CN113081889A

CN113081889A - Three-stage washing and protecting integrated composition

Info

Publication number: CN113081889A
Application number: CN202110401147.1A
Authority: CN
Inventors: 李小军
Original assignee: Guangdong Zhenbao Health Commodity Technology Co ltd
Current assignee: Guangdong Zhenbao Health Commodity Technology Co ltd
Priority date: 2021-04-14
Filing date: 2021-04-14
Publication date: 2021-07-09

Abstract

A three-stage wash-and-care composition comprises a surfactant, a care agent, an auxiliary agent and water, wherein the surfactant comprises an amino acid surfactant, an amphoteric surfactant and a cationic surfactant, and the care agent comprises a polyalcohol, an amino acid type humectant, an anti-allergy agent and a small molecule cationic protein active agent. The invention takes mild amino acid surfactant, amphoteric surfactant and cationic surfactant as main surfactants, utilizes cation in the cationic surfactant to wrap and form a polymer flocculation technology so as to form a lamellar liquid crystal structure, can effectively clean scalp and hair without damaging the scalp and hair, and has the effects of softening and resisting static electricity on the hair. In addition, the hair cream effectively smoothes hair frizziness and repairs hair scales by adding the micromolecule cationic protein active agent and the amino acid type humectant, and is easy to wash and cannot deposit on the scalp.

Description

Three-stage washing and protecting integrated composition

Technical Field

The invention relates to a three-stage washing and protecting integrated composition in the field of daily chemicals, in particular to a hair washing and protecting composition integrating three stages of scalp care, hair cleaning and hair care.

Background

The traditional two-in-one shampoo is excessive in cleaning, causes scalp stimulation, dry and itching hair, is not obvious in hair care effect, is not easy to comb due to frizzy tangles when the hair is semi-dry, is easy to cause deposition after long-term use, and can be used for washing and protecting separate products by firstly washing the hair with shampoo and then washing the hair with hair conditioner, so that the use steps are complex, most of washing and protecting products do not pay attention to the problems of scalp cleaning, moisture preservation and the like, and the product capable of deeply cleaning the scalp and caring the hair is lacked.

Meanwhile, the application of the surfactant in systems contacting with human bodies, such as medicines, foods, cosmetics and personal hygiene products, is more and more extensive, and with the improvement of the living standard of human beings, people pay more and more attention to the toxic and side effects of the surfactant in various formulations contacting with the human bodies. For different purposes, the focus of attention on surfactants is mainly focused on the aspects of irritation to mucosa, sensitization to skin, toxicity, heredity, carcinogenicity, teratogenicity and hemolysis, digestive absorption, biodegradability and the like, and the Chinese shampoo market is one of the earliest and fastest developing markets of the personal care market. The market competition is intense, manufacturers face more pressure, and new products and promotion ways are continuously pushed out to increase the market competition capability. Because the market is developed more rapidly, consumers have relatively mature consumption habits, and the consumption needs are more subdivided. The invention uses the combination of the novel amino acid surfactant, the amphoteric surfactant and the cationic surfactant, has good foaming performance, proper cleaning and washing capacity, and can not excessively degrease and cause hair dryness. At present, no product in the market can clean scalp hair in one step to remove stains without damaging the scalp hair, and the problems of no deep research on toxic and side effects of the product, low safety coefficient and the like exist.

Disclosure of Invention

The invention aims to provide a shampoo composition which can clean scalp and hair in one step to remove stains without damaging the scalp and hair, can realize the rebalancing of the natural barrier of the hair cleaning and hair cleaning in one step, brings an extremely good repairing effect to the hair while cleaning the hair, and solves the problems of excessive cleaning, scalp irritation, complicated separate use steps of the hair cleaning and protecting products and the like.

