セタミン、ＰＥＧ−３ステアラミン、ＰＥＧ−３アラカミン、ＰＥＧ−３ベヘナミン、ＰＥＧ−３カルナバミン、ＰＥＧ−３オレアミン、ＰＥＧ−３エライザミン、ＰＥＧ−３リノラミン、ＰＥＧ−３リノレナル、ラウラミン、ミリスタミン、セタミン、ステアラミン、アラカミン、ベヘナミン、カルナバミン、オレアミン、エライザミン、リノラミン、リノレナル等が挙げられる。
Specific examples of such fatty acid amines include PPG-1 / PEG-1 lauramine, PPG-1 / PEG-1 myristamine, PPG-1 / PEG-1 cetamine, PPG-1 / PEG-
1 stearamine, PPG-1 / PEG-1 aracamine, PPG-1 / PEG-1 behenamine, PPG-1 / PEG-1 carnabamine, PPG-1 / PEG-1 oleamine, PPG-1 / PEG-1 elizamin, PPG- 1 / PEG-1 linalamine, PPG-1 / PEG-1 linolenal, PPG-1 / PEG-2 lauramine, PPG-1 / PEG-2 lauramine, PPG-1 / PEG-2 myristamine, PPG-1 / PEG-2 Cetamine, PPG-1 / PEG-2 stearamine, PPG-1 / PEG-2 alacamine, PPG-1 / PEG-2 behenamine, PPG-1 / PEG-2 carnabamine, PPG-1 / PEG-2 oleamine, PPG-1 / PEG-2 Elizamin, PPG-1 / PEG-2 Linolamine, PPG-1 / PEG-2 Linole , PPG-1 / PEG-3 lauramine, PPG-1 / PEG-3 lauramine, PPG-1 / PEG-3 myristamine, PPG-1 / PEG-3 cetamine, PPG-1 / PEG-3 stearamine, PPG-1 / PEG-3 aracamine, PPG-1 / PEG-3 behenamine, PPG-1 / PEG-3 carnabamine, PPG-1 / PEG-3 oleamine, PPG-1 / PEG-3 elysamine, PPG-1 / PEG-3 linalamine , PPG-1 / PEG-3 linolenal, PPG-2 / PEG-1 lauramine, PPG-2 / PEG-1 myristamine, PPG-2 / PEG-1 cetamine, PPG-2 / PEG-1 stearamine, PPG-2 / PEG-1 aracamine, PPG-2 / PEG-1 behenamine, PPG-2 / PEG-1 carnabamine, PP -2 / PEG-1 oleamine, PPG-2 / PEG-1 elysamine, PPG-2 / PEG-1 linalamine, PPG-2 / PEG-1 linolenal, PPG-2 / PEG-2 lauramine, PPG-2 / PEG- 2 myristamine, PPG-2 / PEG-2 setamine, PPG-2 / PEG-2 stearamine, PPG-2 / PEG-2 aracamine, PPG-2 / PEG-2 behenamine, PPG-2 / PEG-2 carnabamine, PPG- 2 / PEG-2 oleamine, PPG-2 / PEG-2 elysamine, PPG-2 / PEG-2 linalamine, PPG-2 / PEG-2 linolenal, PPG-2 / PEG-3 lauramine, PPG-2 / PEG-3 Myristamine, PPG-2 / PEG-3 sethamine, PPG-2 / PEG-3 stearamine, PPG-2 / PE G-3 aracamine, PPG-2 / PEG-3 behenamine, PPG-2 / PEG-3 carnabamine, PPG-2 / PEG-3 oleamine, PPG-2 / PEG-3 elysamine, PPG-2 / PEG-3 linalamine, PPG-2 / PEG-3 linolenal, PPG-3 / PEG-1 lauramine, PPG-3 / PEG-1 myristamine, PPG-3 / PEG-1 cetamine, PPG-3 / PEG-1 stearamine, PPG-3 / PEG -1 aracamine, PPG-3 / PEG-1 behenamine, PPG-3 / PEG-1 carnabamine, PPG-3 / PEG-1 oleamine, PPG-3 / PEG-1 elysamine, PPG-3 / PEG-1 linalamine, PPG -3 / PEG-1 