CN109864933A - A kind of hair of children cleaning compositions of not silicate-containing oil and preparation method thereof - Google Patents
A kind of hair of children cleaning compositions of not silicate-containing oil and preparation method thereof Download PDFInfo
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Abstract
The present invention discloses a kind of hair of children cleaning compositions and preparation method thereof of not silicate-containing oil, it is grouped as comprising following group by weight percentage: laureth sulfuric ester ammonium 5%~10%, Cocoamidopropyl betaine 1%~5%, cocounut oil acyl both sexes base diethyl acid disodium 1%~5%, Polyquaternium-10 0.05~0.2%, cationic oligomeric fructose 0.5%~2%, ricinoleic acid amide hydroxypropyltrimonium chloride 0.1%~1%, PPG-3 Octyl Ether 0.1%~1%, camellia seed oil 0.01%~0.5%, maltotetraose 1%~5%, camellia flower extract 0.5%~2%, viscosity modifier 0.5~2.0%, chelating agent 0.01~0.05%, pH adjusting agent 0.05~0.2%, essence 0.05~0.3% With preservative 0.1~0.5%, the present invention is widely used in the silicone oil in shampoo using vegetable fat substitution at present, silicone oil is eliminated to deposit on hair, the phenomenon that causing hair fuel-displaced and withered and yellowish hairs, it ensure that the health of hair and scalp, also efficiently solve the problems, such as biodegrade simultaneously, and be added to moisturizer and skin conditioning agent can effectively take good care of scalp health.
Description
Technical field
The present invention relates to a kind of shampoos, more particularly to a kind of not hair of children cleaning compositions of silicate-containing oil and its preparation
Method.
Background technique
From without silicone oil shampoo it is hot in the Japanese market after, be that a wave boosts thousand layers of wave, Cosmetics in China
Enterprise also all imitates exploitation without silicone oil shampoo one after another, while also having found the attraction to contend with trans-corporation shampoo, passes
The shampoo of system all contains silicone oil, and it is to common name a part of in organosilicon series of products, specifically that silicone oil, which has the function of lubrication,
For include dimethyl silicone polymer, X 2-1401 and silicone emulsion；These three are frequently referred to silicone oil, in addition also
The organosilicon products such as silicon wax, elastomer silicone, these are referred to as silicone oil.The property of silicone oil: stable structure is not susceptible to drop
It solves, is not easy to react with other materials under general condition, while between chemical bond flexibly, being easy movement, surface tension is low, institute
With it is smooth be its most common property, while also have waterproofness and gas permeability, be in industry a kind of rare raw material
Ingredient, studies have shown that it is 10%-20% that silicone oil, which is finally deposited on the amount to work on hair, in shampoo, so the mistake of hair washing
Journey can not all wash away silicone oil, and silicone oil fills and leads up hair surface in the gap for being attached to hair scale piece, and hair touches up just
Can be very submissive, but the closed structure based on silicone oil, added nutriment in hair products can be hindered to reach in hair
Portion, with increasing for access times, being gathered in the silicone oil around hair over time will tightly wrap outside hair, and pore is blocked
Plug, leads to a large amount of missings of nutrition inside hair, and the final health for influencing scalp even results in hair follicle atrophy, dandruff increases, takes off
The symptoms such as hair, hair of children is soft, and hair is short and healthy, does not need excessive opsonic action, therefore the cleaning of hair of children
It is more suitable for no silicone oil shampoo.
Summary of the invention
To overcome above-mentioned deficiency, the present invention provides a kind of not the hair of children cleaning compositions of silicate-containing oil and its preparation sides
Method.The technical solution adopted by the present invention to solve the technical problems is: a kind of hair of children cleaning compositions of not silicate-containing oil,
It is characterized in that: being grouped as comprising following group by weight percentage: laureth sulfuric ester ammonium 5%~10%, coconut oleoyl amine
Propyl betaine 1%~5%, cocounut oil acyl both sexes base diethyl acid disodium 1%~5%, Polyquaternium-10 0.05~0.2%, sun
Ionic oligomeric fructose 0.5%~2%, ricinoleic acid amide hydroxypropyltrimonium chloride 0.1%~1%, PPG-3 Octyl Ether
0.1%~1%, camellia seed oil 0.01%~0.5%, maltotetraose 1%~5%, camellia flower extract 0.5%~2%, viscosity
Regulator 0.5~2.0%, chelating agent 0.01~0.05%, pH adjusting agent 0.05~0.2%, essence 0.05~0.3% and anti-corrosion
Agent 0.1~0.5%.
