CN104207966A - High-conditioning shampoo composition - Google Patents
High-conditioning shampoo composition Download PDFInfo
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- CN104207966A CN104207966A CN201310205725.XA CN201310205725A CN104207966A CN 104207966 A CN104207966 A CN 104207966A CN 201310205725 A CN201310205725 A CN 201310205725A CN 104207966 A CN104207966 A CN 104207966A
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Abstract
The invention discloses a high conditioning shampoo composition without silicone oil, which comprises a surfactant, an acrylamide propyl trimethyl ammonium chloride/acrylamide copolymer, a cationic polymer, an emollient and water. The invention further discloses methods of cleansing and conditioning the hair by applying the high conditioning shampoo compositions. In addition, the invention also discloses the application of the high-conditioning shampoo composition in preparing a shampoo product for cleaning and conditioning hair.
Description
Technical field
The present invention relates to a kind of conditioning shampoo composition, particularly, relate to a kind of conditioning shampoo composition comprising surfactant, acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer, cationic polymer, emollient and water, described conditioning shampoo composition significantly can improve the conditioning performance to hair while clean hair.
Background technology
People continue to increase for the demand improving hair conditioning in hair care product formula.Especially, need washing the product requiring to possess while realizing cleaning action conditioning performance in hair products.
There are many shampoo composites that excellent clean hair and conditioning hair effect can be provided in the market, these shampoo composites overwhelming majority is containing silicone oil, i.e. type siloxane (comprising polysiloxane-based conditioner or derivatives thereof, modification conditioner etc.) siliceous conditioner, the excellent conditioning performance of type siloxane conditioner to hair is washed hair care industry and is generally acknowledged, hair washing product of being therefore grown up almost is monopolized by siliceous shampoo.
But these current products can not meet the demand of people well.Find in practical application, the long-term a large amount of hair washing product of silicone-containing that uses easily allows hair become stiff and greasy.The performance of conditioner shampoo depend on to a certain extent shampoo by conditioning polymer opposing in the process that washes away by the ability washed away, i.e. " adhesive force " of so-called conditioning ingredients.Adhesive force can guarantee the effect that conditioner shampoo reaches required.But too much attachment can cause silicone oil excessive buildup on hair and scalp after shampoo cyclic washing.This gathering can cause hair texture stiff and greasy, thus affects sensation that is submissive and conditioning, and usually reduces glossiness and plentiful sense.But then, although some oils and fats can use as conditioner, but oils and fats available in prior art still can not be comparable with silicone oil on conditioning effect, therefore the shampoo of silicone-containing class conditioner not can not get the accreditation of consumer for a long time because conditioning performance is not good.There is the compound action of good cleaning efficacy (comprising anti-dandruff effect) and conditioning performance simultaneously and be not easy to reach.Realization optimum balance therebetween for a long time people is expected always.
Summary of the invention
The present inventor proposes, for a kind of desirable conditioning shampoo composition, need consider to do, moist different aspect, comprise cardability and organoleptic attribute, particularly from following concrete aspect comprehensive consideration and its conditioning performance can be evaluated: good wet Comb rationality, rinse soft and smooth sense, dry sending out is gone entanglement, is sent out rough, the elegant performance of tail unhairing (not heavy), glossiness, etc.Based on above-mentioned Consideration, the present inventor passes through test of many times, find unexpectedly, the conditioning shampoo composition comprising surfactant, acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer, cationic polymer, emollient and water of the present invention can contribute to realizing excellent cleaning action and conditioning performance simultaneously, thus meets the demand.
Therefore, in first, the invention provides a kind of high conditioning shampoo composition, it comprises following component by weight:
A) surfactant of 5% to 50%;
B) the acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer of 0.01% to 0.5%;
C) cationic polymer of 0.01% to 1%;
D) emollient of 0.1% to 5%; With
E) appropriate water.
On the other hand, the present invention relates to method that is clean and conditioning hair, comprise the of the present invention high conditioning shampoo composition using effective dose to hair.In addition, the invention still further relates to the purposes of described high conditioning shampoo composition in the hair washing product for the preparation of clean and conditioning hair.
Conditioning shampoo composition of the present invention provides the good composition with cleaning action and conditioning performance.Conditioning shampoo composition of the present invention, can comprise those components optionally added.
Detailed description of the invention
Except as otherwise noted, otherwise all percent used herein all with the total weight of compositions.
The all components used in the present invention should be that skin is acceptable, namely can not cause unsuitable toxicity, incompatibility, unstability and atopic reaction etc. when contacting with the skin of people.
Term used herein " for hair washing product that is clean and conditioning hair " means to be intended to the hair washing for personal nursing and/or hair products, and it can provide the effects such as clean, the conditioning needed for it to object.
The surfactant comprised in conditioning shampoo composition of the present invention can be selected from one in anion surfactant, zwitterionic surfactant and non-ionic surface active agent or its combination in any.
surfactant
Conditioning shampoo composition of the present invention comprises and accounts for 5% to 50%, 5% to 25% of composition weight, and preferably 8% to 20%, 10% to 20%, the more preferably surfactant of 10% to 18%.Described surfactant can be compositions and brings cleaning action and frothing capacity.When anion surfactant, it can contribute to when dilute with water forming condensed phase.Believe that this cohesion contributes to providing effect of the present invention and opsonic action.
