CN106750361B - A kind of lignin sulfonate modified object and its application and the shampoo comprising the modifier - Google Patents
A kind of lignin sulfonate modified object and its application and the shampoo comprising the modifier Download PDFInfo
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- CN106750361B CN106750361B CN201611052511.3A CN201611052511A CN106750361B CN 106750361 B CN106750361 B CN 106750361B CN 201611052511 A CN201611052511 A CN 201611052511A CN 106750361 B CN106750361 B CN 106750361B
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- lignin sulfonate
- modified object
- sulfonate modified
- lignosulfonates
- shampoo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
Abstract
The invention discloses a kind of lignin sulfonate modified object, molecular weight 10000-40000, molecular weight distribution is 1.5~6.0, and minimum reachable 28 mN/m of surface tension are made by lignosulfonates and dodecylallyldimethylammonium chloride.Shampoo the invention also discloses the application of the lignin sulfonate modified object and containing the lignin sulfonate modified object.The present invention has surface-active, scattered adsorption, chelation and anti-oxidant and antibacterial characteristic using lignosulfonates, and lignosulfonates are added in shampoo formula, can play the effect of deoiling, is anti-dandruff, taking care of hair.The shampoo using effect that product of the present invention preparation process is easy to operate, obtains is obvious, and mild non-stimulated, hair and fur suitable for various characteristics have no toxic side effect without allergic reaction after use, and quick, and generating and nourishing hair effect is good.
Description
Technical field
The present invention relates to a kind of lignin sulfonate modified objects, while being related to the application of the lignin sulfonate modified object.
The invention further relates to the shampoos comprising the lignin sulfonate modified object.
Background technique
The development course for making a general survey of shampoo is developed to today, people to shield unification, shampoo is washed by the cleaning function of early stage
Focus more on product itself it is natural, safe and non-toxic, be provided simultaneously with nourishing and nursing conditioning hair the effect of.No silicone oil is mildly washed
Shampoo comes into being in this context.As 105534822 A of CN discloses a kind of no silicon and has effects that washing for hair care
Shampoo mainly includes the ingredients such as laureth sodium sulfovinate, empgen BB, Tea Saponin and Chinese medicine extract, institute
The primary surfactant of selection is more mild, and formula not silicate-containing oil, obtained product detergency is moderate, do, wet cardability it is good.Extensively
104921989 A of Zhou Huanya company CN reports a kind of not silicate-containing oil and has effects that the shampoo of scalp care, mainly by
Mild surfactant and scalp care agent composition, formula is mild non-stimulated, has nursing scalp and reduces the function of hair loss
Effect.
In conclusion these leading mild non-stimulated, not silicate-containing oil shampoos are substantially concentrated on using mild table
Face activating agent, the ingredient in conjunction with some Chinese medicines or plant extraction liquid as conditioning scalp, still, natural mild surfactant
Development and application is only the following core that the development of shield technology is washed without silicone oil.
Lignin is the non-oil resource that nature is uniquely capable of providing renewable aryl compound, is second largest naturally to have
Machine object.Lignosulfonates are the lignin of sulfonated processing, belong to high molecular surfactant, have biodegradability,
Nantural non-toxic, product price are cheap.There is certain surface-active, absorption dispersibility, chelating properties and anti-oxidant spy simultaneously
Property, it can be used as natural sun-proof component, greatly improve the sun-proof ability of product；In addition, also there is certain collaboration decontamination and kill
Bacterium effect.
Summary of the invention
Primary and foremost purpose of the invention is to provide a kind of lignin sulfonate modified object, and the lignin sulfonate modified object is by wood
Mahogany sulfonate reacts to obtain with dodecylallyldimethylammonium chloride.Lignosulfonates are added in shampoo,
Have effects that deoil, is anti-dandruff, hair care.