The viscosity modifier is PPG-2 hydroxyethyl cocamide, and the chelating agent is sodium glucoheptonate, described
PH adjusting agent is citric acid, and the preservative is the compound of Phenoxyethanol and glycerol caprylate, glycerol monolaurate.
A kind of hair of children cleaning compositions of not silicate-containing oil, it is characterized in that: including following component by weight percentage
Composition: laureth sulfuric ester ammonium 1%~10%, Cocoamidopropyl betaine 1%~3%, cocounut oil acyl both sexes base diethyl
Acid disodium 1%~3%, Polyquaternium-10 0.05~0.1%, cationic oligomeric fructose 1%~2%, ricinoleic acid amide third
Base trimethyl ammonium chloride 0.1%~0.5%, PPG-3 Octyl Ether 0.1%~0.5%, camellia seed oil 0.01%~0.1%, malt
Tetrose 1%~2%, camellia flower extract 0.5%~1%, PPG-2 hydroxyethyl cocamide 0.5~2.0%, sodium glucoheptonate
0.01~0.05%, citric acid 0.05~0.2%, Phenoxyethanol and glycerol caprylate, glycerol monolaurate compound 0.1~
0.5%.
A kind of preparation method of the hair of children cleaning compositions of not silicate-containing oil, characterized in that the following steps are included:
(1) it injects water into agitated kettle, is sprinkled into Polyquaternium-10, be stirred after being heated to 60-65 DEG C and open cooling water
Cooling；
(2) sodium glucoheptonate, laureth sulfuric ester ammonium, Cocoamidopropyl betaine, cocounut oil acyl two are sequentially added
Property base diethyl acid disodium, ricinoleic acid amide hydroxypropyltrimonium chloride, each single item material must confirm the next item up before being added
Material dissolved/and dispersion mixing is uniformly in composition；
(3) uniformly mixed, addition cationic oligomeric fructose, PPG-3 after temperature is down to 45 DEG C are completely dissolved to above-mentioned material
Octyl Ether, camellia seed oil, maltotetraose, camellia flower extract, essence, citric acid and Phenoxyethanol and glycerol caprylate, glycerol
The compound of laurate is eventually adding PPG-2 hydroxyethyl cocamide, continues stirring 20 minutes after all adding.
Present invention has an advantage that being widely used in the silicone oil in shampoo at present using vegetable fat substitution, eliminate
The phenomenon that silicone oil deposits on hair, causes hair fuel-displaced and withered and yellowish hairs ensure that the health of hair and scalp, while also have
Effect solves the problems, such as biodegrade, a kind of hair of children cleaning combination of not silicate-containing oil, foaming abundancy, stabilization, product
Matter milder, safer health, effective protection hair of children and scalp health, while product can be significantly improved in use
Wet comb, bath property, have better smoothness and glossiness, and use after fluffy sense, flexibility, without tangle etc. spies
Point.
Detailed description of the invention:
Fig. 1 is embodiment detail list.
Fig. 2 is effect assessment table.
Specific embodiment:
Below with reference to embodiment to further detailed description of the present invention, embodiments of the present invention are not limited thereto.
Embodiment 1
A kind of hair of children cleaning compositions of not silicate-containing oil, are grouped as: laurel comprising following group by weight percentage
Alcohol polyethers sulfuric ester ammonium 5%~10%, Cocoamidopropyl betaine 1%~5%, cocounut oil acyl both sexes base diethyl acid disodium 1%
~5%, Polyquaternium-10 0.05~0.2%, cationic oligomeric fructose 0.5%~2%, ricinoleic acid amide oxypropyl trimethyl
Ammonium chloride 0.1%~1%, PPG-3 Octyl Ether 0.1%~1%, camellia seed oil 0.01%~0.5%, maltotetraose 1%~
5%, camellia flower extract 0.5%~2%, viscosity modifier 0.5~2.0%, chelating agent 0.01~0.05%, pH adjusting agent
0.05~0.2%, essence 0.05~0.3% and preservative 0.1~0.5%.
