WO2006049311A1

WO2006049311A1 - Hair cosmetic composition

Info

Publication number: WO2006049311A1
Application number: PCT/JP2005/020491
Authority: WO
Inventors: Tanemasa Nagano; Takahiro Akutsu
Original assignee: Shiseido Company, Ltd.
Priority date: 2004-11-05
Filing date: 2005-11-02
Publication date: 2006-05-11
Also published as: JP2007112716A; JP5086522B2; CN101048127A; CN101048127B

Abstract

Disclosed is a hair cosmetic composition containing a cationic surfactant, and a polyhydric alcohol selected from erythritol, diglycerin, 1,3-butyleneglycol and propylene glycol and/or a sugar alcohol. The total amount of the polyhydric alcohol and/or the sugar alcohol contained in the hair cosmetic composition is 10-50% by mass. This hair cosmetic composition repairs damaged hair and imparts it smoothness without making the hair greasy or stiff.

Description

Ming book Hair cosmetics Technical field

The present invention relates to a hair cosmetic, and more particularly, to a hair cosmetic such as a treatment or a treatment that cares for damaged hair and does not feel sticky or stiff. Background art

Conventionally, various oils, water-soluble polymers, and the like have been appropriately blended in order to care for damaged hair in hair cosmetics, improve unity, and impart a moderate moist feeling.

However, when oils such as hydrocarbon oils and ester oils were used, the finish became heavy and stickiness tended to occur. In addition, when a moisturizing agent such as a water-soluble polymer is blended, it has an effect on moisture feeling at the time of use, but tends to become stiff over time. Thus, depending on the type of moisturizer for hair, a satisfactory feeling of use could not be obtained. Therefore, it was desired to develop a hair cosmetic that cares for damaged hair and does not feel sticky or stiff.

As a technology developed to solve such drawbacks, hair cosmetics containing a specific amino acid-based amphoteric surfactant and a plant-based moisturizer, urea-based moisturizer or sugar-based moisturizer as a moisturizer. Is known (refer to Japanese Patent Laid-Open No. 2 00 0 -86 4 5 3).

In addition, hair cosmetics that have set power do not become sticky and supple to the hair by blending certain highly polymerized polyethylene renders, oils, nonionic surfactants, and water-soluble alcohols. Give A hair cosmetic composition is obtained (see Japanese Patent Application Laid-Open No. 2000-265654). Disclosure of the invention

However, the hair cosmetic described in the above-mentioned Japanese Patent Application Laid-Open No. 2000-086 4 53 has a problem that it is too moist and sticky. Further, the hair cosmetic disclosed in Japanese Patent Application Laid-Open No. 20 0 3-2 6 5 4 5 has a problem that it will give a smooth feeling.

Therefore, an object of the present invention is to provide a hair cosmetic composition that can take care of damaged hair and does not feel sticky or stiff, and has good combing properties.

The present invention comprises a cationic surfactant, at least one polyhydric alcohol selected from erythritol, diglycerin, 1,3-butylene glycol and propylene glycol, and Z or sugar alcohol. The total amount of alcohol and Z or sugar alcohol is 10 to 50% by mass of the total mass of the hair cosmetic.

Here, among polyhydric alcohols or sugar alcohols, those that are sugar alcohols are preferred. Sugar alcohols include xylitol, fructose, sorbitol, mannitol, inositol, glucose, lactose, maltitol or sucrose.

In the present invention, it is preferable to further blend one or more modified silicones represented by the following formulas (I), (Π) and (IE). H ₃ C——

(Where m = 3

30 is shown.

Three

(Π)

AO

Where p = 2 0-2 0 0, q-5, r = 5-1 5 ¾T

(Where m + n = 3 0 0 0 o (m + n) = 0.0 o

0 1 to 0 0 0 5 ¾r shown)

o

The hair cosmetic composition of the present invention is excellent in the effect of caring for damaged hair, and n

It does not feel sticky or stiff, and improves combing.

BEST MODE FOR CARRYING OUT THE INVENTION

The best mode of the present invention will be described below.

As used herein and in the appended claims, the singular forms should be understood to include the plural unless the context clearly dictates otherwise.

Cationic surfactant

Examples of the cationic surfactant used in the present invention include alkyl quaternary ammonium salts such as stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, distearyldimethylammonium chloride, and alkylpyridinium salts. Or amine salt, monoalkylhydroxyalkyl ether ammonium salt, polyoxypropylene jetylmethylammonium salt, dialkylamido pyrmethylmethylamine salt, hydroxypropyl-bis-alkylammonium salt Nyum salts, hydroxypropyl-bis-alkylamidoammonium salts, dialkylamidoethylethylhydroxyammonium salts, alkyldimethylpentylammonium salts, and the like are used. Of these, alkyl quaternary ammonium salts are particularly preferred.

