CN103751084B - A kind of trehalose and organic selenium composition and the application in hair conditioner thereof - Google Patents
A kind of trehalose and organic selenium composition and the application in hair conditioner thereof Download PDFInfo
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Abstract
The present invention relates to a kind of trehalose and organic selenium composition and the application in hair conditioner thereof, belong to household chemicals field.Described trehalose and organic selenium composition are made up of the raw material of following masses portion rate: trehalose: yeast rich in selenium=1: (2.5 ~ 3.5).Advantage is: trehalose of the present invention and organic selenium composition are applied in hair conditioner formula; hair can be improved and resist the ability of environmental stimuli and the ability of self-protection; can the Protein requirement invariance of longer time after hair is subject to extraneous physical stimulation or chemical change; hair is subject to after extraneous physical stimulation or chemical change can the maintenance hair epidermis cell of longer time, make hair maintain before gloss and submissive.The invention enables hair under antagonism environmental stimuli, by scalp, its nutrient substance provided is ensured to the balance of selenium element in human body.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of trehalose and the application of yeast rich in selenium compositions in hair conditioner.
Background technology
The outermost layer structure of hair, main composition material is a kind of protein being " keratin ", is made up of the horn cell of scale or tiles.It can resist external physical action and the stimulation of chemical action, and protection sebum also suppresses the evaporation of moisture content.General said hair damage, the i.e. damage of horny layer (hair epidermis).Stratum corneum gets thinner, hair can lose cohesiveness and resistance, and hair quality becomes fragile, when sunlight enters in cell from the translucent cells film of epidermal area, if, can irregular reflection be there is when sunlight is injected, to the sensation that a kind of hair quality of people is coarse in hair quality damage or bifurcated.
Hair-waving is generally the little spring of first breaking cystine with the chemical medicinal liquid of reproducibility, the thin sulphur bridge key of cystine is disconnected, becomes two cysteine.At this moment, the aminoacid chain link of hair just loosens and comes, and controls, coil into certain waveform with people.And then put on the skin and smear fixative, the cysteine of disconnection little spring is combined between two nearby, forms new spring, hair style is fixed up.In the process of hair-waving, the alkaline components in liquid medicine and Oxidation, can cause the scale on hair top layer to be destroyed.Make hair internal structure be in unprotect state, inner moisture and nutrient loss can be made, be harmful to hair, scalp and hair follicle, the keratoprotein generation degeneration of hair can be made more or less, hair is easily turned to be yellow, embrittlement, lackluster, there is no elasticity.
Hair dyeing is equally also open (scale on hair is met alkali and opened) with the hair scale sheet that the alkaline components labour contractor in dye cream delivers layer, and artificial color enters into the cortical layer of hair, combines with the part in natural pigment, the color that formation is wanted.Contaminate the ammonia in cream during hair dyeing, the hair scale sheet that enemy delivers layer has very strong destruction, if maintenance improperly words can cause that the scale of hair comes off, water loss, coarse grain raising, lacks gloss and does not have elasticity.
General containing cationic surface active agent in the hair conditioner supplementary material of existing routine, silicone compound, oily compound, fatty alcohol and fatty acid etc.The cationic surface active agent that act as played respectively is mainly quaternary ammonium compound, and it can play the effect of emulsifying oily mater, and can attract each other with the anion in hair epidermal protein, thus is adsorbed on hair surface and forms protecting film.It because it is with long-chain fat alkyl, there is softness and lubrication, so can make hair submissive, gloss.It is also the main component of anti-static electrification in addition, and in general hair conditioner, content is greatly between 1%-4%.
Silicone compound refers to polysiloxanes and derivant thereof, and its effect makes hair surface become smooth, high resilience.How water insoluble silicone is, need disperse by emulsifying agent and stay on hair.The consumption of silicone in hair conditioner is many at 2%-10%.
Oily compound can play the effect preventing moisture evaporation in hair, thus keeps the flexibility of hair, is easy to combing.Its deal in hair conditioner has very large difference because hair conditioner kind is different.
Fatty alcohol and this compounds of fatty acid, have the feel as butter, can increase and send out a smoothness of the surface, make it be easy to combing, and its content in hair conditioner is generally no more than 10%.
