JP3119962B2 - Hair rinse composition - Google Patents

Hair rinse composition

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Publication number
JP3119962B2
JP3119962B2 JP05085352A JP8535293A JP3119962B2 JP 3119962 B2 JP3119962 B2 JP 3119962B2 JP 05085352 A JP05085352 A JP 05085352A JP 8535293 A JP8535293 A JP 8535293A JP 3119962 B2 JP3119962 B2 JP 3119962B2
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JP
Japan
Prior art keywords
hair
group
weight
present
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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JP05085352A
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Japanese (ja)
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JPH06271431A (en
Inventor
龍雄 大島
Original Assignee
鐘紡株式会社
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Priority to JP05085352A priority Critical patent/JP3119962B2/en
Publication of JPH06271431A publication Critical patent/JPH06271431A/en
Application granted granted Critical
Publication of JP3119962B2 publication Critical patent/JP3119962B2/en
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Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、ヘアーリンス剤に関
し、更に詳しくは、毛髪に対し、艶,なめらかさ及び仕
上がりのしっとり感を大幅に改善するとともに、その他
の毛髪コンディショニング効果にも優れたヘアーリンス
剤組成物に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair rinsing agent, and more particularly to a hair rinsing agent which significantly improves gloss, smoothness, and moistness of the finish, and also has other excellent hair conditioning effects. It relates to a rinsing agent composition.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】毛髪の
汚れを除去するために、アニオン界面活性剤を主成分と
するシャンプーで洗髪すると、毛髪の汚れのほか毛髪表
面を保護している油分も同時に除去され、艶のないくし
通りの悪い髪となり、毛髪の損傷、枝毛,切毛が発生し
易くなる。
2. Description of the Related Art In order to remove hair stains, if the hair is washed with a shampoo containing an anionic surfactant as a main component, not only the hair stains but also the oil protecting the hair surface is reduced. At the same time, the hair is removed, resulting in a dull and poorly combed hair, and hair damage, split ends, and cut hairs are likely to occur.

【0003】そこで、これらの弊害を防ぐ目的で、カチ
オン界面活性剤である第4級アンモニウム塩を有効成分
とするヘアーリンス剤が使用されている。
[0003] For the purpose of preventing these problems, a hair rinse agent containing a quaternary ammonium salt as a cationic surfactant as an active ingredient has been used.

【0004】これらのヘアーリンス剤は、毛髪にコンデ
ィショニング効果(柔軟性,しっとり感,なめらかさ,
くし通り性,艶)を付与することを目的とするものであ
るが、第4級アンモニウム塩のみでは、艶,なめらかさ
及び仕上がりのさらさら感に関して充分な効果が得られ
ない。従って、従来のヘアーリンス剤にはこれらの欠点
を改善するために、高級アルコール,グリセライド,流
動パラフィン等の油脂類を配合することが提案されてい
る。また近年、毛髪の艶,なめらかさの改良を目的にシ
リコンガムを用いたヘアケア製品も提案されている。
[0004] These hair rinses have a conditioning effect (flexibility, moist feeling, smoothness,
It is intended to impart combability and gloss), but a quaternary ammonium salt alone cannot provide a sufficient effect on gloss, smoothness and smoothness of finish. Accordingly, it has been proposed to incorporate oils and fats such as higher alcohols, glycerides, and liquid paraffin in conventional hair rinses in order to improve these disadvantages. In recent years, hair care products using silicone gum have been proposed for the purpose of improving the gloss and smoothness of hair.

【0005】しかしながら、これらのシリコンガムを用
いたヘアケア製品も、消費者が連用する過程で毛髪に付
着したシリコンガムが部分的に脱離するものであって、
なめらかさ,くし通り性,艶において満足のゆくものが
得られていないのが実情であった。
[0005] However, in hair care products using these silicone gums, the silicone gums attached to the hair are partly detached in the process of continuous use by consumers.
In fact, it was not possible to obtain satisfactory smoothness, combability, and luster.

【0006】即ち本発明は、洗浄により適度な脱離性を
有すると共に、毛髪の艶,なめらかさ及び仕上がりのし
っとり感を大幅に改善するヘアーリンス剤を提供するこ
とを目的としている。
[0006] That is, an object of the present invention is to provide a hair rinsing agent which has an appropriate releasing property upon washing and which significantly improves gloss, smoothness and moist feeling of finish of hair.

