CN103845231A - Shampoo conditioning composition containing PPG-3 octyl ether - Google Patents
Shampoo conditioning composition containing PPG-3 octyl ether Download PDFInfo
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- CN103845231A CN103845231A CN201210514308.9A CN201210514308A CN103845231A CN 103845231 A CN103845231 A CN 103845231A CN 201210514308 A CN201210514308 A CN 201210514308A CN 103845231 A CN103845231 A CN 103845231A
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Abstract
A shampoo conditioning composition comprising a surfactant, PPG-3 octyl ether and a non-volatile silicone, a cationic polymer, and water is disclosed. The invention further discloses methods of cleansing and conditioning the hair by applying the shampoo conditioning compositions. In addition, the invention also discloses the application of the shampoo conditioning composition in preparing a shampoo product for cleaning and conditioning hair.
Description
Technical field
The present invention relates to a kind of conditioning shampoo composition, particularly, relate to a kind of conditioning shampoo composition that comprises surfactant, PPG-3 Octyl Ether and fixedness polysiloxanes, cationic polymer and water, described conditioning shampoo composition can improve the conditioning performance to hair in clean hair.
Background technology
People continue to increase for the demand of improving conditioning property in hair care product formula.Especially, the product that possesses conditioning performance in hair products aspect requires to realize cleaning action need to washed.
Occurred in the market many shampoo composites that clean hair and conditioning hair effect can be provided, these shampoo composites contain the multiple rinse additives such as detersive surfactant, cationic cellulose, cation guar gum, polysiloxanes conditioner mostly.
But these current products can not meet people's demand well.For example, the performance of conditioner shampoo depends on that shampoo conditioning polymer in the process being washed away resists the ability being washed away, i.e. " adhesive force " of so-called conditioning ingredients to a certain extent.Adhesive force can guarantee that conditioner shampoo reaches needed effect.Can cause some composition (particularly cationic polymer and silicone oil etc.) excessive buildup on hair and scalp after shampoo cyclic washing but too much adhere to.This gathering can cause hair texture stiff and greasy, and usually reduces glossiness and plentiful sense.On the other hand, there is the compound action of good cleaning efficacy (comprising anti-dandruff effect) and conditioning performance and be not easy to reach.For example, a kind of method that realizes conditioning effect is the cationic polymer that uses suitable high-load in shampoo composite, but, use the cationic polymer of high-load to affect the deposition of the material with cleaning action on hair and scalp and and then to affect between cationic polymer and anion surfactant and form condensed phase in a kind of disadvantageous mode.Therefore the optimum balance of, realizing between the two is desired for a long time.
Summary of the invention
The inventor proposes, for a kind of desirable conditioning shampoo composition, need to consider dry, moist different aspect, comprise cardability and organoleptic attribute, particularly can be from following concrete aspect comprehensive consideration and evaluate its conditioning performance: good wet Comb rationality, rinse soft and smooth sense, dry sending out gone entanglement property, sent out rough, the elegant performance of tail unhairing (not heavy), glossiness, etc.Based on above-mentioned Consideration, inventor's process many experiments, finds, shampoo composite of the present invention can have excellent cleaning action and conditioning performance simultaneously, realizes the demand unexpectedly.Specifically, the invention provides a kind of shampoo care composition that comprises surfactant, PPG-3 Octyl Ether and fixedness polysiloxanes, cationic polymer and water, the combination of described component can effectively realize the demand.
Therefore, aspect first, the invention provides a kind of shampoo care composition, it comprises following component by weight:
A) 5% to 50% surfactant;
B) PPG-3 Octyl Ether and fixedness polysiloxanes, its two content sum is 0.1% to 10%, and the content of wherein said fixedness polysiloxanes is not less than 0.01% but not higher than 2.5%;
C) 0.01% to 3% cationic polymer; With
D) water of 50-80%.
The method that the invention still further relates to clean and conditioning hair, comprises shampoo care composition of the present invention from effective dose to hair that use.In addition, the invention still further relates to the purposes of described shampoo care composition in the hair washing/hair products for the preparation of clean and conditioning hair.