Described anionic surfactant component not only comprises common anion surfactant, is the zwitterionic surfactant of the coupling part of anionic property under being also included in the pH of compositions, or their combination.The example being applicable to the anion surfactant in compositions of the present invention includes but not limited to sulfate, sulfonate, sarcosinate and sarcosine derivative.Preferred anion surfactant is alkyl and alkyl ether sulfate.The example of alkyl sulfate has ammonium lauryl sulfate, cocoyl ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, sodium lauryl sulfate, sodium cocosulfate, lauryl sulfate monoethanolamine, cocoyl diethanolamine, lauryl sulfate diethanolamine, triethanolamine lauryl sulfate, lauryl sulfate triethylamine and composition thereof, particularly preferably is ammonium lauryl sulfate; The example of alkyl ether sulfate has lauryl polyethenoxy ether sodium sulfate, laureth potassium sulfate, sodium laureth sulfate, laureth diethanolamine, laureth sulfate, laureth sulphuric acid triethanolamine, laureth sulphuric acid triethylamine and composition thereof, particularly preferably is lauryl polyethenoxy ether sodium sulfate.The example of the anion surfactant of sulfonate comprises such as tridecyl benzene sulfonate, dodecylbenzene sodium sulfonate, lauryl sulfosuccinates etc.The example of sarcosine and sarcosine derivative comprises sodium lauryl sarcosinate, cocoyl sarcosine, cocoyl sarcosine and composition thereof, wherein preferred sodium lauryl sarcosinate.Other suitable anion surfactant is after the esterification of fatty acid isethionic acid, with in sodium hydroxide and after product, wherein fatty acids is as derived from cocos nucifera oil or palmitic fatty acid, or the fatty acid amide of methyl taurate or potassium salt.Other anion surfactants be suitable for are succinate, as the diamyl ester of N-disodium octadecyl sulfosuccinate, sodium sulfosuccinate, the dibutyl ester etc. of sodium sulfosuccinate.Other be suitable for anion surfactants be derived from amino acid whose those, include but not limited to N-acyl group-Pidolidone, N-acyl group sarcosine and salt thereof etc.In addition, suitable anion surfactant also can comprise taurine derivatives, such as 2-aminoethyl sulfonic acid, especially N-acyl-N-methyl taurine.
The amphoteric surfactant being applicable to high conditioning shampoo composition of the present invention is well known in the art, and those can be used for the material in hair nursing or other personal care cleansing compositions, as described in following patent documentation: United States Patent (USP) 5,104,646, United States Patent (USP) 5,106,609.These amphoteric surfactantes comprise the surfactant that those are secondary aliphatic amine and tertiary amines derived thing, wherein said aliphatic group can be the group of straight or branched, and one in described aliphatic group can containing 8-18 carbon atom of having an appointment, another can comprise a kind of anionic hydrophilic group as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.Be applicable to amphoteric surfactant of the present invention also comprise as aliphatic quaternary ammonium, quaternary phosphine and season sulfonium compound the surfactant of derivant, one of them aliphatic group containing 8-18 carbon atom of having an appointment, another can comprise a kind of anionic hydrophilic group as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.The preferably zwitterionic compound of betanin.Preferably betaines zwitterionic compound; comprise alkyl betaine, sulfobetaines, amidoalkyl betaine, amidosulfo betaines, hydroxyl sulfo betaine and composition thereof, especially cocoamidopropyl, Cocamidopropyl hydroxyl sulfo betaine, cocoyl dimethyl carboxymethyl betaine, cocoyl dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betanin, lauryl amide groups two-(2-ethoxy) propylsultaine betanin.Particularly preferably amide groups hydroxyl sulfo betaine, such as C
12-C
18hydrocarbyl amide base hydroxysultaine, especially C
12-C
14hydrocarbyl amide base hydroxysultaine, such as lauryl amidopropyl hydroxyl sulfo betaine and Cocamidopropyl hydroxyl sulfo betaine.The visible such as USP3 of other sulfobetaine type surfactant, 950,417.
The non-ionic surface active agent being applicable to high conditioning shampoo composition of the present invention is well known in the art, such as there is the compound of hydrophobic group and hydrogen atoms, the polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, spans, Tweens etc. of such as alkyl phenol.Particularly preferred non-ionic surface active agent is hydrogenated castor oils.
cationic polymer
The selection of the cationic polymer in the present invention and amount need make it be dissolved in shampoo composite, and are preferably dissolved in the complex coacervation mutually of shampoo composite when diluting.Preferably, when diluting shampoo composite (such as in washing process), between cationic polymer of the present invention and anion surfactant, condensed phase can be formed.Believe that the cationic moiety of polymer and the anionicsite of surfactant combine and form insoluble complex, they are precipitation (condensed phase) when diluting.The complex coacervation of cationic polymer can also be formed mutually together with other the optional anionic group in shampoo composite.The formation of condensed phase is usually relevant with factors such as molecular weight, concentration of component, ionic strength, charge density, pH.Effect about condensed phase system and these parameters is described in following document: J.Caelles etc., Cosmetics & Toiletries, the 106th volume 49-54 page in 1991; And D.J.Burgess, Journal of Colloid and Interface Science, nineteen ninety the 140th volume 227-238 page.All these documents are incorporated herein.
Believe that condensed phase can provide opsonic action, when particularly using product when hair moistening, by helping to provide conditioning effect by conditioning agent deposit to hair and scalp.
The content of present composition cationic polymer is by weight 0.01% to 1%, 0.02% to 1%, preferably 0.05% to 0.9%, more preferably 0.1% to 0.9%, particularly preferably 0.4 to 0.8%.
Cationic polymer in conditioning shampoo composition of the present invention can comprise following material: cationic polysaccharide, ethylene monomer copolymer, vinylpyrrolidone copolymer, cation-modified protein and some polymer quaternary salt.
cationic polysaccharide:
Cationic polysaccharide is based on C
5-C
6those polymer of sugar and on polysaccharide main chain grafted cation part and there is the derivant of cationic, comprise monomeric unit that quaternary ammonium or cationic amine replace and be optionally combined the homopolymer, copolymer, ter-polymers etc. that are formed with non-cationic monomer.Polysaccharide can be made up of the sugar of a type or more than one sugar.Cationic amine can be primary amine, secondary amine or tertiary amine (preferred secondary amine or tertiary amine), this depend on shampoo composite particular types and the pH value selected.Monomer can make straight or branched.The nonlimiting examples of cationic polysaccharide describes in the following documents: CTFA Cosmetic Ingredient Dictionary, the 3rd edition, 1982.The document is incorporated to herein by reference.
