One kind is without silicone oil shampoo composite
Technical field
The present invention relates to field of daily chemicals, more particularly to one kind is without silicone oil shampoo composite.
Background technology
Shampoo in current Chinese market is generally silicone oil product.Silicone oil is added in shampoo, can come soft to hair carry
Soft smooth glossy sensation, at the same time also brings along the thick and heavy sense of hair.Silicate-containing oil shampoo, which is used for a long time, can cause hair to be done
It is withered, it is greasy, and silicone oil is not degradable, and serious pollution is caused to environment.Therefore, increasingly lifted in health and environmental protection ideas
Today, no silicone oil shampoo is following to turn into huge a market demand and developing direction.At present, no silicone oil technology needs to solve
One it is important the problem of be use rear hair smoothness and glossiness the problem of, in the market is without suitable after silicone oil shampoo use
Slippery and glossiness are all far below smoothness and glossiness after silicone oil shampoo use.
The content of the invention
The present invention solves the technical problem of one kind is provided without silicone oil shampoo composite, from the raw material of natural origin
Substitute silicone oil, degradable, more environmentally friendly, health and safety, while solving no silicone oil shampoo by fruit oil mixture uses back
The problem of smoothness and glossiness are far below silicone oil shampoo is sent out, it is more healthy compared to silicone oil product, gentle, safe, while can be significantly
The smoothness and glossiness for improving product reach the smoothness and glossiness similar to silicone oil product.
In order to solve the above technical problems, one aspect of the present invention is:There is provided one kind without silicone oil shampoo group
Compound, it is characterised in that the constituent mass percentage of described composition is:
Anion surfactant 5-30%;
Amphoteric surfactant 2-20%;
Fruit oil mixture 2-12%;
Pearling agent 0.5-3%;
Viscosity modifier 0.2-0.5%;
Chelating agent 0.02-0.3%;
In above-mentioned, the component of described composition also includes pH adjusting agent, essence and pigment, and remaining is deionized water.
In a preferred embodiment of the present invention, it is described to go fruit oil mixture to use shea butter, PPG-3 Octyl Ethers
With the mixture of the myristic acid benzyl oxide of polypropylene glycol -3, wherein, the weight of the myristic acid benzyl oxide of polypropylene glycol -3 is than content
The weight of 10-40%, PPG-3 Octyl Ether is 10-40% than content, and remaining is shea butter.
In a preferred embodiment of the present invention, the anion surfactant include but is not limited to alkyl sulfate,
Alkyl ether sulfate, sulfonate and sarcosinate, wherein, described alkyl sulfate includes bay alcohol sulfuric ester ammonium, cocoyl
Ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, NaLS, sodium cocosulfate and its mixture;Described alkane
Base ether sulfate includes laureth sulfuric ester ammonium, laureth potassium sulfate and laureth sulphur
Sour sodium;Described sulfonate includes tridecyl benzene sulfonate, neopelex and lauryl sulfosuccinates;
Described sarcosinate includes sodium lauryl sarcosinate;
In a preferred embodiment of the present invention, described anion surfactant is preferably alkyl sulfate and alkyl
Ether sulfate.
In a preferred embodiment of the present invention, described anion surfactant be preferably bay alcohol sulfuric ester ammonium or
One or both of laureth sulfuric ester ammonium.
In a preferred embodiment of the present invention, described amphoteric surfactant is Cocoamidopropyl betaine, the moon
One or both of osmanthus base both sexes sodium acetate.
In a preferred embodiment of the present invention, described pearling agent is one kind in ethylene glycol stearate monoesters and dibasic acid esters
Or its mixture.
In a preferred embodiment of the present invention, described viscosity modifier is sodium chloride, ammonium chloride, sodium sulphate, sulfuric acid
Ammonium, polyglycol distearate, polyethylene glycol mono stearate, carboxymethyl cellulose, carboxyethyl cellulose, carboxylic propyl group fiber
One or both of element, polyethylene glycol, polyvinylpyrrolidone thing mixed above
In a preferred embodiment of the present invention, described chelating agent is disodium ethylene diamine tetraacetate, ethylenediamine tetra-acetic acid
One or both of four sodium, citric acid, ascorbic acid thing mixed above.
In a preferred embodiment of the present invention, described pH conditioning agents are one or both of citric acid, phosphoric acid.
