CN106750361B - A kind of lignin sulfonate modified object and its application and the shampoo comprising the modifier - Google Patents
A kind of lignin sulfonate modified object and its application and the shampoo comprising the modifier Download PDFInfo
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- CN106750361B CN106750361B CN201611052511.3A CN201611052511A CN106750361B CN 106750361 B CN106750361 B CN 106750361B CN 201611052511 A CN201611052511 A CN 201611052511A CN 106750361 B CN106750361 B CN 106750361B
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- China
- Prior art keywords
- lignin sulfonate
- modified object
- sulfonate modified
- lignosulfonates
- shampoo
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- 229920001732 Lignosulfonate Polymers 0.000 title claims abstract description 69
- 239000002453 shampoo Substances 0.000 title claims abstract description 42
- 239000003607 modifier Substances 0.000 title description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 27
- 239000000284 extract Substances 0.000 claims description 21
- 241000196324 Embryophyta Species 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 17
- 238000000605 extraction Methods 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 10
- 229930182490 saponin Natural products 0.000 claims description 10
- 150000007949 saponins Chemical class 0.000 claims description 10
- 239000003755 preservative agent Substances 0.000 claims description 9
- 230000002335 preservative effect Effects 0.000 claims description 9
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims description 8
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 7
- 235000019270 ammonium chloride Nutrition 0.000 claims description 6
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000012043 crude product Substances 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 5
- 239000013049 sediment Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 3
- 241000195493 Cryptophyta Species 0.000 claims description 3
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims description 3
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims description 3
- 229960002216 methylparaben Drugs 0.000 claims description 3
- 210000000582 semen Anatomy 0.000 claims description 3
- 238000003811 acetone extraction Methods 0.000 claims description 2
- 239000012298 atmosphere Substances 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 2
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000000376 reactant Substances 0.000 claims description 2
- JAJWGJBVLPIOOH-IZYKLYLVSA-M sodium taurocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCCS([O-])(=O)=O)C)[C@@]2(C)[C@@H](O)C1 JAJWGJBVLPIOOH-IZYKLYLVSA-M 0.000 claims description 2
- LZBIYPIDWSGLOV-UHFFFAOYSA-N dimethyl(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC=C LZBIYPIDWSGLOV-UHFFFAOYSA-N 0.000 claims 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims 1
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 claims 1
- 240000000249 Morus alba Species 0.000 claims 1
- 235000008708 Morus alba Nutrition 0.000 claims 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 229940101267 panthenol Drugs 0.000 claims 1
- 235000020957 pantothenol Nutrition 0.000 claims 1
- 239000011619 pantothenol Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 19
- 210000004209 hair Anatomy 0.000 abstract description 14
- 238000002360 preparation method Methods 0.000 abstract description 9
- 208000001840 Dandruff Diseases 0.000 abstract description 6
- 239000003963 antioxidant agent Substances 0.000 abstract description 4
- 230000003078 antioxidant effect Effects 0.000 abstract description 4
- 235000006708 antioxidants Nutrition 0.000 abstract description 4
- 206010020751 Hypersensitivity Diseases 0.000 abstract description 2
- 208000030961 allergic reaction Diseases 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 230000009920 chelation Effects 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 13
- 244000303965 Cyamopsis psoralioides Species 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 125000002252 acyl group Chemical group 0.000 description 7
- 229920005550 ammonium lignosulfonate Polymers 0.000 description 7
- -1 aryl compound Chemical class 0.000 description 6
- 239000000686 essence Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 229920005610 lignin Polymers 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 210000004761 scalp Anatomy 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- 229910002567 K2S2O8 Inorganic materials 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 208000003251 Pruritus Diseases 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 230000003656 anti-hair-loss Effects 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 201000004384 Alopecia Diseases 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000000474 nursing effect Effects 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 244000186561 Swietenia macrophylla Species 0.000 description 1
- 230000009102 absorption Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 231100000360 alopecia Toxicity 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 229940126678 chinese medicines Drugs 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 210000003780 hair follicle Anatomy 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 208000024963 hair loss Diseases 0.000 description 1
- 210000004919 hair shaft Anatomy 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Botany (AREA)
- Polymers & Plastics (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Biotechnology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of lignin sulfonate modified object, molecular weight 10000-40000, molecular weight distribution is 1.5~6.0, and minimum reachable 28 mN/m of surface tension are made by lignosulfonates and dodecylallyldimethylammonium chloride.Shampoo the invention also discloses the application of the lignin sulfonate modified object and containing the lignin sulfonate modified object.The present invention has surface-active, scattered adsorption, chelation and anti-oxidant and antibacterial characteristic using lignosulfonates, and lignosulfonates are added in shampoo formula, can play the effect of deoiling, is anti-dandruff, taking care of hair.The shampoo using effect that product of the present invention preparation process is easy to operate, obtains is obvious, and mild non-stimulated, hair and fur suitable for various characteristics have no toxic side effect without allergic reaction after use, and quick, and generating and nourishing hair effect is good.
