KR102402933B1 - Hair cleansing composition comprising sphingomonas ferment extract - Google Patents

Abstract

According to one embodiment of the present invention, provided is a hair cleansing composition. A hair cleansing composition according to one embodiment of the present invention includes a Sphingomonas fermented extract; and a positive ion conditioning agent. According to the present invention, a formulation can be stably formed and maintained.

Description

Hair cleaning composition comprising Sphingomonas fermented extract {HAIR CLEANSING COMPOSITION COMPRISING SPHINGOMONAS FERMENT EXTRACT}

The present invention relates to a hair wash composition comprising a Sphingomonas fermented extract, and specifically, by including the Sphingomonas fermented extract as a thickener, the formulation is stably formed without phase separation or precipitation even when a cationic conditioning agent is included. and to a hair cleanser composition that is maintained.

The hair of modern people is contaminated and damaged due to various causes such as exposure to ultraviolet rays, contact with the surrounding environment such as dust and wind, and perming, drying, dyeing, and combing. Damaged hair is tangled, difficult to manage, and loses shine and softness.

In order to solve this problem, various detergents or cosmetics have appeared during or after washing to improve the gloss and feel of the hair and to restore damaged hair. In particular, products that increase the flexibility of hair by including conditioning agents in shampoo have been developed.

In general, as a conditioning agent included in shampoo, cationic polymers such as cationic guar, polyquaternium-10, polyquaternium-47, etc. having excellent conditioning effect are used. However, when an anionic component is included in such a cationic polymer composition, the formulation is not stably formed, such as precipitation and separation phenomena occur due to binding with the anionic component, and there is a problem that it irritates the skin and lacks the feeling of use. have.

Therefore, there is a need for a hair cleanser composition that can solve such problems.

An object of the present invention is to solve the above problems, and the formulation is stably formed and maintained, and it is an object of the present invention to provide an excellent feeling of use and softness of hair during washing.

The technical problems of the present invention are not limited to the technical problems mentioned above, and other technical problems not mentioned will be clearly understood by those skilled in the art from the following description.

According to one embodiment of the present invention, a hair cleanser composition is provided. A hair cleanser composition according to an embodiment of the present invention comprises: Sphingomonas fermented extract; and cationic conditioning agents.

In addition, the weight ratio of the cation conditioning agent to the Sphingomonas fermented extract may be 0.05 to 1.5: 0.01 to 5.

In addition, the Sphingomonas fermented extract may be included in an amount of 0.05 to 1.5% by weight based on the total weight of the composition.

In addition, the cationic conditioning agent, cationic guar (Cationic Guar), polyquaternium (Polyquaternium), polyquaternium-7 (Polyquaternium-7), polyquaternium-10 (Polyquaternium-10), polyquaternium-47 (Polyquaternium-47), Cellulose, Acrylic Ester, Methacrylic Ester, Polysaccharide, Polyamino Amide Derivative and Cationic Protein It may be at least one selected from the group consisting of.

In addition, the cationic conditioning agent may be included in an amount of 0.01 to 5% by weight based on the total weight of the composition.

In addition, the hair cleanser composition may further include an auxiliary thickener.

In addition, the auxiliary thickener may be included in an amount of 0.2 to 4.0% by weight based on the total weight of the composition.

In addition, the weight ratio of the auxiliary thickener to the Sphingomonas fermented extract may be 1: 0.13 to 80.

In addition, the auxiliary thickener may include a heterogeneous auxiliary thickener composed of the first auxiliary thickener and the second auxiliary thickener.

In addition, the weight ratio of the second auxiliary thickener to the first auxiliary thickener may be 1: 1 to 2.

In addition, the first auxiliary thickener, trihydroxystearin (Trihydroxystearin), carbomer (Carbomer), acrylate / C10-30 alkyl acrylate crosspolymer (Acrylates / C10-30 Alkyl Acrylate Crosspolymer), acrylate copolymer (Acrylates Copolymer), Acrylates/Beheneth-25 Methacrylate Copolymer, Polyacrylate, Hydroxyethylcellulose, Xanthan Gum, De One selected from the group consisting of Dehydroxanthan Gum, PEG-150 Pentaerythrityl Tetrastearate and PEG-120 Methyl Glucose Dioleate may be more than

In addition, the first auxiliary thickener may be included in an amount of 0.1 to 1.5% by weight based on the total weight of the composition.

In addition, the second auxiliary thickener may be a C12-22 fatty alcohol (C12-22 Fatty Alcohol).

In addition, the second auxiliary thickener may be included in an amount of 0.1 to 2.5% by weight based on the total weight of the composition.

In addition, the hair cleanser composition may further include at least one of a surfactant and a polyol.

In addition, the surfactant may be at least one selected from the group consisting of anionic surfactants, amphoteric surfactants, and nonionic surfactants.