To achieve the above object, the invention is realized by the following technical scheme: a kind of lignin sulfonate modified object, point
Son amount is 10000 ~ 40000, and molecular weight distribution is 1.5 ~ 6.0, minimum reachable 28 mN/m of surface tension, by lignosulfonates
It is made with dodecylallyldimethylammonium chloride.
Specifically, the lignin sulfonate modified object is made by following methods, comprising the following steps:
(1) lignosulfonates are added in reactor and water, lignosulfonates is dissolved in deionized water, solution concentration
For 0.04 ~ 0.2 g/mL, initiator is added, under inert gas atmosphere, stirring is uniformly mixed the two；
(2) when the temperature in reactor rises to 70 ~ 80 DEG C, start that dodecylallyldimethylammonium chloride is added dropwise
Solution, control time for adding are 1 ~ 2 h, and the reaction was continued 4 h after being added dropwise obtain copolymer crude product；
(3) a period of time is stood after isopropanol is added, isolates precipitating, 8 ~ 10 h of acetone extraction is carried out to sediment, is removed
After removing homopolymer, it is placed in 50 DEG C of baking ovens dry constant weight, obtains lignin sulfonate modified object.
Step (1) the lignosulfonate solutions concentration is preferably 0.8 ~ 0.12 g/mL；The amount of the initiator is anti-
The 2 ~ 4% of object gross mass are answered, reactant gross mass refers to lignosulfonates and the total matter of dodecylallyldimethylammonium chloride
Amount.The initiator is K2S2O8。
The mass ratio of dodecylallyldimethylammonium chloride described in step (2) and lignosulfonates is 1:1.25
~5；It is preferably in a proportion of 1:2.
The lignosulfonates include but is not limited to ammonium lignosulphonate, calcium lignosulfonate, magnesium lignosulfonate or
One of sodium lignin sulfonate.
Another object of the present invention is to provide the application of above-mentioned lignin sulfonate modified object, specifically the lignin
Application of the sulfonate modified object in shampoo.
Another object of the present invention is to provide the shampoo containing above-mentioned lignin sulfonate modified object.
A kind of related shampoo containing lignosulfonates can be achieved through the following technical solutions: one kind containing lignin
The shampoo of sulfonate includes following components in parts by weight:
10 ~ 25 parts of osmanthus acyl sodium glutamate, 5 ~ 20 parts of sodium lauroyl sarcosine, 1 ~ 15 part of Cocoamidopropyl betaine, first
1 ~ 6 part of base cocoyl sodium taurocholate, 1~8 part of lignin sulfonate modified object, 1 ~ 5 part of Tea Saponin, 2 ~ 8 parts of plant extraction liquid,
1 ~ 5 part of D-pantothenyl aleohol, 2 ~ 4 parts of guar hydroxypropyltrimonium ammonium chloride, citric acid 0.1 ~ 1,0.1 ~ 0.6 part of essence, preservative
0.05 ~ 0.1 part, 80 ~ 120 parts of deionized water.
The plant extraction liquid is marine algae extract, Fructus Mori extract, Semen Sesami Nigrum extract, radix-polygoni multiflori extract and rhizoma zingiberis
Any two kinds in extract.
The essence is one of lemonene and lavender perfume (or spice).
The preservative is one of Kathon CG, methylparaben and propylben.
The preparation method of shampoo of the present invention containing lignosulfonates, the following steps are included:
(1) sodium lauroyl glutamate, sodium lauroyl sarcosine, Cocoamidopropyl betaine, methyl cocoyl are taken in proportion
Acyl taurines sodium and water stir at 50 ~ 70 DEG C until dissolution；
(2) step (1) resulting mixture is cooled to 40 ~ 55 DEG C, sequentially adds Tea Saponin, lignin in proportion
Sulfonate and guar hydroxypropyltrimonium ammonium chloride continue 10 ~ 15 min of stirring;
(3) mixture obtained by the step (2) is maintained at 40 ~ 55 DEG C, plant extraction liquid is added, is sufficiently mixed；
(4) after the step (3) resulting mixture being cooled to 30 ~ 40 DEG C, essence, preservative and citric acid is added,
PH to 5.5 ~ 6.5 is adjusted to get the shampoo containing lignin sulfonate modified object.
