JP6666684B2 - Hair washing composition, fading inhibitor, and method for suppressing fading of hair using the same - Google Patents
Hair washing composition, fading inhibitor, and method for suppressing fading of hair using the same Download PDFInfo
- Publication number
- JP6666684B2 JP6666684B2 JP2015206134A JP2015206134A JP6666684B2 JP 6666684 B2 JP6666684 B2 JP 6666684B2 JP 2015206134 A JP2015206134 A JP 2015206134A JP 2015206134 A JP2015206134 A JP 2015206134A JP 6666684 B2 JP6666684 B2 JP 6666684B2
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- JP
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- Prior art keywords
- hair
- fading
- salt
- registered trademark
- acyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 60
- 238000005562 fading Methods 0.000 title claims description 40
- 238000005406 washing Methods 0.000 title claims description 19
- 239000003112 inhibitor Substances 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 9
- 238000004140 cleaning Methods 0.000 claims description 50
- -1 olefin sulfonate Chemical class 0.000 claims description 39
- 239000004094 surface-active agent Substances 0.000 claims description 22
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 20
- 150000001413 amino acids Chemical class 0.000 claims description 19
- 229920006317 cationic polymer Polymers 0.000 claims description 19
- 150000003839 salts Chemical class 0.000 description 35
- 229940024606 amino acid Drugs 0.000 description 19
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- 230000000052 comparative effect Effects 0.000 description 15
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- 238000012360 testing method Methods 0.000 description 13
- 239000003945 anionic surfactant Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 8
- 238000002845 discoloration Methods 0.000 description 8
- 238000005187 foaming Methods 0.000 description 8
- 229940009098 aspartate Drugs 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 230000037308 hair color Effects 0.000 description 7
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- 238000004043 dyeing Methods 0.000 description 6
- 239000000118 hair dye Substances 0.000 description 6
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 206010019030 Hair colour changes Diseases 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 4
- OTTPFCJTQXRWHO-UHFFFAOYSA-N 3-(2,3-dichloroanilino)cyclohex-2-en-1-one Chemical class ClC1=CC=CC(NC=2CCCC(=O)C=2)=C1Cl OTTPFCJTQXRWHO-UHFFFAOYSA-N 0.000 description 3
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- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
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- 239000004475 Arginine Substances 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
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- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 108010077895 Sarcosine Proteins 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
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- 125000002252 acyl group Chemical group 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 235000004279 alanine Nutrition 0.000 description 2
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
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- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
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- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
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- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- AFAJYBYVKUTWJK-UHFFFAOYSA-N n'-(5-methoxy-2-nitrophenyl)ethane-1,2-diamine;hydrochloride Chemical compound Cl.COC1=CC=C([N+]([O-])=O)C(NCCN)=C1 AFAJYBYVKUTWJK-UHFFFAOYSA-N 0.000 description 1
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- LLLILZLFKGJCCV-UHFFFAOYSA-M n-methyl-n-[(1-methylpyridin-1-ium-4-yl)methylideneamino]aniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C=1C=CC=CC=1N(C)\N=C\C1=CC=[N+](C)C=C1 LLLILZLFKGJCCV-UHFFFAOYSA-M 0.000 description 1
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- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- SOUHUMACVWVDME-UHFFFAOYSA-N safranin O Chemical compound [Cl-].C12=CC(N)=CC=C2N=C2C=CC(N)=CC2=[N+]1C1=CC=CC=C1 SOUHUMACVWVDME-UHFFFAOYSA-N 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
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- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
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- 159000000000 sodium salts Chemical class 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- CAVXVRQDZKMZDB-UHFFFAOYSA-N sodium;2-[dodecanoyl(methyl)amino]ethanesulfonic acid Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O CAVXVRQDZKMZDB-UHFFFAOYSA-N 0.000 description 1
- ZFDPAZDODACYOG-UHFFFAOYSA-M sodium;[(1,5-dimethyl-3-oxo-2-phenylpyrazol-4-yl)amino]methanesulfonate Chemical compound [Na+].CN1C(C)=C(NCS([O-])(=O)=O)C(=O)N1C1=CC=CC=C1 ZFDPAZDODACYOG-UHFFFAOYSA-M 0.000 description 1
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- 239000000375 suspending agent Substances 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- DWKARHJHPSUOBW-UHFFFAOYSA-N trimethyl-[3-[(2e)-2-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)hydrazinyl]phenyl]azanium;chloride Chemical compound [Cl-].CC1=NN(C=2C=CC=CC=2)C(O)=C1N=NC1=CC=CC([N+](C)(C)C)=C1 DWKARHJHPSUOBW-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- LLWJPGAKXJBKKA-UHFFFAOYSA-N victoria blue B Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)=C(C=C1)C2=CC=CC=C2C1=[NH+]C1=CC=CC=C1 LLWJPGAKXJBKKA-UHFFFAOYSA-N 0.000 description 1
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Description
本発明は、毛髪洗浄組成物、褪色抑制剤、及びそれらを用いた毛髪の褪色を抑制する方法に関するもので、特に、泡立ち、洗浄時、及び乾燥後の指通り等を保持しながら、染色された毛髪の褪色を効果的に抑制する毛髪洗浄組成物、褪色抑制剤、及びそれらを用いた毛髪の褪色を抑制する方法に関するものである。 The present invention relates to a hair washing composition, a fading inhibitor, and a method for suppressing fading of hair using the same. TECHNICAL FIELD The present invention relates to a hair washing composition, a discoloration inhibitor, and a method for suppressing discoloration of hair using the same, which effectively suppresses discoloration of hair.
近年、黒髪や白髪を染毛することで様々な髪色を楽しむ人が増えており、染毛剤として、ヘアカラー（「ヘアダイ」という場合もある）、ヘアマニキュア、ヘアカラートリートメント等が、数多く販売されている。しかし、日々のシャンプー、日焼けなどの影響で、染色が褪色してしまうことが問題となっており、染色を維持するためには染毛を何度も繰り返す必要があった。染毛を繰り返すと毛髪が大きなダメージを受けるため、より褪色しやすくなる可能性があり、褪色抑制効果を有するシャンプー等の開発が重要な課題となっている。 In recent years, the number of people who enjoy various hair colors by dyeing black or gray hair is increasing. As hair dyes, there are many hair colors (sometimes called "hair dyes"), hair manicures, and hair color treatments. Sold. However, there is a problem that the dyeing fades due to daily shampooing, sunburn, and the like, and it was necessary to repeat the hair dyeing many times to maintain the dyeing. Repeated hair dyeing causes great damage to the hair, which may cause fading more easily. Development of shampoos and the like having a fading inhibiting effect has become an important issue.
シャンプーの主な洗浄成分として、通常、界面活性剤を含んでおり、特に、界面活性剤の中でも陰イオン性界面活性剤が用いられる。上記陰イオン性界面活性剤としては、ラウリル硫酸ナトリウム、ラウレス硫酸ナトリウム等のサルフェート系の陰イオン性界面活性剤が、他の陰イオン性界面活性剤よりも洗浄力に優れ、かつ泡立ちに非常に優れる点から、よく用いられてきている（特許文献１）。 A surfactant is generally contained as a main cleaning component of the shampoo. In particular, an anionic surfactant is used among the surfactants. As the anionic surfactants, sulfate-based anionic surfactants such as sodium lauryl sulfate and sodium laureth sulfate are more excellent in detergency than other anionic surfactants, and very effective in foaming. It is often used because of its superiority (Patent Document 1).
しかしながら、サルフェート系の陰イオン性界面活性剤のように、洗浄力が強く、脱脂力の高い洗浄成分を用いると、刺激が強くて毛髪の損傷を促進し、また、過度な洗浄力により、特に染色した毛髪の色褪せを加速化させるという問題があった。 However, when a cleaning component having a strong detergency and a high degreasing power, such as a sulfate-based anionic surfactant, is used, irritation is increased and hair damage is promoted. There is a problem that the fading of the dyed hair is accelerated.
