CN102327202A - Conditioner shampoo without silicone oil - Google Patents
Conditioner shampoo without silicone oil Download PDFInfo
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- CN102327202A CN102327202A CN201110207886A CN201110207886A CN102327202A CN 102327202 A CN102327202 A CN 102327202A CN 201110207886 A CN201110207886 A CN 201110207886A CN 201110207886 A CN201110207886 A CN 201110207886A CN 102327202 A CN102327202 A CN 102327202A
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Abstract
The invention claims conditioner shampoo without silicone oil, which comprises (A) a group of surfactants which comprises at least one alkyl polyglucoside (APG) nonionic surfactant, one non-ethoxylated anionic surfactant and one amphoteric surfactant; (B) micro emulsion; (C) at least one cationic conditioner; and (D) the balance of dosage of water. The shampoo provided in the invention has excellent conditioning effect.
Description
[technical field]
The invention belongs to household chemicals field, be specifically related to a kind of conditioner shampoo that does not contain silicone oil.
[background technology]
Can often feel coarse after hair is washed, be easy to fracture, sent out by influence or over-drastic hair dyeing, the electricity of surrounding after, hair can be dry, and the same sensation of time image grass is arranged.
Therefore, can often use the conditioning composition to overcome the hair problem before and after all hair washings in the compositions of flooding, like frequent use silicone oil as conditioner (silicone oil of big particle diameter or small particle diameter).Yet the shortcoming of silicone oil is hair to be produced gather, and too much silicone oil gathering on hair can make hair lose conditioning and submissive sensation on the contrary, and more disadvantageous is that the hair after hair dyeing or electric the sending out is produced adverse influence.
In addition, some oils and fats can be used as conditioner and uses, yet, do not report also that up to the present itself and silicone oil have the effect of comparability, and consider that from the formulation stability that floods greasy addition is extremely low, even does not reach expected effect.
The employed first type surface activating agent that floods is alkyl sulfate or alkyl ether sulfate mostly; Yet under the trend of advocating " green, environmental protection " product, do not contain the product of alcohol ether, do not contain or contain the product of small amount of sulfur hydrochlorate, good product arises at the historic moment not contain silicone oil, natural reproducible and biological degradability.Yet up to the present also do not have a kind of shampoo not contain or contain the small amount of sulfur hydrochlorate, and do not contain silicone oil, and have good conditioning effect.
[summary of the invention]
Main purpose of the present invention is to provide a kind of conditioner shampoo that does not contain silicone oil, and this shampoo composite does not contain silicone oil and has and the corresponding conditioning characteristic of siliceous salted cake fried in sesame oil ripple compositions.
The present invention is achieved in that a kind of conditioner shampoo that does not contain silicone oil, and its component and content are:
(A) account for one group of surfactant of shampoo gross weight 10-30%;
(B) account for the microemulsion of shampoo gross weight 0.5-10%;
(C) account for the cation opsonizing agent of shampoo gross weight 0.05-1%;
(D) surplus is a water;
Said surfactant is: its degree of polymerization of non-ionic surface active agent of carbon 8 to carbon 14 alkyl polyglucoside is 1.4-1.7 and lauryl alcohol sulphuric acid amine and cocamido propyl betaine mixture, and three's ratio is 1: 1: 0.2 by weight percentage;
Said cation opsonizing agent is selected from a kind of in polyquaternary ammonium salt-5, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, the sub-glue of cationic cassia;
Said microemulsion is: the alkyl polyglucoside APG that (i) accounts for carbon 12 to the carbon 14 of microemulsion weight 8-25%; Its degree of polymerization 1.2-1.5; (ii) account for carbon 12 to the carbon 22 saturated or unsaturated fatty acids acid glycerides of microemulsion weight 2-12%, (iii) account for the grease of microemulsion weight 2-35%, (iv) excess water is formed.
The preferred Semen Cassiae glue of cation opsonizing agent according to the invention oxypropyl trimethyl ammonium chloride, its average nitrogen content are between 2% to 4.5%, and charge density is between 1.5meq/g to 3.5meq/g, and the viscosity of 1% aqueous solution is 100mPa.s to 2000mPa.s; Said saturated or unsaturated fatty acids acid glyceride is a diolein.