Except containing except above composition in hair conditioner, also containing carrier components, mostly be the mixture etc. of water or water and ethanol.But these often can only from changing hair quality on the surface, also the resistivity improving it is not enough to, especially hair quality after scalding is directed to, after scalding, the protein of hair itself changes, and it is extremely unstable, common hair conditioner can only maintain its apparent condition the short time, cure the symptoms, not the disease, As time goes on because protein that stability is very poor itself can degeneration gradually under the stimulation in the external world, and the ability adding the several respects such as membership makes the radioprotective of hair, antioxidation, alimentation slow of trehalose obtains raising to a certain extent.
Anti-dehydration mechanism about trehalose has following three kinds of hypothesis: a kind of " water substitutes " hypothesis proposed with artificial representatives such as Crowe; they think when biomacromolecule loses the structure moisture film maintaining its 26S Proteasome Structure and Function characteristic; trehalose can connect with hydrogen bond formation at the dehydrated regions of biomolecule, forms layer protecting film to replace the structure moisture film lost.Another kind is " glassy state " hypothesis, thinks by the trend of trehalose glass transition, causes the formation of amorphous continuous phase, structurally similar to the ice of glassy state, and molecular motion and molecule degeneration react very faint in such an embodiment.The third is " preferential exclusion " hypothesis.Above hypothesis is all investigate the mechanism of action of trehalose from molecule angle, is all formed " molecular complex " with biomolecule substantially.
Can well prevent the adding of trehalose protein freezing, high temperature or dry time degeneration.Can the natural structure of effectively protected protein matter molecule, trehalose also decomposes the unsaturated fatty acid in the oils and fats composition in hair conditioner good inhibitory action.Hair epidermis is also a kind of biomembrane, and trehalose can make still to be in mesomorphic state at the film fat of dehydration conditions by reducing phase transition temperature, plays the biomembranous effect of protection thus.
Trehalose also has stronger radiation resistance simultaneously, and it can remove the OH free radical that α-ray produces.Trehalose can not damaged by radioactive substance by Cell protection DNA.It is reported, when there is 10mmol trehalose, DNA can stand the beta rays of 4 multiple doses, gamma-radiation, and sugared content is higher, and protective effect is stronger.Its mechanism is: the reaction of DNA break that ray causes mainly is dissociated by surrounding water molecules, and the hydroxyl radical free radical that produces causes, and trehalose can effectively be removed.
Yeast rich in selenium, pale yellow powder, add selenium element in the process of culture yeasts, selenium has been absorbed during yeast growth, the protein of selenium in yeast body and polysaccharide organic are combined and are converted into biological selenium, thus eliminate chemical selenium the toxicity of human body and the intestines and stomach are stimulated, selenium more efficiently, is more safely absorbed by the body utilization.Yeast rich in selenium be also up to now domestic the most efficiently, the selenium-replenishing preparation that the safest, nutrition is the most balanced.Yeast rich in selenium is generally containing selenium 300mg/kg, and reach as high as 1000mg/kg, wherein organic selenium content is more than 95%, what combine with protein (cystine) accounts for 83% of total organic selenium amount, another containing protein 55.8%, vitamin B1 is 3.2mg/kg, and vitamin B2 is 33.2mg/kg.
Selenium is the biological element of needed by human, and human body lacks the dysfunction that selenium can cause many vitals, causes the generation of various diseases.Modern medicine confirms, the important physiological actions such as selenium has anticancer, anti-angiocardiopathy, prevents and treats Keshan disease, defying age, enhancing human body immunity function.China 72% area is in scarce selenium, low selenium band, and in meals, the deficiency of selenium intake drastically influence the healthy of China several hundred million population.And we use a large amount of chemicals usually on hair and a small amount of scalp, the health not only having had a strong impact on our hair also causes certain harm to our human body, and the morbidity of especially present many cancers is because of all because it uses a large amount of chemicals to accumulate over a long period produced.
In human body, the content standard value of blood selenium is 0.11 μ g/g, lower than this value, scarce selenium disease likely occurs.The area that China has 29% per capita selenium content, at below 0.02ppm, is decided to be and extremely lacks selenium area, and having the regional human body of 43% containing selenium value between 0.03-0.04ppm, is scarce selenium area.In other words, China have the area of 72% totally 15 provinces and regions about 3 × 108 population be subject to the threat of scarce selenium.Human body is about 6 ~ 21mg containing selenium total amount, be extensively distributed in vivo except fat institute in a organized way, in body fluid and skeleton.Total selenium amount is distributed as muscular tissue and accounts for 50% ~ 52%, and skin and hair account for 14% ~ 15%, and skeleton accounts for 10%, liver accounts for 8%, other tissue accounts for 15% ~ 18%, and visible dermis and hair account for suitable proportion, and hair more serves as connecting an extraneous important contact point effect that can not be ignored.
