JP2001122742A - Shampoo composition - Google Patents

Shampoo composition

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Publication number
JP2001122742A
JP2001122742A JP30672299A JP30672299A JP2001122742A JP 2001122742 A JP2001122742 A JP 2001122742A JP 30672299 A JP30672299 A JP 30672299A JP 30672299 A JP30672299 A JP 30672299A JP 2001122742 A JP2001122742 A JP 2001122742A
Authority
JP
Japan
Prior art keywords
mass
hair
shampoo
good
feeling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP30672299A
Other languages
Japanese (ja)
Inventor
Toshiaki Mori
俊彰 森
Original Assignee
Kose Corp
株式会社コーセー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kose Corp, 株式会社コーセー filed Critical Kose Corp
Priority to JP30672299A priority Critical patent/JP2001122742A/en
Publication of JP2001122742A publication Critical patent/JP2001122742A/en
Application status is Pending legal-status Critical

Links

Abstract

(57) [Summary] [Problem] Good usability, good foaming and good foam feel during washing and sufficient washing effect are obtained, and hair is not supple even when rinsing. Provided is a shampoo composition that imparts suppleness and softness to washed hair. The following components (A) to (E): (A) 1 to 15% by mass of a tetradecenesulfonic acid salt,
(B) 1 to 15% by mass of an N-acylmethyltaurine salt,
(C) 1 to 10% by mass of amphoteric surfactant, (D) 0.05 to 5% by mass of cationic polymer, (E) N-long-chain acyl acidic amino acid ester and / or cystine derivative 0.0
A shampoo composition containing from 0.01 to 5% by mass.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

FIELD OF THE INVENTION The present invention relates to shampoo compositions and, more particularly, to good usability, foaming during cleaning,
The present invention relates to a shampoo composition which has a good foam feel, has a sufficient washing effect, and gives a smooth feel without squeezing hair upon rinsing, and makes the washed hair supple.

[0002]

2. Description of the Related Art Conventionally, in shampoos, desired qualities such as detergency and foaming property are obtained by selecting various surfactants according to the purpose and use thereof or by combining them appropriately. ing. In addition, fatty acid amides, amphoteric surfactants, thickening water-soluble polymers, etc. are added to improve usability, such as giving the shampoo an appropriate viscosity to make it easier to pick up and apply to hair. And the basic quality as a shampoo has been formed. Furthermore, to provide additional quality to the shampoo, such as smoothing the texture of the foam, reducing the squeaky feeling during rinsing, and giving the washed hair a good texture by reducing the stiff feel of the hair Attempts have been made to blend various water-soluble polymers, oils, keratin derivatives and the like.

[0003]

However, in order to impart additional quality to the shampoo, for example, when hydroxyethylcellulose or the like is blended as a water-soluble polymer, it is expected that a certain degree of squeaky feeling is eliminated during rinsing. Although the effect is possible, the effect is not sufficient, and if the amount is increased to compensate for it, the hair may become firm and stiff. In addition, when a hydrocarbon oil, lanolin, or the like is blended as an oil agent, for example, even if a moist feeling or an emollient feeling of the hair is obtained, there are problems such as poor foaming and heavy washed hair. . When a keratin derivative such as hydrolyzed keratin is blended, a certain degree of moist feeling can be obtained, but there are problems such as a stiff feel, excessive firmness, and firmness of the washed hair. Therefore, good usability, foaming during washing, the feeling of foam is good, has a sufficient washing effect, and gives a smooth feeling without squeaking hair when rinsing,
The development of a shampoo that makes the washed hair supple has been desired.

[0004]

In view of such circumstances, the present inventor has conducted intensive studies to solve the above-mentioned problems, and as a result, has found that α
A combination of a specific amount of a cationic polymer in a shampoo composition containing a specific amount of a tetradecene sulfonate, one of olefin sulfonates, an N-acylmethyltaurate salt, and an amphoteric surfactant, and , N-long-chain acyl acidic amino acid ester and / or cystine derivative, provides good foaming and foam feel (smoothness, creamy feeling) and sufficient washing effect during washing. The present inventors have found that an excellent shampoo composition can be obtained that does not cause the hair to be supple at times and that gives the washed hair a supple, soft and good texture, thereby completing the present invention.

