CN104274358B - A kind of scalp maintenance type hair-washing composition and preparation method containing plants essential oil - Google Patents
A kind of scalp maintenance type hair-washing composition and preparation method containing plants essential oil Download PDFInfo
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- CN104274358B CN104274358B CN201410452538.6A CN201410452538A CN104274358B CN 104274358 B CN104274358 B CN 104274358B CN 201410452538 A CN201410452538 A CN 201410452538A CN 104274358 B CN104274358 B CN 104274358B
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Abstract
The present invention relates to a kind of plants essential oil scalp maintenance hair-washing composition and preparation method, the present composition contains in addition to cosmetically acceptable carrier：(A) lauryl sulfate of composition weight 4% to 40% and the composition of ethoxylated dodecyl alcohol ammonium sulfate are accounted for；(B) the APG type nonionic surfactant of composition weight 0.5% to 15% is accounted for；(C) Cocoamidopropyl betaine of composition weight 0.5% to 10% is accounted for；(D) the cationic quaternary ammonium salt form emulsifying agent of composition weight 0.05% to 8.%, dioctadecyl dimethyl ammonium chloride are accounted for；(E) cationic polymer of composition weight 0.05% to 3.0%, guar hydroxypropyltrimonium ammonium chloride are accounted for；(F) plants essential oil of composition weight 0.07625% to 31.2% is accounted for.The present composition plays mitigation scalp itch, conditioning hair and the effect for improving hair gloss by adjusting and recovering the health of scalp.
Description
Technical field
The invention belongs to household chemicals field, a kind of senior hair-washing composition containing plants essential oil and preparation side are specifically related to
Method.
Background technology
Shampoo should play a part of cleaning scalp and hair simultaneously, and safe and effective to user.However, one
Since straight, either shampoo product or various hair care category products, what no matter people paid close attention to from technology or the market level
Nursing such as hair of the focus always in the dry part of hair is submissive, hair gloss, hair jag etc., and more ignores hair
Basis-the scalp depended on for existence, substantial amounts of technical research shows, " ecological balance " of scalp, " microenvironment balance ", scalp
" stratum corneum barrier function " etc. is all healthy closely bound up with scalp, because only that scalp health, hair just can strong, hair
(hair) just can be more glossy.
But reality is, no matter from market or from technological layer, people pay close attention to always hair outward appearance, it is submissive and dry/
Wet logic, is formulated engineers in the technological means used in terms of meeting these requirements in addition to surfactant system,
It is unable to do without the reasonably combined of silicone oil and cationic polymer and is achieved.
With the continuous improvement of people's living standard, people are more and more vigorous to the high level need of hair washing, and this is main anti-
Reflect and incremental consumption is presented year after year in hair washing market of the Chinese personal-care supplies market by representative of daily use chemicals specialty line channel becomes
Gesture.Hair washing product especially using scalp care as attractable point is ready to appear, becomes focus of concern.Especially market is needed
Traditional shampoo technology can be changed by wanting one kind, especially in recent years from declaring silicate-containing oil shampoo to declaring not containing silicone oil
Shampoo be transformed into the topic increasingly paid close attention to for industry and consumer.
Silicone oil is as a kind of important hair conditioner in shampoo, and itself is a kind of intimate chemical inertness, surface
Power is extremely low, and film forming is good, the characteristics of especially hair conditioning is good, and it is that 2-in-1 1 shampoo of P＆G enters China and big earliest that this, which is also,
The technology magic weapon succeeded, the hair that preceding silicone oil is brought from being described herein with " revolutionary character " twenties years washes shield technology
Change, while with " draw virtue " the win beneficiary for being also this technological change and strong evidence for the national enterprise of representative,
Because it was once to sign strategic partner with global maximum organosilicon manufacturer's DOW CORNING (DOW-CORNING) earliest in the industry to draw virtue
Local enterprise.
Although the shampoo technology and product that do not contain silicone oil are market focus of attention, the current hair washing containing silicone oil
The main flow in water still market.The shampoo that not silicate-containing oil is solved in shampoo formula and technology is still industry new raw material and new
The technical barrier captured needed for formula.Or the shampoo for solving not silicate-containing oil conditioner first passes through the substitute solution of silicone oil
Certainly, or being solved by the angle of scalp care, find that the latter is good for by nursing one's health scalp, concern scalp by substantial amounts of research
The technical thought of health is to solve the key technology without silicone oil shampoo.
The technology of the present invention finds that the shampoo for not containing silicone oil conditioner obtains preferable conditioning by substantial amounts of experiment
Property, first have to start with from scalp maintenance to consider scalp and hair conditioning, both are indispensable.Correct leatherware has the thing of maintenance
Matter should have physiologically active, correct leatherware Wheat Protein, to scalp approximate such as with the chemical composition of scalp sebum first
With antiallergy, anti-inflammatory effect etc..Present invention discover that from the vegetable oil of nut fruits and from natural fragrant plant
Simultaneously technique makes and is applied to that in hair washing aqueous systems the effect of scalp and hair maintenance and conditioning can be obtained essential oil scientific matching,
Trigger potential side effect from largely compensate for silicone oil long time sedimentation that may be present or covering on scalp and hair
Hair is such as set to produce a kind of defect of not well sense of heaviness.
The exploitation for washing shield product without silicone oil should not be only merely to take away silicone oil, if simply taking away silicone oil,
Publicity is just probably I guess propagandized without silicone oil concept while reducing product cost.It is therefore proposed that (1) is while silicone oil is taken away, use
Relatively mild surfactant moieties substitute traditional sulfate (AES) class surfactant completely, it is therefore an objective to which improvement is washed
The overall mildness of shampoo, reduces excitant of the cleansing to scalp.(2) silicone oil substitute is used, using a kind of to scalp
Liposoluble substance with physiological action is nourished scalp and recovers the healthy barrier of scalp, so as to realize that scalp maintenance is flat
Weighing apparatus.(3) adding the beneficial functional component of some moods to scalp and people, (such as anti-inflammatory component, antipruritic composition, emotion perfume atmosphere is releived
Composition etc.) to reaching the scalp care effect prevented trouble before it happens.
The content of the invention
It is an object of the invention to provide a kind of senior hair-washing composition of scalp maintenance type containing plants essential oil, the present invention with
Plants essential oil replaces the senior hair-washing composition of traditional silicone oil, and the senior hair washing to scalp and hair with physiologically active is combined
Thing, the hair-washing composition plays mitigation scalp itch by adjusting and recovering the health of scalp, and conditioning hair simultaneously improves hair light
The effect of damp degree.
It is a further object of the present invention to provide the preparation method of the senior hair-washing composition of maintenance type.
The object of the present invention is achieved like this：
A kind of plants essential oil scalp maintenance hair-washing composition, in addition to cosmetically acceptable carrier, contains：
(A) lauryl sulfate of composition weight 4.0% to 40% and the group of ethoxylated dodecyl alcohol ammonium sulfate are accounted for
Compound；
(B) the APG type nonionic surfactant of composition weight 0.5% to 15.0% is accounted for；
(C) Cocoamidopropyl betaine of composition weight 0.5% to 10.0% is accounted for；
(D) dioctadecyl dimethyl ammonium chloride of composition weight 0.05% to 8.0% is accounted for；
(E) the guar hydroxypropyltrimonium ammonium chloride of composition weight 0.05% to 3.0% is accounted for；
(F) plants essential oil of composition weight percentage 0.07625% to 31.2% is accounted for：
The plants essential oil is made up of vegetable oil and aromatic essential oil, wherein：
Vegetable oil is Sweet Almond Oil, aloe, avocado oil, Ah's glycerine, evening primrose oil, grape-kernel oil, jojoba oil, Australia
One or more in macadamia nut oil, olive oil, walnut oil, wheat-germ oil；
Aromatic essential oil is the stacked heath eggplant essential oil of squama (Fabiana imbricate), chamomile essential oil, lavender essence
Oil, lemon, Rosa Damascana, handkerchief Yago Lamela (Paramela) essential oil, Peppermint essential oil, Rosemary Oil, tea oil, Yilan essence
One or more in oil, clove oil, sweet orange oil, Geranium Essential.
