JP2619833B2 - Hair rinse composition - Google Patents
Hair rinse compositionInfo
- Publication number
- JP2619833B2 JP2619833B2 JP31540288A JP31540288A JP2619833B2 JP 2619833 B2 JP2619833 B2 JP 2619833B2 JP 31540288 A JP31540288 A JP 31540288A JP 31540288 A JP31540288 A JP 31540288A JP 2619833 B2 JP2619833 B2 JP 2619833B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- weight
- group
- carbon atoms
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、ヘアーリンス剤に関し、更に詳しくは、毛
髪に対し、仕上がりの軽さ及びさらさら感を大幅に改善
するとともに、毛髪コンディショニング効果に優れたヘ
アーリンス剤組成物に関する。Description: FIELD OF THE INVENTION The present invention relates to a hair rinsing agent, and more particularly, to a hair with a significantly improved lightness and smoothness, and an excellent hair conditioning effect. And a hair rinse composition.
毛髪の汚れを除去するためにアニオン界面活性剤を主
成分とするシャンプーで洗髪すると、毛髪の汚れのほか
毛髪表面を保護している油分も同時に除去され、毛髪の
柔軟性が失なわれ、艶のないくし通りの悪い髪となり、
毛髪の損傷，枝毛，切毛が発生し易くなる。When hair is washed with a shampoo containing an anionic surfactant as a main component to remove hair stains, oils protecting the hair surface as well as hair stains are removed at the same time, and the flexibility of the hair is lost and the gloss is reduced. The hair is as bad as it is without comb,
Hair damage, split ends, and cuts are likely to occur.
これらの弊害を防ぐ目的で、カチオン界面活性剤であ
る第４級アンモニウム塩を有効成分とするヘアーリンス
剤が使用されている。For the purpose of preventing these adverse effects, a hair rinse agent containing a quaternary ammonium salt as a cationic surfactant as an active ingredient has been used.
ヘアーリンス剤は、毛髪にコンディショニング効果
（柔軟性，しっとり感，なめらかさ，くし通り性）を付
与することを目的とするものである。The hair rinse agent is intended to impart a conditioning effect (flexibility, moist feeling, smoothness, combability) to hair.
しかし、第４級アンモニウム塩のみでは、柔軟性，な
めらかさに関し充分な効果が得られない。However, a quaternary ammonium salt alone cannot provide a sufficient effect on flexibility and smoothness.
従って、従来のヘアーリンス剤には、これらの欠点を
改善するために、高級アルコール，グリセライド，流動
パラフィン等の油脂類を配合することが提案されてい
る。また近年毛髪の艶，コンディショニング効果，耐性
（耐洗浄性）の改良を目的にシリコンガムを用いたヘア
ケア製品も提案されている。しかし、これらのヘアケア
製品も消費者が連用する過程で毛髪に吸着したシリコン
ガムが部分的に脱離し、なめらかさ，くし通り性，及び
仕上がりの毛髪の軽さにおいて満足するものではなかっ
た。Therefore, it has been proposed that conventional hair rinses be formulated with fats and oils such as higher alcohols, glycerides, and liquid paraffin in order to improve these disadvantages. In recent years, hair care products using silicone gum have been proposed for the purpose of improving the gloss, conditioning effect, and resistance (washing resistance) of hair. However, these hair care products were not satisfactory in terms of smoothness, combability, and lightness of the finished hair because the silicone gum adsorbed on the hair was partially released during the continuous use by the consumer.
本発明は、洗浄により適度な脱離性を有するととも
に、優れた毛髪コンディショニング効果（柔軟性，しっ
とり感，なめらかさ，くし通り性）及び乾燥後の毛髪の
仕上がりの軽さ、さらさら感を大幅に改善するヘアーリ
ンス剤を提供することを目的としている。INDUSTRIAL APPLICABILITY The present invention not only has an appropriate desorption property by washing, but also has an excellent hair conditioning effect (flexibility, moist feeling, smoothness, combability) and a light finish of hair after drying and a drastic feeling of dryness. It is intended to provide an improved hair rinse.
