JP5172214B2 - Hair cosmetics - Google Patents

Description

  The present invention is a hair cosmetic, in particular, it has a sticky feeling when applied and has an excellent feeling of conformity, and has a very good smoothness when rinsed, and the hair after drying has both a moist feeling and a smooth feeling, The present invention relates to a hair cosmetic which is excellent in softness and smoothness of hair.

After washing hair with shampoo or the like, gloss and fingering generally deteriorate, and thus treatment agents such as hair conditioners have been used after shampooing.
A treatment agent such as a hair conditioner usually contains a cationic surfactant, an oil or the like as a main component. Cationic surfactants are highly effective in imparting flexibility and antistatic properties to hair, so they are incorporated into various hair cosmetics including treatment agents. However, since they lack gloss and smoothness, they usually contain various oils. Is blended.

Patent Document 1 describes that a hair cosmetic blended with a specific amino-modified or ammonium-modified silicone has an excellent hair protecting effect and can impart moist feeling, softness, smoothness and the like. Further, it is described that, by further adding a quaternary ammonium salt, the adsorptivity to the hair can be further improved, the hair can be smooth and glossy, and the combing can be improved.
However, it cannot be said that the feeling of use and the conditioning effect are sufficiently satisfactory at all stages from the time of application to rinsing and after drying, and further improvement has been desired.
JP 2006-117606 A

  The present invention has been made in view of the above-mentioned problems of the prior art, and its purpose is that it is well-familiar with hair, excellent in smoothness and fingering during rinsing, and imparts smoothness and softness to hair after drying. And it is providing the hair cosmetics which can fully provide a moist feeling while having a smooth feeling.

As a result of intensive studies by the present inventors in order to solve the above problems, a highly polymerized silicone emulsion and xyloglucan are blended into a hair cosmetic containing a specific amino-modified or ammonium-modified silicone and a quaternary ammonium salt. As a result, it was found that when applied, it had a sticky feeling and was well adapted to the hair, and in addition, a synergistically excellent effect was exhibited in the feeling of use after rinsing or after drying. In addition, the present inventors have found that an excellent effect can be obtained when a tertiary amine is used instead of a quaternary ammonium salt, and the present invention has been completed.
That is, the hair cosmetic according to the present invention is characterized by containing the following components (A), (B), (C) and (D).

［式（Ｉ）中、Ｒ¹はそれぞれ独立してメチル基、フェニル基又は水酸基である。Ｒ²はそれぞれ独立して式Ｒ⁴Ｚで表される基であり、Ｒ⁴は炭素数３〜６のアルキレン基、Ｚは窒素含有基であり、下記式： (A) Amino-modified or ammonium-modified silicone represented by the following general formula (I).

[In formula (I), each R ¹ independently represents a methyl group, a phenyl group or a hydroxyl group. R ² is each independently a group represented by the formula R ⁴ Z, R ⁴ is an alkylene group having 3 to 6 carbon atoms, Z is a nitrogen-containing group, and the following formula:

（Ｒ⁵はそれぞれ独立して水素原子又は炭素数１〜３０のアルキル基、Ｒ⁶は炭素数１〜３０のアルキル基、Ａは塩素原子又は臭素原子又はヨウ素原子、ｂは２〜６の整数である。）で表される基である。ａは０〜３の整数であり、ｍ及びｎはそれぞれ正の整数で、ｍ＋ｎの平均値は４０００〜６０００、ｎ／ｍの平均値は０．００２〜０．０３である。］

(R ⁵ is independently a hydrogen atom or an alkyl group having 1 to 30 carbon atoms, R ⁶ is an alkyl group having 1 to 30 carbon atoms, A is a chlorine atom, bromine atom or iodine atom, b is an integer of 2 to 6) It is a group represented by. a is an integer of 0 to 3, m and n are each a positive integer, the average value of m + n is 4000 to 6000, and the average value of n / m is 0.002 to 0.03. ]

(B) Highly polymerized organopolysiloxane represented by the following average composition formula (II).
[R ^a R ^b SiO] x (II)
[In the formula (II), R ^a is a methyl group or an aryl group, and R ^b is a methyl group or a hydroxyl group. x is a positive integer representing the degree of siloxane polymerization in a range where the organopolysiloxane exhibits a viscosity of 5 million mPa · s or more at 25 ° C. ]

(C) A compound selected from the group consisting of a xyloglucan (D) quaternary ammonium salt represented by the general formula (III) and a tertiary amine represented by the general formula (IV).

[式（III）中、Ｒ¹，Ｒ²，Ｒ³及びＲ⁴は少なくとも１個は総炭素数８〜３５の、−Ｏ−、−ＯＣＯ−もしくは−ＣＯＯ−で表される官能基で分断又は−ＯＨで置換されていてもよい、直鎖もしくは分岐鎖のアルキル基、アルケニル基、あるいは脂肪族アシルオキシ（ポリエトキシ）エチル基を示し、残余は炭素数１〜５のアルキル基もしくはヒドロキシアルキル基、又は合計付加モル数１０以下のポリオキシエチレン基を示す。Ｘ^-はハロゲンイオン又は有機アニオンを示す。]

[In the formula (III), at least one of R ¹ , R ² , R ³ and R ⁴ is divided by a functional group having a total carbon number of 8 to 35 and represented by —O—, —OCO— or —COO—. Or a linear or branched alkyl group, an alkenyl group, or an aliphatic acyloxy (polyethoxy) ethyl group optionally substituted with —OH, the remainder being an alkyl group or hydroxyalkyl group having 1 to 5 carbon atoms, Alternatively, it represents a polyoxyethylene group having a total number of added moles of 10 or less. X ⁻ represents a halogen ion or an organic anion. ]

［式（IV）中、Ｒ⁵は総炭素数８〜３５の、−Ｏ−もしくは−ＣＯＮＨ−で表される官能基で分断又は−ＯＨで置換されていてもよい、直鎖もしくは分岐鎖のアルキル基又はアルケニル基を示す。Ｒ⁶は炭素数１〜２２のアルキル基、アルケニル基又はヒドロキシアルキル基を示し、２個のＲ⁶は同一でも異なっていても良い。］

[In the formula (IV), R ⁵ is a linear or branched chain having a total carbon number of 8 to 35, which may be divided by a functional group represented by —O— or —CONH— or substituted with —OH. An alkyl group or an alkenyl group is shown. R ⁶ represents an alkyl group, alkenyl group or hydroxyalkyl group having 1 to 22 carbon atoms, and two R ^{6 s} may be the same or different. ]

In the hair cosmetic composition of the present invention, the component (A) is preferably 0.01 to 10.0% by mass in the hair cosmetic composition.
Moreover, it is suitable that a component (B) is 0.01-10.0 mass% in silicone pure in hair cosmetics.
Moreover, it is suitable that a component (C) is 0.01-10.0 mass% in hair cosmetics.
Moreover, it is suitable that a component (D) is 0.01-10.0 mass% in hair cosmetics.
In the hair cosmetic composition of the present invention, it is preferable to further contain at least one of a polyhydric alcohol and / or a sugar alcohol as the component (E).
Moreover, it is preferable that the hair cosmetic composition of the present invention is a hair conditioner composition.