linolenal, PPG-3 / PEG-2 lauramine, PPG-3 / PEG-2 milli Tamine, PPG-3 / PEG-2 setamine, PPG-3 / PEG-2 stearamine, PPG-3 / PEG-2 aracamine, PPG-3 / PEG-2 behenamine, PPG-3 / PEG-2 carnabamine, PPG-3 / PEG-2 oleamine, PPG-3 / PEG-2 elysamine, PPG-3 / PEG-2 linalamine, PPG-3 / PEG-2 linolenal, PPG-3 / PEG-3 lauramine, PPG-3 / PEG-3 myristamine , PPG-3 / PEG-3 setamine, PPG-3 / PEG-3 stearamine, PPG-3 / PEG-3 aracamine, PPG-3 / PEG-3 behenamine, PPG-3 / PEG-3 carnabamine, PPG-3 / PEG-3 oleamine, PPG-3 / PEG-3 elysamine, PPG-3 / PEG-3 linalamine, PG-3 / PEG-3 linolenal, PPG-1 lauramine, PPG-1 myristamine, PPG-1 cetamine, PPG-1 stearamine, PPG-1 alacamine, PPG-1 behenamine, PPG-1 carnabamine, PPG-1 oleamine, PPG -1 Elisamin, PPG-1 linalamine, PPG-1 linolenal, PPG-2 lauramine, PPG-2 myristamine, PPG-2 cetamine, PPG-2 stearamine, PPG-2 aracamine, PPG-2 behenamine, PPG-2 carnabamine, PPG -2 oleamine, PPG-2 elysamine, PPG-2 linalamine, PPG-2 linolenal, PPG-3 lauramine, PPG-3 myristamine, PPG-3 cetamine, PPG-3 stearamine, PPG-3 aracamine, PPG-3 behenamine, PP
G-3 carnabamine, PPG-3 oleamine, PPG-3 elysamine, PPG-3 linalamine, PPG-3 linolenal, PEG-1 lauramine, PEG-1 myristamine, PEG-1 cetamine, PEG-1 stearamine, PEG-1 aracamine, PEG-1 Behenamine, PEG-1 Carnabamine, PEG-1 Oleamine, PEG-1 Elizamin, PEG-1 Linalamine, PEG-1 Linolenal, PEG-2 Lauramine, PEG-2 Myristamine, PEG-2 Cetamine, PEG-2 Stearamine, PEG-2 aracamine, PEG-2 behenamine, PEG-2 carnabamine, PEG-2 oleamine, PEG-2 elysamine, PEG-2 linalamine, PEG-2 linoleal, PEG-3 lauramine, PEG-3 myristamine, PEG-3 seta , PEG-3 stearamine, PEG-3 aracamine, PEG-3 behenamine, PEG-3 carnabamine, PEG-3 oleamine, PEG-3 elyamine, PEG-3 linalamine, PEG-3 linoleal, lauramine, myristamine, cetamine, stearamine, Alacamine, behenamine, carnabamine, oleamine, elizamin, linalamine, linolenal etc. may be mentioned.
これらの中でも、ａ≠０、ｂ≠０のものが好ましく、特にＲ１が炭素数１８のステアリル基、ａ＝１、ｂ＝１である、ＰＰＧ−１／ＰＥＧ−１ステアラミンと、Ｒ１が炭素数２２のベヘニル基、ａ＝１、ｂ＝１である、ＰＰＧ−１／ＰＥＧ−１ベヘナミンが特に好ましい。 Among these, a ≠ 0, b is preferably a ≠ 0, in particular R 1 is stearyl group having 18 carbon atoms, an a = 1, b = 1, and PPG-1 / PEG-1 stearamine, R 1 is Particularly preferred is PPG-1 / PEG-1 behenamine in which the C22 behenyl group, a = 1, b = 1.