Description
Technical field
The present invention relates to a kind of lignin sulfonate modified objects, while being related to the application of the lignin sulfonate modified object.
The invention further relates to the shampoos comprising the lignin sulfonate modified object.
Background technique
The development course for making a general survey of shampoo is developed to today, people to shield unification, shampoo is washed by the cleaning function of early stage
Focus more on product itself it is natural, safe and non-toxic, be provided simultaneously with nourishing and nursing conditioning hair the effect of.No silicone oil is mildly washed
Shampoo comes into being in this context.As 105534822 A of CN discloses a kind of no silicon and has effects that washing for hair care
Shampoo mainly includes the ingredients such as laureth sodium sulfovinate, empgen BB, Tea Saponin and Chinese medicine extract, institute
The primary surfactant of selection is more mild, and formula not silicate-containing oil, obtained product detergency is moderate, do, wet cardability it is good.Extensively
104921989 A of Zhou Huanya company CN reports a kind of not silicate-containing oil and has effects that the shampoo of scalp care, mainly by
Mild surfactant and scalp care agent composition, formula is mild non-stimulated, has nursing scalp and reduces the function of hair loss
Effect.
In conclusion these leading mild non-stimulated, not silicate-containing oil shampoos are substantially concentrated on using mild table
Face activating agent, the ingredient in conjunction with some Chinese medicines or plant extraction liquid as conditioning scalp, still, natural mild surfactant
Development and application is only the following core that the development of shield technology is washed without silicone oil.
Lignin is the non-oil resource that nature is uniquely capable of providing renewable aryl compound, is second largest naturally to have
Machine object.Lignosulfonates are the lignin of sulfonated processing, belong to high molecular surfactant, have biodegradability,
Nantural non-toxic, product price are cheap.There is certain surface-active, absorption dispersibility, chelating properties and anti-oxidant spy simultaneously
Property, it can be used as natural sun-proof component, greatly improve the sun-proof ability of product；In addition, also there is certain collaboration decontamination and kill
Bacterium effect.
Summary of the invention
Primary and foremost purpose of the invention is to provide a kind of lignin sulfonate modified object, and the lignin sulfonate modified object is by wood
Mahogany sulfonate reacts to obtain with dodecylallyldimethylammonium chloride.Lignosulfonates are added in shampoo,
Have effects that deoil, is anti-dandruff, hair care.
To achieve the above object, the invention is realized by the following technical scheme: a kind of lignin sulfonate modified object, point
Son amount is 10000 ~ 40000, and molecular weight distribution is 1.5 ~ 6.0, minimum reachable 28 mN/m of surface tension, by lignosulfonates
It is made with dodecylallyldimethylammonium chloride.
Specifically, the lignin sulfonate modified object is made by following methods, comprising the following steps:
(1) lignosulfonates are added in reactor and water, lignosulfonates is dissolved in deionized water, solution concentration
For 0.04 ~ 0.2 g/mL, initiator is added, under inert gas atmosphere, stirring is uniformly mixed the two；
(2) when the temperature in reactor rises to 70 ~ 80 DEG C, start that dodecylallyldimethylammonium chloride is added dropwise
Solution, control time for adding are 1 ~ 2 h, and the reaction was continued 4 h after being added dropwise obtain copolymer crude product；
(3) a period of time is stood after isopropanol is added, isolates precipitating, 8 ~ 10 h of acetone extraction is carried out to sediment, is removed
After removing homopolymer, it is placed in 50 DEG C of baking ovens dry constant weight, obtains lignin sulfonate modified object.