  The hair cosmetic composition of the present invention comprises a highly polymerized organopolysiloxane and xyloglucan together with a specific amino-modified / ammonium-modified silicone and a quaternary ammonium salt / tertiary amine. It has excellent familiarity, smoothness and rinsing after rinsing, smoothness after drying, moistness, smoothness, softness, etc. It is possible to exhibit an excellent feel at all stages until after.

<Amino-modified or ammonium-modified silicone>
The amino-modified or ammonium-modified silicone of component (A) used in the hair cosmetic composition of the present invention is represented by the general formula (I).
The average value of the degree of polymerization m + n in the modified silicone (I) is preferably in the range of 4000 to 6000. If it is less than 4000 (low degree of polymerization), the effect is insufficient and stickiness occurs. In addition, the stability of the compound itself is deteriorated. If it exceeds 6000 (the degree of polymerization is high), the finish will be non-uniform and the hair will be stiff. In addition, blending into hair cosmetics becomes difficult.

The average value of n / m is preferably 0.002 to 0.03, particularly preferably 0.005 to 0.01. If it is less than 0.002 (low amination rate), the adsorptivity to hair is poor and the sustainability of the effect tends to be poor. On the other hand, if it exceeds 0.03 (amination rate is too high), a sticky feeling is imparted to the hair.
The amino-modified or ammonium-modified silicone can be used alone or in combination of two or more. Even when two or more types are used in combination, the average value of m + n and n / m needs to be within the above range.

The amino-modified or ammonium-modified silicone of the present invention can be produced by the same production method as a general amino-modified or ammonium-modified silicone. For example, it can be produced by subjecting γ-aminopropylmethyldiethoxysilane, cyclic dimethylpolysiloxane, and hexamethyldisiloxane to a polycondensation reaction in the presence of an alkali catalyst.
The compounding amount of the amino-modified or ammonium-modified silicone in the present invention is 0.01 to 10% by mass, preferably 0.1 to 5% by mass in the total amount of the hair cosmetic. If the amount is too small, a sufficient effect cannot be obtained. If the amount is too large, the stability of the preparation deteriorates and the touch is not excellent.

Since the amino-modified or ammonium-modified silicone of the present invention has a high viscosity, it is preferably dissolved in a low-viscosity liquid oil and blended in the hair cosmetic. Examples of the low-viscosity liquid oil include chain silicone, cyclic silicone, and isoparaffinic hydrocarbon.
Examples of the chain silicone oil include dimethylpolysiloxane (viscosity 0.65 to 200 cSt / 25 ° C.).
Examples of the cyclic silicone oil include octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and tetradecamethylcyclohexasiloxane.
Examples of isoparaffinic hydrocarbons include isoparaffinic hydrocarbons having a boiling point in the range of 60 to 260 ° C. under normal pressure, such as Isopar A (registered trademark), C, D, E, G, H, K, L, M, Shellsol 71 (registered trademark) from Shell, Saltol 100 (registered trademark) from Philip or 130, 220, etc. .

As the low-viscosity liquid oil, any one or two or more kinds can be used, and the total blending amount is preferably 1 to 50 times (mass) with respect to amino modification or ammonium modification, It is preferable that it is 1-90 mass%.
The amino-modified or ammonium-modified silicone and the low-viscosity liquid oil may be separately blended in the hair cosmetic and dissolved in the system.

<Highly polymerized organopolysiloxane>
The highly polymerized organopolysiloxane of component (B) used in the present invention is a highly polymerized linear organopolysiloxane represented by the average composition formula (II): [R ^a R ^b SiO] x.
In the average composition formula, R ^a is a methyl group or an aryl group, and R ^b is a methyl group or a hydroxyl group, and is preferably a diorganopolysiloxane. Examples of the aryl group include a phenyl group (—C ₆ H ₅ ) and a trityl group (—C (C ₆ H ₅ ) ₃ ). The molecular terminal of the organopolysiloxane may be any of a hydroxyl group, an alkyl group, and an aryl group.

x is a positive number indicating the degree of siloxane polymerization, and is preferably in a range where the organopolysiloxane has a viscosity of 5 million mPa · s or more, more preferably 10 million mPa · s or more at 25 ° C.
In order to stably blend such a highly polymerized silicone in cosmetics, it is preferable to blend it as an aqueous silicone emulsion dispersed as emulsion particles in an aqueous medium. The average particle size of the highly polymerized organopolysiloxane in the silicone emulsion is not particularly limited, but is preferably 0.2 μm to 20.0 μm.

Although it does not specifically limit as an aqueous medium, Usually, water is the main component and surfactant and other aqueous components can be included as needed.
It is possible to dissolve the high-polymerized organopolysiloxane in advance in a solvent such as low-viscosity silicone oil without emulsifying it, or to emulsify it in hair cosmetics to make an emulsion. It may be difficult to blend in cosmetics and the effects of the present invention may not be sufficiently obtained.

  In the present invention, the blending amount of the highly polymerized organopolysiloxane (B) is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% in the hair cosmetic composition as a pure silicone content. If the blending amount is too small, the effect of the present invention cannot be obtained, and if it is too large, the feel may be lowered or stickiness may occur.

The aqueous emulsion of highly polymerized organopolysiloxane used in the present invention can be produced by a known method. Examples thereof include a mechanical emulsification method and an emulsion polymerization method. The emulsion polymerization method is preferable because the particle size can be easily controlled and a sharp particle size distribution can be obtained.
Regarding the emulsion polymerization method, for example, a method of emulsion polymerization while dropping a crude emulsion comprising dimethylpolysiloxane having a small degree of polymerization, a surfactant, and water into an aqueous solution containing a polymerization catalyst and a surfactant is disclosed in JP-A-63-63. No. 183517. JP-A-62-141029 also describes an emulsion polymerization method.

<Xyloglucan>
The component (C) xyloglucan used in the present invention is a general term for non-starch plant polysaccharides present in seeds and cell walls, and β-D-glucose constituting the main chain and xylose constituting the side chain. Group and a galactoxylose group.
In the present invention, it is the main component of the seed of leguminous plant tamarind (Tamarindus indica) mainly produced in the tropics, and xylose and galactose are side chains in the main chain composed of β-1,4-glucan. A xyloglucan having a structure represented by the following general formula (V) can be particularly preferably used.

（式（V）中、ｇｌｕはグルコース単位、ｘｙｌはキシロース単位、ｇａｌはガラクトース単位を表し、ｎは結合数を表す）

(In formula (V), glu represents a glucose unit, xyl represents a xylose unit, gal represents a galactose unit, and n represents the number of bonds)

  This xyloglucan has excellent chemical stability such as safety, dispersibility, moisture retention, acid resistance, heat resistance, salt resistance, etc. The property is also good. Although xyloglucan is a water-soluble polymer, its aqueous solution is not sticky and gives a refreshing feel.