本発明は、 アルキル基が炭素数11〜21の直鎖又は分岐鎖である、
ビス（２−アルキル−Ｎ−ヒドロキシエチルイミダゾリ
ン）クロル酢酸錯体型両性界面活性剤0.5〜6.0重量％と （Ｂ） 一般式 〔式中、R1は炭素数11〜17の直鎖又は分岐鎖アルキル基
を示し、R2,R3は炭素数１〜３のアルキル基を示す。〕 で表わされる第３アミドアミン0.1〜5.0重量％と （Ｃ） 一般式 〔式中、R4はメチル基またはフェニル基（ただし、R4の
総数の90％以上はメチル基）R5はメチル基または水酸基
を示す。またｎは900〜2500の整数を示す。〕 で表わされる高分子シリコーンの一種または二種以上0.
1〜6.0重量％とを含有するヘアーリンス剤組成物であ
る。In the present invention, the alkyl group is a straight or branched chain having 11 to 21 carbon atoms,
Bis (2-alkyl-N-hydroxyethylimidazoline) chloroacetic acid complex type amphoteric surfactant 0.5 to 6.0% by weight and (B) [Wherein, R 1 represents a linear or branched alkyl group having 11 to 17 carbon atoms, and R 2 and R 3 represent an alkyl group having 1 to 3 carbon atoms. And 0.1 to 5.0% by weight of a tertiary amidoamine represented by the following formula: [In the formula, R 4 represents a methyl group or a phenyl group (provided that 90% or more of the total number of R 4 is a methyl group). R 5 represents a methyl group or a hydroxyl group. N represents an integer of 900 to 2500. One or more of the polymeric silicones represented by
A hair rinse composition containing 1 to 6.0% by weight.
本発明の（Ａ）成分である、アルキル基が炭素数11〜
21の直鎖又は分岐鎖のビス（２−アルキル−Ｎ−ヒドロ
キシエチルイミダゾリン）クロル酢酸錯体型両性界面活
性剤は、公知の物質である。The alkyl group, which is the component (A) of the present invention, has 11 to 11 carbon atoms.
The 21 linear or branched bis (2-alkyl-N-hydroxyethylimidazoline) chloroacetic acid complex type amphoteric surfactants are known substances.
例えば、ビス（ドデシル−Ｎ−ヒドロキシエチルイミ
ダゾリン）クロル酢酸錯体，ビス（テトラデシル−Ｎ−
ヒドロキシエチルイミダゾリン）クロル酢酸錯体，ビス
（ヘキサデシル−Ｎ−ヒドロキシエチルイミダゾリン）
クロル酢酸錯体，ビス（オクタデシル−Ｎ−ヒドロキシ
エチルイミダゾリン）クロル酢酸錯体，ビス（ドコシル
−Ｎ−ヒドロキシエチルイミダゾリン）クロル酢酸錯
体，などが挙げられ、特に好ましいものは、ビス（オク
タデシル−Ｎ−ヒドロキシエチルイミダゾリン）クロル
酢酸錯体である。For example, bis (dodecyl-N-hydroxyethylimidazoline) chloroacetic acid complex, bis (tetradecyl-N-
(Hydroxyethylimidazoline) chloroacetic acid complex, bis (hexadecyl-N-hydroxyethylimidazoline)
Chloroacetic acid complex, bis (octadecyl-N-hydroxyethylimidazoline) chloroacetic acid complex, bis (docosyl-N-hydroxyethylimidazoline) chloroacetic acid complex, and the like, with bis (octadecyl-N-hydroxyethyl) being particularly preferred. Imidazoline) chloroacetic acid complex.
本発明のヘアーリンス剤組成物には、これらの両性界
面活性剤の一種または二種以上の混合物を総量を基準と
して、一般的には0.5〜6.0重量％（以下wt％と略記す
る）好ましくは、1.0〜4.0wt％配合される。配合量が0.
