CN102614096A - Conditioner shampoo composite - Google Patents
Conditioner shampoo composite Download PDFInfo
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- CN102614096A CN102614096A CN2012100572158A CN201210057215A CN102614096A CN 102614096 A CN102614096 A CN 102614096A CN 2012100572158 A CN2012100572158 A CN 2012100572158A CN 201210057215 A CN201210057215 A CN 201210057215A CN 102614096 A CN102614096 A CN 102614096A
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- ammonium salt
- conditioning shampoo
- shampoo composition
- polyquaternary ammonium
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Abstract
The invention relates to a conditioner shampoo composite, which comprises an anion surface active agent and a cation surface active agent and is characterized by further comprising polyquaternium 4. The mass percent ratio of the polyquaternium 4 is 0.01-2%. The nitrogen content of the polyquaternium 4 is 0.75-2.4%, and viscosity of 2% of mass concentration water solution of the polyquaternium 4 is 35-275 centipoises. The conditioner shampoo composite has good cleaning and furfur removal capacity and simultaneously keeps hair to be smooth and not greasy for a long time.
Description
Technical field
The present invention relates to the washing cosmetic technical field, particularly a kind of conditioning shampoo composition that is used to have one's hair wash.
Background technology
At present, the various combination shampoos that contain surfactant and hair conditioner on the market are numerous, and all there is sophisticated product in company both at home and abroad; This series products has good cleaning capacity and washes the back opsonizing capacity; Receive very much the favor of Chinese Consumer's, yet existing conditioner shampoo, conditioning can make also hair have greasy feeling very soon when being provided; Make the thick and heavy sense of hair increase, elegant sense weakens.At present; Also do not have a kind of conditioner shampoo of having one's hair wash that outstanding cleaning capacity and wet excellent sense can be provided when hair washing, after hair dryer, can make hair have slim and graceful, submissive, elegant sensation again; Simultaneously can keep the hair non-greasy, make hair submissive lastingly.
Summary of the invention
The technical problem that the present invention will solve is, a kind of have good cleaning power and anti-dandruff power are provided, and can keep that hair is submissive, the conditioning shampoo composition of non-greasy simultaneously for a long time.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of conditioning shampoo composition, comprise anion surfactant, cationic surfactant, and it is characterized in that: comprise that also mass percent is 0.01%～2% polyquaternary ammonium salt 4.
Further, the nitrogen content of this polyquaternary ammonium salt 4 is 0.75%～2.4% (mass percent), and the 2% mass concentration aqueous solution viscosity at normal temperatures of this polyquaternary ammonium salt 4 is 35 centipoises～275 centipoises.
As preferably, the mass percent that said polyquaternary ammonium salt 4 accounts for compositions is 0.02%～1%.Polyquaternary ammonium salt 4 is copolymers of hydroxyethyl-cellulose and dimethyl-dipropenyl ammonium chloride; Its charge density is higher; When hair surface existed, the film of formation was extremely thin and diopter is high, separately or with the composite use of other cationic surfactants the time; Can make hair very soft, smooth, can bring good conditioning property and outstanding slim and graceful sense.
Said anion surfactant is selected from sodium lauryl sulfate, sodium laureth sulfate, lauryl alcohol sulfuric ester ammonium, laureth sulfuric ester ammonium and their mixture, and above-mentioned anion surfactant can be selected a use, also can mix use.The total amount of anion surfactant generally is 4%～35% of a shampoo composite gross mass, and the present invention is preferably 10%～17%.Such ratio is used with 0.02%～1% polyquaternary ammonium salt 4, and not only clean result is good, and it is too dry to be unlikely to hair after the hair washing, and low-consuming.Other anion surfactants that are fit to also have alkyl sulfate, alkyl ether sulfate, alkylsulfonate, alkyl sarcosine salt, alkyltaurate, alkyl succinate, alkyl-glutamic acid salt etc.