【0007】[0007]

【課題を解決するための手段】上記の目的を達成するた
めに、本発明のヘアーリンス剤組成物は、次のような構
成をとっている。即ち、(A)一般式(I)
Means for Solving the Problems To achieve the above object, the hair rinse composition of the present invention has the following constitution. That is, (A) general formula (I)

【化4】 (式中、R1 〜R4 の1〜2個は炭素数12〜24の長
鎖アルキル基を示し、残余は炭素数1〜3のアルキル基
又はベンジル基を示し、Xはハロゲン原子を示す。)で
表わされる第4級アンモニウム塩の一種または二種以上
0.3〜5重量%と (B)一般式(II)
Embedded image (Wherein, 1 to 2 of R 1 to R 4 represent a long-chain alkyl group having 12 to 24 carbon atoms, the remainder represents an alkyl group having 1 to 3 carbon atoms or a benzyl group, and X represents a halogen atom. One or more quaternary ammonium salts represented by the formula (B): 0.3 to 5% by weight;

【化5】 {式中、R5 は総てがメチル基またはその一部がフェニ
ル基(ただし、R5 の総数の90%以上はメチル基)、
6 はメチル基または水酸基を示す。またmは900〜
1300の整数を示す。}で表わされるシリコーンの一
種または二種以上0.3〜3重量%と (C)一般式(III)
Embedded image {In the formula, all of R 5 are methyl groups or a part thereof is a phenyl group (however, 90% or more of the total number of R 5 is a methyl group);
R 6 represents a methyl group or a hydroxyl group. M is 900 ~
Indicates an integer of 1300. One or more of the silicones represented by}, 0.3 to 3% by weight, and (C) a general formula (III)

【化6】 {式中、R5 は総てがメチル基またはその一部がフェニ
ル基(ただし、R5 の総数の90%以上はメチル基)、
6 はメチル基または水酸基を示す。またnは100〜
300の整数を示す。}で表わされるシリコーンの一種
または二種以上1〜7重量%とを含有することを特徴と
するヘアーリンス剤組成物である。
Embedded image {In the formula, all of R 5 are methyl groups or a part thereof is a phenyl group (however, 90% or more of the total number of R 5 is a methyl group);
R 6 represents a methyl group or a hydroxyl group. Also, n is 100 to
Indicates an integer of 300. A hair rinse composition containing 1 to 7% by weight of one or more of silicones represented by}.

【0008】本発明における前記一般式(I)で表わさ
れる第4級アンモニウム塩としては、通常のヘアーリン
ス剤等に配合され得るすべてのものが使用される。例え
ば、ジメチルジオクタデシルアンモニウムクロライド,
オクタデシルトリメチルアンモニウムクロライド,ドデ
シルトリメチルアンモニウムクロライド,ベンジルジメ
チルオクタデシルアンモニウムクロライド,ジドデシル
ジメチルアンモニウムクロライド,ベンジルジエチルド
デシルアンモニウムクロライド,ヘキサデシルトリメチ
ルアンモニウムクロライド,ドデシルトリメチルアンモ
ニウムブロミド,ドコシルトリメチルアンモニウムクロ
ライド,ジドデシルジメチルアンモニウムブロミドなど
が挙げられる。
As the quaternary ammonium salt represented by the general formula (I) in the present invention, all that can be blended with a usual hair rinse agent and the like are used. For example, dimethyldioctadecyl ammonium chloride,
Octadecyltrimethylammonium chloride, dodecyltrimethylammonium chloride, benzyldimethyloctadecylammonium chloride, didodecyldimethylammonium chloride, benzyldiethyldodecylammonium chloride, hexadecyltrimethylammonium chloride, dodecyltrimethylammonium bromide, docosyltrimethylammonium chloride, didodecyldimethylammonium bromide And the like.