Compared with prior art, beneficial effects of the present invention:
1. in the present invention, polymerize with dodecylallyldimethylammonium chloride using lignosulfonates anti-
It answers.Wherein dodecylallyldimethylammonium chloride is both quaternary ammonium salt and vinyl monomer, is introduced into lignosulfonates
Main structure in, the lignin sulfonate modified object of available both sexes, with just in this lignin sulfonate modified object
Electric group, for conditioner can be played the role of in shampoo.
2. lignosulfonates are natural antioxidant, are added in shampoo the use that can reduce preservative,
Make the more natural safety of product.Lignin sulfonate modified object of the invention has the surface-active of lignosulfonates, dispersion
Absorption, chelation and anti-oxidant and antibacterial function, are added in shampoo formula, can play deoil, be anti-dandruff,
The effect of hair care.In addition, lignosulfonates also have certain Synergistic biocidal bacteriostasis efficacy, to reduce the scalp after hair washing
It itches phenomenon.
3. the present invention, as primary surfactant, passes through the reproducible sulfomethylated lignin of addition using mild surfactant
Sulfonate modified object and plant extraction liquid do not add organic silicon conditioner additionally, obtained properties of product are mild, it is non-stimulated,
Without side-effects, hair and fur suitable for various characteristics have no toxic side effect without allergic reaction after use.In addition, the present invention exists
Plant extraction liquid is added in shampoo formula, the effect that can be played activation hair follicle tissue, promote scalp metabolism, hair tonic is supported
It is good to send out effect, efficiently reduces alopecia and the generation of white hair.
4. the preparation process of lignin sulfonate modified object and shampoo of the invention is easy to operate.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail, and embodiments of the present invention are not limited thereto.
Embodiment 1
Shampoo containing magnesium lignosulfonate modifier, the raw material including following mass parts:
10 parts of sodium lauroyl glutamate, 15 parts of sodium lauroyl sarcosine, 5 parts of Cocoamidopropyl betaine, methyl cocoyl
4 parts of acyl taurines sodium, 1 part of magnesium lignosulfonate modifier, 1 part of Tea Saponin, 2 parts of plant extraction liquid, 5 parts of D-pantothenyl aleohol, Guar
3 parts of glue hydroxypropyl-trimethyl ammonium chloride, 0.3 part of citric acid, 0.1 part of lemon extract, 0.05 part of Kathon CG, 80 parts of deionized water.It plants
Object extracting solution is that marine algae extract and Semen Sesami Nigrum extract are mixed to prepare in quality 1:1 ratio.
Wherein, the preparation of magnesium lignosulfonate modifier comprises the steps of:
(1) in reactor, 10 g magnesium lignosulfonates is dissolved in 83 mL deionized waters, 3% initiator is added
K2S2O8, it is passed through protection gas N2, stirring is uniformly mixed the two.
(2) when the temperature in reactor rises to 70 DEG C, start that 2 g dodecyl dimethyl allyl chlorinations are added dropwise
Ammonium, control time for adding are that 1 h obtains copolymer crude product after being added dropwise after the reaction was continued 4 h.
(3) a period of time is stood after isopropanol is added, precipitating is isolated, sediment is put into soxhlet's extractor, with third
Ketone extracts 8 h, after removing homopolymer, is placed in 50 DEG C of baking ovens dry constant weight.
Shampoo preparation method:
(1) sodium lauroyl glutamate, sodium lauroyl sarcosine, Cocoamidopropyl betaine, methyl cocoyl are taken in proportion
Acyl taurines sodium and water stir at 50~70 DEG C until dissolution.
(2) step (1) resulting mixture is cooled to 40~55 DEG C, sequentially adds Tea Saponin, magnesium lignosulfonate changes
Property object and guar hydroxypropyltrimonium ammonium chloride, continue 10~15 min of stirring.