In order to solve the technical problems and achieve the required technical effects, the invention adopts the following technical scheme: a three-phase wash-and-care composition comprising a surfactant comprising an amino acid surfactant, an amphoteric surfactant and a cationic surfactant, a conditioning agent comprising a polyol, an amino acid type humectant, an anti-sensitivity agent and a small molecule cationic protein active agent, an adjuvant comprising a chelating agent, a preservative and an emulsifier, and water. The surfactant adopts amino acid surfactant, amphoteric surfactant and cationic surfactant, has effects of softening hair, resisting static electricity and emulsifying, improving smoothness of dry and wet water flushing and deeply cleaning scalp and hair, and can make hair fresh, clean and low-irritation, and make hair soft and antistatic. The polyhydric alcohol in the used care agent can improve the foam moisture degree and play a role in nourishing and caring hair, and the amino acid type humectant can keep sufficient hair moisture, supplement nutrient components required by the hair and avoid hair combing and knotting caused by drying. The anti-allergic agent can reduce the stimulation of the shampoo composition to the scalp, and the small molecular cationic protein active agent plays a deep part in repairing the hair scales of the damaged hair, and conditions the hair to make the hair smooth and easy to comb. The chelating agent in the adjuvant can reduce water quality and free ion concentration in raw materials, and reduce stimulation of free ions to hair. The antiseptic can inhibit the growth of microorganism, and the emulsifier can make shampoo composition have certain foaming amount. The low-foam and low-irritation hair washing and protecting composition which realizes one-step hair washing and protecting is characterized in that the whole hair washing process is divided into three stages, namely, the three stages of cleaning the scalp, cleaning the hair and caring the hair are completed at one time.

Further, the components are as follows according to the weight percentage: 7-48% of surfactant, wherein 2-10% of amino acid surfactant, 3-40% of amphoteric surfactant and 2-8% of cationic surfactant; the surfactant cannot foam effectively when the dosage is lower than the minimum dosage, and can irritate scalp skin when the dosage is higher than the maximum dosage, and symptoms such as dry and itchy scalp are easy to cause after the use.

7.55 to 25.1 percent of nursing agent, wherein 5 to 15 percent of polyol, 0.5 to 2 percent of amino acid type humectant, 0.05 to 0.1 percent of anti-allergy agent and 2 to 8 percent of micromolecular cationic protein active agent; when the content of the polyhydric alcohol is lower than 5%, the efficacy of moisturizing and hair care is reduced, and when the content of the polyhydric alcohol is higher than 15%, the production cost is increased, and the washed hair has greasy feeling and can damage the hair of a user; when the content of the amino acid type humectant is less than 0.5%, the moisturizing effect cannot be achieved, and when the content of the amino acid type humectant is more than 2%, the production cost is increased, so that the washed hair has sticky feeling; when the anti-allergy agent content is lower than 0.05%, the anti-allergy effect is not obvious, and when the anti-allergy agent content is higher than 0.1%, the production cost is increased; when the content of the micromolecule cationic protein active agent is lower than 2%, the function of repairing hair scales cannot be realized, when the content of the micromolecule cationic protein active agent is higher than 8%, the production cost is increased, and the amount of the micromolecule cationic protein active agent which can be absorbed by hair is limited, so that waste is caused.

0.65-2.6% of adjuvant, 0.05-0.1% of chelating agent, 0.1-0.5% of preservative, 0.5-2% of emulsifier and the balance of water. When the content of the chelating agent is less than 0.05%, the effect of chelating free ions is poor, and when the content of the chelating agent is more than 0.1%, the excessive chelating agent can cause certain damage to the skin of a user; when the content of the preservative is less than 0.1%, the growth of bacteria cannot be effectively inhibited, when the content of the preservative is more than 0.5%, the production cost is increased, and skin is damaged by adding too much preservative; when the emulsifier is less than 0.5%, the emulsifying effect is poor, the foaming amount is low due to washing protection, and when the emulsifier is more than 2%, the foaming amount is too much, so that the washing is difficult.

Still further, the components are as follows according to the weight percentage: 7% of surfactant, wherein 2% of amino acid surfactant, 3% of amphoteric surfactant and 2% of cationic surfactant are contained; 7.55% of a care agent, wherein 5% of polyol, 0.5% of amino acid type humectant, 0.05% of anti-allergy agent and 2% of micromolecular cationic protein active agent; 0.65% of adjuvant, 0.05% of chelating agent, 0.1% of preservative and 0.5% of emulsifier; the balance being water. The shampoo composition with the components in proportion can achieve the best washing and protecting effect, effectively control the secretion of scalp grease, clean hair and care hair.

