CN103251514B - Anti-dandruff shampoo composition - Google Patents
Anti-dandruff shampoo composition Download PDFInfo
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- CN103251514B CN103251514B CN201310191482.9A CN201310191482A CN103251514B CN 103251514 B CN103251514 B CN 103251514B CN 201310191482 A CN201310191482 A CN 201310191482A CN 103251514 B CN103251514 B CN 103251514B
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Abstract
The invention discloses an anti-dandruff shampoo composition. The composition comprises the following ingredients in percentage by mass: 5-30% of an anionic surfactant, 2-20% of an ampholytic surfactant, 0.1-2% of an anti-dandruff agent, 2-12% of a conditioner, 0.3-3% of a pearling agent, 0.01-5% of a sensitizer, and the balance of water. According to the anti-dandruff shampoo composition provided by the invention, a plurality of epiphytes such as malassezia globosa, malassezia sympodialis, malassezia furfur, monilia albicans and the like, which cause the dandruff, can be effectively killed by the anti-dandruff agent in the composition to achieve the effects of removing dandruff and diminish inflammation, simultaneously, the problems of dry hair, scalp itching and the like caused by a common anti-dandruff shampoo are solved, and the anti-dandruff agent in the shampoo is good in stability, weak in degreasing capacity and good in application effect.
Description
Technical field
The present invention relates to household chemicals field, particularly relate to a kind of anti-dandruff shampoo composition.
Background technology
Anti-dandruff agent conventional in current shampoo mainly contains Bispyrithione zinc, Zinc Pyrithione, octopirox, endecatylene acid derivative, climbazole, ketoconazole etc., wherein Zinc Pyrithione, Bispyrithione zinc and octopirox are the agent of a class efficient spectrum sterilizing and itch-relieving, are also the anti-dandruff agent of a class extensive use.But it often there will be sedimentation and metachromatism in the application of shampoo formula, to photo-labile and degreasing power is excessively strong, life-time service can cause hair withered, low and deep, do not have the problems such as gloss.The anti-dandruff effect of other several anti-dandruff agent or antibacterial effect can not meet the requirement of consumer.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of anti-dandruff shampoo composition, can reach the effect removing dandruff and antiinflammatory.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of anti-dandruff shampoo composition, the constituent mass percentage ratio of described compositions is: anion surfactant 5-30%, amphoteric surfactant 2-20%, anti-dandruff agent 0.1-2%, regulation machine 2-12%, pearling agent 0.3-3%, sensitizer 0.01-5%, water surplus.
In a preferred embodiment of the present invention, the constituent mass percentage ratio of described compositions is: anion surfactant 10-25%, amphoteric surfactant 2-5%, anti-dandruff agent 0.1-1%, regulation machine 2-5%, pearling agent 0.5-3%, sensitizer 0.2-0.8%, water surplus.
In a preferred embodiment of the present invention, the component of described anti-dandruff shampoo composition also comprises viscosity modifier that mass percent is 0.2-5%, mass percent is 0.02-0.3% chelating agen, pH adjusting agent, pigment and spice.
In a preferred embodiment of the present invention, described anti-dandruff agent is α-R base-γ-methylene-gamma butyrolactone, and structural formula is:
, in formula, R is methyl, ethyl, n-pro-pyl, normal-butyl, the positive acrylic of 1-or 1-n-butene base.
In a preferred embodiment of the present invention, described anion surfactant is one or more mixture in fatty alcohol sulphuric acid sodium salt or ammonium salt, polyoxyethylenated alcohol sodium sulfate salt or ammonium salt, and described amphoteric surfactant is one or both in cocamido propyl betaine, lauryl both sexes sodium acetate.
In a preferred embodiment of the present invention, described anion surfactant is one or both in lauryl alcohol sulfuric ester ammonium or laureth sulfuric ester ammonium.
In a preferred embodiment of the present invention, described conditioner is the compositions of cation polyquaternary ammonium salt and polydimethylsiloxane, described pearling agent is one in ethylene glycol stearate monoesters and dibasic acid esters or its mixture, and described sensitizer is the compositions of menthol and Camphora.
In a preferred embodiment of the present invention, described viscosity modifier is one or more mixture in sodium chloride, ammonium chloride, sodium sulfate, ammonium sulfate, polyglycol distearate, polyethylene glycol mono stearate, carboxymethyl cellulose, carboxyethyl cellulose, carboxy-propyl cellulose, Polyethylene Glycol, polyvinylpyrrolidone.
In a preferred embodiment of the present invention, described chelating agen is one or more mixture in disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, ascorbic acid, and described pH adjusting agent is one or both in citric acid, phosphoric acid.