  Note that xyloglucan behaves in such a way that the intermolecular entanglement is reduced and the viscosity is lowered in a system with a high water content. Therefore, the hair cleansing material of the present invention has a characteristic that it is excellent in detergency that it can be easily rinsed away with water while being sticky when used. Moreover, since the hair washing composition of the present invention is excellent in detergency, there is no fear of hair damage or skin irritation after use, and it can be made into a very safe hair cosmetic composition.

In the present invention, a commercially available product (for example, trade name “Glyroid”, manufactured by Dainippon Sumitomo Pharma Co., Ltd.) may be used as xyloglucan. This is widely used as a food thickener in sauces and ice creams. In addition, when mix | blending a commercial item with the hair cosmetics of this invention, it is preferable to use what was refine | purified as much as possible.
Further, the average molecular weight of xyloglucan blended in the hair washing material is preferably 100,000 to 2,000,000, particularly preferably around 650,000 in view of viscosity and stability.

Xyloglucan can be produced by a method described in the above-mentioned “Glyroid” product catalog. That is, foreign substances are removed from the seeds of tamarind, and this is dipped and pulverized to remove impurities from the pulverized product, washed and dried, and finally finely pulverized to obtain xyloglucan.
The amount of xyloglucan in the composition of the present invention is 0.01 to 10% by mass, preferably 0.1 to 1.0% by mass, based on the total amount of the hair cosmetic. If the amount is too small, sufficient effects cannot be obtained, and if the amount is too large, the feel is not excellent.

<Quaternary ammonium salt>
The quaternary ammonium salt of component (D) used in the present invention is represented by the following general formula (III).

In the general formula (III), at least one of R ¹ , R ² , R ³ and R ⁴ is —O—, —OCO— or —COO— having a total carbon number of 8 to 35 (preferably 8 to 26). A linear or branched alkyl group, an alkenyl group, or an aliphatic acyloxy (polyethoxy) ethyl group which may be divided by the functional group represented or substituted with —OH, and the remainder has 1 to 5 carbon atoms An alkyl group or a hydroxyalkyl group, or a polyoxyethylene group having a total number of added moles of 10 or less is shown. X ⁻ represents a halogen ion or an organic anion.

In general formula (III), preferably ¹ , 2 or 3 of R ¹ , R ² , R ³ and R ⁴ are long-chain groups, and the remainder is an alkyl group or hydroxyalkyl group having 1 to 5 carbon atoms. Or a polyoxyethylene group having a total number of added moles of 10 or less.

Examples of compounds in which one of R ¹ , R ² , R ³ and R ⁴ is a long chain group include stearyl trimethyl ammonium chloride, hydroxystearyl trimethyl ammonium chloride, capryl trimethyl ammonium chloride, myristyl trimethyl ammonium chloride, cetyl Examples thereof include trimethylammonium chloride, cetyltriethylammonium bromide, behenyltrimethylammonium chloride, lauryltrimethylammonium chloride, N-stearyl-N, N, N-tri (polyoxyethylene) ammonium chloride (total addition of 3 mol).

Examples of compounds in which two of R ¹ , R ² , R ³ and R ⁴ are long chain groups include, for example, distearyl dimethyl ammonium chloride, di-cured tallow alkyl dimethyl ammonium chloride, di tallow alkyl dimethyl ammonium bromide, geo Raildimethylammonium chloride, dipalmitylmethylhydroxyethylammonium methosulfate, distearyldimethylammonium chloride, diisostearyldimethylammonium methosulfate, di [(2-dodecanoylamino) ethyl] dimethylammonium chloride, di [(2-stearoyl Amino) propyl] dimethylammonium etosulphate and the like.

Examples of compounds in which three of R ¹ , R ² , R ³ and R ⁴ are long-chain groups include, for example, dioleyl monostearyl methyl ammonium chloride, dioleyl monobehenyl methyl ammonium chloride, trioleyl methyl ammonium chloride, Examples include tristearylmethylammonium methosulfate.

(III-1)
［式（III-1）中、Ｒ¹⁸は（ａ）ＣＨ₃−(ＣＨ₂)_i−ＣＨ(Ｒ²⁴)−ＣＨ₂−（式中、Ｒ²⁴はメチル基又はエチル基を示し、ｉはアルキル基中の合計炭素数が８〜１６となる整数を示す）で表される分岐鎖アルキル基及び（ｂ）ＣＨ₃−(ＣＨ₂)_j−（ｊは７〜１５の整数を示す）で表される直鎖アルキル基の混合物で、その分岐鎖率（ａ）／［（ａ）＋（ｂ）］が１０〜１００モル％である基を示す。Ｒ¹⁹及びＲ²⁰はそれぞれ炭素数１〜３のアルキル基又はヒドロキシアルキル基を示す。Ｘ^-は前記一般式（III）と同じである。］ Examples of the quaternary ammonium salt of the general formula (III) include branched quaternary ammonium salts represented by the following general formula (III-1) or (III-2).

(III-1)
[In the formula (III-1), R ¹⁸ represents (a) CH ₃ — (CH ₂ ) _i —CH (R ²⁴ ) —CH ₂ — (wherein R ²⁴ represents a methyl group or an ethyl group; A branched chain alkyl group represented by (b) CH ₃ — (CH ₂ ) _j — (j represents an integer of 7 to 15). In the mixture of linear alkyl groups represented, the branched chain ratio (a) / [(a) + (b)] is 10 to 100 mol%. R ¹⁹ and R ²⁰ each represent an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group. X ⁻ is the same as in the general formula (III). ]

(III-2)
［式（III-2）中、Ｒ¹⁹及びＲ²⁰はそれぞれ炭素数１〜３のアルキル基又はヒドロキシアルキル基を示す。Ｒ²¹及びＲ²²はそれぞれ炭素数２〜１２のアルキル基を示す。Ｒ²³はＲ²¹−ＣＨ₂ＣＨ₂ＣＨ（Ｒ²²）ＣＨ₂−で表される基又は炭素数１〜３のアルキル基を示す。Ｘ^-は前記一般式(III)と同じである。］

(III-2)
[In the formula (III-2), R ¹⁹ and R ²⁰ each represent an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group. R ²¹ and R ²² each represent an alkyl group having 2 to 12 carbon atoms. R ²³ represents a group represented by R ²¹ —CH ₂ CH ₂ CH (R ²² ) CH ₂ — or an alkyl group having 1 to 3 carbon atoms. X ⁻ is the same as in the general formula (III). ]

The branched quaternary ammonium salt represented by the general formula (III-1) is usually synthesized using, for example, an oxo alcohol having 8 to 16 carbon atoms as an example. Examples thereof include dialkyldimethylammonium salts having dialkyl groups and dialkylmethylhydroxyethylammonium salts.
In the present invention, those having a branched chain ratio of R ^{18 in} the general formula (III-1) of usually 10 to 100 mol% are used, and those having 10 to 50 mol% are particularly preferred. In addition, R ^{18 having} a total carbon number of 8 to 16 is used, but those having a certain distribution are preferable. In particular, C _{8 to} C _{11 is} 5 mol% or less, and C _{12 is} 10 to 35 mol%. , C ₁₃ : 15 to 40 mol%, C ₁₄ : 20 to 45 mol%, C ₁₅ : 5 to 30 mol%, and C ₁₆ : 5 mol% or less are preferable.
Specific examples of such a branched quaternary ammonium salt include dialkyldimethylammonium chloride having an alkyl group having 8 to 16 carbon atoms and a branched chain ratio of 10 to 50 mol%.

