CN102920619B - Conditioning shampoo composition containing small amount of sulfate anionic surfactant - Google Patents
Conditioning shampoo composition containing small amount of sulfate anionic surfactant Download PDFInfo
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- CN102920619B CN102920619B CN201210379971.2A CN201210379971A CN102920619B CN 102920619 B CN102920619 B CN 102920619B CN 201210379971 A CN201210379971 A CN 201210379971A CN 102920619 B CN102920619 B CN 102920619B
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Abstract
The invention belongs to the field of daily use chemicals, and particularly relates to a shampoo composition containing a small amount of sulfate anionic surfactant. The shampoo composition comprises the following components: a sulfate-containing anionic surfactant which accounts for 5-25 percent by weight of the composition and cocoalkanoylamido propyl betaine which accounts for 1.0-15.0 percent by weight of the composition; b, a nonionic alkyl glycoside surfactant which accounts for 7.0-20.0 percent by weight of the composition; c, an acrylamidepropyltrimethylammonium chloride/acrylamide copolymer which accounts for 0.01-0.20 percent by weight of the composition; d, a cation guar gum polymer which accounts for 0.01-1.0 percent by weight of the composition; and e, a small amount of common shampoo additive and the balance of water. The composition is a safe and mild composition with conditioning and cleaning effects. The composition disclosed by the invention contains rich foam, has a high conditioning performance, can be particularly easy for dry and wet combing, softening and brightening, is safer for hair nursing, and is free from heavy and sticky feel after use.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of shampoo composite that contains a small amount of sulfate type anion surfactant.
Background technology
All the time, the surfactant that shampoo and bath gel product composition are used is often based on anion, nonionic or amphion type, and with sulfate type anion surfactant as AES, AESA, K12, K12A etc. are first type surface activating agent.The shampoo that the anion of take is master or bath gel before use, first drench hair or skin, then get appropriate said composition and get foam on hair or skin, thereby final rinse water is removed the dirt on hair or skin.
Although above mentioned shampoo has good foam and cleaning capacity, but also there is a very large shortcoming to be exactly, nursing efficacy to hair and skin is poor, be shampoo or the bath gel of contained sulfate type anion surfactant, through human body life-time service, more or less can produce a little injury to hair horny layer and skin, as constantly peeling off of hair or the natural lipid layer of skin surface or protein, and the hair of the attested shampoo that contains sulfate type anion surfactant after can especially dying hair produces the ill effect of fading.In addition, " the dioxanes disturbance " occurring in recent years, also as direct in remaining of dioxanes in AES associated with sulfated surfactant.
At present, external shampoo is praised highly and is not contained or also confirmed above saying containing the technology (Sulfate-free) of a small amount of sulfate.First, not containing sulfate and mean that not containing sulfate type anion surfactant is as AES in shampoo, do not contain or contain residual volume that a small amount of AES means dioxanes in shampoo still less, is even zero.Therefore, shampoo will be safer in a sense; In addition, due to not containing or containing a small amount of sulfate, also can avoid the risk that produces damage and fade because of the hair of sulfate after hair is especially had hair dyed.
Therefore, in order to evade security risks, improve the defect that contains sulfate type anion surfactant product and improve hair because of hair-waving simultaneously, rinsing, hair damage, the fragility that hair dyeing etc. causes and the phenomenon of fading, first, in shampoo composite, research reduces the consumption of sulfate type anion surface active, and increases hair and scalp is gentleer and cleaning effect is good surfactant; In addition, hair conditioner is mainly used in maintenance or reduces the impaired many unfavorable factors of hair.These conditioners are as cationic polymer, and the derivant of silicone oil or silicone oil etc. can play the effect of protection hair, as strengthen dry wet carding property, reduce and are wound around and knotting, and the performance such as submissive is provided.Yet, although along with the development of modern science and technology makes cationic polymer mentioned above, silicone oil etc. play certain maintenance effect and constantly improve in personal cleanliness's articles for use compositions, but up to the present still can not fundamentally obtain satisfied effect, therefore, still there is a kind of strong cry in actual life or aspect, market, and hope can have a product than above-mentioned better effects if to occur.Although market product also has by Vegetable oil lipoprotein and improves conditioning performance etc., but still the effect that can not obtain, phenomenon as greasy in hair, foam is not good, and clean power weakens etc.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of sulfate type anion surfactant that contains less amount and has soft and smooth conditioning and enrich the shampoo of foam.