Plants essential oil is preferably macadimia nut oil, jojoba oil, the stacked heath eggplant essential oil of squama, Geranium Essential in the present invention
Mixture, and this four kinds oily weight ratios are 100：50：3：0.5：
Wherein：It is 0.05% to 20% that macadimia nut oil, which accounts for composition weight ratio,；
It is 0.025% to 10% that jojoba oil, which accounts for composition weight ratio,；
It is 0.0015% to 1.0% that the stacked heath eggplant essential oil of squama, which accounts for composition weight ratio,；
It is 0.00025% to 0.2% that Geranium Essential, which accounts for composition weight ratio,.
Hair-washing composition of the present invention, wherein：The stacked heath eggplant essential oil of squama is a kind of eggplant of Argentinian Patagonia growth
Section plant, extracts from leaf petal, and density is 0.886 at 20 DEG C, and refraction index is 1.745 at 20 DEG C, and terpenoid substance contains
50%-80% is measured, terpenoid substance is wherein：Lemongrass alcohol content 31.7%, citronellyl formate content 12.8%, spiceleaf alcohol content
9.8%.
Hair-washing composition of the present invention, wherein：Jojoba oil squeezes gained, content of fatty acid by the kernel of Jojoba tree
99%, wherein, palmitic acid (C16:0) content 2%, oleic acid (C18:1) content 13%, erucic acid (C22：1) content 13%, peanut one
Olefin(e) acid (C20:1) content 71%, acid number 0.5-1, iodine number 80-85, saponification number 88-96, proportion are 0.86-0.87 at 25 DEG C,
Shading rate is 1.45-1.46 at 40 DEG C.
Hair-washing composition of the present invention, wherein, macadimia nut oil is by being derived from Queensland nut Macadamiatetraphyla
Core, content of fatty acid 95%, wherein, palmitic acid (C16:0) content 9%, stearic acid (C18：0) content 4%, oleic acid (C18:1)
Content 60%, linoleic acid (C18：2) content 2%, palm monoenoic acid (C16：1) content 20%, proportion 0.9218, flash-point ＞ 500
DEG C, 500 DEG C of boiling point ＞,
Hair-washing composition of the present invention, wherein：The Madagascar growing plants that Geranium Essential extracts from Africa is fragrant
Leaf fish pelargonium is spent and got, and its taste is somewhat as rose, with respect to proportion 0.9620-0.9720 (D20/4), shading rate
100 DEG C of 1.4370-1.4400 (n20/D), flash-point ＞.
Hair-washing composition of the present invention, wherein vegetable oil are macadimia nut oil, jojoba oil, the stacked heath eggplant essential oil of squama, day
Zhu Kui essential oils；It is 0.05% to 0.5% that macadimia nut oil, which accounts for composition weight ratio,；Jojoba oil accounts for composition weight ratio
0.025% to 0.25%；It is 0.01% to 0.1% that the stacked heath eggplant essential oil of squama, which accounts for composition weight ratio,；Geranium Essential accounts for group
Polymer weight ratio is 0.0025% to 0.025%, and its weight ratio is 2:1:0.4:0.1.
The present invention does not contain mineral oil and silicone oil composition.
The hair-washing composition of the present invention, wherein：Lauryl sulfate and ethoxylated dodecyl alcohol ammonium sulfate account for composition
Weight 8.0% to 16%；Alkyl-glucoside nonionic surfactant accounts for composition weight 1.0% to 10.0%；Cocounut oil acyl
Amine CAB accounts for composition weight 0.5% to 6.0%；Dioctadecyl dimethyl ammonium chloride account for composition weight 1% to
5%；Guar hydroxypropyltrimonium ammonium chloride accounts for composition weight 0.1% to 0.5%；Plants essential oil accounts for composition weight percentage
Than 0.0875% to 0.875%.
In hair-washing composition of the present invention, alkyl-glucoside nonionic surfactant is that C8-14 alkyl-glucosides are non-
Ionic surface active agent.
The hair-washing composition of the present invention, also comprising the glycerine for accounting for composition weight 0.5% to 6.0%；Comprising accounting for composition
The hexadecanol of weight 0.5% to 1.5%；Also comprising the Vitwas E for accounting for composition weight 0.1% to 1.0%.
Hair-washing composition of the present invention, its preferred ingredient and weight percent content are：
(O) deionized water of appropriate preservative, pigment, pH adjusting agent, salt and essence and surplus.
The preparation method of hair-washing composition of the present invention, is carried out according to the following steps：
(1) plants essential oil emulsion is pre-prepared：
(1) oil phase composition：The hexadecanol that will be accounted in hair-washing composition, macadimia nut oil, jojoba oil, vitamin E acetic acid
Ester is added in oil phase reactor, is heated while stirring, and temperature control is at 72 DEG C；
(2) aqueous phase composition：The deionized water of the above-mentioned oil phase Ingredient Wt of 5 times of weight is taken, present invention hair washing combination is added
Thing dioctadecyl dimethyl ammonium chloride, heats and is uniformly dispersed, and temperature control is at 78 DEG C；
(3) oil phase composition is added to aqueous phase composition, with 3000 revs/min, stirs 2-4 minutes, cool afterwards,
(4) the stacked heath eggplant essential oil of squama and Geranium Essential are added when temperature is reduced to 40 DEG C, continues to stir and cool to
It is 35-38 DEG C, closed to preserve, it is standby；
(2) preparation of hair-washing composition：
(1) by the disodium ethylene diamine tetraacetate in hair-washing composition, glycerine, suspending agent phthalic acid amide (TAB-2)
It is added separately in deionized water, stirs, disperse or dissolve；
(2) add guar hydroxypropyltrimonium ammonium chloride and heating stirring is until dissolving, temperature control is at 80 DEG C, then
It is separately added into lauryl sulfate, ethoxylated dodecyl alcohol ammonium sulfate, Cocoamidopropyl betaine, C8-14 alkyl grapes
Glucosides；Dioctadecyl dimethyl ammonium chloride, pearling agent, the temperature for stirring and being kept for 80 DEG C dissolves back until whole dissolvings
Side cooling is stirred,
(3) preservative, pigment, salt and essence are added when cooling to 50 DEG C and spending, continues to cool to 40 DEG C, and by pH value
It is adjusted to 6.5, it is standby；
(3) plants essential oil emulsion prepared by step (1) is slowly added into 40 DEG C of hair washing group of step (2) preparation
In the system of compound, stir 30 minutes, speed control is in 40 revs/min, 38 DEG C of dischargings.
Compared with prior art, the present invention has advantages below：
Present invention employs the vegetable oil to scalp and hair with physiologically active and the active component of aromatic essential oil,
The science collocation of vegetable oil and aromatic essential oil and manufacture craft not only play physiology to scalp and hair and nourished and maintenance
Effect, and mitigation scalp itch is played by adjusting and recovering the physiological health of scalp, improve hair conditioning and increase hair
The effect of glossiness.
Specific embodiment
Invention is described in detail with reference to embodiment.
It is a kind of with plant essence present invention relates particularly to a kind of senior hair-washing composition of scalp maintenance type containing plants essential oil
Oil replaces the senior hair-washing composition of traditional silicone oil, a kind of senior hair-washing composition to scalp and hair with physiologically active,
The hair-washing composition plays mitigation scalp itch by adjusting and recovering the health of scalp, and conditioning hair simultaneously improves hair gloss
Effect.