(3) mixture obtained by step (2) is maintained at 40~55 DEG C, plant extraction liquid is added, is sufficiently mixed.
(4) after step (3) resulting mixture being cooled to 30~40 DEG C, essence, preservative, citric acid is added, adjusts
PH to 5.5~6.5 to get the modifier containing magnesium lignosulfonate shampoo.
Embodiment 2
Shampoo containing ammonium lignosulphonate's modifier, the raw material including following mass parts:
15 parts of sodium lauroyl glutamate, 5 parts of sodium lauroyl sarcosine, 10 parts of Cocoamidopropyl betaine, methyl cocoyl
1 part of acyl taurines sodium, 5 parts of ammonium lignosulphonate's modifier, 3 parts of Tea Saponin, 5 parts of plant extraction liquid, 2 parts of D-pantothenyl aleohol, Guar
2 parts of glue hydroxypropyl-trimethyl ammonium chloride, 0.5 part of citric acid, 0.3 part of lavender oil, 0.05 part of methylparaben, deionized water
100 parts.Plant extraction liquid is that Fructus Mori extract is mixed to prepare with radix-polygoni multiflori extract 1:1 in mass ratio.
Wherein, the preparation of ammonium lignosulphonate's modifier comprises the steps of:
(1) in reactor, 10 g ammonium lignosulphonates is dissolved in 100 mL deionized waters, 3% initiator is added
K2S2O8, it is passed through protection gas N2, stirring is uniformly mixed the two.
(2) when the temperature in reactor rises to 75 DEG C, start that 5 g dodecyl dimethyl allyl chlorinations are added dropwise
Ammonium, control time for adding are that 1.5 h obtain copolymer crude product after being added dropwise after the reaction was continued 4 h.
(3) a period of time is stood after isopropanol is added, precipitating is isolated, sediment is put into soxhlet's extractor, with third
Ketone extracts 9 h, after removing homopolymer, is placed in 50 DEG C of baking ovens dry constant weight.
Shampoo preparation method:
(1) sodium lauroyl glutamate, sodium lauroyl sarcosine, Cocoamidopropyl betaine, methyl cocoyl are taken in proportion
Acyl taurines sodium and water stir at 50~70 DEG C until dissolution.
(2) step (1) resulting mixture is cooled to 40~55 DEG C, sequentially adds Tea Saponin, ammonium lignosulphonate changes
Property object and guar hydroxypropyltrimonium ammonium chloride, continue 10~15 min of stirring.
(3) mixture obtained by step (2) is maintained at 40~55 DEG C, plant extraction liquid is added, is sufficiently mixed.
(4) after step (3) resulting mixture being cooled to 30~40 DEG C, essence, preservative, citric acid is added, adjusts
PH to 5.5~6.5 to get the modifier containing ammonium lignosulphonate shampoo.
Embodiment 3
Shampoo containing sodium lignin sulfonate modifier, the raw material including following parts by weight:
25 parts of sodium lauroyl glutamate, 20 parts of sodium lauroyl sarcosine, 15 parts of Cocoamidopropyl betaine, methyl cocoyl
6 parts of acyl taurines sodium, 8 parts of sodium lignin sulfonate modifier, 5 parts of Tea Saponin, 8 parts of plant extraction liquid, 1 part of D-pantothenyl aleohol, Guar
2 parts of glue hydroxypropyl-trimethyl ammonium chloride, 0.6 part of citric acid, 0.5 part of lemon extract, 0.05 part of propylben, deionized water
120 parts.Plant extraction liquid is that Fructus Mori extract and Rhizoma Zingiberis extract 1:1 in mass ratio are mixed to prepare.
Wherein, the preparation of sodium lignin sulfonate modifier comprises the steps of:
(1) in reactor, 10 g sodium lignin sulfonates is dissolved in 125 mL deionized waters, 3% initiator is added
K2S2O8, it is passed through protection gas N2, stirring is uniformly mixed the two.
