JP2016117692A - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
- Publication number
- JP2016117692A JP2016117692A JP2014259112A JP2014259112A JP2016117692A JP 2016117692 A JP2016117692 A JP 2016117692A JP 2014259112 A JP2014259112 A JP 2014259112A JP 2014259112 A JP2014259112 A JP 2014259112A JP 2016117692 A JP2016117692 A JP 2016117692A
- Authority
- JP
- Japan
- Prior art keywords
- peg
- ppg
- hair
- alkyl group
- stearamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003676 hair preparation Substances 0.000 title description 6
- -1 amine compounds Chemical class 0.000 claims abstract description 21
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 17
- 239000002537 cosmetic Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 150000001768 cations Chemical class 0.000 claims abstract description 8
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 3
- 125000005843 halogen group Chemical group 0.000 claims abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 2
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 2
- 150000004670 unsaturated fatty acids Chemical group 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 abstract description 14
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 abstract description 13
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- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 abstract description 12
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 5
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- WOGKWSUSGNOHRJ-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethyl-tetradecylamino]ethanol Chemical compound CCCCCCCCCCCCCCN(CCO)CCOCCO WOGKWSUSGNOHRJ-UHFFFAOYSA-N 0.000 description 4
- NDLNTMNRNCENRZ-UHFFFAOYSA-N 2-[2-hydroxyethyl(octadecyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCCCN(CCO)CCO NDLNTMNRNCENRZ-UHFFFAOYSA-N 0.000 description 4
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
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- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229940109850 royal jelly Drugs 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 150000003408 sphingolipids Chemical class 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229960002898 threonine Drugs 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
本発明は、毛髪化粧料に関し、詳しくは、すすぎ時に指通りよくやわらかで、かつ毛髪にべたつきをあたえることなく、やわらかでしっとりとまとまる仕上がり感を与える毛髪化粧料に関する。 TECHNICAL FIELD The present invention relates to a hair cosmetic, and more particularly to a hair cosmetic that is soft and smooth as a finger during rinsing and that gives a soft and moist finish without giving the hair sticky.
女性のヘアスタイルの流行に伴って、求められる髪の仕上がりや感触も並行して変化している。最近では、シャギーやレイヤーカットなどの毛先のボリュームを落としたヘアスタイルが一般的であるが、一方では、カラーリングやパーマ等の施術により、パサツキや髪の硬さが問題となっている。そのような背景から、仕上がりとして、しっとりまとまりながら、べたつかず、やわらかな仕上がり感が求められている。また、カラーリングやパーマ等の施術によって傷んだ髪は、ヘアトリートメントのすすぎ時においても、絡みや引っ掛かりなど不快な感触につながる。このすすぎ時の不快な感触は、仕上がり感の満足度にも大きな影響を与える。従って、満足度の高い仕上がりをえる為には、柔らかでしっとりまとまり、かつべたつかない仕上がりでありながら、さらにヘアトリートメントのすすぎ時も、柔らかで指通り良い使用感が望まれる。ヘアトリートメント等の毛髪化粧料においては、従来、毛髪を柔軟にして櫛通りをよくする目的で、カチオン性界面活性剤やシリコーン等の配合、或いは、しっとりとした感触を与えるために液状や固形状の油剤の配合が試みられているが、これら従来の技術では、近年のヘアスタイルにおいて要求されているニーズを満足させることは困難であり、仕上がりはしっとりまとまりながらべた付かずやわらかで、かつ使用時は、すすぎ時もやわらかで指通りの良い使用感を両立することは課題であった。 With the trend of women's hairstyles, the required finish and feel of hair are changing in parallel. Recently, hair styles with a reduced volume of hair ends such as shaggy and layer cut are common, but on the other hand, treatments such as coloring and perm have become a problem of softness and hair hardness. From such a background, there is a demand for a soft finish that is moist and non-sticky. In addition, hair damaged by treatments such as coloring and perm can lead to an unpleasant feel such as entanglement and catching even when rinsing hair treatment. This unpleasant feel at the time of rinsing has a great influence on the satisfaction of the finished feeling. Therefore, in order to obtain a highly satisfactory finish, it is desired to have a soft, moist, and non-sticky finish, and a soft and comfortable feeling to use even when rinsing hair treatment. In hair cosmetics such as hair treatments, for the purpose of softening the hair and improving the combing, a liquid surfactant or a solid surfactant is added to provide a moist feel or a cationic surfactant or silicone. However, with these conventional technologies, it is difficult to satisfy the needs required in recent hairstyles, and the finish is moist and smooth, not sticky, and in use. It was a challenge to achieve both a soft and comfortable feeling when rinsing.
これらの課題を解決する方法として、例えば、脂肪酸アミドアミン化合物やヒドロキシエーテルアミン化合物を用いることにより、または各種シリコーンを配合して毛髪に滑らかさや柔らかさを付与する毛髪化粧料（例えば、特許文献１〜５参照）が開示されている。更にはカチオン性界面活性剤の研究が進み、ヒドロキシエーテル型カチオンのような構造を有するカチオンに、エーテル型アミンや分岐脂肪酸を配合してべたつきや重さを与ることなくしなやかでしっとりした仕上がり感を与える毛髪化粧料（例えば特許文献６、７参照）が開示されるなど、毛髪にしなやかさを与える技術は年々進歩しているものの、毛髪化粧料の使用感、特にべたつきや重さを低減したいという要求も拡大し続けており、更なる進歩が望まれている。 As a method for solving these problems, for example, a hair cosmetic that imparts smoothness and softness to hair by using a fatty acid amide amine compound or a hydroxy ether amine compound or by blending various silicones (for example, Patent Documents 1 to 3) 5) is disclosed. In addition, research on cationic surfactants has progressed, and a cation that has a structure like a hydroxy ether type cation is blended with an ether type amine or a branched fatty acid to give a smooth and moist finish without giving stickiness or weight. Hair cosmetics that give hair (see, for example, Patent Documents 6 and 7) have been developed year by year. However, it is desired to reduce the feeling of use of hair cosmetics, particularly stickiness and weight. The demand for this has continued to expand, and further progress is desired.
