CN108283583A - A kind of no silicoamino-acid shampoo and preparation method thereof - Google Patents

A kind of no silicoamino-acid shampoo and preparation method thereof Download PDF

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Publication number
CN108283583A
CN108283583A CN201810261589.9A CN201810261589A CN108283583A CN 108283583 A CN108283583 A CN 108283583A CN 201810261589 A CN201810261589 A CN 201810261589A CN 108283583 A CN108283583 A CN 108283583A
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CN
China
Prior art keywords
sodium
silicoamino
acid shampoo
acid
alaninate
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CN201810261589.9A
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Inventor
余超雄
范新雨
严润南
李彩娴
郭芷影
范明
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Guangzhou Heli Biotechnology Co Ltd
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Guangzhou Heli Biotechnology Co Ltd
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Priority to CN201810261589.9A priority Critical patent/CN108283583A/en
Publication of CN108283583A publication Critical patent/CN108283583A/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/34—Free of silicones
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Abstract

The present invention provides a kind of no silicoamino-acid shampoo, and the no silicoamino-acid shampoo does not contain silicon-containing material；By weight percentage, the no silicoamino-acid shampoo includes mainly following components：Sodium fettyamidog-lutamate 5 30%, fatty acyl group Sodium L-alaninate 10 20%, amphoteric surfactant 5 20%, cosurfactant 1 10%, conditioner 0.5 5%, auxiliary agent 0.5 10%, water 30 60%.This is good from thickening properties without silicoamino-acid shampoo, without additional addition thickener, can reduce the cost of production；Foaming power is strong, foam stabilizing ability is good, has abundant foam；To no skin irritation, and without containing silicon-containing material, sulfate He dioxane, harm will not be generated to health.It is easy to operate the present invention also provides the preparation method step of above-mentioned no silicoamino-acid shampoo is simple, industrial production demand can be met.

Description

A kind of no silicoamino-acid shampoo and preparation method thereof
Technical field
The invention belongs to cosmetic field, a kind of no silicoamino-acid shampoo and preparation method thereof is related generally to.
Background technology
With the improvement of living standards with science and technology fast development, requirement of the people to shampoo used in everyday It is higher and higher.
Currently, most common surfactant has laureth sulfuric acid (AES), lauryl sulfate ester in shampoo Salt (K12) etc., these surfactants all contain sulfate, and opposite irritation is bigger, pollution of the building-up process to environment Greatly.
Amino acid surfactant is the mild surfactant of a protein species, has low irritant, hypotoxicity, soft With property, good biodegradability properties and to preferable compatibility of human body etc., every demand of consumer is met, people is increasingly caused Attention.But when amino acid type surfactant is applied in cleaning class product, often there is thickening difficulty even can not The problem of thickening is so as to cause being difficult to apply.Therefore, amino acid type surfactant hair product, skin care item and fertilizer at home Utility ratio is not also very high in soap bath product.
All big enterprises' majority is solved the above problems by adding various high molecular polymer type thickeners, but does so meeting Cause new problem to generate, such as easily leads to high temperature and metachromatism occur；The foam characteristic of amino acid type surfactant is suppressed, Skin experiences influence when cleaning and the price of macromolecule raw material is high so that the production cost increases.
Therefore, there is an urgent need for developing a kind of mild property, foaming abundancy, easily thickening, consistency is moderate and the good no silicone oil of stability Amino acid shampoo.
Invention content
The technical problem to be solved by the present invention is to deficiencies existing for the above-mentioned prior art, provide a kind of no silicone oil Amino acid shampoo and preparation method thereof；This is good from thickening properties without silicone oil amino acid shampoo, and thickener is added without additional, Foaming properties are good, mild non-stimulated.
To achieve the goals above, the present invention uses technical solution below：
A kind of no silicoamino-acid shampoo, the no silicoamino-acid shampoo do not contain silicon-containing material；With weight percent Meter, the no silicoamino-acid shampoo include mainly following components：Sodium fettyamidog-lutamate 5-30%, fatty acyl group alanine Sodium 10-20%, amphoteric surfactant 5-20%, cosurfactant 1-10%, conditioner 0.5-5%, auxiliary agent 0.5- 10% and water 30-60%.