本発明は、このような事情に鑑みなされたもので、泡立ち、洗浄時、及び乾燥後の指通り等を保持しながら、染色された毛髪の褪色を効果的に抑制する毛髪洗浄組成物、褪色抑制剤、及びそれらを用いた毛髪の褪色を抑制する方法の提供を、その目的とする。 The present invention has been made in view of such circumstances, and a hair cleaning composition that effectively suppresses fading of dyed hair while maintaining fingering and the like during bubbling, washing, and after drying, An object of the present invention is to provide an inhibitor and a method for suppressing fading of hair using the same.
上記の目的を達成するため、本発明は、（Ａ）Ｎ−アシル−Ｎ−アルキルタウリン塩、（Ｂ）オレフィンスルホン酸塩、及び（Ｃ）カチオン性ポリマー、を含有する毛髪洗浄組成物を第一の要旨とする。 In order to achieve the above object, the present invention relates to a hair cleaning composition comprising (A) an N-acyl-N-alkyltaurine salt, (B) an olefin sulfonate, and (C) a cationic polymer. This is an abstract.
また、本発明は、上記毛髪洗浄組成物中に、さらに（Ｄ）アミノ酸系界面活性剤（但し、（Ａ）成分を除く）を含有することを第二の要旨とし、さらに、上記（Ａ）Ｎ−アシル−Ｎ−アルキルタウリン塩がＮ−ココイル−Ｎ−メチルタウリンタウリンナトリウム塩であることを、第三の要旨とする。 In addition, the present invention has a second gist that the hair cleaning composition further comprises (D) an amino acid-based surfactant (excluding the component (A)). A third aspect is that the N-acyl-N-alkyltaurine salt is N-cocoyl-N-methyltaurine taurine sodium salt.
そしてまた、本発明は、（Ａ）Ｎ−アシル−Ｎ−アルキルタウリン塩、（Ｂ）オレフィンスルホン酸塩、及び（Ｃ）カチオン性ポリマー、を含有する毛髪洗浄組成物である褪色抑制剤を第四の要旨とする。そして、これらの毛髪洗浄組成物、又は褪色抑制剤を用いることによる、染色された毛髪の褪色を抑制する方法を第五の要旨とする。 Further, the present invention provides a hair washing composition comprising (A) an N-acyl-N-alkyltaurine salt, (B) an olefin sulfonate, and (C) a cationic polymer, as a discoloration inhibitor. The summary is four. A fifth aspect of the present invention is a method for suppressing fading of dyed hair by using these hair washing compositions or fading inhibitors.
すなわち、本発明者らは、カラーリングした毛髪に対して褪色抑制効果に優れ、使用感に優れた毛髪洗浄料を得るべく、鋭意検討を重ねてきた。その結果、毛髪洗浄組成物として、（Ａ）Ｎ−アシル−Ｎ−アルキルタウリン塩、（Ｂ）オレフィンスルホン酸塩、及び（Ｃ）カチオン性ポリマー、を含有すると、毛髪洗浄料の使用感の良さを保持しながら、カラーリングした毛髪の高い褪色抑制効果があることを見出し、本発明の完成に至った。 That is, the present inventors have intensively studied to obtain a hair cleansing agent having an excellent discoloration suppressing effect and an excellent feeling upon use for colored hair. As a result, when the hair cleaning composition contains (A) an N-acyl-N-alkyltaurine salt, (B) an olefin sulfonate, and (C) a cationic polymer, the feeling of use of the hair cleaning composition is good. While maintaining the above, it was found that there was a high effect of suppressing fading of the colored hair, and the present invention was completed.
本発明は、（Ａ）Ｎ−アシル−Ｎ−アルキルタウリン塩、（Ｂ）オレフィンスルホン酸塩、及び（Ｃ）カチオン性ポリマー、を含有する毛髪洗浄組成物であることから、泡立ち、洗浄時、及び乾燥後の指通り等を保持しながら、染色された毛髪の褪色を効果的に抑制することができる。 The present invention relates to a hair cleaning composition containing (A) an N-acyl-N-alkyltaurine salt, (B) an olefin sulfonate, and (C) a cationic polymer. In addition, the fading of the dyed hair can be effectively suppressed while maintaining the finger passage after drying and the like.
＜毛髪洗浄組成物＞
本発明の毛髪洗浄組成物は、Ｎ−アシル−Ｎ−アルキルタウリン塩（Ａ）、オレフィンスルホン酸塩（Ｂ）、及びカチオン性ポリマー（Ｃ）を含有する。
また、本発明の褪色抑制剤は、Ｎ−アシル−Ｎ−アルキルタウリン塩（Ａ）、オレフィンスルホン酸塩（Ｂ）、及びカチオン性ポリマー（Ｃ）を含有する毛髪洗浄組成物である。以下、毛髪洗浄組成物を構成する各成分について順に説明する。
<Hair cleaning composition>
The hair cleaning composition of the present invention contains an N-acyl-N-alkyltaurine salt (A), an olefin sulfonate (B), and a cationic polymer (C).
The discoloration inhibitor of the present invention is a hair cleaning composition containing an N-acyl-N-alkyltaurine salt (A), an olefin sulfonate (B), and a cationic polymer (C). Hereinafter, each component constituting the hair cleaning composition will be described in order.
〈（Ａ）Ｎ−アシル−Ｎ−アルキルタウリン塩〉
本発明で用いられるＮ−アシル−Ｎ−アルキルタウリン塩（Ａ）としては、例えば、Ｎ−Ｃ８〜Ｃ２２アルカノイル−Ｎ−アルキルタウリン塩等が挙げられる。ここで、Ｃ８〜Ｃ２２アルカノイルとしては、例えば、ココイル、ラウロイル、ミリストイル、パルミトイル、ステアロイル等が挙げられ、好ましくはココイルが挙げられる。ここで、アルキルとしては、メチル、エチル、プロピル等が挙げられ、好ましくはメチルが挙げられる。Ｎ−アシル−Ｎ−アルキルタウリン塩（Ａ）における塩としては、ナトリウム塩、カリウム塩等のアルカリ金属との塩、モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩等のアミン塩、タウリンナトリウム塩、タウリンカリウム塩、Ｎ−メチルタウリンナトリウム塩、Ｎ−メチルタウリンカリウム塩等のタウリンとの塩等が挙げられる。中でも、好ましい塩としては、タウリンナトリウム塩が挙げられる。
<(A) N-acyl-N-alkyltaurine salt>
As it is used in the present invention N- acyl -N- alkyl taurate (A), for example, N-C 8 ~C 22 alkanoyl -N- alkyl taurine salts, and the like. Here, the C 8 -C 22 alkanoyl includes, for example, cocoyl, lauroyl, myristoyl, palmitoyl, stearoyl and the like, and preferably cocoyl. Here, examples of the alkyl include methyl, ethyl, propyl and the like, and preferably methyl. Examples of the salt in the N-acyl-N-alkyltaurine salt (A) include a salt with an alkali metal such as a sodium salt and a potassium salt, an amine salt such as a monoethanolamine salt, a diethanolamine salt and a triethanolamine salt, and a taurine sodium salt. And salts with taurine such as potassium salt of taurine, sodium salt of N-methyltaurine, potassium salt of N-methyltaurine and the like. Among them, preferred salts include taurine sodium salt.
褪色抑制の点から特に好ましいＮ−アシル−Ｎ−アルキルタウリン塩（Ａ）としては、Ｎ−ココイル−Ｎ−メチルタウリン塩が挙げられ、さらに好ましくはＮ−ココイル−Ｎ−メチルタウリンタウリンナトリウム塩が挙げられる。
上記Ｎ−アシル−Ｎ−アルキルタウリン塩（Ａ）は、単独でもしくは２種以上併せて用いることができる。
Particularly preferred N-acyl-N-alkyltaurine salts (A) from the viewpoint of fading suppression include N-cocoyl-N-methyltaurine salt, and more preferably N-cocoyl-N-methyltaurine taurine sodium salt. No.
The N-acyl-N-alkyltaurine salts (A) can be used alone or in combination of two or more.