That is, the present invention provides the following components (A) to
(E); (A) 1 to 15% by mass of tetradecene sulfonate (B) 1 to 15% by mass of N-acylmethyltaurine salt (C) 1 to 10% by mass of amphoteric surfactant (D) Cationic polymer 0 A shampoo composition containing 0.005 to 5% by mass of (E) 0.001 to 5% by mass of an N-long-chain acyl acidic amino acid ester and / or a cystine derivative.
The details will be described below.

[0006]

BEST MODE FOR CARRYING OUT THE INVENTION The tetradecene sulfonate of the component (A) used in the present invention is one kind of α-olefin sulfonate which is a general-purpose anionic surfactant in shampoos. In the present invention, it is a component necessary for imparting good foaming properties and obtaining an excellent cleaning effect of removing stains on hair and skin. Examples of the counter base in the tetradecene sulfonate of the component (A) include sodium, potassium, monoethanolamine, diethanolamine, triethanolamine, ammonium, and arginine.
In the present invention, a sodium salt is particularly preferred.

In the present invention, the compounding amount of the tetradecenesulfonic acid salt of the component (A) is 1 to 15% by mass (hereinafter, simply referred to as “%”), and more preferably 5 to 10%. If the compounding amount is less than 1%, sufficient foaming power and cleaning effect cannot be obtained, and if the compounding amount exceeds 15%, a squeaky feeling of the hair tends to be caused during rinsing and the feeling of use tends to be deteriorated. It is difficult to obtain sufficient quality.

[0008] The N-acylmethyltaurine salt of the component (B) used in the present invention is also one of the important detergents for shampoos, and is an effective component for improving foaming properties. In the present invention, by using together with the tetradecene sulfonate of the component (A), a good foaming property is exhibited at the time of washing, and a rich foam is obtained, and the feel of the foam is synergistically improved to provide a smooth foam. You can get creamy foam. The counter base in the N-acylmethyltaurine salt of the component (B) is not particularly limited, and those usually used as bases such as sodium, potassium, monoethanolamine, diethanolamine, triethanolamine, ammonium, and arginine can be used. However, in the present invention, sodium is particularly desirable. Specific examples of the component (B) include N-cocoyl-N-methyltaurine sodium, N-cocoyl-N-methyltaurine calcium,
Examples include sodium lauroyl N-methyltaurine, sodium N-myristoyl-N-methyltaurine, sodium N-palmitoyl N-methyltaurine, sodium N-stearoyl-N-methyltaurine, and the like. In the present invention, N-cocoyl-N-methyl Particularly preferred are sodium taurine and sodium N-lauroyl N-methyltaurine.

In the present invention, the N-acylmethyltaurine salt of the component (B) may be used alone or in combination of one or more kinds, and may be used alone or in combination.
-15%, more preferably 2-10%. If the blending amount is less than 1%, it is difficult to obtain sufficient foaming, a cleaning effect and a good foam feel, and if the blending amount exceeds 15%, the stability with time, especially at low temperatures, is reduced, and a uniform system is not obtained. It is difficult to obtain sufficient quality as a shampoo because it is difficult to form and impairs the appearance and ease of use.