The object of the present invention is achieved like this, and a kind of conditioning shampoo composition, comprises:
A) account for the anion surfactant that contains sulfate and the cocamido propyl betaine that accounts for composition weight 1.0%-15.0% of composition weight 5%-25%, the described anion surfactant that contains sulfate is selected from aliphatic alcohol sulfate and fatty alcohol polyoxyethylene ether sulfate compositions, and the weight ratio of aliphatic alcohol sulfate and fatty alcohol polyoxyethylene ether sulfate is 1:2;
B) account for the nonionic alkyl glycoside type surfactant of composition weight 7.0% to 20.0%;
C) account for the acrylamide propyl trimethyl ammonium chloride/acrylamide copolymer of composition weight 0.01% to 0.20%;
D) account for the cation guar gum polymer of composition weight 0.01% to 1.0%;
E) a small amount of shampoo typical additives and the water of surplus.
Wherein sulphate anion surface active agent active matter and nonionic alkyl glycoside surfactant activity thing weight ratio are 1:1.5 to 2.5:1.
Nonionic alkyl glycoside surfactant is selected from the compound with following logical formula I:
R
1—O—(R
2O)
t-(G)
v （Ⅰ）
Wherein, R
1be selected from saturatedly or unsaturated, the carbon number of linearity or side chain is between 8 to 24 carbochain;
R
2be selected from the alkene that contains 2 to 4 carbon atoms;
G is selected from the reducing sugar that comprises 5 to 6 carbon atoms;
The span of t is 0 to 10;
The span of v is 1 to 15.
In the present invention, sulphate anion surface active agent active matter and nonionic alkyl glycoside (APG) surfactant activity thing weight ratio is 1:1.2 to 2:1.
In the present invention, nonionic alkyl glycoside surfactant is selected from the compound with following logical formula I: R
1-O-(R
2o)
t-(G)
v(I)
Wherein, R
1be selected from saturatedly or unsaturated, the carbon number of linearity or side chain is between 8 to 24 carbochain;
G is selected from the reducing sugar that comprises 5 to 6 carbon atoms;
The span of t is 0 to 10;
The span of v is 1 to 15.
Formula I R is led in the present invention
1be selected from saturated, linear carbon number between 8 to 14 alkane, t is that 0, G is glucose, and v span is 1 to 4.
The optimal proportion of each component of shampoo composite of the present invention is: contain 11.4% alkyl polyglucoside, 2.7% ammonium lauryl sulfate, 5.4% lauryl alcohol ammonium sulfate, 8.0% cocamido propyl betaine, acrylamide propyl trimethyl ammonium chloride/acrylamide copolymer of 0.01%, 0.3% guar hydroxypropyltrimonium chloride, 0.8% coconut monoethanol amide, 1.2% pearlescent flake, antiseptic and sodium chloride are appropriate, deionized water is surplus, finally pH value is adjusted to 5.5, and the ratio that each constituent content accounts for compositions by weight.The present invention is by reducing the consumption of a large amount of sulfate type anion surfactants that use in the existing shampoo of shampoo, select a kind of non-ionic surface active agent and a kind of macromolecule conditioning polymer of alkyl polyglucoside class, just can realize and can contain a small amount of sulfate type anion surfactant, there is again good foaming properties and can be easy to dry wet combing, softness, light and can not use after have the shampoo composite of heavy and sticky sensation.The present composition has significant effect to hair nursing.Therefore, compositions of the present invention is a kind of safety, mildness is good, and thering is conditioning and the compositions of cleaning effect, compositions foam of the present invention enrich and has good conditioning performance, especially can be easy to do the combing of wetting, soft, light, safer to the nursing of hair, and have heavy and sticky sensation after can not using.