Ｎ−アシル−Ｎ−アルキルタウリン塩（Ａ）の含有量としては、例えば、本発明の毛髪洗浄組成物の０．５〜３０重量％であり、好ましくは１〜２０重量％、より好ましくは２〜１５重量％が挙げられる。Ｎ−アシル−Ｎ−アルキルタウリン塩（Ａ）の含有量は、他の界面活性剤をどの程度添加するかに応じて、適宜変えることができる。
Ｎ−アシル−Ｎ−アルキルタウリン塩（Ａ）を毛髪洗浄組成物に組み合せることで、毛髪の褪色が抑制され、洗浄力が向上する。
The content of the N-acyl-N-alkyltaurine salt (A) is, for example, 0.5 to 30% by weight, preferably 1 to 20% by weight, more preferably 2 to 30% by weight of the hair cleaning composition of the present invention. To 15% by weight. The content of the N-acyl-N-alkyltaurine salt (A) can be appropriately changed depending on how much other surfactant is added.
By combining the N-acyl-N-alkyltaurine salt (A) with the hair cleaning composition, the fading of the hair is suppressed and the cleaning power is improved.
〈（Ｂ）オレフィンスルホン酸塩〉
本発明で用いられるオレフィンスルホン酸塩（Ｂ）としては、例えば、Ｃ８〜Ｃ２２アルケニルスルホン酸塩等が挙げられ、オレフィンの位置は末端であっても内部であってもよい。Ｃ８〜Ｃ２２アルケニルスルホン酸塩におけるＣ８〜Ｃ２２アルケニルは、好ましくはＣ１２〜Ｃ２２アルケニルが挙げられ、より好ましくはＣ１４〜Ｃ２０アルケニルが挙げられ、さらに好ましくはＣ１６〜Ｃ１８アルケニルが挙げられる。好ましいＣ８〜Ｃ２２アルケニルスルホン酸塩としては、テトラデセンスルホン酸塩（オレフィン（C14-16）スルホン酸）等が挙げられる。オレフィンスルホン酸塩（Ｂ）における塩としては、例えば、ナトリウム、カリウム等のアルカリ金属との塩、トリエタノールアミン等のトリアルキルアミンとの塩、アルギニン等の塩性アミノ酸との塩等が挙げられる。
上記オレフィンスルホン酸塩（Ｂ）としては、単独でもしくは２種以上併せて用いることができる。
<(B) Olefin sulfonate>
Examples of the olefin sulfonate (B) used in the present invention include C 8 -C 22 alkenyl sulfonates, and the olefin may be located at the terminal or at the inside. C 8 -C 22 alkenyl in C 8 -C 22 alkenyl sulfonate preferably include C 12 -C 22 alkenyl, more preferably include C 14 -C 20 alkenyl, more preferably C 16 -C 18 alkenyl. Preferred C 8 -C 22 alkenyl sulfonates, tetradecene sulfonate (olefin (C14-16) sulfonate), and the like. Examples of the salt in the olefin sulfonate (B) include a salt with an alkali metal such as sodium and potassium, a salt with a trialkylamine such as triethanolamine, and a salt with a salty amino acid such as arginine. .
The olefin sulfonate (B) can be used alone or in combination of two or more.
オレフィンスルホン酸塩（Ｂ）の含有量としては、例えば、本発明の毛髪洗浄組成物の０．５〜３０重量％であり、好ましくは１〜２０重量％、より好ましくは２〜１５重量％が挙げられる。オレフィンスルホン酸塩（Ｂ）の含有量は、他の界面活性剤をどの程度添加するかに応じて、適宜変えることができる。
オレフィンスルホン酸塩（Ｂ）を毛髪洗浄組成物に組み合せることで、毛髪の褪色が抑制され、洗浄力が向上する。
The content of the olefin sulfonate (B) is, for example, 0.5 to 30% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight of the hair cleaning composition of the present invention. No. The content of the olefin sulfonate (B) can be appropriately changed depending on how much other surfactant is added.
By combining the olefin sulfonate (B) with the hair cleaning composition, the fading of the hair is suppressed, and the cleaning power is improved.
〈（Ｃ）カチオン性ポリマー〉
本発明で用いられるカチオン性ポリマー（Ｃ）としては、例えば、カチオン化セルロース、カチオン性澱粉、カチオン化グアーガム、ジアリル四級アンモニウム塩／アクリルアミド共重合物、ビニルイミダゾリウムトリクロライド／ビニルピロリドン共重合体、ヒドロキシエチルセルロース／ジメチルジアリルアンモニウムクロライド共重合体、ビニルピロリドン／四級化ジメチルアミノエチルメタクリレート共重合体、ポリビニルピロリドン／アルキルアミノアクリレート共重合体、ポリビニルピロリドン／アルキルアミノアクリレート／ビニルカプロラクタム共重合体、ビニルピロリドン／メタクリルアミドプロピル塩化トリメチルアンモニウム共重合体、アルキルアクリルアミド／アクリレート／アルキルアミノアルキルアクリルアミド／ポリエチレングリコールメタクリレート共重合体、アジピン酸／ジメチルアミノヒドロキシプロピルエチレントリアミン共重合体等が挙げられる。
<(C) Cationic polymer>
Examples of the cationic polymer (C) used in the present invention include cationized cellulose, cationic starch, cationized guar gum, diallyl quaternary ammonium salt / acrylamide copolymer, vinyl imidazolium trichloride / vinyl pyrrolidone copolymer , Hydroxyethylcellulose / dimethyldiallylammonium chloride copolymer, vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, vinyl Pyrrolidone / methacrylamidopropyl trimethylammonium chloride copolymer, alkyl acrylamide / acrylate / alkylaminoalkylacrylamide / Polyethylene glycol methacrylate copolymers, adipic acid / dimethylaminohydroxypropyl ethylene triamine copolymer.
好ましいカチオン性ポリマー（Ｃ）としては、例えば、塩化トリメチルアンモニウオヒドロキシプロピルヒドロキシエチルセルロース（ポリクオタニウム−１０（カチナールHC-200(登録商標)：東邦化学工業社製）、アクリル酸・塩化ジメチルジアリルアンモニウム共重合体（ポリクオタニウム−２２（マーコート280(登録商標)，マーコート280SD(登録商標)，マーコート281(登録商標)，マーコート295(登録商標)：日本ルーブリゾール社製）、アクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体（ポリクオタニウム−３９（マーコートplus3330(登録商標)，マーコート3330DRY(登録商標)，マーコート3330PR(登録商標)，マーコート3331PR(登録商標)，マーコートplus3331(登録商標)，マーコート3333(登録商標)，マーコート3940(登録商標)：日本ルーブリゾール社製）、アクリル酸メチル・アクリル酸・塩化メタクリルアミドプロピルトリメチルアンモニウム酸共重合体（ポリクオタニウム−４７（マーコート2001(登録商標)：日本ルーブリゾール社製）、アクリルアミド・アクリル酸・塩化メタクリルアミドプロピルトリメチルアンモニウム共重合体（ポリクオタニウム−５３（マーコート2003(登録商標)，マーコート5300(登録商標)：日本ルーブリゾール社製）、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体（ポリクオタニウム−７（マーコート2200(登録商標)，マーコート550(登録商標)，マーコート550PR(登録商標)：日本ルーブリゾール社製）、(メタクリロイルオキシエチルカルボキシベタイン／メタクリル酸アルキル)コポリマー（ユカフォーマーSM(登録商標)，ユカフォーマー301(登録商標)，ユカフォーマー202(登録商標)，ユカフォーマーR205(登録商標)：三菱化学社製）、（オクチルアクリルアミド／アクリル酸ヒドロキシプロピル／メタクリル酸ブチルアミノエチル）コポリマー（アンフォマーSH-30(登録商標)，アンフォマー28-4910(登録商標)：アクゾノーベル社製）等が挙げられる。中でも、より好ましいカチオン性ポリマー（Ｃ）としては、ポリクオタニウム−１０、ポリクオタニウム−２２等が挙げられる。
上記カチオン性ポリマー（Ｃ）は、単独でもしくは２種以上併せて用いることができる。
Preferred cationic polymers (C) include, for example, trimethylammonium hydroxypropylhydroxyethylcellulose (Polyquaternium-10 (Catinal HC-200 (registered trademark): manufactured by Toho Chemical Industry Co., Ltd.), acrylic acid / dimethyldiallylammonium chloride copolymer) Merged (Polyquaternium-22 (Mercoat 280 (registered trademark), Marcoat 280SD (registered trademark), Marcoat 281 (registered trademark), Marcoat 295 (registered trademark): manufactured by Lubrizol Japan Ltd.), acrylamide / acrylic acid / dimethyldiallylammonium chloride The copolymer (Polyquaternium-39 (Mercoat plus3330 (registered trademark), Marcoat 3330DRY (registered trademark), Marcoat 3330PR (registered trademark), Marcoat 3331PR (registered trademark), Marcoat plus3331 (registered trademark), Marcoat 3333 (registered trademark), MARCOAT 3940 (registered trademark): Japan -Brizol Corporation), methyl acrylate / acrylic acid / methacrylamidopropyl chloride trimethylammonium acid copolymer (Polyquaternium-47 (Mercoat 2001 (registered trademark): Nippon Lubrizol Corporation), acrylamide / acrylic acid / methacrylamidochloride chloride Trimethylammonium copolymer (Polyquaternium-53 (Mercoat 2003 (registered trademark), Marcoat 5300 (registered trademark): manufactured by Japan Lubrizol Co., Ltd.), dimethyldiallylammonium chloride-acrylamide copolymer (Polyquaternium-7 (Mercoat 2200 (registered trademark) ), Marcoat 550 (registered trademark), Marcoat 550PR (registered trademark): manufactured by Nippon Lubrisol Co., Ltd., (methacryloyloxyethyl carboxybetaine / alkyl methacrylate) copolymer (Yukaformer SM (registered trademark), Yukafo Mer 301 (registered trademark), Yuka Former 202 (registered trademark), Yuka Former R205 (registered trademark): manufactured by Mitsubishi Chemical Corporation), (octylacrylamide / hydroxypropyl acrylate / butylaminoethyl methacrylate) copolymer (Amphomer SH-30 (registered trademark) (Trademark), Amphomer 28-4910 (registered trademark): manufactured by Akzo Nobel Co.) Among them, more preferable cationic polymer (C) includes polyquaternium-10, polyquaternium-22, and the like.