Said cationic surfactant is selected from two h-tallow carboxyethyl double hydroxyethyl methylsulfuric acid ammonium methyls, two palmityl ethyl alkyl dimethyl ammonium chlorides, palmitamide oxypropyl trimethyl ammonification ammonium, the inferior oil base ammonium chloride of dihydroxypropyl PEG-5, three-cetyl ammonio methacrylate, hexadecyltrimethylammonium chloride, INCROQUAT TMC-80 ECONOL TM22, quaternary ammonium salt 82, lauryl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein or their mixture; Above-mentioned cationic surfactant can be selected a use, also can mix use.Cationic surfactant is generally 0.001%～2% of shampoo composite gross mass; The present invention is preferably 0.001%～0.6%; Preferred cationic surfactants of the present invention can improve conditioning ingredients and on hair, flocculate; Stronger antistatic effect is arranged, can bring the good conditioning effect.
This compositions also includes one of polyquaternary ammonium salt 10, guar hydroxypropyltrimonium chloride, polyquaternary ammonium salt 7, polyquaternary ammonium salt 47, polyquaternary ammonium salt 39, polyquaternary ammonium salt 43 or their mixture; The mass percent of above-mentioned cationic polymer can be 0.01～5%, and the present invention is preferably 0.01～0.6%.
This compositions also includes one of polydimethylsiloxane, dimethiconol, amino end group polydimethylsiloxane or their mixture, and above-mentioned polysiloxanes has insoluble, and it is dispersed in the compositions, has certain particle diameter.The quality of above-mentioned polysiloxanes can account for 0.01～10% of compositions gross mass, and the present invention is preferably 0.5%～5%.
This compositions also includes one of pyrrole sulfur zinc, piroctone olamine salt, climbazole or their mixture, and the content of above-mentioned anti-dandruff composition generally accounts for composition quality percentage ratio 0.1%～2%, and these anti-dandruff compositions can help user to remove the dandruff.
The present invention can also comprise zwitterionic surfactant, like dodecanamide propyl betanin, cocamido propyl betaine, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium, lauryl hydroxyl sulfo betaine or their mixture.
The present invention can also comprise non-ionic surface active agent: like coconut monoethanol amide, cocos nucifera oil diglycollic amide, fatty alcohol ether, alkyl polyglucoside and composition thereof.
The present invention can also comprise higher alcohols such as spermol, stearyl alcohol.
The present invention can also comprise pearling agents such as glycol distearate, ethylene glycol monostearate.
The present invention can also comprise suspending agents such as carbomer, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer, acrylic acid (ester) analog copolymer, xanthan gum.
The present invention can also comprise pH regulator agent such as citric acid, sodium citrate, phosphoric acid, hydrochloric acid, sodium hydroxide, potassium hydroxide.
The present invention can also comprise known composition commonly used in the existing shampoo, like sunscreen, oils and fats, antiseptic, coloring agent, polyhydric alcohol, chelating agen, antioxidant, thickening agent, essence etc.The percentage composition of related material among the present invention under the situation of specified otherwise not, is mass percent.
The inventor is through theory analysis and a large amount of experiments; Select an amount of polyquaternary ammonium salt 4 and suitable anion surfactant, cationic surfactant to arrange in pairs or groups; Prepare and both have good cleaning power and anti-dandruff power, can keep that hair is submissive, the conditioning shampoo composition of non-greasy simultaneously again for a long time.The present invention tries out through the target customer; Wherein 85% target customer thinks stronger than anti-dandruff ability of other hair shampoo articles and cleaning capacity; 80% client can keep soft, suitable sliding, the non-greasy of hair in 3 days after hair washing, more lasting than similar other hair washing product effects.