The blending amount of the cationic surfactant is preferably from 0.01 to 10% by mass, more preferably from 0.1 to 4.0% by mass, based on the total amount of the hair cosmetic composition. If the amount is less than 1% by mass, the intended effect may not be obtained, and if it exceeds 10% by mass, the hair may become sticky.

Polyhydric alcohol and sugar alcohol

The polyhydric alcohol used in the present invention is selected from erythritol, diglycerin, 1,3-butylene glycol and propylene glycol. Other polyhydric alcohols such as dipropylene glycol, glycerin, and isoprene glycol do not improve hair combability.

Examples of the sugar alcohol used in the present invention include xylitol, fructose, sorbitol, mannitol, inositol, glucose, lactose, maltitol, and sucrose. Among the polyhydric alcohols or sugar alcohols, preferred are sugar alcohols, and among the sugar alcohols, sorbitol and sucrose are preferred.

The total amount of the above-mentioned specific polyhydric alcohol and / or sugar alcohol is preferably 10 to 50% by mass, more preferably 15 to 40% by mass in the total amount of the hair cosmetic. If the blending amount is less than 10% by mass, the intended effect may not be obtained. Conversely, if it exceeds 50% by mass, the hair will become sticky.

Modified silicone In the present invention, in addition to the above essential components, it is desirable to further blend one or more modified silicones represented by the above formula (I), (H) or (m).

A preferable blending amount of the modified silicone is 0.1 to 10% by mass. Combability of hair is improved at 0.1% by mass or more. If used in excess of 10% by mass, there is a risk of stickiness on the hair.

In the hair cosmetic composition of the present invention, in addition to the essential components described above, various additive components conventionally used in hair cosmetic compositions can be blended as necessary within a range not detracting from the object of the present invention. . Examples of the additive component include an anionic surfactant, a nonionic surfactant, an amphoteric surfactant, a highly polymerized silicone compound, an organic acid such as succinic acid or phosphonic acid, or a salt thereof, glycine galalanin, etc. Amino acids such as lysine, vinyl-based anionic polymers, cationic polymers, acrylic amphoteric polymers, nonionic polymers, fungicides, higher alcohols, hydrocarbons, natural fats and oils, ester oils, colorants, Examples include fragrances, solvents (for example, ethanol and carbitol derivatives), polyhydric alcohols other than the components of the present invention such as ethylene glycol and glycerin, and fatty acids. These additive components may be used singly or in combination of two or more, and may be blended at an appropriate stage of hair cosmetic preparation.

The hair cosmetic composition of the present invention can be widely used as hair treatments, shampoos, hair rinses, hair conditioners, styling foams, and the like.

Example

The present invention will be described in more detail with reference to the following examples. Is not limited in any way by this. Unless otherwise specified, the amount is shown in mass%.

Examples 1 to 2 2 and Comparative Examples 1 to 7

Hair cosmetics comprising the respective formulation components shown in Tables 1 to 4 below were prepared by a conventional method. About the obtained hair cosmetics, the combability of the hair during rinsing and the combability of the hair after drying were evaluated according to the following criteria.

1. Combability of hair after rinsing, combability of hair after drying

A combing tester '(manufactured by Techno Hashimoto) was used as a comb-pass tester, and measurement was performed by the following method.

The load applied to the hair bundle is detected when the bleached hair and the comb are pulled.

Based on the numerical values obtained above, the following evaluation criteria were used. The measured values and judgments obtained are shown in Tables 1 to 3.

(Evaluation criteria)

©): When Comparative Example 1 is 1.0, the value is 0.8 or less.

◯: When Comparative Example 1 is 1.0, the value is more than 0.8 and 0.95 or less. (Triangle | delta): The value of the Example when the comparative example 1 is set to 1.0 is more than 0.95 and 1.0 or less.

X: The value when Comparative Example 1 is 1.0 is over 1.0.