Preferably, no silicoamino-acid shampoo of the invention, by weight percentage, the no silicoamino-acid shampoo master It to include following components：Sodium fettyamidog-lutamate 10-20%, fatty acyl group Sodium L-alaninate 15-20%, amphoteric surfactant 5-15%, cosurfactant 3-8%, conditioner 1-3%, auxiliary agent 1-6% and water 35-55%.
Preferably, the mass ratio of the sodium fettyamidog-lutamate and fatty acyl group Sodium L-alaninate is 1: 1-3.
Preferably, the sodium fettyamidog-lutamate is sodium cocoyl glutamate.
Preferably, the fatty acyl group Sodium L-alaninate is cocoyl Sodium L-alaninate.
Preferably, the amphoteric surfactant is selected from Sodium Lauroamphoacetate, cocoyl both sexes sodium acetate, coconut palm Oleamide propyl betaine, Coco-Hydroxysultaine, cocamidopropyl propyl amide hydroxyl sulfo betaine, cocoyl ethoxy The mixing of one or more of imidazoline.
Particularly preferred, the amphoteric surfactant is cocoyl both sexes sodium acetate and Cocoamidopropyl betaine Mixture.
Preferably, the cosurfactant is selected from lauroyl N-methyltaurine sodium, Natrulon H-10 oleate, the moon The mixing of one or more of osmanthus acylsarcosine sodium.
Particularly preferred, the cosurfactant is in lauroyl N-methyltaurine sodium and sodium lauroyl sarcosine Mixture.
Preferably, the conditioner be selected from guar hydroxypropyltrimonium chloride, Merquat 280, polyquaternium -7, Polyquaternium-10, sub- oleamide propyl pg dimonium chloride phosphate, isostearoyl dilactic acid sodium, C12-13 alcohol lactic acid Ester, phytosterol/octyl dodecanol lauroyl glutamate ester, glycerol monolaurate, one kind in glycol laurate or two Kind or more mixing.
Particularly preferred, the conditioner is guar hydroxypropyltrimonium chloride, Merquat 280 and polyquaternary amine The mixture of salt -10.
Preferably, the auxiliary agent is one or more of moisturizer, pH adjusting agent, chelating agent, essence, preservative Mixture.
Particularly preferred, the pH adjusting agent is citric acid-sodium citrate buffer solution.
Particularly preferred, the preservative is the mixture of Phenoxyethanol and decoyl hydroximic acid.
The present invention also provides a kind of preparation methods of above-mentioned no silicoamino-acid shampoo, include the following steps：
S1：Take sodium fettyamidog-lutamate, fatty acyl group Sodium L-alaninate, amphoteric surfactant, cosurfactant, Conditioner and water, are mixed, and it is 75 DEG C -85 DEG C to be heated to temperature, and stirring to raw material is completely dissolved；
S2：System is cooled to 40 DEG C, and auxiliary agent is added, stirs evenly, and adjusts pH to 5.5-6.0；
S3：It is stirred under conditions of vacuum, is cooled to 37 DEG C of dischargings.
Beneficial effects of the present invention：
1, no silicoamino-acid shampoo provided by the present invention, passes through sodium fettyamidog-lutamate and amphoteric surfactant Compounding, it is good from thickening properties to realize shampoo, without additional addition thickener；Both amino acid type surfactant had been solved not The defect easily thickened, and without additional addition thickener, reduce the cost of production；
2, no silicoamino-acid shampoo provided by the present invention, passes through fatty acyl group Sodium L-alaninate and amphoteric surfactant Compounding, makes that the shampoo foaming power is strong, foam stabilizing ability is good, has abundant foam；
3, no silicoamino-acid shampoo provided by the present invention is transparent, using mild amino acid pattern surface-active Agent, to no skin irritation, and the shampoo of the present invention does not contain sulfate He dioxane, will not generate danger to health Evil；Not silicon-containing material, it is environmentally friendly, environmentally friendly；
4, preparation method provided by the present invention, step is simple, easy to operate, can meet industrial production demand；It is prepared What is gone out is good from thickening properties without silicoamino-acid shampoo, and without additional addition thickener, foaming properties are good, mild non-stimulated.
Specific implementation mode
Technical scheme of the present invention is described further with reference to embodiment and comparative example and effete test embodiment：
Various reagents used in following embodiment are commercial goods, are that can buy to obtain by commercial sources.