The specific embodiment
Embodiment 1:
A kind of conditioning shampoo composition comprises following component:
5% sodium laureth sulfate
5% sodium lauryl sulfate
1.2% cocos nucifera oil acyl both sexes guanidine-acetic acid sodium
0.88% coconut oleoyl amine MEA
1.8% glycol monomethyl distearate
0.01% polyquaternary ammonium salt 4
0.2% polyquaternary ammonium salt 10
0.2% polyquaternary ammonium salt 7
0.2% guar hydroxypropyltrimonium chloride
0.2% pair of h-tallow carboxyethyl double hydroxyethyl methylsulfuric acid ammonium methyl
0.5% polydimethylsiloxane
0.2% cetearyl alcohol
0.1% pyrrole sulfur zinc
0.4% citric acid
0.1% sodium citrate
1% sodium xylene sulfonate
1% sodium chloride
0.08% antiseptic
0.8% essence
Surplus is a water.The listed percentage ratio of present embodiment is mass percent.
The present invention is through following prepared:
Earlier cationic polymer polyquaternary ammonium salt 4, polyquaternary ammonium salt 10, guar hydroxypropyltrimonium chloride are carried out pretreatment, be dispersed in the water, it is subsequent use to form cationic polymer solution;
The water of remainder is added in the emulsifying pot of band heat exchange, add anion surfactant sodium laureth sulfate, sodium lauryl sulfate, sodium xylene sulfonate, be heated to 70 ℃ to 80 ℃; Add ethylene glycol bisthioglycolate stearyl ester, cetearyl alcohol, coconut monoethanol amide, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium etc. again after the dissolving fully; Make fully and disperse, add scattered cationic polymer solution, the two h-tallow carboxyethyl double hydroxyethyl methylsulfuric acid ammonium methyls of cationic surfactant, after disperseing fully; Be cooled to 30 ℃ to about 40 ℃; Stirring condition adds polydimethylsiloxane, pyrrole sulfur zinc, polyquaternary ammonium salt 7, antiseptic, essence down, behind the mix homogeneously, adds other compositions such as sodium chloride, citric acid, sodium citrate again; Fully stir and obtain uniform mixture, taking the dish out of the pot both gets conditioning shampoo composition.
Embodiment 2:
A kind of conditioning shampoo composition comprises following component:
10% laureth sulfuric ester ammonium
3% lauryl alcohol sulfuric ester ammonium
0.6% dodecanamide propyl betanin
0.88% coconut oleoyl amine MEA
1.5% glycol distearate
0.5% polyquaternary ammonium salt 4
0.2% polyquaternary ammonium salt 10
0.4% polyquaternary ammonium salt 47
0.2% quaternary ammonium salt 82
1.5% polydimethylsiloxane
0.5% cetearyl alcohol
0.5% pyrrole sulfur zinc
0.1% piroctone olamine salt
0.04% citric acid
0.1% sodium citrate
1% ammonium xylene sulfonate
1% sodium chloride
0.08% antiseptic
0.8% essence
Surplus is a water.The listed percentage ratio of present embodiment is mass percent.
The present invention is through following prepared:
Earlier cationic polymer polyquaternary ammonium salt 4, polyquaternary ammonium salt 10 are carried out pretreatment, be dispersed in the water, it is subsequent use to form cationic polymer solution;
The water of remainder is added in the emulsifying pot of band heat exchange, add anion surfactant laureth ammonium sulfate, lauryl alcohol sulfuric ester ammonium, ammonium xylene sulfonate, be heated to 70 ℃ to 80 ℃; Add ethylene glycol bisthioglycolate stearyl ester, cetearyl alcohol, coconut monoethanol amide, dodecanamide propyl betanin etc. again after the dissolving fully; Make fully and disperse, add scattered cationic polymer solution, cationic surfactant quaternary ammonium salt 82, after disperseing fully; Be cooled to 30 ℃ to about 40 ℃; Stirring condition adds polydimethylsiloxane, pyrrole sulfur zinc, quaternary ammonium salt 47, antiseptic, essence down, behind the mix homogeneously, adds other compositions such as sodium chloride, citric acid, sodium citrate again; Fully stir and obtain uniform mixture, taking the dish out of the pot both gets conditioning shampoo composition.