を原料として合成されるものである。 In addition, the branched quaternary ammonium salt represented by the general formula (III-2) is usually a gerber alcohol having 8 to 28 carbon atoms:

Is synthesized as a raw material.

  Among the branched quaternary ammonium salts, preferred are, for example, alkyltrimethylammonium salts, dialkyldimethylammonium salts, dialkylmethylhydroxyethylammonium salts having an alkyl group derived from Gerve alcohol having 8 to 28 carbon atoms, and the like. Can be mentioned. Further, among these, particularly preferred are, for example, 2-decyltetradecyltrimethylammonium chloride, 2-dodecylhexadecyltrimethylammonium chloride, di-2-hexyldecyldimethylammonium chloride, di-2-octyldodecyldimethylammonium chloride. Etc.

  In addition, among the quaternary ammonium salts represented by the general formula (III), an alkyl or alkenyl group or an aliphatic acyloxy (poly) ethoxyethyl group separated by -O-, -COO- or -OCO- Examples of the two quaternary ammonium salts include those represented by the following general formula (III-3).

(III-3)
［式（III-3）中、Ｒ²⁵及びＲ²⁶はそれぞれヒドロキシル基で置換されていてもよい炭素数８〜２２のアルキル基又はアルケニル基を示す。Ｒ²⁷及びＲ²⁸はそれぞれ炭素数１〜３のアルキル基又は−(ＣＨ₂ＣＨ₂Ｏ)_pＨ（ｐは１〜６の数を示す）を示す。ｋ及びｍは０〜５の数を示す。Ｘ^-は前記一般式（III）と同じである。］

(III-3)
[In Formula (III-3), R ²⁵ and R ²⁶ each represents an alkyl group or alkenyl group having 8 to 22 carbon atoms which may be substituted with a hydroxyl group. R ²⁷ and R ²⁸ each represent an alkyl group having 1 to 3 carbon atoms or — (CH ₂ CH ₂ O) _p H (p represents a number of 1 to 6). k and m each represent a number from 0 to 5. X ⁻ is the same as in the general formula (III). ]

Examples of the quaternary ammonium salt represented by the general formula (III-3) include those described in WO93 / 10748, WO92 / 06899, WO94 / 16677, and the like. In particular, in general formula (III-3), R ²⁵ and R ²⁶ are oleyl groups or alkyl groups having 12 to 18 carbon atoms, R ²⁷ is a methyl group, R ²⁸ is —CH ₂ CH ₂ OH, k and m are Zero is preferred.

  Further, among the quaternary ammonium salts represented by the general formula (III), a quaternary ammonium salt having one alkyl group or alkenyl group that is divided by a functional group represented by -OCO- or -COO-. Examples thereof include quaternary ammonium salts represented by the following general formula (III-4) or (III-5).

（III-4）

(III-4)

(III-5)
［式(III-4)及び（III-5）中、Ｒ²⁹は炭素数７〜２５のアルキル基又はアルケニル基を示す。Ｒ³⁰は炭素数１〜５のアルキレン基を示す。Ｒ³¹、Ｒ³²及びＲ³³はそれぞれ炭素数１〜４のアルキル基又はヒドロキシアルキル基を示す。Ｘ^-は一般式（III）と同じである。］

(III-5)
[In the formulas (III-4) and (III-5), R ²⁹ represents an alkyl group or alkenyl group having 7 to 25 carbon atoms. R ³⁰ represents an alkylene group having 1 to 5 carbon atoms. R ³¹ , R ³² and R ³³ each represent an alkyl group having 1 to 4 carbon atoms or a hydroxyalkyl group. X ⁻ is the same as in general formula (III). ]

In the general formulas (III-4) and (III-5), R ²⁹ is preferably a linear or branched alkyl or alkenyl group having 7 to 18 carbon atoms, particularly 11 to 18 carbon atoms. R ³⁰ is preferably an ethylene group or an n-propylene group. R ³¹ , R ³² and R ³³ are preferably a methyl group, an ethyl group, a hydroxyethyl group or a hydroxypropyl group.
Examples of the quaternary ammonium salts of the general formulas (III-4) and (III-5) include those described in JP 2000-128740 A or JP 2000-143458 A.

In the general formula (III), specific examples of X ⁻ which is a counter ion of the quaternary ammonium salt include halogen ions such as chlorine, iodine and bromine; alkyl sulfate ions having 1 to 5 carbon atoms (CH ₃ SO ₄ ^{− _{, C 2 H 5 SO 4 -}} , C 3 H 7 SO 4 - , etc.), alkyl phosphate ions (meth phosphate, ethoxy phosphate, etc.), alkyl carbonate ion (CH ₃ CO ₃ ^-), organic anions and the like Preferred are Cl ⁻ , Br ⁻ , CH ₃ SO ₄ ⁻ , C ₂ H ₅ SO ₄ ⁻ , and CH ₃ CO ₃ ^— .

Among the quaternary ammonium salts represented by the general formula (III), more preferable are those in which R ¹ is a linear alkyl group or alkenyl group having 12 to 22 carbon atoms, and R ² , R ³ and R ⁴ are A mono long chain alkyl quaternary ammonium salt which is an alkyl group having 1 to 3 carbon atoms, an alkyl group having 8 to 16 carbon atoms and a branched chain ratio of 10 to 50 mol% represented by the general formula (III-1); A dialkyl quaternary ammonium salt, particularly preferably a monoalkyl group in which R ¹ is a linear alkyl group or alkenyl group having 12 to 22 carbon atoms, and R ² , R ³ and R ⁴ are alkyl groups having 1 to 3 carbon atoms. It is a long-chain alkyl quaternary ammonium salt.
In the present invention, one or more quaternary ammonium salts can be used.

<Tertiary amine>
The tertiary amine of component (D) used in the present invention is represented by the following general formula (IV).

In the general formula (IV), R ⁵ may be divided by a functional group having a total carbon number of 8 to 35 (preferably 8 to 26) represented by —O— or —CONH— or substituted with —OH. Represents a linear or branched alkyl group or alkenyl group. R ⁶ represents an alkyl group, alkenyl group or hydroxyalkyl group having 1 to 22 carbon atoms (preferably 1 to 5 carbon atoms), and two R ^{6 s} may be the same or different.

  Examples of the tertiary amine represented by the general formula (IV) include distearylmethylamine, dioleylmethylamine, dipalmitoylmethylamine, stearyldimethylamine, stearyldiethylamine, behenyldimethylamine, behenyldiethylamine, oleyldimethylamine, Examples include palmitoyldimethylamine.

  Moreover, as an example of the tertiary amine represented by the general formula (IV), an amidoamine represented by the following general formula (IV-1) having an alkyl group or an alkenyl group which may be separated by -CONH- Is mentioned.