Below in conjunction with embodiment, the present invention is described in further detail:
A very important technical characterictic of the present invention is: compare with traditional shampoo, the sulfate type anion surfactant that contains less amount also has soft and smooth conditioning and more rich foam.In the present invention, in sulphate anion surface active agent, the weight ratio scope of aliphatic alcohol sulfate and fatty alcohol polyoxyethylene ether sulfate is 1:2; Described sulphate anion surface active agent active matter and nonionic alkyl glycoside surfactant activity thing weight ratio are: 1:1.5 to 2.5:1.
Nonvolatile vegetable oil that can choice for use in the present invention is water-insoluble hydrogenated vegetable oil.Conventionally these vegetable oil do not contain glycerine monofatty ester or double glyceride, if contained, its percentage by weight is no more than 2% of the own weight of vegetable oil.
Non-volatile vegetable oil in the present invention, its boiling temperature is greater than 300 degrees Celsius (under 760 millimetress of mercury), can not present a kind of very low vapour pressure scope.Yet quintessence oil is ethereal oil, within being not included in scope of the present invention.
Vegetable oil in the present invention is selected from safflower oil, American Avocado Tree oil, Jojoba oil, Semen Maydis oil, Semen pruni armeniacae oil, soybean oil, Fructus Cucumidis sativi oil, Oleum Vitis viniferae, Oleum sesami, hazelnut oil, Petiolus Trachycarpi oil, Semen Ricini wet goods.In the present invention, preferably use the oil of dicotyledon, as American Avocado Tree oil and Jojoba oil.
The sulfate type anion surfactant using in the present invention is selected from alkyl sulfate, alkyl ether sulfate, alkyl amino ether sulfate, alkyl aryl ether sulfate, alkyl ether thio succinate.The salt adopting is alkali metal salt, ammonium salt, amine salt, ethylaminoethanol salt, magnesium salt.Wherein alkali metal salt tends to use sodium salt and ammonium salt, and the length of alkyl carbon chain is conventionally between 8-24, and between the common 2-50 of the number of oxirane or expoxy propane, the one-step optimization of going forward side by side is between 2-10.
In the present invention, sulphate anion surface active agent is selected from the compositions of alkyl sulfate and alkyl ether sulfate, and alkyl carbon chain is C
8to C
14, be further optimized for C
12to C
14alkyl ether sulfate.
In the present invention, sulphate anion surface active agent is selected from the compositions of alkylsurfuric acid ammonium and alkyl ether ammonium sulfate, and alkyl carbon chain is C
8to C
14, be further optimized for C
12to C
14alkyl ether sulfate.
On above sulfate aliphatic chain the quantity of oxirane be in 2-5. the present invention in preferred alkyl ether sulfate the molal quantity of oxirane be average 2.2
It is 1% to 30% that sulfate type anion surfactant of the present invention accounts for composition weight percentage ratio.
The non-ionic surface active agent of the alkyl polyglucoside using in the present invention (APG) type is the known on the market gentle surfactant of a class, its chemical formula general formula following (1):
R
1—O—(R
2O)
t-(G)
v
Wherein:
R
1be selected from linear and side chain, saturated or undersaturated, approximately carbon chain lengths is the carbochain of 8 to 24 carbon atoms, and is selected from linear and side chain, and carbon chain lengths is the alkylbenzene of 8 to 24 carbon atoms;
R
2be selected from the alkene that contains 2 to 4 carbon atoms;
G is selected from the reducing sugar that has 5 to 6 carbon atoms;
T is between 0 to 10;
V is between 1 to 15.
The preferred alkyl polyglucoside of the present invention is the compound that meets chemical general formula (1), wherein R
1be selected from linearity, saturated, carbon chain lengths is the alkane of 8 to 14 carbon atoms; T, between 0 to 3, is 0 in the present invention; G is selected from glucose, fructose and galactose, the preferred glucose of the present invention.In general formula (1), the degree of polymerization V-value of glucose is between 1 to 15.According to the present invention, the more than percent 80 sugared degree of polymerization is controlled between 1 to 4, and average degree of polymerization is controlled between 1 to 2.