The cationic polymer (C) can be used alone or in combination of two or more.
カチオン性ポリマー（Ｃ）の含有量としては、例えば、本発明の毛髪洗浄組成物の０．０１〜５重量％であり、好ましくは０．０５〜２重量％、より好ましくは０．１〜１重量％が挙げられる。 The content of the cationic polymer (C) is, for example, 0.01 to 5% by weight, preferably 0.05 to 2% by weight, more preferably 0.1 to 1% by weight of the hair cleaning composition of the present invention. % By weight.
本発明の毛髪洗浄組成物にカチオン性ポリマー（Ｃ）を添加することで、染色された毛髪の褪色がさらに抑制される。また、カチオン性ポリマー（Ｃ）は帯電防止作用、微弱な保湿作用等の毛髪に対するコンディショニング効果がある。 By adding the cationic polymer (C) to the hair washing composition of the present invention, the fading of the dyed hair is further suppressed. Further, the cationic polymer (C) has a conditioning effect on hair such as an antistatic action and a weak moisturizing action.
〈（Ｄ）アミノ酸系界面活性剤〉
本発明の毛髪洗浄組成物は、さらに（Ａ）成分以外のアミノ酸系界面活性剤（Ｄ）を含有することができる。アミノ酸系界面活性剤（Ｄ）としては、例えば、Ｎ−Ｃ１２〜Ｃ２２アシル塩基性アミノ酸Ｃ１〜Ｃ８アルキルエステル塩等の陽イオン性界面活性剤、Ｎ−ラウロイル−Ｌ−アルギニン、アルキルオキシヒドロキシプロピルアミノ酸塩等の両性界面活性剤、Ｎ−アシル−Ｎ−アルキルグリシン塩（Ｎ−ココイル−Ｎ−メチルグリシン等のＮ−Ｃ８〜Ｃ２２アルカノイル−Ｎ−アルキルグリシン塩）、Ｎ−アシル−Ｎ−アルキルグルタミン酸塩（Ｎ−ココイル−Ｎ−メチルグルタミン酸塩等のＮ−Ｃ８〜Ｃ２２アルカノイル−Ｎ−アルキルグルタミン酸塩）、Ｎ−アシル−Ｎ−アルキルアスパラギン酸塩（Ｎ−ココイル−Ｎ−メチルアスパラギン酸塩等のＮ−Ｃ８〜Ｃ２２アルカノイル−Ｎ−アルキルアスパラギン酸塩）、Ｎ−アシル−Ｎ−アルキルアラニン塩（Ｎ−ココイル−Ｎ−メチルアラニン塩等のＮ−Ｃ８〜Ｃ２２アルカノイル−Ｎ−アルキルアラニン塩）、Ｎ−アシルグルタミン酸塩（Ｎ−ココイルグルタミン酸塩等のＮ−Ｃ８〜Ｃ２２アルカノイルグルタミン酸塩）、Ｎ−アシルグリシン塩（Ｎ−ココイルグリシン塩等のＮ−Ｃ８〜Ｃ２２アルカノイルグリシン塩）、Ｎ−アシルアラニン塩（Ｎ−ココイルアラニン塩等のＮ−Ｃ８〜Ｃ２２アルカノイルアラニン塩)、Ｎ−アシルアスパラギン酸塩（Ｎ−ラウロイルアスパラギン酸塩等のＮ−Ｃ８〜Ｃ２２アルカノイルアスパラギン酸塩）、Ｎ−アシルサルコシン塩（Ｎ−ココイルサルコシン塩等のＮ−Ｃ８〜Ｃ２２アルカノイルサルコシン塩）等の陰イオン性界面活性剤が挙げられ、中でも好ましくは陰イオン性界面活性剤が挙げられる。これらの塩としては、例えば、ナトリウム、カリウム等のアルカリ金属との塩、トリエタノールアミン等のトリアルキルアミンとの塩、アルギニン等の塩性アミノ酸との塩等が挙げられる。
<(D) Amino acid surfactant>
The hair cleaning composition of the present invention can further contain an amino acid-based surfactant (D) other than the component (A). The amino acid-based surfactant (D), for example, N-C 12 ~C 22 acyl basic amino acid C 1 -C 8 alkyl ester cationic surfactants such as salts, N- lauroyl -L- arginine, alkyl amphoteric surfactants such as oxy-hydroxypropyl amino acid salt, N- acyl -N- alkyl glycine salts (N- cocoyl -N- N-C 8 ~C 22 alkanoyl -N- alkyl glycine salts methyl glycine), N- acyl -N- alkyl glutamates (N- cocoyl -N- N-C 8 ~C 22 alkanoyl -N- alkyl glutamates and methyl glutamate), N- acyl -N- alkyl aspartate (N- cocoyl - N- methyl-N-C 8 ~C 22 alkanoyl -N- alkyl aspartate, such as aspartic acid salt), N- reed -N- alkyl alanine salts (N- cocoyl -N- N-C 8 -C 22 alkanoyl -N- alkyl alanine salts such as methyl alanine salts), such as N- acyl glutamates (N- cocoyl glutamate N-C 8 -C 22 alkanoyl glutamate), N- acyl glycine salt (N- cocoyl N-C 8 -C 22 alkanoyl glycine salts such as glycine salt), such as N- acyl alanine salts (N- cocoyl alanine salt N-C 8 -C 22 alkanoyl alanine salt), N- acyl aspartate (N- lauroyl N-C 8 ~C 22 alkanoyloxy aspartate such as aspartate), N- acyl sarcosine salt (N- cocoyl sarcosine, such as salt N-C 8 ~C 22 alkanoyl sarcosine salts) anionic surfactants, and among them preferred It can be mentioned anionic surface active agent. Examples of these salts include salts with an alkali metal such as sodium and potassium, salts with a trialkylamine such as triethanolamine, and salts with a salty amino acid such as arginine.