In addition, the polyol, glycerin (Glycerin), methylpropanediol (Methylpropanediol), propylene glycol (Propylene Glycol), dipropylene glycol (Dipropylene Glycol), sorbitol (Sorbitol), butylene glycol (Butylene Glycol) And it may be at least one selected from the group consisting of glycereth-based compounds.

In addition, the polyol may be included in an amount of 0.01 to 90% by weight based on the total weight of the composition.

According to the present invention, by including the Sphingomonas fermented extract, it is possible to stably form and maintain the formulation without precipitation or phase separation of the formulation even including the cationic conditioning agent, and to minimize skin irritation to provide an excellent feeling of use can provide

In addition, the hair cleanser composition according to the present invention can impart conditioning effects such as softness, softness, and gloss to hair during and after washing.

In order to more fully understand the drawings cited in the Detailed Description, a brief description of each drawing is provided.
1 is a photograph of a hair cleanser prepared using compositions according to Examples and Comparative Examples with respect to Experimental Example 1 of the present invention.
2 is a photograph of a hair cleanser prepared using compositions according to Examples and Comparative Examples with respect to Experimental Example 2 of the present invention.
3 is a photograph of a hair cleanser prepared using compositions according to Examples and Comparative Examples with respect to Experimental Example 3 of the present invention.
4 is a photograph of a hair cleanser prepared using compositions according to Examples and Comparative Examples with respect to Experimental Example 4 of the present invention.
5 is a photograph of a hair cleanser prepared using compositions according to Examples and Comparative Examples with respect to Experimental Example 5 of the present invention.
6 is a photograph of a hair cleanser prepared using compositions according to Examples and Comparative Examples with respect to Experimental Example 6 of the present invention.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In general, the nomenclature used herein is those well known and commonly used in the art. In addition, in describing the embodiment of the present invention, if it is determined that a detailed description of a related known configuration or function interferes with the understanding of the embodiment of the present invention, the detailed description thereof will be omitted. In addition, the embodiments of the present invention will be described below, but the technical spirit of the present invention is not limited thereto and may be variously implemented by those skilled in the art.

The present invention relates to a hair cleanser composition, and may include a fermented Sphingomonas extract and a cationic conditioning agent.

Sphingomonas fermented extract can stably form the formulation of the detergent composition while stably controlling the viscosity.

In general, when a thickener of an anionic component and a cationic conditioning agent are included together, a phenomenon of precipitation or phase separation occurs due to the combination of the two components. However, despite the fact that the Sphingomonas ferment extract is an anion, no precipitation or separation occurs even when a cationic conditioning agent is used. That is, by including the fermented Sphingomonas extract, the hair cleanser composition of the present invention can prevent precipitation or phase separation, and also can improve the feeling of use by minimizing skin irritation during washing.

Sphingomonas fermented extract of the present invention may be included in an amount of 0.05 to 1.5% by weight based on the total weight of the composition. When the Sphingomonas fermented extract is included in less than 0.05 wt%, phase separation of the formulation may occur, and when the Sphingomonas fermented extract is included in excess of 1.5 wt%, the viscosity is too high and the feeling of use may be reduced.

Cationic conditioning agents can provide conditioning effects such as smoothness, softness and softness to the hair after washing and drying.

For example, the cationic conditioning agent of the present invention is cationic guar (Cationic Guar), polyquaternium (Polyquaternium), polyquaternium-7 (Polyquaternium-7), polyquaternium-10 (Polyquaternium-10), polyquater Polyquaternium-47, Cellulose, Acrylic Ester, Methacrylic Ester, Polysaccharide, Polyamino Amide Derivative and cationic protein ( Cationic Protein) may be one or more selected from the group consisting of, but is not limited thereto.

The cationic conditioning agent of the present invention may be included in an amount of 0.01 to 5% by weight based on the total weight of the composition. When the cationic conditioning agent is included in an amount of less than 0.01% by weight, the conditioning effect after washing or drying may be insufficient, and when the cationic conditioning agent is included in an amount of more than 5% by weight, the formulation stability may be deteriorated and the feeling of use may be reduced.

In the present invention, the weight ratio of the cation conditioning agent to the fermented sphingomonas extract may be 0.05 to 1.5: 0.01 to 5. When the weight ratio of the cationic conditioning agent to the Sphingomonas fermented extract is less than 1.5: 0.01, the viscosity is not sufficiently formed and the spreadability is lowered, and the weight ratio of the cationic conditioning agent to the fermented Sphingomonas extract exceeds 0.05: 5 Formulation may not be stably formed due to precipitation or phase separation.

The composition according to an embodiment of the present invention may further include an auxiliary thickener.

The auxiliary thickener controls the viscosity of the composition together with the Sphingomonas fermented extract, and may play a role in stably forming and maintaining the formulation of the hair wash composition even at low or high temperatures.

