KR100845393B1 - A conditioning shampoo composition - Google Patents

Abstract

A conditioning shampoo composition is provided to have soft and rich air bubbles, improve feeling of combing in a wet state as well as in a dry state and provide smoothness and softness to hair. A conditioning shampoo composition comprises: 5-30 wt.% of an anionic surfactant such as C8-18 alkyl sulfate, alkyl ether sulfate and a mixture thereof; 0.1-10 wt.% of an amino acid surfactant which is an acid or a hydrochloride represented by RCOA or RA(wherein R is linear or branched C8-20 alkyl or alkenyl, and A is an amino acid); 0.01-10 wt.% of alkanol amide such as linear or branched monoethanol amine or diethanolamine substituted or unsubstituted by C1-22 alkyl or alkenyl; and 0.05-5.0 wt.% of a cationic surfactant such as dialkyldimethylammonium chloride where an alkyl group is a C3-22 aliphatic group or an aromatic having a carbon number of less than 22.

Description

Conditioning shampoo composition

The present invention relates to a conditioning shampoo composition. More specifically, the present invention relates to a conditioning shampoo composition which improves the fly-away of a shampoo mixed with a silicone or a hair dressing agent, and does not lack the amount of bubbles even when it contains a cationic surfactant and smoothly improves the softness and smoothness of the hair. will be.

The hair of modern people is contaminated by the exposure to ultraviolet light, contact with the surrounding environment such as dust, and sebum secreted from the hair follicles, which causes a lot of damage due to frequent perm, hair dry, dyeing and combing. Damaged hair can be difficult to handle, such as when wet or dried, tangled and stiff, poorly combed, and poorly glossy. Thus, consumers' demands and preferences for conditioning products that improve the appearance and feel of hair and make them easier to handle are increasing day by day.

Conditioning shampoo is a product that has a cleansing effect that removes contamination on hair and scalp, and a conditioning effect that makes damaged hair easy to handle, shiny and soft. Therefore, the conditioning shampoo composition has been used for the purpose of improving the hair feel and visual benefits, such as softness, flexibility, gloss, antistatic, ease of combing, etc., with an appropriate cleaning effect.

Hair shampoos keep hair clean by removing dirt and sebum from the hair and scalp. However, the shampoo process has the disadvantage of tangling and making the hair difficult to handle. This removes the sebum and hair moisturizing ingredients by the shampoo, so that the softness of the hair becomes weak and dry. In order to compensate for this, the method of increasing the flexibility of the hair by including the hair conditioning agent in the shampoo has been studied, but it is not satisfactory for various reasons.

Conditioning on hair is provided primarily through the use of cationic surfactants and hair conditioning agents such as polymers, silicone conditioning agents, hydrocarbon oils and fatty alcohols.

Cationic surfactants and polymers, hydrocarbon oils and fatty alcohols are known to provide softness to hair and prevent static electricity, but have the disadvantage of inhibiting bubbles by forming complexes with anionic surfactants used for cleaning.

Non-volatile silicone oil and polymer silicone gum (Gum), which are commonly used in hair conditioning agents, give gloss and flexibility to the hair and provide softness to the hair after drying, while lacking moisturizing properties and poor quality with other ingredients. Due to its compatibility, there is a limitation in its utilization, and when it is used repeatedly for a long time, it accumulates in the hair, thereby reducing the softness and accelerating recontamination by dust and sebum. (Personal Care, 2005.11., P.41 ~ 43) In addition, silicone oil acts as an antifoaming agent such as oil in the shampoo composition, significantly reducing the cleaning ability of anionic surfactants (US Pat. Nos. 2,826,551, 3,964,500, 4,364,837). number). In order to improve this, US Pat. No. 4,741,855 states that while using anionic surfactants, while maintaining excellent washing performance, it can provide the benefits of excellent conditioning to hair, but lacks in severely damaged hair.

In order to solve the problem of silicones, Japanese Patent Publications H6-17097 and H7-11287 mention that polyhydric metal ions, anionic surfactants, amino acid surfactants and anionic surfactants can provide conditioning benefits. This is also lacking in hair with severe chemical damage. U.S. Patent No. 6,284,230 mentions certain anionic surfactants that can enhance the conditioning effect by forming coacervates through polyvalent metal ions and amino acid surfactants.However, high adsorption of cationic polymers and silicone hairs on the hair There is a cumulative disadvantage.