Traditional hair conditioner serves the effect of obstruction to the hair follicle on scalp, hair follicle can not be made to carry out Repiration completely, cause scalp can produce the dandruff, but hair conditioner of the present invention suggestion can be evenly coated on scalp and to massage, because a growth quality part for hair takes from the nutrient substance on scalp, scalp to absorb at any time just as soil extraneous to various resources, to transform and accumulating just as plant carries out biology by the selenium drawn in soil, because the level difference of different regions Selenium in Soils is very large, therefore have impact on plant, also have impact on the rich widow of selenium in animal body simultaneously, data is had to show the hundred times in Se content Shi Quexi district in the plant of high selenium zone, in general Fei Quexi district staple food, Se content is also apparently higher than serious Que Xi district, so timely supplement scalp nutrient substance for hair and human body itself all favourable and harmless.
Summary of the invention
The invention provides a kind of trehalose and organic selenium composition and the application in hair conditioner thereof, resist the not high problem of the ability of the ability of environmental stimuli and self-protection to solve current hair.
The technical scheme that the present invention takes is: be made up of the raw material of following masses portion rate:
Trehalose: yeast rich in selenium=1:(2.5 ~ 3.5)
The application in hair conditioner of trehalose and organic selenium composition, described trehalose and organic selenium composition are made up of the raw material of following masses portion rate: trehalose: yeast rich in selenium=1:(2.5 ~ 3.5).
Advantage of the present invention is: trehalose of the present invention and organic selenium composition are applied in hair conditioner formula; hair can be improved and resist the ability of environmental stimuli and the ability of self-protection; can the Protein requirement invariance of longer time after hair is subject to extraneous physical stimulation or chemical change; hair is subject to after extraneous physical stimulation or chemical change can the maintenance hair epidermis cell of longer time, make hair maintain before gloss and submissive.The invention enables hair under antagonism environmental stimuli, by scalp, its nutrient substance provided is ensured to the balance of selenium element in human body.
Detailed description of the invention
Embodiment 1
Be made up of the raw material of following masses portion rate:
Trehalose: yeast rich in selenium=1:2.5;
The application in hair conditioner of trehalose and organic selenium composition, described trehalose and organic selenium composition are made up of the raw material of following masses portion rate: trehalose: yeast rich in selenium=1:2.5.
Embodiment 2
Be made up of the raw material of following masses portion rate:
Trehalose: yeast rich in selenium=1:3;
The application in hair conditioner of trehalose and organic selenium composition, described trehalose and organic selenium composition are made up of the raw material of following masses portion rate: trehalose: yeast rich in selenium=1:3.
Embodiment 3
Be made up of the raw material of following masses portion rate:
Trehalose: yeast rich in selenium=1:3.5;
The application in hair conditioner of trehalose and organic selenium composition, described trehalose and organic selenium composition are made up of the raw material of following masses portion rate: trehalose: yeast rich in selenium=1:3.5.
Effect of the present invention is further illustrated below by real test of specifically taking care of hair.
Yeast rich in selenium used is commercially available prod, and containing selenium 500mg/kg, wherein organic selenium content is more than 95%, what combine with protein (cystine) accounts for 83% of total organic selenium amount, another containing protein 55.8%, vitamin B1 is 3.2mg/kg, and vitamin B2 is 33.2mg/kg.