好ましいアミノ酸系界面活性剤（Ｄ）としては、上記のように陰イオン性界面活性剤が好ましく、中でも、Ｎ−アシル−Ｎ−アルキルグリシン塩、Ｎ−アシル−Ｎ−アルキルグルタミン酸塩、Ｎ−アシル−Ｎ−アルキルアスパラギン酸塩、Ｎ−アシル−Ｎ−アルキルアラニン塩等が挙げられ、より好ましくはＮ−アシル−Ｎ−アルキルグリシン塩、Ｎ−アシル−Ｎ−アルキルグルタミン酸塩、Ｎ−アシル−Ｎ−アスパラギン酸塩等が挙げられ、さらに好ましくはＮ−アシル−Ｎ−アルキルグリシン塩等が挙げられる。これらのアミノ酸系界面活性剤（Ｄ）において、アルキルとしては、メチル、エチル、プロピル等が挙げられ、好ましくはメチルが挙げられる。また、これらのアミノ酸系界面活性剤（Ｄ）において、アシルとしては、例えば、ココイル、ラウロイル、ミリストイル、パルミトイル、ステアロイル等が挙げられ、好ましくはココイルが挙げられる。
上記アミノ酸系界面活性剤（Ｄ）は、単独でもしくは２種以上併せて用いることができる。
As the preferred amino acid surfactant (D), an anionic surfactant is preferable as described above, and among them, N-acyl-N-alkylglycine salt, N-acyl-N-alkylglutamate, N-acyl -N-alkyl aspartate, N-acyl-N-alkylalanine salt and the like, and more preferably N-acyl-N-alkylglycine salt, N-acyl-N-alkylglutamate, N-acyl-N -Aspartate and the like, more preferably N-acyl-N-alkylglycine and the like. In these amino acid-based surfactants (D), examples of the alkyl include methyl, ethyl, propyl and the like, and preferably methyl. In these amino acid-based surfactants (D), examples of the acyl include cocoyl, lauroyl, myristoyl, palmitoyl, stearoyl and the like, and preferably cocoyl.
The amino acid-based surfactants (D) can be used alone or in combination of two or more.
アミノ酸系界面活性剤（Ｄ）の含有量としては、例えば、本発明の毛髪洗浄組成物の０．５〜３０重量％であり、好ましくは１〜２０重量％、より好ましくは２〜１５重量％が挙げられる。 The content of the amino acid-based surfactant (D) is, for example, 0.5 to 30% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight of the hair cleaning composition of the present invention. Is mentioned.
アミノ酸系界面活性剤（Ｄ）を毛髪洗浄組成物に組み合せることで、毛髪の褪色が格段に抑制される。また、アミノ酸系陰イオン性界面活性剤によって、泡立ち、洗浄力が向上させることができる。 By combining the amino acid-based surfactant (D) with the hair cleaning composition, the fading of the hair is remarkably suppressed. In addition, foaming and detergency can be improved by the amino acid-based anionic surfactant.
〈水〉
本発明に用いられる水は、通常配合される品質のものであればよく、蒸留水であっても、イオン交換水であっても、精製水であってもよい。本発明の毛髪洗浄組成物中の水の含有量としては、通常の毛髪洗浄組成物に含まれる水の含有量と同程度の範囲が挙げられる。水を加えることで、毛髪洗浄組成物を使用しやすい粘度等に調整することができる。従って、水の含有量としては、添加する他の成分によっても変わり得るが、例えば、本発明の毛髪洗浄組成物の３０〜８０重量％であり、好ましくは３５〜７５重量％、さらに好ましくは４０〜７０重量％が挙げられる。
<water>
The water used in the present invention may be of a quality that is usually blended, and may be distilled water, ion-exchanged water, or purified water. The content of water in the hair cleaning composition of the present invention may be in the same range as the content of water contained in a normal hair cleaning composition. By adding water, the hair cleaning composition can be adjusted to a viscosity or the like that is easy to use. Accordingly, the content of water may vary depending on other components to be added. For example, it is 30 to 80% by weight, preferably 35 to 75% by weight, and more preferably 40% by weight of the hair cleaning composition of the present invention. ７０70% by weight.
〈その他の成分〉
本発明の毛髪洗浄組成物には、本発明の効果を阻害しない範囲で、さらに他の界面活性剤を加えることもできる。他の界面活性剤としては例えば、ココアンホ酢酸塩等の陰イオン性界面活性剤、陽イオン性界面活性剤、ラウリルベタイン、ココカミドプロピルベタイン等の両性界面活性剤、コカミドＤＥＡ等の非イオン界面活性剤等が挙げられる。
<Other ingredients>
Other surfactants can be further added to the hair cleaning composition of the present invention as long as the effects of the present invention are not impaired. Other surfactants include, for example, anionic surfactants such as cocoamphoacetate, cationic surfactants, amphoteric surfactants such as laurylbetaine and cococamidopropylbetaine, and nonionic surfactants such as cocamide DEA. Activators and the like.
本発明の毛髪洗浄組成物には、また、毛髪洗浄組成物に使用されている他の成分を配合することができる。他の成分としては、例えば、ミリスチン酸イソプロピル、エチレングリコールジステアレート、エチレングリコールモノステアレート等の懸濁剤、ソルビトール、ブチレングリコール、プロピレングリコール、グリセリン、ポリエチレングリコール、尿素等の保湿剤、エチルアルコール、イソプロピルアルコール、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、メチルセルロース、高級アルコール、カルボキシビニルポリマー、カラギーナン、カチオン化セルロース、天然高分子類等の粘度調整剤、ヤシ油、ツバキ油、アボガド油、ラノリン誘導体等の油性成分、カチオン化セルロース、カチオン化グアーガムに代表されるカチオン性ポリマー等のコンディショニング剤、エチレンジアミン四酢酸又はその塩、ヒドロキシエタンジホスホン酸又はその塩等のキレート剤、メチルパラベン、エチルパラベン、プロピルパラベン、ブチルパラベン、安息香酸ナトリウム、イソプロピルメチルフェノール等の防腐剤、トリクロサン、トリクロロカルバニリド等の殺菌剤、グリチルリチン酸ジカリウム、酢酸トコフェロール等の抗炎症剤、塩化ナトリウム等の塩類、その他、パール化剤、スクラブ剤、１−メントール等の冷感剤、蛋白誘導体、動物抽出エキス、植物エキス、香料、色素、紫外線吸収剤、酸化防止剤、抗フケ剤、殺菌剤、防腐剤が挙げられる。これらの他の成分を本発明の効果を損なわない範囲で必要に応じて配合することができる。 The hair cleaning composition of the present invention can also contain other components used in the hair cleaning composition. Other components include, for example, suspending agents such as isopropyl myristate, ethylene glycol distearate, ethylene glycol monostearate, humectants such as sorbitol, butylene glycol, propylene glycol, glycerin, polyethylene glycol, urea, and ethyl alcohol , Isopropyl alcohol, hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose, higher alcohol, carboxyvinyl polymer, carrageenan, cationized cellulose, viscosity modifiers such as natural polymers, coconut oil, camellia oil, avocado oil, oil properties such as lanolin derivatives Ingredients, conditioning agents such as cationized cellulose, cationic polymers represented by cationized guar gum, ethylenediaminetetraacetic acid or a salt thereof, Chelating agents such as diphosphonic acid or a salt thereof, preservatives such as methylparaben, ethylparaben, propylparaben, butylparaben, sodium benzoate, and isopropylmethylphenol; disinfectants such as triclosan and trichlorocarbanilide; dipotassium glycyrrhizinate; tocopherol acetate Anti-inflammatory agents such as sodium chloride, etc., pearlizing agents, scrubbing agents, cooling agents such as 1-menthol, protein derivatives, animal extracts, plant extracts, flavors, pigments, ultraviolet absorbers, antioxidants Agents, antidandruff agents, bactericides, and preservatives. These other components can be blended as needed as long as the effects of the present invention are not impaired.
本発明の毛髪洗浄組成物は、常法に従って製造することができる。例えば、上記の各成分を均一になるまで混合することで製造することができる。 The hair cleaning composition of the present invention can be produced according to a conventional method. For example, it can be manufactured by mixing the above components until they are uniform.