The invention has the beneficial effects as follows: anti-dandruff shampoo composition of the present invention, anti-dandruff agent in described compositions effectively can kill the multiple funguses such as Malassezia cilobosa, sympodium chlosma, Malassezia furfur and the Candida albicans causing dandruff, reach the effect removing dandruff and antiinflammatory, also solve the problems such as hair dries up, scalp is scratched where it itches that usual anti-dandruff shampoo causes simultaneously, described anti-dandruff agent good stability in shampoo, and degreasing power is weak, effect is good.
Detailed description of the invention
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
The invention provides a kind of anti-dandruff shampoo composition, the component of described compositions is: anion surfactant 5-30%, amphoteric surfactant 2-20%, anti-dandruff agent 0.1-2%, regulation machine 2-12%, pearling agent 0.3-3%, sensitizer 0.01-5%, viscosity modifier 0.2-5%, chelating agen 0.02-0.3%, pH adjusting agent, pigment, spice, water surplus, and wherein component is mass percent.More excellent component is anion surfactant 10-25%, amphoteric surfactant 2-5%, anti-dandruff agent 0.1-1%, regulation machine 2-5%, pearling agent 0.5-3%, sensitizer 0.2-0.8%, water surplus.
Described anion surfactant is aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate compositions.Described aliphatic alcohol sulfate structural formula is ROSO
3m, wherein M=NH
4+, R=C
12, i.e. lauryl alcohol sulfuric ester ammonium.Described fatty alcohol polyoxyethylene ether sulfate structural formula is RO(CH
2cH
2o) nSO
3m, wherein n=3, M=NH
4+, R=C
12, i.e. laureth sulfuric ester ammonium.
Described conditioner is the compositions of cation polyquaternary ammonium salt and polydimethylsiloxane, select the Large stone silicone oil of 15 μm-20 μm and the small particle diameter silicone oil of 0.01 μm-2 μm with the use of, improve the dry cardability of shampoo.Described amphoteric surfactant preferred lauryl both sexes sodium acetate, the preferred α of described anti-dandruff agent-positive propinyl-γ-methylene-gamma butyrolactone, the preferred sodium chloride of described viscosity modifier, described pH adjusting agent optimization citric acid, tune pH is 5.5-6.5, described pigment and spice choose the regulation meeting hygienic standards for cosmetics.
The preparation method of described anti-dandruff shampoo composition is: suitable quantity of water joined in retort, add cation polyquaternary ammonium salt under slow stirring to disperse, slowly stirring makes temperature rise to 70 DEG C again, add pH adjusting agent Fructus Citri Limoniae acid for adjusting pH to 6.5, continue to add lauryl alcohol sulfuric ester ammonium, laureth sulfuric ester ammonium, cocamido propyl betaine and lauryl both sexes sodium acetate, fatty acid monoethanolamide, pearlescent flake ethylene glycol stearate monoesters, disodiumedetate, after these materials are disperseed completely, α-positive propinyl-γ-methylene-gamma butyrolactone (AR) is added when being cooled to about 50 DEG C, polydimethylsiloxane, menthol, Camphora, be cooled to about 40 DEG C after these materials are disperseed completely and add color element, essence etc. continue to stir, guarantee to obtain uniform mixture.Adding all substances and surveying a pH again after making it be uniformly dispersed, appropriate viscosity modifier and pH adjusting agent can be added again as required, to regulate the viscosity of product and pH to suitable degree.
The formulation Example of described anti-dandruff shampoo composition sees the following form:
Described anti-dandruff shampoo composition uses in the mode that is clean and conditioning hair of routine, and mainly comprising step is: with water by hair moistening; Hair uses the anti-dandruff shampoo composition of effective dose, and the scope of described effective dose is 1 gram-20 grams, preferably 3 grams-10 grams, and massage hair and scalp 1min-2min, make described anti-dandruff shampoo composition be distributed in hair and scalp surface uniformly; Clean with water rinse.Can repeatedly 1-2 time, to reach described clean and anti-dandruff effect.
Removing scurf and relieving itching performance and smooth easy Carding Degree detect the mode taking volunteer's sensory evaluation, and volunteer all exists dandruff and scalp and to scratch where it itches problem, asks nine groups of people, often organizes ten people, be 30cm ± 5cm and put into long hair.Sensory evaluation shampoo washing hair removing scurf and relieving itching effect and with after smooth easy Carding Degree, wherein anti-dandruff effect is marked according to the number of dandruff and size, antipruritic effect is that the degree of time and the head pruritus started according to head pruritus is marked, smoothness be naturally stretch out again after artificially tiing a knot according to hair needed for time length give a mark, dried easy Carding Degree carries out giving a mark according to the combing difficulty or ease situation of hair after drying.Evaluation cycle is 4 weeks, and evaluate employing 5 points system, 5 are divided into best result, and 1 is divided into minimum point, and mark is higher, and to represent effect better.The Analyses Methods for Sensory Evaluation Results of formulation Example sees the following form:
As can be seen from the Analyses Methods for Sensory Evaluation Results of formulation Example, larger change can be there is in the result satisfaction of each evaluation index because the proportion of composition each in formula is different, when the component in shampoo is formulation Example 9, each sensory evaluation index all can have high satisfaction, what this illustrated that anti-dandruff shampoo composition of the present invention can be effective reaches anti-dandruff object, and solve that the hair that usual anti-dandruff shampoo causes is withered simultaneously, the problem such as difficult combing, scalp are scratched where it itches.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.