Shampoo composite of the present invention does not contain silicone oil, contains microemulsion and polymer, and through microemulsion (discharging a large amount of oil contents), be derived from the natural cation opsonizing agent and the synergistic function of surfactant, produce the good hair opsonic action.
[specific embodiment]
One group of related surfactant of shampoo composite among the present invention: comprise a kind of alkyl polyglucoside (Alkyl Polyglucosides, APG) non-ionic surface active agent, a kind of anion surfactant of non-ethoxylatedization and a kind of amphoteric surfactant at least.
This APG surfactant meets following general formula I:
R
1O(R
2O)b(Z)
Wherein, R1 is that carbon chain lengths is between 6 to 30 intermediary saturated alkyls; R2 represents carbon chain lengths between 2 to 4 unsaturated alkyl; Z represents a carbon chain lengths between 5 to 6 glycosyl; B represents 0 to 12 a numerical value; A represents a kind of numerical value of 1 to 6.Meet the alkyl polyglucoside of above general formula among the present invention, Z represents glucosyl group in the general formula, and b numerical value is zero.The surfactant of this alkyl polyglucoside class such as commercially available APG0810, APG0814, APG1214 is the trade mark of Shanghai Fakai Chemical Co., Ltd.:
1.APG0810-an alkyl polyglucoside, wherein to have comprised carbochain be 8 to 10 scope to alkyl, and average degree of polymerization is 1.7.
2.APG0814-an alkyl polyglucoside, wherein to have comprised carbochain be 8 to 14 scope to alkyl, and average degree of polymerization is 1.4.
3.APG1214-an alkyl polyglucoside, wherein to have comprised carbochain be 12 to 14 scope to alkyl, and average degree of polymerization is 1.4.
According to general formula I, be used for a kind of alkyl polyglucoside of more optimizing of the present invention, R in its formula
1For carbon chain lengths is the saturated alkyl of carbon 8 to carbon 14, b is zero, and the numerical value of a is 1.4 to 1.7, and polyglycoside surfactant activating agent use amount in the present invention is about percent 2 percentage by weights to being about percent 40 percentage by weights.
The anion surfactant of non-ethoxylatedization can comprise sodium alkyl benzene sulfonate, alkylsulfonate; Alkene sulfonate; The fatty acid hydroxyl acetate, acyl glutamate, alkyl phosphate; Fatty alcohol sulfosuccinate esters etc., the present invention preferably uses sodium lauryl sulphate and ammonium lauryl sulfate.
Said amphoteric surfactant is selected from, betaines, beta-amido propanoic acid class and imidazolines etc., preferred cocamido propyl betaine.
A kind of microemulsion of component among the present invention (B), its mean diameter be less than 1 micron, and the microemulsion among the present invention to be based on alkyl polyglucoside be that emulsifying agent is made.
The preparation of microemulsion, the first step at first, this microemulsion contains percent 10 alkyl polyglucoside to 20 percentage by weights, its general formula: R
1O-[Z]
a, wherein, R
1Representing carbon number is 4 to 22 alkyl or alkenyl, and it is 5 or 6 glycosyl that Z represents carbon number, and a represents 1 to 10 a numerical value; Comprise also that a kind of carbon 12 to carbon 22 comprises or the glyceride of unsaturated fatty acid, account for microemulsion percent 4 to 10 percentage by weights; Also comprise a kind of grease, account for microemulsion percent 5 to 30 percentage by weights, remaining is water, adds to absolutely percentage by weight.
The initial notion of microemulsion is, the outward appearance homogeneous, transparent, low viscous, thermodynamically stable two kinds of mutual exclusive liquid and at least a nonionic or a kind of ionic surfactant of containing.The mean diameter of microemulsion is usually less than 100 nanometers, has high transparent and change 2000 not have under minute centrifugal action, and at least 30 minutes centrifugal not stratified.
The preparation of microemulsion be through with the mixing of oil phase substance or oil soluble material and heating up to dissolving, add the aqueous phase substance that contains surfactant then, through suitable stirring, form the heating power stable microemulsion.