Despite these efforts to select a suitable combination of cleansing and conditioning effects, it is desirable to provide a further improved hair conditioning shampoo composition. For example, it is desirable to improve the overall conditioning effect while maintaining the cleaning effect which is the basic performance of the shampoo. Simply increasing the conditioning agent not only causes side effects such as greasy hair feel and accumulation in the hair when repeated use, but also lowers the ability of the cleaning surfactant to remove hair contamination.

Therefore, there is a further need for a shampoo composition which contains a conditioning agent and at the same time can be combined with an anionic surfactant in the shampoo to improve cleaning power without reducing bubbles.

It is an object of the present invention to provide a hair cleaning composition, preferably a composition suitable for rinsing, which contains a conditioning agent and which provides excellent foaming properties.

It is another object of the present invention to provide a hair cosmetic composition which increases the flexibility of the hair with an increase in various conventional conditioning effects.

The present invention to achieve the above object,

In shampoo composition containing anionic surfactant

Provided is a composition comprising 5 to 30% by weight anionic surfactant, 0.1 to 10% by weight amino acid surfactant, 0.01 to 5.0% by weight alkanolamide, and 0.01 to 5.0% by weight cationic surfactant based on the total weight of the composition.

Shampoo compositions of the present invention include anionic surfactants that provide cleaning performance to the composition. Preferred anionic surfactants suitable for use in shampoo compositions are alkyl or alkyl ether sulfates. Preferably alkyl or alkyl ether sulfate having about 8 to 18 carbon atoms. The concentration of the surfactant component of the alkyl or alkylethersulfate in the shampoo composition should be sufficient to provide the desired washing and foaming performance, and in this conditioning shampoo composition about 5 to 50% by weight, preferably based on the total weight of the composition About 8 to 30 weight percent, more preferably about 10 to 25 weight percent. When added below the preferred range, the washing effect is lowered, and when added above the above range, the conditioning effect is inhibited.

These materials are each of the formula ROSO ₃ M and RO (C ₂ H ₄ O) xSO ₃ M, wherein R is alkyl or alkenyl having from about 8 to about 18 carbon atoms, x is an integer from 1 to 10, and M is a cation , For example, polyvalent metal cations such as ammonium, sodium, potassium). The cation M should be chosen such that the anionic surfactant is water soluble.

Preferably they are alkyl groups of about 8 to 22, preferably about 10 to 16, more preferably about 12 to 14 carbon atoms in both alkyl and alkyl ether sulfates. Alkyl ether sulfates have from about 1 to 10, preferably from about 1 to 5, more preferably from 2 to 3 moles of ethylene oxide.

Suitable anionic surfactants for use in the shampoo compositions of the present invention are ammonium lauryl sulfate, ammonium laurate sulfate, sodium lauryl sulfate, sodium laurate sulfate.

Another surfactant suitable for use in the present invention is an amino acid surfactant. The concentration of amino acid surfactant component in the shampoo composition should be sufficient to provide the desired foaming performance and sufficient hair softening effect, and is about 0.001 to 20% by weight, preferably about 0.01, based on the total weight of the conditioning shampoo composition. To 15% by weight, more preferably about 0.1 to 10% by weight. When added below the above range, foaming performance is lowered, and when added in excess, cleaning power is lowered. Amino acid surfactants may be selected in the form of acids or salts as surfactants comprising the structure of amino acids and having structurally hydrophilic character. Amino acid surfactants are of the formula RCOA or RA, wherein R is alkyl or alkenyl having from about 8 to about 20 carbon atoms and may be straight or branched. A is an amino acid selected from glutamic acid, glycine, alanine, sarcosine. Has

Suitable amino acid surfactants for use in the shampoo compositions of the present invention include N-cocoylalaninate, N-acyl potassium glycine, lauroyl glutamate, thioecoylalanine, lauryl sarcosine, cocoyl Sarcosine, sodium lauroyl sarcosinate, sodium cocoylalanine. More suitable amino acid surfactants for use in the shampoo composition of the present invention are teecocoylalanine, sodium cocoylalanine, teecocoylglutamate, disodium cocoylglutamate. Most preferred amino acid surfactants for use in the shampoo composition of the present invention are sodium cocoylalanine, disodium cocoylglutamate.