Still further, the components are as follows according to the weight percentage: 25% of surfactant, wherein 3% of amino acid surfactant, 18% of amphoteric surfactant and 4% of cationic surfactant are contained; the care agent is 16.08 percent, wherein the polyol is 10 percent, the amino acid type humectant is 1 percent, the anti-allergy agent is 0.08 percent, and the micromolecular cationic protein active agent is 5 percent; 1.38% of auxiliary agent, 0.08% of chelating agent, 0.3% of preservative and 1% of emulsifier; the balance being water. The shampoo composition with the formula ratio of the components can achieve the optimal washing and protecting effect, effectively control the secretion of scalp grease, clean hair and care hair.

Still further, the components are as follows according to the weight percentage: 48% of surfactant, wherein 6% of amino acid surfactant, 34% of amphoteric surfactant and 8% of cationic surfactant are contained; 25.1 percent of nursing agent, wherein 15 percent of polyol, 2 percent of amino acid type humectant, 0.1 percent of anti-allergy agent and 8 percent of micromolecular cationic protein active agent; 2.6 percent of auxiliary agent, wherein the content of the chelating agent is 0.1 percent, the content of the preservative is 0.5 percent, and the content of the emulsifier is 2 percent; the balance being water. The shampoo composition with the formula ratio of the components can achieve the optimal washing and protecting effect, effectively control the secretion of scalp grease, clean hair and care hair.

Still further, the shampoo composition also contains essence, and the weight ratio of the essence is less than 1%. After the shampoo composition added with the essence is used, the hair of a user can emit pleasant smell, and the user feels relaxed and happy.

Still further, the amino acid surfactant is one or more of sodium lauroyl sarcosinate and sodium lauroyl glutamate, preferably the combination of the sodium lauroyl sarcosinate and the sodium lauroyl glutamate; the amphoteric surfactant is one or more of alkyl glycoside, cocamidopropyl betaine and PEG-80 sorbitan laurate, and is preferably the combination of alkyl glycoside and cocamidopropyl betaine; the cationic surfactant is one or more of behenyl trimethyl ammonium chloride, quaternary ammonium salt-80, cetrimonium methyl sulfate and stearyl trimethyl ammonium chloride, and is preferably the combination of behenyl trimethyl ammonium chloride and quaternary ammonium salt-80. The surfactants are mild in property, have small irritation to human bodies, do not have sensitization, toxicity, heredity, carcinogenicity, hemolytic property and the like to the human bodies, have high human skin contact safety coefficient, and do not cause negative influence on human health. And the components have good foaming performance and better cleaning performance.

Still further, the polyhydric alcohol is one or more of fatty alcohol, glycerol and propylene glycol of C16-C24, the humectant is one or more of arginine, alanine, serine, aspartic acid, histidine, proline, glutamic acid and glycine, the anti-allergy agent is one or more of bisabolol, allantoin and dipotassium glycyrrhizinate, the small molecule cationic protein active agent is one or more of cationized hydrolyzed sericin, hydrolyzed wheat protein and hydrolyzed silk protein, and the molecular weight of the small molecule cationic protein active agent is preferably 500-9000. The polyalcohol in the care agent has the functions of emulsification and molding and auxiliary moisture retention and esterification. The amino acid type moisturizers are mild in property and high in moisturizing capability, can form a moisturizing protective layer on the surface of hair, moisturize the hair after use, have good hand feeling, and can supplement nutritional ingredients required by the hair. The anti-allergy agent is added, so that allergy can not occur to a user in the using process, wherein the bisabolol, the allantoin and the dipotassium glycyrrhizinate can not be remained on the surface of the scalp, and the influence of drug residues on human health is avoided. The adopted micromolecular cationic protein active agents can deeply repair damaged hair scales and smooth hair and frizzy hair, the hair is smooth and easy to comb, the adopted cationic proteins are natural extracts and have no stimulation to the skin of a user, and the micromolecular cationic protein active agents are more easily absorbed by the hair and the scalp when the molecular weight is 500-9000.

