JP5748681B2 - Transparent liquid cleaning material - Google Patents

Description

  The present invention relates to a transparent liquid cleaning material that is transparent and liquid. More specifically, the present invention relates to a transparent liquid cleaning material that is suitably used for cleaning skin or hair.

  Cleaning agents are roughly classified into two types, surfactant-type cleaning agents and solvent-type cleaning agents, depending on the cleaning mechanism.

  A surfactant-type cleaning material is a cleaning material that provides a cleaning effect by utilizing the emulsification, dispersion, and solubilizing action of a surfactant. Examples of the surfactant type detergent include soap and shampoo. In soaps and shampoos, anionic surfactants and amphoteric surfactants are blended as cleaning ingredients. In addition, it is known that additives such as a foaming agent, a conditioning component and a moisturizing component can be blended with soap and shampoo. As the foam increasing agent, fatty acid monoethanolamide, which is a nonionic surfactant, is used. Cationic surfactants and cationic polymers are used as conditioning components. Glycine betaine is used as a moisturizing component.

  In recent years, methods for blending oily components such as higher alcohols and pasty oils into soaps and shampoos have been proposed for the purpose of enhancing the foaming effect and imparting a moist feeling (Patent Documents 1 to 3). However, in the same way that the washing power of soap and shampoo is reduced due to sebum and oil stains, the washing power is reduced when an oily component is added to the soap and shampoo. Moreover, since an oily component is a defoaming component, foaming power will fall when an oily component is mix | blended with soap or shampoo. In addition, when the oil component is blended with soap or shampoo, there is no problem as long as the blend amount of the oil component is within the range of the solubilization amount of the preparation, but when the solubilization amount is exceeded, the preparation is emulsified. This results in the problem of loss of transparency and poor stability. In particular, when the emulsion is liquid, it is difficult to ensure stability from its properties. From the above, the blending of the oil component into the liquid surfactant type detergent is limited.

  Further, the improvement of the detergency can be easily achieved by increasing the blending amount of the surfactant. However, it is known that when a large amount of surfactant is blended, thickening or gelation occurs and the feeling of use decreases. For this reason, attempts have been made to improve detergency while suppressing a decrease in feeling of use by various methods rather than simply increasing the amount of surfactant. For example, a method of blending a silicone surfactant (Patent Document 4), a method of blending a water-soluble oil such as succinic acid diester (Patent Document 5), a method of using a surfactant phase generated by blending a surfactant ( Patent Document 6) has been proposed. These methods can maintain an excellent feeling of use to some extent. However, when these methods are adopted, for example, the cleaning performance against oil stains that are difficult to remove, such as mascara and hair wax, is not sufficient. Therefore, when the above method is adopted, it is difficult to sufficiently wash away mascara and the like with the skin cleansing agent, and it is difficult to sufficiently wash away hair wax and the like with the hair cleansing agent.

  On the other hand, a solvent-type cleaning material is a cleaning material that contains an oily component as a main component as a solvent, and has a cleaning effect by dissolving oil stains or the like in the blended oily component and detaching from the base. As an example of the solvent-type cleaning agent, a cleansing agent that is a cleaning agent for skin can be given. Examples of cleansing agents include clear liquid cleansing oil that is a single-phase oil (which may solubilize a very small amount of water), cleansing cream (milk) that is an emulsified type of W / O or O / W, and nonion. There are cleansing gels (gels) and cleansing liquids based on special transparent one-phase structures (phases) containing surfactants, polyols, water and a large amount of oil. Since these solvent-type detergents contain a large amount of oily components, they exhibit high detergency against oil stains that are difficult to remove, such as the aforementioned mascara and hair wax.

  These four types of cleansing agents have greatly different effects due to the difference in the cleaning mechanism (phase state). Specifically, an emulsifying type cleansing cream has excellent washability but has the lowest detergency. Cleansing oil, which is a single phase of oil, has the best detergency, but it does not have excellent washability. Cleansing gels and cleansing liquids have a higher detergency than cleansing creams that are emulsified because they are based on special structures. Furthermore, cleansing gels and cleansing liquids can provide a much better feeling of use and functionality than cleansing oils, since face washing in multiple steps is unnecessary in the scene of washing away. In addition, liquid cleansing liquids exhibit properties that are superior in usability, such as spreadability and makeup familiarity, than solid cleansing gels with different structures. However, cleansing liquids that are most excellent in the feeling of use also have a viscosity unique to the preparation and an excellent detergency, but the feeling of use is not satisfactory.

  Moreover, since the cleansing liquid is based on a special structure, stability, functionality, and feeling of use are limited and determined by the type and amount of components. For example, when a special structure breaks down, transparency is deteriorated and stability is deteriorated, and two-phase separation occurs. For this reason, it is difficult to change the blending, configuration and blending amount of optional components for the purpose of improving functionality and usability. In addition, liquid cleansing liquids are more susceptible to stability due to structure formation than solid cleansing gels, and it is difficult to adjust functionality and feeling of use. For example, when the amount of the surfactant is increased in order to improve stability and detergency, the preparation is thickened and the feeling of use is lowered. If the amount of water is increased to improve the feeling of use or reduce the viscosity of the preparation, the stability is lost. In addition, when anionic surfactants or amphoteric surfactants are used to provide cleaning properties with components other than oily components, loss of transparency, deterioration of stability, and decrease in use feeling due to thickening of the formulation occur. .

  For the above reasons, detergent-type detergents such as soap and shampoo are excellent in usability, but they are sufficiently satisfactory in cleaning against hard-to-drop oil stains such as mascara and hair wax. It is not a thing. Solvent-type detergents are cleansing liquids that exhibit excellent cleaning properties against oil stains, such as mascara and hair wax, but are relatively excellent in use feeling among solvent-type detergents. However, the feeling of use is not fully satisfactory. In addition, in the cleansing liquid, it is also difficult to change the blending, composition and blending amount of optional components for the purpose of improving functionality and usability. Specifically, when an anionic surfactant or an amphoteric surfactant is added to the cleansing liquid to provide cleaning properties with components other than oily components, the feeling of use due to loss of transparency, deterioration of stability, and thickening Is likely to decrease. For this reason, it is difficult to give various functions to the cleansing liquid. In addition, since a large amount of the oil component is blended, it is difficult to impart foaming properties to the cleansing liquid.