本発明では、これらの脂肪酸アミンの中から１種単独又は２種以上を任意に組み合わせて用いることができ、その配合量は、好ましくは０．１〜１０質量％（以下、特に記載のあるもの以外は、質量％を単に「％」で示す）、更に好ましくは、０．５〜５％の範囲である。この配合量の範囲であれば、すすぎ時に指通りよくやわらかで、かつ毛髪にべたつきをあたえることなく、やわらかでしっとりとまとまる仕上がり感を与えることができるため好ましい。 In the present invention, one of these fatty acid amines may be used alone or in combination of two or more, and the compounding amount thereof is preferably 0.1 to 10% by mass (hereinafter, particularly described) The mass% is simply indicated by "%" except for the above, more preferably in the range of 0.5 to 5%. If it is in the range of this compounding amount, it is preferable because it can be soft and soft as a finger when rinsing and can give a soft and moist feeling of finish without giving stickiness to hair.
本発明において、（Ｂ）エーテル型カチオンは、下記一般式（２）
Ｒ4−Ｏ−（ＣＨ２）ｎ−Ｎ（Ｒ5）３・Ｘ ・・・（２）
（式中、Ｒ4は、直鎖又は分岐した炭素数１２〜２２の飽和もしくは不飽和脂肪酸残基、Ｒ5は炭素数１〜３のアルキル基、ｎは１〜５の整数、Ｘはハロゲン原子を示す。）で表され、具体例で示すとラウロキシプロピルトリモニウムクロリド、ミリスチロキシプロピルトリモニウムクロリド、セチロキシプロピルトリモニウムクロリド、ステアロキシプロピルトリモニウムクロリド、ベヘニロキシプロピルトリモニウムクロリド、ラウロキシプロピルトリモニウムブロミド、ミリスチロキシプロピルトリモニウムブロミド、セチロキシプロピルトリモニウムブロミド、ステアロキシプロピルトリモニウムブロミド、ベヘニロキシプロピルトリモニウムブロミド等が挙げられる。
In the present invention, the (B) ether type cation has the following general formula (2)
R 4 -O- (CH 2 ) n -N (R 5 ) 3 · X (2)
(Wherein, R 4 is a linear or branched saturated or unsaturated fatty acid residue having 12 to 22 carbon atoms, R 5 is an alkyl group having 1 to 3 carbon atoms, n is an integer of 1 to 5 and X is a halogen Atoms are shown), and specific examples thereof show lauroxypropyltrimonium chloride, myristyloxypropyltrimonium chloride, cetyloxypropyltrimonium chloride, stearoxypropyltrimonium chloride, behenyloxypropyltrimonium chloride And lauroxypropyltrimonium bromide, myristyloxypropyltrimonium bromide, cetyloxypropyltrimonium bromide, stearoxypropyltrimonium bromide, behenyloxypropyltrimonium bromide and the like.
これらの中でもステアロキシプロピルトリモニウムクロリドが特に好ましい。 Among these, stearoxypropyl trimonium chloride is particularly preferred.
本発明では、これらのエーテル型カチオンの中から１種又は２種以上を任意に用いることができ、その配合量は、好ましくは０．１〜１０％、更に好ましくは、０．５〜５％の範囲である。この配合量の範囲であれば、毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができるため好ましい。 In the present invention, one or more of these ether-type cations can be optionally used, and the amount thereof is preferably 0.1 to 10%, more preferably 0.5 to 5%. Range. If it is the range of this compounding quantity, since a soft and moist finish feeling can be given to hair without feeling stickiness and weight, it is preferable.
本発明における（Ｃ）成分の炭素数１４〜２２の長鎖のアルキル基を有する高級アルコールは、好ましいものとしては、炭素数１６〜２２の長鎖高級アルコール、例えばセチルアルコール、ステアリルアルコール、ベヘニルアルコールである。 The higher alcohol having a long-chain alkyl group having 14 to 22 carbon atoms as the component (C) in the present invention is preferably a long-chain higher alcohol having 16 to 22 carbon atoms, such as cetyl alcohol, stearyl alcohol and behenyl alcohol. is there.