Test method: get identical wisp of hair, divides uniformly four parts, and numbering dye scalds A, the boiling hot B of dye, dye scalds C, dye scalds D.Use the sodium lauryl sulfate washed with saline solution 1 minute of 3ml mass fraction 5% respectively, after the moisture that removing is excessive, dye is scalded A with 0.5 gram containing trehalose and hair conditioner sample rubbing 2 minutes, dye scalds the 0.5g hair conditioner sample rubbing 2 minute of B containing trehalose and yeast rich in selenium, dye scalds the 0.5g hair conditioner sample rubbing 2 minute of C containing yeast rich in selenium, the 0.5g hair conditioner sample rubbing that the boiling hot D of dye uses trehalose and yeast rich in selenium compositions containing ratio 1:3 to add 2 minutes, 1 minute is rushed respectively again with flowing water, and with dry napkin, moisture is blotted, combing hair, assess it and establish performance and a wet anti-entangling.By this four bundles bundle of hair around on 20mm reel, make it dried overnight in atmosphere, to irradiate through 6 hours of daylight through continuous every day respectively afterwards, 2 hours blowing hot winds and permanent hair styling in 30 minutes, after the test in 5 week, combing curly hair bundle, assesses its dry carding property, a dry anti-entangling, and hair gloss degree etc., we are by sensory evaluation method, and the mensuration of selenium content then uses standard spectrophotometric method to measure.(principle: selenium can form colored complex with organicvisualization reagent complexation in acidity or alkaline medium, colored complex is (or without the need to extraction directly in aqueous phase) after organic solvent extraction, spectrophotometric analysis can be carried out according to colour developing degree, thus the mensuration of Se content can be carried out.）
Dye is scalded in A containing trehalose and hair conditioner formula
| Basic components project | Adding proportion | Addition |
| Cationic surfactant (alkyl quaternary ammonium salts 1631) | 2.5% | 2.5g |
| Cetostearyl alcohol | 5.0% | 5.0g |
| PEG-20 ceteareth | 0.5% | 0.5g |
| White oil | 2.0% | 2.0g |
| Glycerol | 5.0% | 5.0g |
| Silicone oil | 2.0% | 2.0g |
| Citric acid | Adjusted to ph to 4.0 | 2.0g |
| Antiseptic, essence | In right amount | 1.5g |
| Trehalose powder | 2.0% | 2.0g |
| Water | Be added into 100% |
Get wisp of hair, test under the prerequisite of nutrition is not provided at root, the bundle of hair sodium lauryl sulfate washed with saline solution 1 minute of 3ml mass fraction 5%, after the moisture that removing is excessive, contain trehalose hair conditioner sample rubbing 2 minutes with 0.5 gram, then rush 1 minute with flowing water respectively, and with dry napkin, moisture is blotted, combing hair, assesses it and establishes performance and a wet anti-entangling.By this bundle bundle of hair around on 20mm reel, make it dried overnight in atmosphere, irradiate through 6 hours of daylight by continuous every day, 2 hours blowing hot winds and permanent hair styling in 30 minutes, combing curly hair bundle after the test in 5 week, we assess its carding property by subjective appreciation method, a dry anti-entangling, and hair gloss degree etc.
Hair conditioner containing trehalose scalds A subjective appreciation table to dye
| One week | Fortnight | Three weeks | Four weeks | Five weeks | |
| Outward appearance | Gloss | Gloss | Gloss | Gloss | Gloss |
| Feel | Generally smooth | Generally smooth | Generally smooth | Generally smooth | Generally smooth |
| Anti-entangling | Do not tie a knot | Do not tie a knot | Do not tie a knot | Do not tie a knot | Do not tie a knot |
| Cardability | Be easy to combing | Be easy to combing | Be easy to combing | Be easy to combing | Be easy to combing |
| Antistatic behaviour | 15 degree | 15 degree | 15 degree | 15 degree | 15 degree |
| Selenium content | 710μg | 710μg | 708μg | 707μg | 705μg |
Appearance ratings: tarnish, slightly gloss, gloss; Feel: not smooth, generally smooth, smooth; Anti-entangling: knotting, indivedual place are tied a knot, do not tied a knot; Cardability: combing need be pullled hair, is easy to combing, very easily combing; Antistatic behaviour: under specific temperature humidity condition, be fixed on by topknot in face of disk measuring instrument, utilizes light source to make topknot produce shade, and allow electric charge on Hair girding in specific combing mode, before and after measuring combing, topknot produces the shade angle dispersed, unit: spend.
Dye scalds the hair conditioner formula not containing trehalose and yeast rich in selenium in B:
| Basic components project | Adding proportion | Addition |
| Cationic surfactant (alkyl quaternary ammonium salts 1631) | 2.5% | 2.5g |
| Cetostearyl alcohol | 5.0% | 5.0g |
| PEG-20 ceteareth | 0.5% | 0.5g |
| White oil | 2.0% | 2.0g |
| Glycerol | 5.0% | 5.0g |
| Silicone oil | 2.0% | 2.0g |
| Citric acid | Adjusted to ph to 4.0 | 2.0g |
| Antiseptic, essence | In right amount | 1.5g |
| Water | Be added into 100% |
Get identical wisp of hair, test under the prerequisite of nutrition is not provided at root, the bundle of hair sodium lauryl sulfate washed with saline solution 1 minute of 3ml mass fraction 5%, after the moisture that removing is excessive, with 0.5 gram of above-mentioned hair conditioner sample rubbing 2 minutes, then rush 1 minute with flowing water respectively, and with dry napkin, moisture is blotted, combing hair, assesses it and establishes performance and a wet anti-entangling.By this bundle bundle of hair around on 20mm reel, make it dried overnight in atmosphere, irradiate through 6 hours of daylight by continuous every day, 2 hours blowing hot winds and permanent hair styling in 30 minutes, combing curly hair bundle after the test in 5 week, we assess its carding property by sensory evaluation method, a dry anti-entangling, and hair gloss degree etc.