【0009】本発明のヘアーリンス剤組成物には、これ
らのカチオン界面活性剤の一種または二種以上の混合物
を総量を基準として0.3〜5重量%(以下wt%と略
記する)好ましくは0.5〜4wt%配合される。配合
量が0.3wt%未満では、毛髪コンディショニング効
果に良好な結果が得られず、5wt%を超えると毛髪に
べたつきが生じ好ましくない。
The hair rinse composition of the present invention contains one or more of these cationic surfactants in an amount of from 0.3 to 5% by weight (hereinafter abbreviated as wt%), preferably based on the total amount. 0.5 to 4 wt% is blended. If the amount is less than 0.3% by weight, good results for the hair conditioning effect cannot be obtained. If the amount exceeds 5% by weight, the hair becomes sticky, which is not preferable.

【0010】本発明における前記一般式(II)で表わさ
れるシリコーンとしては、例えばジメチルポリシロキサ
ン,メチルフェニルポリシロキサン,末端水酸基含有ジ
メチルポリシロキサン,末端水酸基含有メチルフェニル
ポリシロキサンなどが挙げられる。
The silicone represented by the general formula (II) in the present invention includes, for example, dimethylpolysiloxane, methylphenylpolysiloxane, dimethylpolysiloxane having a terminal hydroxyl group, and methylphenylpolysiloxane having a terminal hydroxyl group.

【0011】本発明で使用するシリコーンの平均重合度
mは900〜1300であり、好ましくは1000〜1
200である。平均重合度が900に満たないものは効
果がなく、平均重合度が1300を超えると毛髪のしっ
とり感が劣り好ましくない。
The silicone used in the present invention has an average polymerization degree m of 900 to 1300, preferably 1000 to 1300.
200. Those having an average degree of polymerization of less than 900 have no effect.

【0012】本発明のヘアーリンス剤組成物には、これ
らのシリコーンの一種または二種以上の混合物を総量を
基準として0.3〜3wt%好ましくは0.5〜2wt
%配合される。配合量が0.3wt%未満では、乾燥後
の毛髪のなめらかさ,しっとり感に良好な結果が得られ
ず、3wt%を超えると毛髪が重くなり好ましくない。
The hair rinse composition of the present invention contains one or more of these silicones in an amount of 0.3 to 3 wt%, preferably 0.5 to 2 wt%, based on the total amount.
%. If the amount is less than 0.3% by weight, good results cannot be obtained for the smoothness and moist feeling of the dried hair, and if it exceeds 3% by weight, the hair becomes undesirably heavy.

【0013】本発明における前記一般式(III) で表わさ
れるシリコーンとしては、例えばジメチルポリシロキサ
ン,メチルフェニルポリシロキサン,末端水酸基含有ジ
メチルポリシロキサン,末端水酸基含有メチルフェニル
ポリシロキサンなどが挙げられる。
Examples of the silicone represented by the general formula (III) in the present invention include dimethylpolysiloxane, methylphenylpolysiloxane, dimethylpolysiloxane having a terminal hydroxyl group, and methylphenylpolysiloxane having a terminal hydroxyl group.

【0014】本発明で使用するシリコーンの平均重合度
nは100〜300であり、好ましくは150〜250
である。平均重合度が100に満たないものは効果がな
く、平均重合度が300を超えるとなめらかさが劣り好
ましくない。
The average degree of polymerization n of the silicone used in the present invention is from 100 to 300, preferably from 150 to 250.
It is. Those having an average degree of polymerization of less than 100 have no effect, and those having an average degree of polymerization of more than 300 are unfavorable due to poor smoothness.

【0015】本発明のヘアーリンス剤組成物には、これ
らのシリコーンの一種または二種以上の混合物を総量を
基準として1〜7wt%好ましくは、1〜5wt%配合
される。配合量が1wt%未満では、乾燥後の毛髪のな
めらかさ,艶に良好な結果が得られず7wt%を超える
と毛髪にべたつきが生じ好ましくない。これらの
(B),(C)2成分の配合重量比は1:2〜1:6が
好ましい。
The hair rinse composition of the present invention contains 1 to 7 wt%, preferably 1 to 5 wt%, of one or more of these silicones based on the total amount. If the amount is less than 1% by weight, good results cannot be obtained for the smoothness and luster of the dried hair. If the amount exceeds 7% by weight, the hair becomes sticky, which is not preferable. The mixing weight ratio of these two components (B) and (C) is preferably 1: 2 to 1: 6.