The auxiliary thickener of the present invention may be included in an amount of 0.2 to 4% by weight based on the total weight of the composition. When the auxiliary thickener is included in an amount of less than 0.2% by weight, the viscosity is not sufficiently formed, and when the auxiliary thickener is included in an amount of more than 4% by weight, phase separation of the formulation may occur at low or high temperatures.

In the present invention, the weight ratio of the auxiliary thickener to the Sphingomonas fermented extract may be 1: 0.13 to 80. When the weight ratio of the auxiliary thickener to the Sphingomonas fermented extract is less than 1: 0.13, the formulation is not stably formed and usability is reduced, and when the weight ratio of the auxiliary thickener to the Sphingomonas fermented extract exceeds 1: 80, Phase separation of the formulation may occur at high temperatures above 40°C.

According to an embodiment, the auxiliary thickener of the present invention may include a first auxiliary thickener or a second auxiliary thickener, and preferably, a heterogeneous auxiliary thickener consisting of the first auxiliary thickener and the second auxiliary thickener. may include all of them. When the first auxiliary thickener and the second auxiliary thickener are included at the same time, the viscosity is more stably controlled, effectively preventing precipitation or phase separation of the formulation, the formulation can be maintained stably, and the spreadability is improved there is

In the present invention, the weight ratio of the second auxiliary thickener to the first auxiliary thickener may be 1: 1 to 2. When the weight ratio of the second auxiliary thickener to the first auxiliary thickener is less than 1:1, the feeling of use decreases, and when the weight ratio of the second auxiliary thickener to the first auxiliary thickener exceeds 1: 2, There is a problem in that stability is lowered.

For example, the first auxiliary thickener of the present invention is Trihydroxystearin, Carbomer, Acrylates/C10-30 Alkyl Acrylate Crosspolymer, acrylic Acrylates Copolymer, Acrylates/Beheneth-25 Methacrylate Copolymer, Polyacrylate, Hydroxyethylcellulose, Xanthan Gum ), from the group consisting of dehydroxanthan gum (Dehydroxanthan Gum), PEG-150 Pentaerythrityl Tetrastearate and PEG-120 Methyl Glucose Dioleate (PEG-120 Methyl Glucose Dioleate) It may be one or more selected, preferably trihydroxystearin, but is not limited thereto.

The first auxiliary thickener of the present invention may be included in an amount of 0.1 to 1.5% by weight based on the total weight of the composition. When the first auxiliary thickener is included in less than 0.1% by weight, phase separation of the formulation may occur, and when the first auxiliary thickener is included in excess of 1.5% by weight, the viscosity is high so that each component is not uniformly dispersed and the formulation is stable may not be formed.

In addition, for example, the second auxiliary thickener of the present invention may be a C12-22 fatty alcohol (C12-22 Fatty Alcohol), but is not limited thereto.

The second auxiliary thickener of the present invention may be included in an amount of 0.1 to 2.5% by weight, preferably 0.1 to 1.5% by weight, based on the total weight of the composition. When the second auxiliary thickener is included in an amount of less than 0.1% by weight, it is difficult for the viscosity to maintain a certain value, so formulation stability is lowered. have.

The composition according to an embodiment of the present invention may further include at least one of a surfactant and a polyol.

Surfactants have excellent cleaning power and can serve to efficiently remove contaminants from hair.

According to embodiments, the surfactant of the present invention may be at least one selected from the group consisting of anionic surfactants, amphoteric surfactants and nonionic surfactants, and preferably, anionic surfactants, amphoteric surfactants and nonionic surfactants. It may be two or more selected from the group consisting of surfactants. In addition, more preferably, an anionic surfactant, an amphoteric surfactant, and a nonionic surfactant may all be included. When an anionic surfactant, an amphoteric surfactant and a nonionic surfactant are included at the same time, there is a synergistic effect in terms of cleaning power, foam is uniformly created on the hair during washing, and the foam generated on the hair can be efficiently rinsed.

For example, the anionic surfactant of the present invention is a sulfate-based compound, sodium laureth sulfate (Sodium Laureth Sulfate), sodium lauryl sulfate (Sodium Lauryl Sulfate), ammonium laureth sulfate (Ammonium Laureth Sulfate), ammonium laureth sulfate ( Ammonium Lauryl Sulfate, Sodium Coco Sulfate, Taurate Compound, Sodium Methyl Cocoyl Taurate, Sodium Lauroyl Taurate, Sodium Methyl Stearoyl Tau Sodium Methyl Stearoyl Taurate, Glutamate Compound, Sodium Cocoyl Glutamate, Sodium Lauroyl Glutamate, Sodium Cocoyl Alaninate, Potassium Cocoyl Glycinate (Potassium Cocoyl Glycinate), Sodium Cocoyl Isethionate, Sarcosinate Compound, Sodium Lauroyl Sarcosinate, Sodium Myristoyl Sarcosinate, Sodium Myristoyl Sarcosinate It may be at least one selected from the group consisting of a phosuccinate-based compound, disodium laureth sulfosuccinate, and disodium lauryl sulfosuccinate, but is not limited thereto.