(IV-1)
［式(IV-1)中、Ｒ³⁴は炭素数１６〜２２のアルキル基又はアルケニル基、Ｒ³⁵はそれぞれ炭素数１〜３のアルキル基、ｑは１〜３の数を示す。］

(IV-1)
[In the formula (IV-1), R ³⁴ represents an alkyl group or alkenyl group having 16 to 22 carbon atoms, R ³⁵ represents an alkyl group having 1 to 3 carbon atoms, and q represents a number of 1 to 3, respectively. ]

  Examples of amidoamines represented by general formula (IV-1) include stearamidepropyldimethylamine, stearamidepropyldiethylamine, stearamideethyldiethylamine, stearamideethyldimethylamine, palmitoamidopropyldimethylamine, palmitoamidopropyldiethylamine , Palmitoamidoethyldiethylamine, palmitoamidoethyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethylamine, behenamidoethyldimethylamine, arachidoamidopropyldimethylamine, arachidoamidopropyldiethylamine, arachidoamidoethyl And diethylamine, arachidamidoethyldimethylamine, and mixtures thereof. Thearamidopropyldimethylamine, stearamide ethyldiethylamine and mixtures thereof are preferred.

(IV-2)
［式（IV-2）中、Ｒ^１、Ｒ^２はそれぞれ炭素数１〜３のアルキル基あるいはヒドロキシアルキル基あるいは下記一般式（IV-2a）で示される基であるが、Ｒ^１、Ｒ^２の少なくとも一方／又は両方は下記一般式（IV-2a）で示される基である。Ｒ^３は炭素数１〜３のアルキル基あるいはヒドロキシアルキル基である。 Moreover, the hydroxy ether amine shown by the following general formula (IV-2) is mentioned as an example of the tertiary amine represented by general formula (IV).

(IV-2)
Wherein ^{(IV-2), R 1} , R 2 but are each a group represented by alkyl or hydroxyalkyl groups as those of 1 to 3 carbon atoms ^{(IV-2a), R 1} , R 2 At least one or both of these are groups represented by the following general formula (IV-2a). R ³ is an alkyl group having 1 to ³ carbon atoms or a hydroxyalkyl group.

(IV-2a)
（式（IV-2a）中、Ｒは直鎖又は分岐した炭素数６〜１８のアルキル基、アルケニル基あるいはヒドロキシアルキル基であり、ｎは１〜３の整数である。）］

(IV-2a)
(In formula (IV-2a), R represents a linear or branched alkyl group having 6 to 18 carbon atoms, an alkenyl group, or a hydroxyalkyl group, and n is an integer of 1 to 3)]

In general formula (IV-2a), R is preferably an alkyl group, more preferably an alkyl group having 12 to 22 carbon atoms.
n is preferably 1 to 3, and more preferably 1.
The hydroxy ether amine of the general formula (IV-2) can be produced, for example, by the method described in JP-A-2004-323495, but other known methods may be used.

More preferably, the tertiary amine of the general formula (IV) is a mono-long chain alkyl 3 in which R ⁵ is a linear alkyl group having 12 to 22 carbon atoms and R ⁶ is an alkyl group having 1 to 3 carbon atoms. A primary amine, an amidoamine represented by the general formula (IV-1), and a hydroxyetheramine represented by the general formula (IV-2), particularly preferably a hydroxyetheramine represented by the general formula (IV-2). is there.
In the present invention, one or more tertiary amines can be used.

  When the tertiary amine is used as a salt, an organic acid and / or an inorganic acid is added, depending on pH. For example, there are phosphoric acid, hydrochloric acid, acetic acid, L-glutamic acid, lactic acid, malic acid, succinic acid, fumaric acid, tartaric acid and mixtures thereof, but L-glutamic acid, lactic acid, hydrochloric acid and mixtures thereof are preferred.

  In this invention, the compounding quantity of the quaternary ammonium salt of a component (D) and / or a tertiary amine is 0.01-10 mass% in hair cosmetics whole quantity, Preferably it is 0.1-5 mass%. is there. If the amount is too small, the effect is not sufficiently exhibited. If the amount is too large, an increase in the effect corresponding to the effect cannot be expected, and the touch may be adversely affected.

<Polyhydric alcohol / sugar alcohol>
In addition to the above essential components, when a polyhydric alcohol and / or a sugar alcohol is further added as the component (E), the conditioning effect, particularly the smoothness, softness and moistness of the hair after drying can be further improved. it can.
The polyhydric alcohol and / or sugar alcohol is not particularly limited as long as it is usually usable in cosmetics. Examples of the polyhydric alcohol include dipropylene glycol, propylene glycol, ethylene glycol, glycerin, diglycerin, and isopropylene. Glycol, propylene glycol, and 1,3-butylene glycol can be preferably used. As the sugar alcohol, xylitol, fructose, sorbitol, mannitol, inositol, glucose, lactose, maltitol and sucrose can be preferably used. In the present invention, one or more of these can be used.

  Although the compounding quantity of a component (E) is not restrict | limited in particular, 1-50 mass% in hair cosmetics, Furthermore, 5-30% is preferable. If the amount is too small, the effect is not sufficiently exhibited. If the amount is too large, an increase in the effect corresponding to the effect cannot be expected, and the touch may be adversely affected.

  The hair cosmetic composition of the present invention further contains a hair repair component such as lecithin, hydrolyzed protein and derivatives thereof, amino acids such as glutamic acid, arginine, glycine, alanine, serine, proline, leucine, and isoleucine, vitamins, and ceresin. As a result, a hair cosmetic that is further excellent in the effect of repairing and protecting hair and that lasts for a long time can be obtained.

  In addition to the above essential components, the hair cosmetic composition of the present invention has a quantitative and qualitative range that does not impair the effects of the present invention according to the purpose, and further liquid paraffin, squalane, lanolin derivatives, higher alcohols, various alcohols. Oils such as ester oil, avocado oil, palm oil, beef tallow, jojoba oil, polyalkylene glycol polyether and its carboxylic acid oligoester compound, terpene hydrocarbon oil, ultraviolet absorber, ultraviolet scattering agent, acrylic resin, silicone resin , Resins such as polyvinylpyrrolidone, proteins or protein degradation products such as soybean protein, gelatin, collagen, silk fibroin, and elastin, preservatives such as ethylparaben and butylparaben, activators such as biotin and pantothenic acid derivatives, γ-oryzanol , Dextran sulfate sodium, vitamin E derivative, nicotinic acid derivative Blood circulation promoters, antiseborrheic agents such as sulfur and thianthol, diluents such as ethanol, isopropanol and tetrachlorodifluoroethane, thickeners such as carboxyvinyl polymer, drugs, fragrances and coloring agents as necessary You may mix | blend.

  The dosage form of the present invention is not particularly limited as long as the effects of the present invention are not impaired, and any of an emulsion system, a powder dispersion system, an oil-water two-layer system, and an oil-water-powder three-layer system may be used. What is necessary is just to manufacture in accordance with a conventional method in order to make these dosage forms. An aqueous composition having an aqueous phase as a continuous phase is preferred. In the aqueous composition, the effects of the present invention are remarkably exhibited as compared with the oil-based composition having the oil phase as a continuous phase.