このようにして、上記（Ａ）〜（Ｃ）成分を含有し、本発明の効果を阻害しない範囲で、その他の成分を含有することにより、本発明の毛髪洗浄組成物が得られる。
また、上記毛髪洗浄組成物は、染色された毛髪の褪色を効果的に抑制することができることから、褪色抑制剤として用いることができる。
Thus, the hair cleaning composition of the present invention can be obtained by containing the above components (A) to (C) and other components within a range not to impair the effects of the present invention.
In addition, the above-mentioned hair cleaning composition can be used as a fading inhibitor since it can effectively suppress fading of dyed hair.
＜染色された毛髪の褪色を抑制する方法＞
本発明の毛髪洗浄組成物は、通常の毛髪洗浄組成物（シャンプー）と同様に用いて毛髪を洗浄することができる。このようにして毛髪を洗浄することで、染色された毛髪の褪色を抑制することができる。
<Method to control fading of dyed hair>
The hair washing composition of the present invention can be used to wash hair in the same manner as a normal hair washing composition (shampoo). By washing the hair in this way, the fading of the dyed hair can be suppressed.
本発明の毛髪洗浄組成物は、ヘアカラー、ヘアマニキュア、ヘアカラートリートメントのいずれにも効果を発揮することできる。中でも、染着力が弱いとされるヘアカラートリートメントに対しても効果を発揮することができる。 The hair cleaning composition of the present invention can exert an effect on any of hair color, hair manicure, and hair color treatment. Above all, the effect can be exerted even on a hair color treatment having a weak dyeing power.
本発明の毛髪洗浄組成物によって褪色が抑制される好ましい染毛剤として、塩基性染料及び／又はＨＣ染料を含む染毛剤が挙げられる。塩基性染料及び／又はＨＣ染料は、主にヘアカラートリートメントに利用される。染毛剤に用いられる塩基性染料としては、例えば、分子内にアミノ基又は置換アミノ基を有する直接染料が挙げられ、具体的には、赤色２１３号、赤色２１４号、塩基性青７、塩基性青９、塩基性青２６、塩基性青７５、塩基性青９９、塩基性赤２、塩基性赤２２、塩基性赤５１、塩基性赤７６、塩基性黄５７、塩基性黄８７、塩基性橙３１、塩基性茶１６、塩基性茶１７、塩基性紫３、塩基性紫４、塩基性紫１４等が挙げられる。染毛剤に用いられるＨＣ染料としては、例えば、分子内にニトロ基を有する直接染料が挙げられ、具体的には、ＨＣ青２、ＨＣ青８、ＨＣ赤１、ＨＣ赤３、ＨＣ赤７、ＨＣ赤１１、ＨＣ赤１３、ＨＣ青２、ＨＣ青１８、ＨＣ黄２、ＨＣ黄４、ＨＣ黄５、ＨＣ黄９、ＨＣ黄１１、ＨＣ黄１３、ＨＣ橙１、ＨＣ橙２、ＨＣ紫１、ＨＣ紫２、４−ヒドロキシプロピルアミノ−３−ニトロフェノ−ル等が挙げられる。 Preferred hair dyes whose discoloration is suppressed by the hair washing composition of the present invention include hair dyes containing a basic dye and / or an HC dye. Basic dyes and / or HC dyes are mainly used for hair color treatment. Examples of the basic dye used in the hair dye include, for example, direct dyes having an amino group or a substituted amino group in the molecule, and specifically, Red 213, Red 214, Basic Blue 7, and Basic Blue 7. Basic blue 9, basic blue 26, basic blue 75, basic blue 99, basic red 2, basic red 22, basic red 51, basic red 76, basic yellow 57, basic yellow 87, base Basic orange 31, basic tea 16, basic tea 17, basic purple 3, basic purple 4, basic purple 14, and the like. Examples of the HC dye used in the hair dye include a direct dye having a nitro group in a molecule. Specifically, HC blue 2, HC blue 8, HC red 1, HC red 3, HC red 7 , HC red 11, HC red 13, HC blue 2, HC blue 18, HC yellow 2, HC yellow 4, HC yellow 5, HC yellow 9, HC yellow 11, HC yellow 13, HC orange 1, HC orange 2, HC Purple 1, HC Purple 2, 4-hydroxypropylamino-3-nitrophenol, and the like.
以下、本発明を実施例及び比較例によりさらに詳細に説明するが、本発明はこれらに何ら限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited thereto.
実施例及び比較例に先立って、下記に示す毛髪洗浄組成物の各成分を用意した。 Prior to Examples and Comparative Examples, each component of the hair cleaning composition shown below was prepared.
〈（Ａ）Ｎ−アシル−Ｎ−アルキルタウリン塩〉
・ココイルメチルタウリンタウリンＮａ（ダイヤポンK-TS(登録商標)：日油社製）（Ａ−１）
・ココイルメチルタウリンＮａ（NIKKOL CMT-30(登録商標)：日光ケミカルズ社製）（Ａ−２）
<(A) N-acyl-N-alkyltaurine salt>
-Cocoyl methyl taurine taurine Na (Diapon K-TS (registered trademark): manufactured by NOF CORPORATION) (A-1)
-Cocoyl methyl taurine Na (NIKKOL CMT-30 (registered trademark): manufactured by Nikko Chemicals Co., Ltd.) (A-2)
〈（Ｂ）オレフィンスルホン酸塩及びその比較成分〉
・オレフィン（C14-16）スルホン酸Ｎａ（リポランLB-440(登録商標)：ライオン社製）（Ｂ−１）
・ラウレス酢酸Ｎａ（ビューライトLCA-25N(登録商標)：三洋化成工業社製）
・ラウレス硫酸Ｎａ（エマールE-27C(登録商標)：花王社製）
<(B) Olefin sulfonate and its comparative component>
-Na olefin (C14-16) sulfonate (Lipolane LB-440 (registered trademark): manufactured by Lion Corporation) (B-1)
・ Laureth acetate Na (Bureite LCA-25N (registered trademark): manufactured by Sanyo Chemical Industries, Ltd.)
・ Laureth sulfate Na (Emal E-27C (registered trademark): manufactured by Kao Corporation)
〈（Ｃ）カチオン性ポリマー〉
・ポリクオタニウム−１０（カチナールHC-200(登録商標)：東邦化学工業社製）（Ｃ−１）
・塩化ヒドロキシプロピルトリモニウムデンプン（センサマーCI-50(登録商標)：ナルコ社製）（Ｃ−２）
<(C) Cationic polymer>
-Polyquaternium-10 (Catinal HC-200 (registered trademark): manufactured by Toho Chemical Industry Co., Ltd.) (C-1)
・ Hydroxypropyltrimonium chloride starch (Sensormer CI-50 (registered trademark): manufactured by Narco) (C-2)
〈（Ｄ）アミノ酸系界面活性剤〉
・ココイルグルタミン酸ＴＥＡ（アミソフトCT-12S(登録商標)：味の素ヘルシーサプライ社製）（Ｄ−１）
・ココイルグリシンＮａ（アミライトGCS-12K(登録商標)：味の素ヘルシーサプライ社製）（Ｄ−２）
・ココイルアラニンＴＥＡ（アミライトACT-12T(登録商標)：味の素ヘルシーサプライ社製）（Ｄ−３）
<(D) Amino acid surfactant>
・ Cocoylglutamic acid TEA (Amisoft CT-12S (registered trademark): manufactured by Ajinomoto Healthy Supply Co.) (D-1)
-Cocoylglycine Na (Amilite GCS-12K (registered trademark): manufactured by Ajinomoto Healthy Supply Co.) (D-2)
-Cocoylalanine TEA (Amilite ACT-12T (registered trademark): manufactured by Ajinomoto Healthy Supply Co.) (D-3)
〈その他の成分〉
・ラウリルベタイン（アンヒトール24B(登録商標)：花王社製）
・コカミドＤＥＡ（アミゾールCDE-G(登録商標)：川研ファインケミカル社製）
・ソルビトール（ソルビトール花王：花王社製）
・水
<Other ingredients>
・ Lauryl betaine (Amphitol 24B (registered trademark): manufactured by Kao Corporation)
-Cocamide DEA (Amizole CDE-G (registered trademark): manufactured by Kawaken Fine Chemical Co., Ltd.)