JP 05-017342 A Japanese Patent Laid-Open No. 06-287595 JP 2006-335673 A JP 05-179293 A JP 2001-226234 A Japanese Patent Laid-Open No. 2002-020791

  The present invention can further suppress the deterioration of the formulation caused by the increase in viscosity caused by the incorporation of the surfactant, further maintain transparency, improve the stability of the formulation, and improve the detergency against oil stains that are difficult to remove. It is an object to provide a transparent liquid cleaning material.

  According to a broad aspect of the present invention, a nonionic surfactant, at least one of an anionic surfactant and an amphoteric surfactant, an oily component that is liquid at 25 ° C., and at least one of a polyol and ethanol. There is provided a transparent liquid cleaning material containing a seed and a betaine compound, wherein the content of the oily component which is liquid at 25 ° C. is 5 to 40% by mass.

  In a specific aspect of the transparent liquid detergent according to the present invention, the nonionic surfactant is at least selected from the group consisting of alkyl glyceryl ether, glycol fatty acid ester, glycerin fatty acid ester, polyoxyalkylene glyceryl ether fatty acid ester, and fatty acid amide. One type.

  In another specific aspect of the transparent liquid cleaning material according to the present invention, the betaine compound is glycine betaine.

  In still another specific aspect of the transparent liquid cleaning material according to the present invention, the anionic surfactant is at least one selected from the group consisting of a carboxylate, a sulfate ester salt, a sulfonate salt, and a phosphate ester salt. The amphoteric surfactant is at least one of an amino acid type amphoteric surfactant and a betaine type amphoteric surfactant.

  In another specific aspect of the transparent liquid detergent according to the present invention, the anionic surfactant is at least one of fatty acid soap and polyoxyethylene alkyl ether type anionic surfactant, and the amphoteric surfactant Is a betaine amphoteric surfactant.

  The transparent liquid detergent of the present invention comprises a nonionic surfactant, at least one of an anionic surfactant and an amphoteric surfactant, an oily component that is liquid at 25 ° C., and at least one of a polyol and ethanol. Since the content of the oil component that contains seeds and a betaine compound and is liquid at 25 ° C. is 5 to 40% by mass, the deterioration of the formulation caused by the increase in viscosity caused by the incorporation of the surfactant is suppressed. On the other hand, the transparency can be further maintained, the formulation stability can be improved, and the detergency against oil stains which are difficult to remove can be improved.

  The transparent liquid cleaning material of the present invention is transparent and liquid. The transparent liquid detergent of the present invention comprises (A) a nonionic surfactant, (B) at least one of an anionic surfactant and an amphoteric surfactant, and (C) an oil component that is liquid at 25 ° C. , (D) at least one of a polyol and ethanol, and (E) a betaine compound. In the transparent liquid cleaning material of this invention, content of the oil-based component which is liquid at the said 25 degreeC is 5-40 mass%. In the present invention, while suppressing the deterioration of the formulation caused by the increase in viscosity caused by the incorporation of the surfactant, it is possible to maintain transparency further, improve the stability of the formulation, and improve the detergency against oil stains that are difficult to remove. . Specific examples of the deterioration of the preparation include deterioration of the spreadability of the preparation, deterioration of the compatibility between the preparation and skin and hair, and deterioration of the compatibility between the preparation and dirt.

  Hereafter, the detail of each component contained in the transparent liquid cleaning material of this invention is demonstrated.

((A) Nonionic surfactant)
The nonionic surfactant is not particularly limited. For example, alkyl glyceryl ether, polyoxyalkylene alkyl ether, polyoxyalkylene hydrogenated castor oil, glycol fatty acid ester, glycerin fatty acid ester, polyoxyalkylene glyceryl ether fatty acid ester, sorbitan fatty acid ester , Polyoxyalkylene sorbitan fatty acid ester, fatty acid amide, silicone surfactant, amino acid-based nonionic surfactant, and the like. As for the said nonionic surfactant, only 1 type may be used and 2 or more types may be used together.

  Examples of the alkyl glyceryl ether include monocetyl glyceryl ether, monooleyl glyceryl ether, monoisostearyl glyceryl ether, monoisostearyl diglyceryl ether, glycerin mono 2-ethylhexyl ether, and the like.

  A commercially available product may be used as the alkyl glyceryl ether. Commercially available products of the above alkyl glyceryl ethers include, for example, monocetyl glyceryl ether: NIKKOL Kimyl Alcohol 100 (trade name, manufactured by Nikko Chemicals), monooleyl glyceryl ether: NIKKOL seraquil alcohol (trade name, manufactured by Nikko Chemicals) Monoisostearyl glyceryl ether: Penetol GE-IS (trade name, manufactured by Kao Corporation), monolauryl tetraglyceryl ether: PGLAL ML04 (trade name, manufactured by Daicel Chemical Industries), glycerin mono 2-ethylhexyl ether: Sensiva SC 50 ( Trade name, manufactured by Schulke & Mayr).

  Examples of the polyoxyalkylene alkyl ether include polyoxyethylene (10) oleyl ether, polyoxyethylene (10) isostearyl ether, polyoxyethylene (25) octyldodecyl ether, polyoxyethylene (20) decyltetradecyl ether. And polyoxyethylene (7) polyoxypropylene (2) decyl ether. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  A commercially available product may be used as the polyoxyalkylene alkyl ether. Commercially available products of the above polyoxyalkylene alkyl ether include, for example, polyoxyethylene oleyl ether: EMALEX 510 (trade name, manufactured by Nippon Emulsion Co., Ltd.), polyoxyethylene isostearyl ether: EMALEX 1810 (trade name, manufactured by Japan Emulsion Co., Ltd.) , Polyoxyethylene octyldodecyl ether: EMALEX OD-10 (trade name, manufactured by Japan Emulsion), polyoxyethylene decyl tetradecyl ether: EMALX 2410 (trade name, manufactured by Japan Emulsion), polyoxyethylene polyoxypropylene decyl ether : EMALEX DAPE-0205 (trade name, manufactured by Nippon Emulsion Co., Ltd.).

  Examples of the polyoxyalkylene hydrogenated castor oil include polyoxyethylene (60) hydrogenated castor oil. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  A commercially available product may be used as the polyoxyalkylene hydrogenated castor oil. As a commercial item of the said polyoxyalkylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil: EMALEX HC-60 (trade name, manufactured by Nippon Emulsion Co., Ltd.) and the like can be mentioned.

