CN107997974A - Contain a kind of detergent composition of polyol - Google Patents

Contain a kind of detergent composition of polyol Download PDF

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Publication number
CN107997974A
CN107997974A CN201711260326.8A CN201711260326A CN107997974A CN 107997974 A CN107997974 A CN 107997974A CN 201711260326 A CN201711260326 A CN 201711260326A CN 107997974 A CN107997974 A CN 107997974A
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China
Prior art keywords
acid
detergent composition
polyol
peg
alkyl
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CN201711260326.8A
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Chinese (zh)
Inventor
吴海龙
雷秋芬
李泽勇
汤仲标
户献雷
郭守彬
张利萍
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Guangzhou Tinci Materials Technology Co Ltd
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Guangzhou Tinci Materials Technology Co Ltd
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Application filed by Guangzhou Tinci Materials Technology Co Ltd filed Critical Guangzhou Tinci Materials Technology Co Ltd
Priority to CN201711260326.8A priority Critical patent/CN107997974A/en
Publication of CN107997974A publication Critical patent/CN107997974A/en
Priority to PCT/CN2018/116731 priority patent/WO2019109804A1/en
Pending legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/006—Antidandruff preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0073—Anticorrosion compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers
    • A61K2800/524—Preservatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
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Abstract

The present invention relates to a kind of detergent composition, including following component：(a) surfactant of composition quality fraction 3 50% is accounted for；(b) function additive of composition quality fraction 0.01 10% is accounted for；(c) polyol of composition quality fraction 0.1 25% is accounted for；(d) solvent of composition quality fraction 40 96% is accounted for；Wherein polyol has such as lower structure

Description

Contain a kind of detergent composition of polyol
Technical field
The present invention relates to household chemicals technical field, more particularly to the detergent group containing a kind of polyol Compound.
Background technology
Cleaning compositions reach the necessary shelf-life, it is necessary to use preservative to prevent microbial reproduction at present.Additionally The irritation of cleaning compositions can be improved by adding existing preservative, and reduction uses mildness.Currently used existing preservative has Parabens, Kathon CG, DMDM hydantoin etc..
The shortcomings that this kind of common existing preservative, has：It is formulated more restricting condition for use, the irritation of increase product, increase , there is accumulation harmfulness, pathogenic, carcinogenicity in user's allergy risk.
There is the detergent composition of sterilization at present, to reach its function, it is necessary to use extra existing fungicide. Requirement of the extra fungicide except proposing higher to the compound property of washing formula, can also improve the stimulation of cleaning compositions Property, reduction uses mildness.Currently used existing capability fungicide have zinc pyrithione, climbazole, piroctone olamine salt, Ketoconazole, Climbazole or hexamidine two (isethionic acid) salt, parachlorometaxylenol (PCMX), chlorhexidine, Benzalkonium chloride etc..
Patent CN201180066751.8 uses zinc pyrithione class material to need to be formulated as sterilization anti-dandruff agent, the anti-dandruff agent With suspending power, and formula cannot be made pellucidity.
Patent CN201210377379.9 uses Chinese traditional medicine composition extract multiple as sterilization anti-dandruff agent, anti-dandruff agent production Miscellaneous, ingredient stability control requires high, shampoo formula stability difficulty height.
Patent CN201210404271.4 uses zinc pyrithione or climbazole as sterilization anti-dandruff agent, zinc pyrithione anti-dandruff agent Need formula that there is suspending power, and formula cannot be made pellucidity；Climbazole anti-dandruff agent smell is big, is formulated irritation By force.
The shortcomings that this kind of common existing capability fungicide, has：Be formulated restricting condition for use it is more, increase product irritation, , there is accumulation harmfulness, pathogenic, carcinogenicity in increase user allergy risk.
The content of the invention
Based on this, the object of the present invention is to provide a kind of detergent composition containing polyol, the polyhydroxy Compound provides anti-corrosion, function sterilization, conditioning, the ability of moisturizing at the same time.
