CN107603789B - Conditioning type solid shampoo soap - Google Patents
Conditioning type solid shampoo soap Download PDFInfo
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- CN107603789B CN107603789B CN201710780506.2A CN201710780506A CN107603789B CN 107603789 B CN107603789 B CN 107603789B CN 201710780506 A CN201710780506 A CN 201710780506A CN 107603789 B CN107603789 B CN 107603789B
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Abstract
The invention belongs to the field of daily chemicals, and particularly relates to a solid or block shampoo soap. The shampoo soap of the invention comprises the following components besides the common components of the shampoo soap: A. the natural soap base accounts for 70 to 85 percent of the weight percentage of the shampoo soap; B. synthetic detergent surfactant in 5-25 wt% of the shampoo soap; C. the hair conditioner accounts for 0.25 to 3.5 weight percent of the shampoo soap, and the balance is deionized water. The shampoo soap of the present invention can be used for both cleansing hair and scalp and daily skin and body cleansing, does not cause deposition even when used in hard water conditions, and has sufficient lather. Compared with liquid shampoo and the like, the solid shampoo soap has stronger quantitative control capability in use, and is not easy to generate waste due to excessive use amount.
Description
Technical Field
The invention belongs to the field of daily chemicals, and particularly relates to a solid or block shampoo soap.
Background
While soap has long been used for personal hygiene purposes such as body and skin cleansing in humans, many improvements have been made to more effectively cleanse the body and skin, the initial soap products were made from the saponification of animal and vegetable fats. Shampoo soaps are an extension of soap products.
The initial shampoo soaps were derived from fatty soaps or mixtures of fatty soaps which are used to cleanse the hair and are unacceptable (the presence of long carbon chain fatty carboxyl groups forms insoluble calcium and magnesium salts) and thus form deposits on the hair and scalp, especially in hard water hair which has considerable disadvantages and is unacceptable to the user, e.g., poor lather, and readily forms insoluble calcium and magnesium soaps. Therefore, such soaps are very ineffective for shampooing hair.
Over time, shampoo technology such as the use of non-saponified actives or synthetic surface active technologies such as anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, etc., has been developed and used today so far as the 2 in 1 conditioning shampoo technology formulations invented in the 80 s later. However, the block soap cleansing products are used for personal cleansing such as skin and body cleansing, and block fatty soaps are rarely used for hair or scalp cleansing, and do not have the function of conditioning and washing hair, if any.
Disclosure of Invention
The invention aims to provide a cleaning soap product, namely a solid shampoo soap, which can be used for washing hair and cleaning body. The shampoo soap can effectively remove oil, scurf, dust and the like secreted from the surface of hair or scalp, does not form deposition of insoluble lime soap on hair, has good face soaking and cleaning effects for both cleaning skin and body and shampooing, and has good conditioning function.
The technical scheme of the invention is realized as follows: a conditioning solid shampoo soap comprises the following components in addition to the components acceptable by the shampoo soap:
A. the natural soap base accounts for 70 to 85 percent of the weight percentage of the shampoo soap;
B. the synthetic detergent surfactant accounts for 5-25% of the shampoo soap, and comprises the following components in percentage by weight: (a) disodium lauryl sulfosuccinate or disodium laureth sulfosuccinate, and (b) cocoyl monoethanolamine, wherein the disodium lauryl sulfosuccinate or disodium laureth sulfosuccinate accounts for 3 to 15% of the shampoo, and the cocoyl monoethanolamine accounts for 2 to 10% of the shampoo;
C. from 0.25% to 3.5% by weight of the shampoo soap of the invention of a hair conditioning agent comprising: (c) cetyl sodium phosphate accounting for 0.1 to 1.5% by weight of the shampoo soap of the invention, (d) polydimethylsiloxane accounting for 0.1 to 1% by weight of the shampoo soap of the invention, (e) guar hydroxypropyltrimonium chloride accounting for 0.05 to 1% by weight of the shampoo soap of the invention;
D. the balance of deionized water.
In the shampoo soap of the invention, the surfactant comprises: (a) disodium lauryl sulfosuccinate or disodium lauryl polyether sulfosuccinate accounts for 6-12 wt% of the shampoo soap, the cocoyl monoethanolamine (b) accounts for 4-8 wt% of the shampoo soap, and the weight ratio of the coconut monoethanol amine (a) to the coconut monoethanol amine (b) is 3:2.