5wt％未満では、毛髪コンディショニング効果が不十分
となる傾向がみられ、6.0wt％を超えると毛髪にべたつ
きが生じ好ましくない。In the hair rinse composition of the present invention, one or a mixture of two or more of these amphoteric surfactants is generally used in an amount of 0.5 to 6.0% by weight (hereinafter abbreviated as wt%), preferably 0.5 to 6.0% by weight, based on the total amount. , 1.0 to 4.0 wt%. The blending amount is 0.
If the amount is less than 5% by weight, the hair conditioning effect tends to be insufficient. If the amount exceeds 6.0% by weight, the hair becomes sticky, which is not preferable.
本発明の（Ｂ）成分である第３アミドアミンは、公知
の物質であって次の一般式 〔式中、R1は炭素数11〜17の直鎖又は分岐鎖アルキル基
を示し、R2,R3は炭素数１〜３のアルキル基を示す。〕 で表わされる。The tertiary amidoamine which is the component (B) of the present invention is a known substance and has the following general formula [Wherein, R 1 represents a linear or branched alkyl group having 11 to 17 carbon atoms, and R 2 and R 3 represent an alkyl group having 1 to 3 carbon atoms. ] Is represented.
例えば、ドデシル酸ジメチルアミノエチルアミド，テ
トラデシル酸ジメチルアミノエチルアミド，ヘキサデシ
ル酸ジエチルアミノプロピルアミド，ヘキサデシル酸ジ
エチルアミノエチルアミドなどが挙げられ、特に好まし
いものは、ヘキサデシル酸ジエチルアミノエチルアミド
である。For example, dimethylaminoethylamide dodecylate, dimethylaminoethylamide tetradecylate, diethylaminopropylamide hexadecylate, diethylaminoethylamide hexadecylate, and the like are preferable, and particularly preferred is diethylaminoethylamide hexadecylate.
本発明のヘアーリンス剤には、これらの第３アミドア
ミンの一種または二種以上の混合物を総量を基準とし
て、一般的には0.1〜5.0wt％、好ましくは0.3〜3.0wt％
配合される。配合量が0.1wt％未満では、毛髪コンディ
ショニング効果が不十分となる傾向がみられ、5.0wt％
を超えると、乾燥後の毛髪の仕上がりが重くなり好まし
くない。In the hair rinse agent of the present invention, one or more of these tertiary amidoamines are generally used in an amount of 0.1 to 5.0% by weight, preferably 0.3 to 3.0% by weight, based on the total amount.
Be blended. If the compounding amount is less than 0.1 wt%, the hair conditioning effect tends to be insufficient, and 5.0 wt%
If it exceeds, the finished hair after drying becomes heavy, which is not preferable.
本発明の（Ｃ）成分である高分子シリコーンは、次の
一般式 〔式中、R4はメチル基またはフェニル基（ただし、R4の
総数の90％以上はメチル基）,R5はメチル基または水酸
基を示す。またｎは900〜2500の整数を示す。〕 で表わされる高分子シリコーンの一種または二種以上の
混合物が適用される。The polymer silicone as the component (C) of the present invention has the following general formula: [Wherein, R 4 represents a methyl group or a phenyl group (however, 90% or more of the total number of R 4 is a methyl group), and R 5 represents a methyl group or a hydroxyl group. N represents an integer of 900 to 2500. One type or a mixture of two or more types of the high molecular silicone represented by the formula:
例えば、ジメチルポリシロキサン，メチルフェニルポ
リシロキサン，末端水酸基含有ジメチルポリシロキサ
ン，末端水酸基含有メチルフェニルポリシロキサンなど
が挙げられる。For example, dimethylpolysiloxane, methylphenylpolysiloxane, dimethylpolysiloxane having a terminal hydroxyl group, methylphenylpolysiloxane having a terminal hydroxyl group, and the like can be given.
式中のR4は総てメチル基かまたは一部がフェニル基で
あり、メチル基の割合は、R4の総数のうち90％以上であ
ることが必須である。R 4 is or a portion all methyl groups in the formula is a phenyl group, the proportion of methyl groups, it is essential that at least 90% of the total number of R 4.