Silicone oil substitute of the present invention be plants essential oil, the present invention in plants essential oil include vegetable oil and aromatic essential oil,
Vegetable oil and aromatic essential oil are commonly referred to as plants essential oil in the present invention.In the present invention plants essential oil as silicone oil substitute technology
Nourishing scalp is played, maintain and recovers scalp barrier function, scalp itch and conditioning hair is reduced, strengthens the work of hair gloss
With.
There is plants essential oil hair-washing composition with physiologically active anti-sebum to aoxidize and prevent the effect of scalp itch, head
Hair will gather some sebums, dust and dandruff after not washed every several days, and these materials are contacted with the oxygen in air to become sour
And accelerate the breeding of bacterium, cause scalp itch, the microbial environment of scalp changes, and hair becomes more to lack vigor.This hair
Bright hair-washing composition is clean except the soil cleaning that will be accumulated on hair, and long-term use can help to prevent the peroxide of scalp sebum
Change reaction, and then prevent and mitigate itching for scalp, scalp health, hair natural gloss degree can be improved.
Plants essential oil of the present invention includes vegetable oil and aromatic essential oil, and aromatic essential oil has small molecule and volatility
Characteristic, with physiology and psychology adjustment effect；The effect of vegetable oil in the present invention is the carrier oil of aromatic essential oil,
Molecular weight is big, and senior carbon chain fatty acid ester content is high, and its chemical composition is approximate with the skin of people, the vegetable oil conduct in the present invention
The carrier of aromatic essential oil, has the effect nourished and nursed one's health to scalp and hair, while cooperateing with aromatic essential oil to play
Nourishing and opsonic action to scalp and hair.
The development of the present invention is Laf Daily Chemical Products Co., Ltd. and institute of microbiology of the Chinese Academy of Sciences, German BASF and strange
Hua Dun essence and flavoring agents company develops jointly, wherein the cooperation in terms of stressing formula technique with German BASF, stresses with the Chinese Academy of Sciences
The cooperation in terms of research and test in terms of scalp care, the cooperation in terms of plants essential oil screening is mainly with Qi Huadun.
A kind of senior Haircare composition technology of scalp maintenance type containing plants essential oil of the present invention is applied to shampoo, hair washing
The composition technology of the products such as Gao , treatment oil hair creams.
Plants essential oil (vegetable oil and aromatic essential oil) active ingredient content that the present invention is included is high, in such as vegetable oil
Unsaturated fatty acid content it is high, and senior carbon chain fatty acid content is high, the characteristics of molecular weight is big；Terpene is dilute in aromatic essential oil
Class content of material is high, terpenes plant especially sesquiterpene have it is preferably anti-oxidant, the features such as anti-inflammatory.
The selection of instant component:
1. bergamot/Bergamot
Bergamot has title bergamot oil Citrus bergamia, extracts from pericarp.Improve Oily, to acne,
Eczema, chronic eczema, Jie sores, ulcer, varication, bleb etc. are effective in cure；There is good bactericidal purifying in cosmetic composition
Effect, there is balance scalp grease effect well.Odor characteristic：Pure and fresh simple and elegant, similar orange and lemon, the slightly fragrance of a flower, are perfume
In one of the essential oil commonly used.Bergamot is extracted using squeezing hair, and active component is bergamio, linalool methoxy Psoralen
Fat element.
2. Rosemary Oil rosemary
Rosemary Oil Rosmarinus officinalis extract from flower and leaf.There is consolidation effect to slack and undisciplined skin
Really, skin is itched has inhibition, can improve dandruff and stimulate hair growth.Rosemary Oil uses the side of steam distillation
Method, its active matter is 1,8 cineoles, Alpha-sobrerone alkene and bornyl acetate.
3. Lavender lavender
Lavender Lavandula angustifolia extract from flower.Any skin of matters, treatment are burnt, shone
Wound, promotes cytothesis, balance sebum secretion；Suitable for any kind of skin, sebum secretion can be balanced.Lavender is adopted
Extracted with vapor distillation method, its active component is linalool, bergamio, terpinene.
4. Basil Essential basil
Basil Essential Basil Sweet, Ocimum basilicum extract from leaf, flower.Tighten up improvement obstruction skin, cleaning
Sebum, balances scalp environment, nourishes scalp.Basil Essential is extracted using vapor distillation method, and its active component is linalool, folium eucalypti
Oily element, ocimenum and citronellol.
5. clove oil clove
Clove oil Eugenia caryophyllata extract from flower.Treat wound infection, sore and ulcer etc.；Cloves essence
Oil is extracted using vapor distillation method, and its active component is Eugenol, caryophyllene and nerol.
6. sweet orange oil orange
Sweet orange oil Citrus sinesis extract from pericarp.Sweet orange be minority be proved to contrastimulant essential oil it
One, with the effect for nourishing scalp, the pH-value of energy balance skin, sweet orange oil is extracted using squeezing hair, and active component is two
Amylene, myrcene and octanal.
7. tea tree ethereal oil tea tree
Tea tree ethereal oil Melaleuca alternifolia, extract from leaf and spray.The excellent antibacterial essence of clean-up effect
Oil, can bactericidal antiphlogistic, treatment and improve skin problem, restrain pore, treatment scalp overdrying and dandruff problem suppress head and itched.Tea
Set essential oil and extraction is sent out using steam distillation, its active component is terpenes, cineole.
8. Cananga odorata quintessence oil ylang-ylang
Cananga odorata quintessence oil Cananga odorata, extract from flower.Balance sebum secretion, it is anti-aging, wrinkle resistant；Hair conditioning,
Embellish.Cananga odorata quintessence oil is sent out using steam distillation and extracted, and its active component is linalool, geranyl acetate.
9. Rosa Damascana rose
Rose (Rosa rugosa) is rose family Rosa machaka, the Rosa Damascana concentration extracted from its petal
Various odoramentums in spending.Extract from flower.It is adapted to all skins, anti-aging, promotees cytothesis；Treat varication；
Rosa Damascana of the present invention is Damask Rose essential oil Rose Otto, CAS No.90106-38-0. proportions (20 DEG C) 0.8-
0.85,79 DEG C of shading index (20 DEG C) 1.450-1.464, flash-point ＞, terpenoid substance comparision contents are high, such as lemongrass alcohol content
16%, spiceleaf alcohol content 3.2%, lemon aldehyde 0.8%.
10. chamomile essential oil chamomile
Chamomile essential oil Matricaria chamomilla, extract from flower.Improve dry skin；Chamomile essential oil is used
Steam distillation hair is extracted, and its active component is chamazulene, Alpha-bisabolol and farnesene.
11. Ah's glycerine (Morocco's essential oil)
Ah glycerine ARGAN OIL, squeeze gained by Morocco Ah Gan Shu kernel, include the lipid and fat to skin beneficiating
Fat acid composition, such as oleic acid, linoleic acid and tocopherol, also containing sterol, triterpene alcohol, carrotene and polyphenol components, this
A little active components can balance and stimulate the dermal cell in natural physiological process, promote skin vitality and effectively protect skin.Ah
Glycerine, content of fatty acid 99%, wherein unsaturated fatty acid content 80%, oleic acid (C18:1) it is 43-49.1%, linoleic acid
(C18:2) it is 29.3-36%, unsaponifiable matters content 1%, 60-90 milligrams/100 grams of tocopherol content, sterol content 130-
230 milligrams/100 grams, Ah's glycerine of the present invention produces for BASF AG, and the trade mark of BASF is LIPOFRUCTYLTMARGAN
LS9779。
12. handkerchief Yago Lamela essential oil
Handkerchief Yago Lamela essential oil Paramela Essential Oil, INCI title Adesmia boronioides
Essential Oil, belong to Angiospermae, butterfly-type flower Asia sections plant, are grown on the prairie and Andean massif of South America
The transitional region of mound rainforest, is grown in Argentine Patagonia, the sandy soil of 800-1200 meters of height above sea level.Made with leaf and petal
Extracted for raw material, preparation method is steam distillation, yield is 0.3% to 1.5%, and its main active ingredient is sesquialter
Terpene substances content 31.6%, with the happy sweet banksia rose and the spicy smell of Radix Glycyrrhizae.Manufacturer, HIERBAS PATAGONICAS
SRL。
13. the stacked heath eggplant essential oil of squama
The stacked heath eggplant essential oil of squama is a kind of plant of Solanaceae of Argentinian Patagonia growth, the stacked heath eggplant essential oil of squama
Leaf petal is extracted from, the stacked heath eggplant essential oil of squama has the effect of anti-oxidant, antibacterial, anti-inflammatory to scalp sebum, prevents sebum
The head that peroxidating is produced is itched phenomenon.The density (20 DEG C) 0.886 of the stacked heath eggplant essential oil of squama, refraction index 1.745 (20 DEG C), terpene
Alkenes content of material 50%-80%, lemongrass alcohol content 31.7%, citronellyl formate content 12.8%, spiceleaf alcohol content 9.8%.