-Sorbitol (Sorbitol Kao: manufactured by Kao Corporation)
·water
〔実施例１〜９、比較例１〜１１〕
後記の表１および表２に記載の通り記載された量の各成分を添加して、実施例１〜９、及び比較例１〜１１の毛髪洗浄組成物を調製した。
[Examples 1 to 9, Comparative Examples 1 to 11]
The hair washing compositions of Examples 1 to 9 and Comparative Examples 1 to 11 were prepared by adding the respective components in the amounts described in Tables 1 and 2 described below.
＜毛髪褪色性＞
実施例及び比較例で調製された毛髪洗浄組成物の毛髪の褪色の抑制効果は、色差ΔＥ＊ａｂの値に基づいて、本発明の毛髪洗浄組成物を用いた毛髪の洗浄の前後における色差の差（毛髪褪色値）を指標として、評価を行った。
<Hair discoloration>
The effect of the hair cleaning compositions prepared in Examples and Comparative Examples for suppressing the fading of hair is based on the value of the color difference ΔE * ab, based on the value of the color difference before and after washing the hair with the hair cleaning composition of the present invention. Evaluation was performed using the difference (hair fading value) as an index.
ここで色差ΔＥ＊ａｂは、ＣＩＥ１９７６（Ｌ＊，ａ＊，ｂ＊）空間表色系による以下の色差公式：
ΔＥ＊ａｂ＝｛（ΔＬ＊）２＋（Δａ＊）２＋（Δｂ＊）２｝１／２
から求められる値である（日本色彩学会編 新編色彩科学ハンドブック（昭和60年）p.266）。本試験では、ΔＥ＊ａｂは分光測色計（ＣＭ−５, コニカミノルタ社製）を用いて測定した。
Here, the color difference ΔE * ab is expressed by the following color difference formula according to the CIE1976 (L * , a * , b * ) space color system:
ΔE * ab = {(ΔL * ) 2 + (Δa * ) 2 + (Δb * ) 2 } 1/2
(Handbook of New Color Science, edited by the Japan Society of Color Science, p.266). In this test, ΔE * ab was measured using a spectrophotometer (CM-5, manufactured by Konica Minolta).
〔毛髪褪色性の測定方法〕
（１）色差計にて各白髪（人毛白髪１００％、ＢＭ−Ｗ−Ａ（１０ｃｍ、１ｇ、５０本）、ビューラックス社製）を準備する。
（２）１００ｍＬビーカーに毛髪洗浄組成物の１０重量％水溶液を５０ｍＬ入れる。
（３）各白髪を上記ビーカー内の溶液に３分間浸漬させる。
（４）水道の蛇口からの流水で３０秒間すすぐ。
（５）水気を切って各白髪に白髪用利尻カラートリートメント＜ブラック＞（登録商標）を適量取り出し、手袋をして１分間、揉み込んで染色する。
（６）１０分間、静置する。
（７）水道の蛇口からの流水で１分間すすぐ。
（８）紙タオルで水気をふき取り後、ドライヤーで１分間、乾燥する。
（９）色差計にて各染色毛髪のΔＥ＊ａｂを３回測定し、それらの平均値ΔＥ＊ａｂ (α)を求める。
（１０）１００ｍＬビーカーに毛髪洗浄組成物の１０重量％水溶液を５０ｍＬ入れる。
（１１）各白髪を上記ビーカー内の溶液に３分間浸漬させる。
（１２）水道の蛇口からの流水で３０秒間すすぐ。
（１３）紙タオルで水気を拭き取って、ドライヤーで１分間乾燥させる。
（１４）色差計にて各染色毛髪のΔＥ＊ａｂを３回測定し、それらの平均値ΔＥ＊ａｂ (β)を求める。
（１５）ΔＥ＊ａｂ (β)からΔＥ＊ａｂ (α)を減じた値を、各毛髪洗浄組成物の毛髪褪色値とする。
[Method of measuring hair discoloration]
(1) Prepare each gray hair (100% human gray hair, BM-WA (10 cm, 1 g, 50 strands), manufactured by Beurax Co.) using a color difference meter.
(2) 50 mL of a 10% by weight aqueous solution of the hair cleaning composition is placed in a 100 mL beaker.
(3) Each gray hair is immersed in the solution in the beaker for 3 minutes.
(4) Rinse with running water from a tap for 30 seconds.
(5) Drain water, take out an appropriate amount of Rishiri Color Treatment for Black Hair <Black> (registered trademark) on each gray hair, wear gloves, and rub for 1 minute to dye.
(6) Let stand for 10 minutes.
(7) Rinse with running water from a tap for 1 minute.
(8) After wiping off the paper with a paper towel, dry it with a dryer for 1 minute.
(9) The ΔE * ab of each dyed hair is measured three times with a color difference meter, and the average value ΔE * ab (α) is obtained.
(10) 50 mL of a 10% by weight aqueous solution of the hair cleaning composition is placed in a 100 mL beaker.
(11) Each gray hair is immersed in the solution in the beaker for 3 minutes.
(12) Rinse with running water from a tap for 30 seconds.
(13) Wipe off moisture with a paper towel and dry with a dryer for 1 minute.
(14) The ΔE * ab of each dyed hair is measured three times with a color difference meter, and the average value ΔE * ab (β) is obtained.
(15) ΔE * ab value obtained by subtracting the (beta) from ΔE * ab (α), and hair discoloration value of each hair cleansing composition.
これらの毛髪洗浄組成物について毛髪褪色抑制値を測定した結果を、それぞれ以下の基準で評価し、これらの結果及び評価を、下記表１及び表２に併せて示す。なお、毛髪褪色値は数値が少ないほうが、褪色が抑制されたことを示す。
〔毛髪褪色性の評価基準〕
○…毛髪褪色値ΔＥ＊ａｂが、０以上５未満。
△…毛髪褪色値ΔＥ＊ａｂが、５以上７未満。
×…毛髪褪色値ΔＥ＊ａｂが、７以上。
The results of measuring the hair fading inhibition value of these hair cleaning compositions were evaluated according to the following criteria, and these results and evaluations are shown in Tables 1 and 2 below. In addition, the smaller the value of the hair fading value is, the more the fading is suppressed.
[Evaluation criteria for hair discoloration]
…: Hair fading value ΔE * ab is 0 or more and less than 5.
Δ: Hair fading value ΔE * ab is 5 or more and less than 7.
×: Hair fading value ΔE * ab is 7 or more.
上記表１より、Ｎ−アシル−Ｎ−アルキルタウリン塩（Ａ）、オレフィンスルホン酸塩（Ｂ）及びカチオン性ポリマー（Ｃ）を組み合わせた実施例１〜９の毛髪洗浄組成物はいずれも、毛髪の褪色抑制がされている。また、実施例１と実施例２の毛髪洗浄組成物を対比すると、（Ａ）成分としては、ココイルメチルタウリンタウリンナトリウムがココイルメチルタウリンナトリウムよりも褪色抑制効果が高いことが分かる。
（Ａ）〜（Ｃ）の成分に、さらに（Ｄ）アミノ酸系界面活性剤を組み合わせた実施例３〜８の毛髪洗浄組成物では、毛髪の褪色が格段に抑制されている。
From Table 1 above, all of the hair cleaning compositions of Examples 1 to 9 in which the N-acyl-N-alkyltaurine salt (A), the olefin sulfonate (B) and the cationic polymer (C) were combined were all hair. Is suppressed. Further, when the hair cleaning compositions of Example 1 and Example 2 are compared, it can be seen that as the component (A), cocoyl methyl taurine taurine sodium has a higher discoloration suppressing effect than cocoyl methyl taurine sodium.
In the hair cleaning compositions of Examples 3 to 8 in which the components (A) to (C) are further combined with the amino acid-based surfactant (D), the fading of the hair is remarkably suppressed.