Conditioning shampoo composition of the present invention provides the good composition of cleaning action and conditioning performance.The component of conditioning shampoo composition of the present invention, comprises those components and preparation method, using method and the purposes that can optionally add.
The specific embodiment
i component
The surfactant comprising in conditioning shampoo composition of the present invention can be a kind of or its combination in any being selected from anion surfactant, zwitterionic surfactant and non-ionic surface active agent.
A. surfactant
Conditioning shampoo composition of the present invention comprises and accounts for composition weight preferably approximately 5% to 50%, is preferably 8% to 40%, 10% to 30%, more preferably 10% to 25%, 10% to 18% surfactant.Described surfactant can be compositions and brings cleaning action and frothing capacity.The in the situation that of anion surfactant, it can form condensed phase with cationic polymer component of the present invention (as mentioned below) in the time of dilute with water.Believe that this cohesion contributes to provide effect of the present invention and opsonic action.
Anion surfactant component not only comprises common anion surfactant, is also included under the pH of compositions the zwitterionic surfactant for the coupling part of anionic property, or their combination.The example that is applicable to the anion surfactant in compositions of the present invention includes but not limited to sulfate, sulfonate, sarcosinate and sarcosine derivative.Preferred anion surfactant is alkyl and alkyl ether sulfate.The example of alkyl sulfate has ammonium lauryl sulfate, cocoyl ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, sodium lauryl sulfate, sodium cocosulfate, lauryl sulfate monoethanolamine, cocoyl sulphuric acid monoethanolamine, lauryl sulfate diethanolamine, triethanolamine lauryl sulfate, lauryl sulfate triethylamine and composition thereof, particularly preferably is ammonium lauryl sulfate; The example of alkyl ether sulfate has lauryl polyethenoxy ether sodium sulfate, laureth potassium sulfate, sodium laureth sulfate, laureth sulphuric acid monoethanolamine, laureth sulphuric acid diethanolamine, laureth sulphuric acid triethanolamine, laureth sulphuric acid triethylamine and composition thereof, particularly preferably is lauryl polyethenoxy ether sodium sulfate.The example of the anion surfactant of sulfonate comprises such as tridecyl benzene sulfonic acid sodium salt, dodecylbenzene sodium sulfonate, lauryl sulfosuccinate etc.The example of sarcosine and sarcosine derivative comprises sodium lauryl sarcosinate, lauryl sarcosine, cocoyl sarcosine and composition thereof, wherein preferred sodium lauryl sarcosinate.
The amphoteric surfactant that is applicable to shampoo care composition of the present invention is well known in the art, and those can be used for the material in hair nursing or other personal care cleansing compositions, described in following patent documentation: United States Patent (USP) 5,104,646, United States Patent (USP) 5,106,609.These amphoteric surfactantes comprise that those are the surfactant of secondary aliphatic amine and tertiary amines derived thing, wherein said aliphatic group can be the group of straight or branched, and in described aliphatic group one can be containing having an appointment 8-18 carbon atom, another can comprise a kind of anionic hydrophilic group as carboxyl, sulfonic acid are followed, sulfate radical, phosphate radical or phosphonate radical.Be applicable to amphoteric surfactant of the present invention also comprise as aliphatic quaternary ammonium, quaternary phosphine and season sulfonium compound the surfactant of derivant, one of them aliphatic group is containing 8-18 the carbon atom of having an appointment, another can comprise a kind of anionic hydrophilic group as carboxyl, sulfonic acid are followed, sulfate radical, phosphate radical or phosphonate radical.The preferably zwitterionic compound of betanin.