Manufacturer, HIERBAS PATAGONICAS SRL.
14. Geranium Essential
Geranium Essential Rose Geranium, extract from the Madagascar growing plants Pelargonium roseum in Africa
Spend and get, its taste is somewhat as rose, with respect to proportion 0.9620-0.9720 (D20/4), shading rate 1.4370-
100 DEG C of 1.4400 (n20/D), flash-point ＞, its main active be terpenoid substance such as citronellol, citronellyl formate, pine alkene,
Gemic acid, Geraniol, terpinol, citral etc., head caused by sebum peroxidating, which is itched, to have prevents effect, Geranium Essential
Almost it is adapted to various skins, because it can restrain skin, balances sebum secretion, tune is played to pore obstruction and Oily
Section is acted on.In addition, fish pelargonium has anti-melancholy function, to regulation thought and operating pressure, mood, which suddenly rises and suddenly fall to wait to have, manages
The fragrant curative effect thought.Geranium Essential of the present invention is selected from the fragrant oil-soluble Pelargonium roseum flower extract of moral
(Flowerconcentrole Rose Geramium) enemy leatherware plays the role of to restrain and balance scalp grease.
15. macadimia nut oil
Macadimia nut oil is the content of fatty acid 95% by being derived from Queensland nut Macadamiatetraphyla cores, wherein,
Palmitic acid (C16:0) content 9%, stearic acid (C18：0) content 4%, oleic acid (C18:1) content 60%, linoleic acid (C18：2) contain
Amount 2%, palm monoenoic acid (C16：1) content 20%, proportion 0.9218,500 DEG C of flash-point ＞, 500 DEG C of boiling point ＞, macadimia nut oil
The content of Fatty Acids is high, and nourishing and opsonic action, manufacturer, U.S. Lai Baokang LIPO are played to scalp and hair
CHEMICALS。
16. jojoba oil
Jojoba oil JOJOBA OIL, gained, wherein content of fatty acid 99%, palmitic acid are squeezed by the kernel of Jojoba tree
(C16:0) content 2%, oleic acid (C18:1) content 13%, erucic acid (C22：1) content 13%, peanut monoenoic acid (C20:1) content
71%, acid number 0.5-1, iodine number 80-85, saponification number 88-96, proportion 0.86-0.87 (25 DEG C), shading rate 1.45-1.46 (40
℃)；Jojoba oil is a kind of HMW, the liquid oil adipocere of senior carbon chain fatty acid ester, the skin of its chemical composition and people
Approximately, jojoba oil, as the carrier of aromatic essential oil, has the effect nourished and nursed one's health to scalp and hair in the present invention.
Jojoba oil Lipovol J Clear of the present invention, manufacturer, U.S. Lai Baokang LIPO CHEMICALS.
17. Sweet Almond Oil
Sweet Almond Oil Sweet Almond Oil, belong to neutral base oil.Squeezed by apricot fruit and obtained, color and luster is light
Huang, smell delicate fragrance.It is this in aromatotherapy massage rich in materials such as polybasic unsaturated fatty acid, vitamin D, E and protein
Oil is one of the most frequently used base oil to plant (Prunus amygdalus var.dulcis), because it has good ductility,
It is easy to be absorbed by the skin, helps to make skin soft and smooth property, and without greasy feeling.
18. aloe
Aloe Aloe Oil, a kind of essential oil extracted by aloe is the crude vegetal based on C12-C14 aliphatic acid,
Comprising 169 kinds of beneficiating ingredients, the fields such as food, cosmetics, medicine, chemical industry are can be widely used for, there are other greases irreplaceable
Health care and beautification function.Saturation wherein in aloe compositionAliphatic acidA quarter is accounted for, capric acid (capric acid), the moon is included
Cinnamic acid (lauric acid), myristic acid (my ristic acid), pentadecanoic acid (pentadecanoic acid), palm
Sour (palmitic acid), Heptadecanoic acide (margaric acid), stearic acid (stearic acid).Unrighted acid is accounted for
3/4ths, including palmitoleic acid (palmitaleic acid), hexadecadienoic acid (hexadecadienoic acid), oil
Sour (oleic acid), linoleic acid (lonoleic acid), leukotrienes (linolenic acid).Also contain butanedioic acid in addition
(succinic acid), malic acid (malic acid), lactic acid (lactic acid), p-Coumaric Acid (P-coumaric
The organic acid such as acid), during for medicine and cosmetics, iodine number should should be about in 185-195, proportion in 80-100, saponification number
0.903/20 DEG C, the characteristics of possessing aloe plant due relaxation effect of oil institute with based on can stimulate skin to recover work
Power, controls treatment trauma and desalinates tanned color spot.
19. avocado oil
Avocado oil Perseaamericana is squeezed from avocado fruit, is a kind of extraordinary base oil.It is a kind of
The stronger oil of viscosity, penetrating power is strong, rich in nutriments such as multivitamins, so be frequently used among skincare product, can
For treating eczema, psoriasis and skin aging.In aromatherapy therapy, it is a kind of extraordinary base oil.It is one
The stronger oil of viscosity is planted, penetrating power is strong, rich in vitamin A and vitamin D, lecithin, potassium and vitamin E.
20. evening primrose oil
Evening primrose oil EVENING PRIMROSE OIL, are the grease being extract from the seed of oenothera biennis, composition：R- is sub-
Sesame oil acid, magnesium, zinc, injection Vitamin B_6, B6, B5 are applicable：Original name primrose, can adjust evening primrose oil to close the oil of base oil and essential oil
Fat, in aromatotherapy, can reconcile emulsion, creams, improve eczema, and psoriasis helps wound healing, nail development etc..
21. grape-kernel oil
Grape-kernel oil Greep seed oil, are vitaceaeGrapeVitis vinifera L. seed extract.
This base oil quality is very good, almost water white transparency, it is easy to be absorbed by the skin.It has gentle convergence,
It can help to tighten and nursing skin.It is helpful for treatment acne and other disease of skin.It is rich in linoleic acid, is a kind of
Essential fatty acid, it is extremely important to skin and cell membrane.Grape-kernel oil has regeneration and effect of making contributions again, there is very strong guarantor to skin
Wet effect.
22. olive oil
Olive oil OLIVE OIL are the oil that the seed Lan Ren of olive squeezes out with just ripe or ripe olive fresh fruit, are passed through
The natural oil that the cold squeezing process of physics is extracted, olive is a kind of famous seeds with long history in the world,
Olive (Olea Europaea L.) incorporates Oleaceae (Oleaceae), sweet-scented osmanthus (Olea), evergreen little Qiao into Plant Taxonomy
Wood is that unique xylophyta in the form of nature for human consumption is oily in the world.Olive oil is rich in and skin affinity pole
Good squalene and essential fatty acid, absorbs rapid, effectively keeps skin elasticity and moist；Enriched contained by olive oil
Monounsaturated fatty acids and vitamin E, K, A, D etc. and phenols polyphenoils, can eliminate facial wrinkles, prevent skin aging,
The effects such as having skin or hair care and preventing and treating hand and foot from chapping, is the cosmetics and skincare product that " can be eaten ", smears skin energy with olive oil in addition
Resisting ultraviolet prevents cutaneum carcinoma, is a kind of important base oil in volatile oil therapy.