これらの高級アルコールは、１種又は２種以上を組み合わせて用いることができ、その配合量は、好ましくは１〜２０％、更に好ましくは、３〜１０％の範囲である。この配合量
の範囲であれば、毛髪に対して、べたつきを与えることなく、やわらかでしっとりとした仕上がり感を与える事ができ、かつ、すすぎ時に指通りよくやわらかで、仕上がりへの期待感を与える効果を付与することができるため好ましい。
These higher alcohols may be used alone or in combination of two or more, and the blending amount thereof is preferably in the range of 1 to 20%, more preferably 3 to 10%. Within this range, the hair can be given a soft and moist finish without giving a stickiness, and at the same time, it can be expected to have a expectancy of the finish in a well soft manner during the rinse. It is preferable because an effect can be given.
本発明の毛髪化粧料に配合される（Ｄ）アミノポリエーテル変性シリコーンはアミノ変性ポリシロキサン鎖とポリオキシアルキレン鎖とのブロック共重合体である。 The (D) amino polyether modified silicone compounded in the hair cosmetic composition of the present invention is a block copolymer of an amino modified polysiloxane chain and a polyoxyalkylene chain.
このようなアミノポリエーテル変性シリコーンとしては、例えばアミノ・ポリエーテル変性直鎖ＡＢｎタイプである（ビスイソブチルＰＥＧ−１４／アモジメチコン）コポリマー、市販品ではＳＩＬＳＴＹＬＥ１０４、２０１、４０１（東レ・ダウコーニング社製）が特に好ましい。その配合量は、０．１〜１％の範囲であることが好ましい。 As such an aminopolyether modified silicone, for example, an amino polyether modified linear ABn type (bisisobutyl PEG-14 / amodimethicone) copolymer, and as a commercially available product, SILSTYLE 104, 201, 401 (Toray Dow Corning Co., Ltd.) Is particularly preferred. It is preferable that the compounding quantity is the range of 0.1 to 1%.
本発明の毛髪化粧料は、一般式（１）で表されるような脂肪酸アミン、一般式（２）で表されるようなエーテル型カチオン、高級アルコール、上記記載のシリコーン誘導体を必須成分とし、これらを水又は水に適宜な溶剤などを加えた液に含有させることによって調製されるが、これらの必須成分以外にも、本発明の効果を損なわない範囲で通常毛髪化粧料に一般的に配合される他の成分を目的に応じて配合することができる。 The hair cosmetic composition of the present invention comprises, as essential components, fatty acid amines as represented by the general formula (1), ether type cations as represented by the general formula (2), higher alcohols, and the silicone derivatives described above Although these are prepared by containing them in water or a liquid obtained by adding an appropriate solvent to water, etc., in addition to these essential components, they are generally formulated into hair cosmetics as long as the effects of the present invention are not impaired. Other components may be blended according to the purpose.
そのような成分としては、例えば、ラウリル硫酸塩、ポリオキシエチレンラウリルーテル硫酸塩、ラウリルベンゼンスルホン酸塩、ラウロイルメチ−β−アラニンナトリウム等のアニオン性界面活性剤、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾニウムベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ヤシ油アルキルＮ−カルボキシエチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインナトリウム等の両性界面活性剤：ポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリン脂肪酸エステル等の非イオン界面活性剤、カチオン化セルロース、ヒドロキシエチルセルロース、ポリ（塩化ジアリルジメチルアンモニウム）、高重合ポリエチレングリコール等の高分子化合物、グリセリン、プロピレングリコール、ブチレングリコール、ジプロピレングリコール等の湿潤剤、ステアリン酸、ベヘニン酸、オレイン酸等の高級脂肪酸、ミリスチン酸イソプロピル等のエステル油、流動イソパラフィン、ワセリン、スクワラン等の炭化水素、アモジメチコン、ジメチルポリシロキサン、高重合シリコーン、ポリエーテル変性シリコーン等のシリコーン類、ジンクピリチオン、塩化ベンザルコニウム等の抗フケ成分、エタノール、メタノール、プロピルアルコール、イソプロピルアルコール等の低級アルコール、Ｌ−アスパラギン酸、Ｌ−アスパラギン酸ナトリウム、ＤＬ−アラニン、Ｌ−アルギニン、グリシン、Ｌ−グルタミン酸、Ｌ−システイン、Ｌスレオニン等のアミノ酸、その他紫外線吸収剤、防腐剤、糖類、香料、色剤、金属イオン封鎖剤、酸化防止剤、各種薬剤等が挙げられる。 