CN101716130A - Hair-care product composition containing oil-in-water nanometer coating active components - Google Patents
Hair-care product composition containing oil-in-water nanometer coating active components Download PDFInfo
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Abstract
The invention relates to a daily chemical product, in particular to a hair-care product composition. The hair-care product composition containing oil-in-water nanometer coating active components also contains oil-in-water nanometer emulsion of which the weight is 3 to 25 percent of that of the composition, besides hair-care basic components; and the nanometer emulsion comprises a group of emulsifiers of which the weight is 3 to 8 percent of that of the nanometer emulsion, a group of base grease components of which the weight is 17 to 25 percent of that of the nanometer emulsion, and a group of fat soluble hair repairing components of which the weight is 0.1 to 5 percent of that of the nanometer emulsion. The hair-care product composition has effects of caring and regulating hair in depth, for example, the hair-care product composition ensures that the hair is soft, bright and easily shaped for a long time and has much more texture and energy.
Description
Technical field
The present invention relates to a kind of cosmetics of everyday use, be specifically related to a kind of hair-care product composition.
Background technology
Hair-care product such as hair conditioner are the products that is used for hair conditioning and nursing that has been widely used and has accepted.As use the hair behind the hair conditioner can obviously experience submissive.In addition, use hair conditioner that hair is washed easily, do not tie a knot, be easy to combing etc.
The earliest people use cationic surfactant as, quarternary ammonium salt compound often is used to the hair conditioner product, the characteristic of cationic surfactant is that its surface activity concentrates on cation one end that molecule has positive electricity.Therefore, in actual applications, the cationic surfactant that has positive charge is adsorbed in the hair surface that has negative charge.In addition, cationic surfactant has relatively low dissolubility and have bigger molecular weight, dissociates out easily from aqueous matrixes such as hair conditioner or shampoo and is deposited on the hair.All these characteristics make that cationic surfactant such as quarternary ammonium salt compound are particularly suitable for using as cation opsonizing agent in the products such as hair-care product such as hair conditioner.
The cationic quaternary ammonium salt compound has one, and two or three chain alkyls also are connected to an end of nitrogen-atoms.Usually chain alkyl comprises the carbon chain lengths that has 12 to 24 carbon atoms.
Make hair soft and reduce the electrostatic accumulation of hair relevant with the carbochain number that the nitrogen-atoms head end is connected with the cationic surfactant carbon chain lengths.Usually carbochain is long more, and the carbochain number that is connected with the nitrogen-atoms head end is many more, and is good more with the electrostatic ability of hair in the cation, and the compliant characteristic performance is also just good more.
Hair conditioner and shampoo are the branch use of coming the earliest, and afterwards, consumer pursued convenient, wish hair conditioner and shampoo are united two into one, so just had 2 to close 1 recuperating shampoo.2 close 1 recuperating shampoo comprises two kinds of surfactant compositions with cleaning action and opsonic action, in the time of the cleaning hair cation is stayed on the hair.Therefore just need after washing hair, not use hair conditioner.Along with 2 acceptance of closing 1 shampoo market constantly increase, 21 technology of closing have obtained continuous development, the use of conditioner no longer has been limited to cationic surfactant, so, just there has been cationic surfactant to be used silicone oil or silicone compounds and closed the homophony reason composition of 1 shampoo, and used till today always as hair conditioner or 2.
By we find to the analysis of above Hair grooming conditioner: no matter be that hair conditioner or 2 closes 1 shampoo at present, wherein all more or less interpolation two kinds the conditioning compositions, a kind of is to belong to one of cationic surfactant series, a kind of one of silicone compounds series that belongs to.Cationic surfactant can be preferably in and the static in the hair, silicone compounds can provide hair to do preferably, wet comb property.Yet, no matter what use in the hair conditioner is the silicone compounds that cationic surfactant also is to use, all has larger molecular weight, the viscosity scope of especially employed silicone compounds is from 60000 centistoke to 1000000 centistokes, thereby they more are by macromole the effect that the frictional resistance that reduces hair plays conditioning to be played in the covering of hair surface.
Yet, no matter be cation by to the Electrostatic Absorption of hair or silicone compounds macromole parcel to hair, their roles all are to cover the effect of playing soft and smooth opsonic action and preventing hair bifurcated or mechanical injuries by the surface adsorption to hair, and hair quality itself is not had the effect of real maintenance, this is that the hair-care product that life-time service contains cation and silicone compounds makes the hair generation gather easily because high molecular surface coverage has stoped the percdation and the maintenance (seeing also " distortion of hair pulling force and surface electrostatic The Characteristic Study 2008 ") of active ingredient.