23. walnut oil
Walnut oil Walnut oil, use walnut kernel for raw material, and the vegetable oil of squeezing, the fat content of walnut is up to
65%~70%, shelter has first of woody oleiferous plants：Unsaturated fatty acid content >=92%, linoleic acid Ω -6 >=56%, leukotrienes
Ω -3 >=14%, rich in nutriments such as natural VA, VD, absorbs rapid, effectively keeps skin elasticity and moist.
24. wheat-germ oil
Wheat-germ oil Wheat Germ Oil are extracted from wheat " plumule ", and it is located at the center of wheat, rich
Containing vitamin e, B, protein, mineral matter, a variety of unrighted acids such as fresh coconut oil, also leukotrienes, linoleic acid are claimed
For the vitamin treasure-house of skin, have " king of vitamin E " although title plumule only account for the 3% of wheat weight, but contain
The protein of whole wheat 25%, also containing vitamin and mineral matter.
Gather in hair-washing composition of the present invention containing the lauryl sulfate and laruyl alcohol for accounting for composition weight 4.0% to 40%
The composition of oxygen ethene ether ammonium sulfate, the ratio of lauryl sulfate and the ethoxylated dodecyl alcohol ammonium sulfate is 1:2-2:
1.The lauryl sulfate abbreviation K12A or SLSA, its structural formula is：ROSO3NH4 +, R=C12-C18Alkyl, commercially available fatty alcohol
The preferred active matter content of ammonium sulfate is 70%, and its outward appearance is white or faint yellow pastel, what the lauryl sulfate had
Good detergency, hard water resistance property, relatively low excitant, higher foaming power and excellent compatibility.The fatty alcohol
Polyoxyethylene ether ammonium sulfate abbreviation AESA, its structural formula is RO (CH2CH2O)nSO3NH4 +, R=C12-C18Alkyl, n is 2-4, excellent
The average ethoxyquin degree of choosing is n=3.The active matter content of the ethoxylated dodecyl alcohol ammonium sulfate commercially available prod has 25% He
70% two kind, the ethoxylated dodecyl alcohol ammonium sulfate of 25% active matter content is water white transparency thick liquid, 70% active matter
The ethoxylated dodecyl alcohol ammonium sulfate of content is white or faint yellow pastel, and preferably active matter content is 70% laruyl alcohol
Polyoxyethylene ether ammonium sulfate.The ethoxylated dodecyl alcohol ammonium sulfate also has the characteristic of nonionic surfactant, hard
Still there is preferable dirt-removing power in water.The compounding use of lauryl sulfate and laruyl alcohol polyoxy the ether ammonium sulfate, can
To produce good cooperative effect, such as：Abundant foam, extremely gentle sensation, outstanding thickening properties etc. with fine and close.This
Invention lauryl sulfate accounts for hair-washing composition weight 2% to 6%, and ethoxylated dodecyl alcohol ammonium sulfate of the present invention accounts for hair washing group
Polymer weight 6% to 10%.
Hair-washing composition of the present invention contains APG type (APG) the nonionic table for accounting for composition weight 0.5% to 15%
The nonionic surfactant of APG type used in face activating agent, the present invention is the known gentle surface of a class on the market
Activating agent, its chemical formula formula is following (1)：R1—O—(R2O)t-(G)vWherein：R1Selected from linear and side chain, saturation or
Undersaturated, about carbon chain lengths are the alkyl of 8 to 24 carbon atoms, and selected from linear and side chain, about carbochain
Length is the alkylbenzene of 8 to 24 carbon atoms；R2Selected from the alkene containing 2 to 4 carbon atoms；G, which is selected from, possesses 5 to 6
The reduced sugar of carbon atom；T is between 0 to 10；V is between 1 to 15.
Currently preferred APG is the compound for meeting chemical general formula (1), wherein R1Selected from linear, saturation
, about carbon chain lengths are the alkyl of 8 to 14 carbon atoms；T is 0 between 0 to 3, in the present invention；G is selected from glucose,
Fructose and galactolipin, the present invention preferably glucose.The degree of polymerization V values of glucose are between 1 to 15 in formula (1).According to this
Invention, the more than percent 80 sugared degree of polymerization is controlled between 1 to 4, and average degree of polymerization is then controlled between 1 to 2, and it has
The APG APG of representational product such as commercially available BASF (BASF), e.g., APG300, APG350, APG500, APG550,
APG625,APG810,APG818,APG1200,APG2000,
Nonionic alkyl glycoside surfactant of the present invention preferably uses the APG1200 of BASF AG's production i.e.
Plantacare 1200UP or Plantacare 2000UP.Plantacare 1200UP are a kind of sticky C of muddiness12-14's
The aqueous solution of glycan glycosides, active matter 50%, pH value (20% in 15% isopropanol) 11.5-12.5；Viscosity (40 DEG C) 1000-
6000mPas, density (40 DEG C) 1.07-1.08g/cm3, molecular weight about 420g/mol, free alkyl alcohol≤1%；Plantacare
2000UP is a kind of sticky C of muddiness8-14Glycan glycosides the aqueous solution, active matter 50%, pH value (20% in 15% isopropanol)
11.5-12.5；Viscosity (40 DEG C) 2000-4000mPas, density (40 DEG C) 1.07-1.08g/cm3, molecular weight about 390g/mol,
Free alkyl alcohol≤1%.
APG (APG) surfactant of the present invention is preferable over Plantacare 2000UP, a kind of C8-14Alkyl grape
C in glucosides, the present invention8-14Alkyl-glucoside accounts for hair-washing composition percentage by weight and is further optimized for 3% to 8%.
Contain cocounut oil both sexes sodium acetate or the coconut palm for accounting for composition weight 0.5% to 10.0% in the hair-washing composition of the present invention
Oleamide CAB.The cocoyl both sexes sodium acetate is colourless to slightly yellow clear viscous liquids, its commercially available prod
Under the conditions of active matter content is 30%, 25 DEG C, its viscosity is 5000-10000, and sodium chloride content is less than 9.0%, 1% aqueous solution
PH be 6.0-8.0, its structural formula be RN (CH2COONa)2, the excitant of the cocoyl both sexes sodium acetate is low, to skin,
Eyes are especially gentle, and its excitant can be significantly reduced by matching with anion surfactant, and with good foaming power, foam
Abundant fine and closely woven, skin sense is good, can significantly improve the foam state of formula system.The Cocoamidopropyl betaine is slightly yellow
Prescribed liquid, the active matter content of its commercially available prod is 30%, and sodium chloride content is less than 6.0%, and free amine content is less than 0.10%,
The pH value of its 1% aqueous solution is 5.0-7.0, and its structural formula is RCONH (CH2)3N+(CH3)2CH2COO-.The coconut oleoyl amine third
Base glycine betaine has an excellent compatibility, and with excellent foaminess and significant thickening property, with good hard water resistance property,
Antistatic behaviour and biological degradability.
The preferred Cocoamidopropyl betaine of amphoteric surfactant of the present invention, Cocoamidopropyl betaine of the present invention is accounted for
Hair-washing composition percentage by weight is further optimized for 3% to 6%.