B.PPG-3 Octyl Ether
PPG-3 Octyl Ether (PPG-3octyl ether) is polypropylene glycol-3 Octyl Ether, conventionally in cosmetic composition, is used as solvent or carrier etc.The inventor finds unexpectedly, and PPG-3 Octyl Ether can be used as in conditioning shampoo composition, plays the effect of excellent conditioner.The inventor is surprised to find, and by using PPG-3 Octyl Ether, can in the case of significantly reducing the consumption of fixedness polysiloxanes, realize desired conditioning performance, thereby can greatly improve conditioning effect.Especially, aspect conditioning performance, the use of PPG-3 Octyl Ether can make hair gloss degree be significantly improved, make that hair is smooth easily to be arranged, entanglement can effectively remove hair flushing time, effectively prevent that hair is short-tempered, for can effectively prevent the local excessive deposition of polysiloxanes on hair containing the product of polysiloxane, make polysiloxanes can more efficiently be evenly distributed in root of hair to sending out the tip.
C. fixedness polysiloxanes
The fixedness polysiloxanes being used in conditioning shampoo composition of the present invention is normally used conditioner, and it is often used to adjust dry comb and wet comb performance, sends out sense, brightness and the easy property arranged.
Spendable fixedness polysiloxanes comprises poly-alkylsiloxane, poly-aryl siloxanes, poly-alkaryl siloxanes, polyether siloxane copolymer and composition thereof.Term used herein " fixedness " means this silicone material to be had low-down or there is no a significant vapour pressure under environmental condition.Be preferably insoluble fluid.Preferably, the viscosity at 25 ℃ of fixedness polysiloxanes of the present invention is 20-2,000,000 centistoke, preferably 1,000-1,500,000 centistokes, most preferably 10,000-1,000,000 centistoke.
On the other hand, the PPG-3 Octyl Ether containing in conditioning shampoo composition of the present invention and fixedness polysiloxane level sum be preferably by weight 0.1% to 10%, and the content of wherein said fixedness polysiloxanes is not less than 0.01% but not higher than 2.5%.Preferably, described in described PPG-3 Octyl Ether and fixedness polysiloxane level sum compositions by weight 0.1% to 8.0%, be preferably 0.1% to 7.0%, 0.2% to 6.0%, more preferably 0.3% to 5.0%, 0.5% to 5.0%, more preferably 0.5% to 4.0%, 0.5% to 3.0%, 0.5% to 2.0%; And the content of wherein said fixedness polysiloxanes is not less than 0.05% but not higher than 3.0%, preferably be not less than 0.1% but not higher than 2.5%, preferably be not less than 0.1% but not higher than 2.3%, more preferably be not less than 0.1% but not higher than 2.2%, preferably be not less than 0.1% but not higher than 2.1%, be preferably not less than 0.1% but not higher than 2.0%.
The instantiation of spendable fixedness polysiloxanes comprises for example polydimethylsiloxane, and it can be available from as General Electric Company
dow Coming 200 series with SF 96 series and DowCorning; Spendable polyoxyethylene alkyl aryl radical siloxane comprises for example PSI, and they can be available from the SF 1075 aminomethyl phenyl fluids as General Electric Company or 556 cosmetic fluid of Dow Corning; Spendable polyether siloxane copolymer comprises the polydimethylsiloxane (for example DowComing DC-1248) of for example poly(propylene oxide) modification.About the list of references for example US2 as seen of fixedness polysiloxanes, 826,551, US3,964,500, US4,364,837, US5,573,709, British patent 849,433 and PCT application WO83/08787.These open source literatures are incorporated to herein by reference.
D. cationic polymer
Cationic polymer can promote the deposition of polysiloxanes in shampoo use procedure, and the flocculation forming in the washing of shampoo, dilution can effectively help the composition including polysiloxanes to be deposited on hair fiber.
The selection of the cationic polymer in the present invention and amount need make it be dissolved in shampoo composite, and preferably in the time of dilution, are dissolved in the meeting in condensed phase of shampoo composite.Preferably, in the time of dilution shampoo composite (for example, in washing process), between cationic polymer of the present invention and anion surfactant, can form condensed phase.Believe that the cationic moiety of polymer and the anionicsite of surfactant are in conjunction with forming insoluble complex, they are precipitation (condensed phase) in the time of dilution.The complex coacervation of cationic polymer can also form with together with other optional anionic group in shampoo composite mutually.The formation of condensed phase is usually relevant with factors such as molecular weight, concentration of component, ionic strength, charge density, pH.Effect about condensed phase system and these parameters is described in following document: J.Caelles etc., Cosmetics & Toiletries, the 106th volume 49-54 page in 1991; And D.J.Burgess, Journal of Colloid and Interface Science, nineteen ninety the 140th volume 227-238 page.All these documents are incorporated herein.