The anionic surfactant of the present invention may be included in an amount of 0.1 to 90% by weight relative to the total weight of the composition, preferably 1 to 30% by weight relative to the total weight of the composition. When the anionic surfactant is included in less than 0.1% by weight, the cleaning power may be reduced, and when the anionic surfactant is included in more than 90% by weight, damage and irritation of the hair may increase.

In addition, for example, the amphoteric surfactant of the present invention is a betaine-based compound, lauryl betaine (Lauryl Betaine), cocamidopropyl betaine (Cocamidopropyl Betaine), lauramidopropyl betaine (Lauramidopropyl Betaine), coco-beta Phosphorus (Coco-Betaine), Disodium Cocoamphodiacetate (Disodium Cocoamphodiacetate), Sodium Cocoamphoacetate (Sodium Cocoamphoacetate), Sultainic Compounds, Lauryl Hydroxysultaine and Cocamidopropyl Hydroxultaine ( Cocamidopropyl Hydroxysultaine) may be at least one selected from the group consisting of, but is not limited thereto.

The amphoteric surfactant of the present invention may be included in an amount of 0.1 to 90% by weight based on the total weight of the composition, preferably 1 to 30% by weight based on the total weight of the composition. When the amphoteric surfactant is included in less than 0.1% by weight, there is a problem in that it is difficult to rinse the foam of the hair.

In addition, for example, the nonionic surfactant of the present invention is a glucoside-based compound, palm oil fatty acid monoethanolamide (Coconut Fatty Acid Monoethanolamide, Cocamide MEA), Cocamide Methyl MEA (Cocamide Methyl MEA), Laura It may be one or more selected from the group consisting of Lauramide MEA, polyglyceryl-based compounds, and glyceryl monostearate (GMS), but is not limited thereto.

The nonionic surfactant of the present invention may be included in an amount of 0.1 to 90% by weight based on the total weight of the composition, preferably 1 to 30% by weight based on the total weight of the composition. When the nonionic surfactant is included in less than 0.1% by weight, the cleaning power may be lowered, and when the nonionic surfactant is included in more than 90% by weight, there is a problem that the cleaning agent remains on the hair after washing.

The polyol helps to mix the thickener with the composition to keep the formulation stable, and can serve to increase the foam holding power together with the surfactant.

For example, the polyol of the present invention is glycerin (Glycerin), methylpropanediol (Methylpropanediol), propylene glycol (Propylene Glycol), dipropylene glycol (Dipropylene Glycol), sorbitol (Sorbitol), butylene glycol ( Butylene Glycol) and may be at least one selected from the group consisting of glycereth-based compounds, but is not limited thereto.

The polyol of the present invention may be included in an amount of 0.01 to 90% by weight based on the total weight of the composition, preferably 0.1 to 20% by weight based on the total weight of the composition. When the polyol is included in an amount of less than 0.01% by weight, transparency and foaming power may be reduced, and when the polyol is included in an amount of more than 90% by weight, the formulation may not be stably formed or the cleaning power may be reduced.

The hair cleanser composition of the present invention contains other ingredients commonly used in the art, for example, a pH adjuster, a conditioning agent, a fragrance, an antioxidant, a neutralizer, a functional additive, a stabilizer, within a range that does not impair the effects of the present invention. , vitamins, moisturizers, preservatives, proteins and other additives may be further included.

[Experimental example]

Hereinafter, examples for more specifically explaining the present invention are shown as follows, but the present invention is not limited thereto.

Experimental Example 1: Effect according to the ratio of sphingomonas fermented extract and cationic conditioning agent

(1) Preparation of Examples 1 to 8 and Comparative Examples 1 to 4

By using the components described in Table 1 below, Examples and Comparative Examples of the composition according to the present invention were prepared. Table 1 The unit of component content is weight %.

Examples 1 to 8 and Comparative Examples 1 to 4 are hair cleaning compositions in which the ratio of the fermented Sphingomonas extract and the cationic conditioning agent is changed.

The specific manufacturing method is as follows.

A phase A was prepared while stirring the Sphingomonas fermented extract at a temperature of 80° C. for 20 minutes. Phase B was prepared by mixing three types of surfactant, glycerin, and solvent in phase A and uniformly stirring for 20 minutes. After adding trihydroxystearin and cetyl alcohol to phase B, the mixture was stirred for 10 minutes, and after adding polyquaternium-10, it was cooled at room temperature to complete a hair cleanser composition.