Embodiment 2
A kind of hair of children cleaning compositions of not silicate-containing oil, are grouped as: laurel comprising following group by weight percentage
Alcohol polyethers sulfuric ester ammonium 1%~10%, Cocoamidopropyl betaine 1%~3%, cocounut oil acyl both sexes base diethyl acid disodium 1%
~3%, Polyquaternium-10 0.05~0.1%, cationic oligomeric fructose 1%~2%, ricinoleic acid amide oxypropyl trimethyl chlorine
Change ammonium 0.1%~0.5%, PPG-3 Octyl Ether 0.1%~0.5%, camellia seed oil 0.01%~0.1%, maltotetraose 1%~
2%, camellia flower extract 0.5%~1%, PPG-2 hydroxyethyl cocamide 0.5~2.0%, sodium glucoheptonate 0.01~
0.05%, citric acid 0.05~0.2%, the compound 0.1~0.5% of Phenoxyethanol and glycerol caprylate, glycerol monolaurate.
Embodiment 3
A kind of hair of children cleaning compositions of not silicate-containing oil, are grouped as: laurel comprising following group by weight percentage
Alcohol polyethers sulfuric ester ammonium 10%, Cocoamidopropyl betaine 3%, cocounut oil acyl both sexes base diethyl acid disodium 2%, ricinoleic acid acyl
Amine hydroxypropyltrimonium chloride 0.5%, cationic oligomeric fructose 1%, Polyquaternium-10 0.05%, PPG-3 Octyl Ether 0.3%,
Camellia seed oil 0%, maltotetraose 0%, camellia flower extract 1%, PPG-2 hydroxyethyl cocamide 1%, sodium glucoheptonate
0.025%, essence 0.2%, citric acid 0.1%, the compound 0.4% of Phenoxyethanol and glycerol caprylate, glycerol monolaurate,
Deionized water adds to 100%.
Embodiment 4
A kind of hair of children cleaning compositions of not silicate-containing oil, are grouped as: laurel comprising following group by weight percentage
Alcohol polyethers sulfuric ester ammonium 10%, Cocoamidopropyl betaine 3%, cocounut oil acyl both sexes base diethyl acid disodium 2%, ricinoleic acid acyl
Amine hydroxypropyltrimonium chloride 0.5%, cationic oligomeric fructose 1.5%, Polyquaternium-10 0.05%, PPG-3 Octyl Ether
0.3%, camellia seed oil 0.05%, maltotetraose 1%, camellia flower extract 1%, PPG-2 hydroxyethyl cocamide 1%, Portugal heptan
Sodium saccharate 0.025%, essence 0.2%, citric acid 0.1%, the compound of Phenoxyethanol and glycerol caprylate, glycerol monolaurate
0.4%, deionized water adds to 100%.
Embodiment 5
A kind of hair of children cleaning compositions of not silicate-containing oil, are grouped as: laurel comprising following group by weight percentage
Alcohol polyethers sulfuric ester ammonium 10%, Cocoamidopropyl betaine 3%, cocounut oil acyl both sexes base diethyl acid disodium 2%, ricinoleic acid acyl
Amine hydroxypropyltrimonium chloride 0.5%, cationic oligomeric fructose 2%, Polyquaternium-10 0.1%, PPG-3 Octyl Ether 0.3%,
Camellia seed oil 0.1%, maltotetraose 2%, camellia flower extract 1%, PPG-2 hydroxyethyl cocamide 1%, sodium glucoheptonate
0.025%, essence 0.2%, citric acid 0.1%, the compound 0.4% of Phenoxyethanol and glycerol caprylate, glycerol monolaurate,
Deionized water adds to 100%.
Embodiment 6
A kind of hair of children cleaning compositions of not silicate-containing oil, are grouped as: laurel comprising following group by weight percentage
Alcohol polyethers sulfuric ester ammonium 10%, Cocoamidopropyl betaine 3%, cocounut oil acyl both sexes base diethyl acid disodium 2%, ricinoleic acid acyl
Amine hydroxypropyltrimonium chloride 0.5%, cationic oligomeric fructose 1%, Polyquaternium-10 0.1%, PPG-3 Octyl Ether 0.3%,
Camellia seed oil 0%, maltotetraose 0%, camellia flower extract 1%, PPG-2 hydroxyethyl cocamide 1%, sodium glucoheptonate
0.025%, essence 0.2%, citric acid 0.1%, the compound 0.4% of Phenoxyethanol and glycerol caprylate, glycerol monolaurate,
Deionized water adds to 100%.