Specific technical solution is as follows：
A kind of detergent composition, including following component：
(a) surfactant of composition quality fraction 3-50% is accounted for；
(b) function additive of composition quality fraction 0.01-10% is accounted for；
(c) polyol of composition quality fraction 0.1-25% is accounted for；
(d) account for the solvent of composition quality fraction 40-96% (summation of above constituent content is 100%).
In wherein some embodiments, the polyol structure is as follows：
Wherein R1Optionally from C6-C20Alkylamide propyl, C6-C20Alkylamide ethyl, C6-C20Alkyl acyl-oxygen second Base, C6-C20Alkyl monomethacryloxypropyl, C6-C20Alkyl acyl-oxygen isopropyl or H (OCH2CH2)n-, 2≤n≤20；R2、R3Appoint respectively Selected from ethoxy, C1-C20Alkyl, C6-C20Alkylamide propyl, C6-C20Alkylamide ethyl, C6-C20Alkyl acyl Oxygen ethyl, C6-C20Alkyl monomethacryloxypropyl, C6-C20Alkyl acyl-oxygen isopropyl or H (OCH2CH2)m-, 2≤m≤20, R4For- OCH2CH(OH)CH2(OH), X is Cl or Br.
In wherein some embodiments, the surfactant is selected from：
(a) anion surfactant, ammonium lauryl sulfate, laureth ammonium sulfate, lauryl sulfate Triethylamine, laureth monoethanolamine, sodium alkyl benzene sulfonate, alkyl benzene sulphonate ammonium, fatty ylmethyl ox Sodium sulfonate, triethanolamine lauryl sulfate, laureth sulfuric acid triethanolamine, lauryl sulfate monoethanolamine, the moon Osmanthus base polyoxyethylene ether diethanolamine, lauryl sulfate diethanolamine, laureth sulfate, the moon Osmanthus monoglyceride sodium sulfate, NaLS, sodium laureth sulfate, aliphatic acid, lauryl potassium sulfate, the moon Osmanthus base polyoxyethylene ether potassium sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosine, lauryl sarcosinate, fatty alcohol glycerin ether Sulfonate, cocoyl sarcosine, cocoyl ammonium sulfate, dodecane acyl group ammonium sulfate, sodium cocosulfate, fatty alcohol ether carboxylic acid Salt, lauroyl sodium sulfate, cocoyl potassium sulfate, lauryl potassium sulfate, triethanolamine lauryl sulfate, three ethanol of lauryl sulfate Amine, cocoyl diethanolamine, lauryl sulfate monoethanolamine, above-mentioned sulfate radical, isethionic acid root, sulfonate radical, sulfo group Beyond amber acid radical, available for other possible anion in anion surfactant further include phosphonate radical, phosphate radical and Carboxylate radical；
(b) amphoteric surfactant, cocoyl alanine sodium, cocoyl lauriminodipropionate, cocounut oil acyl both sexes base second Sour sodium, cocounut oil acyl both sexes base hydroxypropyl azochlorosulfonate acid sodium, cocounut oil acyl both sexes base sodium propionate, corn oleoyl both sexes base sodium propionate, bay ammonia Base sodium propionate, Sodium Lauroamphoacetate, lauroyl both sexes base hydroxypropyl azochlorosulfonate acid sodium, lauroyl both sexes base sodium propionate, corn Oleoyl both sexes base sodium propionate, bay dipropionic acid sodium, cocoyl alanine ammonium, cocoyl amino dipropionic acid ammonium, cocounut oil Acyl both sexes guanidine-acetic acid ammonium, cocounut oil acyl both sexes base hydroxypropyl sulfonic acid ammonium, cocounut oil acyl both sexes base propionic acid ammonium, corn oleoyl both sexes base propionic acid Ammonium, laurylamino-propionic acid ammonium, lauroyl both sexes guanidine-acetic acid ammonium, lauroyl both sexes base hydroxypropyl sulfonic acid ammonium, lauroyl both sexes base third Sour ammonium, corn oleoyl both sexes base propionic acid ammonium, bay dipropionic acid ammonium, cocoyl alanine triethanolamine, cocoyl ammonia Base dipropionic acid triethanolamine, cocoamphoacetate triethanolamine, cocounut oil acyl both sexes base hydroxypropyl sulfonic acid triethanolamine, cocounut oil Acyl both sexes base propionic acid triethanolamine, corn oleoyl both sexes base propionic acid triethanolamine, laurylamino-propionic acid triethanolamine, lauroyl two Property