(2) Formulation stability evaluation

A hair wash was prepared using the compositions according to Examples 1 to 8, and a hair wash was prepared using the compositions according to Comparative Examples 1 to 4. Then, by visually observing the samples of the Examples and Comparative Examples, whether the formulation is stably formed without the occurrence of precipitation or phase separation of the formulation, and low temperature (5° C.), room temperature, and high temperature for the samples of Examples and Comparative Examples It was determined whether the formulation was stably maintained at (40° C.) and the results are shown in Table 2.

As a result of the experiment, it was confirmed that Examples 1 to 8 did not cause precipitation or phase separation of the formulation of the hair cleanser, and the formulation was stably formed.

On the other hand, in the case of Comparative Example 1, in which the ratio of the cationic conditioning agent to the fermented Sphingomonas extract was small, the feeling of use was remarkably deteriorated, so that it could not act as a hair cleanser. In Comparative Examples 2 to 4, in which the ratio of the cationic conditioning agent to the fermented Sphingomonas extract was large, the formulation could not be stably formed due to precipitation and phase separation of the formulation. The hair cleanser prepared using the composition according to Examples and Comparative Examples is shown in FIG. 1 .

(3) Evaluation of usability

In order to examine the feeling of use of the compositions according to Examples 1 to 8 and Comparative Examples 1 to 4, the cleaning effect and conditioning effect items were evaluated, and the results are shown in Table 2.

The experimental method is as follows. In the case of the cleaning effect, 3 g of each of the samples of Examples and Comparative Examples was taken, and the degree of cleaning was evaluated in the cleaning effect evaluation item after foaming the human hair string. For the conditioning effect, 3 g of each of the samples of Examples and Comparative Examples was taken, and the softness of the hair through combing, etc. when rinsing with water after foaming the human hair string was evaluated in the softness evaluation item of wet hair. In addition, the softness of the hair after rinsing and drying through combing, etc. was evaluated in the softness evaluation item of the hair after drying. As an evaluation scale, it was evaluated in 5 stages, and the score was given in units of 1 point according to the stage on a 5-point scale.

As a result of the experiment, in the case of Examples 1 to 8, it was confirmed that the cleaning effect, the softness of wet hair, and the softness of the hair after drying all obtained high scores to have an excellent feeling of use.

On the other hand, in the case of Comparative Examples 1 to 4, it was confirmed that the precipitation and phase separation of the formulation occurred, and the scores of the cleaning effect and the conditioning effect were low, so that the feeling of use was not good.

division formulation cleaning effect conditioning effect wet hair softness hair softness after drying Example 1 Formulation is stably formed 5 3 4 Example 2 Formulation is stably formed 4 4 3 Example 3 Formulation is stably formed 5 3 4 Example 4 Formulation is stably formed 3 4 4 Example 5 Formulation is stably formed 4 5 5 Example 6 Formulation is stably formed 5 4 4 Example 7 Formulation is stably formed 5 4 3 Example 8 Formulation is stably formed 5 5 3 Comparative Example 1 Formulation precipitation and phase separation 2 One One Comparative Example 2 Formulation precipitation and phase separation One 3 One Comparative Example 3 Formulation precipitation and phase separation One 2 2 Comparative Example 4 Formulation precipitation and phase separation One 2 One <Evaluation items>
- Cleaning effect: the better the hair is washed, the higher the score
- Softness of wet hair: The softer the hair being rinsed, the higher the score
- Softness after drying: The softer the hair after rinsing and drying, the higher the score

Experimental Example 2: Confirmation of the effect of Sphingomonas fermented extract as a thickener

(1) Preparation of Comparative Examples 5 to 8

By using the components described in Table 3 below, Examples and Comparative Examples of the composition according to the present invention were prepared. Comparative Examples 5 to 8 are hair cleaning compositions in which a thickener component commonly used in the art is added instead of the Sphingomonas fermented extract in Example 3. Table 3 The unit of component content is weight %.

The specific manufacturing method is the same as in Examples 1 to 8.

(2) Formulation stability evaluation

The formulation stability according to Example 3 and Comparative Examples 5 to 8 was tested, and the results are shown in Table 4. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, in Example 3, there was no precipitation or phase separation of the formulation of the hair cleanser, and the formulation was stably formed. On the other hand, in Comparative Examples 5 to 8 in which other thickeners were used instead of the Sphingomonas fermented extract, the formulation could not be stably formed due to precipitation and phase separation of the formulation. The hair cleanser prepared using the composition according to Examples and Comparative Examples is shown in FIG. 2 .