Contain the cationic polymer for accounting for composition weight 0.05% to 3.0%, the sun in hair-washing composition of the present invention
Ionomer is selected from：At least one in cationic cellulose polymer, cation melon xanthan polymer, the cation is fine
The plain polymer of dimension is the copolymer of hydroxyethyl cellulose and alkyl trimethyl ammonium chloride, can be divided according to the difference of degree ofacationic substitution
For：High-cation substitution value JR, cationic substitution value LR and tri- kinds of models of low degree ofacationic substitution LK, preferably high-cation take
Dai Du cationic cellulose polymer, i.e. Polyquaternium-10, other cationic cellulose polymers for being suitable for the present invention
Also copolymer of hydroxyethyl cellulose and dialkyl dimethyl ammonium chloride etc.；The cation melon glue is by melon glue quaternary ammonium
The product obtained after change, its key component is melon glue hydroxypropyltrimonium chloride, is according to the difference of substitution value available one
The cation melon glue product of row, preferably substitution value are 0.1 to 0.2, and the cation melon glue for the present invention is in 25 DEG C of conditions
Under, the viscosity of its 1% aqueous solution is 2000mPa.s to 4000mPa.s.
Melon glue oxypropyl trimethyl in the preferred melon glue hydroxypropyltrimonium chloride of subject cationic polymer, the present invention
Ammonium chloride accounts for hair-washing composition percentage by weight and is further optimized for 0.2% to 0.5%.
Contain the cationic quaternary ammonium salt form emulsification for accounting for composition weight 0.05% to 8% in the shampoo composite of the present invention
Agent, the cationic emulsifier is selected from Alkyl benzyl dimethyl ammonium salt, alkyl trimethyl quaternary ammonium salt, double alkyl dimethyl quaternary ammoniums
One kind in salt, preferably double octadecyldimethyl quaternary ammonium salts.
Double octadecyldimethyl quaternary ammonium salt emulsifiers account for hair-washing composition percentage by weight and further optimized in the present invention
For 1% to 5%.
Hair-washing composition of the present invention includes accounting for composition weight 0.5% to 5.0%, and preferably 1.0% to 3.0% be used for hangs
The thickener of floating plants essential oil emulsion and thickener composition, improves the stability of hair-washing composition, wherein the thickener is preferred
Phthalic acid amide, the phthalic acid amide trade name is TAB-2, by double hydrogenated-tallow group secondary amine and O-phthalic
Anhydride reaction is made, and is a kind of multifunctional suspending stabilizer, can be used as emulsifying agent, suspending agent, can effectively stablize and contain plant
The hair-washing composition of essential oil, can have preferable salt tolerance, in wider pH models with all components compatibility in the present composition
There is constant thickening effect, it is 6000mPa.s to 12000mPa.s that can make the viscosity of composition at room temperature, preferably in enclosing
8000mPa.s to 10000mPa.s.The non-limiting example of other thickeners for being applied to the present invention also has：Sodium chloride, chlorination
Electrolyte such as ammonium, ETHANOLAMINE HYDROCHLORIDE, diethanol amine chloride, sodium sulphate, ammonium sulfate, disodium hydrogen phosphate, the sodium of phosphoric acid five and poly-
Glycol distearate, polyethylene glycol mono stearate, polyethylene glycol dilaurate, sodium cellulose glycolate, ethoxy
Cellulose, hydroxypropyl methyl cellulose, xanthan gum, trade name are Aculyn22 acrylic acid/polyoxyethylene (20) octadecyl alcolol
The anionic thickeners such as the acrylic copolymer that ether methyl acid copolymer, trade name are Aculyn33, trade name are
Aculyn44 non-ionic thickening agent C10Poly- carbamyl macrogol ester, trade name SF-1 acrylate copolymer, poly- second
Glycol, polyvinylpyrrolidone etc..
The hair-washing composition of the present invention is also containing the pearlescent flake for accounting for composition weight 0.05% to 3.0%, further optimization
For 0.5% to 1.5% pearlescent flake, the pearlescent flake is ethylene glycol monostearate and EGDS.The pearl
The addition of mating plate, can assign shampoo beautiful pearl effect.
The hair-washing composition of the present invention is also containing the higher aliphatic for accounting for composition weight 0.2% to 3.0%, such as carbon 1618
Alcohol, the alcohol of carbon 16, the alcohol of carbon 22 etc., the present invention further preferably alcohol of carbon 16, the alcohol of carbon 16 be further optimized in the present invention 0.5% to
1.5%.
Antioxidant is BHT, BHA, and Vitwas E, preferred vitamin E of the present invention in hair-washing composition of the present invention
Acetate.The hair-washing composition of the present invention is 0.05% to 5.0% comprising composition weight percentage is accounted for.Further it is optimized for
0.1% to 1%
NMF is glycerine, propane diols, 1,3 butanediol, sorbierite, glycerine (glycerine) in hair-washing composition of the present invention
Deng.In NMF preferably glycerine in hair-washing composition of the present invention, hair-washing composition of the present invention glycerine account for composition weight 0.5% to
10%, further it is optimized for 1% to 6%.
The acceptable component of other cosmetics that includes of hair-washing composition of the present invention, including viscosity-controlling agent, chelating agent,
PH adjusting agent, preservative, pigment and spices etc..The viscosity-controlling agent accounts for the 0.1% to 5.0% of composition weight, described glutinous
The non-limiting example of degree conditioning agent has：Sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, cellulose derivative, acrylic acid copolymer
Thing etc..The chelating agent accounts for the 0.01% to 0.30% of composition weight, is further optimized for 0.05% to 0.15%, the chela
The non-limiting example of mixture has：Ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphorus
Acid, ascorbic acid etc., preferably disodium ethylene diamine tetraacetate；The non-limiting example of the pH adjusting agent has：Citric acid, phosphoric acid
Deng, optimization citric acid, the pH of regulation system is in 5.0 to 8.0, preferably 5.5 to 6.5；The preservative, essence, the selection of pigment,
Meet the regulation of hygienic standards for cosmetics, from the raw material of safety.
Preparation method
(1) plants essential oil emulsion is pre-prepared：
(1) in oil phase composition, each embodiment, the hexadecanol of hair-washing composition weight 0.5% to 1.5% of the present invention will be accounted for,
The macadimia nut oil of weight 0025% to 0.25%, the jojoba oil of weight 0025% to 0.25%, weight 0.1% to 1%
Vitwas E is added in oil phase, is heated while stirring, and temperature control (does not contain plant at 72 DEG C in placebo of the present invention
Exempt from addition in thing essential oil, said oil phase composition)；
(2) aqueous phase composition, takes the deionized water of the above-mentioned oil phase Ingredient Wt of 5 times of weight, and addition accounts for hair washing group of the present invention
The dioctadecyl dimethyl ammonium chloride of polymer weight 0.5% to 2.5%, heats and is uniformly dispersed, and temperature control is at 78 DEG C；
(3) oil phase composition is added to aqueous phase composition, and (3000 revs/min) of homogeneous is stirred 2-4 minutes, is cooled afterwards；
(4) the stacked heath eggplant of squama for accounting for present composition weight 001% to 0.10% is added when temperature is reduced to 40 degree
Essential oil and the Geranium Essential for accounting for present composition weight 0.0025% to 0.025%, continue to stir and cool to 35-38
DEG C, it is closed to preserve, it is standby；
(2) preparation of hair-washing composition：
(1) in each embodiment, the ethylenediamine tetra-acetic acid two of hair-washing composition weight 0.05% to 0.15% of the present invention will be accounted for
Sodium, the glycerine for accounting for hair-washing composition weight 1% to 6% of the present invention is added separately in deionized water, and then stirring and dissolving adds
The guar hydroxypropyltrimonium ammonium chloride and heating stirring of hair-washing composition weight 0.2% to 0.5% of the present invention are accounted for until molten
Solution, temperature control is then respectively adding the laruyl alcohol sulfuric acid for accounting for hair-washing composition weight 2.0% to 6.0% of the present invention at 80 DEG C
Ammonium, adds the ethoxylated dodecyl alcohol ammonium sulfate for accounting for hair-washing composition weight 6.0% to 10.0% of the present invention；Addition accounts for this hair
The Cocoamidopropyl betaine of bright hair-washing composition weight 3.0% to 6.0%；Addition accounts for hair-washing composition weight of the present invention
1.0% to 3.0% phthalic acid amide；Add the C8-14 alkane for accounting for hair-washing composition weight 3.0% to 8.0% of the present invention
Base glucoside；Add the dioctadecyl dimethyl ammonium chloride for accounting for hair-washing composition weight 0.5% to 2.5% of the present invention；With
And the pearling agent of hair-washing composition weight 0.5% to 1.5% of the present invention is accounted for, stir and keep 80 DEG C of temperature until all molten
Solution, cools while stirring after dissolving, is added when cooling to 50 DEG C and accounts for the appropriate percentage by weight of hair-washing composition weight of the present invention
Preservative, pigment, salt and essence, continue to cool to 40 DEG C, and pH value is adjusted to 6.5, it is standby；
(3) the plants essential oil emulsion for preparing step (1) is slowly added into step (2) according to corresponding ratio and prepared
About 40 DEG C of hair-washing composition system in, stir 30 minutes, speed control is at 40 revs/min, and 38 degree discharge.