【0016】本発明のヘアーリンス剤組成物は、上述し
た3成分を必須の構成成分とするが、当該組成物には、
本発明の目的を達成する範囲で他の成分を適宜配合する
ことができる。
The hair rinse composition of the present invention comprises the above-mentioned three components as essential components.
Other components can be appropriately blended within a range that achieves the object of the present invention.

【0017】即ち、流動パラフィン,ワセリン,スクワ
ラン等の炭化水素,イソプロピルミリステート,イソプ
ロピルパルミテート等のエステル油,ツバキ油,オリー
ブ油,アボガド油等の植物油,ポリグリセリン脂肪酸エ
ステル,ポリオキシエチレンソルビタン脂肪酸エステ
ル,ポリオキシエチレン硬化ヒマシ油等の非イオン界面
活性剤,メチルセルロース,ヒドロキシエチルセルロー
ス,カチオン化セルロース等のセルロース誘導体,エチ
レングリコール,プロピレングリコール,グリセリン等
の保湿剤,ポリペプチド,その他殺菌剤,フケ取り剤,
キレート剤,紫外線吸収剤,着色剤,香料などが挙げら
れこれらの一種または二種以上を配合することができ
る。
That is, liquid paraffin, hydrocarbons such as petrolatum, squalane and the like, ester oils such as isopropyl myristate and isopropyl palmitate, vegetable oils such as camellia oil, olive oil and avocado oil, polyglycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester , Nonionic surfactants such as polyoxyethylene hydrogenated castor oil, cellulose derivatives such as methylcellulose, hydroxyethylcellulose, and cationized cellulose; humectants such as ethylene glycol, propylene glycol, and glycerin; polypeptides; other disinfectants; ,
Examples thereof include a chelating agent, an ultraviolet absorber, a coloring agent, and a fragrance, and one or more of these can be blended.

【0018】次に実施例を挙げ本発明を説明するが、本
発明はこれら実施例に限定されるものではない。尚、本
実施例中で用いた試験方法は、下記のとおりである。
Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples. The test method used in this example is as follows.

【0019】(毛髪の艶,なめらかさ,くし通り性及び
仕上がりのしっとり感試験)各例における、毛髪の
「艶」,「なめらかさ」,「くし通り性」及び仕上がり
の「しっとり感」を女性20名の専門パネラーにて連用
後、官能的に比較し、下記基準で評価を行った。 ◎;良いと答えた人が18人以上の場合 ○;良いと答えた人が14〜17人の場合 △;良いと答えた人が8〜13人の場合 ×;良いと答えた人が7人以下の場合
(Test of gloss, smoothness, combability and finish moistness of hair) In each example, the "gloss", "smoothness", "comb passability" and "finishness" of the finish of the hair were evaluated by women. After continuous use by 20 specialized panelists, they were sensually compared and evaluated according to the following criteria. ◎: 18 or more answered good ○: 14 to 17 answered good △: 8 to 13 answered good ×: 7 answered good If you are less than

【0020】実施例1〜3,比較例1〜3 表1の上段に示す配合組成のヘアーリンス剤を通常の方
法で調製し、上記試験を行い表1の下段にその結果を示
した。
Examples 1 to 3 and Comparative Examples 1 to 3 Hair rinses having the composition shown in the upper part of Table 1 were prepared by a usual method, and the above test was conducted. The results are shown in the lower part of Table 1.

【0021】[0021]

【表1】 [Table 1]

【0022】実施例4〜6,比較例4〜10 表2に示す配合組成のヘアーリンス剤を通常の方法で調
製し、上記試験を行い表2の下段にその結果を示した。
Examples 4 to 6 and Comparative Examples 4 to 10 Hair rinses having the composition shown in Table 2 were prepared by a usual method, and the above test was conducted. The results are shown in the lower part of Table 2.