Embodiment 1-3
According to the preparation embodiment of table 1 1-3 without silicoamino-acid shampoo A-C.
Table 1 is without silicoamino-acid shampoo A-C
Component Embodiment 1 Embodiment 2 Embodiment 3
Weight percent % Weight percent % Weight percent %
Water 57.35 40.35 43.35
Cocounut oil acyl disodium glutamate 5 15 20
Cocoamido sodium propionate 15 25 20
Cocoamidopropyl betaine 8 6 4
Cocoyl both sexes sodium acetate 5 4 3
Sodium lauroyl sarcosine 3 3 3
Lauroyl N-methyltaurine sodium 4 4 4
Merquat 280 0.3 0.3 0.3
Guar hydroxypropyltrimonium chloride 0.2 0.2 0.2
Polyquaternium-10 0.15 0.15 0.15
Essence 0.2 0.2 0.2
Phenoxyethanol 0.5 0.5 0.5
Decoyl hydroximic acid 0.3 0.3 0.3
Citric acid 0.8 0.8 0.8
Sodium citrate 0.2 0.2 0.2
The preparation method of above-mentioned no silicoamino-acid shampoo A-C includes the following steps：
S1：Take cocounut oil acyl disodium glutamate, cocoamido sodium propionate, coconut oleoyl amine third class glycine betaine, cocoyl two Property sodium acetate, sodium lauroyl sarcosine, lauroyl N-methyltaurine sodium, lauroyl N-methyltaurine sodium, polyquaternium- 22, guar hydroxypropyltrimonium chloride, Polyquaternium-10 and water, are mixed, and it is 75 DEG C -85 DEG C to be heated to temperature, is stirred It mixes to raw material and is completely dissolved；
S2：System is cooled to 40 DEG C, and essence, Phenoxyethanol, decoyl hydroximic acid, citric acid-sodium citrate buffer solution is added, It stirs evenly, adjusts pH to 5.0-7.0；
S3：It is stirred under conditions of vacuum, is cooled to 37 DEG C of dischargings.
Comparative example 1-3
According to the preparation comparative example of table 2 1-3 without silicoamino-acid shampoo D-F.
Table 2 is without silicoamino-acid shampoo D-F
Component Comparative example 1 Comparative example 2 Comparative example 3
Weight percent % Weight percent % Weight percent %
Water 55.35 55.35 38.35
Cocounut oil acyl disodium glutamate 25 / 25
Cocoamido sodium propionate / 25 25
Cocoamidopropyl betaine 5 5 1
Cocoyl both sexes sodium acetate 5 5 1
Sodium lauroyl sarcosine 3 3 3
Lauroyl N-methyltaurine sodium 4 4 4
Merquat 280 0.3 0.3 0.3
Guar hydroxypropyltrimonium chloride 0.2 0.2 0.2
Polyquaternium-10 0.15 0.15 0.15
Essence 0.2 0.2 0.2
Phenoxyethanol 0.5 0.5 0.5
Decoyl hydroximic acid 0.3 0.3 0.3
Citric acid 0.8 0.8 0.8
Sodium citrate 0.2 0.2 0.2
The preparation method of above-mentioned no silicoamino-acid shampoo D-F includes the following steps：
S1：Take cocounut oil acyl disodium glutamate, cocoamido sodium propionate, coconut oleoyl amine third class glycine betaine, cocoyl two Property sodium acetate, sodium lauroyl sarcosine, lauroyl N-methyltaurine sodium, lauroyl N-methyltaurine sodium, polyquaternium- 22, guar hydroxypropyltrimonium chloride, Polyquaternium-10 and water, are mixed, and it is 75 DEG C -85 DEG C to be heated to temperature, is stirred It mixes to raw material and is completely dissolved；
S2：System is cooled to 40 DEG C, and essence, Phenoxyethanol, decoyl hydroximic acid, citric acid-sodium citrate buffer solution is added, It stirs evenly, adjusts pH to 5.5-6.0；
S3：It is stirred under conditions of vacuum, is cooled to 37 DEG C of dischargings.