Another surfactant used in the present invention is alkanolamide. The concentration of alkanolamide in the shampoo composition should be sufficient to have the desired foaming performance and foam stability, and about 0.001 to 20% by weight, preferably about 0.01 to 10% by weight, based on the total weight of the conditioning shampoo composition, More preferably about 0.1 to 5% by weight. Alkanolamides have the formula RCO (CH ₂ CH ₂ OH) x wherein R is alkyl or alkenyl of about 1 to about 22 carbon atoms and may be straight or branched and x is an integer between 1 and 2. Have

According to one embodiment of the present invention, the alkanolamide may be a linear or branched monoethanolamine or diethanolamine unsubstituted or substituted with alkyl or alkenyl having 1 to 22 carbon atoms.

According to one embodiment of the present invention, suitable alkanolamides for use in shampoo compositions are cocamide monoethanolamine (cocamide MEA), acetamide MEA, behenamide MEA, Hydroxy stearamide M, lactamide M, lauramide M, linoleamide M, octasamide M, octaamide M, oleamide M, oliveamide M, palmamide M, iso Stearamide die, almondamide die, apricotamide die, avocadoamide die, cocamide die, behenamide die, conamide die, hydrogenated tallowamide die, isotearamide die Ei, lauramid die, myristamide Yieyi Num Ca Id di yieyi, oleic amide di yieyi, an amide di yieyi olive, palm amide di yieyi. More suitable alkanol amides for use in the shampoo compositions of the invention include cocamide M, acetamide M, behenamide M.A., Babasuamide M.A., hydroxy stearamide M.A., Lactamide M.A., Lauramide A.M., Linoleamide M.A., Myramideamide.A.M. M.A., Palmamide M.A. The most preferred alkanol amides for use in the shampoo composition of the present invention are cocamide M, behenamide M, lauramid M, linoleamide M, myramide amide, oleamide M, olive amide M This is Palmamide M.A.

The present invention includes cationic surfactants as conditioning agents. The cationic surfactant is represented by [R1R2-N-R3R4] ⁺ X ^- wherein R1, R2, R3 and R4 are each independently or simultaneously saturated or unsaturated chain groups having 1 to 20 carbon atoms, benzyl group, hydroxy ethyl group, Or a hydroxy ethyl group to which 1 to 20 ethyl oxide groups or propylene oxide groups are added, and X is a halogen group element, sulfate group, or acetate group. The concentration of cationic surfactant in the shampoo composition should be sufficient to have the desired foaming performance and foam stability, and generally about 0.001 to 20% by weight, preferably about 0.01 to 10% by weight, based on the total weight of the composition, More preferably about 0.05 to 5% by weight. When added below the above range, the conditioning effect is lowered, and when added above, foaming performance and foam stability are insufficient.

In the present invention, a general conditioning agent may be used to increase the conditioning effect, and a fatty alcohol, a cationic surfactant, or the like may be used alone or in combination.

The fatty alcohol preferably has 14 to 22 carbons if it has a straight chain or branched alkali or alkenyl group having 12 to 26 carbon atoms.

Cationic surfactants are cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, stearamidopropyltrimethylammonium chloride, behemamidopropyltrimethylammonium chloride, stearamidopropyltrimethylammoniummethosulfate, dicetyldimethylammonium Chloride, distearyl dimethylammonium chloride, ditallowdimethylammonium chloride, cetylstearyldimethylammonium chloride, tricetylmethylammonium chloride and the like can be used, preferably disetyldimethylammonium chloride, distearyldimethylammonium chloride , Ditallowdimethylammonium chloride, cetylstearyldimethylammonium chloride, tricetylmethylammonium chloride, dicodimethylammonium chloride, more preferably dicetyldi It is butyl ammonium chloride, distearyl dimethyl ammonium chloride, low dital dimethyl ammonium chloride, cetyl stearyl dimethyl ammonium chloride, methyl ammonium chloride decoder coordination is selected to be a dialkyl dimethyl ammonium chloride.