Embodiment 7
A kind of hair of children cleaning compositions of not silicate-containing oil, are grouped as: laurel comprising following group by weight percentage
Alcohol polyethers sulfuric ester ammonium 10%, Cocoamidopropyl betaine 3%, cocounut oil acyl both sexes base diethyl acid disodium 2%, ricinoleic acid acyl
Amine hydroxypropyltrimonium chloride 0.5%, cationic oligomeric fructose 1.5%, Polyquaternium-10 0.05%, PPG-3 Octyl Ether
0.5%, camellia seed oil 0.05%, maltotetraose 1%, camellia flower extract 1%, PPG-2 hydroxyethyl cocamide 1%, Portugal heptan
Sodium saccharate 0.025%, essence 0.2%, citric acid 0.1%, the compound of Phenoxyethanol and glycerol caprylate, glycerol monolaurate
0.4%, deionized water adds to 100%.
Embodiment 8
A kind of hair of children cleaning compositions of not silicate-containing oil, are grouped as: laurel comprising following group by weight percentage
Alcohol polyethers sulfuric ester ammonium 10%, Cocoamidopropyl betaine 3%, cocounut oil acyl both sexes base diethyl acid disodium 2%, ricinoleic acid acyl
Amine hydroxypropyltrimonium chloride 0.5%, cationic oligomeric fructose 2%, Polyquaternium-10 0.1%, PPG-3 Octyl Ether 0.5%,
Camellia seed oil 0.1%, maltotetraose 2%, camellia flower extract 1%, PPG-2 hydroxyethyl cocamide 1%, sodium glucoheptonate
0.025%, essence 0.2%, citric acid 0.1%, the compound 0.4% of Phenoxyethanol and glycerol caprylate, glycerol monolaurate,
Deionized water adds to 100%.
The preparation method of one of above embodiments not hair of children cleaning compositions of silicate-containing oil, including following step
It is rapid:
(1) it injects water into agitated kettle, is sprinkled into Polyquaternium-10, be stirred after being heated to 60-65 DEG C and open cooling water
Cooling；
(2) sodium glucoheptonate, laureth sulfuric ester ammonium, Cocoamidopropyl betaine, cocounut oil acyl two are sequentially added
Property base diethyl acid disodium, ricinoleic acid amide hydroxypropyltrimonium chloride, each single item material must confirm the next item up before being added
Material dissolved/and dispersion mixing is uniformly in composition；
(3) uniformly mixed, addition cationic oligomeric fructose, PPG-3 after temperature is down to 45 DEG C are completely dissolved to above-mentioned material
Octyl Ether, camellia seed oil, maltotetraose, camellia flower extract, essence, citric acid, Phenoxyethanol and glycerol caprylate, the glycerol moon
The compound of cinnamic acid ester is eventually adding PPG-2 hydroxyethyl cocamide, continues stirring 20 minutes after all adding.
Above-described laureth sulfuric ester ammonium is the main active agent in current shampoo, foaming abundancy is fine and smooth,
Strong detergency, biological degradability are good.Degreasing power is moderate, and being used in shampoo has good cleaning force and skin comfort.
Above-described Cocoamidopropyl betaine and cocounut oil acyl both sexes base diethyl acid disodium, the former is betaine type two
Property ionic surface active agent, the latter is imidazoline type zwitterionic surfactant, in the structure of this kind of surfactant simultaneously
The hydrophilic radical of hydrophilic radical and anion with cation.In neutral medium environment, existing cationic surfactant
Characteristic also have the characteristic of anionic surfactant；In the environment of strong acid medium, hydrophilic radical is positively charged, shows
Be cationic surfactant characteristic；And in the media environment of strong basicity, hydrophilic radical band is negative electrical charge, is shown
Be anionic surfactant characteristic.This kind of surfactant almost can be all with other types surfactant match
5, and have certain synergistic effect；Toxicity is low, and stimulation is small, can reduce original with surfactant compound use excitatory
Some irritations, so that compound is to skin and eyes seldom or almost without irritation；The electrolysis of resistance to hard water and higher concentration
Matter can be adsorbed on negatively charged or positively charged material surface without will form hydrophobic film, to generate good
Wetability and foaminess.Composition for hair cleaning containing amphoteric imidazoline can make hair soft, easily comb, is antistatic.