The compound that meets general formula (1), its representative product is as the alkyl polyglucoside APG of commercially available BASF (BASF), as, APG300, APG350, APG500, APG550, APG625, APG810, APG818, APG1200, APG2000,
The APG1200 that nonionic alkyl glycoside surfactant of the present invention is preferably used BASF AG to produce is that Plantacare1200UP or Plantacare2000UP.Plantacare1200UP are a kind of C of muddy thickness
12-14the aqueous solution of polysaccharide glycosides, active matter 50%, pH value (20% at 15% isopropyl alcohol) 11.5-12.5; Viscosity (40 ℃) 1000-6000mPas, density (40 ℃) 1.07-1.08g/cm
3, the about 420g/mol of molecular weight, free alkyl alcohol≤1%; Plantacare2000UP is a kind of C of muddy thickness
8-14the aqueous solution of polysaccharide glycosides, active matter 50%, pH value (20% at 15% isopropyl alcohol) 11.5-12.5; Viscosity (40 ℃) 2000-4000mPas, density (40 ℃) 1.07-1.08g/cm
3, the about 390g/mol of molecular weight, free alkyl alcohol≤1%.
It is 2% to 25% that nonionic alkyl glycoside surfactant of the present invention accounts for composition weight percentage ratio.
The present invention also includes the surfactant of amphoteric type, amphoteric surfactant is selected from fatty amine, the derivant of secondary amine and tertiary amine, wherein fat-based be selected from carbon chain lengths be the aliphatic chain of 8 to 18 linearity and side chain and contain at least one hydrophilic anionic group (as carboxylate, sulfonate, sulfate, phosphate), for example, amphoteric surfactant, C
8-C
20alkyl betaine, C
8-C
20alkyl sulfo betaines;
Another amphoteric surfactant of the present invention, its structural formula following (II):
R
2—CONHCH
2CH
2—N(R
2)(R
4)(CH
2COO—)
Wherein, R
2be selected from Oleum Cocois alkyl in the fatty acid that obtains after hydrolysis, and heptyl, nonyl, undecyl; R
3beta-hydroxyethyl, R
4it is carboxymethyl
Or structural formula following (III):
R
2`—CONHCH
2CH
2—N(D)(E)
Wherein, D representative-CH
2cH
2oX`, E representative-(CH
2)
z-Y`, Z=1 or 2,
R
2be selected from Oleum Cocois alkyl in the fatty acid that obtains after hydrolysis, and heptyl, nonyl, undecyl; R
3beta-hydroxyethyl, R
4it is carboxymethyl
Be selected from-CH of X`
2cH
2-COOH and H atom,
Be selected from-COOH of Y` and-CH
2-CHOH-SO
3h,
R
2`be selected from the fatty acid that oleum lini and Oleum Cocois obtain after hydrolysis, and alkyl, carbon chain lengths is 7,9,11,13 alkyl, carbon 17 alkyl and isomer thereof and undersaturated carbon 17 alkyl.
Above-described amphoteric surfactant is as, cocoyl both sexes sodium acetate, lauroyl both sexes sodium acetate, and capryl both sexes sodium acetate, cocoyl both sexes sodium propionate, lauroyl both sexes sodium propionate, capryl both sexes sodium propionate etc. all belongs to this category.
The amphoteric surfactant using in the present invention is selected from BASF (BASF) company and produces, its trade name is: DEHYTON ML-CN, the international called after of INCI: cocos nucifera oil acyl both sexes guanidine-acetic acid sodium, color and luster (APHA) is less than or equal to 3.0, solid content (%) 35 ± 2, pH value 9.5-10.5, viscosity≤5000, sodium chloride (%) 5.5-7.5.
According to the present invention, preferentially use non-ionic surface active agent for betanin, as alkyl or cocamido propyl betaine, manufacturer BASF AG, commodity are called Dehyton KET.
Thing combined according to the invention, also may contain anion surfactant and be selected from phosphate, sulfate and carboxylate.These anion surfactants are selected from alkylphosphonic; alkyl sulfate; alkylamide sulfate; alkyl aryl sulfate; a-alkene sulfonate; alkyl sulfo succinate, alkyl ether sulfo succinate, alkylamide sulfosuccinate; alkyl sulphosuccinamate; alkyl sulfoethanoic acid. salt, alkyl ether phosphate, alkyl sarcosine salt; alkyl isethionate and N-acyl taurine salt; alkyl or the acyl group of all above different compounds, its carbon number is between 12 to 30, and aryl is selected from phenyl and benzyl.Anion surfactant is alkyl-D galactoside alduronic acid and salt thereof more preferably, and polyoxyethylene carbon 6 is to carbon 24 alkyl ether carboxylic acids and salt thereof, and the oxirane number comprising is 2 to 50.