【0023】[0023]

【表2】 [Table 2]

【0024】実施例1〜6より明らかなように、本発明
のヘアーリンス剤組成物は、いずれも優れた性能を示し
た。一方、必須成分である第4級アンモニウム塩,シリ
コーンのどちらかを欠いた場合(比較例1〜3)、また
はこれらの配合量およびシリコーンの平均重合度(m,
n)が本発明の範囲外の場合(比較例4〜10)は、い
ずれも劣った性能を示し本発明の目的を達成できなかっ
た。
As is clear from Examples 1 to 6, all of the hair rinse compositions of the present invention exhibited excellent performance. On the other hand, when either the quaternary ammonium salt or the silicone, which is an essential component, is missing (Comparative Examples 1 to 3), or the blending amount thereof and the average degree of polymerization of the silicone (m,
When n) was out of the range of the present invention (Comparative Examples 4 to 10), all exhibited poor performance, and the object of the present invention could not be achieved.

【0025】[0025]

【発明の効果】以上記載のごとく、本発明は毛髪に対
し、艶,なめらかさ,くし通り性及び仕上がりのしっと
り感に優れた有用なるヘアーリンス剤組成物を提供する
ことは明らかである。
As described above, it is apparent that the present invention provides a useful hair rinse composition excellent in gloss, smoothness, combability and finish moistness to hair.

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 (A)一般式(I) 【化1】 (式中、R1 〜R4 の1〜2個は炭素数12〜24の長
鎖アルキル基を示し、残余は炭素数1〜3のアルキル基
又はベンジル基を示し、Xはハロゲン原子を示す。)で
表わされる第4級アンモニウム塩の一種または二種以上
0.3〜5重量%と (B)一般式(II) 【化2】 {式中、R5 は総てがメチル基またはその一部がフェニ
ル基(ただし、R5 の総数の90%以上はメチル基)、
6 はメチル基または水酸基を示す。またmは900〜
1300の整数を示す。}で表わされるシリコーンの一
種または二種以上0.3〜3重量%と (C)一般式(III) 【化3】 {式中、R5 は総てがメチル基またはその一部がフェニ
ル基(ただし、R5 の総数の90%以上はメチル基)、
6 はメチル基または水酸基を示す。またnは100〜
300の整数を示す。}で表わされるシリコーンの一種
または二種以上1〜7重量%とを含有することを特徴と
するヘアーリンス剤組成物。
(A) General formula (I) (Wherein, 1 to 2 of R 1 to R 4 represent a long-chain alkyl group having 12 to 24 carbon atoms, the remainder represents an alkyl group having 1 to 3 carbon atoms or a benzyl group, and X represents a halogen atom. ), And 0.3 to 5% by weight of one or more of the quaternary ammonium salts represented by the formula (II): {In the formula, all of R 5 are methyl groups or a part thereof is a phenyl group (however, 90% or more of the total number of R 5 is a methyl group);
R 6 represents a methyl group or a hydroxyl group. M is 900 ~
Indicates an integer of 1300. One or two or more silicones represented by} and 0.3 to 3% by weight of (C) a general formula (III) {In the formula, all of R 5 are methyl groups or a part thereof is a phenyl group (however, 90% or more of the total number of R 5 is a methyl group);
R 6 represents a methyl group or a hydroxyl group. Also, n is 100 to
Indicates an integer of 300. A hair rinse composition comprising 1 to 7% by weight of one or more silicones represented by}.
JP05085352A 1993-03-19 1993-03-19 Hair rinse composition Expired - Fee Related JP3119962B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP05085352A JP3119962B2 (en) 1993-03-19 1993-03-19 Hair rinse composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP05085352A JP3119962B2 (en) 1993-03-19 1993-03-19 Hair rinse composition

Publications (2)

Publication Number Publication Date
JPH06271431A JPH06271431A (en) 1994-09-27
JP3119962B2 true JP3119962B2 (en) 2000-12-25

Family

ID=13856300

Family Applications (1)

Application Number Title Priority Date Filing Date
JP05085352A Expired - Fee Related JP3119962B2 (en) 1993-03-19 1993-03-19 Hair rinse composition

Country Status (1)

Country Link
JP (1) JP3119962B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09323916A (en) * 1996-06-04 1997-12-16 Shiseido Co Ltd Cosmetic material

Also Published As

Publication number Publication date
JPH06271431A (en) 1994-09-27

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