Cationic polymer comprises cationic cellulose and hydroxyethyl-cellulose; Cationic starch and hydroxyalkyl starch; Based on the cationic polymer being called the galactomannan of guar gum that the endosperm from Guar beans obtains; Based on the cationic polymer of Arabinose plant gum; Derived from the cationic polymer of xylose polymer; Derived from the cationic polymer of trehalose polymer; Derived from the cationic polymer (as inulin) of fructose polymer; Based on the cationic polymer (such as galacturonic acid and glucuronic acid) of the sugar containing acid; Based on the cationic polymer (as galactosamine and glycosamine) of osamine; Based on five and the cationic polymer of polyhydric alcohol of hexatomic ring; Based on the cationic polymer of galactose monomers; And based on the cationic polymer of mannosyl units; Etc..Preferably cationic cellulose and hydroxyethyl-cellulose; Cationic starch and hydroxyalkyl starch; Based on the cationic polymer of guar gum, and their mixture.
cationic cellulose derivative
Preferred cationic cellulose polymer includes but not limited to, can from Amerchol company with its series of polymers
with
buy those, as the salt of the epoxide reactive hydroxyethyl-cellulose replaced with trimethyl ammonium, in industry, be called what Polyquaternium10(such as obtained from Amerchol company
).The non-limiting example of the cationic cellulose of another kind of preferred type comprises the polymeric quaternary ammonium salts of the epoxide reactive hydroxyethyl-cellulose replaced with lauryl dimethyl ammonium, is called Polyquaternium24(such as from the Polymer that Amerchol company obtains in industry
).
Be applicable to the cellulose copolymer containing quaternary nitrogen of the hydroxyethyl-cellulose also having those and diallyldimethylammonium chloride to react of the present invention, in industry, be called what polyquaternium4(such as obtained from National Starch company
h-100).Be applicable to the cellulose ether containing quaternary nitrogen of the present invention be described in United States Patent (USP) 3962418, be applicable to of the present invention other the cellulose of etherificate and the copolymer of starch be described in United States Patent (USP) 3958581.Above-mentioned patent documentation is incorporated to herein all by reference.
cation melon that polymer
Being applicable to a cationoid polymer of the present invention is cation melon that polymer.Melon that is galactomannan (melon that) gum derivative of the replacement of positively charged.The molecular weight of these derivants is generally about 50, and 000 to about 2,500,000, preferably about 50,000 to about 1,000,000, more preferably from about 100,000 to about 350,000.Preferred your instantiation of polymer of concrete cation melon comprises:
c13S, its cationic charge density is that 0.8meq/g(obtains from Rhodia Company);
c17, its cationic charge density is that 1.6meq/g(obtains from Rhodia Company).Your polymer of other suitable cation melon comprises the cation melon that polymer of hydroxypropylation.Also have other suitable cationic polymer to comprise your copolymer of melon of etherificate, some of them example is described in United States Patent (USP) 3958581, and the present invention introduces this patent documentation as a reference.
Term " polymer " used herein " include material or the material (i.e. copolymer) having two kinds of monomer polymerizations to produce of a kind of monomer polymerization generation or be polymerized the material or naturally occurring polymer that produce by various of monomer.The cationic polymer preferably used in the present invention is cation guar gum, one or more in cassia gum Hydroxyproyl Trimethyl ammonia chloride, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, Polyquaternium-10, polyquaternary ammonium salt-11, Polyquaternium-67, polyquaternary ammonium salt-73, polyquaternary ammonium salt-74.
Preferably, the cationic polymer in the present composition be selected from cation guar gum, cassia gum Hydroxyproyl Trimethyl ammonia chloride, polyquaternary ammonium salt-7, Polyquaternium-10, Polyquaternium-67, hydroxypropyl emthylcellulose, polyquaternary ammonium salt-73 and polyquaternary ammonium salt-74 one or more.In an especially preferred embodiment, described cationic polymer is selected from polyquaternary ammonium salt-7 and Polyquaternium-10.
emollient
Being applicable to emollient of the present invention can be Vegetable oil lipoprotein or its modifier; Petroleum base fatty acid ester; Ethyoxyl alkyl esters; Ethoxylated fatty acid ester; Aliphatic alcohols; Polysiloxane-based or its mixture; The fatty acid ester of PEGization and the polysiloxane-based of PEGization; Skin moistening esters; And other skin moistening class material.The petroleum based emollient be suitable for comprises the hydrocarbon or its mixture that chain length is 16-32 carbon atom, and the petroleum base hydrocarbon with this chain length comprises mineral oil and vaseline; The fatty acid ester emollient be suitable for comprises C
12-C
28fatty acid, preferably C
16-C
22satisfied fatty acid and short chain (C
1-C
8, preferred C
1-C
3) the derivative emollient of single hydroxyl alcohol, the representative example of these esters comprises methyl palmitate, methyl stearate, dodecyl isopropyl ester, myristyl isopropyl ester, cetyl isopropyl ester and cetyl diethyl acetamidomalonate; The fatty acid ester emollient be suitable for also comprises by long-chain fatty alcohol (C
12-C
28, preferred C
12-C
16) and the ester that formed of short-chain fatty acid (such as lactic acid); The ethyoxyl alkyl ester emollients be suitable for comprises C
12-C
22ethoxylated fatty acid ester, its average degree of ethoxylation is about 2 to about 30, preferred described ethoxylated fatty alcohol ester emollient is selected from ethyoxyl dodecyl ester, cetyl ester and stearate, and preferred described ethyoxyl Arrcostab is ethoxylated dodecyl base ester, ethoxylated hexadecyl base ester, ethoxylation stearate etc.