The percentage by weight that in the present invention, sulfate type anion surfactant accounts for compositions is further optimized for: 3% to 30%, and the one-step optimization of going forward side by side is: 5% to 25%.
The percentage by weight that the non-ionic surface active agent of the alkyl polyglucoside type in the present invention accounts for compositions is further optimized for: 5% to 25%, and the one-step optimization of going forward side by side is 7% to 20%.
Amphoteric surfactant in the present invention account for compositions weight percent 0.5% to 20%, the one-step optimization of going forward side by side is 2% to 15%.
In the present invention, sulphate anion surface active agent active matter and nonionic alkyl glycoside type surfactant activity thing weight ratio scope are: 1:1.5 to 2.5:1, is further optimized for 1:1.2 to 2:1.
In the present composition, surfactant accounts for 25.3% to 39.1%.
In the present invention, in compositions, the shared percentage by weight of non-volatile vegetable oil is 0.01% to 2%, is further optimized for 0.05% to 1.0%.
In the present invention cosmetics acceptable carrier as, the solvent containing in deionized water and aqueous solution or polyhydric alcohol be as C1-C4 alcohol, as ethanol, isopropyl alcohol, the tert-butyl alcohol, n-butyl alcohol, polyhydric alcohol is as propylene glycol or glycol ester etc.
The surfactant using in the present invention, its final pH value scope is 3 to 10, the one-step optimization of going forward side by side is 5 to 8, the pH value that is further optimized for again 5.5. system can obtain by adding organic or inorganic alkali to be in harmonious proportion, as sodium hydroxide, and ammonia, brothers tertiary amine, monoethanolamine, diethanolamine, triethanolamine, isopropanolamine or 1,3 Malondiamide, and by adding acid, as carboxylic acids, citric acid etc.
The present invention also comprises system viscosity modifier, as electrolyte or thickening agent, and as sodium chloride, sodium xylene sulfonate, HANSHENGJIAO, fatty acid alkanol amides (as coconut monoethanol amide, diglycollic amide), and acrylate copolymer etc.
The present composition also comprise weight percent be 0.5% to 5% pearling agent or opacifier as ethylene glycol monostearate, Ethylene Glycol Distearate, polyethylene glycol mono stearate, polyethylene glycol stearate diester etc.
Can also selectivity in the present invention use or comprise the acceptable composition of some cosmetics as, cationic surfactant, anion or nonionic or cation or amphoteric ion polymer, protein, hydrolyzed protein, 18-methyl arachic acid, hydroxy acid, vitamin, D-panthenol, fatty acid ester, volatilization or non-volatile silicone oil, wetting agent, anti-dandruff dose or seborrhea go out agent, sunscreen, free radical resisting composition, mineral oil, synthetic organic oils and fats and mixture.
Cationic polymer described in the present invention is selected from quaternized cellulose ethers derivant, as the JR-400 of Tao Shi, LR400, and the copolymer of diallyl 2 ammonio methacrylate salt homopolymer and diallyl 2 ammonio methacrylate salt and acrylamide, as Merquat100 polyammonium salt-6 of Merck & Co., Inc. and Merquat550 polyammonium salt-7, diallyl alkyl dimethyl ammonium chloride/the acrylamide copolymer of BASF AG (SALCARE Super7), acrylamide propyl trimethyl ammonium chloride/the acrylamide copolymer of BASF AG (SALCARE SC60), and cationization polysaccharide is as the guar gum of cationization, cation is selected from 2, 3-epoxypropyltrimethylchloride chloride.Cation guar gum, as sieve sub-Jaguar C13S, Jaguar C14S, or selective crosslinking homopolymer and the copolymer of (methyl) acryloyl ethyoxyl trimethyl ammonium chloride, as the Salcare SC92 of national starch, a kind of cationic solution (cross-linked copolymer of methacryl ethyoxyl trimethyl ammonium chloride and acrylamide) that is dispersed in content in mineral oil percent 50, and Salcare SC95 (cross-linked homopolymer of methacryl ethyoxyl trimethyl ammonium chloride).