(Mass%) Examples Examples Examples Examples Examples Examples Examples Examples Examples Examples Components

1 2 3 4 5 6 7 8 Stearyl alcohol 5 5 5 5 5 5 5 5 Hexyltrimethylammonium chloride 2 2 2 2 2 2 2 2 2 Cenoic acid 0. 01 0. 01 0. 01 0. 01 0. 01 0. 01 0. 01 0. 01 Erythritol 15 30 ― ― One ― One ― Shik 'Reserine ― ― 15 30-― ― ― Xylitol ― ― ― One 15 ― ― ― Fructose ― ― ― ― 15 ― ― Lil! : "Tall 1-1--1 15 30 Mannitol--1---1-Immortal--------Root course------1-Lactose--1 ---1 Multi HF 1----1-Scroll----1---

1, 3-7 “Chilenk” recall — — — — — One — — F. Lopilenk “recall” ― ― ― ― ― ― ― ― Purified water MM}

(Evaluation item)

Combability of hair after rinsing 0. 88 0. 94 0. 88 0. 88 0. 69 0. 73 0. 60 0. 55 Combability of hair after drying 0. 70 0. 79 0. 84 0 71 0. 79 0. 80 0. 78 0. 67

(Evaluation item)

Combability of hair after rinsing 〇〇〇 ◎ ◎ ◎ ◎ ◎ Combability of hair after drying ◎ ◎ ○ ◎ ◎ ◎ ◎ ◎

Table 2

9 10 11 12 13 14 15 16 Stearyl alcohol 5 5 5 5 5 5 5 5 Chloride hexyltrimethylammonium 2 2 2 2 2 2 2 2 Cenoic acid 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 Erythritol ― ― One ― ― ― ― ― 'Silk' reserin ― ― ― ― ― ― ― ― Xylitol ― ― ― ― ― ― Fructose ― ― ― ― ―

'Norbitol ― ― ― ― ― ― ― Mannitol 15 ― One ― ― ― ― Ihuntol ― 15 One ― ― One ― Reluctance ― ― 15 ― ― ― ― Lactose ― ― One 15 ― ― ―-Multi-toll ― ― ― 15 ― ― Scroll ― ― ― ― 15 ― ―

1, 3-F "Chylenek" recall 1-1--30-

T-propylene alcohol 1 ― 1 ― ― ― 30 Denatured silicone

(In the above formula (I), m = 50

, n = 5, a = 0, b =

5 compounds)

Denatured silicone

(In the above formula (m), m = one ― one ― ― ― ―

5000, n = 25 compounds)

Denatured silicone

(In the above formula (Π), p = 100

, Q = 5, r = 10

object)

Purified water Appropriate amount,, Weekly right amount Appropriate amount Appropriate amount Weekly

(Evaluation item)

Combability of hair after rinsing 0.63 0.62 0.70 0.70 0.60 0.53 0.87 0.89 Combability of hair after drying 0.76 0.74 0.61 0.65 0.73 0.61 0.73 0.73

(Evaluation item)

Combability of hair after rinsing ◎ © ◎ ◎ ◎ ◎ 〇 Combability of hair after drying ◎ ◎ ◎ ◎ ◎ ◎ ◎ Table 3

(Mass%) Examples Examples Examples Examples Examples Examples Examples Ingredients

17 18 19 20 21 22 Stearyl alcohol 5 5 5 5 5 5 Hexyltrimethylammonium chloride 2 2 2 2 2 2 Cenoic acid 0.01 0.01 0.01 0.01 0.01 0.01 Erythritol------ ”Reserin ― ― ― ― ― ― Xylitol ― ― One ― ― ― Fructose ― ― One ― ― ― Sorbitol 15 30 30 ― ― ― Manner ― ― ― ― ― ― Inositol ― ― ― ― Course course ― One ― ― ― ― Lactose ― ― ― ― ― ― Multi-tall Uniform ― ― ― ― Succeed ― One 15 15 30

1, 3-7 'Tylene' Recall ― ― ― ― 1 Fluoropolymer “Recovery 1 ― ― ― ― ― Denatured Silicone

(In the above formula (I), m = 50, n = 1 ― ― 3 ― 5

5, compounds with a = 0, b = 5)

Denatured silicone

(In the above formula (ΠΙ), m = 5000, n ― 3 ― ― 5 1

= 25 compounds)

Denatured silicone

(In the above formula (Π), p = 100, q = ― ― 10 ― ― 2

5, r = 10 compounds)

Purified water Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount

(Evaluation item)

Combability of hair when rinsed 0.56 0.58 0.48 0.53 0.40 0.41 Combability of hair after drying 0.53 0.45 0.43 0.51 0.45 0.35

(Evaluation item)

Combability of hair after rinsing ◎ ◎ ◎ ◎ ◎ ◎ Combability of hair after drying ◎ ◎ ◎ ◎ ◎ ◎ Table 4

(Mass%)

Examples of the hair cosmetic composition of the present invention are shown below.