The composition of the hair cosmetic of the present invention can be applied to any cosmetic used for hair, so-called hair cleaning agents such as shampoos, hair rinses, hair conditioners, hair treatments, hair packs, hair sprays, styling agents, etc. And so-called hair treatment agents.
In addition, the form of use may include both those that are applied to the hair and thoroughly rinsed after being applied to the entire hair, and those that are not washed away. The hair cosmetic of the present invention is a type of hair that is used after being applied by rinsing. Particularly suitable for conditioners.

Hereinafter, the present invention will be described in more detail with reference to examples. The present invention is not limited to these examples. The blending amount is expressed in mass% unless otherwise specified.
The evaluation method used in the present invention is as follows.

Evaluation 1: Stickiness at the time of application The sensory evaluation was performed by 20 professional panelists on the stickiness when each sample was applied to the hair. Judgment criteria are as follows.
A: 17 or more out of 20 responded that they had a more sticky feeling than the control.
○: 13 to 16 out of 20 responded that they had a more sticky feeling than the control.
Δ: 8 to 12 out of 20 responded that they were more sticky than the control.
×: 7 or less of 20 responded that they had a more sticky feeling than the control.

Evaluation 2: Smoothness at the time of rinsing After each sample was applied to the hair, the smoothness when the sample was rinsed was subjected to sensory evaluation by 20 professional panelists. Judgment criteria are as follows.
A: More than 17 out of 20 responded that they were smoother than the control.
○: 13 to 16 out of 20 responded that they were smoother than the control.
Δ: 8 to 12 out of 20 responded that they were smoother than the control.
×: 7 or less of 20 responded that they were smoother than the control.

Evaluation 3: Smoothness after drying Each sample was applied to the hair, rinsed, and the smoothness of the hair after drying was subjected to sensory evaluation by 20 professional panelists. Judgment criteria are as follows.
A: More than 17 out of 20 responded that they were smoother than the control.
○: 13 to 16 out of 20 responded that they were smoother than the control.
Δ: 8 to 12 out of 20 responded that they were smoother than the control.
×: 7 or less of 20 responded that they were smoother than the control.

Evaluation 4: Moist feeling after drying (no crispness)
Each sample was applied to the hair, rinsed, and sensory evaluation was performed by 20 professional panelists on the moist feeling of the hair after drying (the absence of roughness). Judgment criteria are as follows.
A: More than 17 out of 20 responded that they were moist than the control.
○: 13 to 16 out of 20 responded that they were moist than the control.
Δ: 8 to 12 out of 20 responded that they were moist than the control.
×: 7 or less of 20 responded that they were moist than the control.

Evaluation 5: Dry feeling after drying Each sample was applied to the hair, rinsed, and the dry feeling of the hair after drying was subjected to sensory evaluation by 20 professional panelists. Judgment criteria are as follows.
A: 17 or more out of 20 responded that there was a feeling of smoother than the control.
○: 13 to 16 out of 20 responded that there was a smoother feeling than the control.
Δ: 8 to 12 out of 20 responded that there was a feeling of smoother than the control.
×: 7 or less of 20 responded that there was a more smooth feeling than the control.

Evaluation 6: Softness after drying (no firmness)
Each sample was applied to the hair, rinsed, and sensory evaluation was performed by 20 professional panelists on the softness (no firmness) of the hair after drying. Judgment criteria are as follows.
A: 17 or more out of 20 responded that they were softer than the control.
○: 13 to 16 out of 20 responded that they were softer than the control.
Δ: 8 to 12 out of 20 responded that they were softer than the control.
X: 7 or less of 20 responded that it was softer than the control.

Test Example 1 Combination of silicone emulsion and xyloglucan A hair conditioner composition was prepared according to the composition shown in Table 1 and used as a sample. The preparation method is as follows.
(Preparation method)
Water-soluble components (citric acid, behenyltrimethylammonium chloride, xyloglucan) are heated and dissolved in ion-exchanged water to make uniform. To this, an oil-soluble component (stearyl alcohol) dissolved by heating is added, and further amino-modified silicone and silicone emulsion are added, followed by emulsification and cooling.

Table 1 shows the results of comparative evaluation using Sample 1 (silicone emulsion and xyloglucan-free formulation) as a control (reference) (the same applies to Tables 2 to 7).
As shown in Table 1, when the silicone emulsion and xyloglucan were used in combination (sample 4), compared to the case where both were not blended (sample 1), the stickiness at the time of application was excellent and very good for hair. A very high effect was obtained in all of familiarity, smoothness at the time of rinsing, smoothness after drying, smoothness, moistness, and softness.
In the case of only the silicone emulsion (sample 2) and the case of only xyloglucan (sample 3), the high effect as in the sample 4 was not obtained.
Therefore, by using a combination of silicone emulsion and xyloglucan, in all items such as stickiness and familiarity at the time of application, smoothness at the time of rinsing, smoothness after drying, smoothness, moistness, softness, etc. It is considered that a synergistic effect is exhibited.

Test Example 2 The case of using other glucans instead of xyloglucan xyloglucan was examined. As a result, as shown in Table 2, even when a glucan other than xyloglucan was used in combination with the silicone emulsion, it was difficult to achieve both a feeling of stickiness during application and a feeling of use after rinsing and after drying. .

Moreover, the case where the compounding quantity of xyloglucan was changed was also examined. As a result, as shown in Table 3, when the amount of xyloglucan is too small, the effect is not sufficiently exhibited, and when it is too large, the effect tends to be lowered.
Therefore, the amount of xyloglucan (C) is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass in the hair cosmetic.

Test Example 3 Silicone Emulsion Furthermore, the case where the blending amount of the silicone emulsion was changed was also examined. As a result, as shown in Table 4, if the silicone emulsion is too small, the effect is not sufficiently exhibited, and if it is too much, the effect tends to be reduced.
Therefore, the blending amount of the silicone emulsion (B) is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass in the hair cosmetic composition.
Further, as in sample 29, a sufficiently polymerized emulsion having a low viscosity may not provide a sufficient effect.
For this reason, in the present invention, it is preferable to use a silicone emulsion in which a highly polymerized silicone having a viscosity of 5 million mPa · s or more, further 10 million mPa · s or more is dispersed.

Test Example 4 Amino-modified silicone The case where the amino-modified silicone was changed was also examined. As a result, as shown in Table 5, when an amino-modified silicone having m + n of 4000 to 6000 and n / m of 0.002 to 0.03 (samples 30 to 31) was used, a high effect was obtained. It was. In addition, when a plurality of amino-modified silicones that were outside the above range alone were used as in Sample 36, the effect was obtained if the average value was within the above range.
On the other hand, when m + n or n / m is outside the above range (samples 32 to 35), a sufficient effect was not obtained. Moreover, although the amino modified silicone which is in the said range independently is mix | blended like the samples 37-38, sufficient effect was not acquired even when the average value was outside the said range.

Moreover, the case where the compounding quantity of amino modified silicone was changed was also examined. As a result, as shown in Table 6, if the amount of the amino-modified silicone is too small, the effect is not sufficiently exhibited, and if it is too much, the effect tends to decrease.
Therefore, the compounding amount of the amino-modified silicone (A) is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass in the hair cosmetic.