Claims (8)
1. an anti-dandruff shampoo composition, it is characterized in that, the constituent mass percentage ratio of described compositions is: anion surfactant 5-30%, amphoteric surfactant 2-20%, anti-dandruff agent 0.1-2%, conditioner 2-12%, pearling agent 0.3-3%, sensitizer 0.01-5%, water surplus, wherein said anti-dandruff agent is α-R base-γ-methylene-gamma butyrolactone, and structural formula is:
, in formula, R is the positive acrylic of 1-or positive propinyl.
2. anti-dandruff shampoo composition according to claim 1, it is characterized in that, the constituent mass percentage ratio of described compositions is: anion surfactant 10-25%, amphoteric surfactant 2-5%, anti-dandruff agent 0.1-1%, conditioner 2-5%, pearling agent 0.5-3%, sensitizer 0.2-0.8%, water surplus.
3. anti-dandruff shampoo composition according to claim 1 and 2, it is characterized in that, the component of described anti-dandruff shampoo composition also comprises viscosity modifier that mass percent is 0.2-5%, chelating agen, pH adjusting agent, pigment and spice that mass percent is 0.02-0.3%.
4. anti-dandruff shampoo composition according to claim 1, it is characterized in that, described anion surfactant is one or more mixture in fatty alcohol sulphuric acid sodium salt or ammonium salt, polyoxyethylenated alcohol sodium sulfate salt or ammonium salt, and described amphoteric surfactant is one or both in cocamido propyl betaine, lauryl both sexes sodium acetate.
5. anti-dandruff shampoo composition according to claim 4, is characterized in that, described anion surfactant is one or both in lauryl alcohol sulfuric ester ammonium or laureth sulfuric ester ammonium.
6. anti-dandruff shampoo composition according to claim 1, it is characterized in that, described conditioner is the compositions of cation polyquaternary ammonium salt and polydimethylsiloxane, described pearling agent is one in ethylene glycol stearate monoesters and dibasic acid esters or its mixture, and described sensitizer is the compositions of menthol and Camphora.
7. anti-dandruff shampoo composition according to claim 3, it is characterized in that, described viscosity modifier is one or more mixture in sodium chloride, ammonium chloride, sodium sulfate, ammonium sulfate, polyglycol distearate, polyethylene glycol mono stearate, carboxymethyl cellulose, carboxyethyl cellulose, carboxy-propyl cellulose, Polyethylene Glycol, polyvinylpyrrolidone.
8. anti-dandruff shampoo composition according to claim 3, it is characterized in that, described chelating agen is one or more mixture in disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, ascorbic acid, and described pH adjusting agent is one or both in citric acid, phosphoric acid.
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CN104739718B (en) * | 2015-03-05 | 2017-09-15 | 江苏隆力奇生物科技股份有限公司 | One kind is without silicone oil shampoo composite |
CN105267060A (en) * | 2015-11-20 | 2016-01-27 | 扬州中福生物技术有限公司 | Silver-based anti-dandruff shampoo and preparation method thereof |
CN106726991A (en) * | 2016-12-29 | 2017-05-31 | 日昇昌科技有限公司 | A kind of baobab fruit oil wash shampoo and preparation method thereof |
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CN101214201B (en) * | 2008-01-08 | 2011-02-23 | 广东拉芳日化有限公司 | Nourishing anti-dandruff shampoo composition |
CN101601667A (en) * | 2009-05-25 | 2009-12-16 | 陈觉非 | Protoanemonin skin-cleansing fluid |
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Effective date of registration: 20201104 Address after: Beside Taojing Road, Xinzhuang section, 227 provincial road, Changshu City, Suzhou City, Jiangsu Province Patentee after: Carlyle Cosmetics Co., Ltd Patentee after: TSINGHUA University Address before: 215500 long nilfisk bio Industrial Park, Suzhou, Jiangsu, Changshu Patentee before: JIANGSU LONGRICH BIOTECH Co.,Ltd. Patentee before: TSINGHUA University |