In the shampoo soap, the hair conditioner accounts for 0.55 to 1.9 percent of the weight of the shampoo soap, wherein (c) the sodium hexadecyl phosphate accounts for 0.3 to 1 percent of the weight of the shampoo soap; (d) polydimethylsiloxane accounts for 0.15 to 0.55 percent of the weight of the shampoo soap, and (e) guar gum hydroxypropyl trimethyl ammonium chloride accounts for 0.1 to 0.35 percent of the weight of the shampoo soap.
The shampoo soap also comprises tetrahydrocurcumin which accounts for 0.1 to 0.35 percent of the weight of the shampoo soap.
A conditioning type solid shampoo soap comprises the following components in percentage by weight:
the invention has the beneficial effects that:
1. the invention contains a soap base system consisting of natural soap base and synthetic washing soap base (synthetic surfactant) in certain weight percentage, and the synthetic washing soap base is prepared by mixing disodium lauryl sulfosuccinate or disodium lauryl polyether sulfosuccinate and cocoyl monoethanolamine in a weight ratio of 3:2, the shampoo soap can play a role in synergistic solubilization, enhances the solubility of the natural soap base in the shampoo soap, and eliminates the phenomenon that the shampoo soap generates lime soap during the hair washing process and deposits on the hair and the scalp to generate dry and astringent.
2. The hair conditioner containing sodium hexadecyl phosphate, polydimethylsiloxane, guar gum hydroxypropyl trimethyl ammonium chloride and the like enhances the dry and wet combing property of the hair of the shampoo soap.
3. The shampoo soap of the present invention can be used for both cleansing hair and scalp and daily skin and body cleansing, does not cause deposition even when used in hard water conditions, and has sufficient lather. The solid shampoo soap has the advantages that compared with liquid shampoos and the like, the solid shampoo soap has stronger quantitative control capability and is not easy to generate waste due to excessive dosage.
Detailed Description
The present invention will be described in further detail with reference to examples.
The conditioning solid shampoo soap can be used for cleaning hair, scalp, skin and body. The shampoo soap comprises a natural soap base which is a mixture of fatty acid salts such as obtained by basic saponification using animal and vegetable oils and fats, or a mixture of natural soap bases which can be sodium hydroxide or potassium hydroxide or alkanolamines such as ethanolamine and the like, and a synthetic washing soap base (synthetic surfactant) which is a natural soap base using saponified coconut oil as a raw material.
The synthetic cleansing soap base of the present invention can be used in combination with a natural soap base, and the suitable synthetic soap base is usually an anionic or nonionic synthetic cleansing surfactant. The synthetic detersive surfactant compatible with the natural soap base of the present invention may be anionic such as alkyl benzene sulfonate, alkyl sulfate, alkyl benzene polyoxyethylene sulfonate, coconut monoglyceride sulfate, fatty alcohol ether sulfate, disodium alkyl succinate, disodium cocoglucoside sulfosuccinate, isethionate, etc., or nonionic such as polyoxyethylene sorbitan fatty acid ester (tween), etc.
The composition of the invention may comprise only pure soap base, and may comprise natural soap base and synthetic surfactant (syndetic soap base), in the present invention, the natural soap base accounts for 70 to 90% by weight of the shampoo soap of the invention, and the syndetic soap base accounts for 5 to 25% by weight of the shampoo soap of the invention. In order to maintain the solid state formation of the shampoo soap of the present invention, the synthetic detergent soap base accounts for 30% or less by weight of the shampoo soap of the present invention.
Synthetic washing soap base (synthetic surfactant) contained in shampoo soap of the present invention
In addition to the natural soap base, the present invention also comprises synthetic surfactants such as (a) disodium lauryl sulfosuccinate, disodium cocoglucoside sulfosuccinate, disodium laureth sulfosuccinate, sodium cocoisethionate or sodium lauryl sulfate in a weight percentage of 3% to 15%, further preferably 6% to 12%, of the present invention (a) preferably disodium lauryl sulfosuccinate or disodium laureth sulfosuccinate, and (b) preferably cocomonoethanolamide, cocodiethanolamide or laureth lauramide in a weight percentage of 2% to 10%, further preferably 4% to 8%, of the present invention (b) preferably cocomonoethanolamide, and the weight ratio of component (a) to component (b) is 3:2 the (a), (b) components may be part of a synthetic detergent base, or added into natural soap base or the mixture of natural soap base and synthetic washing soap base. In summary, the two components (a) and (b) are present in an amount of from 5% to 25% by weight of the shampoo soap of the invention, preferably from 10% to 20%.