また、（非特許文献１、２）ＰＰＧ−１／ＰＥＧ−１ステアラミンを、シリコーン類、カチオン活性剤と併用し配合する事によって、塗布時に髪になじみやすく、乾燥後にまで優れたコンディショニング効果を維持する技術が提案されているが、柔らかさを付与しながら乾燥後のしっとりまとまる仕上がり感において十分ではない。また、４級アルキル型カチオンと組み合わせることにより一定の改善がなされているが（特許文献８）まとまりの点でまだ十分に消費者を満足させていない。 (Non-Patent Documents 1 and 2) By blending PPG-1 / PEG-1 stearamine in combination with silicones and cationic activators, it is easy to adjust to hair during application and maintains an excellent conditioning effect even after drying. However, it is not sufficient in the feeling of finishing that gives a soft and moist feeling after drying. Moreover, although a certain improvement is made | formed by combining with a quaternary alkyl type cation (patent document 8), the consumer is not fully satisfied yet in terms of unity.
本発明の目的は、すすぎ時に指通りよくやわらかで、かつ毛髪にべたつきをあたえることなく、やわらかでしっとりとまとまる仕上がり感を与える毛髪化粧料を提供することにある。 An object of the present invention is to provide a hair cosmetic composition that is soft and soft as a finger at the time of rinsing and that gives a soft and moist finish without giving the hair sticky.
本発明者は、このような状況に鑑み、鋭意研究した結果、特定の脂肪酸アミンと、特定のカチオン性界面活性剤と、アミノポリエーテル変性シリコーンを含有する毛髪化粧料が、上記課題を解決することを見出し、本発明を完成するに至った。 As a result of diligent research in view of such circumstances, the present inventor has solved the above problems by a hair cosmetic composition containing a specific fatty acid amine, a specific cationic surfactant, and an amino polyether-modified silicone. As a result, the present invention has been completed.
本発明の毛髪化粧料は、すすぎ時に指通りよくやわらかで、かつ毛髪にべたつきをあたえることなく、やわらかでしっとりとまとまる仕上がり感を与える効果を付与することができる。 The hair cosmetic composition of the present invention can be imparted with an effect of giving a finished feeling that is soft and moist, without being sticky to the hair, being soft and soft as a finger when rinsing.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明における（Ａ）成分の脂肪酸アミンは、例えば下記一般式（１）で表される。 The fatty acid amine as the component (A) in the present invention is represented by, for example, the following general formula (1).
このような脂肪酸アミンを具体的に示すとＰＰＧ−１／ＰＥＧ−１ラウラミン、ＰＰＧ−１／ＰＥＧ−１ミリスタミン、ＰＰＧ−１／ＰＥＧ−１セタミン、ＰＰＧ−１／ＰＥＧ−
１ステアラミン、ＰＰＧ−１／ＰＥＧ−１アラカミン、ＰＰＧ−１／ＰＥＧ−１ベヘナミン、ＰＰＧ−１／ＰＥＧ−１カルナバミン、ＰＰＧ−１／ＰＥＧ−１オレアミン、ＰＰＧ−１／ＰＥＧ−１エライザミン、ＰＰＧ−１／ＰＥＧ−１リノラミン、ＰＰＧ−１／ＰＥＧ−１リノレナル、ＰＰＧ−１／ＰＥＧ−２ラウラミン、ＰＰＧ−１／ＰＥＧ−２ラウラミン、ＰＰＧ−１／ＰＥＧ−２ミリスタミン、ＰＰＧ−１／ＰＥＧ−２セタミン、ＰＰＧ−１／ＰＥＧ−２ステアラミン、ＰＰＧ−１／ＰＥＧ−２アラカミン、ＰＰＧ−１／ＰＥＧ−２ベヘナミン、ＰＰＧ−１／ＰＥＧ−２カルナバミン、ＰＰＧ−１／ＰＥＧ−２オレアミン、ＰＰＧ−１／ＰＥＧ−２エライザミン、ＰＰＧ−１／ＰＥＧ−２リノラミン、ＰＰＧ−１／ＰＥＧ−２リノレナル、ＰＰＧ−１／ＰＥＧ−３ラウラミン、ＰＰＧ−１／ＰＥＧ−３ラウラミン、ＰＰＧ−１／ＰＥＧ−３ミリスタミン、ＰＰＧ−１／ＰＥＧ−３セタミン、ＰＰＧ−１／ＰＥＧ−３ステアラミン、ＰＰＧ−１／ＰＥＧ−３アラカミン、ＰＰＧ−１／ＰＥＧ−３ベヘナミン、ＰＰＧ−１／ＰＥＧ−３カルナバミン、ＰＰＧ−１／ＰＥＧ−３オレアミン、ＰＰＧ−１／ＰＥＧ−３エライザミン、ＰＰＧ−１／ＰＥＧ−３リノラミン、ＰＰＧ−１／ＰＥＧ−３リノレナル、ＰＰＧ−２／ＰＥＧ−１ラウラミン、ＰＰＧ−２／ＰＥＧ−１ミリスタミン、ＰＰＧ−２／ＰＥＧ−１セタミン、ＰＰＧ−２／ＰＥＧ−１ステアラミン、ＰＰＧ−２／ＰＥＧ−１アラカミン、ＰＰＧ−２／ＰＥＧ−１ベヘナミン、ＰＰＧ−２／ＰＥＧ−１カルナバミン、ＰＰＧ−２／ＰＥＧ−１オレアミン、ＰＰＧ−２／ＰＥＧ−１エライザミン、ＰＰＧ−２／ＰＥＧ−１リノラミン、ＰＰＧ−２／ＰＥＧ−１リノレナル、ＰＰＧ−２／ＰＥＧ−２ラウラミン、ＰＰＧ−２／