The composition of necessity that microemulsion comprised such as a kind of glucosides emulsifying agent, its general formula: R
1O-[Z] a, wherein, it is 4 to 22 alkyl or alkenyl that R1 represents carbon number, and it is 5 or 6 glycosyl that Z represents carbon number, and a represents 1 to 10 a numerical value; In addition, a represents the degree of polymerization (DP) in the general formula, as, sugared singly gathers; Dimerization, trimerization are 1 to 10 numerical value, in specified chemical compound to the distribution of poly etc.; A is integer always necessarily, but in a specific alkyl oligosaccharide, a is through the parameter that calculates, and is generally mark; And on the meaning of practical application, the degree of polymerization numerical value of alkyl polyglucoside is smaller or equal to 1.7, and further is optimized between 1.2 to 1.5.The amount of the alkyl polyglucoside that uses in the microemulsion of the present invention is between percent 8 percentage by weight to percent 25 percentage by weights, and the one-step optimization of going forward side by side is percent 10 percentage by weight to percent 20 percentage by weights, is based on the percentage ratio of microemulsion.
In addition; Carbon 12 to carbon 22 fatty glycerides that use in the microemulsion of the present invention are preferably the glycerol dibasic acid esters; And be the glycerol dibasic acid esters that has linear unsaturated fatty acid, the present invention is preferably glycerin bi-fatty acid ester, and INCI is called polyglycereol-6 dioleic acid ester; Its use amount accounts for microemulsion percent 2 percentage by weight to percent 12 percentage by weights, and the one-step optimization of going forward side by side is percent 5 percentage by weight to percent 9 percentage by weights.
At last; Involved in the present invention to microemulsion in also comprised the oils and fats that content accounts for microemulsion percent 2 percentage by weight to percent 35 percentage by weights; The greasy range of choice at room temperature is the liquid state except not containing silicone oil with requiring, and does not have special requirement, has no particular limits in the present invention.
The composition of microemulsion is following:
The cation opsonizing agent that uses among the present invention is preferably from the copolymer or the homopolymer (by name like INCI, polyquaternary ammonium salt-7) of acrylic or methacrylic acid amide or ester; The homopolymer of methacrylic acid ethyl-trimethyl salmiac (INCI is by name, polyquaternary ammonium salt-37), (INCI is by name for the quaternized copolymer of hydroxyethyl-cellulose and diallyl ammonio methacrylate; Polyquaternary ammonium salt-4), the polymer of hydroxyethyl-cellulose quaternary ammonium salt, wherein the ethoxy position of hydroxyethyl-cellulose is modified by epoxidation that (INCI is by name; Polyquaternary ammonium salt-10; Polyquaternary ammonium salt-67), by the Semen Cassiae gum derivative of quaternised depolymerization (INCI is by name, Semen Cassiae glue hydroxypropyl-trimethyl ammonium chloride); The quaternized copolymer of ampholyte copolymer (INCI is by name, polyquaternary ammonium salt-74) or quaternised guar derivative and hydroxyethyl-cellulose and diallyl alkyl dimethyl ammonium chloride.
The selection of cation opsonizing agent among the present invention, optimization is selected from polyquaternary ammonium salt-7, polyquaternary ammonium salt-10 and the sub-gum derivative of cationic cassia.The one-step optimization of going forward side by side is polyquaternary ammonium salt-10 and the sub-gum derivative of cationic cassia, because the sub-gum derivative of cationic cassia meets the demand of " green " more.
The sub-glue of said cationic cassia is the product that Semen Cassiae glue is obtained after quaternized; Its key component is a Semen Cassiae glue oxypropyl trimethyl ammonium chloride; Difference according to substitution value can obtain the sub-glue product of a series of cationic cassia, and preferred nitrogen content is 2% to 4.5%, charge density is between 1.5meq/g to 3.5meq/g.Be used for the sub-glue of cationic cassia of the present invention under 25 ℃ of conditions, the viscosity of its 1% aqueous solution is 100mPa.s to 2000mPa.s.
The use amount of cation opsonizing agent is optimized for 0.05 percent percentage by weight to percent 1 percentage by weight in the present composition.
A kind of conditioner shampoo that does not contain silicone oil of the present invention is formed as follows:
(a) alkyl polyglucoside, alkyl sulfate and cocamido propyl betaine;
(b) a kind of microemulsion comprises:
(b1) alkyl polyglucoside;
(b2) the saturated or unsaturated fatty acids acid glyceride of carbon 12 to carbon 22 chain lengths;
(b3) a kind of oils and fats;
(b4) deionized water;
(c) a kind of cation opsonizing agent is selected from polyquaternary ammonium salt-7, polyquaternary ammonium salt-10 and the sub-gum derivative of cationic cassia.