The amphoteric surfactant of component (C) used in the present invention is similar to the anionic surfactants such as the tetradecene sulfonate of component (A) and the N-acylmethyltaurine salt of component (B). In addition, it is one of the important bases of shampoo, and is an effective component for improving the foaming property. In the present invention, in addition to this, the effect of synergistically improving the feel of the foam, such as the smoothness and the creamy feeling of the foam at the time of washing, is exhibited. In the present invention, the amphoteric surfactant of the component (C) is not particularly limited as long as it is an amphoteric surfactant which can be usually used in shampoos. However, a betaine acetate-type amphoteric surfactant, an amidobetaine-type amphoteric surfactant or imidazoline Amphoteric surfactants are preferred. Specifically, as the betaine acetate-type surfactant, octyl dimethyl amino acetate betaine, lauryl dimethyl amino acetate betaine, coconut oil alkyl dimethyl amino acetate betaine, myristyl dimethyl amino acetate betaine, cetyl dimethyl amino acetate betaine, lauryl dihydroxyethyl amino acetic acid Betaine,
Cetyl dihydroxyethylaminoacetic acid betaine and the like, amide betaine type amphoteric surfactants include coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine, lauric acid amidopropyldimethylaminoacetic acid betaine, and the like, and as an imidazoline type amphoteric surfactant. Is N-
Examples include coconut fatty acid acyl-N-carboxymethyl-N-hydroxyethylethylenediamine sodium, N-coconut fatty acid acyl-N-carboxymethoxyethyl-N-carboxymethylethylenediamine disodium, and the like. Among these, betaine lauryl dimethylaminoacetate, betaine coconut alkyldimethylaminoacetate, betaine coconut fatty acid amidopropyldimethylaminoacetate, betaine laurate amidopropyldimethylaminoacetic acid betaine, N-coconut fatty acid acyl-N-carboxymethoxyethyl- N-carboxymethylethylenediamine disodium is particularly preferred.

In the present invention, one or two or more amphoteric surfactants of the component (C) can be appropriately selected and used alone or in combination.
%, More preferably 2 to 7%. If it is less than 1%, a sufficient amount of foam or a good feeling of smooth and creamy foam cannot be obtained, and if it is more than 10%, the viscosity of the system becomes too high, so that it can be used as a shampoo with appropriate viscosity. Is difficult to obtain.

The cationic polymer of the component (D) used in the present invention is a substance having good affinity and adsorptivity to hair. Has the effect of reducing the squeaky feeling of the hair and giving the hair a smooth feel. In the present invention, the cationic polymer of the component (D) is used in ordinary shampoos and is not particularly limited as long as it can impart a conditioning effect to hair, but may contain an amino group or an ammonium group bonded to a polymer chain. Or a water-soluble compound containing dimethyldiallylammonium halide as a structural unit. Specific examples include a cationized cellulose derivative, a cationized guar gum derivative, a diallyl quaternary ammonium salt / acrylamide copolymer, and the like. One or more of these may be appropriately selected or used in combination. it can.

In the present invention, the component (D) may be used alone or in combination of one or more kinds, and may be used alone or in combination. 0.1 to 2%. If it is less than 0.05%, the feeling of squeaking on the hair at the time of rinsing cannot be sufficiently reduced, and if it is more than 5%, a sufficient washing effect as a shampoo cannot be obtained.

The N-long-chain acyl acidic amino acid ester and / or cystine derivative of the component (E) used in the present invention serves as a conditioning component for hair in the present invention.

Among the components (E), the N-long-chain acyl acidic amino acid ester is an ester of a condensate of a higher fatty acid and an acidic amino acid with a compound having an alcoholic hydroxyl group, It is a compound having moisturizing properties. In the present invention, the N-long-chain acyl acidic amino acid ester has the effect of suppressing the squeaky feeling at the time of rinsing, making the washed hair moist and not sticky, and giving the finished hair a soft and supple texture.
The N-long-chain acyl acidic amino acid ester used as the component (E) is not particularly limited, and specifically, N-lauroyl-L-glutamic acid di (phytosteryl-2-octyldodecyl), N-lauroyl- L-glutamic acid di (cholesteryl behenyl octyldodecyl), N-lauroyl-L-glutamic acid di (cholesteryl octyldodecyl), N-lauroyl-L-glutamic acid di (phytosteryl behenyl-2-octyldodecyl), N-lauroyl -L-glutamic acid di (2
-Octyldodecyl) and the like.