本発明のヘアーリンス剤組成物には、これらの高分子
シリコーンの一種または二種以上の混合物を総量を基準
として0.1〜6.0wt％、好ましくは0.3〜5.0wt％配合され
る。配合量が0.1wt％未満では、乾燥後のさらさら感に
良好な結果が得られず、6.0wt％を超えると毛髪にべた
つきが生じ好ましくない。The hair rinse composition of the present invention is blended with 0.1 to 6.0% by weight, preferably 0.3 to 5.0% by weight, based on the total amount, of one or a mixture of two or more of these polymeric silicones. If the amount is less than 0.1% by weight, good results cannot be obtained for the dry feeling after drying, and if it exceeds 6.0% by weight, the hair becomes sticky, which is not preferable.
一方、本発明で使用する高分子シリコーンの平均重合
度（ｎ）は900〜2500であり、好ましくは1000〜2000で
ある。平均重合度が900に満たないものは効果がなく、
平均重合度が2500を超えるものを使用すると連用した場
合なめらかさ，くし通り性が悪いので好ましくない。On the other hand, the average polymerization degree (n) of the high molecular silicone used in the present invention is from 900 to 2500, preferably from 1,000 to 2,000. Those with an average degree of polymerization less than 900 have no effect,
It is not preferable to use a polymer having an average degree of polymerization of more than 2500 because of its smoothness and poor combability when used continuously.
本発明のヘアーリンス剤組成物は、上述した３成分を
必須の構成成分とするが、当該組成物には、本発明の目
的を達成する範囲で他の成分を適宜配合することができ
る。The hair rinse composition of the present invention contains the above-mentioned three components as essential components, but other components can be appropriately added to the composition as long as the object of the present invention is achieved.
即ち、ワセリン，スクワラン，低沸点イソパラフィ
ン，流動パラフィン等の炭化水素，イソプロピルミリス
テート，イソプロピルパルミテート等のエステル油，ツ
バキ油，オリーブ油，アボガド油等の植物油，低沸点シ
リコーン，環状シリコーン等のシリコン油，ポリグリセ
リン脂肪酸エステル，ポリオキシエチレンソルビタンモ
ノラウレート等の非イオン界面活性剤，メチルセルロー
ス，ヒドロキシエチルセルロース，カチオン化セルロー
ス等のセルロース誘導体，エチレングリコール，プロピ
レングリコール，グリセリン等の保湿剤，ポリペプチ
ド，その他殺菌剤，着色剤，香料などが挙げられこれら
の一種または二種以上を配合することができる。That is, hydrocarbons such as petrolatum, squalane, low-boiling isoparaffin, and liquid paraffin; ester oils such as isopropyl myristate and isopropyl palmitate; vegetable oils such as camellia oil, olive oil and avocado oil; silicone oils such as low-boiling silicone and cyclic silicone Nonionic surfactants such as glycerin, polyglycerin fatty acid ester, polyoxyethylene sorbitan monolaurate, cellulose derivatives such as methylcellulose, hydroxyethylcellulose, cationized cellulose, humectants such as ethylene glycol, propylene glycol, glycerin, polypeptides, etc. A bactericide, a coloring agent, a fragrance and the like can be mentioned, and one or more of these can be blended.
次に実施例を挙げ本発明を説明するが、本発明はこれ
ら実施例に限定されるものではない。Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples.
なお、本実施例中で用いた試験方法は、下記のとおり
である。The test method used in this example is as follows.
（毛髪コンディショニング効果並びに乾燥後の毛髪の仕
上がりの軽さ及びさらさら感試験） 各例におけるコンディショニング効果（「髪の柔軟
生」，「髪のしっとり感」，「髪のなめらかさ」，「く
し通り性」）、並びに乾燥後の毛髪の仕上がりの軽さ及
びさらさら感を女性20名の専門パネラーにて一週間連用
後、官能的に比較し、下記基準で評価を行なった。(Test of hair conditioning effect and lightness and smoothness of finished hair after drying) Conditioning effect in each example ("flexible hair", "moistness of hair", "smoothness of hair", "combability" )) And the lightness and smoothness of the finished hair after drying were continuously used for one week by a professional panel of 20 women, and then organoleptically compared, and evaluated according to the following criteria.
