JP5963572B2 - Skin cleansing composition - Google Patents

Description

  The present invention relates to a composition for a skin cleanser.

  Traditionally, skin cleansing agents such as shampoos, body soaps, cleansings, and facial cleansing agents not only remove dust and dirt on the skin and hair, but also remove sebum stains such as the scalp, face, and body. Expected to be effective. In order to remove sebum dirt, various surfactants have been used in conventional skin cleansing agents from the viewpoint of solubility with sebum and a feeling of use.

  Specifically, a sebum selective removing agent containing a hydrophilic surfactant and ethanol (see Patent Document 1), an anionic surfactant, an amphoteric surfactant, and a nonionic surfactant are specified. Scalp cleanser containing monohydric alcohol (see Patent Document 2), sebum remover composition containing inorganic salt, nonionic surfactant and cationic surfactant (see Patent Document 3), Gel-like skin cleanser containing hydrophilic polyglycerin fatty acid ester, acrylic polymer and alkylpolyglucoside (see Patent Document 4), specific anionic surface activity having a function of selectively removing sebum squalene Detergent composition (see Patent Document 5) containing at least one agent, specific amphoteric surfactant, nonionic surfactant, anionic surfactant and cationic high content And oil preparation containing skin cleanser composition (see Patent Document 6), skin dirt removing composition containing polyglycerol fatty acid ester having specific physical properties (see Patent Document 7), polyoxyalkylene alkyl ether A hair cleansing composition (see Patent Document 8) containing a sulfate, a betaine-type amphoteric surfactant, a specific cationic polymer, an inorganic salt, and a specific polyglycerin fatty acid ester has been proposed.

  On the other hand, it is known that the composition of sebum components secreted from the skin changes with age. Furthermore, it is said that changes in the sebum component that is secreted affect the “stickiness” and “glare” of the skin and hair. Removal of sebum components secreted from the skin is effective for suppressing such “stickiness” and “glare” peculiar to middle-aged and elderly people. However, none of the skin cleansing agents aimed at removing sebum that has been studied so far can sufficiently satisfy the removal effect on specific sebum components secreted by middle-aged and older people. It was.

JP 2000-34222 A JP 2000-95651 A JP 2000-128757 A JP 2003-73255 A JP 2003-306426 A JP 2004-262838 A JP-A-2005-75797 JP 2008-81415 A

  The present invention has been made in view of the prior art, and provides a composition for a skin cleanser that exhibits an excellent cleaning and removing effect on specific sebum components secreted from middle-aged and older people. Let it be an issue.

  As a result of analyzing the composition of specific sebum components secreted from middle-aged and elderly people, the present applicant prepared an artificial sebum model that is a pseudo-sebum composition, and conducted an evaluation test of sebum removal using the artificial sebum model. Established. The inventors of the present invention conducted a screening test for a component that cleans and removes a specific sebum component secreted from middle-aged and older people using the evaluation test, and as a result, a specific anionic surfactant and a specific nonionic property were obtained. By combining the surfactant with a specific mass ratio, a remarkably excellent removal effect was found, and the present invention was completed.

That is, the present invention
[1] It contains (A) polyoxyethylene alkyl ether sulfate, (B) polyoxyethylene hydrogenated castor oil , ( C) water , and (D) an amphoteric surfactant, and the HLB value of the component (B) is a 10 to 15, mass content ratio of the component (a) the component (B) is from 1: 1 to 1: 4 der is, the a component (a) and the component (B) ( D) Composition for skin cleanser satisfying the mass content ratio with component (A) + (B) :( D) = 10: 1 to 3: 1 ,
[2 ] The composition for skin cleanser according to [1 ], wherein the content of the component (B) is 1 to 15% by mass ,
[3] The skin cleaning according to [1] or [2], wherein the component (D) contains an amidopropyl betaine type amphoteric surfactant, an aminoacetic acid betaine type amphoteric surfactant, or a sulfobetaine type amphoteric surfactant. Pharmaceutical composition,
[4] The mass content ratio of the component (A) and the component (B) is 1: 1 to 1: 2, and the component (A), the component (B), and the component (D) The composition for skin cleanser according to any one of [1] to [3], wherein the mass content ratio satisfies (A) + (B) :( D) = 8: 1 to 5: 1. About.