guanidine-acetic acid triethanolamine, lauroyl both sexes base hydroxypropyl sulfonic acid triethanolamine, lauroyl both sexes base propionic acid triethanolamine, corn Oleoyl both sexes base propionic acid triethanolamine, bay dipropionic acid triethanolamine, cocounut oil acyl both sexes base dipropionic acid, caprinoyl both sexes base Diethyl acid disodium, caprinoyl both sexes base disodium beclomethasone, decoyl both sexes base diethyl acid disodium, decoyl both sexes base disodium beclomethasone, coconut palm Oleoyl both sexes base carboxyethyl hydroxypropyl sulfonic acid disodium, cocounut oil acyl both sexes base diethyl acid disodium, cocounut oil acyl both sexes base disodium beclomethasone, Two carboxyethyl cocoyl propane diamine disodiums, the carboxyl both sexes base diethyl of laureth -5 acid disodium, bay imino-diacetic Propionic acid disodium, lauroyl both sexes base diethyl acid disodium, lauroyl both sexes base disodium beclomethasone, oil base both sexes base disodium beclomethasone, - 7 carboxyl both sexes base diethyl acid disodium of PPG-2- isodecanols polyethers, lauryl amino propionic acid, lauroyl both sexes base dipropionic acid, bay The sub- second diaminourea glycine of base aminopropyl glycine, lauryl two, cocounut oil acyl both sexes base sodium diacelate, lauroyl both sexes base diethyl Sour sodium, cocoamidoethyl betaines, Cocamidopropyl amine oxide, cocamidopropyl betaine, coconut oleoyl amine Base propyl-dimethyl amino hydroxypropyl hydrolytic collagen, acylamidopropyldimethyl ammonium hydroxypropyl hydrolytic collagen, coconut oleoyl amine Base hydroxysultaine, coco betaine amide groups both sexes base propionate, coco betaine, cocoyl weight ratio Glycine betaine, cocoyl/oil base amido propyl betaine, cocoyl sulfobetaines, lauroyl amido propyl betaine, lauryl Glycine betaine, lauryl hydroxyl sulfo betaine, lauryl sulfobetaines, cocoyl sulfobetaines；
(c) nonionic surfactant, coconut oleoyl amine, coconut oleoyl amine methyl MEA, coconut oleoyl amine DEA, coconut oleoyl amine MEA, Coconut oleoyl amine MIPA, lauramide DEA, lauramide MEA, lauramide MIPA, myristamide DEA, myristamide MEA, PEG-20 coconut oleoyl amine MEA, PEG-2 coconut oleoyl amine, PEG-3 coconut oleoyl amines, PEG-4 coconut oleoyl amines, PEG-5 coconut oleoyl amines, PEG-6 coconut oleoyl amines, PEG-7 coconut oleoyl amines, PEG-3 lauramides, PEG-5 lauramides, PEG-3 oleamides, PPG-2 cocounut oil Acid amides, PPG-2 hydroxyethyl cocamides, fatty alcohol polyoxyethylene ether, fatty alcohol, alkyl glycosides；
(d) cationic surfactant, alkyl trimethyl ammonium chloride, alkyl trimethyl ammonium bromide, alkyl trimethyl sulfuric acid Methyl esters, alkyl dimethyl ethyl-sulfate ammonium, fatty amide propyl trimethyl ammonium chloride, fatty amide propyl trimethyl bromination Ammonium, fatty amide propyl trimethyl sulfate methyl ammonium, fatty amide propyl dimethyl ethyl ethyl-sulfate ammonium, alkyl dihydroxy ethyl Ammonio methacrylate, alkyl dihydroxy ethyl methyl bromide ammonium, alkyl dihydroxy ethyl methylsulfuric acid ammonium methyl, alkyl dihydroxy ethyl ethyl Ethyl-sulfate ammonium, fatty amide propyl dihydroxy ethyl ammonio methacrylate, fatty amide propyl dihydroxy ethyl methyl bromide ammonium, fat Amido propyl dihydroxy ethyl methylsulfuric acid ammonium methyl, fatty amide propyl dihydroxy ethyl ethyl sulfuric acid ethyl ester ammonium, fatty acid amide second Base trimethyl ammonium chloride, fatty acid amide ethyMmethylammonium bromide, fatty acid amide ethyl-trimethyl sulfate methyl ammonium, fatty acid amide Ethyl dimethyl ethyl ethyl-sulfate ammonium, fatty acid amide ethyl dihydroxy ethyl ammonio methacrylate, fatty acid amide ethyl dihydroxy ethyl Methyl bromide ammonium, fatty acid amide ethyl dihydroxy ethyl methylsulfuric acid ammonium methyl, fatty acid amide ethyl dihydroxy ethyl ethyl sulfuric acid second It is one or more of in ester ammonium.