Above-described Polyquaternium-10 cation opsonizing agent, cationic oligomeric fructose and ricinoleic acid amide propyl three
The combination of ammonio methacrylate, formula of the invention are especially added with cationic oligomeric fructose and use as conditioner.Oligofructose
(FOS) also known as fructooligosaccharide, Fructooligosaccharides or cane fruit trisaccharide oligosaccharides, molecular formula are that (n=1,2,3, G be grape to G-F-Fn
Sugar, F are fructose), it is to pass through β -1, the ketose that the fructosyl in 2 glycosidic bonds is combined by sucrose and 1-3 fructose
(GF2), a kind of carbohydrate general name such as Nystose (GF3) and sugarcane sugar (GF4).Oligomeric fruit used in this formula
Sugar forms methylsulfuric acid oligofructose acetate groups dihydroxy ethyl methyl ammonium by the association of cation, and the whole of formation produces
Object has both a variety of excellent properties simultaneously, and fluffy, soft, moist, low accumulation, low stimulation are mild, environmentally friendly, balance formula charge energy,
Remained on surface is reduced, it is sustainable to use.The ingredient in conjunction with wet hair, neutralizes the weak anionic electricity of dry hair by hydrogen bond
Lotus, to show the better hair conditionings of long chain alkyl ammonium salts such as three (cetyl) ammonio methacrylates；It is soft and moist to cross water, wet comb
Lubrication wipes soft and smooth；Slim and graceful elegant, soft smooth, not at random after dry, permanent antistatic, does not knot at rub resistance.Polyquaternium-
10 mutually use, and can improve historic deposition of the cation on hair, ensure that hair can be shown each time after washing
Comfortable slim and graceful smooth feeling.It can also balance formula ionic surfactants charge energy, and reduce its residual, make corresponding
The conditioner shampoo of formula becomes can be long lasting for the product used, without worrying that it is coarse, dry and astringent, thick and heavy etc. old that hair occurs
Problem.This is a quaternary ammonium derivative derived from sucrose and amino acid, environmentally protective, extremely friendly to environment；Natural safety,
It is extremely mild to eyes and skin；Cationic oligomeric fructose can be affine with keratoderma Protein high, enhances skin
Resist the ability of environmental stimuli；With certain bacteriostasis, skin sensitivity can reduce, possess outstanding moisturizing energy
Power, the tight feeling after washing can be improved, soft skin, in conjunction with the ricinoleic acid amide with antistatic and soft hair effect
Hydroxypropyltrimonium chloride is used in compounding, and is supplied to the superior soft comfortable sense of user.
The non-ionic conditioning agents of PPG-3 Octyl Ether described above, PPG-3 Octyl Ether, that is, -3 Octyl Ether of polypropylene glycol, is one
The hydrophilic finish composition of money.PPG-3 Octyl Ether has improvement nursing role well in composition for hair cleaning.Pass through examination
Issue after examination and approval existing, the hair washing washing back hair for being added to PPG-3 Octyl Ether is more fluffy slim and graceful, more smooth softness, not short-tempered and more have light
Pool can improve cationic polymerization species conditioner is used for a long time and the hair and scalp that generate excessively are assembled, bring hair from
Root of hair is to the suitable feeling being full of of the hair tip, convenient for combing, making hair to possess using the feeling after silicate-containing oil hair washing product.
Above-described tax ester agent is preferably camellia seed oil.The squalene and Flavonoid substances being rich in camellia oil, to pre-
Anti-cancer plays the role of splendid；Camellianin has anticancer, cardiac effect；Omega-fatty acid can promote the natural death of cancer cell,
The effect of slowing down the speed of growth of tumor, the diffusion of cancer cell can also be prevented, chemotherapy can be increased.In this regard, many tumours
Camellia oil is referred to as " anticancer oil " by section doctor.High-content unsaturated fatty acid in camellia oil is referred to as " beauty acid ", has
Significant beauty functions, camellia oil cuisines, which are eaten for a long time, in women can make skin become tight, moist.In addition, camellia oil is naturally pure
Only, it is gentle, is free of any chemical stimulating compositions, therefore can be used as basic skin care item to smear, taken after daily shower suitable
Amount camellia oil is gently massaged, and is adhered to for a long time, and skin can be allowed to keep smooth, beautiful.Camellia oil can nourish hair care, and adhering to for a long time can
Make scalp health, hair is smooth submissive, improves dry hair, jag, scalds the problems such as dye damage.