In addition, emollient available in the present invention can also comprise the following: (a) silicone oil and modifier thereof, the polydimethylsiloxane of such as straight chain and ring-type, amino, alkyl, alkaryl and aryl silicone oil, b () oils, comprises natural oil lipid, such as Jojoba oil, soybean oil, sunflower oil, Testa oryzae oil, American Avocado Tree oil, almond oil, olive oil, Oleum sesami, peach kernel oil, Oleum Ricini, Oleum Cocois, ermine oil, cocoa butter, Adeps Bovis seu Bubali (fat), leaf fat, the sclerosis oils that above-mentioned oils hydrogenation obtains, and the monoglyceride of synthesis, diglyceride and triglyceride, such as myristin and 2 ethyl hexanoic acid glyceride, (c) wax class, such as Brazil wax, spermaceti, Cera Flava, lanoline and derivant thereof, (d) Hydrophobic plant extract, (e) hydro carbons, such as liquid paraffin (paraffin oil), vaseline, microwax, ceresine, Squalene and mineral oil, (f) higher fatty acids, such as lauric acid, myristic acid, Palmic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, lanoceric acid, isostearic acid, arachidonic acid and polyunsaturated fatty acid, (g) higher alcohol, such as lauryl alcohol, spermol, stearyl alcohol, oleyl alcohol, cholesterol, (h) esters, such as Octanoic acid, hexadecyl ester, Tetradecyl lactate, cetyl lactate, Semen Myristicae calculate isopropyl ester, isopropyl palmitate, adipic acid isopropyl ester, butyl stearate, decyl oleate, cholesterol isostearate, lactic acid alkane ester, citric acid alkyl esters and tartaric acid Arrcostab, (i) quintessence oil and extract thereof, such as Oleum menthae, Flos Jasmini Sambac oil, Oleum Camphora, bitter orange oil, Oleum Terebinthinae, Oleum Cinnamomi, oleum bergamottae, citrus unshiu Marcovitch oil, Oil of sweet flag, Oleum Pini, Oleum lavandula angustifolia, laurel, Oleum Caryophylli, cypress oil, Eucalyptus oil, Fructus Citri Limoniae oil, thyme oil, Oleum menthae, Oleum Rosae Rugosae, sage oil, Oleum sesami, oil of ginger, basil oil, oleum juniperi e baccarae, Indian oil of verbena, oil of rosemary, bois de rose oil, American Avocado Tree oil, grapefruit, Oleum Vitis viniferae, Myrrha, Fructus Cucumidis sativi oil, water fennel oil, Flos Inulae oil, linden flower oil, Amaranthus mangostanus L. chilli oil, algal oil, ginkgo oil, symphysis caul-fat, cupu oil, orange blossom oil, green tea oil, menthol, eucalyptole, Radix Oenotherae erythrosepalae oil, Camphora wet goods.
For the preferred emollient of the present composition be selected from following in one or more: Vegetable oil lipoprotein or its modifier, such as Fructus oleae europaeae fruit oil, Jojoba seed oil, Oleum Helianthi, Semen Tritici aestivi germ oil, Butyrospermum parkii fruit fat, Cremophor RH40, maleic acid modified Semen Ricini wet goods; Skin moistening esters, such as PEG-7 glyceryl cocoate, caprylic/capric triglyceride, C
12-13alcohol lactate, PPG-3 benzylic ether myristinate, glyceryl oleate etc.; Other skin moistening class materials, such as, in Sargassum polysaccharides, stearyl (dihydroxypropyl) Dimethyl Ammonium oligosaccharide, hydrogenated polydecene, PPG-3 Octyl Ether, methyl gluceth-20 one or more.
Particularly preferably, the emollient in the present composition be selected from PEG-7 glyceryl cocoate, stearyl (dihydroxypropyl) Dimethyl Ammonium oligosaccharide and PPG-3 Octyl Ether one or more.
water
In conditioning shampoo composition of the present invention, except said components and other auxiliary element, add to requirement with water (preferred deionized water).
In an especially preferred embodiment, high conditioning shampoo composition of the present invention comprises the component of following percetage by weight:
The laureth ammonium sulfate of 12%;
The coconut oleoyl amine MEA of 1.5%;
The polyquaternium-10 of 0.2% and the polyquaternium-7 of 0.8%;
Acrylamido propyl trimethyl ammonium chloride/the acrylamide copolymer of 0.05%;
The lauroylamidopropyl betaine of 5%;
The PPG-3 Octyl Ether of 0.3%;
The PEG-7 glyceryl cocoate of 2%; And
Appropriate water.
Particularly preferably, above-mentioned composition also can comprise appropriate citric acid, essence, sodium chloride and the component such as methylchloroisothiazandnone and Methylisothiazolinone.
optional components
High conditioning shampoo composition of the present invention also optionally comprise in following component one or more: dandruff removing agent, suspending agent, natural on-off cycles of hair growth regulator, antistatic additive, foam booster, viscosity modifier and thickening agent, pH adjusting agent, dyestuff, organic solvent or diluent etc.These components and amount thereof suitably can be selected according to the actual needs of product, and join in compositions of the present invention.
dandruff removing agent
Dandruff removing agent of the present invention can be the material with antimicrobial acivity, such as pyrithione, selenium sulfide, micronize sulfur and compositions thereof.Preferably pyrithione.The example of the dandruff removing agent of an indefiniteness is ketoconazole.
suspending agent
Can comprise in certain embodiments in high conditioning shampoo composition of the present invention and account for composition weight about 0.1% to about 10%, preferably about 0.3% to the suspending agent be applicable on hair or skin of about 5.0%, more preferably from about 0.3% to about 2.5%.The example of these suspending agents can include but not limited to: acyl derivative, long chain amine oxide, xanthan gum and composition thereof.The example that can be used on the suspending agent in shampoo composite of the present invention includes but not limited to: acyl derivative, long chain amine oxide, xanthan gum and composition thereof.These and other suitable suspending agents are described in further detail as follows.
1. acyl derivative and long chain amine oxide
Acyl group oxide suspending agent includes but not limited to: the long-chain ester of glyceride, long chain hydrocarbon, long-chain fatty acid, the long-chain ester of long chain alkanol amides.Other suitable suspending agents comprise long chain amine oxide.Acyl derivative and long chain amine oxide suspending agent are described in United States Patent (USP) 4741855.
Be glyceride for preferred acyl derivative of the present invention, comprise the glycol ester of the fatty acid with 16-22 carbon atom.More preferably ethylene glycol fatty acid, comprises monoesters and diester, most preferably comprises the diglycol stearate of the monostearate being less than about 7%.
Other are applicable in shampoo composite of the present invention be long chain hydrocarbon, comprise N, N-dialkyl amido benzoic acid and its soluble-salt (such as potassium salt and sodium salt).Non-limiting example as the suitable long chain amine oxide of suspending agent of the present invention comprises alkyl (C
16-C
22) dimethyl amine (such as stearyl dimethyl amine oxide).