  Examples of the glycol fatty acid ester include propylene glycol monoisostearate, propylene glycol diisostearate, polyethylene glycol monolaurate (12), polyethylene glycol monoisostearate (12), polyethylene glycol diisostearate (8), and the like. In addition, the numerical value in a parenthesis represents the addition mole number of ethylene glycol.

  A commercially available product may be used as the glycol fatty acid ester. Examples of commercially available glycol fatty acid esters include glycol stearate: EMALEX EGS-A (trade name, manufactured by Nippon Emulsion Co., Ltd.), propylene glycol monoisostearate: prisoline 2034 (trade name, manufactured by Croda), and propylene diisostearate. Glycol: EMALX PG-di-1S (trade name, manufactured by Nippon Emulsion Co., Ltd.), Polyethylene glycol monolaurate: EMALX PEL-12 (trade name, manufactured by Japan Emulsion Co., Ltd.), Polyethylene glycol monoisostearate: EMALX PEIS-12EX (trade name) , Manufactured by Nippon Emulsion Co., Ltd.), polyethylene glycol diisostearate: EMALEX 600 di-1SEX (trade name, manufactured by Nippon Emulsion Co., Ltd.), and the like.

  Examples of the glycerin fatty acid ester include glyceryl monostearate, glyceryl isostearate, glyceryl tri (caprylic acid / capric acid), diglyceryl monostearate, tetraglyceryl monolaurate, and decaglyceryl diisostearate.

  A commercially available product may be used as the glycerin fatty acid ester. Examples of commercially available glycerin fatty acid esters include glyceryl monoisostearate: EMALEX GWIS-100EX (trade name, manufactured by Nippon Emulsion), tri (caprylic acid / capric acid) glyceryl: EMALEX KTG (trade name, Japan Emulsion) Manufactured), decaglyceryl monolaurate: Sunsoft Q-12Y, Sunsoft A-12E, Sunsoft Q-12S (all trade names, manufactured by Taiyo Kagaku Co., Ltd.), monoisostearate diglyceryl: NIKKOL DGMIS (trade names, Nikko) Chemical Co., Ltd.), deisoglyceryl diisostearate (trade name, manufactured by Nippon Emulsion Co., Ltd.) and the like.

  Examples of the polyoxyalkylene glyceryl ether fatty acid ester include polyoxyethylene (8) glyceryl monoisostearate, polyoxyethylene (20) glyceryl monoisostearate, polyoxyethylene (20) glyceryl triisostearate, polyoxyethylene ( 7) Palm oil fatty acid glyceryl, polyoxyethylene (8) (caprylic acid / capric acid) glyceryl and the like. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  A commercially available product may be used as the polyoxyalkylene glyceryl ether fatty acid ester. As a commercial item of the said polyoxyalkylene glyceryl ether fatty acid ester, for example, polyisoethylene glyceryl monoisostearate: EMALEX GWIS-120 (trade name, manufactured by Nippon Emulsion Co., Ltd.), polyoxyethylene glyceryl triisostearate: EMALEX GWIS-320 (Trade name, manufactured by Nippon Emulsion Co., Ltd.), polyoxyethylene coconut oil fatty acid glyceryl: M fine oil COG-7M (trade name, manufactured by Miyoshi Oil & Fats Co., Ltd.), polyoxyethylene (caprylic acid / capric acid) glyceryl: M fine oil MCG -8M (trade name, manufactured by Miyoshi Oil & Fats Co., Ltd.).

  Examples of the sorbitan fatty acid ester include sorbitan monoisostearate, sorbitan tristearate, sorbitan sesquistearate, coconut oil fatty acid sorbitan, and the like.

  A commercial product may be used as the sorbitan fatty acid ester. Examples of commercially available sorbitan fatty acid esters include sorbitan monoisostearate: EMALEX SPIS-100 (trade name, manufactured by Nippon Emulsion Co., Ltd.), sorbitan sesquiisostearate: EMALEX SSIS-150 (trade name, manufactured by Nippon Emulsion Co., Ltd.), and the like. Is mentioned.

  Examples of the polyoxyalkylene sorbitan fatty acid ester include polyoxyethylene (20) sorbitan monooleate, polyoxyethylene (20) sorbitan trioleate, polyoxyethylene (30) sorbitan tetraoleate, polyoxyethylene (20 ) Palm oil fatty acid sorbitan and the like. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  Commercially available products may be used as the polyoxyalkylene sorbitan fatty acid ester. As a commercial item of the said polyoxyalkylene sorbitan fatty acid ester, for example, monooleic acid polyoxyethylene sorbitan: EMALEX ET-8020 (trade name, manufactured by Nippon Emulsion Co., Ltd.), trioleic acid polyoxyethylene sorbitan: EMALEX ET-8040 ( Trade name, manufactured by Nippon Emulsion Co., Ltd.), tetraoleic acid polyoxyethylene sorbit: NIKKOL GO-430NV (trade name, manufactured by Nikko Chemicals), polyoxyethylene coconut oil fatty acid sorbitan: EMLAX ET-2020 (trade name, Nippon Emulsion Co., Ltd.) Manufactured).

  Examples of the fatty acid amide include coconut oil fatty acid diethanolamide, polyoxyethylene (3) coconut oil fatty acid monoethanolamide, and the like. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  As the fatty acid amide, a commercially available product may be used. Examples of commercially available fatty acid amides include coconut oil fatty acid diethanolamide: Amizole CDE (trade name, manufactured by Kawaken Fine Chemical Co., Ltd.), polyoxyethylene coconut oil fatty acid monoethanolamide: Amidette 2C (trade name, Kawaken Fine Chemical Co., Ltd.) Manufactured).

  Examples of the silicone surfactant include polyoxyethylene (12) / methylpolysiloxane copolymer. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  A commercially available product may be used as the silicone surfactant. As a commercial item of the said silicone surfactant, polyoxyethylene methyl polysiloxane copolymer: DOW CORNING TORAY SH 3771 M (brand name, the Toray Dow Corning company make) etc. are mentioned, for example.