Still further, the chelating agent is disodium ethylene diamine tetraacetate or phytic acid, the preservative is one or more of methyl p-hydroxybenzoate, propyl p-hydroxybenzoate and dimethyloldimethylhydantoin, and the emulsifier is one or more of cetyl ester wax polyether-20 and hydroxyethyl cellulose. The chelating agent can effectively reduce the concentration of free ions in water and raw materials, and reduce the damage of the free ions to hair. The phytic acid is natural extract, has good affinity to human skin, and has strong ion chelating ability. The preservative can prevent the growth of microorganisms and prolong the shelf life of the product. The emulsifier can foam the shampoo composition sufficiently and effectively clean hair and scalp.

The preparation method is prepared by the conventional mixing technology, is used in a conventional hair washing mode and mainly comprises the following steps:

(1) firstly, wetting hair by using clear water;

(2) the product of the invention is evenly smeared on the hair, and the scalp is gently kneaded until fine foam is generated for 1 to 3 minutes;

(3) kneading to large foam to clean hair;

(4) when the foam disappears, the hair is massaged until the hair is absorbed for about 1-2 minutes, and the hair is rinsed with water.

Compared with the prior art, the invention has the beneficial technical effects that:

firstly, the scalp and hair are effectively cleaned. The invention takes mild amino acid surfactant, amphoteric surfactant and cationic surfactant as main surfactants, utilizes cation in the cationic surfactant to wrap and form a polymer flocculation technology so as to form a lamellar liquid crystal structure, can effectively clean scalp and hair without damaging the scalp and hair, and has the effects of softening and resisting static electricity on the hair.

Secondly, the hair is effectively cured without conditioner deposition. The traditional shampoo achieves the hair care effect mainly by adding siloxane, but the siloxane is easy to deposit on scalp hair, so that the washing and care effect is poor, and the long-term accumulation of the deposit can stimulate the scalp to cause scalp discomfort of a user. According to the invention, the hair frizziness is effectively smoothed and the hair scales are repaired by adding the micromolecular cationic protein active agent and the amino acid type humectant, and the hair frizziness is easy to wash and cannot be deposited on the scalp.

Thirdly, the product is mild and non-toxic. The surfactant is selected from amino acid surfactant, amphoteric surfactant and cationic surfactant with mild irritation, and the caring agent and adjuvant are selected from mild irritation and little irritation, and natural extract is abundant and has no toxicity to human body.

Fourthly, the hair care is convenient to wash and care, and the hair care steps are reduced. Through adjustment of a formula of the care agent, the hair cleaning and the hair natural barrier rebalancing are realized in one step, an extremely repairing effect is brought to the hair while the hair is cleaned, the hair washing and the hair protection are completed in one step, and the whole hair washing process, namely the three stages of cleaning the scalp, cleaning the hair and caring the hair, is completed at one time.

Detailed Description

In order that those skilled in the art will better understand the technical solutions of the present invention, the present invention will now be further described with reference to the specific embodiments.

The specific compositions and amounts of examples 1-3 are given in the following table (in weight percent):

the three-stage combined cleansing and caring composition described in the above examples 1 to 3 has low production cost, can effectively clean scalp and hair, can effectively care hair, is mild and non-toxic, and is convenient for cleansing and caring.

The surfactant pairs used in the above examples 1 to 3 are very mild, have little irritation to the human body, do not have sensitization, toxicity, inheritance, carcinogenicity, hemolytic property and the like to the human body, have high safety factor for human skin contact, and do not have negative effects on human health. And the components have good foaming performance and better cleaning performance. Therefore, one or more of the components are selected as the surfactant, so that the shampoo composition is mild and not irritant, does not cause negative effects on the health of human bodies, and has better foaming and cleaning performances.

The present inventors carried out mild evaluation with respect to the irritativeness of the surfactant by in vivo test (Invivotest) and ex vivo test (Invitrotest). The in-vivo test is mainly carried out on rabbit skin and rabbit eye mucosa, and the in-vitro test is carried out by simulating organisms with in-vitro cells or proteins, observing the effect of the surfactant on the in-vitro proteins or cells, and deducing the degree of the effect on the in-vivo tissues. The inventors distributed that the irritativeness of the surfactants was tested using the drialize rabbit eye mucosa test and the rebloodcorrbestest (rbctest). Tables 1 and 2 respectively list the results of irritation tests for some common surfactants.