ＰＥＧ−２ミリスタミン、ＰＰＧ−２／ＰＥＧ−２セタミン、ＰＰＧ−２／ＰＥＧ−２ステアラミン、ＰＰＧ−２／ＰＥＧ−２アラカミン、ＰＰＧ−２／ＰＥＧ−２ベヘナミン、ＰＰＧ−２／ＰＥＧ−２カルナバミン、ＰＰＧ−２／ＰＥＧ−２オレアミン、ＰＰＧ−２／ＰＥＧ−２エライザミン、ＰＰＧ−２／ＰＥＧ−２リノラミン、ＰＰＧ−２／ＰＥＧ−２リノレナル、ＰＰＧ−２／ＰＥＧ−３ラウラミン、ＰＰＧ−２／ＰＥＧ−３ミリスタミン、ＰＰＧ−２／ＰＥＧ−３セタミン、ＰＰＧ−２／ＰＥＧ−３ステアラミン、ＰＰＧ−２／ＰＥＧ−３アラカミン、ＰＰＧ−２／ＰＥＧ−３ベヘナミン、ＰＰＧ−２／ＰＥＧ−３カルナバミン、ＰＰＧ−２／ＰＥＧ−３オレアミン、ＰＰＧ−２／ＰＥＧ−３エライザミン、ＰＰＧ−２／ＰＥＧ−３リノラミン、ＰＰＧ−２／ＰＥＧ−３リノレナル、ＰＰＧ−３／ＰＥＧ−１ラウラミン、ＰＰＧ−３／ＰＥＧ−１ミリスタミン、ＰＰＧ−３／ＰＥＧ−１セタミン、ＰＰＧ−３／ＰＥＧ−１ステアラミン、ＰＰＧ−３／ＰＥＧ−１アラカミン、ＰＰＧ−３／ＰＥＧ−１ベヘナミン、ＰＰＧ−３／ＰＥＧ−１カルナバミン、ＰＰＧ−３／ＰＥＧ−１オレアミン、ＰＰＧ−３／ＰＥＧ−１エライザミン、ＰＰＧ−３／ＰＥＧ−１リノラミン、ＰＰＧ−３／ＰＥＧ−１リノレナル、ＰＰＧ−３／ＰＥＧ−２ラウラミン、ＰＰＧ−３／ＰＥＧ−２ミリスタミン、ＰＰＧ−３／ＰＥＧ−２セタミン、ＰＰＧ−３／ＰＥＧ−２ステアラミン、ＰＰＧ−３／ＰＥＧ−２アラカミン、ＰＰＧ−３／ＰＥＧ−２ベヘナミン、ＰＰＧ−３／ＰＥＧ−２カルナバミン、ＰＰＧ−３／ＰＥＧ−２オレアミン、ＰＰＧ−３／ＰＥＧ−２エライザミン、ＰＰＧ−３／ＰＥＧ−２リノラミン、ＰＰＧ−３／ＰＥＧ−２リノレナル、ＰＰＧ−３／ＰＥＧ−３ラウラミン、ＰＰＧ−３／ＰＥＧ−３ミリスタミン、ＰＰＧ−３／ＰＥＧ−３セタミン、ＰＰＧ−３／ＰＥＧ−３ステアラミン、ＰＰＧ−３／ＰＥＧ−３アラカミン、ＰＰＧ−３／ＰＥＧ−３ベヘナミン、ＰＰＧ−３／ＰＥＧ−３カルナバミン、ＰＰＧ−３／ＰＥＧ−３オレアミン、ＰＰＧ−３／ＰＥＧ−３エライザミン、ＰＰＧ−３／ＰＥＧ−３リノラミン、ＰＰＧ−３／ＰＥＧ−３リノレナル、ＰＰＧ−１ラウラミン、ＰＰＧ−１ミリスタミン、ＰＰＧ−１セタミン、ＰＰＧ−１ステアラミン、ＰＰＧ−１アラカミン、ＰＰＧ−１ベヘナミン、ＰＰＧ−１カルナバミン、ＰＰＧ−１オレアミン、ＰＰＧ−１エライザミン、ＰＰＧ−１リノラミン、ＰＰＧ−１リノレナル、ＰＰＧ−２ラウラミン、ＰＰＧ−２ミリスタミン、ＰＰＧ−２セタミン、ＰＰＧ−２ステアラミン、ＰＰＧ−２アラカミン、ＰＰＧ−２ベヘナミン、ＰＰＧ−２カルナバミン、ＰＰＧ−２オレアミン、ＰＰＧ−２エライザミン、ＰＰＧ−２リノラミン、ＰＰＧ−２リノレナル、ＰＰＧ−３ラウラミン、ＰＰＧ−３ミリスタミン、ＰＰＧ−３セタミン、ＰＰＧ−３ステアラミン、ＰＰＧ−３アラカミン、ＰＰＧ−３ベヘナミン、ＰＰ
Ｇ−３カルナバミン、ＰＰＧ−３オレアミン、ＰＰＧ−３エライザミン、ＰＰＧ−３リノラミン、ＰＰＧ−３リノレナル、ＰＥＧ−１ラウラミン、ＰＥＧ−１ミリスタミン、ＰＥＧ−１セタミン、ＰＥＧ−１ステアラミン、ＰＥＧ−１アラカミン、ＰＥＧ−１ベヘナミン、ＰＥＧ−１カルナバミン、ＰＥＧ−１オレアミン、ＰＥＧ−１エライザミン、ＰＥＧ−１リノラミン、ＰＥＧ−１リノレナル、ＰＥＧ−２ラウラミン、ＰＥＧ−２ミリスタミン、ＰＥＧ−２セタミン、ＰＥＧ−２ステアラミン、ＰＥＧ−２アラカミン、ＰＥＧ−２ベヘナミン、ＰＥＧ−２カルナバミン、ＰＥＧ−２オレアミン、ＰＥＧ−２エライザミン、ＰＥＧ−２リノラミン、ＰＥＧ−２リノレナル、ＰＥＧ−３ラウラミン、ＰＥＧ−３ミリスタミン、ＰＥＧ−３セタミン、ＰＥＧ−３ステアラミン、ＰＥＧ−３アラカミン、ＰＥＧ−３ベヘナミン、ＰＥＧ−３カルナバミン、ＰＥＧ−３オレアミン、ＰＥＧ−３エライザミン、ＰＥＧ−３リノラミン、ＰＥＧ−３リノレナル、ラウラミン、ミリスタミン、セタミン、ステアラミン、アラカミン、ベヘナミン、カルナバミン、オレアミン、エライザミン、リノラミン、リノレナル等が挙げられる。
Specific examples of such fatty acid amines include PPG-1 / PEG-1 lauramine, PPG-1 / PEG-1 myristamine, PPG-1 / PEG-1 cetamine, PPG-1 / PEG-
1 stearamine, PPG-1 / PEG-1 alacamine, PPG-1 / PEG-1 behenamine, PPG-1 / PEG-1 carnabamine, PPG-1 / PEG-1 oleamine, PPG-1 / PEG-1 Elizamin, PPG- 1 / PEG-1 linolamine, PPG-1 / PEG-1 linolenal, PPG-1 / PEG-2 lauramine, PPG-1 / PEG-2 lauramine, PPG-1 / PEG-2 myristamine, PPG-1 / PEG-2 Cetamine, PPG-1 / PEG-2 stearamine, PPG-1 / PEG-2 alacamine, PPG-1 / PEG-2 behenamine, PPG-1 / PEG-2 carnabamine, PPG-1 / PEG-2 oleamine, PPG-1 / PEG-2 Elizamin, PPG-1 / PEG-2 linolamine, PPG-1 / PEG-2 linole PPG-1 / PEG-3 lauramine, PPG-1 / PEG-3 lauramine, PPG-1 / PEG-3 myristamine, PPG-1 / PEG-3 cetamine, PPG-1 / PEG-3 stearamine, PPG-1 / PEG-3 alacamine, PPG-1 / PEG-3 behenamine, PPG-1 / PEG-3 carnabamine, PPG-1 / PEG-3 oleamine, PPG-1 / PEG-3 elizamin, PPG-1 / PEG-3 linolamine , PPG-1 / PEG-3 linolenal, PPG-2 / PEG-1 lauramine, PPG-2 / PEG-1 myristamine, PPG-2 / PEG-1 cetamine, PPG-2 / PEG-1 stearamine, PPG-2 / PEG-1 alacamine, PPG-2 / PEG-1 