Comparative example 4-7
Buy commercial shampoos 4-7 as a comparison case
Effete test embodiment 1
Highest viscosity test
According to the rotary process in standard GB/T/T 10247-2008 Viscosity Measurement Methods, fly DV-S type numbers using rich strangle Aobvious viscosimeter test sample (prepared by embodiment 1-3 without prepared by silicoamino-acid shampoo A-C and comparative example 1-3 without silicon Amino acid shampoo D-F) viscosity, 25 DEG C of constant temperature, retest is averaged for 3 times, the results are shown in Table 3.
3 highest viscosity test results of table
Sample Highest viscosity (Pas)
Embodiment 1 3310#
Embodiment 2 4570##
Embodiment 3 4780##
Comparative example 1 1450
Comparative example 2 2380
Comparative example 3 1620
Note：#Show that comparative example 1-3 is compared, there is significant difference (P ＜ 0.05)；##Show compared with any one of comparative example 1-3, With pole significant difference (P ＜ 0.01).
As can be seen from Table 3, the ratio of viscosities comparative example without silicoamino-acid shampoo A-C prepared by embodiment 1-3 It is much higher without silicoamino-acid shampoo D-F prepared by 1-3, there is significant difference.It is possible thereby to illustrate, the present invention passes through The ingenious collocation of activating agent and the rational ratio of each component so that having without silicoamino-acid shampoo for being provided preferably thickens certainly Ability.
Effete test embodiment 2
Foaming power is tested
According to standard GB/T/T13173.6-2000 detergent foaming power assay methods, is measured and implemented with Roche foam meter The foaming power of the shampoo of example 1-3 and comparative example 1-7, test result are shown in Table 4.
4 foaming power test result of table
Note：#Show that comparative example 1-7 is compared, there is significant difference (P ＜ 0.05)；##Show and any one of comparative example 1-7 phase Than having pole significant difference (P ＜ 0.01).
The foaming power and foam stabilizing ability without silicoamino-acid shampoo A-C of embodiment 1-3 it can be seen from the data of table 4 Shampoo compared with comparative example 1-7 is all good, and has significant difference.Illustrate no silicoamino-acid shampoo tool provided by the present invention There are good foaming properties.
Effete test embodiment 3
Irritation is tested
According to People's Republic of China's inspection and quarantining for import/export professional standard SN/T 2329-2009 cosmetics eye irritation/ The eye irritation of the shampoo of corrosive chick chorioallantoic membrane experiment, testing example 1-3 and comparative example 4-7.Using anti- The experiment for answering Time Method to carry out calculates stimulation scoring (IS), as a result retains 2 significant digits.
IS=(301-secH) × 5300+ (301-secL) × 7300+ (301-secC) × 9300
In formula：
SecH (bleeding time) --- observe that the average time that bleeding takes place, unit are the second (s) on CAM films；
SecL (blood vessel melts the time) --- it is observed on CAM films and the average time that blood vessel melts takes place, unit is Second (s)；
SecC (clotting time) --- observe that the average time for starting blood coagulation occur, unit are the second (s) on CAM films.
Classified to tested material eye irritation by table 5 according to the IS numerical value of calculating.Test result is shown in Table 6.
Table 5 stimulates appraisal result to evaluate
Stimulation scoring Irritation is classified
IS ＜ 1 It is nonirritant
1≤IS ＜ 5 Subexcite
5≤IS ＜ 9 Moderate irritation
IS≥10 Strong and stimulating/corrosivity
6 irritation test result of table
Note：#Show that comparative example 4-7 is compared, there is significant difference (P ＜ 0.05)；##Show and any one of comparative example 4-7 phase Than having pole significant difference (P ＜ 0.01).
Embodiment 1-3's is non-stimulated to eye without silicoamino-acid shampoo A-C it can be seen from 6 data of table, and commercially available production The shampoo of product comparative example 4-7 has eye slight irritation, and has pole significant difference.Illustrate provided by the present invention Have the advantages that without silicoamino-acid shampoo it is mild non-stimulated.
The above described is only a preferred embodiment of the present invention, limitation in any form not is done to the present invention, therefore All contents without departing from technical solution of the present invention, it is made to the above embodiment according to the technical essence of the invention any simply to repair Change, equivalent variations and modification, in the range of still falling within technical solution of the present invention.