Application method
The shampoo composite of the present invention is used in the way of conventional cleaning and conditioning hair, mainly including following step
Suddenly：
(A) hair is soaked with water；
(B) hair-washing composition of the foregoing any one claim of effective dose is applied on the hair, with finger belly gently
Massaging scalp 0.5-1 minutes, the effective dose is generally in the range of 1 gram to 50 grams, preferably 2 to 20 grams；
(C) hair-washing composition on the hair is rinsed with water.
These steps can be repeated as many times as desired, to reach the work(of sought cleaning, conditioning, moist and moisturizing
Effect.
Embodiment
Here is the non-limiting example of the shampoo composite of the present invention.These embodiments are only given to illustrate
Purpose, limitation of the invention can not be interpreted as, can be with because without departing from the spirit and scope of the present invention
Many change is carried out to the present invention.In these embodiments, unless stated otherwise, all concentration is all percentage by weight.Institute
Those optional materials, such as preservative, viscosity modifier, pH adjusting agent, spices, pigment are referred to term " a small amount of material "
Selection Deng, these a small amount of materials will change with selected to prepare the physics and chemical characteristic of the special component of the present invention
Become.
Prepare embodiment I-Ⅹ V
Embodiment I-V
Embodiment VI-X
Efficacy assessments
The efficacy assessments of the present invention, are based on a kind of scalp maintenance type hair-washing composition institute containing plants essential oil of the present invention
What the technological means of use was carried out.
Hair-washing composition of the present invention, employs the vegetable oil and aromatic essential oil for having physiologically active to scalp and hair
Active component, scalp and hair are played physiology nourishing, maintenance and conditioning effect, pass through regulation and recover scalp health
Play mitigation scalp itch, conditioning hair and the effect for improving hair gloss.
Therefore, the present invention is used after the embodiment of the present invention by testing, the percutaneous water loss numerical value of scalp, scalp itch
Sensory evaluation, and hair gloss sensory evaluation, come verify the present invention it is both effectiveness.
The present invention carries out the survey of the percutaneous water loss TEWL numerical value of scalp by comfort 1 and comfort 2 with embodiment I to Ⅹ
Examination, to test the change that the correct tare weight of the embodiment of the present invention wants the percutaneous water loss numerical value of one of health indicator, is further related to
The present invention is by the improvement of scalp cutin layer function, and the acquisition of the numerical value is the multi-functional surveys of MPA9 using CK companies of Germany
Tewameter TM300 (the water loss test probe TEWL) tests for trying platform are obtained；
(1) present invention carries out the contrast of sensory evaluation, testing example I by comfort 1 and comfort 2 with embodiment I to Ⅹ
To Ⅹ using after the 14th day, scalp itch sense organ integral estimation, the sensory evaluation method is：Embodiment I-Ⅹ will be prepared, point
Tester's contrast is not issued to use.Tester washes hair in the same manner using during embodiment sample, every kind of embodiment
Hair-washing composition is respectively used two weeks.Tester is scored according to the sensation of oneself, and wherein antipruritic effect is according to using comfort 1
Or comfort time for starting after 21 days to scalp itch of the 2 or each embodiment and head degree itched scores, antipruritic effect is basis
The number and size of dandruff scores.Standards of grading using 7 points system, 1 point is worst, and 7 points are best, fraction more high effect it is more good more
It is good.
(2) present invention carries out the contrast of sensory evaluation, testing example I by comfort 1 and comfort 2 with embodiment I to Ⅹ
To Ⅹ using after the 21st day, hair brightness sense organ integral estimation, the sensory evaluation method is：Embodiment I-Ⅹ will be prepared
V, it is respectively issued to 40 tester's contrasts and uses.Tester washes hair in the same manner using during embodiment sample, often
Embodiment hair-washing composition is planted respectively to use three weeks.Tester scores the glossiness of hair according to the sensation of oneself, hair
Brightness sensory effects are the degree and size of the hair light judged according to individual to score.Standards of grading are using 7 points of systems, 1
Divide worst, 7 points best, the better of fraction more high effect
The people of women 126 is selected in the present embodiment, the age, hair thickness and length were close, are divided into six small between 20-40 Sui
Group, every group of people of efficiently individual quantity 20, in using embodiment of the present invention sample, its habits and customs, the shampoo used in the past
Brand does not change.
The test of the percutaneous water loss TEWL numerical value of scalp, is divided into first, second group, every group of 20 people.
First group, in 20 people, wherein 10 people are using comfort 1, remaining 10 people is intended using comfort 2, application method with the present invention
Fixed application method is defined, and the TEWL values of scalp are determined when distinguishing the 7th day, the 28th day, and calculates the 28th natural gift value changes
Percentage (is averaged)；
Second group, in 20 people, respectively using the embodiment of the present invention I to Ⅹ, the user that application method is drafted with the present invention
Method is defined, and the TEWL values of scalp are determined when distinguishing the 7th day, the 28th day, and calculates the percentage of the 28th natural gift value changes；
Scalp itch, sensory evaluation method is divided into the 3rd, the 4th group, every group of 20 people.
3rd group, in 20 people, wherein 10 people use blank 1, remaining 10 people uses blank 2, and application method is intended with the present invention
Fixed application method is defined, and carries out sensory evaluation (averaging) to the situation of scalp itch when distinguishing the 14th day；
4th group, in 20 people, respectively using the embodiment of the present invention I to Ⅹ, the user that application method is drafted with the present invention
Method is defined, and the 14th day progress sensory evaluation scores (averaging) of itching to scalp respectively；
Hair gloss, sensory evaluation method is divided into the 5th, the 6th group, every group of 20 people
5th group, in 20 people, wherein 10 people use blank 1, remaining 10 people uses blank 2, and application method is intended with the present invention
Fixed application method is defined, and the sensory evaluation that hair of the hair washing after dry carries out brightness is scored in after use the 21st day
(averaging)；
6th group, in 20 people, respectively using the embodiment of the present invention I to Ⅹ, the user that application method is drafted with the present invention
Method is defined, and scores (averaging) to the sensory evaluation that hair of the hair washing after dry carries out brightness in after use the 21st day；
Efficacy assessments table 1
The percutaneous water loss TEWL (T7, T28) of scalp, the antipruritic sensory evaluation of scalp, hair brightness sensory evaluation
It can be seen that from the actual test data of the form of efficacy assessments 1：
1st, comfort 1 and comfort that 2 reduced value of the percutaneous water loss of scalp is respectively 1.5% and 3.8%, placebo
TEWL reduces percentage of the percentage well below the percutaneous water loss reduction of scalp that each embodiment of embodiment I to Ⅹ is measured,
Illustrate that the protective effect of I to Ⅹ pair of scalp barrier of embodiment is significantly larger than comfort 1 and comfort 2.