2. xanthan gum
The suspending agent be applicable in the present invention also has xanthan gum.The concentration of xanthan gum is generally about 0.1% of composition weight to about 3%.
3. other suspending agents
Other suspending agents be applicable in shampoo composite of the present invention comprise carboxy vinyl polymer.Preferably with acrylic acid copolymer that polyallylsucrose is crosslinked, it is described in United States Patent (USP) 2798053.The example of these polymer comprises Carbopol934, and 940,941 and 956, can purchased from B.F.Goodrich company.
natural on-off cycles of hair growth regulator
Optionally growth regulator is comprised in compositions of the present invention.Described natural on-off cycles of hair growth regulator is the regulator of the natural on-off cycles of hair growth effect that can strengthen the present composition.Described " natural on-off cycles of hair growth adjustment " refers to the regulator comprising and can realize following effect: stimulate natural on-off cycles of hair growth and/or hair thickening; Prevention, minimizing, prevention and/or delay hair damage and/or hair tail off; Increase the speed of growth of hair; Bring out the formation of more bunch; Increase and send out bunch diameter; Make to send out bunch elongated; Hair growth, and their combination.Its non-limiting example includes but not limited to vasodilation, androgen antagonist, immunosuppressant, antimicrobial etc.
antistatic additive
Operable optional antistatic additive is such as water-insoluble cationic surfactant, and its concentration is generally 0.1% of composition weight to about 5%.Such antistatic additive answers serviceability and the benefit of the high conditioning shampoo composition of not obvious impact; Especially, described antistatic additive should not disturb anion surfactant.The concrete non-limiting example of suitable antistatic additive is three cetyl ammonio methacrylates.
foam booster
Optional foam booster for high conditioning shampoo composition of the present invention comprises fatty alkanol amide, particularly C
1-C
3alkanolamide.The concrete non-limiting example of such foam booster comprises coconut monoethanol amide, cocos nucifera oil diglycollic amide and composition thereof.
viscosity modifier and thickening agent
Usually be used for, in high conditioning shampoo composition of the present invention, making overall viscosity be about 1 with available phosphorus for the optional viscosity modifier of high conditioning shampoo composition of the present invention and thickening agent, 000 centistoke is to about 20,000 centistoke, preferably about 3,000 centistoke to about 10,000 centistoke.The concrete non-limiting example of this viscosity modifier and thickening agent comprises sodium chloride, sodium sulfate and composition thereof.
production method
High conditioning shampoo composition of the present invention can by any known or other be effectively suitable for providing the technology of shampoo composite to prepare, prerequisite is that resulting composition provides conditioning performance outstanding as described in the present invention.The method preparing high conditioning shampoo composition of the present invention comprises conventional preparation and hybrid technology.Such as, can with reference to the such as method described in United States Patent (USP) 5837661.
using method
On the other hand, present invention also offers a kind of method with conditioning hair that cleans, described method comprises the of the present invention high conditioning shampoo composition using effective dose to hair and/or scalp.Specifically, high conditioning shampoo composition of the present invention uses with clean and conditioning hair or skin usual manner.Described compositions can be coated on the hair of moistening in advance (usually using water) or other positions of health, then by compositions rinsing or rinse out.The scope of the compositions of effective dose is generally about 1 gram to about 50 grams, preferably about 1 gram to about 20 grams.Be applied to hair to generally include compositions rubbed in hair and smear, thus make major part or all hair contact with compositions.
Specifically comprise the steps: that (a) is by Hair grooming water-wet for method that is clean and conditioning hair; B the shampoo composite of effective dose is applied on hair by (), and (c) uses water from rinsing shampoo composite hair.These steps can repeatedly repeatedly, to reach the effects such as sought clean, conditioning and anti-dandruff.
purposes
The invention still further relates to the purposes of described high conditioning shampoo composition in the hair washing product for the preparation of clean and conditioning hair.The present inventor is found by research, uses the present composition significantly can improve the skin condition performance of product; More unexpectedly, shampoo composite of the present invention has excellent cleaning action and conditioning performance simultaneously, comprises and hair gloss degree can be made to be significantly improved, make that hair is smooth more easily to be arranged, effectively can remove entanglement when hair rinses, effectively prevent hair short-tempered, etc.
Embodiment
It is below the non-limiting example of high conditioning shampoo composition of the present invention.Providing of these embodiments is only for illustrative purposes, and should not be construed as limitation of the invention.It will be understood by those skilled in the art that and without departing from the spirit and scope of the present invention, many changes and adjustment can be carried out to the present invention.In description of the present invention and following instance, unless stated otherwise, all concentration is all percetage by weight." a small amount of material " refers to those optional materials, as antiseptic, viscosity modifier, pH adjusting agent, spice, foam booster etc.Those skilled in the art are very clear, change along with the selected physicochemical property for the preparation of specific components of the present invention the selection of these a small amount of materials.
The preparation method of the high conditioning shampoo composition of the embodiment of the present invention is as follows: for the preferred shampoo A in comparative study, A phase component mix and blend is heated to 75-80 DEG C in agitated kettle to continue to keep stirring to make its mix homogeneously in 15 minutes, B phase component mix and blend is heated to 60-65 DEG C in another agitated kettle to continue to keep stirring to make its mix homogeneously in 15 minutes, after making the A phase component of mix homogeneously cool to 60-65 DEG C, the B phase component of mix homogeneously and A phase component mixing and stirring are cooled to 40-45 DEG C, C phase component is added one by one after in the mixture of A and B phase and stir 30 minutes, namely the shampoo I in table 1 is obtained.
1. prepare example I-XI
Obtain example I-IV, EXAMPLE V-VIII and the example I X-XI of following composition as stated above:
Embodiment: I-IV
Embodiment: V-VIII
Embodiment: Ⅸ-Ⅺ
2. effect example (conditioning effect evaluation)
Prepared example I-XI and the preferred embodiment of the present invention (shampoo A) effect relative to contrast shampoo B-D is have rated by comparative study.