According to the present invention, cation acrylamide copolymer (acrylamide propyl trimethyl ammonium chloride/acrylamide copolymer) is 0.001% to 1.0% as SALCARE SC60 accounts for composition weight percentage ratio, further be optimized for 0.005% to 0.5%, be optimized for again 0.01% to 0.2%.
According to the present invention, it is 0.005% to 5% that cation melon xanthan polymer accounts for composition weight percentage ratio, is optimized for again 0.01% to 1%.
The present composition also comprises a kind of steady foam, is selected from carbon 10 to carbon 181,2-alkyl 2 alcohol, or fatty alkanolamide comprises fatty monoethanolamine and fatty diethanol amide.The present invention preferably uses coconut monoethanol amide as foam stabilizer, and it is 0.1% to 5% that coconut monoethanol amide accounts for composition weight percentage ratio, is further optimized for 0.5% to 2%.
Certainly, those skilled in the art needs these interpolation property compositions of careful selection and addition to avoid because arbitrary decision interpolation affects result of use of the present invention.
The foam volume of the present composition is measured with foam height, and foam height is greater than 75 millimeters conventionally, is optimized for and is greater than 100 millimeters, and what measuring method adopted is Roche foam meter.
Roche foam meter detection method is as follows: (1) opens thermostat, and when thermostat reaches uniform temperature, the temperature of pipe clamp cover water-bath, makes to be stabilized in 40 ℃ ± 0.5 ℃.(2) with distilled water flushing graded tube inwall, rinse and must then with test solution, rinse tube wall completely, also must rush Xian complete.(3) close graded tube piston, with other minim pipette, inject 50ml test solution to this test solution of 50ml scale place and be heated in advance 40 ℃.(4) minim pipette is filled with to 200ml test solution, this test solution is heated to 40 ℃ in advance.(5) minim pipette is arranged on prior ready pipe support and becomes vertical configuration with the section of graded tube, make solution flow to the center of graded tube, the outlet of minim pipette should be by putting on 900mm graduation mark.(6) open the piston of minim pipette, make under flow of solution.When flow of solution in minim pipette is complete, start immediately stopwatch, well surveying is determined foam height, then through 5 minutes, 10 minutes,, 15 minutes record height again, foam value represents it with foam height.(7) repeat above test two to three times, each first wall must being cleaned and affected data of testing.
The specific embodiment
The processing technology of shampoo composite of the present invention:
1. respectively 0.01% acrylamide propyl trimethyl ammonium chloride/acrylamide copolymer (SALCARE SC60) and 0.3% guar hydroxypropyltrimonium chloride are soaked with suitable water, until form uniform solution for standby;
2. respectively by 2.7% ammonium lauryl sulfate, 5.4% lauryl alcohol ammonium sulfate imports the agitated kettle that water is housed, then dispersed with stirring, add betanin, and add citric acid that pH value is adjusted to 6 left and right, then add 11.4% nonionic alkyl glycoside surfactant, be warmed up to 70 degree, and stir until all dissolve always;
3. respectively the aqueous solution of the 0.01% acrylamide propyl trimethyl ammonium chloride/acrylamide copolymer (SALCARE SC60) having dissolved and 0.3% guar hydroxypropyltrimonium chloride is poured in agitated kettle and continues and stir, keep temperature and add 0.8% coconut monoethanol amide, 1.2% pearlescent flake, continues stir and dissolve approximately 30 minutes.
4. cool to 40 degree left and right, add antiseptic, sodium chloride, and the water of surplus, and with citric acid, the pH value of system is adjusted to 5.5 left and right.
Embodiment I
The contrast of the embodiment of two shampoo composites below, wherein I is embodiment of the present invention I compositions, A is Comparative composition.
In embodiment I compositions, the weight ratio of sulfate type anion surfactant active matter and nonionic alkyl glycoside (APG) active matter is 2:1; In Comparative composition A, the weight ratio of sulfate type anion surfactant active matter and nonionic alkyl glycoside (APG) active matter is 4:1, embodiment I compositions and Comparative composition A, the consumption of both total surfactants (active matter) is identical, is approximately 18.1%.