Among the components (E), the cystine derivative is an amino acid constituting the hair or a compound similar thereto, and unlike cysteine, has no reducing power, and therefore has little damage to the hair. In addition, the cystine derivative has a high adsorptivity to hair, has an effect of repairing and smoothing a damaged site, and making hair healthy. In the present invention, the cystine derivative imparts flexibility to the hair, has the effect of eliminating stiffness from the washed hair and making the finished hair soft and supple. The cystine derivative used as the component (E) is not particularly limited, and specifically, cystine,
N, N'-diacetyl-L-cystine dimethyl ester, N, N'-diacetylcystine dimethyl and the like are exemplified.

The component (E) may be used alone or in combination of one or more kinds, and may be used alone or in combination.
1% to 2.5%. If less than 0.001%, a sufficient conditioning effect cannot be obtained, and 5%
If the amount is more than that, the hair may feel heavy and the finish may be adversely affected.

The shampoo composition of the present invention may further comprise, in addition to the above-mentioned essential components, an ionic interface other than the above-mentioned components (A) to (C) within a quantitative and qualitative range which does not impair the effects of the present invention depending on the purpose. Activators; nonionic surfactants such as fatty acid alkylolamides, polyalkylene glycol fatty acid esters and polyoxyalkylene alkyl ethers; viscosity or feel improvers such as water-soluble polymers and water-soluble polysaccharides; alkylene glycol fatty acid esters and the like Pearl agent; Lanolin,
Oily components such as hydrocarbons, oils and fats, silicone oils, and high molecular silicones; powders; ultraviolet absorbers; antioxidants;
Kayumi inhibitor; fungicide; preservative; chelating agent; electrolyte;
Other ingredients commonly used in shampoos, such as coloring agents, hair care cosmetic ingredients, and fragrances, can be added.

Representative cosmetic ingredients for hair care include plant extracts, proteins and derivatives thereof, peptides and derivatives thereof which can be used for hair care. Specific examples of the plant extract include Altea extract, Lily of the valley extract, Ginkgo biloba extract, Bodaiju extract, Seaweed extract, Assembly extract, Mukuroji extract, Touki extract, Chamomile extract, Peppermint extract, Hop extract And one or two or more of them can be used alone or in combination.

The shampoo composition of the present invention comprises the above essential components of tetradecenesulfonic acid salt, N-acylmethyltaurine salt, amphoteric surfactant, cationic polymer and N-long-chain acyl acidic amino acid ester and / or cystine. A specific amount of each derivative or the like can be stirred and mixed, and in some cases, can be produced by heating, cooling, or the like. The shampoo composition of the present invention is used in combination with other components, and has a low-viscosity to high-viscosity liquid, an emulsion, a cream, a gel, and the like.
It can be implemented in various forms. In addition, a mousse-shaped aerosol-type shampoo can also be obtained by using together with a propellant such as liquefied petroleum gas, dimethyl ether, carbon dioxide gas, and nitrogen gas, or by using a container mechanism.

[0021]

The present invention will be further described with reference to the following examples. These do not limit the present invention at all.

Examples 1 to 14 and Comparative Examples 1 to 12 Shampoo (Liquid) Liquid shampoos were prepared according to the compositions shown in Tables 1 and 2 and by the following method, and foaming during washing, foam feeling, washing effect, The feeling of the hair during rinsing, the feeling of the washed hair, and the usability were evaluated.

[0023]

[Table 1]

[0024]

[Table 2]

(Production method) A. The components (1) to (13) are uniformly heated and mixed at 70 ° C., and then cooled. B. Fill A into a container to obtain a shampoo.