Claims (10)

1. a kind of no silicoamino-acid shampoo, which is characterized in that do not contain silicon-containing material；By weight percentage, the no silicon Amino acid shampoo includes mainly following components：Sodium fettyamidog-lutamate 5-30%, fatty acyl group Sodium L-alaninate 10-20%, Amphoteric surfactant 5-20%, cosurfactant 1-10%, conditioner 0.5-5%, auxiliary agent 0.5-10% and water 30- 60%.
2. no silicoamino-acid shampoo according to claim 1, which is characterized in that by weight percentage, the no silicon Amino acid shampoo includes mainly following components：Sodium fettyamidog-lutamate 10-20%, fatty acyl group Sodium L-alaninate 15-20%, Amphoteric surfactant 5-15%, cosurfactant 3-8%, conditioner 1-3%, auxiliary agent 1-6% and water 35-55%.
3. no silicoamino-acid shampoo according to claim 1 or 2, it is characterised in that：The sodium fettyamidog-lutamate Mass ratio with fatty acyl group Sodium L-alaninate is 1: 1-3.
4. no silicoamino-acid shampoo according to claim 1 or 2, it is characterised in that：The sodium fettyamidog-lutamate For sodium cocoyl glutamate.
5. no silicoamino-acid shampoo according to claim 1 or 2, it is characterised in that：The fatty acyl group Sodium L-alaninate For cocoyl Sodium L-alaninate.
6. no silicoamino-acid shampoo according to claim 1 or 2, it is characterised in that：The amphoteric surfactant choosing From Sodium Lauroamphoacetate, cocoyl both sexes sodium acetate, Cocoamidopropyl betaine, cocoyl weight ratio beet The mixing of one or more of alkali, cocamidopropyl propyl amide hydroxyl sulfo betaine, cocoyl hydroxyethyl imidazole quinoline.
7. no silicoamino-acid shampoo according to claim 1 or 2, it is characterised in that：The cosurfactant choosing From the mixed of one or more of lauroyl N-methyltaurine sodium, Natrulon H-10 oleate, sodium lauroyl sarcosine It closes.
8. no silicoamino-acid shampoo according to claim 1 or 2, it is characterised in that：The conditioner is selected from melon glue Hydroxypropyl-trimethyl ammonium chloride, Merquat 280, polyquaternium -7, Polyquaternium-10, sub- oleamide propyl PG- dimethyl chlorides Change ammonium phosphate, isostearoyl dilactic acid sodium, C12-13 alcohol lactate, phytosterol/octyl dodecanol lauroyl glutamate The mixing of one or more of ester, glycerol monolaurate, glycol laurate.
9. no silicoamino-acid shampoo according to claim 1 or 2, it is characterised in that：The auxiliary agent is moisturizer, pH tune Save the mixture of one or more of agent, chelating agent, essence, preservative.
10. the preparation method as claimed in claim 1 or 2 without silicoamino-acid shampoo, which is characterized in that including following step Suddenly：
S1：Take sodium fettyamidog-lutamate, fatty acyl group Sodium L-alaninate, amphoteric surfactant, cosurfactant, conditioning Agent and water, are mixed, and it is 75 DEG C -85 DEG C to be heated to temperature, and stirring to raw material is completely dissolved；
S2：System is cooled to 40 DEG C, and auxiliary agent is added, stirs evenly, and adjusts pH to 5.0-7.0；
S3：It is stirred under conditions of vacuum, is cooled to 37 DEG C of dischargings.