  The composition for skin cleanser of the present invention exerts an excellent cleaning and removing effect on specific sebum components secreted from middle-aged and older people, and is “sticky” and “greasy” peculiar to middle-aged and older people in skin and hair. The effect of suppressing "

  Moreover, the composition for skin cleansing agents of this invention has the effect that foamability can be provided, without inhibiting the above-mentioned washing | cleaning removal effect by further containing an amphoteric surfactant.

  The composition for skin cleanser of the present invention contains (A) polyoxyethylene alkyl ether sulfate, (B) polyoxyethylene hydrogenated castor oil, and (C) water, and comprises the component (A) and the component (B ) Component mass content ratio is 1: 1 to 1: 5.

  Specific examples of the component (A) polyoxyethylene alkyl ether sulfate used include sodium polyoxyethylene decyl ether sulfate, sodium polyoxyethylene undecyl ether sulfate, polyoxyethylene tridecyl ether sodium sulfate, polyoxyethylene lauryl Sodium ether sulfate, polyoxyethylene lauryl ether magnesium sulfate, polyoxyethylene lauryl ether sulfate monoethanolamine, polyoxyethylene lauryl ether sulfate diethanolamine, polyoxyethylene lauryl ether sulfate triethanolamine, polyoxyethylene lauryl ether sulfate monoisopropanolamine, Polyoxyethylene lauryl ether ammonium sulfate, polyoxyethylene myristyl ether Sodium acid, polyoxyethylene myristyl ether diethanolamine sulfate, polyoxyethylene myristyl ether sulfuric acid triethanol amine, polyoxyethylene myristyl ether sulfate, and the like can be exemplified polyoxyethylene oleyl ether ammonium sulfate. These (A) components may be used individually by 1 type, and can also be used in combination of 2 or more type as appropriate.

  The number of moles of ethylene oxide added as the component (A) is not particularly limited as long as the desired effect is sufficiently exerted, but from the viewpoint of enhancing the washing and removing effect on the specific sebum component secreted from middle-aged and elderly people. It is preferable to use one having an addition mole number of 1 to 3. As the most suitable component (A), it is preferable to use polyoxyethylene (2) sodium lauryl ether sulfate. In addition, the numerical value in a parenthesis represents the addition mole number of ethylene oxide.

  As the polyoxyethylene alkyl ether sulfate (A), a commercially available product can be used as it is. As commercially available products of polyoxyethylene (2) sodium lauryl ether sulfate, Sinoline SPE-1250 (trade name, manufactured by Shin Nippon Rika Co., Ltd.), Emar 20C, Emar 270J (trade name, both manufactured by Kao Corporation), Sandet EN ( (Trade name, manufactured by Sanyo Kasei Co., Ltd.).

  The content of the component (A) is not particularly limited as long as the desired effect is sufficiently imparted, but usually 0.2% by mass or more is preferable in the composition from the viewpoint of washing and removal, more preferably 1% by mass or more. Further, from the viewpoint of foaming and irritation to the scalp, it is preferably 15% by mass or less, more preferably 10% by mass or less. From these viewpoints, the content of the component (A) is preferably 0.2 to 15% by mass, more preferably 1 to 10% by mass.

  The component (B) used is polyoxyethylene hydrogenated castor oil. In the present invention, by combining the polyoxyethylene hydrogenated castor oil which is the component (B) and the component (A) described above, an excellent washing and removing effect on the specific sebum component secreted from middle-aged and elderly people Can be exhibited.

  The HLB value of the component (B) used is not particularly limited as long as the desired effect is sufficiently exhibited, but it is preferably 7 to 17 from the viewpoint of washing and removing. Specific examples of the component (B) include polyoxyethylene (10) hydrogenated castor oil (HLB value 7), polyoxyethylene (20) hydrogenated castor oil (HLB value 9), polyoxyethylene (25) hydrogenated castor oil ( HLB value 10.7), polyoxyethylene (40) hydrogenated castor oil (HLB value 12.5), polyoxyethylene (50) hydrogenated castor oil (HLB value 13), polyoxyethylene (60) hydrogenated castor oil (HLB) Examples include value 14), polyoxyethylene (100) hydrogenated castor oil (HLB value 15), and the like. These (B) components may be used individually by 1 type, and can also be used in combination of 2 or more types as appropriate. In addition, the numerical value in a parenthesis represents the addition mole number of ethylene oxide.