Step (1) the lignosulfonate solutions concentration is preferably 0.8 ~ 0.12 g/mL；The amount of the initiator is anti-
The 2 ~ 4% of object gross mass are answered, reactant gross mass refers to lignosulfonates and the total matter of dodecylallyldimethylammonium chloride
Amount.The initiator is K2S2O8。
The mass ratio of dodecylallyldimethylammonium chloride described in step (2) and lignosulfonates is 1:1.25
~5；It is preferably in a proportion of 1:2.
The lignosulfonates include but is not limited to ammonium lignosulphonate, calcium lignosulfonate, magnesium lignosulfonate or
One of sodium lignin sulfonate.
Another object of the present invention is to provide the application of above-mentioned lignin sulfonate modified object, specifically the lignin
Application of the sulfonate modified object in shampoo.
Another object of the present invention is to provide the shampoo containing above-mentioned lignin sulfonate modified object.
A kind of related shampoo containing lignosulfonates can be achieved through the following technical solutions: one kind containing lignin
The shampoo of sulfonate includes following components in parts by weight:
10 ~ 25 parts of osmanthus acyl sodium glutamate, 5 ~ 20 parts of sodium lauroyl sarcosine, 1 ~ 15 part of Cocoamidopropyl betaine, first
1 ~ 6 part of base cocoyl sodium taurocholate, 1~8 part of lignin sulfonate modified object, 1 ~ 5 part of Tea Saponin, 2 ~ 8 parts of plant extraction liquid,
1 ~ 5 part of D-pantothenyl aleohol, 2 ~ 4 parts of guar hydroxypropyltrimonium ammonium chloride, citric acid 0.1 ~ 1,0.1 ~ 0.6 part of essence, preservative
0.05 ~ 0.1 part, 80 ~ 120 parts of deionized water.
The plant extraction liquid is marine algae extract, Fructus Mori extract, Semen Sesami Nigrum extract, radix-polygoni multiflori extract and rhizoma zingiberis
Any two kinds in extract.
The essence is one of lemonene and lavender perfume (or spice).
The preservative is one of Kathon CG, methylparaben and propylben.
The preparation method of shampoo of the present invention containing lignosulfonates, the following steps are included:
(1) sodium lauroyl glutamate, sodium lauroyl sarcosine, Cocoamidopropyl betaine, methyl cocoyl are taken in proportion
Acyl taurines sodium and water stir at 50 ~ 70 DEG C until dissolution；
(2) step (1) resulting mixture is cooled to 40 ~ 55 DEG C, sequentially adds Tea Saponin, lignin in proportion
Sulfonate and guar hydroxypropyltrimonium ammonium chloride continue 10 ~ 15 min of stirring;
(3) mixture obtained by the step (2) is maintained at 40 ~ 55 DEG C, plant extraction liquid is added, is sufficiently mixed；
(4) after the step (3) resulting mixture being cooled to 30 ~ 40 DEG C, essence, preservative and citric acid is added,
PH to 5.5 ~ 6.5 is adjusted to get the shampoo containing lignin sulfonate modified object.
Compared with prior art, beneficial effects of the present invention:
1. in the present invention, polymerize with dodecylallyldimethylammonium chloride using lignosulfonates anti-
It answers.Wherein dodecylallyldimethylammonium chloride is both quaternary ammonium salt and vinyl monomer, is introduced into lignosulfonates
Main structure in, the lignin sulfonate modified object of available both sexes, with just in this lignin sulfonate modified object
Electric group, for conditioner can be played the role of in shampoo.
2. lignosulfonates are natural antioxidant, are added in shampoo the use that can reduce preservative,
Make the more natural safety of product.Lignin sulfonate modified object of the invention has the surface-active of lignosulfonates, dispersion
Absorption, chelation and anti-oxidant and antibacterial function, are added in shampoo formula, can play deoil, be anti-dandruff,
The effect of hair care.In addition, lignosulfonates also have certain Synergistic biocidal bacteriostasis efficacy, to reduce the scalp after hair washing
It itches phenomenon.