Above-described maltotetraose moisturizer, it is by α-Isosorbide-5-Nitrae glucosides key connection glucose tetramer, is a kind of new
The malto-oligosaccharide of type is prepared using single-minded maltotetraose forming amylase hydrolysis starch.It is appearance colorless, transparent, thick
Liquid is also free of macroscopic impurity without any not benign peculiar smell.It is good that the design feature of maltotetraose has it
Moisture retention and hygroscopicity is lower can play preferable thickening power, and have certain acidproof and heat resistance, there is uniqueness
Antibacterial activity.Utilization in cosmetics other than it can be used as moisturizer, while can also be used as scalp and skin only
Itch agent.
The skin conditioning agent of above-described camellia flower extract, skin play from physics and chemistry unfavorable shadow human body
The increase of loud effect, environmental pollution causes human skin to be encroached on；Continuous skin is exposed to dirt, dust, free radical, purple
It will lead to the decline of dermal inflammatory skin barrier function, premature aging in outside line and smog pollution material；Infant's skin barrier function
It is more much weaker than adult, therefore the behave for resisting pollutant should be done from the nursing of infant.Winter cypress is most notable camellia
One of section's species, the also referred to as rose in winter are a kind of dungarunga to bloom, winter cypress flower extract nutrients rich in
Matter has potent antioxidation, while having the function of anti-inflammatory and promoting collagen synthesis, moreover it is possible to inhibit by a huge sum of money
Belong to oxidative stress caused by mixture to act on, so as to improve dermal composition and dermis density, and raw material stability itself is good,
Even if being also able to maintain stabilization under extreme ultraviolet light and heat condition.Research shows that winter cypress flower extract can effectively inhibit dirty
Keratoderma layer oxidative stress caused by object (polycyclic aromatic hydrocarbon & heavy metallic mixture) is contaminated, to inhibit the collagen egg in skin corium
White decomposition reaches crease-resistant effect；It can effective Keratoderma layer oxidative stress caused by contaminant restraining (10 μm and 2.5 μm)
Reaction, increases the survival rate of keratinocyte.
The viscosity modifier of PPG-2 hydroxyethyl cocamide described above, the ingredient are novel non-ionic surface active
Agent has very excellent thickening properties, diethanol amine and nitrosamine without European Union's limitation.With good frost resistance, produce
Product are not muddy at low ambient temperatures, do not solidify, and are mobility liquid.Compared with traditional 6501 and CMEA, have superior
Thickening, foaming and foam stability energy, while there is good wetting, decontamination, performance of deoiling.
The chelating agent of sodium glucoheptonate described above, sodium glucoheptonate are a kind of sodium salts of seven yuan of saccharic acids, molecular formula:
C7H13NaO8, molecular weight 248.18；Sodium glucoheptonate is divided into two kinds of isomeries of α-D- sodium glucoheptonate and β-D- sodium glucoheptonate
Body, pure α type and β type glucoheptonic acid sodium crystal are slightly with the pale yellow odorless fine crystal of white, are usually palm fibre when containing impurity
Red or deep amber, α type and the crystallization of β type all have good water solubility at normal temperatures and pressures, have excellent chelating
Ability, its sequestering power is 2-3 times of common chelating agent EDTA, dissolubility and stability in highly basic medium under the same terms
It is significantly better than EDTA.
The pH adjusting agent of citric acid described above, the group belong to optional components, and additive amount need to be according to the reality of product
It needs suitably to be selected, and is added in the composition.
Above-described preservative is preferably the compounding of mild Phenoxyethanol and glycerol caprylate, glycerol monolaurate
Object.
Embodiment:
It is the embodiment (details are referring to " Figure of description ") of shampoo composite of the invention below, these embodiments are only
In order to illustrate the present invention use and provide, but be not intended to limit the invention, i.e., it will be appreciated by those skilled in the art that not
It is detached from the basis of original intention and range of the invention, can be varied multiple times and be adjusted, until the determination of optimal embodiment.