  In the present invention, it is more preferable to use polyoxyethylene hydrogenated castor oil having an HLB value of 10 to 15 among the above-described components (B) from the viewpoint of further enhancing the cleaning removal effect.

  As the (B) component polyoxyethylene hydrogenated castor oil, a commercially available product can be used as it is. Specifically, as a commercially available product of polyoxyethylene (25) hydrogenated castor oil, Emanon CH-25 (trade name, manufactured by Kao Corporation, HLB value 10.7) and the like can be exemplified. As a commercial item of polyoxyethylene (40) hydrogenated castor oil, Emanon CH-40 (HLB value 12.5) etc. can be illustrated. Examples of commercial products of polyoxyethylene (50) hydrogenated castor oil include EMALEX HC-50 (trade name, manufactured by Nippon Emulsion Co., Ltd., HLB value 13). Examples of commercial products of polyoxyethylene (100) hydrogenated castor oil include EMALEX HC-100 (trade name, manufactured by Nippon Emulsion Co., Ltd., HLB value 15).

  The content of the component (B) is not particularly limited as long as the desired effect is sufficiently imparted, but is usually preferably 1% by mass or more, more preferably 2% in the composition from the viewpoint of washing and removing. % Or more. Moreover, from a viewpoint of maintenance of bubble bulk, 15 mass% or less is preferable, More preferably, it is 12 mass% or less. From these viewpoints, the content of the component (B) is preferably 1 to 15% by mass, more preferably 2 to 12% by mass.

  In addition, the above-mentioned (A) component and (B) component are contained as a mass ratio (A) from a viewpoint of exhibiting the remarkably excellent washing | cleaning removal effect with respect to the specific sebum component secreted from the person of middle-aged and elderly people. ): (B) = 1: 1 to 1: 5. In the present invention, from the viewpoint of further enhancing the cleaning removal effect, it is more preferable that the composition satisfies the range of (A) :( B) = 1: 1 to 1: 4, and more preferably (A) :( B ) = 1: 1 to 1: 2.

  The water of component (C) used is not particularly limited as long as it can be used as a cosmetic raw material, but purified water is usually used. Although content of (C) component will not be specifically limited if a desired effect is provided, Usually, 40-99.5 mass% is preferable in a composition from a viewpoint of a feeling of use, More preferably, it is 55. ˜97.5% by mass.

  Furthermore, (D) amphoteric surfactant can be contained in the composition for skin cleansing agents of this invention from a viewpoint of providing foamability. Specific examples of the component (D) include amidopropyl betaine-type amphoteric surfactants, aminoacetic acid betaine-type amphoteric surfactants, imidazolinium-type amphoteric surfactants, sulfobetaine-type amphoteric surfactants, and sodium propionate-type amphoteric surfactants. Surfactant etc. can be illustrated. These (D) components may be used alone or in a suitable combination of two or more.

  Among the components (D), amidopropyl betaine amphoteric surfactant, aminoacetic acid betaine amphoteric surfactant, sulfobetaine type from the viewpoint of imparting foaming properties without hindering the cleaning and removing effect. It is preferable to use an amphoteric surfactant.

  Suitable amidopropyl betaine-type amphoteric surfactants include palm oil fatty acid amidopropyl betaine, palm oil fatty acid amidopropyl betaine, lauric acid amidopropyl betaine, myristic amidopropyl betaine, ricinoleic acid amidopropyl betaine, lauric acid amidopropyl hydroxy Examples include sulfobetaine, palm kernel oil fatty acid acyl-N-carboxyethyl-N-hydroxyethylethylenediamine sodium, amidopropyldimethylamine oxide laurate, and the like.