◎；良いと答えた人が18人以上の場合 ○；良いと答えた人が14〜17人の場合 △；良いと答えた人が８〜13人の場合 ×；良いと答えた人が７人以下の場合 実施例１〜3,比較例１〜３ 第一表の上段に示す配合組成のヘアーリンス剤を通常
の方法で調整し、上記試験を行い第一表の下段にその結
果を示した。◎: 18 or more people answered good ○: 14-17 people answered good △: 8-13 people answered good ×: 7 people answered good In the case of humans or less Examples 1-3, Comparative Examples 1-3 A hair rinse agent having the composition shown in the upper row of Table 1 was prepared by a usual method, the above test was conducted, and the results are shown in the lower row of Table 1. Was.
実施例４〜7,比較例４〜９ 第二表の上段に示す配合組成のヘアーリンス剤を通常
の方法で調製し、上記試験を行い第二表の下段にその結
果を示した。 Examples 4 to 7, Comparative Examples 4 to 9 Hair rinse agents having the composition shown in the upper part of the second table were prepared by a usual method, and the above test was conducted. The results are shown in the lower part of the second table.
（特性） 実施例１〜７より明らかなように、本発明のヘアーリ
ンス剤組成物は、いずれも優れた性能を示していた。 (Characteristics) As is clear from Examples 1 to 7, all of the hair rinse composition of the present invention showed excellent performance.
一方、必須成分であるビス（２−アルキル−Ｎ−ヒド
ロキシエチルイミダゾリン）クロル酢酸錯体型両性界面
活性剤，第３級アミドアミン，高分子シリコーンのどれ
かを欠いた場合（比較例１〜３）又は、これらの配合量
および高分子シリコーンの平均重合度（ｎ）が本発明の
範囲外の場合（比較例４〜９）はいずれも劣った性能を
示し本発明の目的を達成できなかった。On the other hand, when any of the essential components bis (2-alkyl-N-hydroxyethylimidazoline) chloroacetic acid complex type amphoteric surfactant, tertiary amidoamine, and high molecular silicone is missing (Comparative Examples 1 to 3) or When the amounts of these components and the average degree of polymerization (n) of the high molecular silicone were out of the range of the present invention (Comparative Examples 4 to 9), the performance was inferior, and the object of the present invention could not be achieved.
以上記載のごとく、本発明は毛髪コンディショニング
効果（柔軟性，しっとり感，なめらかさ，くし通り性）
及び乾燥後の毛髪の仕上がりの軽さ，さらさら感に優
れ、連用しても髪を傷めない有用なるヘアーリンス剤組
成物を提供することは明らかである。As described above, the present invention provides a hair conditioning effect (flexibility, moist feeling, smoothness, combability).
It is apparent that the present invention provides a useful hair rinse composition which is excellent in lightness and smoothness of the finished hair after drying and which does not damage the hair even if it is used continuously.
Claims (1)
は分岐鎖である、ビス（２−アルキル−Ｎ−ヒドロキシ
エチルイミダゾリン）クロル酢酸錯体型両性界面活性剤
0.5〜6.0重量％と （Ｂ）一般式 〔式中、R1は炭素数11〜17の直鎖又は分岐鎖アルキル基
を示し、R2,R3は炭素数１〜３のアルキル基を示す。〕 で表わされる第３アミドアミン0.1〜5.0重量％と （Ｃ）一般式 〔式中、R4はメチル基またはフェニル基（ただし、R4の
総数の90％以上はメチル基）,R5はメチル基または水酸
基を示す。またｎは900〜2500の整数を示す。〕 で表わされる高分子シリコーンの一種または二種以上0.
1〜6.0重量％とを含有することを特徴とするヘアーリン
ス剤組成物。1. A bis (2-alkyl-N-hydroxyethylimidazoline) chloroacetic acid complex type amphoteric surfactant wherein (A) the alkyl group is a straight or branched chain having 11 to 21 carbon atoms.