behenamine, PPG-2 / PEG-1 carnabamine, PP -2 / PEG-1 oleamine, PPG-2 / PEG-1 Elizamin, PPG-2 / PEG-1 linolamine, PPG-2 / PEG-1 linolenal, PPG-2 / PEG-2 lauramine, PPG-2 / PEG- 2 myristamine, PPG-2 / PEG-2 cetamine, PPG-2 / PEG-2 stearamine, PPG-2 / PEG-2 alacamine, PPG-2 / PEG-2 behenamine, PPG-2 / PEG-2 carnabamine, PPG- 2 / PEG-2 oleamine, PPG-2 / PEG-2 Elizamin, PPG-2 / PEG-2 linolamine, PPG-2 / PEG-2 linolenal, PPG-2 / PEG-3 lauramine, PPG-2 / PEG-3 Myristamine, PPG-2 / PEG-3 cetamine, PPG-2 / PEG-3 stearamine, PPG-2 / PE G-3 alacamine, PPG-2 / PEG-3 behenamine, PPG-2 / PEG-3 carnabamine, PPG-2 / PEG-3 oleamine, PPG-2 / PEG-3 elizamin, PPG-2 / PEG-3 linolamine, PPG-2 / PEG-3 linolenal, PPG-3 / PEG-1 lauramine, PPG-3 / PEG-1 myristamine, PPG-3 / PEG-1 cetamine, PPG-3 / PEG-1 stearamine, PPG-3 / PEG -1 alacamine, PPG-3 / PEG-1 behenamine, PPG-3 / PEG-1 carnabamine, PPG-3 / PEG-1 oleamine, PPG-3 / PEG-1 elizamin, PPG-3 / PEG-1 linolamine, PPG -3 / PEG-1 linolenal, PPG-3 / PEG-2 lauramine, PPG-3 / PEG-2 milli Tamine, PPG-3 / PEG-2 cetamine, PPG-3 / PEG-2 stearamine, PPG-3 / PEG-2 alacamine, PPG-3 / PEG-2 behenamine, PPG-3 / PEG-2 carnabamine, PPG-3 / PEG-2 oleamine, PPG-3 / PEG-2 elizamin, PPG-3 / PEG-2 linolamine, PPG-3 / PEG-2 linolenal, PPG-3 / PEG-3 lauramine, PPG-3 / PEG-3 myristamine , PPG-3 / PEG-3 cetamine, PPG-3 / PEG-3 stearamine, PPG-3 / PEG-3 alacamine, PPG-3 / PEG-3 behenamine, PPG-3 / PEG-3 carnabamine, PPG-3 / PEG-3 oleamine, PPG-3 / PEG-3 elizamin, PPG-3 / PEG-3 linolamine, PG-3 / PEG-3 linolenal, PPG-1 lauramine, PPG-1 myristamine, PPG-1 cetamine, PPG-1 stearamine, PPG-1 alacamine, PPG-1 behenamine, PPG-1 carnabamine, PPG-1 oleamine, PPG -1 Elizamin, PPG-1 linolamine, PPG-1 linolenal, PPG-2 lauramine, PPG-2 myristamine, PPG-2 cetamine, PPG-2 stearamine, PPG-2 alacamine, PPG-2 behenamine, PPG-2 carnabamine, PPG -2 oleamine, PPG-2 elizamin, PPG-2 linolamine, PPG-2 linolenal, PPG-3 lauramine, PPG-3 myristamine, PPG-3 cetamine, PPG-3 stearamine, PPG-3 alacamine, PPG-3 behenamine, PP
G-3 carnabamine, PPG-3 oleamine, PPG-3 elizamin, PPG-3 linolamine, PPG-3 linolenal, PEG-1 lauramine, PEG-1 myristamine, PEG-1 cetamine, PEG-1 stearamine, PEG-1 alacamine, PEG-1 behenamine, PEG-1 carnabamine, PEG-1 oleamine, PEG-1 elizamin, PEG-1 linolamine, PEG-1 linolenal, PEG-2 lauramine, PEG-2 myristamine, PEG-2 cetamine, PEG-2 stearamine, PEG-2 alacamine, PEG-2 behenamine, PEG-2 carnabamine, PEG-2 oleamine, PEG-2 elizamin, PEG-2 linolamine, PEG-2 linolenal, PEG-3 lauramine, PEG-3 myristamine, PEG-3 seta PEG-3 stearamine, PEG-3 alacamine, PEG-3 behenamine, PEG-3 carnabamine, PEG-3 oleamine, PEG-3 elizamin, PEG-3 linolamine, PEG-3 linolenal, lauramine, myristamine, cetamine, stearamine, Examples include alacamine, behenamine, carnabamine, oleamine, elizamin, linolamine, and linolenal.