A kind of conditioner shampoo that does not contain silicone oil of the present invention is formed further optimization as follows:
(a) account for one group of surfactant that total composition is percent 5 percentage by weight to percent 20 percentage by weights, wherein, carbon 8 to carbon 14 alkyl polyglucoside (APG) average degree of polymerization is 1.5; Carbon 12 to carbon 14 alkylsurfuric acid ammonium and cocamido propyl betaine;
(b) account for a kind of microemulsion that total composition is percent 0.5 percentage by weight to percent 10 percentage by weights, wherein comprise:
(b1) account for the APG that the microemulsion total amount is percent 8 percentage by weight to percent 25 percentage by weights,, wherein APG is carbon 12 to carbon 14 alkyl polyglucoside, average degree of polymerization is 1.4, uses APG1214 among the present invention;
(b2) account for the fatty glyceride that the microemulsion total amount is percent 2 percentage by weight to percent 12 percentage by weights, wherein fatty glyceride does, the saturated or unsaturated fatty acids acid glyceride of carbon 12 to carbon 22 chain lengths uses glycerin bi-fatty acid ester among the present invention;
(b3) account for the oils and fats that the microemulsion total amount is percent 2 percentage by weight to percent 35 percentage by weights; Use oils and fats can derive from plant in the microemulsion of the present invention; Animal; Mineral or synthetic ester oil, greasy form is the restriction of liquid state under silicone oil and room temperature, does not have other restriction scope of application among the present invention;
(b4) residue percent 100 is a deionized water.
(c) account for a kind of cation opsonizing agent that the microemulsion total amount is 0.05 percent percentage by weight to percent 1 percentage by weight, be selected from polyquaternary ammonium salt-7, polyquaternary ammonium salt-10 and the sub-gum derivative of cationic cassia.
Embodiment
The composition of microemulsion among the present invention:
Shampoo formula and combing merit test result
Embodiment 1-5
Embodiment 6-10
Effect is estimated embodiment
Effect evaluation methodology for embodiment is divided into sensory evaluation method and two parts of cardability test.
Said sensory evaluation method is: will prepare embodiment 1-10 and issue 60 testers' uses respectively.According to the hair washing of identical method, every kind of shampoo used for two weeks when the tester used the shampoo sample, and the tester marks according to own feeling, standards of grading adopt to be made in 7 minutes, and 1 minute the poorest, and 7 minutes best, and the high more effect of mark is good more good more.Various shampoo composite result of use evaluation results are listed in table 1.
Table 1 shampoo composite result of use is estimated
Said cardability test comprises dried cardability, wet cardability test; Said wet cardability test is: at first with the hair moistening; Rub and wash 2-3min with 2g embodiment (1)-(10) (blank sample with 3% sodium laurylsulfate), rinse well with flowing water then, with the comb combing once to remove redundant moisture; On Instron 2343 miniature spring testers, measure wet cardability, rate of extension is 300mm/min; Repeat above-mentioned steps, each sample determination 6 times, the mensuration result after the 6th flushing of each embodiment lists in table 3.
Said dried cardability test is: after the cardability that wets test is accomplished hair sample is placed on air drying, treats its dry back its dried cardability of mensuration.The dried cardability test result of each embodiment is listed in table 3.
Table 3 shampoo composite cardability test result
Claims (3)
1. conditioner shampoo that does not contain silicone oil, its component and content are:
(A) account for one group of surfactant of shampoo gross weight 10-30%;
(B) account for the microemulsion of shampoo gross weight 0.5-10%;
(C) account for the cation opsonizing agent of shampoo gross weight 0.05-1%;
(D) surplus is a water;
Said surfactant is: the non-ionic surface active agent of carbon 8 to carbon 14 alkyl polyglucoside, its degree of polymerization are 1.4-1.7 and lauryl alcohol sulphuric acid amine and cocamido propyl betaine mixture, and three's ratio is 1: 1: 0.2 by weight percentage;
Said cation opsonizing agent is selected from a kind of in polyquaternary ammonium salt-5, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, the sub-glue of cationic cassia;
Said microemulsion is: the alkyl polyglucoside that (i) accounts for carbon 12 to the carbon 14 of microemulsion weight 8-25%; Its degree of polymerization 1.2-1.5; (ii) account for carbon 12 to the carbon 22 saturated or unsaturated fatty acids acid glycerides of microemulsion weight 2-12%, (iii) account for the grease of microemulsion weight 2-35%, (iv) excess water is formed.