3. the present invention, as primary surfactant, passes through the reproducible sulfomethylated lignin of addition using mild surfactant
Sulfonate modified object and plant extraction liquid do not add organic silicon conditioner additionally, obtained properties of product are mild, it is non-stimulated,
Without side-effects, hair and fur suitable for various characteristics have no toxic side effect without allergic reaction after use.In addition, the present invention exists
Plant extraction liquid is added in shampoo formula, the effect that can be played activation hair follicle tissue, promote scalp metabolism, hair tonic is supported
It is good to send out effect, efficiently reduces alopecia and the generation of white hair.
4. the preparation process of lignin sulfonate modified object and shampoo of the invention is easy to operate.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail, and embodiments of the present invention are not limited thereto.
Embodiment 1
Shampoo containing magnesium lignosulfonate modifier, the raw material including following mass parts:
10 parts of sodium lauroyl glutamate, 15 parts of sodium lauroyl sarcosine, 5 parts of Cocoamidopropyl betaine, methyl cocoyl
4 parts of acyl taurines sodium, 1 part of magnesium lignosulfonate modifier, 1 part of Tea Saponin, 2 parts of plant extraction liquid, 5 parts of D-pantothenyl aleohol, Guar
3 parts of glue hydroxypropyl-trimethyl ammonium chloride, 0.3 part of citric acid, 0.1 part of lemon extract, 0.05 part of Kathon CG, 80 parts of deionized water.It plants
Object extracting solution is that marine algae extract and Semen Sesami Nigrum extract are mixed to prepare in quality 1:1 ratio.
Wherein, the preparation of magnesium lignosulfonate modifier comprises the steps of:
(1) in reactor, 10 g magnesium lignosulfonates is dissolved in 83 mL deionized waters, 3% initiator is added
K2S2O8, it is passed through protection gas N2, stirring is uniformly mixed the two.
(2) when the temperature in reactor rises to 70 DEG C, start that 2 g dodecyl dimethyl allyl chlorinations are added dropwise
Ammonium, control time for adding are that 1 h obtains copolymer crude product after being added dropwise after the reaction was continued 4 h.
(3) a period of time is stood after isopropanol is added, precipitating is isolated, sediment is put into soxhlet's extractor, with third
Ketone extracts 8 h, after removing homopolymer, is placed in 50 DEG C of baking ovens dry constant weight.
Shampoo preparation method:
(1) sodium lauroyl glutamate, sodium lauroyl sarcosine, Cocoamidopropyl betaine, methyl cocoyl are taken in proportion
Acyl taurines sodium and water stir at 50~70 DEG C until dissolution.
(2) step (1) resulting mixture is cooled to 40~55 DEG C, sequentially adds Tea Saponin, magnesium lignosulfonate changes
Property object and guar hydroxypropyltrimonium ammonium chloride, continue 10~15 min of stirring.
(3) mixture obtained by step (2) is maintained at 40~55 DEG C, plant extraction liquid is added, is sufficiently mixed.
(4) after step (3) resulting mixture being cooled to 30~40 DEG C, essence, preservative, citric acid is added, adjusts
PH to 5.5~6.5 to get the modifier containing magnesium lignosulfonate shampoo.
Embodiment 2
Shampoo containing ammonium lignosulphonate's modifier, the raw material including following mass parts:
15 parts of sodium lauroyl glutamate, 5 parts of sodium lauroyl sarcosine, 10 parts of Cocoamidopropyl betaine, methyl cocoyl
1 part of acyl taurines sodium, 5 parts of ammonium lignosulphonate's modifier, 3 parts of Tea Saponin, 5 parts of plant extraction liquid, 2 parts of D-pantothenyl aleohol, Guar
2 parts of glue hydroxypropyl-trimethyl ammonium chloride, 0.5 part of citric acid, 0.3 part of lavender oil, 0.05 part of methylparaben, deionized water
100 parts.Plant extraction liquid is that Fructus Mori extract is mixed to prepare with radix-polygoni multiflori extract 1:1 in mass ratio.
Wherein, the preparation of ammonium lignosulphonate's modifier comprises the steps of:
(1) in reactor, 10 g ammonium lignosulphonates is dissolved in 100 mL deionized waters, 3% initiator is added
K2S2O8, it is passed through protection gas N2, stirring is uniformly mixed the two.
(2) when the temperature in reactor rises to 75 DEG C, start that 5 g dodecyl dimethyl allyl chlorinations are added dropwise
Ammonium, control time for adding are that 1.5 h obtain copolymer crude product after being added dropwise after the reaction was continued 4 h.