これらの中でも、ａ≠０、ｂ≠０のものが好ましく、特にＲ１が炭素数１８のステアリル基、ａ＝１、ｂ＝１である、ＰＰＧ−１／ＰＥＧ−１ステアラミンと、Ｒ１が炭素数２２のベヘニル基、ａ＝１、ｂ＝１である、ＰＰＧ−１／ＰＥＧ−１ベヘナミンが特に好ましい。 Among these, those in which a ≠ 0 and b ≠ 0 are preferable, and in particular, R 1 is a stearyl group having 18 carbon atoms, a = 1, b = 1, PPG-1 / PEG-1 stearamine, and R 1 is PPG-1 / PEG-1 behenamine, which is a behenyl group having 22 carbon atoms and a = 1 and b = 1, is particularly preferred.
本発明では、これらの脂肪酸アミンの中から１種単独又は２種以上を任意に組み合わせて用いることができ、その配合量は、好ましくは０．１〜１０質量％（以下、特に記載のあるもの以外は、質量％を単に「％」で示す）、更に好ましくは、０．５〜５％の範囲である。この配合量の範囲であれば、すすぎ時に指通りよくやわらかで、かつ毛髪にべたつきをあたえることなく、やわらかでしっとりとまとまる仕上がり感を与えることができるため好ましい。 In the present invention, one of these fatty acid amines can be used alone, or two or more of them can be used in any combination, and the blending amount is preferably 0.1 to 10% by mass (hereinafter, particularly described). The mass% is simply indicated by “%”, and more preferably in the range of 0.5 to 5%. When the amount is within this range, it is preferable because it gives a soft and moist finish feeling without being sticky to the hair while being soft and easy to touch when rinsing.
本発明において、（Ｂ）エーテル型カチオンは、下記一般式（２）
Ｒ4−Ｏ−（ＣＨ２）ｎ−Ｎ（Ｒ5）３・Ｘ ・・・（２）
（式中、Ｒ4は、直鎖又は分岐した炭素数１２〜２２の飽和もしくは不飽和脂肪酸残基、Ｒ5は炭素数１〜３のアルキル基、ｎは１〜５の整数、Ｘはハロゲン原子を示す。）で表され、具体例で示すとラウロキシプロピルトリモニウムクロリド、ミリスチロキシプロピルトリモニウムクロリド、セチロキシプロピルトリモニウムクロリド、ステアロキシプロピルトリモニウムクロリド、ベヘニロキシプロピルトリモニウムクロリド、ラウロキシプロピルトリモニウムブロミド、ミリスチロキシプロピルトリモニウムブロミド、セチロキシプロピルトリモニウムブロミド、ステアロキシプロピルトリモニウムブロミド、ベヘニロキシプロピルトリモニウムブロミド等が挙げられる。
In the present invention, (B) the ether type cation is represented by the following general formula (2):
R 4 —O— (CH 2 ) n —N (R 5 ) 3 · X (2)
(In the formula, R 4 is a linear or branched saturated or unsaturated fatty acid residue having 12 to 22 carbon atoms, R 5 is an alkyl group having 1 to 3 carbon atoms, n is an integer of 1 to 5, and X is a halogen. In particular, lauroxypropyltrimonium chloride, myristyloxypropyltrimonium chloride, cetyloxypropyltrimonium chloride, stearoxypropyltrimonium chloride, behenyloxypropyltrimonium chloride , Lauroxypropyltrimonium bromide, myristyloxypropyltrimonium bromide, cetyloxypropyltrimonium bromide, stearoxypropyltrimonium bromide, behenyloxypropyltrimonium bromide, and the like.
これらの中でもステアロキシプロピルトリモニウムクロリドが特に好ましい。 Of these, stearoxypropyltrimonium chloride is particularly preferred.
本発明では、これらのエーテル型カチオンの中から１種又は２種以上を任意に用いることができ、その配合量は、好ましくは０．１〜１０％、更に好ましくは、０．５〜５％の範囲である。この配合量の範囲であれば、毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができるため好ましい。 In the present invention, one or more of these ether type cations can be arbitrarily used, and the blending amount thereof is preferably 0.1 to 10%, more preferably 0.5 to 5%. Range. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.
本発明における（Ｃ）成分の炭素数１４〜２２の長鎖のアルキル基を有する高級アルコールは、好ましいものとしては、炭素数１６〜２２の長鎖高級アルコール、例えばセチルアルコール、ステアリルアルコール、ベヘニルアルコールである。 The higher alcohol having a long chain alkyl group having 14 to 22 carbon atoms as the component (C) in the present invention is preferably a long chain higher alcohol having 16 to 22 carbon atoms such as cetyl alcohol, stearyl alcohol, and behenyl alcohol. is there.
これらの高級アルコールは、１種又は２種以上を組み合わせて用いることができ、その配合量は、好ましくは１〜２０％、更に好ましくは、３〜１０％の範囲である。この配合量
の範囲であれば、毛髪に対して、べたつきを与えることなく、やわらかでしっとりとした仕上がり感を与える事ができ、かつ、すすぎ時に指通りよくやわらかで、仕上がりへの期待感を与える効果を付与することができるため好ましい。
These higher alcohols can be used singly or in combination of two or more, and the blending amount is preferably 1 to 20%, more preferably 3 to 10%. If it is within this range, the hair can be given a soft and moist finish without giving it stickiness, and it will give a sense of anticipation for the finish when it is rinsed. Since an effect can be provided, it is preferable.
本発明の毛髪化粧料に配合される（Ｄ）アミノポリエーテル変性シリコーンはアミノ変性ポリシロキサン鎖とポリオキシアルキレン鎖とのブロック共重合体である。 The (D) amino polyether-modified silicone compounded in the hair cosmetic composition of the present invention is a block copolymer of an amino-modified polysiloxane chain and a polyoxyalkylene chain.