As such components, for example, anionic surfactants such as lauryl sulfate, polyoxyethylene lauryl ether sulfate, lauryl benzene sulfonate, lauroyl methyl-β-alanine sodium, 2-alkyl-N-carboxymethyl Amphoteric surfactants such as N-hydroxyethylimidazonium betaine, coconut oil fatty acid amidopropyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethylimidazolinium sodium, etc .: polyoxyethylene alkyl ether, polyoxyethylene sorbitan Nonionic surfactants such as fatty acid ester and glycerine fatty acid ester, cationic cellulose, hydroxyethyl cellulose, poly (diallyldimethyl ammonium chloride), high polymers such as polyethylene glycol Wetting agents such as glycerin, propylene glycol, butylene glycol and dipropylene glycol, higher fatty acids such as stearic acid, behenic acid and oleic acid, ester oils such as isopropyl myristate, hydrocarbons such as liquid isoparaffin, vaseline and squalane Amodimethicone, dimethylpolysiloxane, silicones such as highly polymerized silicones, polyether modified silicones, zinc pyrithione, anti-dandruff components such as benzalkonium chloride, lower alcohols such as ethanol, methanol, propyl alcohol, isopropyl alcohol, L-asparagine Acids, sodium L-aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, amino acids such as L-threonine, other ultraviolet absorbers, preservatives, saccharides , Perfumes, coloring agents, sequestering agents, antioxidants, various drugs and the like.
本発明の毛髪化粧料は、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック、ヘアローション、ヘアリキッド、ヘアクリーム、ヘアフォーム、リーブオントリートメント、パーマ剤、ヘアカラー等に用いることができる。また本発明の毛髪化粧料は、常法により製造することができる。 The hair cosmetic composition of the present invention can be used for hair rinse, hair conditioner, hair treatment, hair pack, hair lotion, hair liquid, hair cream, hair foam, leave on treatment, perming agent, hair color and the like. The hair cosmetic composition of the present invention can be produced by a conventional method.
次に本発明を実施例を用いて詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。 EXAMPLES The present invention will next be described in detail by way of examples, which should not be construed as limiting the invention thereto. Prior to the examples, test methods and evaluation methods adopted in each example will be described.
（１）使用時の感触試験法
２０名のパネルが本発明の実施例及び比較例の試料を使用し、すすぎ時の指通り、すすぎ時のやわらかさ、すすぎ時のなめらかさについて「良い」、「普通」、「悪い」の３段階で判定し、判定結果を「良い」と回答した人数により判断した。判断基準は以下の通りで
ある。
◎：大変優れている・・・「良い」と答えた試験対象者の数が１６名以上
○：優れている ・・・「良い」と答えた試験対象者の数が１１〜１５名
△：劣っている ・・・「良い」と答えた試験対象者の数が６〜１０名
×：大変劣っている・・・「良い」と答えた試験対象者の数が５名以下
(1) Touch test method at the time of use The panel of 20 people uses the sample of the example of the present invention and the comparative example, and it is "good" about the softness at the time of rinse, the softness at the time of rinse, and the smoothness at the time of rinse It judged by three steps of "normal" and "bad", and judged the judgment result by the number of persons who answered "good". The judgment criteria are as follows.