(Evaluation Method) Evaluation by use test Examples 1 to 14 and Comparative Examples 1 to 1
2 each sample was used, foaming during washing, feeling of foam (smoothness, creamy feeling), washing effect, feeling of hair during rinsing (suppleness, lack of squeaky feeling), The feeling (suppleness, softness) and usability (ease of taking into the hand due to moderate viscosity, ease of use) were evaluated on a seven-point scale using the following absolute evaluation criteria. Further, the average value of the scores of each sample was obtained, and the evaluation was made using a four-step criterion. [Evaluation] 6 points: Very good 5 points: Good 4 points: Somewhat good 3 points: Normal 2 points: Somewhat poor 1 point: Poor 0 points: Very poor [Criterion] ◎: Average score of 5 points or more ○: Average point 4 points or more and less than 5 points Δ: Average point 2 points or more and less than 4 points ×: Average point less than 2 points The results obtained by the above evaluation and judgment methods are also shown in Tables 1 and 2.

As is clear from the results in Tables 1 and 2,
The shampoo composition of the present invention exhibits excellent effects in any of foaming during washing, foam feeling, washing effect, hair feeling during rinsing, hair feeling after washing, and usability. Was proved. On the other hand, Comparative Examples 1 to 12 did not satisfy all the items.

Example 15 Rinse-in shampoo A rinse-in shampoo was prepared by the following composition and manufacturing method. (Composition) (Component) (% by mass) (1) Sodium tetradecenesulfonate 10 (2) Betaine lauryldimethylaminoacetate 4 (3) Sodium coconut fatty acid methyltaurine 2 (4) Dimethyldiallylammonium chloride / acrylamide copolymer 1 (5) Stearyltrimethylammonium chloride 2 (6) L-cystine 1 (7) N-lauroyl-L-glutamic acid di (phytosteryl-2-octyldodecyl) 0.5 (8) Propylene glycol 1 (9) Polyethylene glycol Epichlorohydrin / coconut oil alkylamine / dipropylenetriamine condensate 1 (10) coconut oil fatty acid diethanolamide 3 (11) ethylene glycol distearate 2 (12) hydrolyzed collagen 0.2 (13) assembly extract 0.2 (14 ) Mukuroji extract 0.2 (15) Touki extract 0.2 (16) Isopropyl methylphenol 0.2 (17) Citric acid suitable amount (18) Disodium edetate proper amount (19) Preservative proper amount (20) Flavor proper amount (21) ) Remaining purified water

(Production method) The components (1) to (21) are uniformly heated and mixed at 70 ° C., and then cooled. B. Fill A into a container to obtain a rinse-in shampoo.

The rinse-in shampoo obtained as described above has good lathering during washing, has a good washing effect with a creamy lather, does not squeak during rinsing, and has a supple and soft shampoo, and is excellent as a shampoo. It was.

Example 16 Tonic shampoo A tonic shampoo was prepared according to the following composition and manufacturing method. (Composition) (Ingredient) (% by mass) (1) Sodium tetradecenesulfonate 10 (2) Sodium methyltaurine coconut oil fatty acid 3 (3) Betaine lauryldimethylaminoacetate 4 (4) Cationized guar gum (Note 2) 1 (5) N, N'-diacetyl-L-cystine dimethyl ester 0.5 (6) N-lauroyl-L-glutamic acid di (phytosteryl-2-octyldodecyl) 0.5 (7) L-menthol 0.8 (8) Palm oil fatty acid diethanolamide 2 (9) Highly polymerized polyethylene glycol (average molecular weight 2,000,000) (Note 3) 0.5 (10) 1,3-butylene glycol 2 (11) Urea 0.2 (12) Lactic acid Appropriate amount (13) Disodium edetate Appropriate amount (14) Preservatives Appropriate amount (15) Fragrance Appropriate amount (16) Purified water Remaining amount Note 2: JAGUA C-14S (manufactured by Rhone Poulenc) Note 3: Polyox WSR-N-60K (manufactured by Union Carbide Corp.)

(Production method) A. The components (1) to (16) are uniformly heated and mixed at 70 ° C., and then cooled. B. Fill A into a container to obtain a tonic shampoo.

The tonic shampoo obtained as described above is easy to pick up, has an excellent refreshing feeling, foams during washing,
The foam amount, foam feeling, washing effect, and feel during rinsing were all good, and the washed hair also showed a supple and excellent effect.