  Examples of the amino acid-based nonionic surfactant include pyroglutamate isostearate polyoxyethylene (60) hydrogenated castor oil, lauroylglutamate polyoxyethylene (2) octyldodecyl ether diester, pyroglutamate oleate glyceryl, and the like. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  A commercially available product may be used as the amino acid-based nonionic surfactant. Examples of commercially available amino acid nonionic surfactants include lauroyl glutamic acid polyoxyethylene octyldodecyl ether diester: AMITER LGOD-2 (H) (trade name, manufactured by Nippon Emulsion Co., Ltd.).

  The nonionic surfactant preferably contains a fatty acid type nonionic surfactant from the viewpoint of obtaining a more stable transparent liquid detergent. In addition, the nonionic surfactant preferably contains one kind selected from the group consisting of alkyl glyceryl ether, glycol fatty acid ester, glycerin fatty acid ester, polyoxyalkylene glyceryl ether fatty acid ester and fatty acid amide, glycol fatty acid ester, More preferably, it contains at least one selected from the group of polyoxyalkylene glyceryl ether fatty acid esters and fatty acid amides.

  Content of the said nonionic surfactant is not specifically limited, It can change suitably according to the compounding quantity of another component. The content of the nonionic surfactant is usually from the viewpoint of further suppressing the deterioration of the formulation caused by the increase in viscosity caused by the blending of the nonionic surfactant, the viewpoint of reducing the squeaky feeling during application, and the feeling of tension after washing off. From the viewpoint of reducing the feeling of stiffness, the viewpoint of preventing the loss of transparency, and the viewpoint of preventing the deterioration of the stability, 100 to 100% by mass of the transparent liquid cleaning material, preferably 8 to 45% by mass, more preferably 10 to 40% by mass. %.

((B) at least one of anionic surfactant and amphoteric surfactant)
Although it does not specifically limit as said anionic surfactant, For example, carboxylic acid and its salt, sulfate ester and its salt, sulfonic acid and its salt, phosphate ester and its salt, etc. are mentioned.

  Examples of the carboxylic acid and salts thereof include, for example, kaurim laurate, potassium myristic acid, potassium coconut oil fatty acid, polyoxyethylene (5) lauryl ether acetic acid, polyoxyethylene (4) sodium tridecyl ether acetate, lauroylmethyl-β. -Sodium alanine, N-stearoyl-L-glutamate sodium, N-coconut oil fatty acid acyl-L-glutamate sodium, etc. are mentioned. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  Examples of the sulfate and its salt include sodium lauryl sulfate, sodium myristyl sulfate, hydrogenated coconut oil fatty acid sodium glyceryl sulfate, and polyoxyethylene (3) sodium lauryl ether sulfate. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  Examples of the sulfonic acid and its salt include sodium di (2-ethylhexyl) sulfosuccinate, disodium polyoxyethylene sulfosuccinate lauryl, polyoxyethylene sulfosuccinate (5) disodium lauroylethanolamide, N-stearoyl-N- Examples include methyl taurine sodium and coconut oil fatty acid methyl taurine sodium. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  As said phosphate ester and its salt, a sodium lauryl phosphate, polyoxyethylene (1) lauryl ether phosphoric acid, etc. are mentioned, for example. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  A commercially available product may be used as the anionic surfactant.

  Examples of commercially available carboxylic acids and salts thereof include, for example, kaurim laurate: NIKKOL potassium laurate: K-120 (trade name, manufactured by Nikko Chemicals), potassium myristate: cosmetic soap MF-K (trade name, Miyoshi) (Oil & Fats Co., Ltd.), palm oil fatty acid potassium: Alhome K-100 (trade name, manufactured by Shin Nippon Chemical Co., Ltd.), polyoxyethylene lauryl ether acetic acid: NIKKOL AKYPO RLM 45 NV (trade name, manufactured by Nikko Chemicals), polyoxy Sodium ethylene tridecyl ether acetate: NIKKOL ECT-3NEX (trade name, manufactured by Nikko Chemicals), Lauroylmethyl-β-alanine sodium: NIKKOL alaninate LN-30 (trade name, manufactured by Nikko Chemicals), N-stearoyl-L- Glutamic acid Sodium: Amisoft HS-11P (trade name, manufactured by Ajinomoto Co., Inc.), N-coconut oil fatty acid acyl-L-glutamate sodium: Amisoft CS-11 (trade name, manufactured by Ajinomoto Co., Inc.), and the like.

  Examples of commercially available sulfates and salts thereof include sodium lauryl sulfate: NIKKOL SLS (trade name, manufactured by Nikko Chemicals), sodium myristyl sulfate: NIKKOL SMS (trade name, manufactured by Nikko Chemicals), and hardened coconut oil fatty acid. Sodium glyceryl sulfate: NIKKOL SGC-80N (trade name, manufactured by Nikko Chemicals), sodium polyoxyethylene lauryl ether sulfate: Sinoline SPE-1300 (trade name, manufactured by Shin Nippon Chemical Co., Ltd.) and the like.

  Commercially available products of the above sulfonic acid and its salts include di (2-ethylhexyl) sodium sulfosuccinate solution: NIKKOL OTP-75 (trade name, manufactured by Nikko Chemicals), disodium lauryl polyoxyethylene sulfosuccinate: Burelite LSS ( Trade name, manufactured by Sanyo Chemical Industries), sulfosuccinic acid polyoxyethylene lauroylethanolamide disodium: burite A-5000 (trade name, manufactured by Sanyo Chemical Industries), N-myristoyl methyl taurine sodium: NIKKOL MMT (trade name, Nikko Chemicals), N-stearoyl-N-methyl taurine sodium: NIKKOL SMT (trade name, manufactured by Nikko Chemicals), palm oil fatty acid methyl taurine sodium: NIKKOL CMT-30 (trade name, Nikko Chemicals) ), And the like.

  Commercially available products of the above phosphate esters and salts thereof include sodium lauryl phosphate: NIKKOL SLP-N (trade name, manufactured by Nikko Chemicals), polyoxyethylene lauryl ether phosphate: NIKKOL phosten HLP-1 (trade name, Nikko) Chemicals).

  Although it does not specifically limit as said amphoteric surfactant, For example, amino acid type amphoteric surfactant, betaine type amphoteric surfactant, imidazoline type amphoteric surfactant, amine oxide type amphoteric surfactant, phosphate ester type double-sided surfactant And amino acid-based amphoteric surfactants.