Embodiment 3:
A kind of conditioning shampoo composition comprises following component:
10% laureth sulfuric ester ammonium
7% lauryl alcohol sulfuric ester ammonium
0.6% dodecanamide propyl betanin
0.5% coconut oleoyl amine MEA
1.5% glycol distearate
1.0% polyquaternary ammonium salt 4
0.1% guar hydroxypropyltrimonium chloride
0.2% 3-cetyl ammonio methacrylate
0.1% lauryl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein
2.5% polydimethylsiloxane
0.5% cetearyl alcohol
1.0% pyrrole sulfur zinc
0.1% climbazole
0.04% citric acid
0.1% sodium citrate
1% ammonium xylene sulfonate
1% sodium chloride
0.08% antiseptic
0.8% essence
Surplus is a water.The listed percentage ratio of present embodiment is mass percent.
The present invention is through following prepared:
Earlier cationic polymer polyquaternary ammonium salt 4, melon glue hydroxypropyl ammonium chloride are carried out pretreatment, be dispersed in the water, it is subsequent use to form cationic polymer solution;
The water of remainder is added in the emulsifying pot of band heat exchange, add anion surfactant laureth ammonium sulfate, lauryl alcohol sulfuric ester ammonium, ammonium xylene sulfonate, be heated to 70 ℃ to 80 ℃; Add ethylene glycol bisthioglycolate stearyl ester, cetearyl alcohol, coconut monoethanol amide, dodecanamide propyl betanin etc. again after the dissolving fully; Make fully and disperse, add scattered cationic polymer solution, cationic surfactant three-cetyl ammonio methacrylate, after disperseing fully; Be cooled to 30 ℃ to about 40 ℃; Stirring condition adds polydimethylsiloxane, pyrrole sulfur zinc, lauryl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein, antiseptic, essence down, behind the mix homogeneously, adds other compositions such as sodium chloride, citric acid, sodium citrate again; Fully stir and obtain uniform mixture, taking the dish out of the pot both gets conditioning shampoo composition.
Claims (8)
1. a conditioning shampoo composition comprises anion surfactant, cationic surfactant, it is characterized in that: comprise that also mass percent is 0.01%～2% polyquaternary ammonium salt 4.
2. conditioning shampoo composition according to claim 1 is characterized in that: the nitrogen content of said polyquaternary ammonium salt 4 is 0.75%～2.4%, and the 2% mass concentration aqueous solution viscosity at normal temperatures of this polyquaternary ammonium salt 4 is 35 centipoises～275 centipoises.
3. conditioning shampoo composition according to claim 1 and 2 is characterized in that: the mass percent that said polyquaternary ammonium salt 4 accounts for compositions is 0.02%～1%.
4. conditioning shampoo composition according to claim 1 and 2 is characterized in that: said anion surfactant is selected from one of sodium lauryl sulfate, sodium laureth sulfate, lauryl alcohol sulfuric ester ammonium, laureth sulfuric ester ammonium or their mixture.
5. conditioning shampoo composition according to claim 1 and 2 is characterized in that: said cationic surfactant is selected from one of two h-tallow carboxyethyl double hydroxyethyl methylsulfuric acid ammonium methyls, two palmityl ethyl alkyl dimethyl ammonium chlorides, palmitamide oxypropyl trimethyl ammonium chloride, the inferior oil base ammonium chloride of dihydroxypropyl PEG-5, three-cetyl ammonio methacrylate, hexadecyltrimethylammonium chloride, INCROQUAT TMC-80 ECONOL TM22, quaternary ammonium salt 82, lauryl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein or their mixture.