(3) Evaluation of usability

In order to examine the feeling of use of the compositions according to Example 3 and Comparative Examples 5 to 8, the cleaning effect and conditioning effect items were evaluated, and the results are shown in Table 4. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, in the case of Example 3, high scores were obtained in all of the cleaning effect, the softness of wet hair, and the softness of the hair after drying, thereby having an excellent feeling of use, whereas in Comparative Examples 5 to 8, the precipitation and phase separation of the formulation As a result, it was confirmed that the feeling of use was not good because the scores of the cleaning effect and the conditioning effect were low.

division formulation cleaning effect conditioning effect wet hair softness hair softness after drying Example 3 Formulation is stably formed 5 3 4 Comparative Example 5 Formulation precipitation and phase separation 3 One One Comparative Example 6 Formulation precipitation and phase separation 2 One One Comparative Example 7 Formulation precipitation and phase separation 2 2 2 Comparative Example 8 Formulation precipitation and phase separation 3 2 2 <Evaluation items>
- Cleaning effect: the better the hair is washed, the higher the score
- Softness of wet hair: The softer the hair being rinsed, the higher the score
- Softness after drying: The softer the hair after rinsing and drying, the higher the score

Experimental Example 3: Confirmation of effect according to the ratio of sphingomonas fermented extract and auxiliary thickener

(1) Preparation of Examples 9 to 11 and Comparative Examples 9 to 11

Examples of compositions according to the present invention were prepared using the components shown in Table 5 below. Table 5 The unit of component content is weight %.

Examples 9 to 11 and Comparative Examples 10 and 11 are hair wash compositions in which the ratio of the Sphingomonas fermented extract and the auxiliary thickener is changed, and Comparative Example 9 is a hair cleanser composition in the case where the auxiliary thickener is not added. Table 5 The unit of component content is weight %.

The specific manufacturing method is the same as in Examples 1 to 8.

(2) Formulation stability evaluation

The formulation stability according to Examples 9 to 11 and Comparative Examples 9 to 11 was tested, and the results are shown in Table 6. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, in Examples 9 to 11, it was confirmed that the formulation was stably formed without precipitation or phase separation of the formulation of the hair cleanser.

On the other hand, in Comparative Example 9 in which no auxiliary thickener was added and Comparative Example 11 in which the ratio of auxiliary thickener to Sphingomonas fermented extract was large, a formulation was formed, but phase separation of the formulation occurred at high temperature (40°C). The formulation did not remain stable. In addition, in the case of Comparative Example 10, in which the ratio of the auxiliary thickener to the Sphingomonas ferment extract was small, the formulation could not be stably formed due to precipitation and phase separation of the formulation. The hair cleanser prepared using the composition according to Examples and Comparative Examples is shown in FIG. 3 .

(3) Evaluation of usability

In order to find out the feeling of use of the compositions according to Examples 9 to 11 and Comparative Examples 9 to 11, the cleaning effect and conditioning effect items were evaluated, and the results are shown in Table 6. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, in the case of Examples 9 to 11, it was confirmed that the cleaning effect, the softness of wet hair, and the softness of the hair after drying all obtained high scores to have an excellent feeling of use. On the other hand, in the case of Comparative Examples 9 to 11, it was confirmed that the cleaning effect and conditioning effect scores were low, so that the feeling of use was not good.

division formulation cleaning effect conditioning effect wet hair softness hair softness after drying Example 9 Formulation is stably formed 4 3 5 Example 10 Formulation is stably formed 4 5 4 Example 11 Formulation is stably formed 3 5 4 Comparative Example 9 Phase separation occurs at high temperature (40℃) 2 2 One Comparative Example 10 Formulation precipitation and phase separation 3 One 2 Comparative Example 11 Phase separation occurs at high temperature (40℃) One 3 2 <Evaluation items>
- Cleaning effect: the better the hair is washed, the higher the score
- Softness of wet hair: The softer the hair being rinsed, the higher the score
- Softness after drying: The softer the hair after rinsing and drying, the higher the score

Experimental Example 4: Confirmation of the effect according to the content of the auxiliary thickener

(1) Preparation of Examples 12 and 13 and Comparative Examples 12 and 13

Examples of compositions according to the present invention were prepared using the components shown in Table 7 below. Table 7 The unit of component content is weight %.

Examples 12 and 13 and Comparative Examples 12 and 13 are hair wash compositions in which the content of the auxiliary thickener is changed. Table 7 The unit of component content is weight %.

The specific manufacturing method is the same as in Examples 1 to 8.

(2) Formulation stability evaluation

The formulation stability according to Examples 12 and 13 and Comparative Examples 12 and 13 was tested, and the results are shown in Table 8. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, in Examples 12 and 13, it was confirmed that the formulation of the hair cleanser did not precipitate or phase separated, and the formulation was stably formed.

On the other hand, in the case of Comparative Example 12 with a small content of the auxiliary thickener, the formulation could not be stably formed due to precipitation and phase separation of the formulation, and in Comparative Example 13 with a large content of the auxiliary thickener, the formulation was formed However, the formulation was not stably maintained, such as phase separation of the formulation at high temperature (40° C.). The hair cleanser prepared using the compositions according to Examples and Comparative Examples is shown in FIG. 4 .