0.5-6.0% by weight (B) General formula [In the formula, R 1 represents a straight-chain or branched-chain alkyl group having 11 to 17 carbon atoms, and R 2 and R 3 represent an alkyl group having 1 to 3 carbon atoms. And 0.1 to 5.0% by weight of a tertiary amidoamine represented by the following formula: [In the formula, R 4 represents a methyl group or a phenyl group (however, 90% or more of the total number of R 4 is a methyl group), and R 5 represents a methyl group or a hydroxyl group. N represents an integer of 900 to 2500. One or more of the polymeric silicones represented by
A hair rinse composition comprising 1 to 6.0% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31540288A JP2619833B2 (en) | 1988-12-13 | 1988-12-13 | Hair rinse composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31540288A JP2619833B2 (en) | 1988-12-13 | 1988-12-13 | Hair rinse composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02160714A JPH02160714A (en) | 1990-06-20 |
| JP2619833B2 true JP2619833B2 (en) | 1997-06-11 |
Family
ID=18064959
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP31540288A Expired - Lifetime JP2619833B2 (en) | 1988-12-13 | 1988-12-13 | Hair rinse composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2619833B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI930458A (en) * | 1992-03-27 | 1993-09-28 | Curtis Helene Ind Inc | OPACIFIERINGSMEDEL FOER VATTENBASERADE KOMPOSITIONER |
| AU2071897A (en) * | 1997-03-10 | 1998-09-29 | Procter & Gamble Company, The | Hair conditioning compositions |
| WO1999011226A1 (en) * | 1997-08-29 | 1999-03-11 | The Procter & Gamble Company | Hair conditioning compositions |
| JP2002338438A (en) * | 2001-05-18 | 2002-11-27 | Kao Corp | Hair-treatment agent composition |
| JP5297631B2 (en) * | 2007-11-13 | 2013-09-25 | 花王株式会社 | Skin external composition |
-
1988
- 1988-12-13 JP JP31540288A patent/JP2619833B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02160714A (en) | 1990-06-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2619833B2 (en) | Hair rinse composition | |
| JP2735940B2 (en) | Hair rinse composition | |
| JP2744519B2 (en) | Hair rinse composition | |
| JP2619834B2 (en) | Hair rinse composition | |
| JP2758494B2 (en) | Hair rinse composition | |
| JP2781645B2 (en) | Hair rinse composition | |
| JP3126544B2 (en) | Hair rinse composition | |
| JP3126545B2 (en) | Hair rinse composition | |
| JP3020683B2 (en) | Hair rinse composition | |
| JP3119962B2 (en) | Hair rinse composition | |
| JP2763820B2 (en) | Hair rinse composition | |
| JP2896257B2 (en) | Hair rinse composition | |
| JP3117839B2 (en) | Hair rinse composition | |
| JP2020121937A (en) | Hair dying composition | |
| JP2607440B2 (en) | Hair rinse composition | |
| JP3979495B2 (en) | Hair protectant | |
| JP2619835B2 (en) | Hair rinse composition | |
| JP2607439B2 (en) | Hair rinse composition | |
| JPH0645526B2 (en) | Hair-rinse composition | |
| JP2960587B2 (en) | Hair rinse composition | |
| JP2896258B2 (en) | Hair rinse composition | |
| JP2902797B2 (en) | Hair rinse composition | |
| JPH0558857A (en) | Hair rinse agent composition | |
| JP2735939B2 (en) | Hair rinse composition | |
| JP3979496B2 (en) | Hair protectant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| R371 | Transfer withdrawn |
Free format text: JAPANESE INTERMEDIATE CODE: R371 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| S202 | Request for registration of non-exclusive licence |
Free format text: JAPANESE INTERMEDIATE CODE: R315201 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080311 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 12 Free format text: PAYMENT UNTIL: 20090311 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090311 Year of fee payment: 12 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 12 Free format text: PAYMENT UNTIL: 20090311 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090311 Year of fee payment: 12 |
|
| EXPY | Cancellation because of completion of term |