Hair conditioner not containing trehalose and yeast rich in selenium scalds B sensory evaluation table to dye
| One week | Fortnight | Three weeks | Four weeks | Five weeks | |
| Outward appearance | Gloss | Slightly gloss | Slightly gloss | Slightly gloss | Matt |
| Feel | Smooth | Generally smooth | Generally smooth | Generally smooth | Not smooth |
| Anti-entangling | Do not tie a knot | The knotting of indivedual places | Tie a knot in many places | Knotting | Knotting |
| Cardability | Be easy to combing | Be easy to combing | Hair need be pullled | Hair need be pullled | Hair need be pullled |
| Antistatic behaviour | 15 degree | 18 degree | 24 degree | 32 degree | 40 degree |
| Selenium content | 710μg | 710μg | 708μg | 707μg | 705μg |
Appearance ratings: tarnish, slightly gloss, gloss; Feel: not smooth, generally smooth, smooth; Anti-entangling: tie a knot, do not tie a knot in knotting, indivedual local knotting, many places; Cardability: combing need be pullled hair, is easy to combing, very easily combing; Antistatic behaviour: under specific temperature humidity condition, be fixed on by topknot in face of disk measuring instrument, utilizes light source to make topknot produce shade, and allow electric charge on Hair girding in specific combing mode, before and after measuring combing, topknot produces the shade angle dispersed, unit: spend.
Dye scalds the hair conditioner formula containing yeast rich in selenium in C
| Basic components project | Adding proportion | Addition |
| Cationic surfactant (alkyl quaternary ammonium salts 1631) | 2.5% | 2.5g |
| Cetostearyl alcohol | 5.0% | 5.0g |
| PEG-20 ceteareth | 0.5% | 0.5g |
| White oil | 2.0% | 2.0g |
| Glycerol | 5.0% | 5.0g |
| Silicone oil | 2.0% | 2.0g |
| Citric acid | Adjusted to ph to 4.0 | 2.0g |
| Antiseptic, essence | In right amount | 1.5g |
| Yeast rich in selenium | 6.0% | 6.0g |
| Water | Be added into 100% |
Get wisp of hair, test under the prerequisite of nutrition is not provided at root, the bundle of hair sodium lauryl sulfate washed with saline solution 1 minute of 3ml mass fraction 5%, after the moisture that removing is excessive, above-mentionedly send out sample rubbing plain 2 minutes containing yeast rich in selenium with 0.5 gram, then rush 1 minute with flowing water respectively, and with dry napkin, moisture is blotted, combing hair, assesses it and establishes performance and a wet anti-entangling.By this bundle bundle of hair around on 20mm reel, make it dried overnight in atmosphere, irradiate through 6 hours of daylight by continuous every day, 2 hours blowing hot winds and permanent hair styling in 30 minutes, combing curly hair bundle after the test in 5 week, we assess its carding property by sensory evaluation method, a dry anti-entangling, and hair gloss degree etc.
Hair conditioner containing yeast rich in selenium scalds the sensory evaluation table of C to dye
| One week | Fortnight | Three weeks | Four weeks | Five weeks | |
| Outward appearance | Gloss | Slightly gloss | Slightly gloss | Slightly gloss | Matt |
| Feel | Smooth | Generally smooth | Generally smooth | Generally smooth | Not smooth |
| Anti-entangling | Do not tie a knot | The knotting of indivedual places | Tie a knot in many places | Knotting | Knotting |
| Cardability | Be easy to combing | Be easy to combing | Hair need be pullled | Hair need be pullled | Hair need be pullled |
| Antistatic behaviour | 15 degree | 18 degree | 24 degree | 32 degree | 40 degree |
| Selenium content | 712μg | 716μg | 718μg | 719μg | 720μg |
Appearance ratings: tarnish, slightly gloss, gloss; Feel: not smooth, generally smooth, smooth; Anti-entangling: knotting, indivedual place are tied a knot, do not tied a knot; Cardability: combing need be pullled hair, is easy to combing, very easily combing; Antistatic behaviour: under specific temperature humidity condition, be fixed on by topknot in face of disk measuring instrument, utilizes light source to make topknot produce shade, and allow electric charge on Hair girding in specific combing mode, before and after measuring combing, topknot produces the shade angle dispersed, unit: spend.