(3) a period of time is stood after isopropanol is added, precipitating is isolated, sediment is put into soxhlet's extractor, with third
Ketone extracts 9 h, after removing homopolymer, is placed in 50 DEG C of baking ovens dry constant weight.
Shampoo preparation method:
(1) sodium lauroyl glutamate, sodium lauroyl sarcosine, Cocoamidopropyl betaine, methyl cocoyl are taken in proportion
Acyl taurines sodium and water stir at 50~70 DEG C until dissolution.
(2) step (1) resulting mixture is cooled to 40~55 DEG C, sequentially adds Tea Saponin, ammonium lignosulphonate changes
Property object and guar hydroxypropyltrimonium ammonium chloride, continue 10~15 min of stirring.
(3) mixture obtained by step (2) is maintained at 40~55 DEG C, plant extraction liquid is added, is sufficiently mixed.
(4) after step (3) resulting mixture being cooled to 30~40 DEG C, essence, preservative, citric acid is added, adjusts
PH to 5.5~6.5 to get the modifier containing ammonium lignosulphonate shampoo.
Embodiment 3
Shampoo containing sodium lignin sulfonate modifier, the raw material including following parts by weight:
25 parts of sodium lauroyl glutamate, 20 parts of sodium lauroyl sarcosine, 15 parts of Cocoamidopropyl betaine, methyl cocoyl
6 parts of acyl taurines sodium, 8 parts of sodium lignin sulfonate modifier, 5 parts of Tea Saponin, 8 parts of plant extraction liquid, 1 part of D-pantothenyl aleohol, Guar
2 parts of glue hydroxypropyl-trimethyl ammonium chloride, 0.6 part of citric acid, 0.5 part of lemon extract, 0.05 part of propylben, deionized water
120 parts.Plant extraction liquid is that Fructus Mori extract and Rhizoma Zingiberis extract 1:1 in mass ratio are mixed to prepare.
Wherein, the preparation of sodium lignin sulfonate modifier comprises the steps of:
(1) in reactor, 10 g sodium lignin sulfonates is dissolved in 125 mL deionized waters, 3% initiator is added
K2S2O8, it is passed through protection gas N2, stirring is uniformly mixed the two.
(2) when the temperature in reactor rises to 80 DEG C, start that 8 g dodecyl dimethyl allyl chlorinations are added dropwise
Ammonium, control time for adding are that 2 h obtain copolymer crude product after being added dropwise after the reaction was continued 4 h.
(3) a period of time is stood after isopropanol is added, precipitating is isolated, sediment is put into soxhlet's extractor, with third
Ketone extracts 10 h, after removing homopolymer, is placed in 50 DEG C of baking ovens dry constant weight.
Shampoo preparation method:
(1) sodium lauroyl glutamate, sodium lauroyl sarcosine, Cocoamidopropyl betaine, methyl cocoyl are taken in proportion
Acyl taurines sodium and water stir at 50~70 DEG C until dissolution.
(2) step (1) resulting mixture is cooled to 40~55 DEG C, sequentially adds Tea Saponin, sodium lignin sulfonate changes
Property object and guar hydroxypropyltrimonium ammonium chloride, continue 10~15 min of stirring.
(3) mixture obtained by step (2) is maintained at 40~55 DEG C, plant extraction liquid is added, is sufficiently mixed.
(4) after step (3) resulting mixture being cooled to 30~40 DEG C, essence, preservative, citric acid is added, adjusts
PH to 5.5~6.5 to get the modifier containing sodium lignin sulfonate shampoo.
The mode for taking volunteer's sensory evaluation is asked four groups of people as subjects, is had one's hair wash using Examples 1 to 3 weekly
Water twice, while as a control group with the shampoo of commercially available silicate-containing oil, to the shampoo of the invention containing lignosulfonates into
The aesthetic evaluation of row.Respectively to after shampoo hair washing anti-dandruff and itching-relieving, dry cardability, wet cardability, feel, Anti-hair loss effect into
Row evaluation, evaluation is using 5 points of systems, and 5 points are best result, and 1 point is minimum point.The evaluation result of Examples 1 to 3 is as shown in table 1.