In wherein some embodiments, the function additive is selected from vitamin, chelating agent, spices, brightening agent, enzyme, conditioning One or more in agent, thickener, attractant, dyestuff, pigment, bleaching agent and pearling agent.
In wherein some embodiments, the solvent is in water, ethanol, glycerine, propane diols, polyethylene glycol, isopropanol It is one or more of.
In wherein some embodiments, the chelating agent is selected from：Ethylenediamine tetra-acetic acid, aminotriacetic acid, diethylidene Pentaacetic acid and its salt, citric acid, tartaric acid and gluconic acid, hydroxyethylethylene diamine tri-acetic acid, bicine N-, have It is a kind of in machine polyphosphonic acid, polyacrylic acid, polymethylacrylic acid, hydrolysis of polymaleic anhydride or fumaric acid-propene sulfonic acid copolymer It is or several.
In wherein some embodiments, the conditioner is selected from：The non-guar gum of cationic guar polymer, cation half Newborn mannosan polymer, cationic modified starch polymer, acrylamide monomer and cationic monomer cation copolymer, It is one or more of in cationic cellulose polymer, polysiloxanes or cationic cassia xanthan polymer.
In wherein some embodiments, the thickener is selected from：Modified hydroxyethyl cellulose, the polypropylene of hydrophobically modified Acid esters, the polyacrylic acid of hydrophobically modified, the polyacrylamide of hydrophobically modified, PEG-120 methyl glucose dioleates, PEG-40 Four oleate of sorbitan, four oleate of PEG-60 sorbitans, PEG-150 pentaerythritol tetrastearates, It is one or more of in PEG-55 propylene glycol oleates or PEG-150 distearates.
In wherein some embodiments, the pearling agent is selected from：Stearic acid diethylene glycol dilaurate, stearic acid ethylene glycol ester Middle one or two.
Said detergent composition uses the polyol, has corrosion-resistant effect, existing anti-without additionally adding Rotten agent, cleaning compositions irritation is low, and mildness is high；Said detergent composition uses the polyol, can be effective Killing chlosma, propionibacterium acnes, detergent composition has anti-dandruff, anti-acne effect；Said detergent composition Using the polyol, detergent composition has the function of conditioning, moisturizing at the same time.
Brief description of the drawings
Fig. 1 is embodiment 1 and 1 volunteer of comparative example hair washing test result.
Embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.But the present invention can be with perhaps More different form is realized, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make Understanding more thorough and comprehensive to the disclosure.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention The normally understood implication of technical staff is identical.Term used in the description of the invention herein is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein "and/or" includes one or more phases The arbitrary and all combination of the Listed Items of pass.
Embodiment 1
It is prepared by the present embodiment, the detergent composition containing a kind of polyol：
(1) recipe ingredient
(2) Recipe
A, it is A heat phase stirring and dissolvings is uniform.