TABLE 1 part surfactant and three phase Wash-Care combination maximum Draize concentration for Leporus mucosa of Draize Rabbit A three-stage shampoo composition of the invention is the composition described in example 2)

Note: higher maximum concentrations of the tolerated stimulus indicate a milder system.
	TABLE 2 comparison of some surfactants with RBCTest results of a three-stage rinse-care composition of the invention (wherein the three stages of the invention Shampoo composition the composition described in example 2

	Note: a higher L/D value for RBCTest represents lower stimulation.

From table 1, it can be seen that: the highest concentration of the common surfactant for the shampoo is less than 30 percent and can reach 0.5 percent at least, while the highest concentration of the shampoo composition for the shampoo is 60.4 percent, and the stimulation index of the shampoo composition is half of the minimum stimulation index of the common shampoo surfactant, which shows that the common surfactant for the shampoo is relatively more irritant to human skin, and the shampoo for the shampoo has very low irritation to the human skin.

From table 2, it can be seen that: the L/D value of the surfactant generally used in the general shampoo was less than 200, while the L/D value of the shampoo composition of example 2 of the present invention was 330, which is more than 100, compared to the L/D value of the surfactant generally used in the general shampoo, indicating that the shampoo composition of the present invention has very low irritation and mild properties.

To further fully demonstrate the low irritation, foaming, pliability, and water usage of the present invention, the inventors prepared comparative examples 1-3 as shown in the following table, while also subjecting example 2 of the present invention and a commercially available shampoo A, B to the Draize rabbit eye mucosa test and RBCTest, respectively, and the results of the tests are shown in table 3.

TABLE 3 Draize Rabbit eye Mucosa test and RBCTest evaluation and comparison of a commercially available shampoo A, B and a three-stage Care composition according to example 2 of the present invention

As can be seen from the test results in Table 3, the irritation of example 2 of the present invention was milder and less irritating to human skin than the other two commercially available shampoos A, B.

The nursing agent comprises polyalcohol which is C16-C24 fatty alcohol, has emulsification effect and auxiliary moisturizing and esterification effect, and the amino acid type humectant is one or more of arginine, alanine, serine, aspartic acid, histidine, proline, glutamic acid and glycine, and has effects of moistening hair and smoothing hair. The anti-allergic agent is one or more of bisabolol, allantoin and dipotassium glycyrrhizinate, so that skin allergy of users can be avoided, and the safety coefficient of use is higher. The micromolecular cationic protein active agent is one or more of cationized hydrolyzed sericin, cationized hydrolyzed wheat protein and cationized hydrolyzed fibroin, the micromolecular cationic protein active agent is obtained by hydrolyzing natural protein, and the molecular weight of the micromolecular cationic protein active agent is 500-9000. Can effectively smooth the frizzy hair, repair hair scales and make the hair smoother.

The present inventors conducted comparative tests of hair washing effect on the three-stage shampoo-care composition of example 2 of the present invention, comparative examples 1 to 3 and 2 commercially available shampoos A, B, and compared the foaming ability, washing ability, degreasing ability and hair softness, respectively, and the results of the tests are shown in Table 4.

As can be seen from Table 4, the foam heights of the commercially available shampoo A and the commercially available shampoo B were 110mm and 105mm, respectively, whereas the foam height of the shampoo composition of example 2 of the present invention was 50mm, and the foam heights of the shampoo composition of the present invention and the commercially available shampoo were 60mm and 55mm, respectively, but the foam strength was not so strong that the rinse water consumption was high, and the foam amount was moderate and the rinse water was easy. The washing capacities of the commercially available shampoo A and the commercially available shampoo B are 20 and 15 respectively, and the washing capacity of the shampoo composition is 30, which shows that the shampoo composition has stronger washing capacity and can effectively clean hair and scalp. The degreasing dissolution rates of the commercially available shampoo A and the commercially available shampoo B are respectively 70% and 65%, while the degreasing dissolution rate of the shampoo composition is 40%, and the degreasing dissolution rates of the commercially available shampoo A and the commercially available shampoo B are respectively higher than that of the shampoo composition provided by the invention, however, the higher the degreasing dissolution rate is, the better the degreasing dissolution rate is, the stronger the degreasing dissolution rate is, the hair can lose a grease film for protecting the hair, and the scalp and the hair can be damaged, and the grease dissolution rate of the shampoo provided by the invention is just moderate, so that a protective layer for protecting the scalp and the hair can be simultaneously not damaged in the hair cleaning process, and the optimal hair care effect can be achieved. The softness of the commercial shampoo A and the commercial shampoo B is respectively 15% and 10% less than that of the shampoo composition, and the shampoo composition provided by the invention is proved to have better softness. In conclusion, the shampoo composition of the present invention is superior in foaming ability, washing ability, defatting rate and hair softness compared to commercially available shampoos A and B.