このようなアミノポリエーテル変性シリコーンとしては、例えばアミノ・ポリエーテル変性直鎖ＡＢｎタイプである（ビスイソブチルＰＥＧ−１４／アモジメチコン）コポリマー、市販品ではＳＩＬＳＴＹＬＥ１０４、２０１、４０１（東レ・ダウコーニング社製）が特に好ましい。その配合量は、０．１〜１％の範囲であることが好ましい。 Examples of such aminopolyether-modified silicone include amino / polyether-modified linear ABn type (bisisobutyl PEG-14 / amodimethicone) copolymer, and commercially available products such as SILSTLE 104, 201, 401 (manufactured by Dow Corning Toray). Is particularly preferred. The blending amount is preferably in the range of 0.1 to 1%.
本発明の毛髪化粧料は、一般式（１）で表されるような脂肪酸アミン、一般式（２）で表されるようなエーテル型カチオン、高級アルコール、上記記載のシリコーン誘導体を必須成分とし、これらを水又は水に適宜な溶剤などを加えた液に含有させることによって調製されるが、これらの必須成分以外にも、本発明の効果を損なわない範囲で通常毛髪化粧料に一般的に配合される他の成分を目的に応じて配合することができる。 The hair cosmetic composition of the present invention comprises a fatty acid amine represented by the general formula (1), an ether type cation represented by the general formula (2), a higher alcohol, and the silicone derivative described above as essential components. These are prepared by adding them to water or a solution obtained by adding an appropriate solvent to water. In addition to these essential components, they are generally blended into normal hair cosmetics as long as the effects of the present invention are not impaired. Other ingredients can be blended depending on the purpose.
そのような成分としては、例えば、ラウリル硫酸塩、ポリオキシエチレンラウリルーテル硫酸塩、ラウリルベンゼンスルホン酸塩、ラウロイルメチ−β−アラニンナトリウム等のアニオン性界面活性剤、２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾニウムベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ヤシ油アルキルＮ−カルボキシエチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインナトリウム等の両性界面活性剤：ポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリン脂肪酸エステル等の非イオン界面活性剤、カチオン化セルロース、ヒドロキシエチルセルロース、ポリ（塩化ジアリルジメチルアンモニウム）、高重合ポリエチレングリコール等の高分子化合物、グリセリン、プロピレングリコール、ブチレングリコール、ジプロピレングリコール等の湿潤剤、ステアリン酸、ベヘニン酸、オレイン酸等の高級脂肪酸、ミリスチン酸イソプロピル等のエステル油、流動イソパラフィン、ワセリン、スクワラン等の炭化水素、アモジメチコン、ジメチルポリシロキサン、高重合シリコーン、ポリエーテル変性シリコーン等のシリコーン類、ジンクピリチオン、塩化ベンザルコニウム等の抗フケ成分、エタノール、メタノール、プロピルアルコール、イソプロピルアルコール等の低級アルコール、Ｌ−アスパラギン酸、Ｌ−アスパラギン酸ナトリウム、ＤＬ−アラニン、Ｌ−アルギニン、グリシン、Ｌ−グルタミン酸、Ｌ−システイン、Ｌスレオニン等のアミノ酸、その他紫外線吸収剤、防腐剤、糖類、香料、色剤、金属イオン封鎖剤、酸化防止剤、各種薬剤等が挙げられる。 Examples of such components include anionic surfactants such as lauryl sulfate, polyoxyethylene lauryl sulfate sulfate, lauryl benzene sulfonate, sodium lauroylmethy-β-alanine, and 2-alkyl-N-carboxymethyl. -Amphoteric surfactants such as N-hydroxyethyl imidazolium betaine, coconut oil fatty acid amidopropyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethyl imidazolinium betaine sodium: polyoxyethylene alkyl ether, polyoxyethylene sorbitan Nonionic surfactants such as fatty acid esters and glycerin fatty acid esters, polymers such as cationized cellulose, hydroxyethyl cellulose, poly (diallyldimethylammonium chloride), and highly polymerized polyethylene glycol Compounds, wetting agents such as glycerin, propylene glycol, butylene glycol, dipropylene glycol, higher fatty acids such as stearic acid, behenic acid, oleic acid, ester oils such as isopropyl myristate, hydrocarbons such as liquid isoparaffin, petrolatum, squalane , Silicones such as amodimethicone, dimethylpolysiloxane, highly polymerized silicone and polyether-modified silicone, anti-dandruff components such as zinc pyrithione and benzalkonium chloride, lower alcohols such as ethanol, methanol, propyl alcohol and isopropyl alcohol, L-asparagine Acids, amino acids such as sodium L-aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, L-threonine, other UV absorbers, preservatives, saccharides , Fragrances, coloring agents, sequestering agents, antioxidants, various agents and the like.
本発明の毛髪化粧料は、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック、ヘアローション、ヘアリキッド、ヘアクリーム、ヘアフォーム、リーブオントリートメント、パーマ剤、ヘアカラー等に用いることができる。また本発明の毛髪化粧料は、常法により製造することができる。 The hair cosmetic composition of the present invention can be used for hair rinses, hair conditioners, hair treatments, hair packs, hair lotions, hair liquids, hair creams, hair foams, leave-on treatments, permanent agents, hair colors, and the like. The hair cosmetic composition of the present invention can be produced by a conventional method.
次に本発明を実施例を用いて詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。 EXAMPLES Next, although this invention is demonstrated in detail using an Example, this invention is not limited by this. Prior to the examples, test methods and evaluation methods employed in each example will be described.