  Examples of the amino acid type amphoteric surfactant include sodium β-lauroylaminopropionate and sodium N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine.

  Examples of the betaine-type amphoteric surfactant include lauric acid amidopropyl betaine, lauryldimethylaminoacetic acid betaine, and coconut oil fatty acid amidopropyl betaine.

  Examples of the imidazoline-type amphoteric surfactant include 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine.

  Examples of the amine oxide type amphoteric surfactant include lauryl dimethylamine oxide.

  Examples of the phosphate ester type double-sided activator include lecithin and hydrogenated soybean phospholipid.

  Examples of the amino acid-based amphoteric surfactant include N-lauroyl-L-arginine and N- [3-alkyl (12,14) oxy-2-hydroxypropyl] -L-arginine hydrochloride.

  Commercial products may be used as the amphoteric surfactant.

  Examples of the amino acid type amphoteric surfactant include β-lauroylaminopropionate sodium: Repon APL (trade name, manufactured by Sanyo Chemical Industries), N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium. : Repon 101-H (trade name, manufactured by Sanyo Chemical Industries).

  Examples of the betaine-type amphoteric surfactant include lauramide amidopropyl betaine: Amphitol 20AB (trade name, manufactured by Kao Corporation), lauryldimethylaminoacetic acid betaine: NIKKOL AM-301 (trade name, manufactured by Nikko Chemicals), palm Oil fatty acid amidopropyl betaine: NIKKOL AM-3130N (trade name, manufactured by Nikko Chemicals) and the like.

  Examples of the imidazoline-type amphoteric surfactant include 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine: Amphitol 20Y-B (trade name, manufactured by Kao Corporation).

  Examples of the amine oxide type amphoteric surfactant include lauryl dimethylamine oxide: Amphitol 20N (trade name, manufactured by Kao Corporation).

  Examples of the phosphoric acid ester type double-sided active agent include lecithin: Basis LS-60 (trade name, manufactured by Nisshin Oillio Co., Ltd.), hydrogenated soybean phospholipid: NIKKOL recinol S-10 (trade name, manufactured by Nikko Chemicals Co., Ltd.). Etc.

  Examples of the amino acid-based amphoteric surfactant include N-lauroyl-L-arginine: Amisafe LA-01 (trade name, manufactured by Ajinomoto Co., Inc.), N- [3-alkyl (12,14) oxy-2-hydroxypropyl]- L-arginine hydrochloride: Amisafe LMA-60 (trade name, manufactured by Ajinomoto Co., Inc.) and the like.

  The anionic surfactants and amphoteric surfactants may be used alone or in combination of two or more. As at least one of the anionic surfactants and amphoteric surfactants, only an anionic surfactant may be used, or an amphoteric surfactant may be used alone. An anionic surfactant and an amphoteric surfactant Both of them may be used. At least one of the anionic surfactant and the amphoteric surfactant is preferably an anionic surfactant, and is preferably an amphoteric surfactant. As for the said amphoteric surfactant, only 1 type may be used and 2 or more types may be used together. As for the said anionic surfactant, only 1 type may be used and 2 or more types may be used together.

  From the viewpoint of obtaining a stable transparent liquid detergent, the anionic surfactant is preferably at least one selected from the group consisting of carboxylates, sulfates, sulfonates and phosphates, and fatty acid soaps. And at least one of polyoxyethylene alkyl ether type anionic surfactants is more preferable. From the viewpoint of obtaining a stable transparent liquid detergent, the amphoteric surfactant is preferably at least one of an amino acid type amphoteric surfactant and a betaine type amphoteric surfactant, and is a betaine type amphoteric surfactant. More preferably.

  From the viewpoint of obtaining a more stable transparent liquid detergent, the anionic surfactant is preferably at least one selected from the group of carboxylates, sulfates, sulfonates and phosphates, Preferably, it is at least one of fatty acid soap and polyoxyethylene alkyl ether type anionic surfactant. The amphoteric surfactant is preferably at least one of amino acid type amphoteric surfactant and betaine type amphoteric surfactant, more preferably betaine type amphoteric from the viewpoint of obtaining a more stable transparent liquid detergent. Is a surfactant

  The total content of at least one of the anionic surfactant and the amphoteric surfactant is not particularly limited, and can be appropriately changed according to the blending amount of other components. The total content of at least one of the anionic surfactants and amphoteric surfactants is usually from the viewpoint of improving detergency, and the blending of at least one of the anionic surfactants and amphoteric surfactants From the viewpoint of further suppressing the deterioration of the formulation caused by the increase in viscosity caused by the above, the viewpoint of reducing the squeaky feeling at the time of application, the viewpoint of reducing the feeling of stickiness and stiffness after washing, the viewpoint of preventing the loss of transparency, and stability From the viewpoint of preventing the deterioration, it is preferably 0.1 to 25% by mass, more preferably 0.5 to 20% by mass in 100% by mass of the transparent liquid cleaning material.

((C) Oily component that is liquid at 25 ° C.)
The oily component that is liquid at 25 ° C. is not particularly limited, and examples thereof include oils and fats, hydrocarbon oils, higher alcohols, fatty acid esters, and silicone compounds. The oily component that is liquid at 25 ° C. is preferably at least one selected from the group consisting of fats and oils, hydrocarbon oils, higher alcohols, fatty acid esters, and silicone compounds. The oily component that is liquid at 25 ° C. preferably contains at least one of a fatty acid ester and a silicone compound. The oil component preferably contains fats and oils, preferably contains hydrocarbon oil, preferably contains higher alcohols, preferably contains fatty acid esters, and preferably contains silicone compounds.

  Examples of the oil include sunflower oil, cottonseed oil, soybean oil, olive oil, coconut oil, castor oil, rapeseed oil, and coconut oil.

  Examples of the hydrocarbon oil include liquid paraffin, liquid isoparaffin, light isoparaffin, squalane and the like.

  Examples of the higher alcohol include oleyl alcohol and octyldodecanol.

  Examples of the fatty acid ester include ethyl oleate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, octyldodecyl oleate, isopropyl isostearate, cetyl 2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, tetra Examples include 2-ethylhexanoic acid pentaerythritol, isocetyl octanoate, 2-ethylhexyl palmitate, isocetyl isostearate, octyldodecyl isostearate, octyldodecyl dimethyloctanoate, isononyl isononanoate, and dioctyl succinate.