Test Example 5 Quaternary ammonium salt / tertiary amine Further , the case where the quaternary ammonium salt was changed was also examined. As a result, as shown in Table 7, the effects of the present invention were exhibited with various quaternary ammonium salts. Further, when a tertiary amine was used in place of the quaternary ammonium salt, the same or more effect was exhibited. In particular, when a hydroxy ether amine compound was blended (sample 53), a remarkable effect was exhibited, and the smoothness at the time of rinsing was particularly excellent.

Test Example 6 Polyhydric alcohol / sugar alcohol Table 8 shows the results of comparative evaluation using Sample 54 as a control.
As shown in Table 8, blending of polyhydric alcohol and / or sugar alcohol improved the feeling of use at the time of rinsing and after drying, and in particular, the smoothness, moist feeling and softness after drying were improved. The stickiness at the time of application was not particularly affected even when polyhydric alcohol or sugar alcohol was added.
If the amount of polyhydric alcohol and / or sugar alcohol is too small, the effect cannot be sufficiently obtained, and if too much, the effect is lowered. Therefore, the polyhydric alcohol and / or sugar alcohol is preferably 1 to 50% by mass, more preferably 5 to 30% by mass in the hair cosmetic.

  Examples of the hair cosmetic composition of the present invention are shown below. When any of the hair cosmetics was applied, it was sticky and very well-familiar with the hair, and it had excellent smoothness after rinsing, smoothness after drying, moistness, smoothness and softness. .

Formulation Example 1 Hairist (1) Amino-modified silicone 0.2% by mass
^{(R 1 = OH, R 2} = - (CH 2) 3 NH 2, m = 4000, n = 120, a = 3)
(2) Dimethylpolysiloxane 1.0
(3) Ethanol 5.0
(4) Stearyl alcohol 0.1
(5) Behenyl alcohol 0.2
(6) Sucrose 12.0
(7) Dipropylene glycol 1.0
(8) 1,3-butylene glycol 1.0
(9) Behenyltrimethylammonium chloride 0.5
(10) Vinylpyrrolidone
N, N-dimethylaminoethyl methacrylic acid copolymer 2.5
(11) Paraoxybenzoic acid ester appropriate amount (12) Purified water Residual (13) Xyloglucan 0.1
(14) Silicone emulsion 1 1.8
(15) Perfume appropriate amount <Production method>
The oil phase mixed with (1) to (5) and the aqueous phase mixed with (6) to (12) are heated and dissolved, and the former is added to the latter and emulsified. (13) to (15) are added to make uniform.

Formulation Example 2 Hair Oil (1) Light liquid isoparaffin 80.0% by mass
(2) Amino-modified silicone 2.0
(R ¹ = _{^{methyl, R 2 = - (CH 2}} ) 3 N (CH 3) (CH 2) 2 N (CH 3) 2, m = 4000, n = 20, a = 3)
(3) 1,3-butylene glycol 14.5
(4) Methylphenylpolysiloxane 5.0
(5) Behenyltrimethylammonium chloride 0.2
(6) Xyloglucan 0.3
(7) Silicone emulsion 1 3.0
(8) Perfume appropriate amount <Production method>
After mixing (1) to (4), add (5) to (7) to make uniform, and finally add (7).

Formulation Example 3 Hair Mousse (Aerosol)
(1) Ethanol 5.0% by mass
(2) Dimethylpolysiloxane 5.0
(3) Amino-modified silicone 5.0
(R ¹ = methyl, R ² =-(CH ₂ ) ₃ NH ₂ , m = 5000, n = 10, a = 3)
(4) Volatile isoparaffin 25.0
(5) 1,3-butylene glycol 5.0
(6) Isostearic acid 1.0
(7) Polyoxyethylene hydrogenated castor oil 1.0
(8) 2-alkyl-N-carboxymethyl 6.0
-N-hydroxyethylimidazolinium betaine (9) phenoxyethanol appropriate amount (10) purified water residue (11) xyloglucan 0.1
(12) Silicone emulsion 1 5.0
(13) Perfume appropriate amount <Production method>
A mixture of (5) to (12) and a mixture of (1) to (4) and (13) are added and emulsified.

Formulation Example 4 Hair Cream (1) Liquid Paraffin 5.0% by mass
(2) Vaseline 2.0
(3) Dimethylpolysiloxane 5.0
(4) Ammonium modified silicone 1.0
(R ¹ = _{^{methyl, R 2 = - (CH 2}} ) 3 N + (CH 3) 2 C 18 H 37 Cl -, m = 5000, n = 25, a = 3)
(5) Cetanol 4.0
(6) Stearyl alcohol 1.0
(7) Behenyltrimethylammonium chloride 0.2
(8) Xyloglucan 1.0
(9) Silicone emulsion 1 3.0
(10) 1,3-butylene glycol 10.0
(11) Polyoxyethylene / polyoxypropylene dimethyl ether 2.0
(12) Polyoxypropylene glyceryl ether 2.0
(13) Polyoxyethylene glyceryl isostearate 2.0
(14) Lipophilic glyceryl monostearate 2.0
(15) Polymer JR-400 ^TM (manufactured by Toho Chemical Industry Co., Ltd.) 0.5
(16) Hydrolyzed wheat protein 0.1
(17) paraoxybenzoic acid ester appropriate amount (18) purified water residue (19) perfume appropriate amount <production method>
The oil phase (1) to (7) and the aqueous phase (8) to (18) are dissolved and mixed by heating, respectively, (19) is added to the oil phase to make it uniform, and then the two phases are mixed. Emulsify.

Formulation Example 5 Hair Cream (1) Liquid Paraffin 10.0% by mass
(2) Petrolatum 3.0
(3) Dimethylpolysiloxane 2.0
(4) Amino-modified silicone 1.0
(R ¹ = methyl, R ² =-(CH ₂ ) ₃ N (CH ₂ ) ₂ , m = 5000, n = 25, a = 3)
(5) Propylene glycol 10.0
(6) Polyoxypropylene (40) Butyl ether 2.0
(7) Xyloglucan 0.2
(8) Silicone emulsion 1 3.0
(9) Tetra-2-ethylhexanoic acid pentaerythritol 3.0
(10) Polyoxyethylene hydrogenated castor oil 2.0
(11) Potassium hydroxide 0.1
(12) Carboxyvinyl polymer 0.3
(13) Hydroxyethyl polyacrylate 0.1
-Acryloyldimethyltaurine sodium copolymer (14) Camellia seed oil 0.01
(15) Purified water Residue (16) Perfume appropriate amount <Production method>
The mixture of (1) to (4), (14) and (16) is added to the mixture of (5) to (10), (12) and (15) and emulsified. (13) is added to make uniform, then neutralized with (11), and further stirred to make uniform.