Example 2 3; Hair conditioner

Benenyl chloride Limethylammonium: 2.0% stearyl alcohol 5.0%

Sucrose 1 5. 0

Modified silicone cone 1.0

(In the above formula (I), m = 50, n = 5, a = 0, b

object)

Preservative

Perfume

Purified water remaining

Example 2 4; Hair conditioner

Benenyltrimethylammonium chloride: hum 3.2

Stearyl alcohol 7.0

Sorbitol 3 0. 0 Denatured silicone 3.0

(In the formula (ΠΙ), m = 5 0 0 0, n 2 5 compound) Preservative

Fragrance

purified water

Example 2 5; Hair conditioner

Benenyl chloride trimethylammonium 2 0

Stearyl alcohol 5 0

Fruct 1 5 0

Modified silicone cone 2 0

(In the above formula (H), p = 1 0 0, q 5, r = 1 0 compound) Preservative

Fragrance

purified water

Example 2 6; Hair conditioner

Benenyl chloride methylammonium 2.

Stearyl alcohol 5.

Sucrose 5.

Modified silicone 2.

(In the formula (I), compounds of 2 4 and b 2 4)

Modified silicone cone, 0

(In the above formula (Π), 0 compound) Preservative

Fragrance mm

purified water

Example 2 7 "Hair mist Dimethylpolysiloxane 1.0% by mass Ethanol 5.0

Stearyl alcohol 0.1

Behenyl alcohol 0.2

Sucrose 1 2. 0

Dipropylene glycol 1.0

1, 3 —Butylene glycol 1.0

Alkyltrimethylammonium chloride (7 7) 0.5 Vinylpyrrolidone N N-dimethylaminoethylmethacrylic acid copolymer 2.5

Paraxybenzoic acid ester

Purified water residue

Perfume

Example 2 8: Hair Cream

Volatile isoparaffin 1 0.0% by weight Dimethylpolysiloxane 2.0

Sorbitol 2 0. 0

Polyethylene glycol 6 0 0 0 1. 0

Polyglyceryl diisostearate 0.5

Sodium hydroxide 0. 0 6

Suitable amount of phenoxyethanol

Edetate 3 sodium

Force Lagginan 0.5

Dimethyldistearyl ammonium tritate 0.5 Alkyl chloride trimethyl ammonium 0.3

Stearyl alcohol 1.0

Forced L-Poxyvinyl Polymer 0.5 Highly polymerized dimethylpolysiloxane 2.0

Purified water residue

Perfume

Example 2 9; hair spray

Ethanol 1 0. 0

Sucrose 1 5. 0

Behenyl alcohol 1. 0

Alkyl chloride methylammonium chloride (7 7%) 0.

Yukafi Ma M S M 1 0. 0

Polyoxyethylene / methylpolysiloxane copolymer 0 Volatile isoparaffin 5.0

Highly polymerized dimethylpolysiloxane 1.0

Purified water residue

Perfume

Example 30: hair spray

Sucrose 2 0.0 Ethanol 5. 0 Yucaphor 1 S M 1 2. 0

2 —Alkyl mono N-carboxymethyl-N—

Hydroxychetylimidane bethanine 1. 0 Polyoxyethylene hydrogenated castor oil (6 0 E. 0.) 0 Alkyltrimethylammonium chloride 0. 2 Stearyl alcohol 0.5 Paramethoxybenzoate

Purified water residue

Perfume

4 3 MP a: DME SI

(O S: 0 8 =

T6l70Z0 / S00Zdf / X3d 11 £ 6 00 OAV

Claims

1. Cationic surfactant and erythritol, diglycerin,

1, 3-butylene glycol and propylene glycol at least one kind selected from polyhydric alcohol and / or sugar alcohol, and a total blend of polyhydric alcohol and / or sugar alcohol

Hair cosmetics whose amount is 10 to 50% by mass of the total mass of the hair cosmetics.

2. A hair cosmetic comprising a cationic surfactant and a sugar alcohol, wherein the amount of the sugar alcohol is 10 to 50% by mass of the total mass of the hair cosmetic.

3. The sugar alcohol is xylitol, fructose, sorbite

The hair cosmetic composition according to claim 1 or 2, wherein the hair cosmetic composition is at least one selected from the group consisting of glucose, mannitol, inositol, glucose, lactose, maltitol, and sucrose.

4. The hair cosmetic according to claim 1, further comprising at least one modified silicone represented by the formulas (I), (H) and (ΠΙ).

(Where m = 3

30 is shown.

NH ₂

(In the formula, m + n = 3 0 0 0 to 1 0 0 0 0, n / (m + n) = 0.0 1 to 0.0 0 5 is shown.)