In addition, although have numerous conditioning compositions, because hair often uses shampoo to clean and nurse one's health, the natural oil on hair scale surface also can run off thereupon, the substitute is some chemosynthesis high molecular cationic polymer and polysiloxanes.Therefore, make hair behind the life-time service hair care conditioning products occur gathering, heavy, be clamminess and make the withered negative effect of hair etc.
In view of above factor, the inventor has done a large amount of discovering: when a kind of hair-care product not only uses above-described macromolecular conditioner but also uses micromolecular hair nursing composition (as nanometer maintenance composition), can remedy the technological deficiency that existing hair-care product exists well.
Summary of the invention
The purpose of this invention is to provide a kind of Haircare composition of washing that remarkable nursing efficacy can be provided.
Technical scheme of the present invention is achieved in that a kind of hair-care product composition of oil-in-water nanometer coating active components, said composition is except that containing the hair nursing solvent, contain also that to account for composition weight percentage ratio be 3% to 25% nanoemulsions, in this nanoemulsions, comprising:
One group of emulsifying agent, this emulsifier content account for nanoemulsions percentage by weight 3%-8%;
It is 17% to 25% that one group of basic grease composition, fat content account for the nano-emulsion percentage by weight;
It is than 0.1%-5% that one group of fat-soluble hair maintenance composition, this component content account for the nanoemulsions weight percent;
Wherein said emulsifying agent comprises two kinds of amphiphilic surfactants, it is liquid non-ionic amphiphilic surfactant that wherein a kind of amphiphilic surfactant requires below 45 degree, the following non-ionic amphiphilic surfactant for liquid state of 45 degree is a kind of mixing esters that comprises a hydroxy compounds at least, the hydroxy compounds that this mixing esters is comprised is by saturated or unsaturation, to be carbon 8 obtain through carrying out esterification with the Polyethylene Glycol that contains 1-60 epoxy radicals after the chloride to the fatty acid of carbon 22 alkane the carbon chain lengths of side chain, and the percentage by weight that its content accounts for nanoemulsions is 3% to 7%; The alkyl dilactic acid ester that below 0 degree, is selected from N-stearoyl-L-glutamic acid 2 sodium or has following chemical constitution for liquid amphiphilic surfactant, the percentage by weight that its content accounts for nanoemulsions is 0.1% to 3%:
Alkyl dilactic acid esterification structural formula is as follows:
Wherein, R is the straight chained alkyl that is selected from C6-C18, and the basic grease composition is made up of for the oils and fats or the silicone oil of liquid plant origin down room temperature, the oil droplet mean diameter is smaller or equal to 150 nanometers, wherein, Vegetable oil lipoprotein is selected from safflower oil, American Avocado Tree oil, Radix Oenotherae erythrosepalae oil, Semen Maydis oil, soybean oil, Oleum Vitis viniferae, at least a in the fish oil, use amount accounts for the percentage by weight 1% to 30% of whole O/w emulsion; Silicone oil is selected from volatility or non-volatile silicone oil: volatile silicone oils is selected from decamethylcyclopentaandoxane, a kind of in ten diformazan basic rings, six siloxanes, use amount accounts for the percentage by weight 0.5% to 5% of whole O/w emulsion, non-volatile silicone oil is a polydimethylsiloxane, and use amount accounts for the percentage by weight 2% to 10% of whole O/w emulsion;
Fat-soluble hair maintenance composition is made up of hair antioxidation composition and hair keratoprotein maintenance composition; Hair antioxidation nursing composition is selected from a kind of in Yoshinox BHT, coenzyme Q10, the a-tocopherol acetate; Wherein to account for the nanoemulsions percentage by weight be 0.0005% to 0.2% to Yoshinox BHT content, and it is 0.005% to 4% that coenzyme Q10 content accounts for the nanoemulsions percentage by weight, and it is 0.3% to 7.% that a-tocopherol acetate content accounts for the nanoemulsions percentage by weight; Hair keratoprotein maintenance composition is selected from the palmityl dipeptides, the palmityl tripeptides, and Palmitoyl Tetrapeptide, a kind of in palmityl six peptides, it is 0.1% to 5% that its content accounts for the nano oil-in-water emulsion percentage by weight.