（１）使用時の感触試験法
２０名のパネルが本発明の実施例及び比較例の試料を使用し、すすぎ時の指通り、すすぎ時のやわらかさ、すすぎ時のなめらかさについて「良い」、「普通」、「悪い」の３段階で判定し、判定結果を「良い」と回答した人数により判断した。判断基準は以下の通りで
ある。
◎：大変優れている・・・「良い」と答えた試験対象者の数が１６名以上
○：優れている ・・・「良い」と答えた試験対象者の数が１１〜１５名
△：劣っている ・・・「良い」と答えた試験対象者の数が６〜１０名
×：大変劣っている・・・「良い」と答えた試験対象者の数が５名以下
(1) Tactile test method at the time of use 20 panels used the samples of the examples and comparative examples of the present invention, and “good” for fingering during rinsing, softness during rinsing, and smoothness during rinsing. Judgment was made in three stages, “normal” and “bad”, and the judgment result was judged by the number of people who answered “good”. Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less
（２）使用後の毛髪の仕上がり感試験法
２０名のパネルが本発明の実施例及び比較例の試料を使用し、使用後の毛髪の仕上がりのしっとり感、仕上がりのべたつきの無さ、仕上がりのやわらかさについて「良い」、「普通」、「悪い」の３段階で判定し、判定結果を「良い」と回答した人数により判断した。判断基準は以下の通りである。
◎：大変優れている・・・「良い」と答えた試験対象者の数が１６名以上
○：優れている ・・・「良い」と答えた試験対象者の数が１１〜１５名
△：劣っている ・・・「良い」と答えた試験対象者の数が６〜１０名
×：大変劣っている・・・「良い」と答えた試験対象者の数が５名以下
(2) Hair finish feeling test method after use 20 panels used the samples of the examples and comparative examples of the present invention, the moist feeling of the finished hair after use, the non-stickiness of the finish, the finish The softness was judged in three stages, “good”, “normal”, and “bad”, and the judgment result was judged by the number of people who answered “good”. Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less
実施例１〜２及び比較例１〜７（ヘアリンス）
表１に記載の配合組成によるヘアリンスを調整し、すすぎ時の指通り、やわらかさ、なめらかさ、使用後のしっとり感、使用後のべたつきの無さ、使用後のやわらかさについて調べ、その結果も表１に示した。
Examples 1-2 and comparative examples 1-7 (hair rinse)
Adjust the hair rinse according to the formulation shown in Table 1 and examine the finger rinse, softness, smoothness, moist feeling after use, no stickiness after use, and softness after use. It is shown in Table 1.
表１から明らかなように、本発明の成分を用いた実施例１〜２のヘアリンスは、比較例１〜７の組成物に比べていずれも優れた性能を見出した。 As is clear from Table 1, the hair rinses of Examples 1 and 2 using the components of the present invention found superior performance compared to the compositions of Comparative Examples 1 to 7.
以下、本発明の毛髪化粧料のその他の処方例を実施例３〜４として挙げる。なお、これらの実施例の毛髪化粧料についても、上記の使用時の指通り、すすぎ時の指通り、やわらかさ、なめらかさ、使用後のしっとり感、使用後のべたつきの無さ、使用後のやわらかさの各項目を検討したところ、いずれの実施例においても優れた特性を有しており良好であった。 Hereinafter, other formulation examples of the hair cosmetic composition of the present invention will be described as Examples 3 to 4. In addition, for the hair cosmetics of these examples, as per the above finger during use, as per finger during rinsing, softness, smoothness, moist feeling after use, no stickiness after use, after use When each item of softness was examined, all the examples had excellent characteristics and were good.
実施例３（ヘアコンディショナー）
配合量（質量％）（１）ＰＰＧ−１／ＰＥＧ−１ステアラミン １．０
（２）ステアロキシプロピルトリモニウムクロリド １．０
（３）セトステアリルアルコール ６．５
（４）ジリノール酸ジ（フィトステアリル／イソステアリル／
セチル／ステアリル／ベヘニル） １．０
（５）ベヘニルアルコール ０．５
（６）べヘニルＰＧトリモニウムクロリド １．０
（７）ステアリルＰＧトリモニウムクロリド １．０
（８）コハク酸ジエチルヘキシル ２．０
（９）ダイマージリーノール酸（フィトステリル／イソステアリル／
セチル／ステアリル／ベヘニル） ２．０
（１０）乳酸 １．０
（１１）パラフィン １．０
（１２）プロピレングリコール ０．５
（１３）ソルビトール ３．０
（１４）グリセリン ０．５
（１５）ヒドロキシエチルセルロース ０．４
（１６）アモジメチコン ２．０
（１７）メチルポリシロキサン（３００ｃｓ） ５．０
（１８）アミノポリエーテル変性シリコーン
（ＳＩＬＳＴＹＬＥ１０４、東レ・ダウコーニング社製） ０．５
（１９）アンズ核油 ０．１
（２０）セラミド２ ０．１
（２１）トウモロコシ由来スフィンゴ脂質 ０．１
（２２）ポリグルタミン酸 ０．１
（２３）シャクヤクエキス ０．１
（２４）ローヤルゼリーエキス ０．１
（２５）ユズ果実エキス ０．１
（２６）コメヌカエキス ０．１
（２７）フェノキシエタノール ０．２
（２８）サリチル酸 ０．１
（２９）香料 ０．５
（３０）精製水 残余
Example 3 (hair conditioner)
Compounding amount (mass%) (1) PPG-1 / PEG-1 stearamine 1.0
(2) Stearoxypropyltrimonium chloride 1.0
(3) Cetostearyl alcohol 6.5
(4) Dilinoleic acid di (phytostearyl / isostearyl /
Cetyl / stearyl / behenyl) 1.0
(5) Behenyl alcohol 0.5
(6) Behenyl PG trimonium chloride 1.0
(7) Stearyl PG trimonium chloride 1.0
(8) Diethylhexyl succinate 2.0
(9) Dimer linoleic acid (phytosteryl / isostearyl /
Cetyl / stearyl / behenyl) 2.0
(10) Lactic acid 1.0
(11) Paraffin 1.0
(12) Propylene glycol 0.5
(13) Sorbitol 3.0
(14) Glycerin 0.5
(15) Hydroxyethyl cellulose 0.4
(16) Amodimethicone 2.0
(17) Methyl polysiloxane (300 cs) 5.0
(18) Aminopolyether-modified silicone (SILSTYLE 104, manufactured by Toray Dow Corning) 0.5
(19) Apricot kernel oil 0.1
(20) Ceramide 2 0.1
(21) Corn-derived sphingolipid 0.1
(22) Polyglutamic acid 0.1
(23) Peonies extract 0.1
(24) Royal jelly extract 0.1
(25) Yuzu fruit extract 0.1
(26) Rice bran extract 0.1
(27) Phenoxyethanol 0.2
(28) Salicylic acid 0.1
(29) Fragrance 0.5
(30) Purified water residue
［製法］
（１）〜（１１）を８０℃にて均一に混合溶解したものに、８０℃に加温した（１２）〜（１５）、（３０）を分散したものをプロペラで攪拌しながら加え、乳化を行う。徐々に冷却を行い、６０℃にて（１６）〜（２９）を添加し、室温まで冷却して、ヘアコンディショナーを調製した。
[Production method]
(1) to (11) are uniformly mixed and dissolved at 80 ° C., and (12) to (15) and (30) dispersed at 80 ° C. are added with stirring with a propeller to emulsify. I do. The hair conditioner was prepared by gradually cooling, adding (16) to (29) at 60 ° C., and cooling to room temperature.