Using method: get about 12 grams of embodiment I compositionss and evenly spread upon on moistening in advance hair, get foam, then clean with warm water washing; The using method of Comparative composition A is with embodiment I compositions.Then, the special messenger group being comprised of 15 people is used for evaluating foam and the sensation of flood embodiment I compositions and Comparative composition A.
Result shows: the initial expansion rate of embodiment I compositions and the foam volume in use procedure are all better than Comparative composition A, and the foam of water embodiment I compositions is finer and close, and softness and persistent period are long.
Then, the special messenger group being comprised of 15 people evaluates the effect after hair is done again.
Result shows: use the hair after the washing of embodiment I compositions is sent out more soft, more glossy; Soft and smooth property contrast after hair is dry:
Soft and smooth property after embodiment I compositions is correct dry is stronger, has the sensation of film forming.
Therefore, the present composition is used sulfate type anion surfactant general in prior art by minimizing, and increases in proportion nonionic alkyl glucoside surfactant, can, to foam quality, use sensation to wait and bring beyond thought effect.
Embodiment II
The contrast of the embodiment of two shampoo composites below, wherein II is embodiment of the present invention II compositions, A is Comparative composition.
In embodiment II compositions, the weight ratio of sulfate type anion surfactant active matter and nonionic alkyl glycoside (APG) active matter is 2:1; In Comparative composition A, the weight ratio of sulfate type anion surfactant active matter and nonionic alkyl glycoside (APG) active matter is 4:1, embodiment II compositions and Comparative composition A, the consumption of both total surfactants (active matter) is identical, is approximately 18.1%.
Using method: get about 12 grams of embodiment II compositionss and evenly spread upon on moistening in advance hair, get foam, then clean with warm water washing; The using method of Comparative composition A is with embodiment II compositions.Then, the special messenger group being comprised of 15 people is used for evaluating foam and the sensation of flood embodiment II compositions and Comparative composition A.
Result shows: the initial expansion rate of embodiment II compositions and the foam volume in use procedure are all better than Comparative composition A, and the foam of water embodiment II compositions is finer and close, and softness and persistent period are long.
Then, the special messenger group being comprised of 15 people evaluates the effect after hair is done again.
Result shows: use the hair after the washing of embodiment II compositions is sent out more soft, more glossy; Soft and smooth property contrast after hair is dry:
Soft and smooth property after embodiment II compositions is correct dry is stronger, has the sensation of film forming.
Therefore, consistent with the result of the test of embodiment I and embodiment II compositions: the present composition is used sulfate type anion surfactant general in prior art by minimizing, and increase in proportion nonionic alkyl glucoside surfactant, can, to foam quality, use sensation to wait and bring beyond thought effect.
Embodiment III-XI
In the compositions of embodiment III-XI, the weight ratio scope of sulfate type anion surfactant active matter and nonionic alkyl glycoside (APG) active matter is 1:1.2 to 2:1.Embodiment III is preferred forms of the present invention.
Using method: get about 12 grams of said compositions and evenly spread upon on moistening in advance hair, get foam, then clean with warm water washing.
Result shows: use each compositions shampoo, before hair is dry, hair is very soft under moisture state.Satisfied cardability; Hair shows smooth after doing, soft and light sense.
Claims (4)
1. a conditioning shampoo composition, comprises:
A) account for the anion surfactant that contains sulfate and the cocamido propyl betaine that accounts for composition weight 1.0%-15.0% of composition weight 5%-25%, the described anion surfactant that contains sulfate is selected from aliphatic alcohol sulfate and fatty alcohol polyoxyethylene ether sulfate compositions, and the weight ratio of aliphatic alcohol sulfate and fatty alcohol polyoxyethylene ether sulfate is 1:2;
B) account for the nonionic alkyl glycoside type surfactant of composition weight 7.0%-20.0%;
C) account for acrylamide propyl trimethyl ammonium chloride/acrylamide copolymer of composition weight 0.01%-0.20%;
D) account for the cation guar gum polymer of composition weight 0.01%-1.0%;
E) a small amount of shampoo typical additives and the water of surplus;
Wherein sulphate anion surface active agent active matter and nonionic alkyl glycoside surfactant activity thing weight ratio are 1:1.5 to 2.5:1;
Nonionic alkyl glycoside surfactant is selected from the compound with following logical formula I:
R
1—O—(R
2O)
t-(G)
v （Ⅰ）
Wherein, R
1be selected from saturatedly or unsaturated, the carbon number of linearity or side chain is between 8 to 24 carbochain;
R
2be selected from the alkene that contains 2 to 4 carbon atoms;
G is selected from the reducing sugar that comprises 5 to 6 carbon atoms;
The span of t is 0 to 10;
The span of v is 1 to 15.