(2) when the temperature in reactor rises to 80 DEG C, start that 8 g dodecyl dimethyl allyl chlorinations are added dropwise
Ammonium, control time for adding are that 2 h obtain copolymer crude product after being added dropwise after the reaction was continued 4 h.
(3) a period of time is stood after isopropanol is added, precipitating is isolated, sediment is put into soxhlet's extractor, with third
Ketone extracts 10 h, after removing homopolymer, is placed in 50 DEG C of baking ovens dry constant weight.
Shampoo preparation method:
(1) sodium lauroyl glutamate, sodium lauroyl sarcosine, Cocoamidopropyl betaine, methyl cocoyl are taken in proportion
Acyl taurines sodium and water stir at 50~70 DEG C until dissolution.
(2) step (1) resulting mixture is cooled to 40~55 DEG C, sequentially adds Tea Saponin, sodium lignin sulfonate changes
Property object and guar hydroxypropyltrimonium ammonium chloride, continue 10~15 min of stirring.
(3) mixture obtained by step (2) is maintained at 40~55 DEG C, plant extraction liquid is added, is sufficiently mixed.
(4) after step (3) resulting mixture being cooled to 30~40 DEG C, essence, preservative, citric acid is added, adjusts
PH to 5.5~6.5 to get the modifier containing sodium lignin sulfonate shampoo.
The mode for taking volunteer's sensory evaluation is asked four groups of people as subjects, is had one's hair wash using Examples 1 to 3 weekly
Water twice, while as a control group with the shampoo of commercially available silicate-containing oil, to the shampoo of the invention containing lignosulfonates into
The aesthetic evaluation of row.Respectively to after shampoo hair washing anti-dandruff and itching-relieving, dry cardability, wet cardability, feel, Anti-hair loss effect into
Row evaluation, evaluation is using 5 points of systems, and 5 points are best result, and 1 point is minimum point.The evaluation result of Examples 1 to 3 is as shown in table 1.
The different group shampoo Analyses Methods for Sensory Evaluation Results of table 1
| Anti-dandruff and itching-relieving | Dry cardability | Wet cardability | Feel | Anti-hair loss effect | Comprehensive score | |
| Embodiment 1 | 3.3 | 4.0 | 4.3 | 3.5 | 3.5 | 18.6 |
| Embodiment 2 | 4.0 | 4.5 | 4.5 | 4.0 | 3.9 | 20.9 |
| Embodiment 3 | 4.6 | 4.5 | 4.6 | 4.2 | 4.8 | 22.7 |
| Commercially available siliceous shampoo | 3.9 | 3.5 | 4.5 | 3.2 | 3.4 | 18.5 |
As it can be seen from table 1 the shampoo of the invention containing lignosulfonates have relatively good anti-dandruff and itching-relieving, it is dry,
Wet carding effect washes refreshing not short-tempered, the good hand touch of hair back hair shaft, and being used for a long time has more apparent Anti-hair loss effect.
Claims (9)
1. a kind of lignin sulfonate modified object, which is characterized in that its molecular weight is 10000 ~ 40000, molecular weight distribution 1.5
~ 6.0, minimum reachable 28 mN/m of surface tension are made by lignosulfonates and dodecylallyldimethylammonium chloride.
2. lignin sulfonate modified object according to claim 1, which is characterized in that the lignin sulfonate modified object
It is made by following methods, comprising the following steps:
(1) lignosulfonates are added in reactor and water, lignosulfonates is dissolved in deionized water, solution concentration is
Initiator is added in 0.04 ~ 0.2 g/mL, and under inert gas atmosphere, stirring is uniformly mixed the two；
(2) when the temperature in reactor rises to 70 ~ 80 DEG C, it is molten to start dropwise addition dodecylallyldimethylammonium chloride
Liquid, control time for adding are 1 ~ 2 h, and the reaction was continued 3 ~ 5 h after being added dropwise obtain copolymer crude product；
(3) it is stood after isopropanol being added, isolates precipitating, 8 ~ 10 h of acetone extraction is carried out to sediment, after removing homopolymer, is set
Dry constant weight, obtains lignin sulfonate modified object in baking oven.