The preferred embodiments of the present invention shampoo A and comparative example shampoo D
The preparation method of preferred shampoo A and comparative example shampoo D as previously mentioned.
Comparative example shampoo B and C is the commercially available prod containing siloxanes.
Comparative example shampoo B: Pantene plant quintessence water profit gloss shampoo: containing dimethiconol; Comparative example shampoo C: Shi Hua cool water-setting collagen maintenance shampoo: containing PEG-12 polydimethylsiloxane.
Evaluation methodology:
Effect evaluation method for embodiment I-Ⅺ is: the shampoo of preparation embodiment, and use topknot to carry out the marking evaluation of multinomial test index to each shampoo by 10 appraisers through professional training, concrete evaluation methodology step is as follows:
1. buy the unified standard topknot made from professional institution;
2. by each evaluator, topknot is numbered;
3. pretreatment, to blank sample marking An1: the water of thermostatic water bath is adjusted to 40 DEG C, open constant flow pump, rinse topknot 30 seconds, then use the unified certain density surfactant prepared in advance of 1ml to rub topknot 1 minute, then rinse topknot 1 minute, to corresponding each test index marking (1 to 10 points, score value is more high better), dry up rear to dry marking evaluation;
4. evaluate shampoo marking An2: the water of thermostatic water bath is adjusted to 40 DEG C, opens constant flow pump, flushing topknot 30 seconds, then use 1ml shampoo rubs topknot 1 minute, then rinses topknot 1 minute, to corresponding each test index marking, dries up rear marking to dry and evaluates;
5. draw the indices score (An2-An1) of shampoo to this topknot;
6. use another root topknot to repeat step 3,4,5, each shampoo uses 6 topknots altogether;
7. pair each evaluation index gets the final meansigma methods of 6 topknots as evaluation result.
| ? | Ⅰ | Ⅱ | Ⅲ | Ⅳ | Ⅴ | Ⅵ | Ⅶ | Ⅷ | Ⅸ | Ⅹ | Ⅺ |
| Flushing goes to tangle | 2.54 | 5.35 | 6.43 | 5.86 | 6.46 | 6.54 | 6.15 | 6.47 | 6.89 | 7.25 | 7.64 |
| Rinse soft and smooth sense | 3.22 | 5.56 | 6.45 | 6.15 | 6.53 | 6.65 | 6.35 | 6.63 | 6.78 | 6.89 | 7.20 |
| Wet sending out goes to tangle | 2.86 | 5.46 | 6.35 | 6.12 | 6.44 | 6.49 | 6.12 | 6.35 | 6.88 | 7.12 | 7.35 |
| Wet Comb reason | 2.87 | 5.12 | 5.89 | 6.12 | 5.98 | 6.12 | 5.71 | 6.25 | 6.35 | 6.78 | 7.24 |
| Wet send out sense submissive | 3.25 | 5.86 | 6.23 | 6.05 | 6.27 | 6.37 | 6.23 | 6.35 | 6.64 | 7.12 | 7.45 |
| Dry sending out goes to tangle | 4.21 | 5.56 | 5.78 | 5.56 | 5.88 | 5.89 | 5.55 | 6.13 | 6.58 | 7.11 | 7.23 |
| Dry comb | 4.35 | 5.89 | 6.02 | 5.98 | 5.78 | 5.98 | 5.86 | 6.11 | 6.69 | 6.98 | 7.26 |
| Dry send out sense submissive | 4.56 | 4.78 | 4.89 | 4.85 | 4.86 | 4.78 | 4.65 | 5.02 | 5.89 | 6.53 | 6.98 |
| Dry luminous pool | 4.64 | 5.26 | 5.56 | 5.65 | 5.63 | 5.65 | 5.35 | 5.78 | 6.56 | 7.23 | 7.34 |
Effect evaluation method for embodiment shampoo A and comparative example shampoo B, C, D is: prepare embodiment shampoo A and comparative example shampoo D, shampoo B and C is bought in large supermarket, by the salon tester of professional training, the hair of every tester of one group of 8 consumer is evenly divided into left half a head and right half a head, a kind of shampoo is respectively used to wash hair to the left side half a head of the same consumer and the right half a head respectively, wash rear to the left side and the right hair carry out evaluation marking, standards of grading adopt ten point system, 1 point the poorest, 10 points best, and mark is more high better.
| ? | Shampoo A | Shampoo D | ? | Shampoo A | Shampoo B | ? | Shampoo A | Shampoo C |
| Flushing goes to tangle | 7.85 | 7.35 | ? | 7.78 | 7.65 | ? | 7.69 | 7.35 |
| Rinse soft and smooth sense | 8.26 | 7.52 | ? | 7.98 | 7.24 | ? | 7.96 | 7.54 |
| Wet sending out goes to tangle | 7.89 | 7.68 | ? | 7.86 | 7.55 | ? | 7.82 | 7.63 |
| Wet Comb reason | 7.65 | 7.78 | ? | 7.67 | 7.65 | ? | 7.76 | 7.65 |
| Wet send out sense submissive | 7.68 | 7.65 | ? | 7.75 | 7.65 | ? | 7.87 | 7.78 |
| Dry sending out goes to tangle | 7.56 | 7.54 | ? | 7.54 | 7.56 | ? | 7.65 | 7.21 |
| Dry comb | 7.65 | 7.68 | ? | 7.63 | 7.65 | ? | 7.68 | 7.64 |
| Dry send out sense submissive | 7.89 | 7.56 | ? | 7.89 | 7.64 | ? | 7.96 | 7.62 |
| Dry luminous pool | 8.25 | 7.86 | ? | 7.84 | 7.78 | ? | 7.85 | 7.66 |
| Elegant not heavy | 8.56 | 7.25 | ? | 8.25 | 7.53 | ? | 8.36 | 7.64 |
Effect for embodiment shampoo A and comparative example shampoo B and C amplifies evaluation methodology: preparation embodiment shampoo A, shampoo B and C is bought in large supermarket, shampoo A, B, C are filled to the special test Packaging Bottle 160 bottles of 200ml, transferred to by test sample professional research company to issue test population comparisons to use, professional test personnel design questionnaire on probation, use during shampoo sample and wash hair according to identical method, shampoo uses two weeks at least continuously, and answers professional questionnaire.Tester according to oneself feel mark.Standards of grading adopt 7 points of systems, and 1 point the poorest, and 7 points best, and mark is more high better, ensure that efficient recovery 120 parts carries out statistical summaries.