実施例４ ヘアパック
配合量（％）
（１）ＰＰＧ−１／ＰＥＧ−１ステアラミン ２．０
（２）ステアロキシプロピルトリモニウムクロリド ０．５
（３）セトステアリルアルコール ５．０
（４）ベヘニルアルコール １．０
（５）ラノリン １．０
（６）アモジメチコン １．０
（７）アミノポリエーテル変性シリコーン
（ＳＩＬＳＴＹＬＥ１０４、東レ・ダウコーニング社製） ０．５
（８）べヘニルＰＧトリモニウムクロリド ０．５
（９）ステアリルＰＧトリモニウムクロリド ０．５
（１０）シリコーン水性エマルジョン
（ＸＳ６５−Ｂ７１１６、ＧＥ東芝シリコーン社製） ５．０
（１１）ヒドロキシウレア １．０
（１２）ＰＧ ３．０
（１３）セバシン酸ジエチル １．０
（１４）乳酸 ０．５
（１５）フェノキシエタノール ０．２
（１６）香料 ０．６
（１７）ＰＥＧ−１６０Ｍ ０．１
（１８）精製水 残余
Example 4 Hair Pack
Compounding amount (%)
(1) PPG-1 / PEG-1 stearamine 2.0
(2) Stearoxypropyltrimonium chloride 0.5
(3) cetostearyl alcohol 5.0
(4) Behenyl alcohol 1.0
(5) Lanolin 1.0
(6) Amodimethicone 1.0
(7) Amino polyether-modified silicone (SILSTLE 104, manufactured by Toray Dow Corning) 0.5
(8) Behenyl PG trimonium chloride 0.5
(9) Stearyl PG trimonium chloride 0.5
(10) Silicone aqueous emulsion
(XS65-B7116, manufactured by GE Toshiba Silicones) 5.0
(11) Hydroxyurea 1.0
(12) PG 3.0
(13) Diethyl sebacate 1.0
(14) Lactic acid 0.5
(15) Phenoxyethanol 0.2
(16) Fragrance 0.6
(17) PEG-160M 0.1
(18) Purified water residue
［製法］
（１）〜（９）、（１４）を８０℃にて均一に混合溶解させ、（１２）（１７）（１８）を５０℃にて混合したものを加えて乳化し、ホモミキサーで混合分散を行いながら、５０℃で（１０）、（１１）、（１５）、（１６）を加えて、室温まで冷却して、ヘアパックを調製した。
[Production method]
(1) to (9) and (14) are uniformly mixed and dissolved at 80 ° C., and (12), (17) and (18) mixed at 50 ° C. are added and emulsified, and then mixed and dispersed with a homomixer. (10), (11), (15) and (16) were added at 50 ° C. while cooling, and cooled to room temperature to prepare a hair pack.
Claims (1)
（Ａ）下記一般式（１）で表される脂肪酸アミン
（Ｂ）下記一般式（２）で示されるエーテル型カチオン
Ｒ4−Ｏ−（ＣＨ２）ｎ−Ｎ（Ｒ5）３・Ｘ ・・・（２）
（式中、Ｒ4は、直鎖又は分岐した炭素数１２〜２２の飽和もしくは不飽和脂肪酸残基、Ｒ5は炭素数１〜３のアルキル基、ｎは１〜５の整数、Ｘはハロゲン原子を示す。）
（Ｃ）炭素数１４〜２４の長鎖のアルキル基を有する高級アルコール
（Ｄ）アミノポリエーテル変性シリコーン
A hair cosmetic comprising the following components (A) to (D) and having a content of the component (D) of 0.1 to 1.0% by mass in the total composition contained in the hair cosmetic.
(A) Fatty acid amine represented by the following general formula (1)
(B) Ether type cation R 4 —O— (CH 2 ) n —N (R 5 ) 3 · X (2) represented by the following general formula (2)
(In the formula, R 4 is a linear or branched saturated or unsaturated fatty acid residue having 12 to 22 carbon atoms, R 5 is an alkyl group having 1 to 3 carbon atoms, n is an integer of 1 to 5, and X is a halogen. Indicates an atom.)
(C) A higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms (D) aminopolyether-modified silicone
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019099496A (en) * | 2017-12-01 | 2019-06-24 | クラシエホームプロダクツ株式会社 | Hair cosmetic |
| JP2019214570A (en) * | 2018-06-12 | 2019-12-19 | 花王株式会社 | Hair cosmetic |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012197267A (en) * | 2011-03-04 | 2012-10-18 | Kawaken Fine Chem Co Ltd | Composition for hair |
| JP2014040569A (en) * | 2012-03-13 | 2014-03-06 | Kao Corp | Cationized glycerolized cellulose |
| JP2014043419A (en) * | 2012-08-27 | 2014-03-13 | Kracie Home Products Ltd | Hair cosmetic |
-
2014
- 2014-12-22 JP JP2014259112A patent/JP6538346B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012197267A (en) * | 2011-03-04 | 2012-10-18 | Kawaken Fine Chem Co Ltd | Composition for hair |
| JP2014040569A (en) * | 2012-03-13 | 2014-03-06 | Kao Corp | Cationized glycerolized cellulose |
| JP2014043419A (en) * | 2012-08-27 | 2014-03-13 | Kracie Home Products Ltd | Hair cosmetic |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019099496A (en) * | 2017-12-01 | 2019-06-24 | クラシエホームプロダクツ株式会社 | Hair cosmetic |
| JP7036421B2 (en) | 2017-12-01 | 2022-03-15 | クラシエホームプロダクツ株式会社 | Hair cosmetics |
| JP2019214570A (en) * | 2018-06-12 | 2019-12-19 | 花王株式会社 | Hair cosmetic |
| WO2019240091A1 (en) * | 2018-06-12 | 2019-12-19 | 花王株式会社 | Hair cosmetic |
| TWI827617B (en) * | 2018-06-12 | 2024-01-01 | 日商花王股份有限公司 | hair cosmetics |
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