The above-mentioned (a) component and (b) component are 3:2 by weight ratio, and can exert synergistic effect, can play solubilizing action in the shampoo of the invention, enhance the solubility of natural soap base in the invention, and eliminate the phenomenon that the shampoo produces lime soap and deposits on hair and scalp to produce "dryness" during the washing process, besides, (a) component and (b) component are 3:2 by weight ratio and can play the role of helping to foam and conditioning skin and hair in the shampoo of the invention.
Therefore, the shampoo soap of the present invention can be used as both daily skin and body cleansing products and for cleansing hair and scalp, does not cause deposition even when used in hard water conditions, and has sufficient lather. The solid shampoo soap has the advantages that compared with liquid shampoos and the like, the solid shampoo soap has stronger quantitative control capability and is not easy to generate waste due to excessive dosage.
Natural soap base: the natural soap base of the invention is derived from the saponified product of coconut oil and is the natural coconut oil soap base. The natural soap base accounts for 70 to 85 percent of the shampoo soap.
Synthetic detergent soap base (synthetic surfactant): the synthetic washing soap base is an anionic synthetic surfactant, such as disodium lauryl sulfosuccinate or disodium laureth sulfosuccinate, wherein the disodium lauryl sulfosuccinate is mild and has a high Krafft point, and a high-concentration aqueous solution can form a large amount of crystals at room temperature, and the crystals are white paste at normal temperature, have a pH value of 5.5-7.5 and a solid content of 48-52%; the disodium laureth sulfosuccinate has good decontamination effect, is milder, can reduce the stimulation of soap base, has colorless to light yellow transparent viscous liquid appearance, has the pH value of 5.0-7.0 and the solid content of 38-42 percent. The synthetic surfactants of the present invention also include nonionic surfactants such as coconut monoethanolamide, which in the present invention functions to thicken and stabilize foam and reduce soap base irritation.
Hair conditioner: the shampoo compositions of the present invention also comprise a hair conditioning agent, and suitable hair conditioning agents of the present invention do not adversely affect the release of the shampoo, nor do they contribute to the build-up effect on the hair and scalp during use. The present invention may comprise one or more hair conditioning agents such as sodium alkyl phosphate, coconut oil, sodium cocoyl sarcosinate, lanolin, dimethicone (silicone oil), cationic polymers, isopropyl myristate, and glycerin and propylene glycol, among others. Sodium alkyl phosphate, dimethicone and cationic polymer conditioner ingredients are preferred herein and are present in an amount of from 0.25% to 3.5% by weight of the shampoo soap of the invention, and more preferably from 0.55% to 1.9% by weight.
Sodium alkyl phosphate: the sodium alkyl phosphate is hexadecyl phosphate which has the function of conditioning and the function of emulsifying polydimethylsiloxane, and the dosage of the sodium hexadecyl phosphate accounts for 0.1-1.5 percent of the weight of the sodium hexadecyl phosphate, and is further optimized to be 0.3-1 percent.
Silicone oil: there is also a need for a hair conditioner that can both retain natural oils on the hair and provide hair shine, such as a silicone selected from the group consisting of polydimethylsiloxanes (silicone oils) having a viscosity in the range of 1CST to 60000CST, further optimized to 10000CST to 60000CST, and polydimethylsiloxanes according to the invention comprising from 0.1 to 1 weight percent of the shampoo of the invention, further optimized to 015 to 0.55 weight percent.
Cationic polymer: the cationic polymer used in the present invention is preferably selected from copolymers or homopolymers of acrylic or methacrylic acid amides or esters (e.g., INCI name, polyquaternium-7), homopolymers of ethyltrimethylammonium methacrylate (INCI name, polyquaternium-37), quaternary ammonium salt copolymers of hydroxyethylcellulose and diallylmethylammonium chloride (INCI name, polyquaternium-4), polymers of hydroxyethylcellulose quaternary ammonium salts in which the hydroxyethyl position of the hydroxyethylcellulose is modified by epoxidation (INCI name, polyquaternium-10, polyquaternium-67), quaternized depolymerized cassia gum derivatives (INCI name, cassia gum hydroxypropyltrimonium chloride), quaternized depolymerized guar gum derivatives (INCI name, guar hydroxypropyltrimonium chloride), amphoteric copolymers (INCI name, polyquaternium-74) or quaternized guar derivatives and quaternized copolymers of hydroxyethyl cellulose and dipropenyldimethylammonium chloride.