The following non-ionic amphiphilic surfactant for liquid state of 45 degree of the present invention is selected from the PEG400 isostearate, Polyethylene Glycol 100 isostearates, glyceryl isostearate, a kind of in the sorbitan isostearate, the percentage by weight that its content accounts for nanoemulsions is 4% to 6%; It is liquid amphiphilic surfactant that another kind of amphiphilic surfactant requires below 0 degree, is selected from N-stearoyl-L-glutamic acid 2 sodium or alkyl dilactic acid ester, and the percentage by weight that its content accounts for nanoemulsions is 0.3% to 2%.
45 degree that use in the nanoemulsions of the present invention are following to be that liquid non-ionic amphiphilic surfactant is selected from the PEG400 isostearate, and the following amphiphilic surfactant for liquid state of 0 degree is preferably carbon 8 to carbon 14 alkyl dilactic acid esters.
The room temperature that nanoemulsions of the present invention uses is the liquid preferred American Avocado Tree oil of Vegetable oil lipoprotein down, and the percentage by weight that use amount accounts for whole O/w emulsion is 5% to 25%; Volatile silicone oils is preferably decamethylcyclopentaandoxane, and the percentage by weight that use amount accounts for whole O/w emulsion is 1% to 4%; The percentage by weight that the non-volatile silicone oil use amount accounts for whole O/w emulsion is 3% to 8%.
The non-volatile silicone oil that nanoemulsions of the present invention uses such as the viscosity of polydimethylsiloxane are selected to the viscosity that 25 degree have 10CS to 60000CS.
To account for whole hair-care product composition percentage by weight be 4% to 20% to nano oil-in-water emulsion in the present composition.
The present invention is owing to contain the cuticular lipid absorption of hair and the maintenance that can help micromolecule type oil-in-water nanometer coating active components, therefore have suitable doing, wet conditioning property, thereby play hair deep layer maintenance preferably and the conditioning as, hair is soft and moist more glossy, hair is more prone to typing, and the hair style retention time is more lasting, and hair more is added with texture and vigor.This neoteric hair care composition can be attached to a large amount of oil and produce slowly infiltration maintenance and conditioning effect on the hair with micromolecular form, and does not have oily sensation.
Detailed description of the invention
Emulsifying agent comprises two kinds of amphiphilic surfactants among the present invention, and it is liquid non-ionic amphiphilic surfactant that wherein a kind of amphiphilic surfactant requires below 45 degree.The following ester that mainly is selected from polyol for liquid non-ionic amphiphilic surfactant of 45 degree that uses in the nano oil-in-water emulsion, as comprise 1 mole of macrogol ester to 60 moles of ethylene oxide, sorbitan ester, comprise 2 moles of glyceride to 30 moles of ethylene oxide, comprise 2 moles to the polyglycerin ester of 15 mole of glycerin bases and ester chain be a kind of 8 saturated or unsaturated fatty acid esterifications of carbon to 22 carbon side chain and getting.
The following excellent polyethylene glycol isostearate (wherein the molecular weight of ethylene glycol is 400) that is selected from of non-ionic amphiphilic surfactant of employed 45 degree of nano oil-in-water emulsion of the present invention for liquid state, glyceryl isostearate, sorbitan isostearate, and the further preferred polyethylene glycol isostearate (wherein the molecular weight of ethylene glycol is 400) of using.
The alkyl dilactic acid ester that the following amphiphilic surfactant for liquid state of 0 degree that uses in the nano oil-in-water emulsion of the present invention is selected from N-stearoyl-L-glutamic acid 2 sodium and has following chemical constitution:
Wherein, R is the straight chained alkyl that is selected from C6-C18, preferred C8-C14;
The following amphiphilic surfactant for liquid state of 0 degree that uses in the nanoemulsions of the present invention is preferably alkyl dilactic acid ester.
45 degree that use in the nano oil-in-water emulsion of the present invention are following for liquid non-ionic amphiphilic surfactant is preferably the PEG400 isostearate, and the percentage by weight that accounts for whole nano oil-in-water emulsion is 3% to 7%, further is optimized for 4% to 6%; 0 degree is following for liquid amphiphilic surfactant is preferably carbon 8 to carbon 14 alkyl dilactic acid esters, and the percentage by weight that accounts for whole nano oil-in-water emulsion is 0.1% to 3%, further is optimized for 0.3% to 2%.
The percentage by weight that all oils and fats compositions that comprise in the nano oil-in-water emulsion of the present invention account for whole nano oil-in-water emulsion is 5% to 40%, is preferably 9% to 30%.
The one group of oil phase composition that comprises in the nano oil-in-water emulsion of the present invention is preferable over following classification:
Animal or plant oil is generally the ester of fatty acid and polyol, especially with the triglyceride of liquid state for as long as composition, as, safflower oil, American Avocado Tree oil, Radix Oenotherae erythrosepalae oil, Semen Maydis oil, soybean oil, Oleum Vitis viniferae, fish oil or sad capric acid triglyceride etc.