[0034]

As described in detail above, the shampoo composition of the present invention has good usability, provides good foaming and foaming feeling during washing, and a sufficient washing effect, and also has a hair rinsing property even when rinsed. It does not become supple and has excellent effects of imparting suppleness and softness to washed hair, and has excellent quality as a shampoo composition.

──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI theme coat ゛ (reference) C11D 3/37 C11D 3/37 3/384 3/384 F term (reference) 4C083 AA112 AC122 AC302 AC392 AC472 AC532 AC532 AC581 AC582 AC642 AC661 AC662 AC682 AC691 AC711 AC712 AC782 AC791 AC792 AD042 AD072 AD131 AD132 AD262 AD432 AD532 CC38 CC39 EE06 FF05 4H003 AB14 AB23 AB27 AB46 AD04 BA12 BA20 DA02 EB08 EB09 EB17 EB21 EB42 EB44 FA21 FA18 FA18 FA18

Claims (1)

[Claims]
1. The following components (A) to (E): (A) 1 to 15% by mass of a tetradecenesulfonic acid salt (B) 1 to 15% by mass of an N-acylmethyltaurine salt (C) Amphoteric surfactant 1 to 10% by mass (D) Cationic polymer 0.05 to 5% by mass (E) N-long-chain acyl acidic amino acid ester and / or cystine derivative 0.001 to 5% by mass Composition.
JP30672299A 1999-10-28 1999-10-28 Shampoo composition Pending JP2001122742A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30672299A JP2001122742A (en) 1999-10-28 1999-10-28 Shampoo composition

Publications (1)

Publication Number Publication Date
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Family Applications (1)

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Country Status (1)

Country Link
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002072040A1 (en) * 2001-03-13 2002-09-19 Ajinomoto Co., Inc. Comsetics or external preparaiotns for skin
JP2006077184A (en) * 2004-09-13 2006-03-23 Ajinomoto Co Inc Cleanser composition
WO2006030990A1 (en) * 2004-09-17 2006-03-23 Nof Corporation Detergent composition
JP2012102050A (en) * 2010-11-10 2012-05-31 Nof Corp Hair shampoo composition
JP2013544246A (en) * 2010-11-22 2013-12-12 ▲蘇▼州元素集▲化▼学工▲業▼有限公司Suzhou Eleco Chemical Industry Co., Ltd. Dense cleaning composition
JP2014091723A (en) * 2012-11-06 2014-05-19 Milbon Co Ltd Shampoo

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002072040A1 (en) * 2001-03-13 2002-09-19 Ajinomoto Co., Inc. Comsetics or external preparaiotns for skin
JP2006077184A (en) * 2004-09-13 2006-03-23 Ajinomoto Co Inc Cleanser composition
WO2006030881A1 (en) * 2004-09-13 2006-03-23 Ajinomoto Co., Inc. Detergent composition
US7867961B2 (en) 2004-09-13 2011-01-11 Ajinomoto Co., Inc. Wash composition
JP4696507B2 (en) * 2004-09-13 2011-06-08 味の素株式会社 Cleaning composition
WO2006030990A1 (en) * 2004-09-17 2006-03-23 Nof Corporation Detergent composition
JPWO2006030990A1 (en) * 2004-09-17 2008-05-15 日油株式会社 Cleaning composition
JP2012102050A (en) * 2010-11-10 2012-05-31 Nof Corp Hair shampoo composition
JP2013544246A (en) * 2010-11-22 2013-12-12 ▲蘇▼州元素集▲化▼学工▲業▼有限公司Suzhou Eleco Chemical Industry Co., Ltd. Dense cleaning composition
US9326928B2 (en) 2010-11-22 2016-05-03 Suzhou Eleco Chemical Industry CO., Ltd. Thick cleaning composition
JP2014091723A (en) * 2012-11-06 2014-05-19 Milbon Co Ltd Shampoo

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