  Suitable aminoacetic acid betaine-type amphoteric surfactants include lauryl dimethylaminoacetic acid betaine, coconut oil alkyldimethylaminoacetic acid betaine, stearyldimethylaminoacetic acid betaine, stearyl dihydroxyethyl betaine, 2-alkyl-N-carboxymethyl-N-hydroxy. Ethyl imidazolinium betaine, sodium undecylhydroxyethyl imidazolinium betaine, N-coconut oil fatty acid acyl-N′-carboxyethyl-N′-hydroxyethylethylenediamine sodium (coconut oil alkylcarboxyethyl hydroxyethyl imidazolinium betaine sodium) And sodium laurylaminodipropionate.

  Suitable sulfobetaine-type amphoteric surfactants include lauric acid amidopropyl hydroxysulfobetaine, lauryl hydroxysulfobetaine, coconut oil fatty acid hydroxysulfobetaine, myristic acid amidopropyl hydroxysulfobetaine, oleamidopropyl hydroxysulfobetaine, lauryl sulfobetaine And cocosulfobetaine, cocamidopropylhydroxysultain and the like.

  The content of the component (D) is not particularly limited as long as the desired effect is sufficiently imparted, but usually, 0.12% by mass or more is preferable and more preferable in the composition from the viewpoint of foamability. Is 0.2% by mass or more. Moreover, from a viewpoint of a sebum cleaning effect, 8 mass% or less is preferable, More preferably, it is 5 mass% or less. From these viewpoints, the content of the component (D) is preferably 0.12 to 8% by mass, more preferably 0.2 to 5% by mass.

  In the present invention, the above-described (A) component, (B) component, and (D) component, from the viewpoint of exerting a remarkably excellent washing and removing effect on the specific sebum component secreted from middle-aged and elderly people, The content ratio of (A) + (B) :( D) = 10: 1 to 3: 1 is preferably satisfied, and more preferably 8: 1 to 5: 1. It is a range.

  In the composition for skin cleanser of the present invention, within the range not impairing the effects of the present invention, in addition to the above-described components, components commonly used in cosmetics, for example, O- [2-hydroxy-3-chloride] (Trimethylammonio) propyl] hydroxyethylcellulose, O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, dimethyldiallylammonium chloride / acrylic acid co Polymers, cationic polymers such as polydimethylmethylenepiperidinium chloride; anionic polymers such as carboxyvinyl polymer and acrylic acid / alkyl methacrylate copolymer; silicones such as dimethylpolysiloxane and polyether-modified silicone; olive oil and camellia Oil, ma Liquid oils such as demia nut oil and orange oil; solid oils such as stearic acid, myristic acid and lauric acid; coconut oil fatty acid diethanolamide, lauric acid diethanolamide, polyoxyethylene coconut oil fatty acid monoethanolamide, coconut oil fatty acid monoethanolamide Alkyl alkanolamides such as coconut oil fatty acid N-methylethanolamide; polyhydric alcohols such as 1,3-butylene glycol, glycerin, propylene glycol, polyethylene glycol and polyoxypropylene glyceryl ether; sugar alcohols such as sorbitol and maltitol; Preservatives, antioxidants, ultraviolet absorbers, plant extracts, pearlizing agents, powders, pH adjusters, fragrances and the like can be appropriately blended depending on the purpose.

  The skin cleansing composition of the present invention can be produced by a conventional method, and can be applied to various dosage forms such as liquid, emulsion, cream, and gel. Moreover, it can use suitably as a scalp washing | cleaning agent, a shampoo, a face-washing agent, a cleansing agent, a body shampoo, a hand soap etc. as a usage form. Among these, from the viewpoint of suppressing “stickiness” and “glare” peculiar to middle-aged and elderly people, it is more preferable to use them as scalp cleaning agents, shampoos, facial cleansing agents and cleansing agents.

  Thus, the composition for skin cleansing agents obtained can exhibit the outstanding washing | cleaning removal effect with respect to the specific sebum component secreted from the middle-aged person by satisfying the structure of above-described this invention.

  In this specification, “middle-aged and elderly” refers to those 35 years and older. The middle-aged group is preferably 40 to 59 years old.

  In the present specification, the specific sebum component secreted from middle-aged and elderly people contains triglyceride and fatty acid, and the mass ratio of triglyceride to fatty acid (triglyceride / fatty acid) is 0.57 / 1 or more. It is characterized by being.