3. lignin sulfonate modified object according to claim 2, which is characterized in that the amount of step (1) described initiator
It is the 2 ~ 4% of reactant gross mass.
4. lignin sulfonate modified object according to claim 2, which is characterized in that dodecyl described in step (2)
The mass ratio of dimethylallylammonium chloride and lignosulfonates is 1 ﹕ 1.25 ~ 5.
5. lignin sulfonate modified object according to claim 2, which is characterized in that dodecyl described in step (2)
The mass ratio of dimethylallylammonium chloride and lignosulfonates is 1:2；Step (1) the lignosulfonate solutions concentration
For 0.8 ~ 0.12 g/mL.
6. lignin sulfonate modified object according to claim 1, which is characterized in that the lignosulfonates are wooden
One of plain ichthyodin, calcium lignosulfonate, magnesium lignosulfonate and sodium lignin sulfonate.
7. application of any one of the claim 1-6 lignin sulfonate modified object in shampoo.
8. a kind of shampoo containing lignin sulfonate modified object described in any one of claims 1-6, which is characterized in that packet
Component containing following mass parts:
10 ~ 25 parts of sodium lauroyl glutamate, 5 ~ 20 parts of sodium lauroyl sarcosine, 1 ~ 15 part of Cocoamidopropyl betaine, methyl
1 ~ 6 part of cocoyl sodium taurocholate, 1 ~ 8 part of lignin sulfonate modified object, 1 ~ 5 part of Tea Saponin, 2 ~ 8 parts of plant extraction liquid, D-
1 ~ 5 part of panthenol, 2 ~ 4 parts of guar hydroxypropyltrimonium ammonium chloride, citric acid 0.1 ~ 1,0.1 ~ 0.6 part of essence, preservative 0.05 ~
0.1 part, 80 ~ 120 parts of deionized water.
9. shampoo according to claim 8, which is characterized in that the plant extraction liquid is marine algae extract, mulberry fruit mentions
Take any two kinds in object, Semen Sesami Nigrum extract, radix-polygoni multiflori extract and Rhizoma Zingiberis extract；The essence is lemonene and smokes
One of clothing hay-scented；The preservative is one of Kathon CG, methylparaben and propylben.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275903A (en) * | 1997-09-17 | 2000-12-06 | 宝洁公司 | Hair care compositions comprising optical brighteners which provide UV protection |
| CN101054512A (en) * | 2006-04-14 | 2007-10-17 | 中国石油化工股份有限公司 | Filtrate reducer for oil field well drilling fluid |
| CN104546513A (en) * | 2013-10-11 | 2015-04-29 | 国际香料和香精公司 | Terpolymer-coated polymer encapsulated active material |
| CN104892956A (en) * | 2015-06-24 | 2015-09-09 | 济南圣泉集团股份有限公司 | Modified lignosulphonate and preparing method thereof |
-
2016
- 2016-11-25 CN CN201611052511.3A patent/CN106750361B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275903A (en) * | 1997-09-17 | 2000-12-06 | 宝洁公司 | Hair care compositions comprising optical brighteners which provide UV protection |
| CN101054512A (en) * | 2006-04-14 | 2007-10-17 | 中国石油化工股份有限公司 | Filtrate reducer for oil field well drilling fluid |
| CN104546513A (en) * | 2013-10-11 | 2015-04-29 | 国际香料和香精公司 | Terpolymer-coated polymer encapsulated active material |
| CN104892956A (en) * | 2015-06-24 | 2015-09-09 | 济南圣泉集团股份有限公司 | Modified lignosulphonate and preparing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 木质素磺酸盐两性高分子聚合物合成及应用;孙岩峰等;《大连理工大学学报》;20120731;第52卷(第4期);第469-475页 |
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