2. conditioning shampoo composition according to claim 1, wherein sulphate anion surface active agent active matter and nonionic alkyl glycoside surfactant activity thing weight ratio are 1:1.2 to 2:1.
3. conditioning shampoo composition according to claim 1, leads to formula I R
1be selected from saturated and linear carbon number between 8 to 14 alkane, t is that 0, G is glucose, and v span is 1 to 4.
4. a shampoo composite, contain following component, the ratio that each constituent content accounts for compositions by weight, contain 11.4% alkyl polyglucoside, 2.7% ammonium lauryl sulfate, 5.4% lauryl alcohol ammonium sulfate, 8.0% cocamido propyl betaine, acrylamide propyl trimethyl ammonium chloride/acrylamide copolymer of 0.01%, 0.3% guar hydroxypropyltrimonium chloride, 0.8% coconut monoethanol amide, 1.2% pearlescent flake, appropriate antiseptic and sodium chloride, the deionized water of surplus, is finally adjusted to 5.5 by pH value.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210379971.2A CN102920619B (en) | 2012-10-09 | 2012-10-09 | Conditioning shampoo composition containing small amount of sulfate anionic surfactant |
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|---|---|---|---|
| CN201210379971.2A CN102920619B (en) | 2012-10-09 | 2012-10-09 | Conditioning shampoo composition containing small amount of sulfate anionic surfactant |
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| CN102920619A CN102920619A (en) | 2013-02-13 |
| CN102920619B true CN102920619B (en) | 2014-04-16 |
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| CN104207966A (en) * | 2013-05-29 | 2014-12-17 | 拜尔斯道夫股份有限公司 | High-conditioning shampoo composition |
| CN104168883B (en) * | 2013-09-12 | 2016-05-25 | 拉芳家化股份有限公司 | A kind of shampoo composite containing efficient anticreep complexing agent |
| CN104274359B (en) * | 2014-09-05 | 2017-07-18 | 拉芳家化股份有限公司 | A kind of Haircare composition containing handkerchief Yago Lamela essential oil |
| CN104274358B (en) * | 2014-09-05 | 2017-07-18 | 拉芳家化股份有限公司 | A kind of scalp maintenance type hair-washing composition and preparation method containing plants essential oil |
| CN104940039B (en) * | 2015-07-10 | 2016-05-04 | 江苏灵豹药业股份有限公司 | Ketoconazol/Clobetasol Propionate hair lotion |
| MX2018015885A (en) * | 2016-07-06 | 2019-05-27 | Unilever Nv | Personal cleansing compositions. |
| CN108570318B (en) * | 2017-03-13 | 2020-11-13 | 中国石油化工股份有限公司 | CO for oil field2Foam foaming liquid composition and preparation method thereof |
| CN109464299A (en) * | 2018-12-26 | 2019-03-15 | 拉芳家化股份有限公司 | A kind of for a long time more fragrant excellent hair conditioning shampoo composite |
| CN111388365A (en) * | 2020-03-17 | 2020-07-10 | 广州市加中榕科技有限公司 | Silicon-free smoothing and anti-dandruff shampoo and preparation method thereof |
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| ES2629767T5 (en) * | 2006-07-04 | 2020-10-15 | Kao Corp | Skin cleansing composition |
| CN102133160A (en) * | 2010-01-21 | 2011-07-27 | 上海华银日用品有限公司 | Antidandruff and antipruritic shampoo and preparation method thereof |
| CN102327202B (en) * | 2011-07-25 | 2013-02-13 | 拉芳家化股份有限公司 | Conditioner shampoo without silicone oil |
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