In addition, as can be seen from table 4, the composition of example 2 of the present invention has stronger washing ability than comparative examples 1 and 2, and better flexibility than comparative example 3, and example 2 of the present invention shows more excellent ability than comparative examples 1, 2 and 3 in overall combination of washing, degreasing and flexibility. The combination of the amino acid surfactant, the cationic surfactant, the amino acid humectant and the cationized hydrolyzed protein is adopted, so that the comprehensive excellent performances of washing, degreasing and softening can be achieved.

The present inventors conducted comparative tests on the ease of rinsing with the shampoo composition of example 2 of the present invention, comparative examples 1 to 3 and commercially available shampoo A, B, and compared the effects of the same amount of shampoo used in the tests with respect to the rinsing time, the rinsing degree of foam and the amount of water, respectively, and the results of the tests are shown in Table 5.

As can be seen from table 5, the water flushing time of the commercially available shampoo a and the commercially available shampoo B was 16 seconds and 12 seconds, respectively, and the water flushing time of the present invention was 6 seconds, which was 10 seconds and 6 seconds shorter than the water flushing time of the commercially available shampoo a and the commercially available shampoo B, respectively, and it was confirmed that the present invention was easier to rinse. The water consumption of the commercially available shampoo A and the commercially available shampoo B is respectively 2.5 liters and 2.1 liters, the water consumption of the shampoo is 1 liter, and is respectively 1.5 liters and 1.1 liter less than the water consumption of the commercially available shampoo A and the commercially available shampoo B, and the shampoo is proved to be easy to wash, can effectively reduce the water consumption and save the water. Example 2 is superior to comparative examples 1-3 in overall performance of washing, degreasing, and softening, although the flush time is longer.

The foregoing is merely a preferred embodiment of the invention and is not intended to limit the invention in any manner; those of ordinary skill in the art can readily practice the present invention as described above; however, those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiments as a basis for designing or modifying other structures for carrying out the same purposes of the present invention without departing from the scope of the invention as defined by the appended claims; meanwhile, any changes, modifications, and evolutions of the equivalent changes of the above embodiments according to the actual techniques of the present invention are still within the protection scope of the technical solution of the present invention.

Claims

1. A three-stage combined cleaning and care composition, which is characterized in that: the composition comprises a surfactant, a care agent, an auxiliary agent and water, wherein the surfactant comprises an amino acid surfactant, an amphoteric surfactant and a cationic surfactant, the care agent comprises a polyhydric alcohol, an amino acid type humectant, an anti-allergy agent and a small-molecule cationic protein active agent, and the auxiliary agent comprises a chelating agent, a preservative and an emulsifier.

2. The three-stage rinse-care composition according to claim 1, characterized in that: the formula of the components in percentage by weight is as follows:

7-48% of surfactant, wherein 2-10% of amino acid surfactant, 3-40% of amphoteric surfactant and 2-8% of cationic surfactant;

7.55 to 25.1 percent of nursing agent, wherein 5 to 15 percent of polyol, 0.5 to 2 percent of amino acid type humectant, 0.05 to 0.1 percent of anti-allergy agent and 2 to 8 percent of micromolecular cationic protein active agent;

0.65-2.6% of adjuvant, 0.05-0.1% of chelating agent, 0.1-0.5% of preservative and 0.5-2% of emulsifier;

the balance being water.