B, after A phased solns are uniform, addition B phases continue heating stirring and are uniformly dissolved.
C, after B phased solns are uniform, room temperature is cooled to, C phases is added, stirs evenly.
Embodiment 2
It is prepared by the present embodiment, the detergent composition containing a kind of polyol：
(1) recipe ingredient
(2) Recipe
A, it is A heat phase stirring and dissolvings is uniform.
B, after A phased solns are uniform, addition B phases continue heating stirring and are uniformly dissolved.
C, after B phased solns are uniform, room temperature is cooled to, C phases is added, stirs evenly.
Embodiment 3
It is prepared by the present embodiment, the detergent composition containing a kind of polyol：
(1) recipe ingredient
(2) Recipe
A, it is A heat phase stirring and dissolvings is uniform.
B, after A phased solns are uniform, addition B phases continue heating stirring and are uniformly dissolved.
C, after B phased solns are uniform, room temperature is cooled to, C phases is added, stirs evenly.
Embodiment 4
It is prepared by the present embodiment, the detergent composition containing a kind of polyol：
(1) recipe ingredient
(2) Recipe
A, it is A heat phase stirring and dissolvings is uniform.
B, after A phased solns are uniform, addition B phases continue heating stirring and are uniformly dissolved.
C, after B phased solns are uniform, room temperature is cooled to, C phases is added, stirs evenly.
Embodiment 5
It is prepared by the present embodiment, the detergent composition containing a kind of polyol：
(1) recipe ingredient
(2) Recipe
A, it is A heat phase stirring and dissolvings is uniform.
B, after A phased solns are uniform, addition B phases continue heating stirring and are uniformly dissolved.
C, after B phased solns are uniform, room temperature is cooled to, C phases is added, stirs evenly.
Embodiment 6
It is prepared by the present embodiment, the detergent composition containing a kind of polyol：
(1) recipe ingredient
(2) Recipe
A, it is A heat phase stirring and dissolvings is uniform.
B, after A phased solns are uniform, room temperature is cooled to, B phases is added, stirs evenly.
Embodiment 7
It is prepared by the present embodiment, the detergent composition containing a kind of polyol：
(1) recipe ingredient
(2) Recipe
A, it is A heat phase stirring and dissolvings is uniform.
B, after A phased solns are uniform, room temperature is cooled to, B phases is added, stirs evenly.
Embodiment 8
It is prepared by the present embodiment, the detergent composition containing a kind of polyol：
(1) recipe ingredient
(2) Recipe
A, it is A heat phase stirring and dissolvings is uniform.
B, after A phased solns are uniform, room temperature is cooled to, B phases is added, stirs evenly.
Comparative example 1
Difference lies in do not contain polyol compared with Example 1 for 1 formulation of detergent composition of comparative example.Comparative example 1 sees Fig. 1 with 1 volunteer of embodiment hair washing test result.
Volunteer's hair washing test method is as follows：
1:Explanation on probation：Half a head experiment be exactly hair washing when or so half a head wash two kinds of shampoos at the same time, it is same by two hands When impression hair washing when and hair washing after different feeling.
2：Impression point explanation on probation：In corresponding period evaluation corresponding index：
Hair washing flow includes：Smear shampoo, bath, flush with foam, flushing finishes and hair is dried.
After smearing shampoo, foaming abundancy degree is evaluated；The sliding astringent sense of evaluation bath during flush with foam；After flushing Hair soft degree when hair smooth feeling when evaluating wet hair and wet hair；It is smooth feeling hair evaluates dry hair after drying when, dry Soft feeling when moisture feeling during hair and dry hair.
3. combining actual use situation, according to Indexes of Evaluation Effect used below, objective score evaluation is given；
Test evaluation is had one's hair wash as a result, may indicate that moisture feeling, the soft feeling of embodiment 1 from Fig. 1 radar maps by volunteer It is better than comparative example 1, which plays conditioning, moisture-keeping function in cleaning compositions.