  Sebum components secreted from middle-aged and older people tend to have higher triglyceride content and less fatty acid content compared to sebum components secreted from people in their 20s There are features.

  Examples of the triglyceride include triglycerides having an acyl group having 7 to 26 carbon atoms. Specifically, it is a mixture containing tristearin, tripalmitin, trimyristin and triolein.

  The content of tristearin in the mixture is 1 to 13% by mass, the content of tripalmitin in the mixture is 19 to 44% by mass, and the content of trimyristin in the mixture is 9 to 52% by mass. The content of triolein in the mixture is 20 to 56% by mass.

  Examples of the fatty acid include saturated fatty acids having 7 to 26 carbon atoms or unsaturated fatty acids. Specifically, it is a mixture containing myristic acid, palmitic acid, stearic acid, and oleic acid.

  The content of myristic acid in the mixture is 9 to 52% by mass, the content of palmitic acid in the mixture is 19 to 44% by mass, and the content of stearic acid in the mixture is 1 to 13% by mass. The content of oleic acid in the mixture is 20 to 56% by mass.

  The mass ratio of triglyceride to fatty acid (triglyceride / fatty acid) is 0.57 / 1 or more, preferably 0.68 / 1 or more, more preferably 0.81 / 1 or more. In addition, it is preferable that the upper limit of the mass ratio of the said triglyceride and a fatty acid is 50/1 or less.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. The blending amount represents “% by mass” unless otherwise specified.

(Preparation of artificial sebum model)
In the present invention, liquid paraffin, squalane, wax ester, triglyceride, fatty acid, cholesterol, and ceramide are used in order to faithfully reproduce the washing and removal of the specific sebum components secreted by middle-aged and older people. An artificial sebum model having a triglyceride / fatty acid (mass ratio) of 0.81 / 1 was prepared so as to have the composition shown in Table 1.

  As the liquid paraffin, trade name: KAYDOL (manufactured by Sonneborn Inc.) was used. As the squalane, trade name: squalane (manufactured by Wako Pure Chemical Industries, Ltd.) was used. Examples of the wax ester include hexadecyl palmitate (trade name: hexadecyl palmitate, manufactured by Wako Pure Chemical Industries, Ltd.), myristyl myristate (trade name: Exepal MY-M, manufactured by Kao Corporation), and oleyl oleate (trade name: A mixture with CETIOL (manufactured by Cognis Japan) (hexadecyl palmitate: myristyl myristate: oleyl oleate (mass ratio) = 7: 2: 5) was used. Examples of the triglycerides include tristearin (trade name: Tristearin, manufactured by Nacalai Tesque), tripalmitin (trade name: tripalmitine, manufactured by Wako Pure Chemical Industries), and trimyristin (trade name: trimyristin, Wako Pure Chemicals). Kogyo Co., Ltd.) and triolein (trade name: Triolein, manufactured by Wako Pure Chemical Industries, Ltd.) (Tristearin: Tripalmitin: Trimyristin: Triolein (mass ratio) = 1: 8: 3: 9) Was used. As the fatty acid, myristic acid (trade name: myristic acid, manufactured by Nacalai Tesque), palmitic acid (trade name: palmitic acid, manufactured by Nacalai Tesque), and stearic acid (trade name: stearic acid, Wako Pure Chemical Industries, Ltd.) And a mixture of oleic acid (trade name: oleic acid, manufactured by Wako Pure Chemical Industries, Ltd.) (myristic acid: palmitic acid: stearic acid: oleic acid (mass ratio) = 4: 10: 2: 10) It was. As the cholesterol, trade name: cholesterol (manufactured by Wako Pure Chemical Industries, Ltd.) was used. As the ceramide, Ceramide 2 (trade name: Ceramide TIC-001, manufactured by Takasago International Corporation) was used.

(Sample preparation)
According to the composition described in Tables 2-5, each composition for skin cleansing agents of Reference Examples 1-6, Examples 7-12, and Comparative Examples 1-12 was prepared, and it used for the following evaluation. The results are also shown in Tables 2-4. In addition, all evaluation was implemented on the constant conditions of constant temperature and humidity of 23 degreeC and 60% of humidity. Moreover, POE in the table is an abbreviation for polyoxyethylene, and the numerical value in parentheses represents the number of added moles of ethylene oxide.