  Examples of the silicone compound include methylpolysiloxane, methylphenylpolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylcyclopolysiloxane. And silicones.

  The oily components that are liquid at 25 ° C. may be used alone or in appropriate combination of two or more. The oily component that is liquid at 25 ° C. includes a branched fatty acid ester, a branched hydrocarbon oil, a phenyl-modified silicone, or a cyclic silicone from the viewpoint of obtaining a transparent liquid cleaning agent that has excellent usability and higher detergency. It is preferable.

  Preferable examples of the branched fatty acid ester include isopropyl myristate, isopropyl palmitate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, isononyl isononanoate and the like.

  Preferable examples of the branched hydrocarbon oil include liquid isoparaffin and light isoparaffin.

  Preferable examples of the phenyl-modified silicone or cyclic silicone include methylphenyl polysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, and the like.

  The content of the oily component that is liquid at 25 ° C. is 5 to 40% by mass, preferably 5 to 5% in 100% by mass of the transparent liquid detergent from the viewpoint of obtaining a transparent liquid detergent having excellent detergency. 35% by mass. The reason is that when the content of the oil component is less than 5% by mass, a transparent liquid cleaning material having excellent detergency cannot be obtained. This is because if the content of the oil component exceeds the upper limit, transparency is lost due to the oil component and stability is deteriorated.

((D) at least one of polyol and ethanol)
Although it does not specifically limit as at least 1 sort (s) of the said polyol and ethanol, For example, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, 1, 3- butylene glycol, 1, Examples include 2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, glycerin, concentrated glycerin, diglycerin, polyglycerin, and ethanol. The said polyol and ethanol may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate. As at least one of the polyol and ethanol, only the polyol may be used, only ethanol may be used, or both the polyol and ethanol may be used. At least one of the polyol and ethanol is preferably a polyol, and more preferably ethanol. As for the said polyol, only 1 type may be used and 2 or more types may be used together.

  The content of at least one of the polyol and ethanol is not particularly limited, and can be appropriately changed according to the blending amount of other components. From the viewpoint of obtaining a stable transparent liquid detergent, the total content of at least one of the polyol and ethanol is usually from 100% by mass, preferably from 5 to 35% by mass, more preferably from the viewpoint of obtaining a stable transparent liquid detergent. It is 5-30 mass%.

((E) Betaine compound)
The betaine compound has a betaine skeleton. The betaine compounds include betaine and betaine derivatives. Betaine and betaine derivatives are also called betaines. Betaine compounds are sometimes simply referred to as betaines. The betaine compound does not contain the surfactant described above.

  Examples of the betaine compound include glycine betaine, alanine betaine, γ-butyrobetaine, valine betaine, lysine betaine, glutamic acid betaine, homarine, trigonelline, carnitine, atrinin, and antopleurin. The said betaine compound may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate. The betaine compound is more preferably glycine betaine.

  A commercially available product may be used as the betaine compound. Examples of commercially available products of glycine betaine include amino coat (trade name, manufactured by Asahi Kasei Chemicals Corporation). Moreover, as a commercial item of the mixed raw material containing glycine betaine, for example, PRODUU 400 (trade name, manufactured by Ajinomoto Co., Inc.) and the like can be mentioned.

  Content of the said betaine compound is not specifically limited, It is possible to change suitably according to the compounding quantity of another component. The content of the betaine compound is usually a viewpoint of further suppressing deterioration of the formulation caused by the increase in viscosity caused by the combination of the nonionic surfactant and at least one of the anionic surfactant and the amphoteric surfactant. From the viewpoint of maintaining transparency, and from the viewpoint of preventing deterioration of the stability of the transparent liquid cleaning material due to the blending of the betaine compound, in 100% by weight of the transparent liquid cleaning material, preferably 0.5 to 35% by weight, more preferably Is 0.5-30 mass%.

(Other ingredients)
In the transparent liquid cleaning material of the present invention, in addition to the above-described components, components usually used in cosmetics can be appropriately blended depending on the purpose as long as the effects of the present invention are not impaired. Examples of the components include cationic surfactants, water-soluble thickeners, vitamins, antioxidants, preservatives, antibacterial agents, sequestering agents, pH adjusters and the like.

  Examples of the cationic surfactant include dimethyl stearylamine, dimethylaminopropylamide stearate, polyoxypropylene chloride (40) methyldiethylammonium chloride, dipolyoxyethylene chloride (2) oleylmethylammonium chloride, cetyltrimethylammonium chloride, and chloride. Coconut oil alkyldimethylammonium chloride, octadecyloxypropyltrimethylammonium chloride, γ-gluconamidopropyldimethylhydroxyethylammonium chloride, benzalkonium chloride, N-coconut oil fatty acid acyl-L-arginine ethyl DL-pyrrolidone carboxylate, etc. Can be mentioned. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  Examples of the water-soluble thickener include xanthan gum, carboxyvinyl polymer, alkyl acrylate copolymer, acrylic acid / alkyl methacrylate copolymer, (hydroxyethyl acrylate / acryloyldimethyltaurine sodium) copolymer, and (acryloyldimethyltaurine ammonium methacrylate). Polyoxyethylene (25) behenyl ether) crosspolymer, (acrylic acid / vinyl pyrrolidone) copolymer, (acrylates / polyoxyethylene (25) behenyl ether methacrylate) copolymer, (dimethylacrylamide / ethyltrimonium chloride methacrylate) copolymer , Hydroxypropylcellulose, hydroxypropylated phosphate cross-linked starch, hectorite, bentonite, silicic anhydride, etc. And the like. In addition, the numerical value in a parenthesis represents the addition mole number of alkylene oxide.

  Examples of the vitamins include thiamine, riboflavin, niacin, pantothenic acid, pyridoxine, biotin, folic acid, ascorbic acid, retinal, retinol, and tocopherol. These salts and derivatives may be used.

  Examples of the antioxidant include dibutylhydroxytoluene and sulfite.

  Examples of the preservative and the antibacterial agent include phenoxyethanol, methyl paraben, ethyl paraben, propyl paraben, butyl paraben, benzoate, methyl isothiazoline, triclosan, isopropyl methyl phenol, zinc pyrithione, piroctone olamine, sorbic acid, photosensitive Element, antibacterial zeolite, silver ion and the like.