上記表２より、比較例１〜５の毛髪洗浄組成物は、（Ａ）〜（Ｃ）成分の少なくとも一つを用いないものであるが、いずれも毛髪の褪色は抑制されていない。
また、比較例６の毛髪洗浄組成物は、（Ｂ）成分の代わりに他の陰イオン性洗浄成分を用いたものであるが、実施例１および２の（Ｂ）成分を用いた場合と比較すると、毛髪の褪色が抑制されていない。
また、比較例７〜９の毛髪洗浄組成物は、（Ａ）成分の代わりに他のアミノ酸系界面活性剤（Ｄ）を用いたものであるが、いずれの場合も実施例１および２の（Ａ）成分を用いた場合と比較すると、毛髪の褪色が抑制されていない。
さらに、比較例１０〜１１の毛髪洗浄組成物は、（Ｂ）成分の代わりに他の陰イオン性洗浄成分を用いたものであるが、アミノ酸系界面活性剤（Ｄ）をさらに組み合わせているにもかかわらず、いずれの場合も実施例１および２の（Ａ）成分を用いた場合と比較すると、毛髪の褪色が抑制されていない。
From Table 2 above, the hair cleaning compositions of Comparative Examples 1 to 5 do not use at least one of the components (A) to (C), but none of them does not suppress the fading of the hair.
The hair cleaning composition of Comparative Example 6 used another anionic cleaning component instead of the component (B), but compared with the case where the component (B) of Examples 1 and 2 was used. Then, the fading of the hair is not suppressed.
The hair cleaning compositions of Comparative Examples 7 to 9 used other amino acid-based surfactants (D) instead of the component (A). Compared with the case where the component (A) is used, the fading of the hair is not suppressed.
Furthermore, the hair cleaning compositions of Comparative Examples 10 to 11 use other anionic cleaning components instead of the component (B), but further include an amino acid-based surfactant (D). Nevertheless, in each case, the fading of the hair is not suppressed as compared with the case where the component (A) of Examples 1 and 2 is used.
＜泡立ち試験＞
上記褪色試験で用いた実施例１、実施例２、比較例７を用いて、以下の方法により泡立ち試験行った。
（１）ミルサー（岩谷産業社製、ＩＦＭ−６２０ＤＧ)の容器に、毛髪洗浄組成物の０．２重量％水溶液を１００ｍＬ入れる。
（２）１０秒間撹拌をする。
（３）撹拌停止してから、１分３０秒後の泡の高さ（ｍｍ）を測定する。
<Bubbling test>
Using Example 1, Example 2, and Comparative Example 7 used in the fading test, a bubbling test was performed by the following method.
(1) 100 mL of a 0.2% by weight aqueous solution of a hair cleaning composition is placed in a container of a millcer (IFM-620DG, manufactured by Iwatani Corporation).
(2) Stir for 10 seconds.
(3) Measure the height (mm) of the foam 1 minute and 30 seconds after the stirring was stopped.
上記泡の高さを測定した泡立ち試験の結果を、それぞれ以下の基準で評価し、これらの結果及び評価を、下記表３に併せて示す。
〔泡立ち試験の評価基準〕
○…泡立ちの高さが３０ｍｍ以上。
×…泡立ちの高さが３０ｍｍ未満。
The results of the foaming test in which the height of the foam was measured were evaluated according to the following criteria, and the results and evaluation are shown in Table 3 below.
[Evaluation criteria for foaming test]
…: Foaming height is 30 mm or more.
X: Foaming height is less than 30 mm.
上記表３より、実施例１及び２は、比較例７に比べて、泡の高さが高く、良好な泡立ちであることが分かった。 From Table 3 above, it was found that Examples 1 and 2 had higher foam height and better foaming than Comparative Example 7.
＜使用感試験＞
上記泡立ち試験と同様、褪色試験で用いた実施例１、実施例２、比較例７を用いて、使用感試験を行った。
使用感試験は、社内モニター５名で洗髪を実施し、洗浄時の泡の柔らかさ，髪のキシミ、乾燥後の髪の滑らかさ，髪のパサつき，頭皮の保湿感について、実施例１の使用感を基準（ＣＴＲ）とし、実施例２、比較例７を、それぞれ以下の基準で採点し、平均値を算出した。
<Usability test>
As in the foaming test, a usability test was conducted using Examples 1 and 2 and Comparative Example 7 used in the fading test.
The usability test was carried out with five in-house monitors to wash the hair. The softness of the foam at the time of washing, the blemishes of the hair, the smoothness of the hair after drying, the dryness of the hair, and the moisturizing sensation of the scalp of Using the feeling of use as a reference (CTR), Example 2 and Comparative Example 7 were scored according to the following criteria, respectively, and the average value was calculated.
〔使用感の採点基準〕
非常によい：＋３点、よい：＋２点、少し良い：＋１点、同じ：０点、少し悪い：−１点、悪い: −２点、非常に悪い：−３点
[Scoring criteria for usability]
Very good: +3 points, good: +2 points, slightly good: +1 point, same: 0 points, slightly bad: -1 point, bad: -2 points, very bad: -3 points
上記使用感試験の採点結果（平均値）を、それぞれ以下の基準で評価し、これらの結果及び評価を、下記表４に併せて示す。
〔使用感試験の評価基準〕
○…平均値が−０．４以上。
×…平均値が−０．４未満。
The scoring results (average values) of the usability test were evaluated according to the following criteria, and the results and evaluation are shown in Table 4 below.
[Evaluation criteria for usability test]
…: Average value is -0.4 or more.
X: Average value is less than -0.4.
上記表４より、実施例１及び２は、比較例７に比べて、洗浄時の泡が柔らかい感触のよいもので、洗浄時の髪のキシミを感じることがなく、乾燥後の髪が滑らかで、パサつきも少ないとともに頭皮の保湿感もある、毛髪洗浄組成物として、使用感のバランスが取れたよいものであった。 From Table 4 above, in Examples 1 and 2, compared to Comparative Example 7, the foam at the time of washing was soft and had a good feel, and the hair after drying was not felt and the hair after drying was smooth and smooth. It was a good hair-washing composition with less dryness and moisture on the scalp, with a good balance of feeling of use.
本発明の毛髪洗浄組成物によって、染色された毛髪の褪色を充分に抑制することができる。 The hair washing composition of the present invention can sufficiently suppress fading of dyed hair.
Claims (4)
（Ｂ）オレフィンスルホン酸塩、及び
（Ｃ）カチオン性ポリマー、
を含有する毛髪洗浄組成物。 (A) N-cocoyl-N-methyltaurine taurine sodium salt,
(B) an olefin sulfonate, and (C) a cationic polymer,
A hair washing composition comprising:
（Ｂ）オレフィンスルホン酸塩、及び
（Ｃ）カチオン性ポリマー、
を含有する毛髪洗浄組成物である褪色抑制剤。 (A) N-cocoyl-N-methyltaurine taurine sodium salt ,
(B) an olefin sulfonate, and (C) a cationic polymer,
Hair cleansing composition der Ru褪 color inhibitor containing.
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| JP3624338B2 (en) * | 1998-04-22 | 2005-03-02 | 株式会社コーセー | Shampoo composition |
| JP2001122742A (en) * | 1999-10-28 | 2001-05-08 | Kose Corp | Shampoo composition |
| JP4675525B2 (en) * | 2001-09-21 | 2011-04-27 | 日本メナード化粧品株式会社 | Hair washing cosmetics |
| JP3961976B2 (en) * | 2003-03-27 | 2007-08-22 | 美智子 朝田 | Shampoo for curly hair |
| JP3909038B2 (en) * | 2003-04-28 | 2007-04-25 | 株式会社資生堂 | Cleaning composition |
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| EP2612653B2 (en) * | 2010-08-31 | 2021-06-09 | Otsuka Pharmaceutical Co., Ltd. | Composition for cleaning scalp and head hair |
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| JP6272058B2 (en) * | 2013-02-01 | 2018-01-31 | 花王株式会社 | Internal olefin sulfonate composition |
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