The compositions of the present invention optionally contain components well known to those skilled in the art, such as amphoteric surfactants, other surfactants, humectants, fatty substances, wetting, as conventional optional ingredients for maintaining basic physical properties and quality. Of course, the ingredients, silicones, oils, fragrances, preservatives, vitamins, proteins and the like may include components commonly used in the manufacture of hair cosmetics. Specifically, Preservative such as paraoxybenzoic acid ester; Humectants, such as carboxy vinyl polymers; Hair repair agents such as hydrolyzed wheat protein; Viscosity modifiers such as sodium chloride, ammonium chloride and the like; And the like can be used within the ordinary knowledge of those skilled in the art.

Hereinafter, the present invention will be described in more detail with reference to the following examples. These examples are only for illustrating the present invention, but the scope of the present invention is not limited thereto. That is, other variations of the invention may be permitted without departing from the spirit and scope of the invention within the scope of the skilled person of the hair care composition.

All percentages of the present invention are by weight unless otherwise indicated, and all ratios are by weight unless otherwise indicated. Unless indicated otherwise, all percentages, ratios, and contents of ingredients mentioned herein are based on the actual amounts of ingredients and do not include solvents, fillers, or other materials that can be combined with the ingredients in the commercial product.

Example  1 to 6

According to the invention, conditioning shampoo compositions having the compositions of Examples 1 to 6 are prepared.

(Unit: weight%) Composition Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Sodium Lauret-2 Sulfate 10 10 10 10 10 10 Pulping agent 8 8 8 8 8 8 Dimethicone emulsion 2 2 2 2 2 2 Cocamidopropyl Betaine 2 2 2 2 2 2 Cetyl alcohol 0.5 0.5 0.5 0.5 0.5 0.5 Disodium cocoyl glutamate ^{1 )} 0.5 One 3 5 Sodium cocoyl alanate ^{2 )} - - - - One 3 Cocamide MB ^{3 )} 0.5 0.5 0.5 0.5 0.5 0.5 Distearyldimethylammonium chloride ^{4 )} 0.8 0.8 0.8 0.8 0.8 0.8 Carboxy Vinyl Polymer 0.2 0.2 0.2 0.2 0.2 0.2 Hydrolyzed Wheat Protein 0.2 0.2 0.2 0.2 0.2 0.2 Polyquaternium-10 0.1 0.1 0.1 0.1 0.1 0.1 Paraoxybenzoic acid ester 0.05 0.05 0.05 0.05 0.05 0.05 incense A reasonable amount A reasonable amount A reasonable amount A reasonable amount A reasonable amount A reasonable amount Citric acid A reasonable amount A reasonable amount A reasonable amount A reasonable amount A reasonable amount A reasonable amount Purified water Residual amount Residual amount Residual amount Residual amount Residual amount Residual amount

1) Product Name: Amisoft CS-22 (Maker: Ajinomoto)

2) Product Name: Amilite ACS-12 (Maker: Ajinomoto)

3) Product Name: Hisol CME (Maker: Taedong)

4) Product Name: Varisoft TA 100 (Maker: Goldschmidt)

The present compositions according to the above-mentioned Examples 1 to 6 go through the following manufacturing process according to the composition of Table 1. Sodium laurate-2 sulfate, cocamide propyl betaine, cetyl alcohol, distearyl dimethyl ammonium chloride, polyquaternium 10 and cocamide ME were added to the purified water and warmed up to 70 ° C. Stirred for a minute. Next, the carboxyvinyl polymer dispersed in advance in an appropriate amount of water was added, and the mixture was cooled and stirred to 45 ° C., followed by addition of paraoxybenzoate, fragrance, and dimethicone emulsion to the mixture, followed by stirring for 30 minutes to prepare a shampoo.

Comparative example  1 to 4

In order to compare the conditioning shampoo composition and the product using the conventional moisturizing agent and conditioning agent according to the above embodiment, the amount of the other composition except the content of aminoalkyldimethicone and dialkyl carbonate was the same, and the hair was glossy in the dry state. Comparative Examples 1 to 4 were prepared by varying the content of the polymer dimethicone having an effect on the softness and the composition shown in Table 2 below.