The cationic polymer is selected from polyquaternium-7, polyquaternium-10 and cationic guar gum derivatives. And further optimized as polyquaternium-10 and cationic guar derivatives.
The cationic guar gum is a product obtained by quaternizing guar gum, the main component of the cationic guar gum is guar gum propyl trimethyl ammonium chloride, a series of cationic guar gum products can be obtained according to different substitution degrees, preferably, the nitrogen content is 2-4.5%, and the viscosity of a 1% aqueous solution of the cationic guar gum used in the invention is 100-2000 mPa.s at 25 ℃. Cationic guar gum is further preferred shampoo soaps according to the present invention.
The cationic guar gum contained in the shampoo soap is guar gum hydroxypropyl trimethyl ammonium chloride. The dosage of the guar gum hydroxypropyl trimethyl ammonium chloride accounts for 0.05 to 1 percent of the weight percentage of the shampoo soap, and is further optimized to be 0.1 to 0.35 percent.
Coconut oil: wherein the coconut oil comprises about 45% lauric acid, about 18% myristic acid, about 10% palmitic acid, about 8% caprylic acid, about 8% capric acid, about 8% oleic acid, about 2% stearic acid, about 1% linoleic acid and a minor amount of caproic acid. The melting point is 20-24 ℃. The coconut oil plays a role in assisting in foaming besides assisting in promoting and conditioning, and the coconut oil accounts for 1% by weight of the shampoo, and is further optimized to be 0.5%.
Sodium silicate: the sodium silicate (Na2SiO3), water glass (xNa2O "ySiO 2) and colorless, green or brown solid are used as the sodium silicate in the soap, and the functions of the sodium silicate in the soap are to increase the hardness and washing capacity of the soap after the sodium silicate is mixed in the soap, prevent the soap from rancidity and relieve the loss of the soap in hard water. The sodium silicate accounts for 0.5-2.5 wt% of the shampoo soap, and is further optimized to be 0.5-1.5 wt%.
Chelating agent: the present invention also includes one or more chelating agents, suitably used in an amount to neutralize unwanted alkali metals, thereby preventing the formation of lime soap. Chelating agents such as citric acid, tetrasodium pyrophosphate, sodium tripolyphosphate, tetrasodium etidronate, salts of ethylenediaminetetraacetic acid such as disodium ethylenediaminetetraacetate, hydroxyethylethylenediaminetriacetic acid (HEDTA), tetrasodium ethylenediaminetetraacetate, etc. are preferably used in the present invention, tetrasodium etidronate and hydroxyethylethylenediaminetriacetic acid, wherein tetrasodium etidronate is 0.1-0.5% by weight of the shampoo of the present invention, more preferably 0.15-0.30%, hydroxyethylethylenediaminetriacetic acid is 0.1-0.5% by weight of the shampoo of the present invention, more preferably 0.15-0.30%,
antioxidant: the antioxidant can keep the shelf life of the product, and in the invention, the selection of the antioxidant plays a role in keeping the solid shampoo soap fresh and has a good protection effect on scalp and hair. The antioxidant can be selected from curcumin, Butylated Hydroxytoluene (BHT) or Butylated Hydroxyanisole (BHA), the Butylated Hydroxytoluene (BHT) and curcumin are preferred in the invention, and the curcumin is tetrahydrocurcumin and has a structural formula shown in formula I.
Tetrahydrocurcumin: tetrahydrocurcumin is obtained by hydrogenating curcumin (curcumin) separated from rhizome of Curcuma longa (curcumlonga) of Zingiberaceae. White powder with a content of 95 percent, a molecular weight of 372.2 and a CAS number of 36062-04-1. Can effectively inhibit the generation of oxygen free radicals and clear the formed free radicals, has obvious antioxidation effect, such as resisting human skin aging, repairing, fading pigments, removing freckles and the like, and is used as an antioxidant in the invention.
Tetrahydrocurcumin having molecular structure I
In addition, the shampoo soap of the invention can also contain a proper amount of essence, deodorant, pigment or dye.