:: very good ... more than 16 test subjects who answered "good" ○: excellent ... 11-15 subjects who answered "good" :: Poor ・ ・ ・ The number of test subjects who answered "Good" is 6 to 10 people ×: Very poor ... The number of test subjects who answered "Good" is 5 or less
（２）使用後の毛髪の仕上がり感試験法
２０名のパネルが本発明の実施例及び比較例の試料を使用し、使用後の毛髪の仕上がりのしっとり感、仕上がりのべたつきの無さ、仕上がりのやわらかさについて「良い」、「普通」、「悪い」の３段階で判定し、判定結果を「良い」と回答した人数により判断した。判断基準は以下の通りである。
◎：大変優れている・・・「良い」と答えた試験対象者の数が１６名以上
○：優れている ・・・「良い」と答えた試験対象者の数が１１〜１５名
△：劣っている ・・・「良い」と答えた試験対象者の数が６〜１０名
×：大変劣っている・・・「良い」と答えた試験対象者の数が５名以下
(2) Finishing feeling test of hair after use method The panel of 20 people uses the sample of the example and comparative example of the present invention, moist feeling of finish of the hair after use, no stickiness of finish, finish The softness was judged in three steps of "good", "normal" and "bad", and the judgment result was judged by the number of persons who answered "good". The judgment criteria are as follows.
:: very good ... more than 16 test subjects who answered "good" ○: excellent ... 11-15 subjects who answered "good" :: Poor ・ ・ ・ The number of test subjects who answered "Good" is 6 to 10 people ×: Very poor ... The number of test subjects who answered "Good" is 5 or less
実施例１〜２及び比較例１〜７（ヘアリンス）
表１に記載の配合組成によるヘアリンスを調整し、すすぎ時の指通り、やわらかさ、なめらかさ、使用後のしっとり感、使用後のべたつきの無さ、使用後のやわらかさについて調べ、その結果も表１に示した。
Examples 1-2 and Comparative Examples 1-7 (hair rinse)
Adjust the hair rinse according to the composition described in Table 1, and check the fingerness at rinse, softness, smoothness, moist feeling after use, no stickiness after use, softness after use, the results also It is shown in Table 1.
表１から明らかなように、本発明の成分を用いた実施例１〜２のヘアリンスは、比較例１〜７の組成物に比べていずれも優れた性能を見出した。 As apparent from Table 1, the hair rinses of Examples 1 and 2 using the component of the present invention were found to have superior performance as compared with the compositions of Comparative Examples 1 to 7.
以下、本発明の毛髪化粧料のその他の処方例を実施例５として挙げる。なお、実施例５の毛髪化粧料についても、上記の使用時の指通り、すすぎ時の指通り、やわらかさ、なめらかさ、使用後のしっとり感、使用後のべたつきの無さ、使用後のやわらかさの各項目を検討したところ、いずれの実施例においても優れた特性を有しており良好であった。
Hereinafter, another formulation example of the hair cosmetic composition of the present invention will be described as Example 5 . In the hair cosmetic composition of Example 5 , the above-mentioned fingering during use, fingering during rinse, softness, smoothness, moist feeling after use, no stickiness after use, soft after use As a result of examining each item of H, all the examples had excellent characteristics and were good.