CN201810261589.9A 2018-03-27 2018-03-27 A kind of no silicoamino-acid shampoo and preparation method thereof Pending CN108283583A (en)

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CN110327257A (en) * 2019-08-22 2019-10-15 南京华狮新材料有限公司 A kind of transparent amino acid shampoo with treatment
CN110721108A (en) * 2019-09-26 2020-01-24 广州妮趣化妆品有限公司 Thickening composition of cocoyl alanine salt and application thereof
CN110897988A (en) * 2019-12-17 2020-03-24 湖北省麦诗特生物科技有限公司 Hair-strengthening and hair-nourishing amino acid shampoo containing sturgeon roe extract liposome and preparation method thereof
CN110981759A (en) * 2019-12-10 2020-04-10 上海嘉亨日用化学品有限公司 Preparation method of N-acyl-N-methyltaurate and application of N-acyl-N-methyltaurate in silicone oil-free shampoo
WO2020104129A1 (en) * 2018-11-22 2020-05-28 Beiersdorf Ag A cosmetic cleansing composition
CN112472618A (en) * 2019-09-12 2021-03-12 南京华狮新材料有限公司 Amino acid hair cleaning composition
CN113425615A (en) * 2021-08-16 2021-09-24 中山市匠研日用化工有限公司 Deep-care smooth shampoo without silicone oil and sulfate and preparation method thereof
WO2023060178A1 (en) * 2021-10-07 2023-04-13 The Procter & Gamble Company Sulfate free personal cleansing composition comprising low inorganic salt content and hydroxamic acid or hydroxamic acid derivatives
WO2023060177A1 (en) * 2021-10-07 2023-04-13 The Procter & Gamble Company Sulfate free personal cleansing composition comprising low inorganic salt content and hydroxamic acid or hydroxamic acid derivatives
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US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
US11819474B2 (en) 2020-12-04 2023-11-21 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials
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US11904036B2 (en) 2017-10-10 2024-02-20 The Procter & Gamble Company Sulfate free clear personal cleansing composition comprising low inorganic salt
CN108685734A (en) * 2018-08-09 2018-10-23 广州荣创优品科技有限公司 A kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon
WO2020104129A1 (en) * 2018-11-22 2020-05-28 Beiersdorf Ag A cosmetic cleansing composition
CN109288725A (en) * 2018-12-04 2019-02-01 南京华狮新材料有限公司 A kind of transparent amino acid pattern is without silicone oil shampoo
CN110090176A (en) * 2019-05-07 2019-08-06 湖北中医药大学 A kind of preparation method of the soap kind for shampoo
CN110279634A (en) * 2019-08-07 2019-09-27 广州优敏泉生物科技有限公司 A kind of no silicone oil amino acid shampoo and preparation method thereof
CN110327257A (en) * 2019-08-22 2019-10-15 南京华狮新材料有限公司 A kind of transparent amino acid shampoo with treatment
CN110327257B (en) * 2019-08-22 2022-04-29 南京华狮新材料有限公司 Transparent amino acid conditioning shampoo
CN112472618A (en) * 2019-09-12 2021-03-12 南京华狮新材料有限公司 Amino acid hair cleaning composition
CN110721108A (en) * 2019-09-26 2020-01-24 广州妮趣化妆品有限公司 Thickening composition of cocoyl alanine salt and application thereof
CN110981759A (en) * 2019-12-10 2020-04-10 上海嘉亨日用化学品有限公司 Preparation method of N-acyl-N-methyltaurate and application of N-acyl-N-methyltaurate in silicone oil-free shampoo
CN110981759B (en) * 2019-12-10 2022-06-21 上海嘉亨日用化学品有限公司 Preparation method of N-acyl-N-methyltaurate and application of N-acyl-N-methyltaurate in silicone oil-free shampoo
CN110897988A (en) * 2019-12-17 2020-03-24 湖北省麦诗特生物科技有限公司 Hair-strengthening and hair-nourishing amino acid shampoo containing sturgeon roe extract liposome and preparation method thereof
CN110897988B (en) * 2019-12-17 2022-05-03 湖北省麦诗特生物科技有限公司 Hair-strengthening and hair-nourishing amino acid shampoo containing sturgeon roe extract liposome and preparation method thereof
US11679065B2 (en) 2020-02-27 2023-06-20 The Procter & Gamble Company Compositions with sulfur having enhanced efficacy and aesthetics
US11819474B2 (en) 2020-12-04 2023-11-21 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials
US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
CN113425615A (en) * 2021-08-16 2021-09-24 中山市匠研日用化工有限公司 Deep-care smooth shampoo without silicone oil and sulfate and preparation method thereof
WO2023060177A1 (en) * 2021-10-07 2023-04-13 The Procter & Gamble Company Sulfate free personal cleansing composition comprising low inorganic salt content and hydroxamic acid or hydroxamic acid derivatives
WO2023060178A1 (en) * 2021-10-07 2023-04-13 The Procter & Gamble Company Sulfate free personal cleansing composition comprising low inorganic salt content and hydroxamic acid or hydroxamic acid derivatives

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Application publication date: 20180717