(Unit: weight%) Composition Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Sodium Lauret-2 Sulfate 13 13 10 10 Pulping agent 8 8 8 8 Dimethicone emulsion 2 2 2 2 Cocamidopropyl Betaine 2 2 2 2 Cetyl alcohol 0.5 0.5 0.5 0.5 Disodium cocoyl glutamate ^{1 )} - - 3 - Sodium cocoyl alanate ^{2 )} - - - 3 Cocamide MB ^{3 )} 0.5 0.5 - - Distearyldimethylammonium chloride ^{4 )} 0.8 - 0.8 0.8 Carboxy Vinyl Polymer 0.2 0.2 0.2 0.2 Hydrolyzed Wheat Protein 0.2 0.2 0.2 0.2 Polyquaternium-10 0.1 0.5 0.1 0.1 Paraoxybenzoic acid ester 0.05 0.05 0.05 0.05 incense A reasonable amount A reasonable amount A reasonable amount A reasonable amount Citric acid A reasonable amount A reasonable amount A reasonable amount A reasonable amount Purified water Residual amount Residual amount Residual amount Residual amount

Comparative example  5 to 8

In addition, Comparative Examples 5 to 8 were prepared as the compositions shown in Table 3 below to determine the ratio of the conditioning shampoo composition and the specific ingredients of the present technology.

(Unit: weight%) Composition Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Sodium Lauret-2 Sulfate 10 10 10 10 Pulping agent 8 8 8 8 Dimethicone emulsion 2 2 2 2 Cocamidopropyl Betaine 2 2 2 2 Cetyl alcohol 0.5 0.5 0.5 0.5 Disodium cocoyl glutamate ^{1 )} 0.05 20 - - Sodium cocoyl alanate ^{2 )} - - 0.05 20 Cocamide MB ^{3 )} 0.5 0.5 0.5 0.5 Distearyldimethylammonium chloride ^{4 )} 0.8 0.8 0.8 0.8 Carboxy Vinyl Polymer 0.2 0.2 0.2 0.2 Hydrolyzed Wheat Protein 0.2 0.2 0.2 0.2 Polyquaternium-10 0.1 0.1 0.1 0.1 Paraoxybenzoic acid ester 0.05 0.05 0.05 0.05 incense A reasonable amount A reasonable amount A reasonable amount A reasonable amount Citric acid A reasonable amount A reasonable amount A reasonable amount A reasonable amount Purified water Residual amount Residual amount Residual amount Residual amount

Experimental Example  1: [bubble force evaluation]

200 ml of the conditioning shampoo 0.25% solution prepared in Examples 1 to 6 and Comparative Examples 1 to 4 were dropped freely for 30 seconds using a pipette at a height of 90 cm in a 50 mm diameter cylinder containing 50 ml of the same shampoo solution for 30 seconds. The bubbles generated were measured and the results are shown in Tables 4 and 5 below. The shampoo diluent and bubble measuring cylinder were kept at 40 ° C.

Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Bubble force (mm) 210 215 230 260 210 235 Bubble stability after 1 hour (mm) 190 200 220 255 200 230

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Bubble force (mm) 165 200 190 185 Bubble stability after 1 hour (mm) 85 140 120 120

Through Table 4 and Table 5, the shampoo of Example 1 to Example 6 containing all of the anionic surfactant, amino acid surfactant, alkanolamide, cationic surfactant according to the present invention Comparative Example 1 containing a cationic surfactant It was confirmed that the foaming power and bubble stability significantly improved than Comparative Example 4.

Experimental Example  2: [consumer Feeling  evaluation : Feeling  And conditioning]

In order to evaluate the feeling of use and conditioning effects of the conditioning shampoos prepared in Examples 3, 6 and Comparative Examples 1, 2 and 3, the 25 to 40 years old with hair damaged relatively due to dyeing and perming 200 women were selected and compared to the evaluation items shown in Table 5 below for one month. The lowest score was 1 point and the highest score was 5 points. The test results are shown in Table 6 below.