The beneficial effects of the invention are as follows:The present invention without silicone oil shampoo composite, using the fruit oil mixture of natural origin
Replace the silicone oil generally used in existing shampoo technology, eliminate silicone oil the old product of scalp trigger scalp is fuel-displaced and withered and yellowish hairs
Phenomenon;The raw material of use is easily biodegradable, it is to avoid silicone oil is degradable so as to the environmental problem produced, compared to silicone oil production
Product are more healthy, gentle, safe, at the same smoothness and glossiness that product can be significantly improved reach it is similar to silicone oil product smooth
Degree and glossiness.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common
All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
The embodiment of the present invention includes:
One kind is without silicone oil shampoo composite, it is characterised in that the constituent mass percentage of described composition is:
Anion surfactant 5-30%;
Amphoteric surfactant 2-20%;
Fruit oil mixture 2-12%;
Pearling agent 0.5-3%;
Viscosity modifier 0.2-0.5%;
Chelating agent 0.02-0.3%;
In above-mentioned, the component of described composition also includes pH adjusting agent, essence and pigment, and remaining is deionized water.
Further, it is described to go fruit oil mixture to use shea butter, PPG-3 Octyl Ethers and the Pork and beans of polypropylene glycol -3
The mixture of cool sour benzyl oxide, wherein, the weight of the myristic acid benzyl oxide of polypropylene glycol -3 is 10-40%, PPG-3 octyl groups than content
The weight of ether is 10-40% than content, and remaining is shea butter.
1. shea butter
Shea butter is refined shea butter, also referred to as breast wood fruit, Butyrospermum parkii fruit.Main component is Butyrospermum parkii fruit
Fat unsaponifiable matter, ethyl oleate, ethyl stearte and ethyl linoleate;The content of wherein Butyrospermum parkii fruit fat unsaponifiable matter is
90% or so, the content of unsaponifiable matter is 10% or so.Refined shea butter has the performance of soft moist hair very well.
2.PPG-3 Octyl Ethers
The PPG-3 Octyl Ethers in natural oil source have is uniformly distributed performance well, shea butter is effectively coated with
In damaged hair, make hair more smooth;
3. the myristic acid benzyl oxide of polypropylene glycol -3
The myristic acid benzyl oxide of polypropylene glycol -3 in palm source has high refractive index, and index of refraction is 1.467(Dimethyl
Siloxanes index of refraction:1.397), by increasing capacitance it is possible to increase the glossiness of hair, solve and shea butter glossiness asking not enough is used alone
Topic.Adherence can be reduced simultaneously, further the greasy feeling after reduction use, makes hair salubriouser, be difficult fuel-displaced.
The anion surfactant includes but is not limited to alkyl sulfate, alkyl ether sulfate, sulfonate and flesh ammonia
Hydrochlorate, wherein, described alkyl sulfate includes bay alcohol sulfuric ester ammonium, cocoyl ammonium sulfate, lauryl potassium sulfate, cocoyl
Potassium sulfate, NaLS, sodium cocosulfate and its mixture;Described alkyl ether sulfate includes laureth sulphur
Acid esters ammonium, laureth potassium sulfate and sodium laureth sulfate;Described sulfonate includes 13
Sodium alkyl benzene sulfonate, neopelex and lauryl sulfosuccinates;Described sarcosinate includes lauryl
Sodium sarcosinate;
Wherein, described anion surfactant is preferably alkyl sulfate and alkyl ether sulfate;It is described it is cloudy from
Sub- surfactant is particularly preferably one or both of bay alcohol sulfuric ester ammonium or laureth sulfuric ester ammonium.
Described amphoteric surfactant is one kind or two in Cocoamidopropyl betaine, lauryl both sexes sodium acetate
Kind.
Described pearling agent is ethylene glycol stearate monoesters and one kind or its mixture in dibasic acid esters.
Described viscosity modifier is sodium chloride, ammonium chloride, sodium sulphate, ammonium sulfate, polyglycol distearate, poly- second
Glycol monostearate, carboxymethyl cellulose, carboxyethyl cellulose, carboxy-propyl cellulose, polyethylene glycol, polyvinylpyrrolidone
One or both of thing mixed above
Described chelating agent is one in disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate, citric acid, ascorbic acid
Plant or two or more mixtures.
Described pH conditioning agents are one or both of citric acid, phosphoric acid.
Embodiment:
Prepare fruit oil mixture(Ⅰ)
Shea butter 50%;
PPG-3 Octyl Ethers 25%;
The myristic acid of polypropylene glycol -3 benzyl oxide 25%.
Prepare fruit oil mixture(Ⅱ)
Shea butter 50%;
PPG-3 Octyl Ethers 30%;
The myristic acid of polypropylene glycol -3 benzyl oxide 20%.