Formulation Example 6 Hair Lotion (1) Light Isoparaffin 15.0% by mass
(2) Amino-modified silicone 3.0
(R ¹ = _{^{methyl, R 2 = - (CH 2}} ) 3 N (CH 3) C 2 H 5, m = 5000, n = 50, a = 3)
(3) Dimethyl silicone 6.0
(4) Sorbitol 20.0
(5) Polyoxyethylene (60 mol) hydrogenated castor oil ester 2.0
(6) Titanium oxide sol 10.0
(7) Ethanol 15.0
(8) Behenyltrimethylammonium chloride 0.5
(9) Purified water Residual (10) Xyloglucan 0.5
(11) Silicone emulsion 1 10.0
(12) Perfume appropriate amount (production method)
A mixture of (1) to (3) and (12) is added to (4) to (11) and emulsified.

Formulation Example 7 Hairist (1) Amino-modified silicone 0.2% by mass
^{(R 1 = OH, R 2} = - (CH 2) 3 NH 2, m = 4000, n = 120, a = 3)
(2) Dimethylpolysiloxane 1.0
(3) Ethanol 5.0
(4) Stearyl alcohol 0.1
(5) Behenyl alcohol 0.2
(6) Xyloglucan 0.05
(7) Silicone emulsion 1 1.0
(8) Glycerin 20.0
(9) Dipropylene glycol 1.0
(10) 1,3-butylene glycol 1.0
(11) Alkyltrimethylammonium chloride (77%) 0.5
(12) Vinylpyrrolidone
N, N-dimethylaminoethyl methacrylic acid copolymer 2.5
(13) Arginine 0.1
(14) Lecithin 0.1
(15) Octylmethoxycinnamate 0.1
(16) Paraoxybenzoic acid ester appropriate amount (17) Camellia seed oil 0.005
(18) Purified water Residue (19) Perfume appropriate amount <Production method>
The oil phase in which (1) to (5) and (17) are mixed and the aqueous phase in which (6) to (16) and (18) are mixed are dissolved by heating, and the former is added to the latter and emulsified. (19) is added to make uniform.

Formulation Example 8 Hair Conditioner (1) Dimethylpolysiloxane 10.0% by mass
(2) Amino-modified silicone 1.0
(R ¹ = _{^{methyl, R 2 = - (CH 2}} ) 3 N (CH 3) 2, m = 5000, n = 20, a = 3)
(3) Hardened rapeseed oil alcohol 3.0
(4) Cetanol 1.5
(5) Sucrose 20.0
(6) Cetyl 2-ethylhexanoate 2.0
(7) Behenyltrimethylammonium chloride 1.5
(8) Sorbitol 2.0
(9) Glutamic acid 0.5
(10) Arginine 0.1
(11) Glycine 0.1
(12) Citric acid 0.01
(13) Tocopherol acetate 0.05
(14) paraoxybenzoic acid ester appropriate amount (15) phenoxyethanol appropriate amount (16) xyloglucan 0.2
(17) Silicone emulsion 1 5.0
(18) Camellia seed oil 0.05
(19) Purified water Residue (20) Perfume appropriate amount <Production method>
Water-soluble components are mixed and dissolved by heating until uniform. The oil-soluble component is mixed with this and heated and dissolved, and then emulsified. (15) and (20) are added to make uniform, and then cooled.

Formulation Example 9 Hair Conditioner (1) Isopentyldiol 5.0% by mass
(2) Sorbitol 15.0
(3) Silicone emulsion 1 3.0
(4) Stearyl alcohol 3.0
(5) Behenyl alcohol 2.0
(6) Behenyltrimethylammonium chloride 2.0
(7) Cetyl isooctanoate 1.0
(8) Aminopropyl dimethicone (m = 4000, n = 120) 0.2
(9) Arginine 0.01
(10) Xyloglucan 0.25
(11) Stearyl dihydroxypropyl dimonium oligosaccharide 0.05
(12) Citric acid 0.07
(13) Appropriate amount of phenoxyethanol (14) Appropriate fragrance Appropriate amount (15) Soy lecithin 0.1
(16) Hydrolyzed wheat protein / hydrolyzed wheat starch 0.02
(17) N-lauroyl glutamic acid
Di (phytosteryl / 2-octyldodecyl) 0.1
(18) Purified water residue <Production method>
A water-soluble component is dissolved by heating to make it uniform. To this, an oil-soluble component mixed and heated and dissolved is added, emulsified, and then cooled.

Claims (3)

Contains the following components (A), (B), (C) and (D) , the component (A) is 0.01 to 10.0% by mass in the hair cosmetic, and the component (B) is silicone in the hair cosmetic. 0.01-10.0% by mass in pure content, 0.01-10.0% by mass of component (C) in hair cosmetics, and 0.01-10.0% by mass of component (D) in hair cosmetics % Hair cosmetics characterized by
(A) Amino-modified or ammonium-modified silicone represented by the following general formula (I).

[In formula (I), each R ¹ independently represents a methyl group, a phenyl group or a hydroxyl group. R ² is each independently a group represented by the formula R ⁴ Z, R ⁴ is an alkylene group having 3 to 6 carbon atoms, Z is a nitrogen-containing group, and the following formula:

(R ⁵ is independently a hydrogen atom or an alkyl group having 1 to 30 carbon atoms, R ⁶ is an alkyl group having 1 to 30 carbon atoms, A is a chlorine atom, bromine atom or iodine atom, b is an integer of 2 to 6) It is a group represented by. a is an integer of 0 to 3, m and n are each a positive integer, the average value of m + n is 4000 to 6000, and the average value of n / m is 0.002 to 0.03. ]
(B) Highly polymerized organopolysiloxane represented by the following average composition formula (II).
[R ^a R ^b SiO] x (II)
[In the formula (II), R ^a is a methyl group or an aryl group, and R ^b is a methyl group or a hydroxyl group. x is a positive integer representing the degree of siloxane polymerization in a range where the organopolysiloxane exhibits a viscosity of 5 million mPa · s or more at 25 ° C. ]
(C) A compound selected from the group consisting of a xyloglucan (D) quaternary ammonium salt represented by the general formula (III) and a tertiary amine represented by the general formula (IV).

[In the formula (III), at least one of R ¹ , R ² , R ³ and R ⁴ is divided by a functional group having a total carbon number of 8 to 35 and represented by —O—, —OCO— or —COO—. Or a linear or branched alkyl group, an alkenyl group, or an aliphatic acyloxy (polyethoxy) ethyl group optionally substituted with —OH, the remainder being an alkyl group or hydroxyalkyl group having 1 to 5 carbon atoms, Alternatively, it represents a polyoxyethylene group having a total number of added moles of 10 or less. X ⁻ represents a halogen ion or an organic anion. ]

[In the formula (IV), R ⁵ is a linear or branched chain having a total carbon number of 8 to 35, which may be divided by a functional group represented by —O— or —CONH— or substituted with —OH. An alkyl group or an alkenyl group is shown. R ⁶ represents an alkyl group, alkenyl group or hydroxyalkyl group having 1 to 22 carbon atoms, and two R ^{6 s} may be the same or different. ] The hair cosmetic according to claim 1 , further comprising at least one of a polyhydric alcohol and / or a sugar alcohol as component (E). A hair conditioner composition comprising the hair cosmetic composition according to claim 1 or 2 .