Evaluation Item Example 3 Example 6 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 6 Rich amount of bubbles in shampoo 4.5 4.7 2.0 3.6 3.3 4.8 Good feeling of bubbles when shampooing 4.5 4.5 1.5 2.5 2.5 2.0 Hair does not tangle during shampooing. 4.2 4.1 3.1 2.1 2.5 2.0 Hair does not clump during rinsing. 4.0 4.0 3.5 1.8 2.4 2.0 Hair is soft after drying 4.0 4.5 3.3 1.3 2.1 1.3 Good hair gloss after drying 4.3 4.0 3.5 1.5 2.2 1.5

As a result of the test, Examples 3 and 6 according to the present invention, the amount of bubbles, feeling, hairiness and dryness in the shampoo than Comparative Example 1, Comparative Example 3 does not contain an amino acid surfactant and / or alkanolamide It was evaluated as excellent in hair softness and gloss after. In addition, Examples 3 and 6 according to the present invention was evaluated to have an excellent improvement effect on the feeling of air bubbles, hair dressing, softness after drying, and shine than Comparative Example 2 containing no cationic surfactant. In addition, Example 3 according to the present invention has been evaluated to have an excellent improvement in the feeling of air bubbles, hair feel, softness after drying, shine compared to Comparative Example 6 containing an excessive amount of the amino acid surfactant, the specificity of the amino acid surfactant It was confirmed that there is an improvement effect within the content range.

As described above, the conditioning shampoo composition of the present invention contains a cationic surfactant while containing an anionic surfactant, an amino acid surfactant, an alkanolamide, and a cationic surfactant, so that the bubbles are soft and abundant, wet or dry. Not only does it improve the feeling of combing of the hair, but it also has the effect of imparting hair such as hair softness and smoothness, in particular.

Claims (10)

Based on the total weight of the composition (A) 5 to 30% by weight of anionic surfactant, (B) 0.1 to 10% by weight amino acid surfactant (C) Alkanolamide 0.01 to 5.0% by weight (D) Conditioning shampoo composition, characterized in that it comprises 0.05 to 5.0% by weight cationic surfactant. The conditioning shampoo composition of claim 1, wherein the anionic surfactant is an alkyl sulfate, an alkyl ether sulfate or a mixture thereof having 8 to 18 carbon atoms. The acid or chloride according to claim 1, wherein the amino acid surfactant is represented by the formula RCOA or RA, wherein R is alkyl or alkenyl having 8 to 20 carbon atoms and may be straight or branched. A is an amino acid. Conditioning shampoo composition, characterized in that. The conditioning shampoo composition of claim 3, wherein A of the amino acid surfactant is selected from glutamic acid, glycine, alanine, and sarcosine. The method of claim 1, wherein the amino acid surfactant is N-cocoylalaninate, N-acyl potassium glycine, lauroyl glutamate, thyicoycoylalanine, lauryl sarcosine, cocoyl sarcosine, sodium Conditioning shampoo composition, characterized in that at least one or a mixture of two or more selected from the group consisting of lauroyl sarcosinate, sodium cocoyl alanate. The method according to claim 5, wherein the amino acid surfactant is at least one or a mixture of two or more selected from the group consisting of thyicoycoyl alanate, sodium cocoyl alanate, thyicoycoyl glutamate, disodium cocoyl glutamate Conditioning shampoo composition. The conditioning shampoo composition of claim 1, wherein the alkanolamide is a straight or branched chain monoethanolamine or diethanolamine unsubstituted or substituted with alkyl or alkenyl having 1 to 22 carbon atoms. The method of claim 1, wherein the alkanolamide is cocamide monoethanolamine (CACamide MEA), acetamide MEA, behenamide MEI, hydroxy stearamide M, lactamide M, Laura Amide M, linoleamide amide, myramide amide, octaamide amide, oleamide amide, olive amide MI, palmamide DY, isostearamide DY, almond amide DY, aprim Cotamide Dei, Avocardamide Dei, Cocamide Dei, Behenamide Dei, Conamide Dei, Hydrogenated Tallowamide Dei, Isostearamid Dei, Lauramide Dei, Myramideamide Dei , Mincamide die, oleamide die, Conditioning shampoo composition, characterized in that at least one or a mixture of two or more selected from the group consisting of olive amide die, or palmamide die. The conditioning shampoo composition of claim 1, wherein the cationic surfactant is an aliphatic group having 3 to 22 carbon atoms or a dialkyldimethylammonium chloride selected from aromatics having 22 or less carbon atoms. 10. The dialkyldimethylammonium of claim 9, wherein the cationic surfactant is selected from dicetyldimethylammonium chloride, distearyldimethylammonium chloride, ditallowdimethylammonium chloride, cetylstearyldimethylammonium chloride, and dicocodimethylammonium chloride. Conditioning shampoo composition, characterized in that one or more mixtures from the group consisting of chlorides.