3. The three-stage rinse-care composition according to claim 2, characterized in that: the formula of the components in percentage by weight is as follows:

7% of surfactant, wherein 2% of amino acid surfactant, 3% of amphoteric surfactant and 2% of cationic surfactant are contained;

7.55% of a care agent, wherein 5% of polyol, 0.5% of amino acid type humectant, 0.05% of anti-allergy agent and 2% of micromolecular cationic protein active agent;

0.65% of adjuvant, 0.05% of chelating agent, 0.1% of preservative and 0.5% of emulsifier;

the balance being water.

4. The three-stage rinse-care composition according to claim 2, characterized in that: the formula of each component in percentage by weight is as follows:

25% of surfactant, wherein 3% of amino acid surfactant, 18% of amphoteric surfactant and 4% of cationic surfactant are contained;

the care agent is 16.08 percent, wherein the polyol is 10 percent, the amino acid type humectant is 1 percent, the anti-allergy agent is 0.08 percent, and the micromolecular cationic protein active agent is 5 percent;

1.38% of auxiliary agent, 0.08% of chelating agent, 0.3% of preservative and 1% of emulsifier;

the balance being water.

5. The three-stage rinse-care composition according to claim 2, characterized in that: the formula of each component in percentage by weight is as follows:

48% of surfactant, wherein 6% of amino acid surfactant, 34% of amphoteric surfactant and 8% of cationic surfactant are contained;

25.1 percent of nursing agent, wherein 15 percent of polyol, 2 percent of amino acid type humectant, 0.1 percent of anti-allergy agent and 8 percent of micromolecular cationic protein active agent;

2.6 percent of auxiliary agent, wherein the content of the chelating agent is 0.1 percent, the content of the preservative is 0.5 percent, and the content of the emulsifier is 2 percent;

the balance being water.

6. The three-stage rinse-care composition according to claim 1, characterized in that: the composition also contains essence, and the weight ratio of the essence is less than 1%.

7. The three-stage rinse-care composition according to claim 1, characterized in that: the amino acid surfactant is one or more of sodium lauroyl sarcosinate and sodium lauroyl glutamate, and is preferably the combination of the sodium lauroyl sarcosinate and the sodium lauroyl glutamate;

the amphoteric surfactant is one or more of alkyl glycoside, cocamidopropyl betaine and PEG-80 sorbitan laurate, and is preferably the combination of alkyl glycoside and cocamidopropyl betaine;

the cationic surfactant is one or more of behenyl trimethyl ammonium chloride, quaternary ammonium salt-80, cetrimonium methyl sulfate and stearyl trimethyl ammonium chloride, and is preferably the combination of behenyl trimethyl ammonium chloride and quaternary ammonium salt-80.

8. The three-stage rinse-care composition according to claim 1, characterized in that: the polyalcohol is one or more of C16-C24 fatty alcohol, glycerol and propylene glycol;

the amino acid type humectant is one or more of arginine, alanine, serine, aspartic acid, histidine, proline, glutamic acid and glycine;

the anti-allergic agent is one or more of bisabolol, allantoin and dipotassium glycyrrhizinate;

the small molecular cationic protein active agent is one or more of cationized hydrolyzed sericin, hydrolyzed wheat protein and hydrolyzed fibroin, and preferably has the molecular weight of 500-9000.

9. The three-stage rinse-care composition according to claim 1, characterized in that: the chelating agent is disodium ethylene diamine tetraacetate or phytic acid;

the preservative is one or more of methyl p-hydroxybenzoate, propyl p-hydroxybenzoate and dimethylol dimethyl hydantoin;

the emulsifier is one or more of cetyl ester wax polyether-20 and hydroxyethyl cellulose.

10. A method of using a three-stage rinse-and-care composition according to any of claims 1 to 9, consisting essentially of the steps of:

(1) firstly, wetting hair by using clear water;

(2) evenly applying the three-stage cleansing and caring composition as claimed in any one of claims 1-9 to the hair, gently massaging the scalp to give a fine foam for 1-3 minutes;

(3) kneading to large foam to clean hair;

(4) and after the foam disappears, massaging the hair until the hair is absorbed for 1 to 2 minutes approximately, and then washing the hair clean with water.