Preservative: the antioxidant Butylated Hydroxytoluene (BHT) accounts for 0.1-0.5% by weight of the shampoo soap, and is further optimized to be 0.15-0.25%.
The antioxidant tetrahydrocurcumin accounts for 0.05 to 0.5 percent of the weight of the shampoo soap, and is further optimized to be 0.1 to 0.35 percent.
Examples
Examples 1 to 5
Examples 6 to 10
The invention relates to a method for preparing solid shampoo soap, which comprises the following steps:
1. heating natural soap base with slow fire, adding appropriate amount of water, disodium laureth sulfosuccinate or disodium laureth sulfosuccinate, sodium cetyl phosphate, and polydimethylsiloxane, and stirring;
2. respectively adding the dispersed guar gum hydroxypropyl trimethyl ammonium chloride, sodium silicate, coconut oil, 2,6 di-tert-butyl p-methylphenol, curcumin, sodium etidronate, hydroxyethyl ethylenediamine triacetic acid and a proper amount of essence, pigment and preservative into the solution 1, and continuously stirring until the dispersion and the dissolution are carried out;
3. rolling the above 2 by equipment, pressing into strips, cooling, demoulding and packaging until the finished product is obtained.
Experiments show that the above examples 1-10 are in solid form at room temperature.
The application method of the shampoo soap comprises the following steps:
1. firstly, wetting hair with clear water, then holding the shampoo soap by hand, adding water and rubbing to obtain foam;
2. massaging the wetted scalp and hair or body with both hands until rich foam is present;
3. the above actions 1, and 2 may be repeated if necessary, and finally washed with clean water.
The shampoo soap can be used as a body cleaning soap.
And (3) evaluating the efficacy:
instrumental testing
As with the liquid shampoo, the combing test includes dry combing, wet combing tests, the wet combing test being: the hair was first moistened, massaged with approximately 2g of examples 1-10 (blank samples with 3% pure coconut oil soap base) for 2-3min, then rinsed clean with running water, combed once with a comb to remove excess moisture, and wet combability was measured on an Instron2343 micro tensile tester with a pull rate of 300 mm/min; the above procedure was repeated 6 times for each sample, and the results of the measurement after the sixth rinsing in each example are shown in Table 1.
The dry combing test is: after the wet combing test was completed, the hair sample was dried in air, and after drying, the dry combing property was measured. The results of the dry combing test for each example are set forth in Table 1.
TABLE 1 Hair soap combing test results
The results of the above carding performance tests can be seen in table 1: the values of wet and dry combing work for the three comparative examples, namely example 1 (comparative), example 2 (comparative) and example 6 (comparative), are all much higher than the wet/dry combing work of the present invention, examples 3, 4, 5, 7, 8, 9 and 10, and the wet and dry combing work of examples 3, 4, 5, 7, 8, 9 and 10 generally exhibited a decreasing trend, indicating that the use of a synthetic detersive surfactant, such as disodium laureth sulfosuccinate or disodium laureth sulfosuccinate in combination with the nonionic surfactant cocoyl monoethanolamine, contained in the present invention (both at a weight ratio of 3: 2) has a significant effect on the reduction of wet and dry combing work (J) in the test experiments, the reduction in combing work (J) and dry combing work (J) indicates that the shampoo bars of the examples have good conditioning of dry/wet combing, with the dry combing work and wet combing work of example 9 being minimal, and therefore the best results in terms of dry combing and wet combing of example 9.
Furthermore, it can also be seen from table 1 that the dry/wet combing work values of the three comparative examples, namely example 1 (comparative), example 2 (comparative) and example 6 (comparative), show a decreasing trend, although the dry/wet combing work is greater than that of the other examples, indicating that the dry/wet combing performance of the comparative examples increases with increasing amounts of guar hydroxypropyltrimonium chloride in weight percent.
Sensory evaluation
According to the using method of the shampoo soap, the shampoo soap is divided into two groups A and B (20 persons respectively) by market regulators, wherein the group A is used for washing hair in the invention example 9, the group B is used for washing hair in the invention example 1, the using period is 1 week, testers score according to own feelings, the scoring standard adopts 7 points, 1 point is worst, 7 points are best, the result shows that more than 80% of users in the group A score more than 5, and only 20% of persons in the group B give a score of 4, thus the shampoo soap has good shampoo effect; when the same method was used to cleanse the body and the foam and comfort after body washing were evaluated, group A of the present invention was found to be superior to group B in both foam quality and skin lubrication after body washing.