Non-volatile silicone oil such as polydimethylsiloxane, the phenyl polydimethylsiloxane
Volatile silicone oils such as decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes.
It is the oils and fats of the plant origin of liquid state that the one group of base oil phase composition that contains in the nano oil-in-water emulsion of the present invention comprises under a kind of room temperature at least, this base oil phase composition is selected from American Avocado Tree oil, Radix Oenotherae erythrosepalae oil, Oleum Vitis viniferae, the safflower oil Semen Maydis oil, volatile silicone oils such as decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, (volatile silicone oils is selected from Guangdong and marks U.S. fluosilicic, trade names SF-946), non-volatile silicone oil such as polydimethylsiloxane, (be selected from Guangdong and mark U.S. fluosilicic, trade names SF-906 or Dow corning DC200)
The further preferred American Avocado Tree oil of base oil phase composition in the nano oil-in-water emulsion of the present invention, decamethylcyclopentaandoxane, polydimethylsiloxane.
Silicone compounds that uses in the present composition nano oil-in-water emulsion such as polydimethylsiloxane preferably have the viscosity of about 5CS to about 100000CS, more preferably 10CS to 60000CS at 25 degree.
At least a vegetalitas liquid fat that one group of oil phase composition in the O/w emulsion of the present invention is comprised is preferably American Avocado Tree oil, and use amount accounts for the percentage by weight 1% to 30% of whole O/w emulsion, further is optimized for 5% to 25%; Volatile silicone oils such as decamethylcyclopentaandoxane use amount account for the percentage by weight 0.1% to 5% of whole O/w emulsion, further be optimized for 1% to 4%, non-volatile silicone oil such as polydimethylsiloxane use amount account for the percentage by weight 2% to 10% of whole O/w emulsion, further are optimized for 3% to 8%.
Also comprise one group of active maintenance composition of fat-soluble hair in the nano oil-in-water emulsion of the present invention and comprise hair antioxidation maintenance composition and fat-soluble hair keratoprotein maintenance composition.Hair antioxidation nursing composition is selected from Yoshinox BHT, butylated hydroxyanisol, coenzyme Q10, a-tocopherol three plough acid esters, a-tocopherol acetate etc.
One group of fat-soluble hair antioxidation composition in the nano oil-in-water emulsion of the present invention is Yoshinox BHT more preferably, coenzyme Q10, the a-tocopherol acetate, wherein to account for the percentage by weight of whole oil-in-water composition be 0.0005% to 0.2% to Yoshinox BHT, further be optimized for 0.05% to 0.1%, the percentage by weight that coenzyme Q10 accounts for whole oil-in-water composition is 0.005% to 4%, further be optimized for 0.05% to 3%, the percentage by weight that the a-tocopherol acetate accounts for whole oil-in-water composition is 0.3% to 7.%, further is optimized for 0.4% to 6%;
Fat-soluble hair keratoprotein maintenance composition is selected from the palmityl dipeptides in the nano oil-in-water emulsion of the present invention, the palmityl tripeptides, Palmitoyl Tetrapeptide, polypeptide compounds such as palmityl six peptides, wherein preferably use Palmitoyl Tetrapeptide and palmityl six peptides, more preferably use palmityl six peptides, wherein, the percentage by weight that palmityl six peptides account for whole oil-in-water composition is 0.1% to 5%, further is optimized for 0.2% to 4%.
To account for whole hair-care product composition percentage by weight be 3% to 25% to nano oil-in-water emulsion in the present composition, and the one-step optimization of going forward side by side is 4% to 20%.
All oils and fats compositions account for whole hair care composition percentage by weight about 0.5% to about 5% in the nano oil-in-water emulsion of the present invention, and the one-step optimization of going forward side by side is about 1% to about 4%.
Nano oil-in-water emulsion of the present invention also comprises some water-soluble components such as low-carbon (LC) alcohols such as ethanol, isopropyl alcohol; Glycerol, propylene glycol, 1,3 butylene glycol.Nano oil-in-water emulsion water composition preferred alcohol of the present invention and glycerol.In addition, nano oil-in-water emulsion of the present invention also comprises an amount of EDTA-2 sodium and deionized water.