Dye scalds the hair conditioner formula containing trehalose and yeast rich in selenium in D:
| Basic components project | Adding proportion | Addition |
| Cationic surfactant (alkyl quaternary ammonium salts 1631) | 2.5% | 2.5g |
| Cetostearyl alcohol | 5.0% | 5.0g |
| PEG-20 ceteareth | 0.5% | 0.5g |
| White oil | 2.0% | 2.0g |
| Glycerol | 5.0% | 5.0g |
| Silicone oil | 2.0% | 2.0g |
| Citric acid | Adjusted to ph to 4.0 | 2.0g |
| Antiseptic, essence | In right amount | 1.5g |
| Trehalose | 2.0% | 2.0g |
| Yeast rich in selenium | 6.0% | 6.0g |
| Water | Be added into 100% |
Get wisp of hair, test under the prerequisite of nutrition is not provided at root, the bundle of hair sodium lauryl sulfate washed with saline solution 1 minute of 3ml mass fraction 5%, after the moisture that removing is excessive, above-mentioned containing trehalose and yeast rich in selenium hair conditioner sample rubbing 2 minutes with 0.5 gram, then rush 1 minute with flowing water respectively, and with dry napkin, moisture is blotted, combing hair, assesses it and establishes performance and a wet anti-entangling.By this bundle bundle of hair around on 20mm reel, make it dried overnight in atmosphere, irradiate through 6 hours of daylight by continuous every day, 2 hours blowing hot winds and permanent hair styling in 30 minutes, after the test in 5 week, combing curly hair bundle, assesses its carding property, a dry anti-entangling, and hair gloss degree etc.
Containing trehalose and yeast rich in selenium hair conditioner to dye scald D sensory evaluation table
| One week | Fortnight | Three weeks | Four weeks | Five weeks | |
| Outward appearance | Gloss | Gloss | Gloss | Gloss | Gloss |
| Feel | Generally smooth | Generally smooth | Generally smooth | Generally smooth | Generally smooth |
| Anti-entangling | Do not tie a knot | Do not tie a knot | Do not tie a knot | Do not tie a knot | Do not tie a knot |
| Cardability | Be easy to combing | Be easy to combing | Be easy to combing | Be easy to combing | Be easy to combing |
| Antistatic behaviour | 15 degree | 15 degree | 15 degree | 15 degree | 15 degree |
| Selenium content | 712μg | 716μg | 718μg | 719μg | 720μg |
Appearance ratings: tarnish, slightly gloss, gloss; Feel: not smooth, generally smooth, smooth; Anti-entangling: knotting, indivedual local knotting, the local knotting of major part, not tie a knot; Cardability: combing need be pullled hair, is easy to combing, very easily combing; Antistatic behaviour: under specific temperature humidity condition, be fixed on by topknot in face of disk measuring instrument, utilizes light source to make topknot produce shade, and allow electric charge on Hair girding in specific combing mode, before and after measuring combing, topknot produces the shade angle dispersed, unit: spend.
Claims (1)
1. trehalose and the organic selenium composition application in hair conditioner, consisting of of described trehalose and organic selenium composition: by ratio of quality and the number of copies, trehalose: yeast rich in selenium=1:(2.5 ~ 3.5).
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| WO2006135601A1 (en) * | 2005-06-09 | 2006-12-21 | John Peldyak | Composition for the mineralization of dental hard tissues and the reduction of caries-inducive microflora |
| CN101829160A (en) * | 2010-05-06 | 2010-09-15 | 广东省食品工业研究所 | Functional composition with functions of controlling blood sugar and enhancing nutrition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2006135601A1 (en) * | 2005-06-09 | 2006-12-21 | John Peldyak | Composition for the mineralization of dental hard tissues and the reduction of caries-inducive microflora |
| CN101829160A (en) * | 2010-05-06 | 2010-09-15 | 广东省食品工业研究所 | Functional composition with functions of controlling blood sugar and enhancing nutrition |
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