(Test Example 1: Evaluation of cleaning removal)
Each sample of the reference example, the example and the comparative example was dissolved in purified water so as to have a concentration of 7% by mass to obtain an aqueous solution for washing test.

  The artificial sebum model shown in Table 1 was liquefied by heating to 60 ° C., and 0.25 g of the artificial sebum model was uniformly applied to a keratin cloth (20 mm × 20 mm). The keratin cloth after application of the artificial sebum model was allowed to stand at 35 ° C. for 12 hours or more.

Next, the prepared keratin cloth after application of the artificial sebum model was immersed in a container containing 100 mL of the aqueous solution for cleaning test previously maintained at 45 ° C. The keratin cloth after application of the artificial sebum model was washed by shaking the container for 60 minutes under the conditions of a vibration frequency of 60 cm ⁻¹ and an amplitude of 15 mm.

  The artificial sebum model remaining on the washed keratin cloth was extracted with chloroform. The obtained extract was subjected to gas chromatography with a flame ionization detector (GC-FID) under the following analysis conditions, and peaks corresponding to components (fatty acid, squalene, wax ester or triglyceride) contained in the artificial sebum model were measured. The area (hereinafter referred to as “area A”) was determined.

  Further, except that the artificial sebum model attached to the keratin cloth before washing was used instead of the artificial sebum model remaining on the washed keratin cloth, the same operation as described above was performed, and the peak area corresponding to the component (Hereinafter referred to as “area B”).

<Analysis conditions>
Apparatus: Agilent 6890N (manufactured by Agilent Technologies)
Column: Ultra ALLOY UA-DX30 (manufactured by Frontier Laboratories)
Carrier gas: Helium inlet temperature: 360 ° C
Column temperature: 40 ° C. to 20 ° C./min and held at 400 ° C. for 12 minutes Column flow rate: 2 mL / min Detector: Flame ionization detector (FID)
Detector temperature: 250 ° C
Injection volume: 2 μL

  Next, the residual rate of the lipid [(area A / area B) × 100] (%) was calculated from the obtained analysis result. Based on the calculation result of the residual rate, it evaluated according to the following evaluation criteria.

<Evaluation criteria for cleaning removal>
◎: The residual ratio of lipid in the keratin cloth after washing is 0% or more and less than 40% ○: The residual ratio of lipid in the keratin cloth after washing is 40% or more and less than 60% △: The lipid remaining in the keratin cloth after washing Residual rate is 60% or more and less than 90% x: The residual rate of lipid in the keratin cloth after washing is 90% or more

(Test Example 2: Evaluation of foamability)
Each of the samples obtained in Examples 7 to 12 was uniformly applied to a wig (Lesson Mannequin: manufactured by Eucalyptus Japan) wetted with warm water by 20 evaluation panels, and the foaming property was evaluated according to the following evaluation criteria. Sensory evaluation was performed.

<Evaluation criteria for foamability>
◎: Reply if 16 or more out of 20 people are excellent in foamability ○: Reply if 11-15 in 20 people are excellent in foamability △: 6-10 out of 20 people in foamability Answered as excellent ×: 5 or less out of 20 responded that foaming was excellent

From the results shown in Tables 2 to 4, the compositions for skin cleansing agents of the present invention described in Reference Examples 1 to 6 are excellent in cleaning and removing the specific sebum components secreted from middle-aged and elderly people. It can be seen that In other words, it can be said that the composition for skin cleanser of the present invention suppresses “stickiness” and “glare” peculiar to middle-aged and elderly people. Furthermore, it turns out that the composition for skin washing | cleaning agents containing the amphoteric surfactant described in Examples 7-12 has provided foaming property, without inhibiting the washing | cleaning removal effect.

  On the other hand, the composition for skin cleansing agents described in Comparative Examples 1 to 6 that does not satisfy the essential components of the present invention or replace the essential components of the present invention with other components, and satisfies the mass content ratio of the present invention. The compositions for skin cleansing agents described in Comparative Examples 7 to 12 are inferior in cleaning and removal of sebum components, so that “stickiness” and “glitter” peculiar to middle-aged and elderly people cannot be sufficiently suppressed. It can be said that there is.