Prepare fruit oil mixture(Ⅲ)
Shea butter 50%;
PPG-3 Octyl Ethers 20%;
The myristic acid of polypropylene glycol -3 benzyl oxide 30%.
The preparation method without silicone oil shampoo composite is:Suitable quantity of water is added in retort, under slow stirring
Cation polyquaternium is added to be disperseed, then being slowly stirred makes temperature rise to 70 DEG C, adds pH conditioning agent citric acids, continues
Add bay alcohol sulfuric ester ammonium, laureth sulfuric ester ammonium, Cocoamidopropyl betaine and lauryl both sexes sodium acetate, second
Glycol stearate, disodium ethylene diamine tetraacetate, make after these materials are completely dispersed, breast wood fruit is added when being cooled to 50 DEG C or so
The mixture of oil, PPG-3 Octyl Ethers and the myristic acid benzyl oxide of polypropylene glycol -3, makes these materials be cooled to 40 after being completely dispersed
DEG C or so add pigment, sodium chloride continue stir, it is ensured that obtain uniform mixture.
The formulation Example without silicone oil shampoo composite see the table below:
Glossiness and smoothness evaluation:
The mode of volunteer's sensory evaluation is taken in glossiness and smoothness detection, and volunteer is long hair women, asks nine groups
People, every group of ten people are given a mark.Glossiness is the glossy degree of hair;Smoothness is commented by the cardability of hair after drying
Valency.Detect and containing only 3% shea butter(Shampoo composite 1), containing only 3%PPG-3 Octyl Ethers(Shampoo composite 2)With containing only 3%
The myristic acid benzyl oxide of polypropylene glycol -3(Shampoo composite 3)Shampoo composite make comparisons, while and containing 1%, 2% and 3%
Dimethyl silicone polymer(Shampoo composite 4,5,6)Shampoo composite compare.
Evaluation cycle is 4 weeks, is evaluated using 5 points of systems, and 5 points are best result, and 1 point is minimum point, and fraction is higher to be represented
Effect is better.The Analyses Methods for Sensory Evaluation Results of formulation Example see the table below:
Note:1. shampoo composite 1:Fruit oil mixture is substituted with 3% shea butter, other components proportioning all same, preparation side
Method is identical with preparation method of the present invention;
2. shampoo composite 2:Fruit oil mixture is substituted with 3%PPG-3 Octyl Ethers, other components proportioning all same, is prepared
Method is identical with preparation method of the present invention;
3. shampoo composite 3:Fruit oil mixture is substituted with the myristic acid benzyl oxide of 3% polypropylene glycol -3, other components proportioning
All same, preparation method is identical with preparation method of the present invention;
4. shampoo composite 4:Fruit oil mixture is substituted with 1% dimethyl silicone polymer, other components proportioning all same, system
Preparation Method is identical with preparation method of the present invention;
5. shampoo composite 5:Fruit oil mixture is substituted with 2% dimethyl silicone polymer, other components proportioning all same, system
Preparation Method is identical with preparation method of the present invention;
6. shampoo composite 6:Fruit oil mixture is substituted with 3% dimethyl silicone polymer, other components proportioning all same, system
Preparation Method is identical with preparation method of the present invention.
The result satisfaction of each evaluation index can be because in formula it can be seen from the Analyses Methods for Sensory Evaluation Results of formulation Example
The proportion of each composition is different and changes, when the component in shampoo is formulation Example 3, two sense organs of glossiness and smoothness
Evaluation index is shown and high dose silicone oil shampoo composite 6 (3% dimethyl silicone polymer) identical satisfaction;When in shampoo
Component be formulation Example 4 when, addition 3% fruit oil mixture to be substantially better than the shampoo composite 1,2 containing 3% single component
With 3 satisfaction;And show satisfaction more more preferable than high dose silicone oil shampoo composite 6 (3% dimethyl silicone polymer).This
Illustrate that the composition of the present invention can be with the effective purpose for reaching smoothness and glossiness.
In summary, it is of the invention without silicone oil shampoo composite, existing perfume (or spice) is replaced using the fruit oil mixture of natural origin
The silicone oil generally used in wave technology, eliminate silicone oil the old product of scalp trigger scalp is fuel-displaced and withered and yellowish hairs phenomenon;Using
Raw material be easily biodegradable, it is to avoid silicone oil is not degradable so as to the environmental problem produced, it is compared to silicone oil product more healthy,
Gently, safety, while the smoothness and glossiness that can significantly improve product reach the smoothness similar to silicone oil product and gloss
Degree.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.