  Examples of the sequestering agent include edetate, pentetate, etidronate, and the like.

  Examples of the pH adjuster include citric acid, lactic acid, glycolic acid, succinic acid, acetic acid, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, triethanolamine, isopropanolamine, 2-amino-2-methyl- Examples include 1,3-propanediol, arginine, sodium hydroxide, potassium hydroxide and the like.

(Other details of transparent liquid cleaning material)
In the transparent liquid cleaning material of the present invention, the special structure is preferably a transparent one-phase structure. In this case, the transparency of the preparation can be used as a measure of structure formation and stability determination. For example, an opaque liquid composition is an emulsified type that does not form a special structure, and exhibits a lower detergency than a case where a structure is formed. If the liquid composition is opaque, it can be easily determined that the liquid composition is not excellent in stability.

  The term “transparent” in the present invention means that when the liquid composition is placed in an annular transparent glass container having a diameter of 5 cm, the background behind the glass container can be visually observed through the glass container. “Transparent” includes translucent. The transparent liquid cleaning material of the present invention may be slightly turbid. Further, “liquid” in the present invention indicates that it is liquid at 25 ° C., and that the cleaning material has fluidity at 25 ° C.

  The transparent liquid cleaning material of the present invention can be produced by various methods. By mixing and stirring the constituent components of the present invention in an arbitrary order, the transparent liquid cleaning material of the present invention can be easily obtained. For example, components (A) to (D) are mixed and stirred to obtain a transparent liquid material. Subsequently, after adding purified water to the obtained transparent liquid material, mixing and stirring, the component (E) is added and dissolved to obtain the transparent liquid cleaning material of the present invention.

  In the transparent liquid detergent of the present invention, while suppressing the deterioration of the formulation caused by the increase in viscosity caused by the blending of the surfactant, the transparency is further maintained, the formulation stability is improved, and the detergency to oil stains that are difficult to remove. Can be increased. Examples of oil stains that are difficult to remove include oil stains represented by mascara and hair wax. The transparent liquid cleaning material of the present invention can be easily washed away even with mascara or hair wax.

  Because of such effects, the transparent liquid cleaning material of the present invention can be suitably used as a cleaning material for skin or hair.

  The transparent liquid cleaning material of the present invention is preferably used for cleaning hair or skin. The transparent liquid cleaning material of the present invention is preferably used for hair cleaning, and is also preferably used for skin cleaning. The transparent liquid cleaning material of the present invention is preferably a transparent liquid cleaning material for hair or skin. The transparent liquid detergent of the present invention is preferably a transparent liquid detergent for hair, and is also preferably a transparent liquid detergent for skin. The transparent liquid cleaning material of the present invention may be used by impregnating a carrier such as a nonwoven fabric or cotton.

  Hereinafter, the present invention will be described in more detail based on examples. The present invention is not limited only to the following examples. The blending amount represents “% by mass” unless otherwise specified. In the table, “POE” is an abbreviation for polyoxyethylene, and the numerical value in parentheses represents the number of added moles of polyoxyethylene.

(Sample preparation 1)
Each component was mix | blended according to the composition shown to Table 2, 3, and each liquid cleaning material of Examples 1-15 and Comparative Examples 1-14 was prepared. Using the obtained liquid cleaning materials, the following evaluation items were evaluated.

(Test Example 1: Measurement of viscosity)
Each liquid cleaning material immediately after preparation was preserve | saved for 24 hours on 25 degreeC conditions. The viscosity of each liquid detergent after storage for 24 hours was measured. As a viscometer, a tuning fork viscometer (SV-10A: manufactured by A & D) was used.

(Test Example 2: Evaluation of detergency against wax)
Ten professional evaluation panels evaluated the detergency of each of the obtained liquid detergents against wax by the following test method.

<Test method>
Each component was blended according to the composition shown in Table 1 below to obtain a test hair styling (wax).

  2 g of the obtained test hairdressing material was applied to 20 g and 20 cm hair bundles, and dried at 40 ° C. for 6 hours. Next, 5 g of the obtained liquid cleaning material was applied to the hair and blended. Then, sensory evaluation was performed according to the following five-stage evaluation criteria by washing with water.

  Regarding the “detergency against wax”, the case where the residual feeling and stickiness of the hairdressing material was low was evaluated as “good”. The detergency against wax was determined from the average score calculated from the scores based on the following evaluation criteria of 10 panelists according to the following criteria.

<Evaluation criteria>
5 points: very good 4 points: good 3 points: normal 2 points: bad 1 point: very bad

<Criteria>
◯: Average 4.0 points or more ○: Average 3.0 points or more and less than 4.0 points △: Average 2.0 points or more and less than 3.0 points ×: Average less than 2.0 points

(Test Example 3: Evaluation of “excellent spreadability on the skin”, “good makeup familiarity with mascara”, “detergency against mascara”, “good wash-off during cleaning”)
Ten professional evaluation panels used each liquid cleaning material obtained by the following test method. Evaluations were made on “excellent spreadability on the skin”, “excellent fit of mascara”, “detergency against mascara”, and “good wash-off during cleaning”.

<Test method>
A commercially available waterproof mascara was applied to a 3 × 3 cm square on the back of the hand and dried at 25 ° C. for 10 minutes. Next, 1.5 g of the obtained liquid cleaning material was applied to the coated surface of the mascara and made familiar. Then, sensory evaluation was performed according to the following five-stage evaluation criteria by washing with water.

  “Good spreadability on the skin” is “good” when resistance and squeaky feeling on the skin is low, and it is easy to spread like water, and “good makeup familiarity with mascara” When the mascara and the preparation quickly blend in with a low feeling of slipping on the top, it is considered as “good”, and the “detergency against mascara” is considered as “good” when the mascara removal effect is high, and “good washing off during washing” For the case, the case where the water was washed with water, the slipperiness and the oily feeling after drying were evaluated as “good”. Judgment was made according to the following criteria from the average score calculated from the scores of the following 10 panelists.