The oil-in-water nanometer of hair nursing active ingredient parcel emulsion is exemplified below among the present invention:
The % that is weight percentage of each amounts of components unit
The oil-in-water nanometer of hair nursing active ingredient parcel emulsion adopts following method preparation among the present invention:
1 in beaker in the prescription in ratio add active ingredient successively, vegetable oil, silicone oil, the amphiphilic non-ionic surface active agent, join then stir in the ethanol standby.
2 in another beaker with EDTA-2 sodium, it is evenly standby that glycerol joins deionized water for stirring respectively.
3 with above 1 joining in 2 of having prepared, and homogenizing to stir the mixed liquor that forms homogeneous be elementary emulsion.
The 4 elementary emulsions with above-mentioned steps import in the high pressure homogenisers, the circulation homogenizing also obtains required emulsion particle diameter, pressure during homogenizing in the high pressure chest is 500 crust-1500 crust, the circulation homogenizing time did not wait in 10-30 minute, carry out under the constant temperature of temperature 35-45 degree, form the particle size distribution homogeneous, stable, the nano oil-in-water emulsion of particle diameter between 30 nanometer to 250 nanometers.
The particle diameter of nano oil-in-water emulsion is preferably 30 nanometer to 250 nanometers in the hair care composition of the present invention, and more preferably between 40 nanometer to 200 nanometers.The nanoemulsions apparatus for preparation that the present invention adopts is Italian Niro NS1001L, and the particle size distribution tester that is adopted is U.S. PSSNicomp380z or Malvern particle diameter detector.
Hair-care product composition of the present invention can comprise disposable or the washing-off type emulsion, the hair conditioner of dosage forms such as condensation, and hair care elite or hair nursing type approved product such as elastin etc., therefore, hair care composition of the present invention also comprises following component:
Hair care composition of the present invention also comprises thickening agent or suspending agent, as be selected from HANSHENGJIAO, hydroxypropyl emthylcellulose, ethylene glycol monostearate, Ethylene Glycol Distearate, acrylic acid ester copolymer (as SF-1), through the cross-linked copolymer of the carboxylic acid with amphipathic characteristic of hydrophobically modified and alkyl carboxylates as, acrylic acid ester/C10-30 acrylic acid Arrcostab cross-linked copolymer is (as TR-1, TR-2), and the nonionic polyacrylamide polymer of polymer that the polyacrylamide polymer particularly comprises substituted side chain or straight chain is as the non-ionic polyalcohol (as Sepigel305) of, INCI chemistry polyacrylamide by name and isoparaffin and lauryl ether-7 etc.
Preferred thickening suspension composition comprises that the non-ionic polyalcohol (as trade name Sepigel305) of acrylic acid ester/C10-30 acrylic acid Arrcostab cross-linked copolymer (commodity are called TR-2) and polyacrylamide and isoparaffin and lauryl ether-7 is as the suspension thickening agent in the present composition, wherein to account for whole composition weight percentage ratio be 005%-5% to the non-ionic polyalcohol consumption of polyacrylamide and isoparaffin and lauryl ether-7, further be optimized for 1%-3%, the percentage by weight that acrylic acid ester/C10-30 acrylic acid Arrcostab cross-linked copolymer accounts for whole compositions is 0.05% to 0.50%, further is optimized for 0.1% to 0.4%.
The emulsifying agent that may use in the hair care composition of the present invention is the cationic surfactant with opsonic action, is selected from the fat primary amine of polyoxy second desaturation, fatty primary secondary amine and fat tertiary amine; Quaternary ammonium salt such as tetra-alkyl ammonium chloride, trialkyl hydroxyalkyl ammonium chloride, triakyl benzyl ammonium chloride, trialkyl hydroxyalkyl ammonium chloride etc., further be optimized for hexadecyltrimethylammonium chloride, Varisoft 432PPG, dioctadecyl dimethyl ammonium chloride, INCROQUAT TMC-80 ECONOL TM22, the present invention is further preferred to use 22 alkyl trimethyl ammonium chlorides (to originate from the company in Degussa EVONIK, product grade VARISOFT BT85) and 16 alkyl trimethyl ammonium chlorides (originating from company, product grade VARISOFT 300) in Degussa EVONIK.
Preferred cationic surfactants is 0.5% to 4% as the percentage by weight that the consumption of 16 alkyl trimethyl ammonium chlorides accounts for whole hair-care product composition in the hair care composition of the present invention, the one-step optimization of going forward side by side is 1% to 3%, the percentage by weight that the consumption of preferred 22 alkyl trimethyl ammonium chlorides accounts for whole hair-care product composition is 0.5% to 3%, and the one-step optimization of going forward side by side is 1% to 2%;
In addition, also comprise other auxiliary composition such as non-ionic surface active agent among the hair care composition embodiment of the present invention, volatile silicone oils and long carbochain aliphatic alcohol and polyhydric alcohol, the preferred glyceryl monostearate of nonionic emulsifier wherein, the preferred decamethylcyclopentaandoxane of volatile silicone oils, the preferred 16/18 carbon alcohol of long carbochain aliphatic alcohol, polyhydric alcohol is preferably propylene glycol.