Effect assessment:
Evaluation method: detection takes test crowd to try out, the children that tester is 6-12 years old, 5 boys, 5 young girls, by
The mother of test children tests, and evaluation cycle is continuous use 10 times, and professional questionnaire is filled in after test.
Specific test method are as follows: 1. soak hair, and taking shampoo dosage used in daily hair washing, (preferably 1g is extremely
Overhead two sides 20g) are coated on after the centre of the palm slightly rubs and generates foam, are gradually postponed to entire head, so that all hairs
It can be contacted with shampoo composite；2. suitably being grabbed with finger pulp and rubbing scalp, cleaned after light rubbing hair with clear water.
Above-mentioned steps can be repeated as many times according to daily habits or needs.Shampoo composite is experienced not in hair washing process
The dense degree of foam size before bath, foam, foam stability, wet comb；The cleaning strength, submissive of shampoo composite is experienced when bath
Degree, bath property；Pliability, dry comb property, fluffy sense, glossiness and the comfort level of hair are experienced after hair is dry.Each assessment item
Marking system statistics is carried out by way of sensory evaluation, standards of grading are using 5 points of systems, and 1 point worst, and 5 points best.
Evaluation result is as shown in Figure 2.
As can be seen from the above table: the general comfort degree of embodiment 3 be it is best, implement in the test of each evaluation index
Example 3 also shows that more outstanding general performance；In addition, head can be obviously improved after the embodiment for being added to maltotetraose is on probation
The phenomenon that skin is itched, the embodiment use process for adding camellia seed oil are more comfortable.
Claims (4)
1. a kind of hair of children cleaning compositions of not silicate-containing oil, it is characterised in that: include following component by weight percentage
Composition: laureth sulfuric ester ammonium 5%~10%, Cocoamidopropyl betaine 1%~5%, cocounut oil acyl both sexes base diethyl
Acid disodium 1%~5%, Polyquaternium-10 0.05~0.2%, cationic oligomeric fructose 0.5%~2%, ricinoleic acid amide
Hydroxypropyltrimonium chloride 0.1%~1%, PPG-3 Octyl Ether 0.1%~1%, camellia seed oil 0.01%~0.5%, malt four
Sugar 1%~5%, camellia flower extract 0.5%~2%, viscosity modifier 0.5~2.0%, chelating agent 0.01~0.05%, pH
Regulator 0.05~0.2%, essence 0.05~0.3% and preservative 0.1~0.5%.
2. the hair of children cleaning compositions of a kind of not silicate-containing oil according to claim 1, it is characterized in that: the viscosity
Regulator is PPG-2 hydroxyethyl cocamide, and the chelating agent is sodium glucoheptonate, and the pH adjusting agent is citric acid,
The preservative is the compound of Phenoxyethanol and glycerol caprylate, glycerol monolaurate.
3. a kind of hair of children cleaning compositions of not silicate-containing oil according to claim 1 or 2, it is characterized in that: comprising
Group by weight percentage is grouped as below: laureth sulfuric ester ammonium 1%~10%, Cocoamidopropyl betaine 1%
~3%, cocounut oil acyl both sexes base diethyl acid disodium 1%~3%, Polyquaternium-10 0.05~0.1%, cationic oligomeric fructose
1%~2%, ricinoleic acid amide hydroxypropyltrimonium chloride 0.1%~0.5%, PPG-3 Octyl Ether 0.1%~0.5%, mountain
Tea-seed oil 0.01%~0.1%, maltotetraose 1%~2%, camellia flower extract 0.5%~1%, PPG-2 ethoxy cocounut oil acyl
It is amine 0.5~2.0%, sodium glucoheptonate 0.01~0.05%, citric acid 0.05~0.2%, Phenoxyethanol and glycerol caprylate, sweet
The compound 0.1~0.5% of oily laurate.