2. the conditioner shampoo that does not contain silicone oil according to claim 1; It is characterized by the preferred Semen Cassiae glue of said cation opsonizing agent oxypropyl trimethyl ammonium chloride; Its average nitrogen content is between 2% to 4.5%; Charge density is between 1.5meq/g to 3.5meq/g, and the viscosity of 1% aqueous solution is 100mPa.s to 2000mPa.s.
3. the conditioner shampoo that does not contain silicone oil according to claim 1, it is characterized by said saturated or unsaturated fatty acids acid glyceride is diolein.
Priority Applications (1)
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|---|---|---|---|
| CN 201110207886 CN102327202B (en) | 2011-07-25 | 2011-07-25 | Conditioner shampoo without silicone oil |
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|---|---|---|---|
| CN 201110207886 CN102327202B (en) | 2011-07-25 | 2011-07-25 | Conditioner shampoo without silicone oil |
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| CN102327202B CN102327202B (en) | 2013-02-13 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102614096A (en) * | 2012-03-05 | 2012-08-01 | 珀莱雅(湖州)化妆品有限公司 | Conditioner shampoo composite |
| CN102920619A (en) * | 2012-10-09 | 2013-02-13 | 拉芳家化股份有限公司 | Conditioning shampoo composition containing small amount of sulfate anionic surfactant |
| CN104207966A (en) * | 2013-05-29 | 2014-12-17 | 拜尔斯道夫股份有限公司 | High-conditioning shampoo composition |
| CN104274358A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Scalp repair shampoo composition containing plant essential oil and preparation method thereof |
| CN104274359A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Hair care composition containing paramela plant essential oil |
| CN105147538A (en) * | 2015-09-21 | 2015-12-16 | 江苏素问化妆品有限公司 | Transparent bathing mousse free of silicone oil and preparation method thereof |
| CN106473994A (en) * | 2016-12-12 | 2017-03-08 | 德阳力久云智知识产权运营有限公司 | One kind no silicone oil Hair-loss-preventingshampoo shampoo and preparation method thereof |
| WO2019047000A1 (en) * | 2017-09-05 | 2019-03-14 | 拉芳家化股份有限公司 | Silicone-free shampoo containing zingiber zerumbet flower bud extract |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102614096A (en) * | 2012-03-05 | 2012-08-01 | 珀莱雅(湖州)化妆品有限公司 | Conditioner shampoo composite |
| CN102920619A (en) * | 2012-10-09 | 2013-02-13 | 拉芳家化股份有限公司 | Conditioning shampoo composition containing small amount of sulfate anionic surfactant |
| CN104207966A (en) * | 2013-05-29 | 2014-12-17 | 拜尔斯道夫股份有限公司 | High-conditioning shampoo composition |
| CN104274358A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Scalp repair shampoo composition containing plant essential oil and preparation method thereof |
| CN104274359A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Hair care composition containing paramela plant essential oil |
| CN104274358B (en) * | 2014-09-05 | 2017-07-18 | 拉芳家化股份有限公司 | A kind of scalp maintenance type hair-washing composition and preparation method containing plants essential oil |
| CN105147538A (en) * | 2015-09-21 | 2015-12-16 | 江苏素问化妆品有限公司 | Transparent bathing mousse free of silicone oil and preparation method thereof |
| CN106473994A (en) * | 2016-12-12 | 2017-03-08 | 德阳力久云智知识产权运营有限公司 | One kind no silicone oil Hair-loss-preventingshampoo shampoo and preparation method thereof |
| WO2019047000A1 (en) * | 2017-09-05 | 2019-03-14 | 拉芳家化股份有限公司 | Silicone-free shampoo containing zingiber zerumbet flower bud extract |
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| CN102327202B (en) | 2013-02-13 |
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