Also use among the hair care composition embodiment of the present invention hair fixing copolymer as, AMP-methylmethacrylate copolymer (Lubrizol Fixate G-100 Polymer), polyacrylate-14 (Lubrizol Fixate Plus Polymer), the rare basic imidazoles copolymer of Methacrylamide/second (BASF Luvisel Clear) etc., hair care composition of the present invention preferably uses polyacrylate-14 (Lubrizol Fixate Plus Polymer) and the rare basic imidazoles copolymer of Methacrylamide/second (BASF Luvisel Clear), wherein polyacrylate-14 (Lubrizol Fixate Plus Polymer) accounts for whole composition weight percentage ratio and is preferably 5%, and the rare basic imidazoles copolymer of Methacrylamide/second (BASF Luvisel Clear) accounts for whole composition weight percentage ratio and is preferably 3% to 9%.
The present composition also comprises antiseptic and an amount of essence, and wherein antiseptic preferably uses phenoxyethanol.
The present composition can be with frost, and emulsion has the liquid of some viscosity, the product performance of different dosage forms such as gel, and be confirmed by following 7 embodiment.Nano oil-in-water emulsion adopts the nanoemulsions of abovementioned steps preparation among all embodiment.The % that is weight percentage of each amounts of components unit in the following example
Embodiment 1
The leave daily hair treatment
The non-ionic polyalcohol 2% of polyacrylamide and isoparaffin and lauryl ether-7
Phenoxyethanol 0.5%
Nano oil-in-water emulsion 1 (50 nanometer) 7.5%
Essence 0.1%
The deionized water surplus
Embodiment 2
Leave hair conditioner
The non-ionic polyalcohol 1.5% of polyacrylamide and isoparaffin and lauryl ether-7
Acrylic acid ester/C10-30 acrylic acid Arrcostab cross-linked copolymer (commodity are called TR-2) 0.3%
Decamethylcyclopentaandoxane (volatile silicone oils) 3.0%
Phenoxyethanol 0.5%
Nano oil-in-water emulsion 2 (100 nanometer) 15%
Essence 0.1%
Triethanolamine 0.2%
The deionized water surplus
Leave hair conditioner preparation method:
1, the non-ionic polyalcohol 1.5% of thickening suspending agent such as polyacrylamide and isoparaffin and lauryl ether-7 or acrylic acid ester/C10-30 acrylic acid Arrcostab cross-linked copolymer (commodity are called TR-2) 0.3% are dispersed in the water swelling respectively to be opened, add volatile silicone oils then, the water of phenoxyethanol and surplus, stir and the low speed homogenizing is made the emulsified body of a homogeneous, and pH value is adjusted between the 6-6.5.
2, nano oil-in-water emulsion is slowly added in 1, and slowly stir, mixing speed 10-30 rev/min,, add essence at last up to homodisperse.
Embodiment 3
Washing-off type hair conditioner
16/18 alcohol 2.5%
Glyceryl monostearate 0.8%
Phenoxyethanol 0.5%
Hexadecyltrimethylammonium chloride 2.5%
Nano oil-in-water emulsion 3 (150 nanometer) 10%
Essence 0.1%
The deionized water surplus
Embodiment 4
Washing-off type hair conditioner
16/18 alcohol 3.5%
Glyceryl monostearate 0.5%
Phenoxyethanol 0.5%
INCROQUAT TMC-80 ECONOL TM22 2.0%
Nano oil-in-water emulsion 7 (150 nanometer) 15%
Essence 0.1%
The deionized water surplus
Washing-off type hair conditioner preparation method:
1, with water composition phenoxyethanol, INCROQUAT TMC-80 ECONOL TM22 successively is added to the water, and stirs and be heated to 75 degree, and it is standby to stir; With oil phase composition 16/18 alcohol, it is standby that glyceryl monostearate is heated to 75 degree again.
2, the oil phase composition is joined in the water composition stirring and middling speed homogenizing 5-10 minute.Cool then.
3, when being cooled to 35-40 when spending, nano oil-in-water emulsion is slowly added wherein, and slowly stir, mixing speed 10-30 rev/min, up to homodisperse.