2nd, in terms of the test of scalp antipruritic effect, sensory evaluation score value of the embodiment I to Ⅹ after the 14th day is above the present invention
Sensory evaluation score value of the placebo after the 14th day.Illustrate that not only there is the embodiment I to Ⅹ containing plants essential oil scalp maintenance to make
With also with anti-sebum oxidation, so as to reduce the generation of scalp itch phenomenon.
3rd, in terms of hair gloss test, this hair is above using the sensory evaluation score value after embodiment I to Ⅹ the 21st day
Sensory evaluation score value of the bright placebo after the 21st day.Illustrate the embodiment I to Ⅹ containing plants essential oil after scalp barrier is recovered,
The closed enhancing that not only scalp itch phenomenon mitigates but also hair is dry, therefore hair surface is brighter, hair is looked
It is more healthy vibrant.
Claims (8)
1. a kind of maintenance hair-washing composition of scalp containing plants essential oil, in addition to cosmetically acceptable carrier, contains：
(A) composition weight 4.0%-40% lauryl sulfate and the composition of ethoxylated dodecyl alcohol ammonium sulfate are accounted for；
(B) composition weight 0.5%-15.0% APG type nonionic surfactant is accounted for；
(C) composition weight 0.5%-10.0% Cocoamidopropyl betaine is accounted for；
(D) composition weight 0.05%-8.0% dioctadecyl dimethyl ammonium chloride is accounted for；
(E) composition weight 0.05%-3.0% guar hydroxypropyltrimonium ammonium chloride is accounted for；
(F) composition weight 0.07625%-31.2% plants essential oil is accounted for：
(G) hexadecanol of composition weight 0.5% to 1.5% is accounted for；
The plants essential oil be macadimia nut oil, jojoba oil, the stacked heath eggplant essential oil of squama, the mixture of Geranium Essential, and
The weight of four kinds of essential oils compares macadimia nut oil：Jojoba oil：The stacked heath eggplant essential oil of squama：Geranium Essential is 100:50:
3:0.5 wherein：
Macadimia nut oil accounts for composition weight 0.05%-20%；
Jojoba oil accounts for composition weight 0.025%-10%；
The stacked heath eggplant essential oil of squama accounts for composition weight 0.0015%-1.0%；
Geranium Essential accounts for composition weight 0.00025%-0.2%.
2. hair-washing composition according to claim 1, wherein：The stacked heath eggplant essential oil density of squama is 0.886, folding at 20 DEG C
Optical index is 1.745 at 20 DEG C, terpenoid substance content 50%-80%, lemongrass alcohol content 31.7%, first in terpenoid substance
Sour lemongrass ester content 12.8%, spiceleaf alcohol content 9.8%.
3. hair-washing composition according to claim 1, wherein：The content of fatty acid 99% of jojoba oil；Wherein：Palmitic acid contains
Measure as 2%, oleic acid content is 13%, and content of erucic acid is 13%, peanut monoenoic acid content 71%；Jojoba oil acid number 0.5-1, iodine
Value 80-85, saponification number 88-96, proportion are 0.86-0.87 at 25 DEG C, and shading rate is 1.45-1.46 at 40 DEG C.
4. hair-washing composition according to claim 1, wherein, macadimia nut oil content of fatty acid 95%, wherein, palmitic acid
Content is 9%, stearic content 4%, the content 60% of oleic acid, linoleic content 2%, the content of palm monoenoic acid
20%, proportion 0.9218,500 DEG C of flash-point ＞, 500 DEG C of boiling point ＞.
5. hair-washing composition according to claim 1, wherein：Geranium Essential is with respect to proportion 0.9620-0.9720, shading rate
100 DEG C of 1.4370-1.4400, flash-point ＞.
6. hair-washing composition according to claim 1, wherein：Lauryl sulfate and ethoxylated dodecyl alcohol ammonium sulfate
Account for composition weight 8.0%-16%；Alkyl-glucoside nonionic surfactant accounts for composition weight 1.0%-10.0%；
Cocoamidopropyl betaine accounts for composition weight 0.5%-6.0%；Dioctadecyl dimethyl ammonium chloride accounts for composition weight
1%-5%；Guar hydroxypropyltrimonium ammonium chloride accounts for composition weight 0.1%-0.5%；Plants essential oil accounts for composition weight
Percentage 0.0875%-0.875%.
7. a kind of hair-washing composition, its component and weight percent content are：
8. the preparation method of hair-washing composition described in claim 1, is carried out according to the following steps：
(1) plants essential oil emulsion is pre-prepared：
(1) oil phase composition：By the hexadecanol in hair-washing composition, macadimia nut oil, jojoba oil, Vitwas E is added
Into oil phase reactor, heat while stirring, temperature control is at 72 DEG C；
(2) aqueous phase composition：The deionized water of the above-mentioned oil phase Ingredient Wt of 5 times of weight is taken, double octadecyldimethyl chlorine are added
Change ammonium, heat and be uniformly dispersed, temperature control is at 78 DEG C；
(3) oil phase composition is added to aqueous phase composition, with 3000 revs/min, stirs 2-4 minutes, cool afterwards；
(4) the stacked heath eggplant essential oil of squama and Geranium Essential are added when temperature is reduced to 40 DEG C, continues to stir and cool to 35-38
DEG C, it is closed to preserve, it is standby；
(2) preparation of hair-washing composition：
(1) by the disodium ethylene diamine tetraacetate in hair-washing composition, glycerine, suspending agent phthalic acid amide (TAB-2) is respectively
It is added in deionized water, stirs, disperse or dissolve, then adds guar hydroxypropyltrimonium ammonium chloride and heating stirring is straight
To dissolving, temperature control is at 80 DEG C；
(2) lauryl sulfate, ethoxylated dodecyl alcohol ammonium sulfate, Cocoamidopropyl betaine, C8-14 alkane are separately added into
Base glucoside；Dioctadecyl dimethyl ammonium chloride, pearling agent stirs and keeps 80 DEG C of temperature until whole dissolvings, molten
Cool while stirring after solution；
(3) preservative, pigment, salt and essence are added when cooling to 50 DEG C and spending, continues to cool to 40 DEG C, and pH value is adjusted
It is standby to 6.5；
(3) step (1) is prepared into plants essential oil emulsion and is slowly added into 40 DEG C of hair-washing composition prepared by step (2)
In system, stir 30 minutes, speed control is in 40 revs/min, 38 DEG C of dischargings.
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| CN105476895B (en) * | 2015-10-23 | 2018-09-28 | 重庆菩璞生物科技有限公司 | A kind of hair-washing composition containing lotus active constituent |
| CN105640803B (en) * | 2016-02-25 | 2018-10-30 | 刘忠波 | A kind of anti-dandruff, Anti-hair loss, hair products and preparation method thereof |
| CN106214528A (en) * | 2016-09-09 | 2016-12-14 | 拉芳家化股份有限公司 | A kind of quick-drying hair-care essence oil |
| CN107569408B (en) * | 2017-09-08 | 2020-10-16 | 新时代健康产业（集团）有限公司 | Hair care essence for increasing hair brightness and preparation method thereof |
| CN107595678B (en) * | 2017-09-13 | 2022-10-28 | 广州环亚化妆品科技股份有限公司 | Hair care composition and preparation method and application thereof |
| CN108785139A (en) * | 2018-07-24 | 2018-11-13 | 福建春辉生物工程有限公司 | A kind of hair care and hair growth essential oil and preparation method thereof |
| CN109363973A (en) * | 2018-11-27 | 2019-02-22 | 上海应用技术大学 | A kind of shampoo and preparation method thereof containing rose essential-oil microcapsule |
| CN112043628B (en) * | 2020-09-16 | 2021-09-14 | 广州德谷个人护理用品有限公司 | Composition containing plant essential oil, preparation method thereof and shampoo composition containing plant essential oil composition |
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