6. conditioning shampoo composition according to claim 1 is characterized in that: said composition also includes one of polyquaternary ammonium salt 10, guar hydroxypropyltrimonium chloride, polyquaternary ammonium salt 7, polyquaternary ammonium salt 47, polyquaternary ammonium salt 39, polyquaternary ammonium salt 43 or their mixture.
7. conditioning shampoo composition according to claim 1 is characterized in that: said composition also includes one of polydimethylsiloxane, dimethiconol, amino end group polydimethylsiloxane or their mixture.
8. conditioning shampoo composition according to claim 1 is characterized in that: said composition also includes one of pyrrole sulfur zinc, piroctone olamine salt, climbazole or their mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100572158A CN102614096A (en) | 2012-03-05 | 2012-03-05 | Conditioner shampoo composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100572158A CN102614096A (en) | 2012-03-05 | 2012-03-05 | Conditioner shampoo composite |
Publications (1)
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|---|---|
| CN102614096A true CN102614096A (en) | 2012-08-01 |
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Family Applications (1)
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| CN2012100572158A Pending CN102614096A (en) | 2012-03-05 | 2012-03-05 | Conditioner shampoo composite |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104940071A (en) * | 2015-06-25 | 2015-09-30 | 广州保税区雅兰国际化妆品有限公司 | Mild antidandruff shampoo and preparation method thereof |
| CN106860053A (en) * | 2015-09-23 | 2017-06-20 | 株式会社爱茉莉太平洋 | Hair hair composition |
| CN106974839A (en) * | 2015-09-23 | 2017-07-25 | 株式会社爱茉莉太平洋 | Hair hair composition |
| CN107669541A (en) * | 2017-09-30 | 2018-02-09 | 朱耀灯 | A kind of net profit anti-dandruff shampoo |
| CN108272663A (en) * | 2018-04-13 | 2018-07-13 | 广东御之叶科技有限公司 | Hair care conditioning shampoo and preparation method thereof |
| CN108619053A (en) * | 2018-06-20 | 2018-10-09 | 广州市惠芳日化有限公司 | Desquamation compositions, leaves shampoo and preparation method thereof |
| CN108785198A (en) * | 2018-06-20 | 2018-11-13 | 广州市惠芳日化有限公司 | Strengthen the hair composition, leaves shampoo and preparation method thereof |
| WO2018205258A1 (en) * | 2017-05-12 | 2018-11-15 | Beiersdorf Ag | Hair styling composition comprising polyquaternium-4, polyquaternium-37 and c12-15 alkyl benzoate |
| CN108815067A (en) * | 2018-06-20 | 2018-11-16 | 广州市惠芳日化有限公司 | Hair nourishing composition, leaves shampoo and preparation method thereof |
| CN109125098A (en) * | 2018-07-10 | 2019-01-04 | 广州温雅日用化妆品有限公司 | A kind of bubble formulation conditioner and its preparation and application |
| CN109589294A (en) * | 2019-01-31 | 2019-04-09 | 浙江树人学院（浙江树人大学） | A method of with rice milk and rice wine production shampoo |
| CN111182885A (en) * | 2017-10-31 | 2020-05-19 | 株式会社爱茉莉太平洋 | Dust control composition |
| CN111743806A (en) * | 2020-08-01 | 2020-10-09 | 广州市舒悦化妆品有限公司 | Gemini process mild nourishing and softening shampoo and preparation method thereof |
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| CN102327202A (en) * | 2011-07-25 | 2012-01-25 | 广东拉芳日化有限公司 | Conditioner shampoo without silicone oil |
| WO2012016943A2 (en) * | 2010-08-05 | 2012-02-09 | Kpss-Kao Professional Salon Services Gmbh | Conditioning composition for hair |