実施例５ ヘアパック
配合量（％）
（１）ＰＰＧ−１／ＰＥＧ−１ステアラミン ２．０
（２）ステアロキシプロピルトリモニウムクロリド ０．５
（３）セトステアリルアルコール ５．０
（４）ベヘニルアルコール １．０
（５）ラノリン １．０
（６）アモジメチコン １．０
（７）アミノポリエーテル変性シリコーン
（ＳＩＬＳＴＹＬＥ１０４、東レ・ダウコーニング社製） ０．５
（８）べヘニルＰＧトリモニウムクロリド ０．５
（９）ステアリルＰＧトリモニウムクロリド ０．５
（１０）シリコーン水性エマルジョン
（ＸＳ６５−Ｂ７１１６、ＧＥ東芝シリコーン社製） ５．０
（１１）ヒドロキシウレア １．０
（１２）ＰＧ ３．０
（１３）セバシン酸ジエチル １．０
（１４）乳酸 ０．５
（１５）フェノキシエタノール ０．２
（１６）香料 ０．６
（１７）ＰＥＧ−１６０Ｍ ０．１
（１８）精製水 残余
Example 5 Hair Pack
Compounding amount (%)
(1) PPG-1 / PEG-1 stearamine 2.0
(2) Stearoxypropyltrimonium chloride 0.5
(3) cetostearyl alcohol 5.0
(4) Behenyl alcohol 1.0
(5) Lanolin 1.0
(6) Amodimethicone 1.0
(7) Aminopolyether modified silicone (SILSTYLE 104, manufactured by Toray Dow Corning) 0.5
(8) Behenyl PG trimonium chloride 0.5
(9) Stearyl PG trimonium chloride 0.5
(10) Silicone aqueous emulsion
(XS65-B7116, manufactured by GE Toshiba Silicone Co., Ltd.) 5.0
(11) Hydroxyurea 1.0
(12) PG 3.0
(13) Diethyl sebacate 1.0
(14) Lactic acid 0.5
(15) Phenoxyethanol 0.2
(16) Flavoring agent 0.6
(17) PEG-160 M 0.1
(18) Purified water residue
［製法］
（１）〜（９）、（１４）を８０℃にて均一に混合溶解させ、（１２）（１７）（１８）を５０℃にて混合したものを加えて乳化し、ホモミキサーで混合分散を行いながら、５０℃で（１０）、（１１）、（１５）、（１６）を加えて、室温まで冷却して、ヘアパックを調製した。
[Manufacturing method]
(1) to (9) and (14) are uniformly mixed and dissolved at 80 ° C, and a mixture of (12), (17) and (18) at 50 ° C is added and emulsified, and mixed and dispersed by a homomixer (10), (11), (15) and (16) were added at 50 ° C. while cooling and the hair pack was prepared by cooling to room temperature.
Claims (1)
（Ａ）下記一般式（１）で表される脂肪酸アミン
（式中、Ｒ1は、直鎖又は分岐した炭素数１２〜２４の飽和もしくは不飽和アルキル基、Ｒ2 a−Ｈは（Ｃ2Ｈ4Ｏ）a−Ｈで表されるヒドロキシエチル基、Ｒ3 b−Ｈは（Ｃ3Ｈ6Ｏ）b−Ｈで表されるヒドロキシプロピル基、ａ、ｂは１〜３の整数）
（Ｂ）下記一般式（２）で示されるエーテル型カチオン性界面活性剤
Ｒ4−Ｏ−（ＣＨ2）n−Ｎ（Ｒ5）3・Ｘ ・・・（２）
（式中、Ｒ4は、直鎖又は分岐した炭素数１２〜２２の飽和もしくは不飽和脂肪酸残基、Ｒ5は炭素数１〜３のアルキル基、ｎは１〜５の整数、Ｘはハロゲン原子を示す。）
（Ｃ）炭素数１４〜２４の長鎖のアルキル基を有する高級アルコール
（Ｄ）アミノポリエーテル変性シリコーン The hair cosmetics which contain the following (A)-(D) component, and whose content of (D) component is 0.1-1.0 mass% in all the compositions contained in hair cosmetics.
(A) Fatty acid amine represented by the following general formula (1)
(Wherein, R 1 is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R 2 a -H is a hydroxyethyl group represented by (C 2 H 4 O) a -H, R 3 b -H is a hydroxypropyl group represented by (C 3 H 6 O) b -H, and a and b are integers of 1 to 3)
(B) Ether-type cationic surfactant R 4 -O- (CH 2 ) n -N (R 5 ) 3 · X (2) represented by the following general formula (2)
(Wherein, R 4 is a linear or branched saturated or unsaturated fatty acid residue having 12 to 22 carbon atoms, R 5 is an alkyl group having 1 to 3 carbon atoms, n is an integer of 1 to 5 and X is a halogen Indicates an atom.)
(C) Higher alcohol (D) amino polyether modified silicone having long chain alkyl group having 14 to 24 carbon atoms
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| JP2014259112A JP6538346B2 (en) | 2014-12-22 | 2014-12-22 | Hair cosmetics |
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| JP2019214570A (en) * | 2018-06-12 | 2019-12-19 | 花王株式会社 | Hair cosmetic |
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