4. a kind of preparation method of not hair of children cleaning compositions of silicate-containing oil according to claim 1 or 2, special
Sign is, comprising the following steps:
(1) it injects water into agitated kettle, is sprinkled into Polyquaternium-10, be stirred after being heated to 60-65 DEG C and open cooling water drop
Temperature；
(2) sodium glucoheptonate, laureth sulfuric ester ammonium, Cocoamidopropyl betaine, cocounut oil acyl both sexes base are sequentially added
Diethyl acid disodium, ricinoleic acid amide hydroxypropyltrimonium chloride, each single item material must confirm the next item up material before being added
Dissolved/dispersion mixing is uniformly in composition；
(3) uniformly mixed, addition cationic oligomeric fructose, PPG-3 octyl after temperature is down to 45 DEG C are completely dissolved to above-mentioned material
Ether, camellia seed oil, maltotetraose, camellia flower extract, essence, citric acid, Phenoxyethanol and glycerol caprylate, glycerol lauric acid
The compound of ester is eventually adding PPG-2 hydroxyethyl cocamide, continues stirring 20 minutes after all adding.
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| CN201910320794.2A CN109864933A (en) | 2019-04-20 | 2019-04-20 | A kind of hair of children cleaning compositions of not silicate-containing oil and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111956522A (en) * | 2020-09-22 | 2020-11-20 | 福建省梦娇兰日用化学品有限公司 | Infant shampoo without silicone oil and preparation method thereof |
| CN112220735A (en) * | 2020-11-19 | 2021-01-15 | 聂绪明 | EM (effective microorganism) fungus shower gel and preparation method thereof |
| CN113456537A (en) * | 2021-07-24 | 2021-10-01 | 广州市清佁日用化工有限公司 | Cocoa fatty acyl amphoteric sodium acetate silicon-free shampoo and preparation method thereof |
| CN114767561A (en) * | 2022-05-05 | 2022-07-22 | 广州禾力生物科技有限公司 | Anti-dandruff shampoo composition |
| CN115813819A (en) * | 2022-12-03 | 2023-03-21 | 福建省梦娇兰日用化学品有限公司 | Children shampoo free of silicone oil and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106420407A (en) * | 2016-08-31 | 2017-02-22 | 福建省梦娇兰日用化学品有限公司 | Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil |
| KR20180058315A (en) * | 2016-11-24 | 2018-06-01 | 애경산업(주) | Hair cosmetic composition |
| CN108403462A (en) * | 2018-04-26 | 2018-08-17 | 内蒙古伊草恋生物科技有限责任公司 | A kind of baby bath dew containing licorice |
| WO2018152718A1 (en) * | 2017-02-23 | 2018-08-30 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | Silicone-free shampoo composition |
-
2019
- 2019-04-20 CN CN201910320794.2A patent/CN109864933A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106420407A (en) * | 2016-08-31 | 2017-02-22 | 福建省梦娇兰日用化学品有限公司 | Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil |
| KR20180058315A (en) * | 2016-11-24 | 2018-06-01 | 애경산업(주) | Hair cosmetic composition |
| WO2018152718A1 (en) * | 2017-02-23 | 2018-08-30 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | Silicone-free shampoo composition |
| CN108403462A (en) * | 2018-04-26 | 2018-08-17 | 内蒙古伊草恋生物科技有限责任公司 | A kind of baby bath dew containing licorice |
Non-Patent Citations (1)
| Title |
|---|
| 国产非特殊用途化妆品备案服务平台: ""小浣熊森活至亲肤系列儿童清润洗发沐浴二合一"", 《HTTP://FTBA.NMPA.GOV.CN:8181/FTBAN/FW.JSP》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111956522A (en) * | 2020-09-22 | 2020-11-20 | 福建省梦娇兰日用化学品有限公司 | Infant shampoo without silicone oil and preparation method thereof |
| CN112220735A (en) * | 2020-11-19 | 2021-01-15 | 聂绪明 | EM (effective microorganism) fungus shower gel and preparation method thereof |
| CN113456537A (en) * | 2021-07-24 | 2021-10-01 | 广州市清佁日用化工有限公司 | Cocoa fatty acyl amphoteric sodium acetate silicon-free shampoo and preparation method thereof |
| CN114767561A (en) * | 2022-05-05 | 2022-07-22 | 广州禾力生物科技有限公司 | Anti-dandruff shampoo composition |
| CN114767561B (en) * | 2022-05-05 | 2024-03-26 | 广州禾力生物科技有限公司 | Anti-dandruff shampoo composition |
| CN115813819A (en) * | 2022-12-03 | 2023-03-21 | 福建省梦娇兰日用化学品有限公司 | Children shampoo free of silicone oil and preparation method thereof |
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