(3) Evaluation of usability

In order to find out the feeling of use of the compositions according to Examples 12 and 13 and Comparative Examples 12 and 13, the cleaning effect and conditioning effect items were evaluated, and the results are shown in Table 8. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, in the case of Examples 12 and 13, it was confirmed that the cleaning effect, the softness of wet hair, and the softness of the hair after drying all obtained high scores to have an excellent feeling of use. On the other hand, in the case of Comparative Examples 12 and 13, it was confirmed that the cleaning effect and conditioning effect scores were low, so that the feeling of use was not good.

division formulation cleaning effect conditioning effect wet hair softness hair softness after drying Example 12 Formulation is stably formed 5 4 3 Example 13 Formulation is stably formed 3 4 4 Comparative Example 12 Formulation precipitation and phase separation One One 3 Comparative Example 13 Phase separation occurs at high temperature (40℃) 3 One One <Evaluation items>
- Cleaning effect: the better the hair is washed, the higher the score
- Softness of wet hair: The softer the hair being rinsed, the higher the score
- Softness after drying: The softer the hair after rinsing and drying, the higher the score

Experimental Example 5: Confirmation of effects according to the ratio of the first auxiliary thickener to the second auxiliary thickener

(1) Preparation of Examples 14 to 16 and Comparative Examples 14 to 17

Examples of compositions according to the present invention were prepared using the components shown in Table 9 below. Table 9 The unit of component content is weight %.

Examples 14 to 16 are hair wash compositions in which the ratios of the first auxiliary thickener and the second auxiliary thickener are changed, and Comparative Examples 14 and 15 are hair wash compositions when one of the different auxiliary thickeners is omitted, Comparative Examples 16 and 17 are hair wash compositions in which the ratios of the first auxiliary thickener and the second auxiliary thickener are changed. Table 9 The unit of component content is weight %.

The specific manufacturing method is the same as in Examples 1 to 8.

(2) Formulation stability evaluation

The formulation stability according to Examples 14 to 16 and Comparative Examples 14 to 17 was tested, and the results are shown in Table 10. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, it was confirmed that Examples 14 to 16 did not cause precipitation or phase separation of the formulation of the hair cleanser, and the formulation was stably formed.

On the other hand, in Comparative Examples 14 and 15 in which one auxiliary thickener was omitted among the different types of auxiliary thickeners, and in Comparative Example 16 in which the ratio of the second auxiliary thickener to the first auxiliary thickener was small, precipitation and phase separation of the formulation This phenomenon occurred and the formulation could not be stably formed. In addition, in Comparative Example 17, in which the ratio of the second auxiliary thickener to the first auxiliary thickener was large, the formulation was formed, but the formulation was not stably maintained, such as phase separation of the formulation at high temperature (40° C.). The hair cleaners prepared using the compositions according to Examples and Comparative Examples are shown in FIG. 5 .

(3) Evaluation of usability

In order to examine the feeling of use of the compositions according to Examples 14 to 16 and Comparative Examples 14 to 17, the cleaning effect and conditioning effect items were evaluated, and the results are shown in Table 10. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, in the case of Examples 14 to 16, it was confirmed that the cleaning effect, the softness of wet hair, and the softness of the hair after drying all obtained high scores to have an excellent feeling of use. On the other hand, in the case of Comparative Examples 14 to 17, it was confirmed that the cleaning effect and conditioning effect scores were low, so that the feeling of use was not good.

division formulation cleaning effect conditioning effect wet hair softness hair softness after drying Example 14 Formulation is stably formed 4 5 3 Example 15 Formulation is stably formed 5 4 4 Example 16 Formulation is stably formed 3 5 4 Comparative Example 14 Formulation precipitation and phase separation 2 2 One Comparative Example 15 Formulation precipitation and phase separation 2 3 One Comparative Example 16 Formulation precipitation and phase separation One One 3 Comparative Example 16 Phase separation occurs at high temperature (40℃) 3 One One <Evaluation items>
- Cleaning effect: the better the hair is washed, the higher the score
- Softness of wet hair: The softer the hair being rinsed, the higher the score
- Softness after drying: The softer the hair after rinsing and drying, the higher the score

Experimental Example 6: Confirmation of effects according to the components of the cationic conditioning agent

(1) Preparation of Examples 17 to 24

Examples of compositions according to the present invention were prepared using the components shown in Table 11 below. Table 11 The unit of component content is weight %.

Examples 17 to 24 are hair wash compositions in which the components of each cationic conditioning agent are changed from the compositions of Examples 1 to 8.

The specific manufacturing method is the same as in Examples 1 to 8.

(2) Evaluation of formulation stability and feeling of use

The formulation stability according to Examples 17 to 24 was tested, and the cleaning effect and conditioning effect items were evaluated, and the results are shown in Table 12. The experimental method is the same as in the case of Experimental Example 1.