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| CN1353976A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Chinese herbal medicine dandruff-removing shampoo |
| CN1798541A (en) * | 2003-05-29 | 2006-07-05 | 高露洁-棕榄公司 | Transparent conditioning shampoo |
| WO2012016943A2 (en) * | 2010-08-05 | 2012-02-09 | Kpss-Kao Professional Salon Services Gmbh | Conditioning composition for hair |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104940071A (en) * | 2015-06-25 | 2015-09-30 | 广州保税区雅兰国际化妆品有限公司 | Mild antidandruff shampoo and preparation method thereof |
| CN106860053A (en) * | 2015-09-23 | 2017-06-20 | 株式会社爱茉莉太平洋 | Hair hair composition |
| CN106974839A (en) * | 2015-09-23 | 2017-07-25 | 株式会社爱茉莉太平洋 | Hair hair composition |
| CN106860053B (en) * | 2015-09-23 | 2021-08-13 | 株式会社爱茉莉太平洋 | Hair composition |
| CN106974839B (en) * | 2015-09-23 | 2021-08-17 | 株式会社爱茉莉太平洋 | Hair composition |
| WO2018205258A1 (en) * | 2017-05-12 | 2018-11-15 | Beiersdorf Ag | Hair styling composition comprising polyquaternium-4, polyquaternium-37 and c12-15 alkyl benzoate |
| CN107669541A (en) * | 2017-09-30 | 2018-02-09 | 朱耀灯 | A kind of net profit anti-dandruff shampoo |
| TWI803531B (en) * | 2017-10-31 | 2023-06-01 | 南韓商愛茉莉太平洋股份有限公司 | Composition for anti-fine dust |
| CN111182885A (en) * | 2017-10-31 | 2020-05-19 | 株式会社爱茉莉太平洋 | Dust control composition |
| CN108272663A (en) * | 2018-04-13 | 2018-07-13 | 广东御之叶科技有限公司 | Hair care conditioning shampoo and preparation method thereof |
| CN108815067A (en) * | 2018-06-20 | 2018-11-16 | 广州市惠芳日化有限公司 | Hair nourishing composition, leaves shampoo and preparation method thereof |
| CN108785198A (en) * | 2018-06-20 | 2018-11-13 | 广州市惠芳日化有限公司 | Strengthen the hair composition, leaves shampoo and preparation method thereof |
| CN108619053A (en) * | 2018-06-20 | 2018-10-09 | 广州市惠芳日化有限公司 | Desquamation compositions, leaves shampoo and preparation method thereof |
| CN108815067B (en) * | 2018-06-20 | 2021-04-23 | 广州市惠芳日化有限公司 | Hair nourishing composition, hair washing cream and preparation method thereof |
| CN108785198B (en) * | 2018-06-20 | 2021-04-23 | 广州市惠芳日化有限公司 | Hair-strengthening composition, shampoo and preparation method thereof |
| CN109125098B (en) * | 2018-07-10 | 2021-07-13 | 广州温雅日用化妆品有限公司 | Bubble-formulation hair-moistening agent and preparation and use methods thereof |
| CN109125098A (en) * | 2018-07-10 | 2019-01-04 | 广州温雅日用化妆品有限公司 | A kind of bubble formulation conditioner and its preparation and application |
| CN109589294A (en) * | 2019-01-31 | 2019-04-09 | 浙江树人学院（浙江树人大学） | A method of with rice milk and rice wine production shampoo |
| CN109589294B (en) * | 2019-01-31 | 2021-09-24 | 浙江树人学院（浙江树人大学） | Method for producing shampoo by rice milk water and yellow wine |
| CN111743806A (en) * | 2020-08-01 | 2020-10-09 | 广州市舒悦化妆品有限公司 | Gemini process mild nourishing and softening shampoo and preparation method thereof |
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Address after: Hangzhou City, Zhejiang province 310012 Xihu District World Trade Center Building 1, and Richland city (area D) room 1605 Applicant after: Proya Cosmetics Co., Ltd. Address before: 313023 No. 16, National Road, Huzhou Industrial Park, Zhejiang Province Applicant before: proya (Huzhou) Cosmetics Co., Ltd. |
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Application publication date: 20120801 |