Comparative example 2
Difference lies in substituted using Kathon CG (15ppm additive amounts) compared with Example 1 for 2 formulation of detergent composition of comparative example Polyol.
Comparative example 3
Difference lies in use equivalent quaternary ammonium trihydroxy dipropyl ether compared with Example 1 for 3 formulation of detergent composition of comparative example Substitute polyol.
Comparative example 4
Difference lies in use equivalent quaternary ammonium trimethyl dipropyl ether compared with Example 1 for 4 formulation of detergent composition of comparative example Substitute polyol.
Comparative example 5
Difference lies in use equivalent lauryl dimethyl hydroxypropyl compared with Example 1 for 5 formulation of detergent composition of comparative example Base glycerol ether ammonium chloride substitutes polyol.
It is as follows with the preservative efficacy test data that USP32 methods carry out：
1 detergent composition preservative efficacy test comparison of table
2 detergent composition preservative efficacy test comparison of table
Cleaning compositions containing the polyol can be tested by preservative efficacy, such as embodiment 1 and implementation 2 preservative efficacy of example is tested；The substantially equivalent Kathon CG of anti-corrosion effect, is shown in that 2 preservative efficacy of comparative example is tested；Without the polyol Cleaning compositions cannot be tested by preservative efficacy, see 1 preservative efficacy of comparative example test.Trihydroxy dipropyl containing equivalent Ether, quaternary ammonium trimethyl dipropyl ether, the cleaning compositions of lauryl dimethyl hydroxypropyl glycerine ether ammonium chloride cannot pass through preservative Efficacy test, is shown in comparative example 3, comparative example 4 and the test of 5 preservative efficacy of comparative example.The polyol is in cleaning compositions Play the role of preservative.
Comparative example 6
Difference lies in use piroctone olamine salt compared with Example 1 for 6 formulation of detergent composition of comparative example (0.9% additive amount) substitutes polyol.
The Malassezia furfur carried out in QB/T2738-2012 (7.3) method is sterilized, bacteriostasis property test data is as follows：
The sterilization of 3 Malassezia furfur of table, antibacterial test comparison
Cleaning compositions containing the polyol can be tested by Malassezia furfur bactericidal property, such as be implemented Example 1 and the sterilization of 5 Malassezia furfur of embodiment, bacteriostasis property test；Bactericidal effect>99%, it is essentially identical to piroctone second Hydramine, is shown in the sterilization of 6 Malassezia furfur of comparative example, bacteriostasis property test；Cleaning compositions without the polyol are not It can be sterilized by Malassezia furfur, bacteriostasis property test, see the sterilization of 1 Malassezia furfur of comparative example, bacteriostasis property test.Contain There are the trihydroxy dipropyl ether, quaternary ammonium trimethyl dipropyl ether, the washing group of lauryl dimethyl hydroxypropyl glycerine ether ammonium chloride of equivalent Compound cannot be sterilized by Malassezia furfur, bacteriostasis property test, see 5 chaff horse traction of comparative example 3, comparative example 4 and comparative example The sterilization of color bacterium, bacteriostasis property test.The polyol plays Malassezia furfur bactericidal effect in cleaning compositions.
The propionibacterium acnes carried out in QB/T2738-2012 (7.3) method is sterilized, bacteriostasis property test data is as follows：
The sterilization of 4 propionibacterium acnes of table, bacteriostasis property test comparison
Cleaning compositions containing the polyol can be tested by propionibacterium acnes bactericidal property, sterilization effect Fruit>99, such as embodiment 1 and the sterilization of 3 propionibacterium acnes of embodiment, bacteriostasis property test.Washing without the polyol Wash composition and cannot be sterilized by propionibacterium acnes, antibacterial test, see the sterilization of 1 propionibacterium acnes of comparative example, bacteriostasis property Test.Trihydroxy dipropyl ether containing equivalent, quaternary ammonium trimethyl dipropyl ether, lauryl dimethyl hydroxypropyl glycerine ether ammonium chloride Cleaning compositions cannot be sterilized by propionibacterium acnes, bacteriostasis property test, see 5 Cuo of comparative example 3, comparative example 4 and comparative example The sterilization of sore Propionibacterium, bacteriostasis property test.The polyol plays propionibacterium acnes sterilization in cleaning compositions Effect.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, the scope that this specification is recorded all is considered to be.