Embodiment 5
The hair fixing elastin
The non-ionic polyalcohol 1.5% of polyacrylamide and isoparaffin and lauryl ether-7
The rare basic imidazoles copolymer of Methacrylamide/second (BASF Luvisel Clear) 5%
Propylene glycol 2%
Volatile silicone oils 2%
Nano oil-in-water emulsion 5 (150 nanometer) 15%
Phenoxyethanol 0.5%
Essence 0.1%
The deionized water surplus
Embodiment 6
The hair fixing elastin
The non-ionic polyalcohol 2% of polyacrylamide and isoparaffin and lauryl ether-7
The rare basic imidazoles copolymer of Methacrylamide/second (BASF Luvisel Clear) 7%
Propylene glycol 2%
Volatile silicone oils 2%
Nano oil-in-water emulsion 6 (150 nanometer) 10%
Phenoxyethanol 0.5%
Essence 0.15%
The deionized water surplus
Embodiment 7
The hair fixing elastin
The non-ionic polyalcohol 2.5% of polyacrylamide and isoparaffin and lauryl ether-7
Polyacrylate-14 (Lubrizol Fixate Plus) 5%
Propylene glycol 2%
Volatile silicone oils 2%
Nano oil-in-water emulsion 4 (80 nanometer) 10%
Phenoxyethanol 0.5%
Essence 0.15%
The deionized water surplus
Hair fixing elastin preparation method:
1, the non-ionic polyalcohol 2.5% of thickening suspending agent such as polyacrylamide and isoparaffin and lauryl ether-7 is dispersed in the water swelling to be opened, add volatile silicone oils then while stirring, the dispersion liquid of polyacrylate-14 (Lubrizol Fixate Plus) and propylene glycol, stir 60 rev/mins, make the emulsified body of a homogeneous.
2, nano oil-in-water emulsion is slowly added in 1, and slowly stir, mixing speed 10-30 rev/min,, add phenoxyethanol and essence at last up to homodisperse.
Claims (7)
1. the hair-care product composition of an oil-in-water nanometer coating active components, said composition contain also that to account for composition weight percentage ratio be 3% to 25% nanoemulsions except that containing the hair nursing solvent, in this nanoemulsions, comprising:
One group of emulsifying agent, this emulsifier content account for nanoemulsions percentage by weight 3%-8%;
It is 17% to 25% that one group of basic grease composition, fat content account for the nanoemulsions percentage by weight;
It is than 0.1%-5% that one group of fat-soluble hair maintenance composition, this component content account for the nanoemulsions weight percent;
Wherein said emulsifying agent comprises two kinds of amphiphilic surfactants, it is liquid non-ionic amphiphilic surfactant that wherein a kind of amphiphilic surfactant requires below 45 degree, the following non-ionic amphiphilic surfactant for liquid state of 45 degree is a kind of mixing esters that comprises a hydroxy compounds at least, the hydroxy compounds that this mixing esters is comprised is by saturated or unsaturation, to be carbon 8 obtain through carrying out esterification with the Polyethylene Glycol that contains 1-60 epoxy radicals after the chloride to the fatty acid of carbon 22 alkane the carbon chain lengths of side chain, and the percentage by weight that its content accounts for nanoemulsions is 3% to 7%; The alkyl dilactic acid ester that below 0 degree, is selected from N-stearoyl-L-glutamic acid 2 sodium or has following chemical constitution for liquid amphiphilic surfactant, the percentage by weight that its content accounts for nanoemulsions is 0.1% to 3%:
Alkyl dilactic acid esterification structural formula is as follows:
Wherein, R is the straight chained alkyl that is selected from C6-C18, the basic grease composition is made up of for the oils and fats or the silicone oil of liquid plant origin down room temperature, the oil droplet mean diameter is smaller or equal to 150 nanometers, wherein, Vegetable oil lipoprotein is selected from least a in safflower oil, American Avocado Tree oil, Radix Oenotherae erythrosepalae oil, Semen Maydis oil, soybean oil, Oleum Vitis viniferae, the fish oil, and use amount accounts for the percentage by weight 1% to 30% of whole O/w emulsion; Silicone oil is selected from volatility or non-volatile silicone oil: volatile silicone oils is selected from decamethylcyclopentaandoxane, a kind of in ten diformazan basic rings, six siloxanes, use amount accounts for the percentage by weight 0.5% to 5% of whole nano oil-in-water emulsion, non-volatile silicone oil is a polydimethylsiloxane, and use amount accounts for the percentage by weight 2% to 10% of whole O/w emulsion;
Fat-soluble hair maintenance composition is made up of hair antioxidation composition and hair keratoprotein maintenance composition; Hair antioxidation nursing composition is selected from least a in Yoshinox BHT, coenzyme Q10, the a-tocopherol acetate; Wherein to account for the nanoemulsions percentage by weight be 0.0005% to 0.2% to Yoshinox BHT content, and it is 0.005% to 4% that enzyme Q10 content accounts for the nanoemulsions percentage by weight, and it is 0.3% to 7% that a-tocopherol acetate content accounts for the nanoemulsions percentage by weight; Hair keratoprotein maintenance composition is selected from the palmityl dipeptides, the palmityl tripeptides, and Palmitoyl Tetrapeptide, a kind of in palmityl six peptides, it is 0.1% to 5% that its content accounts for the nano oil-in-water emulsion percentage by weight.