Claims (5)
1. A conditioning solid shampoo soap comprising, in addition to shampoo soap acceptable components:
A. the natural soap base accounts for 70 to 85 percent of the weight of the shampoo soap;
B. a synthetic detersive surfactant comprising from 5% to 25% by weight of the shampoo soap, said synthetic detersive surfactant comprising: (a) disodium lauryl sulfosuccinate or disodium laureth sulfosuccinate, and (b) cocoyl monoethanolamine, wherein the disodium lauryl sulfosuccinate or disodium laureth sulfosuccinate is present in an amount of 3% to 15% by weight of the shampoo, and the cocoyl monoethanolamine is present in an amount of 2% to 10% by weight of the shampoo;
C. from 0.25% to 3.5% by weight of the shampoo soap of a hair conditioning agent comprising: (c) cetyl sodium phosphate in an amount of 0.1 to 1.5% by weight of the shampoo, (d) polydimethylsiloxane in an amount of 0.1 to 1% by weight of the shampoo, (e) guar hydroxypropyltrimethylammonium chloride in an amount of 0.05 to 1% by weight of the shampoo;
D. the balance of deionized water.
2. The shampoo soap of claim 1, wherein of said surfactants: (a) disodium lauryl sulfosuccinate or disodium lauryl polyether sulfosuccinate accounts for 6-12 wt% of the shampoo soap, the cocoyl monoethanolamine (b) accounts for 4-8 wt% of the shampoo soap, and the weight ratio of the (a) to the (b) is 3:2.
3. The shampoo soap of claim 1, said hair conditioning agent comprising from 0.55% to 1.9% by weight of the shampoo soap, wherein (c) sodium cetyl phosphate comprises from 0.3% to 1% by weight of the shampoo soap; (d) polydimethylsiloxane accounts for 0.15 to 0.55 percent of the weight of the shampoo soap, and (e) guar gum hydroxypropyl trimethyl ammonium chloride accounts for 0.1 to 0.35 percent of the weight of the shampoo soap.
4. The shampoo soap of claim 1, further comprising tetrahydrocurcumin in an amount of 0.1% to 0.35% by weight of the shampoo soap.
5. A conditioning type solid shampoo soap comprises the following components in percentage by weight:
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| CN201710780506.2A CN107603789B (en) | 2017-09-01 | 2017-09-01 | Conditioning type solid shampoo soap |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109666549B (en) * | 2018-10-31 | 2021-04-23 | 广东头缘生物科技有限公司 | Hair soap containing soapberry extract |
| CN109666548B (en) * | 2018-10-31 | 2021-04-23 | 广东头缘生物科技有限公司 | Hair soap containing seaweed essence extract |
| CN111849662A (en) * | 2020-06-23 | 2020-10-30 | 岳海军 | Special perfumed soap for washing hair |
| CN112043609A (en) * | 2020-08-28 | 2020-12-08 | 孙晓波 | Method for preparing shampoo soap |
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| CN102716045A (en) * | 2012-06-11 | 2012-10-10 | 广东拉芳日化有限公司 | Shampoo composition containing double anti-dandruff agents |
| CN104540495A (en) * | 2012-06-04 | 2015-04-22 | Elc管理有限责任公司 | Compositions and methods for enhancing the structure of hair fibers |
| CN106420407A (en) * | 2016-08-31 | 2017-02-22 | 福建省梦娇兰日用化学品有限公司 | Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil |
| CN107049816A (en) * | 2017-04-25 | 2017-08-18 | 佛山市富馨科技实业有限公司 | One kind hair washing, face cleaning and take a shower three-in-one purification breast and preparation method |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104540495A (en) * | 2012-06-04 | 2015-04-22 | Elc管理有限责任公司 | Compositions and methods for enhancing the structure of hair fibers |
| CN102716045A (en) * | 2012-06-11 | 2012-10-10 | 广东拉芳日化有限公司 | Shampoo composition containing double anti-dandruff agents |
| CN106420407A (en) * | 2016-08-31 | 2017-02-22 | 福建省梦娇兰日用化学品有限公司 | Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil |
| CN107049816A (en) * | 2017-04-25 | 2017-08-18 | 佛山市富馨科技实业有限公司 | One kind hair washing, face cleaning and take a shower three-in-one purification breast and preparation method |
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