As a result of the experiment, it was confirmed that Examples 17 to 24 did not cause precipitation or phase separation of the formulation of the hair cleanser, and the formulation was stably formed. The hair cleanser prepared using the composition according to the example is shown in FIG. 6 .

In addition, Examples 17 to 24 obtained high scores in all of the cleaning effect, the softness of wet hair, and the softness of the hair after drying, confirming that they had an excellent feeling of use.

division formulation cleaning effect conditioning effect wet hair softness hair softness after drying Example 17 Formulation is stably formed 5 3 4 Example 18 Formulation is stably formed 4 3 4 Example 19 Formulation is stably formed 5 3 4 Example 20 Formulation is stably formed 4 4 4 Example 21 Formulation is stably formed 3 5 5 Example 22 Formulation is stably formed 5 3 3 Example 23 Formulation is stably formed 5 3 4 Example 24 Formulation is stably formed 5 4 4 <Evaluation items>
- Cleaning effect: the better the hair is washed, the higher the score
- Softness of wet hair: The softer the hair being rinsed, the higher the score
- Softness after drying: The softer the hair after rinsing and drying, the higher the score

As described above in detail a specific part of the content of the present invention, for those of ordinary skill in the art, this specific description is only a preferred embodiment, and the scope of the present invention is not limited thereby It will be obvious. Accordingly, the substantial scope of the present invention will be defined by the appended claims and their equivalents.

Claims (18)

Sphingomonas fermented extract;
cationic conditioning agents; and
a heterogeneous auxiliary thickener comprising a first auxiliary thickener and a second auxiliary thickener;
The sphingomonas fermented extract is included in an amount of 0.05 to 1.5% by weight relative to the total weight of the composition, and the cationic conditioning agent is included in an amount of 0.01 to 5% by weight relative to the total weight of the composition,
The first auxiliary thickener is included in an amount of 0.1 to 1.5% by weight based on the total weight of the composition, and the second auxiliary thickener is included in an amount of 0.1 to 2.5% by weight based on the total weight of the composition. The method of claim 1,
The weight ratio of the cationic conditioning agent to the fermented Sphingomonas extract is 0.05 to 1.5: 0.01 to 5, a hair cleanser composition. delete The method of claim 1,
The cationic conditioning agent, cationic guar (Cationic Guar), polyquaternium (Polyquaternium), polyquaternium-7 (Polyquaternium-7), polyquaternium-10 (Polyquaternium-10), polyquaternium-47 (Polyquaternium) -47), cellulose, acrylic ester, methacrylic ester, polysaccharide, polyamino amide derivative (Polyamino Amide Derivative) and cationic protein (Cationic Protein) A hair cleanser composition, characterized in that at least one selected from the group. delete delete The method of claim 1,
The auxiliary thickener, hair detergent composition, characterized in that contained in 0.2 to 4.0% by weight based on the total weight of the composition. The method of claim 1,
The weight ratio of the auxiliary thickener to the Sphingomonas fermented extract is 1: 0.13 to 80, a hair cleanser composition. delete The method of claim 1,
The weight ratio of the second auxiliary thickener to the first auxiliary thickener is 1:1 to 2, the hair cleanser composition. The method of claim 1,
The first auxiliary thickener, Trihydroxystearin, Carbomer, Acrylates/C10-30 Alkyl Acrylate Crosspolymer, Acrylates Copolymer), Acrylates/Beheneth-25 Methacrylate Copolymer, Polyacrylate, Hydroxyethylcellulose, Xanthan Gum, Dehydroxanthan Gum (Dehydroxanthan Gum), PEG-150 Pentaerythrityl Tetrastearate (PEG-150 Pentaerythrityl Tetrastearate) and PEG-120 Methyl Glucose Dioleate (PEG-120 Methyl Glucose Dioleate) at least one selected from the group consisting of Characterized in the hair cleanser composition. delete The method of claim 1,
The second auxiliary thickener is a C12-22 fatty alcohol (C12-22 Fatty Alcohol), characterized in that, hair wash composition. delete The method of claim 1,
A hair cleanser composition further comprising at least one of a surfactant and a polyol. 16. The method of claim 15,
The surfactant is, characterized in that at least one selected from the group consisting of anionic surfactants, amphoteric surfactants and nonionic surfactants, a hair cleanser composition. 16. The method of claim 15,
The polyol is, glycerin (Glycerin), methylpropanediol (Methylpropanediol), propylene glycol (Propylene Glycol), dipropylene glycol (Dipropylene Glycol), sorbitol (Sorbitol), butylene glycol (Butylene Glycol) and glycerol A hair cleanser composition, characterized in that at least one selected from the group consisting of less compounds. 16. The method of claim 15,
The polyol is, characterized in that contained in 0.01 to 90% by weight based on the total weight of the composition, hair cleanser composition.

Images