Embodiment described above only expresses the several embodiments of the present invention, its description is more specific and detailed, but simultaneously Cannot therefore it be construed as limiting the scope of the patent.It should be pointed out that come for those of ordinary skill in the art Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (9)

1. a kind of detergent composition, it is characterised in that including following component：
(a) surfactant of composition quality fraction 3-50% is accounted for；
(b) function additive of composition quality fraction 0.01-10% is accounted for；
(c) polyol of composition quality fraction 0.1-25% is accounted for；
(d) solvent of composition quality fraction 40-96% is accounted for.
2. detergent composition according to claim 1, it is characterised in that the polyol structure is as follows：
Wherein R1Optionally from C6-C20Alkylamide propyl, C6-C20Alkylamide ethyl, C6-C20Alkyl acyloxyethyl, C6-C20Alkyl monomethacryloxypropyl, C6-C20Alkyl acyl-oxygen isopropyl or H (OCH2CH2)n-, 2≤n≤20；R2、R3It is optional respectively From ethoxy, C1-C20Alkyl, C6-C20Alkylamide propyl, C6-C20Alkylamide ethyl, C6-C20Alkyl acyl-oxygen Ethyl, C6-C20Alkyl monomethacryloxypropyl, C6-C20Alkyl acyl-oxygen isopropyl or H (OCH2CH2)m-, 2≤m≤20, R4For- OCH2CH(OH)CH2(OH), X is Cl or Br.
3. detergent composition according to claim 1, it is characterised in that the surfactant is selected from anionic surface One or more in activating agent, amphoteric surfactant, nonionic surfactant or cationic surfactant.
4. detergent composition according to claim 1, it is characterised in that the function additive is selected from vitamin, chelating One kind or several in agent, spices, brightening agent, enzyme, conditioner, thickener, attractant, dyestuff, pigment, bleaching agent and pearling agent Kind.
5. detergent composition according to claim 1, it is characterised in that the solvent is selected from water, ethanol, glycerine, third It is one or more of in glycol, polyethylene glycol, isopropanol.
6. detergent composition according to claim 4, it is characterised in that the chelating agent is selected from：Ethylenediamine tetrem Acid, aminotriacetic acid, diethylene-triamine pentaacetic acid and its salt, citric acid, tartaric acid and gluconic acid, hydroxyethyl ethylenediamine three Acetic acid, bicine N-, organic multicomponent phosphonic acids, polyacrylic acid, polymethylacrylic acid, hydrolysis of polymaleic anhydride or rich horse It is one or more of in acid-propene sulfonic acid copolymer.
7. detergent composition according to claim 4, it is characterised in that the conditioner is selected from：Cation guar gum The non-guar gum galactomannan polymer of polymer, cation, cationic modified starch polymer, acrylamide monomer and sun It is one or more of in the copolymer of ion monomer, cationic cellulose polymer, polysiloxanes or cationic cassia xanthan polymer.
8. detergent composition according to claim 4, it is characterised in that the thickener is selected from：Modified ethoxy Cellulose, the polyacrylate of hydrophobically modified, the polyacrylic acid of hydrophobically modified, the polyacrylamide of hydrophobically modified, PEG-120 first Base glucose dioleates, four oleate of PEG-40 sorbitans, four oleate of PEG-60 sorbitans, PEG- It is one or more of in 150 pentaerythritol tetrastearates, PEG-55 propylene glycol oleates or PEG-150 distearates.
9. detergent composition according to claim 4, it is characterised in that the pearling agent is selected from：Stearic acid second two It is one or two kinds of in alcohol dibasic acid esters, stearic acid ethylene glycol ester.
CN201711260326.8A 2017-12-04 2017-12-04 Contain a kind of detergent composition of polyol Pending CN107997974A (en)

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Application publication date: 20180508