Hereinafter, the formulation example of the composition for skin cleaning agents containing the composition for skin cleaning agents which concerns on this invention is shown. In addition, content is mass%. POE is an abbreviation for polyoxyethylene, and the numerical value in parentheses represents the number of added moles of ethylene oxide.

(Formulation Example 1: Scalp cleanser)
POE (2) sodium lauryl ether sulfate 2.0
Polyoxyethylene (25) hydrogenated castor oil 2.0
Polyoxyethylene (100) hydrogenated castor oil 2.0
Amidopropyl betaine laurate 1.0
Diglycerin 1.0
1,3-butylene glycol 10.0
Ethanol 5.0
l-Menthol 0.5
Acrylic acid / alkyl methacrylate copolymer 0.4
pH adjuster (triethanolamine) Amount to make pH 6.0
Purified water balance part Total 100.0

(Formulation Example 2: Scalp cleanser)
POE (2) sodium lauryl ether sulfate 2.0
Polyoxyethylene (100) hydrogenated castor oil 4.0
POE glyceryl ether (9) 3.0
Dipropylene glycol 10.0
Ethanol 7.0
l-Menthol 0.3
Acrylic acid / alkyl methacrylate copolymer 0.2
pH adjuster (triethanolamine) Amount to make pH 6.0
Purified water balance part Total 100.0

(Prescription Example 3: Shampoo)
POE (2) sodium lauryl ether sulfate 5.0
Polyoxyethylene (100) hydrogenated castor oil 1.5
Polyoxyethylene (50) hydrogenated castor oil 3.5
Amidopropyl betaine laurate 2.0
Palm oil fatty acid diethanolamide 3.0
Sorbitol 1.0
1,3-butylene glycol 0.5
l-Menthol 1.0
O- [2-hydroxy-3- (trimethylammonio) propyl] chloride
Hydroxyethyl cellulose 0.3
Polydimethylmethylenepiperidinium chloride solution 0.1
Ethylene glycol distearate 1.0
pH adjuster (citric acid) Amount to make pH 5.8
Purified water balance part Total 100.0

(Prescription Example 4: Face Wash)
Lauric acid 6.5
Myristic acid 13.0
Stearic acid 12.5
Glycerin 10.0
Propylene glycol 9.0
Polyethylene glycol 1500 8.0
POE (2) sodium lauryl ether sulfate 1.0
Polyoxyethylene (50) hydrogenated castor oil 2.0
Lauric acid amidopropyl betaine 0.4
pH adjuster (potassium hydroxide) Amount to make pH 9.5
Purified water balance part Total 100.0

(Formulation example 5: cleansing agent)
POE (2) sodium lauryl ether sulfate 1.0
Polyoxyethylene (25) hydrogenated castor oil 1.5
Lauric acid amidopropyl betaine 0.5
Glycerin 5.0
POE (7) Palm oil fatty acid glyceryl 5.0
pH adjuster (potassium hydroxide) Amount to make pH 6.0
Purified water balance part Total 100.0

Claims (4)

(A) polyoxyethylene alkyl ether sulfate, (B) polyoxyethylene hydrogenated castor oil , ( C) water , and (D) an amphoteric surfactant ,
The HLB value of the component (B) is 10-15,
Mass content ratio of the component (A) the component (B) is from 1: 1 to 1: are four der,
Composition for skin cleanser wherein the mass content ratio of the component (A) and the component (B) to the component (D) satisfies (A) + (B) :( D) = 10: 1 to 3: 1 object. The composition for skin cleanser according to claim 1, wherein the content of the component (B) is 1 to 15% by mass. The composition for a skin cleanser according to claim 1 or 2, wherein the component (D) comprises an amidopropyl betaine type amphoteric surfactant, an aminoacetic acid betaine type amphoteric surfactant, or a sulfobetaine type amphoteric surfactant. The mass content ratio of the component (A) and the component (B) is 1: 1 to 1: 2.
The mass content ratio of the component (A) and the component (B) to the component (D) satisfies (A) + (B) :( D) = 8: 1 to 5: 1. The composition for skin cleansing agents in any one of.