2. compositions according to claim 1, it is characterized in that: the following non-ionic amphiphilic surfactant for liquid state of described 45 degree is selected from the PEG400 isostearate, Polyethylene Glycol 100 isostearates, glyceryl isostearate, a kind of in the sorbitan isostearate, the percentage by weight that its content accounts for nanoemulsions is 4% to 6%; Below 0 degree is liquid amphiphilic surfactant, is selected from N-stearoyl-L-glutamic acid 2 sodium or alkyl dilactic acid ester, and the percentage by weight that its content accounts for nanoemulsions is 0.3% to 2%.
3. compositions according to claim 2, it is characterized in that: 45 degree that use in the nanoemulsions are following to be that liquid non-ionic amphiphilic surfactant is selected from the PEG400 isostearate, and the following amphiphilic surfactant for liquid state of 0 degree is preferably carbon 8 to carbon 14 alkyl dilactic acid esters.
4. compositions according to claim 1 is characterized in that: the room temperature that nanoemulsions uses is the liquid preferred American Avocado Tree oil of Vegetable oil lipoprotein down, and the percentage by weight that use amount accounts for whole O/w emulsion is 5% to 25%; Volatile silicone oils is preferably decamethylcyclopentaandoxane, and the percentage by weight that use amount accounts for whole O/w emulsion is 1% to 4%; The percentage by weight that the non-volatile silicone oil use amount accounts for whole O/w emulsion is 3% to 8%.
5. compositions according to claim 1 is characterized in that: the non-volatile silicone oil that nanoemulsions uses such as the viscosity of polydimethylsiloxane are selected to the viscosity that 25 degree have 10CS to 60000CS.
6. compositions according to claim 1, it is characterized in that it is 0.05% to 0.1% that described Yoshinox BHT content accounts for the nanoemulsions percentage by weight, it is 0.05% to 3% that coenzyme Q10 content accounts for the nanoemulsions percentage by weight, and it is 0.4% to 6% that a-tocopherol acetate content accounts for the nanoemulsions percentage by weight.
7. compositions according to claim 1 is characterized in that: to account for whole hair-care product composition percentage by weight be 4% to 20% to nano oil-in-water emulsion in the compositions.
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| CN200910213619A CN101716130A (en) | 2009-12-07 | 2009-12-07 | Hair-care product composition containing oil-in-water nanometer coating active components |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103079540A (en) * | 2010-07-01 | 2013-05-01 | 高道尹 | Method for preparing a hair and scalp condition-enhancing composition with increased efficacy of blending aroma oil |
| CN104274359A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Hair care composition containing paramela plant essential oil |
| CN104274358A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Scalp repair shampoo composition containing plant essential oil and preparation method thereof |
| CN107405284A (en) * | 2014-12-23 | 2017-11-28 | 莱雅公司 | Composition for conditioning keratin fibers |
-
2009
- 2009-12-07 CN CN200910213619A patent/CN101716130A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103079540A (en) * | 2010-07-01 | 2013-05-01 | 高道尹 | Method for preparing a hair and scalp condition-enhancing composition with increased efficacy of blending aroma oil |
| CN104274359A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Hair care composition containing paramela plant essential oil |
| CN104274358A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Scalp repair shampoo composition containing plant essential oil and preparation method thereof |
| CN104274358B (en) * | 2014-09-05 | 2017-07-18 | 拉芳家化股份有限公司 | A kind of scalp maintenance type hair-washing composition and preparation method containing plants essential oil |
| CN107405284A (en) * | 2014-12-23 | 2017-11-28 | 莱雅公司 | Composition for conditioning keratin fibers |
| CN107405284B (en) * | 2014-12-23 | 2020-11-24 | 莱雅公司 | Composition for conditioning keratin fibers |
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