Following table is that respondent is to product cohersive and integrated data.
| ? | Shampoo A | Shampoo B | Shampoo C |
| Overall assessment | 5.23 C | 5.03 | 4.96 |
| The purchase intention of brandless prompting | 5.38 | 5.18 | 5.09 |
| There is the purchase intention that brand is pointed out | 5.42 | 5.23 | 5.17 |
| Make your hair more plentiful | 5.10 | 4.93 | 5.03 |
| Obviously your hair quality tough | 5.07 | 4.88 | 4.83 |
| Allow your hair particularly soft | 5.29 | 5.19 | 5.05 |
| Make to dry in the air (blowing) dry after hair especially easily combing | 5.43 | 5.25 | 5.28 |
| Clean hair as mild as a dove | 5.48 | 5.34 | 5.46 |
| To gloss as your hairline | 5.08 | 5.00 | 4.96 |
| Effectively can nurse your hair | 5.28 | 5.21 | 5.06 |
| Make wet especially easily combing | 5.13 | 5.19 | 5.13 |
| Do not hang down heavy, very elegant with rear hair | 5.35 B | 5.00 | 5.13 |
| Make your dry to feel and feel comfortable | 5.38 | 5.24 | 5.27 |
| Damaged hair can be repaired | 4.91 | 4.68 | 4.68 |
| Hair is looked well | 5.25 | 5.15 | 5.16 |
| Be very easy to rinse | 5.58 | 5.35 | 5.34 |
| Your hair can be protected not dry up | 5.22 | 4.98 | 5.07 |
| To your hair and scalp as mild as a dove | 5.55 BC | 5.23 | 5.15 |
| Make your wet to feel and feel comfortable | 5.37 | 5.15 | 5.18 |
| Thoroughly can clean hair | 5.51 | 5.37 | 5.34 |
| Your hair and scalp health can be kept | 5.32 BC | 5.04 | 5.00 |
| Quality is very high | 5.05 | 4.87 | 4.80 |
| Deep layer can nourish hair | 5.08 | 4.86 | 4.88 |
| Effectively can moisten hair | 5.10 | 4.93 | 4.91 |
| Scalp can be nourished | 5.01 | 4.83 | 4.82 |
| Effectively can remove hair during flushing to tangle | 5.18 | 4.96 | 4.99 |
| Hair is made to become smooth especially | 5.23 | 5.08 | 5.02 |
| Hair can be helped to keep moisture content | 5.05 | 4.91 | 4.99 |
| Can effectively prevent hair short-tempered | 5.06 | 4.85 | 5.00 |
| Can effectively prevent hair from producing electrostatic | 4.98 | 4.86 | 4.95 |
| After flushing, hair is not sticky | 5.58 B | 5.30 | 5.37 |
| Hair unlike at ordinary times, dirty so soon | 5.26 BC | 4.97 | 4.93 |
| Can effectively prevent hair from disorderly sticking up/making hair docile | 5.21 | 5.09 | 5.01 |
Note: the two-tailed test under the confidence level of 95%, subscript B or C represents there is significant difference relative to reference product B or C respectively
According to above result, high conditioning shampoo composition of the present invention clean persistency, not sticky, keep hair with in scalp health, elegant sense and mildness etc. with containing type siloxane as conditioner reference product compared with there is significant difference, and score in other respects is also all better than reference product substantially, in overall assessment, with reference product, there is significant difference, show excellent conditioning performance.
Claims (14)
1. a high conditioning shampoo composition for not silicate-containing oil, it comprises following component by weight:
A) surfactant of 5% to 50%;
B) the acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer of 0.01% to 0.5%;
C) cationic polymer of 0.01% to 1%;
D) emollient of 0.1% to 5%; With
E) appropriate water.
2. high conditioning shampoo composition according to claim 1, wherein said surfactant is selected from least one in anion surfactant, zwitterionic surfactant and non-ionic surface active agent or its mixture.
3., according to the high conditioning shampoo composition of claim 1 or 2, the content of wherein said surfactant is by weight 5% to 25%, preferably 8% to 20%, more preferably 10% to 18%.
4. the high conditioning shampoo composition any one of claims 1 to 3, wherein said cationic polymer be selected from cation guar gum, cassia gum Hydroxyproyl Trimethyl ammonia chloride, polyquaternary ammonium salt-7, Polyquaternium-10, Polyquaternium-67, hydroxypropyl emthylcellulose, polyquaternary ammonium salt-73 and polyquaternary ammonium salt-74 one or more.
5. the high conditioning shampoo composition of claim 4, wherein said cationic polymer is selected from polyquaternary ammonium salt-7 and Polyquaternium-10.
6. the high conditioning shampoo composition any one of claim 1 to 5, the content of wherein said cationic polymer is by weight 0.02% to 1%, preferably 0.05% to 0.9%, more preferably 0.1% to 0.9%, particularly preferably 0.4 to 0.8%.
7. the high conditioning shampoo composition any one of claim 1 to 6, the content of wherein said acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer is by weight 0.02% to 0.4%, preferably 0.03% to 0.1%, more preferably 0.04% to 0.07%, particularly preferably 0.05%.
8. the high conditioning shampoo composition any one of claim 1 to 7, wherein said emollient be selected from following material one or more: Vegetable oil lipoprotein or its modifier, such as Fructus oleae europaeae fruit oil, Jojoba seed oil, Oleum Helianthi, Semen Tritici aestivi germ oil, Butyrospermum parkii fruit fat, Cremophor RH40 and maleic acid modified Oleum Ricini; Skin moistening esters, such as PEG-7 glyceryl cocoate, caprylic/capric triglyceride, C
12-13alcohol lactate, PPG-3 benzylic ether myristinate and glyceryl oleate; Other skin moistening class materials, such as Sargassum polysaccharides, stearyl (dihydroxypropyl) Dimethyl Ammonium oligosaccharide, hydrogenated polydecene, PPG-3 Octyl Ether and methyl gluceth-20.