The different group shampoo Analyses Methods for Sensory Evaluation Results of table 1
| Anti-dandruff and itching-relieving | Dry cardability | Wet cardability | Feel | Anti-hair loss effect | Comprehensive score | |
| Embodiment 1 | 3.3 | 4.0 | 4.3 | 3.5 | 3.5 | 18.6 |
| Embodiment 2 | 4.0 | 4.5 | 4.5 | 4.0 | 3.9 | 20.9 |
| Embodiment 3 | 4.6 | 4.5 | 4.6 | 4.2 | 4.8 | 22.7 |
| Commercially available siliceous shampoo | 3.9 | 3.5 | 4.5 | 3.2 | 3.4 | 18.5 |
As it can be seen from table 1 the shampoo of the invention containing lignosulfonates have relatively good anti-dandruff and itching-relieving, it is dry,
Wet carding effect washes refreshing not short-tempered, the good hand touch of hair back hair shaft, and being used for a long time has more apparent Anti-hair loss effect.
Claims (9)
1. a kind of lignin sulfonate modified object, which is characterized in that its molecular weight is 10000 ~ 40000, molecular weight distribution 1.5
~ 6.0, minimum reachable 28 mN/m of surface tension are made by lignosulfonates and dodecylallyldimethylammonium chloride.
2. lignin sulfonate modified object according to claim 1, which is characterized in that the lignin sulfonate modified object
It is made by following methods, comprising the following steps:
(1) lignosulfonates are added in reactor and water, lignosulfonates is dissolved in deionized water, solution concentration is
Initiator is added in 0.04 ~ 0.2 g/mL, and under inert gas atmosphere, stirring is uniformly mixed the two；
(2) when the temperature in reactor rises to 70 ~ 80 DEG C, it is molten to start dropwise addition dodecylallyldimethylammonium chloride
Liquid, control time for adding are 1 ~ 2 h, and the reaction was continued 3 ~ 5 h after being added dropwise obtain copolymer crude product；
(3) it is stood after isopropanol being added, isolates precipitating, 8 ~ 10 h of acetone extraction is carried out to sediment, after removing homopolymer, is set
Dry constant weight, obtains lignin sulfonate modified object in baking oven.
3. lignin sulfonate modified object according to claim 2, which is characterized in that the amount of step (1) described initiator
It is the 2 ~ 4% of reactant gross mass.
4. lignin sulfonate modified object according to claim 2, which is characterized in that dodecyl described in step (2)
The mass ratio of dimethylallylammonium chloride and lignosulfonates is 1 ﹕ 1.25 ~ 5.
5. lignin sulfonate modified object according to claim 2, which is characterized in that dodecyl described in step (2)
The mass ratio of dimethylallylammonium chloride and lignosulfonates is 1:2；Step (1) the lignosulfonate solutions concentration
For 0.8 ~ 0.12 g/mL.
6. lignin sulfonate modified object according to claim 1, which is characterized in that the lignosulfonates are wooden
One of plain ichthyodin, calcium lignosulfonate, magnesium lignosulfonate and sodium lignin sulfonate.
7. application of any one of the claim 1-6 lignin sulfonate modified object in shampoo.
8. a kind of shampoo containing lignin sulfonate modified object described in any one of claims 1-6, which is characterized in that packet
Component containing following mass parts:
10 ~ 25 parts of sodium lauroyl glutamate, 5 ~ 20 parts of sodium lauroyl sarcosine, 1 ~ 15 part of Cocoamidopropyl betaine, methyl
1 ~ 6 part of cocoyl sodium taurocholate, 1 ~ 8 part of lignin sulfonate modified object, 1 ~ 5 part of Tea Saponin, 2 ~ 8 parts of plant extraction liquid, D-
1 ~ 5 part of panthenol, 2 ~ 4 parts of guar hydroxypropyltrimonium ammonium chloride, citric acid 0.1 ~ 1,0.1 ~ 0.6 part of essence, preservative 0.05 ~
0.1 part, 80 ~ 120 parts of deionized water.
9. shampoo according to claim 8, which is characterized in that the plant extraction liquid is marine algae extract, mulberry fruit mentions
Take any two kinds in object, Semen Sesami Nigrum extract, radix-polygoni multiflori extract and Rhizoma Zingiberis extract；The essence is lemonene and smokes
One of clothing hay-scented；The preservative is one of Kathon CG, methylparaben and propylben.
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