<Evaluation criteria>
5 points: very good 4 points: good 3 points: normal 2 points: bad 1 point: very bad

<Criteria>
◯: Average 4.0 points or more ○: Average 3.0 points or more and less than 4.0 points △: Average 2.0 points or more and less than 3.0 points ×: Average less than 2.0 points

(Test Example 4: Evaluation of stability)
Each obtained liquid washing | cleaning material was stored for 1.5 months on each conditions of 5 degreeC and 40 degreeC. The liquid cleaning material after storage was visually observed, and the stability was determined according to the following criteria.

<Criteria for stability>
○: Entirely uniform ×: Partially or entirely separated

  The compositions and results are shown in Tables 2 and 3 below.

  From the results shown in Table 2 and Table 3, the transparent liquid detergent of each Example maintained transparency even when at least one of an anionic surfactant and an amphoteric surfactant was blended, and was excellent. It turns out that it has stability. Moreover, it turns out that the transparent liquid cleaning material of each Example shows high detergency with respect to the mascara and hair wax which are oil stains which are hard to remove. On the other hand, in each liquid cleaning material of Comparative Examples 1-14, it turns out that a sufficiently satisfactory result is not obtained regarding cleaning property and stability. In addition, when Examples and Comparative Examples are compared, not only the stability improvement effect is obtained by the compounding of the betaine compound, but also the viscosity increase caused by the compounding of the surfactant is suppressed, and the extension is extended. It can be seen that the decrease in compatibility and makeup familiarity is reduced.

(Sample preparation 2)
Each component was mix | blended according to the composition shown in Table 4, and each liquid cleaning material of Examples 16-21 and Comparative Examples 15-19 was prepared. Using the obtained liquid cleaning materials, the following evaluation items were evaluated.

  About Examples 16-21 and Comparative Examples 15-19, it evaluated about the evaluation item of Test Examples 1-3 evaluated in Examples 1-15 and Comparative Examples 1-14. However, for Test Example 3, only “detergency against mascara” was evaluated. Furthermore, about Examples 16-21 and Comparative Examples 15-19, the following evaluation items were also evaluated.

(Test Example 5: Evaluation of foamability during discharge)
Each liquid cleaning material obtained was filled into a container of a phone former. Ten professional evaluation panels evaluated the foamability at the time of discharge by the following test method.

<Test method>
Each liquid cleaning material was discharged 10 times, and then the foaming property of each liquid cleaning material at the time of the 11th discharge was subjected to sensory evaluation according to the following five evaluation criteria.

  Regarding the “foaming property at the time of discharge”, the case where each liquid cleaning material had good foaming was evaluated as “good”. Judgment was made according to the following criteria from the average score calculated from the scores of the following 10 panelists.

<Evaluation criteria>
5 points: very good 4 points: good 3 points: normal 2 points: bad 1 point: very bad

<Criteria>
◯: Average 4.0 points or more ○: Average 3.0 points or more and less than 4.0 points △: Average 2.0 points or more and less than 3.0 points ×: Average less than 2.0 points

(Test Example 6: Evaluation of foam texture)
Following the evaluation of foaming properties at the time of ejection in Test Example 5, the same 10 expert evaluation panels evaluated the texture of the foam by the following test method.

<Test method>
After evaluating the foaming property at the time of discharge, sensory evaluation was performed on the texture of the foam immediately after the discharge according to the following five-level evaluation criteria.

  As for “bubble texture”, the case where the texture of the foam was fine was evaluated as “good”. Judgment was made according to the following criteria from the average score calculated from the scores of the following 10 panelists.

<Evaluation criteria>
5 points: very good 4 points: good 3 points: normal 2 points: bad 1 point: very bad

<Criteria>
◯: Average 4.0 points or more ○: Average 3.0 points or more and less than 4.0 points △: Average 2.0 points or more and less than 3.0 points ×: Average less than 2.0 points

(Test Example 7: Evaluation of foam stability)
Following the evaluation of Test Examples 5 and 6, 10 professional evaluation panels evaluated the stability of the foam by the following test method.

<Test method>
From the properties of the foam generated by the discharge after 2 minutes under the condition of 25 ° C., the foam stability was subjected to sensory evaluation according to the following five-stage evaluation criteria.

  Regarding “foam stability”, the case where the volume of the foam did not change and the case where the foam texture was fine were evaluated as “good”. Judgment was made according to the following criteria from the average score calculated from the scores of the following 10 panelists.

<Evaluation criteria>
5 points: very good 4 points: good 3 points: normal 2 points: bad 1 point: very bad

<Criteria>
◯: Average 4.0 points or more ○: Average 3.0 points or more and less than 4.0 points △: Average 2.0 points or more and less than 3.0 points ×: Average less than 2.0 points

  The composition and results are shown in Table 4 below.

  From the results shown in Table 4, it can be seen that the transparent liquid cleaning material of each example can be foamed using a pump former and is excellent in terms of foam quality. Moreover, it turns out that the transparent liquid cleaning material of each Example shows high detergency with respect to the mascara and hair wax which are oil stains which are hard to remove. On the other hand, in each liquid washing material of Comparative Examples 15-19, it turns out that the result which fully satisfy | fills all the effects of this invention is not obtained.

  In addition, Tables 5 to 9 below show formulation examples of transparent liquid cleaning materials. In addition, content is mass%.

Claims (4)

A nonionic surfactant, at least one of an anionic surfactant and an amphoteric surfactant, an oily component that is liquid at 25 ° C., at least one of a polyol and ethanol, and glycine betaine. ,
The transparent liquid washing | cleaning material whose content of the oil-based component which is a liquid at 25 degreeC is 5-40 mass%.   The transparent liquid cleaning material according to claim 1, wherein the nonionic surfactant is at least one selected from the group consisting of alkyl glyceryl ether, glycol fatty acid ester, glycerin fatty acid ester, polyoxyalkylene glyceryl ether fatty acid ester and fatty acid amide. . The anionic surfactant is at least one selected from the group of carboxylate, sulfate, sulfonate and phosphate,
The transparent liquid cleaning material according to claim 1 or 2 , wherein the amphoteric surfactant is at least one of an amino acid type amphoteric surfactant and a betaine type amphoteric surfactant. The anionic surfactant is at least one of fatty acid soap and polyoxyethylene alkyl ether type anionic surfactant;
The transparent liquid cleaning material according to any one of claims 1 to 3 , wherein the amphoteric surfactant is a betaine amphoteric surfactant.