9. high conditioning shampoo composition according to claim 8, wherein said emollient is selected from PEG-7 glyceryl cocoate, stearyl (dihydroxypropyl) Dimethyl Ammonium oligosaccharide and PPG-3 Octyl Ether.
10. the high conditioning shampoo composition any one of claim 1 to 9, the amount of wherein said emollient is 1.0%-4.0%, preferred 1.5%-3.5%, more preferably 2.0%-3.0%.
11. high conditioning shampoo compositions any one of claim 1 to 10, it also comprises one or more in following component: dandruff removing agent, suspending agent, natural on-off cycles of hair growth regulator, antistatic additive, foam booster, viscosity modifier and thickening agent, pH adjusting agent, dyestuff, organic solvent and diluent.
12. high conditioning shampoo compositions according to claim 1, it comprises the component of following percetage by weight:
The laureth ammonium sulfate of 12%;
The coconut oleoyl amine MEA of 1.5%;
The polyquaternium-10 of 0.2% and the polyquaternium-7 of 0.8%;
Acrylamido propyl trimethyl ammonium chloride/the acrylamide copolymer of 0.05%;
The lauroylamidopropyl betaine of 5%;
The PPG-3 Octyl Ether of 0.3%;
The PEG-7 glyceryl cocoate of 2%; And
Appropriate water.
The method of 13. 1 kinds of clean and conditioning hairs, comprises the high conditioning shampoo composition any one of claim 1 to 12 using effective dose to hair.
The purposes of high conditioning shampoo composition any one of 14. claim 1 to 12 in the hair washing product for the preparation of clean and conditioning hair.
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| CN104940071A (en) * | 2015-06-25 | 2015-09-30 | 广州保税区雅兰国际化妆品有限公司 | Mild antidandruff shampoo and preparation method thereof |
| CN106074215A (en) * | 2016-07-25 | 2016-11-09 | 深圳市美福源日用品有限公司 | A kind of plasticine bath shampoo |
| CN106265167A (en) * | 2016-09-30 | 2017-01-04 | 广州赛莱拉干细胞科技股份有限公司 | A kind of compositions and shampoo and preparation method thereof |
| CN106309287A (en) * | 2016-10-20 | 2017-01-11 | 黛普（上海）贸易有限公司 | Ginger hair-growing shampoo and preparation method thereof |
| CN106420407A (en) * | 2016-08-31 | 2017-02-22 | 福建省梦娇兰日用化学品有限公司 | Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil |
| CN106619277A (en) * | 2016-11-15 | 2017-05-10 | 东莞自然衡健康科技有限公司 | Silicone oil-free grease control anti-hair loss shampoo |
| CN106852766A (en) * | 2017-01-11 | 2017-06-16 | 广州温雅日用化妆品有限公司 | Shampoo composition |
| CN108186421A (en) * | 2018-03-28 | 2018-06-22 | 广州禾力生物科技有限公司 | A kind of conditioning shampoo composition containing Thallus Laminariae (Thallus Eckloniae) extract and preparation method thereof |
| WO2018152718A1 (en) * | 2017-02-23 | 2018-08-30 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | Silicone-free shampoo composition |
| CN109464299A (en) * | 2018-12-26 | 2019-03-15 | 拉芳家化股份有限公司 | A kind of for a long time more fragrant excellent hair conditioning shampoo composite |
| CN111053706A (en) * | 2020-02-17 | 2020-04-24 | 澳宝化妆品（惠州）有限公司 | Self-heating pre-wash hair care composition |
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| WO2021102714A1 (en) * | 2019-11-27 | 2021-06-03 | Beiersdorf Daily Chemical (Wuhan) Co., Ltd. | A conditioning composition |
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| CN104940071A (en) * | 2015-06-25 | 2015-09-30 | 广州保税区雅兰国际化妆品有限公司 | Mild antidandruff shampoo and preparation method thereof |
| CN106074215A (en) * | 2016-07-25 | 2016-11-09 | 深圳市美福源日用品有限公司 | A kind of plasticine bath shampoo |
| CN106420407A (en) * | 2016-08-31 | 2017-02-22 | 福建省梦娇兰日用化学品有限公司 | Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil |
| CN106265167A (en) * | 2016-09-30 | 2017-01-04 | 广州赛莱拉干细胞科技股份有限公司 | A kind of compositions and shampoo and preparation method thereof |
| CN106309287A (en) * | 2016-10-20 | 2017-01-11 | 黛普（上海）贸易有限公司 | Ginger hair-growing shampoo and preparation method thereof |
| CN106619277A (en) * | 2016-11-15 | 2017-05-10 | 东莞自然衡健康科技有限公司 | Silicone oil-free grease control anti-hair loss shampoo |
| CN106852766A (en) * | 2017-01-11 | 2017-06-16 | 广州温雅日用化妆品有限公司 | Shampoo composition |
| WO2018152718A1 (en) * | 2017-02-23 | 2018-08-30 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | Silicone-free shampoo composition |
| CN108186421A (en) * | 2018-03-28 | 2018-06-22 | 广州禾力生物科技有限公司 | A kind of conditioning shampoo composition containing Thallus Laminariae (Thallus Eckloniae) extract and preparation method thereof |
| CN109464299A (en) * | 2018-12-26 | 2019-03-15 | 拉芳家化股份有限公司 | A kind of for a long time more fragrant excellent hair conditioning shampoo composite |
| WO2021102714A1 (en) * | 2019-11-27 | 2021-06-03 | Beiersdorf Daily Chemical (Wuhan) Co., Ltd. | A conditioning composition |
| CN111053706A (en) * | 2020-02-17 | 2020-04-24 | 澳宝化妆品（惠州）有限公司 | Self-heating pre-wash hair care composition |
| CN111632016A (en) * | 2020-07-15 | 2020-09-08 | 云南柏莎健康产业有限公司 | Rose-fragrance-type bioactive hair-washing and hair-protecting antibacterial liquid |
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