Believe that condensed phase can provide opsonic action, while particularly using product in the time of hair moistening, by helping to provide conditioning effect by conditioning agent deposit on hair and scalp.
The mean molecule quantity that is applicable to cationic polymer of the present invention is approximately 2,500 to approximately 2,500,000, preferably approximately 5,000 to approximately 2,000,000, more preferably from about 10,000 to approximately 1,000,000.Under pH in the time that the expection of shampoo care composition is used, the cationic charge density that records polymer is about between 0.1 to 4.0meq/g, and preferably approximately 0.2 to 3.8meq/g, and more preferably from about 0.5 to 3.5meq/g, and particularly preferably approximately 0.6 to 3.0meq/g.The charge density of cationic polymer can be measured according to Kjeldahl method.It will be appreciated by those skilled in the art that the charge density that contains amino polymer will change with pH.Therefore, pH value when pH when mensuration is generally shampoo composite expection use, it typically is approximately 3 to approximately 9, preferred approximately 4 to approximately 7.
In the present composition, the content of cationic polymer is by weight 0.01% to 3.0%, is preferably 0.01% to 2.0%, more preferably 0.01% to 1.5%, most preferably be 0.01% to 1.0%.
Cationic polymer in conditioning shampoo composition of the present invention can comprise following material: cationic polysaccharide, ethylene monomer copolymer, vinylpyrrolidone copolymer, cation-modified protein and some polymer quaternary salt.
cationic polysaccharide:
Cationic polysaccharide is based on C
5-C
6those polymer of sugar and on polysaccharide main chain grafted cation part and there is the derivant of cationic, comprise the monomeric unit that quaternary ammonium or cationic amine replace and be optionally combined the homopolymer that forms, copolymer, ter-polymers etc. with non-cationic monomer.Polysaccharide can be made up of the sugar of one type or more than one sugar.Cationic amine can be primary amine, secondary amine or tertiary amine (preferably secondary amine or tertiary amine), and this depends on the particular types of shampoo composite and selected pH value thereof.Monomer can make straight or branched.The indefiniteness embodiment of cationic polysaccharide is described in in Publication about Document: CTFA Cosmetic Ingredient Dictionary, the 3rd edition, 1982.The document is incorporated to herein by reference.
Cationic polymer comprises cationic cellulose and hydroxyethyl-cellulose; Cationic starch and hydroxyalkyl starch; The cationic polymer of the galactomannan that is called guar gum based on obtaining from the endosperm of Guar beans; Based on the cationic polymer of Arabinose plant gum; Derived from the cationic polymer of xylose polymer; Derived from the cationic polymer of trehalose polymer; Derived from the cationic polymer (as inulin) of fructose polymer; For example, based on containing sour sugared cationic polymer (galacturonic acid and glucuronic acid); Cationic polymer (as galactose is pressed and glycosamine) based on amine sugar; Based on five and the cationic polymer of the polyhydric alcohol of hexatomic ring; Based on the cationic polymer of galactose monomer; And cationic polymer based on mannose unit; Etc..Preferably cationic cellulose and hydroxyethyl-cellulose; Cationic starch and hydroxyalkyl starch; Based on the cationic polymer of guar gum, and their mixture.
cationic cellulose derivative
Preferably cationic cellulose polymer includes but not limited to, can be from Amerchol company with its series of polymers Polymer
with
those that buy, as the salt of epoxide reactive hydroxyethyl-cellulose replacing with trimethyl ammonium, are called the Polyquaternium 10 (JR for example obtaining from Amerchol company in industry
).The non-limiting example of the cationic cellulose of another kind of preferred type comprises the polymeric quaternary ammonium salts of the epoxide reactive hydroxyethyl-cellulose replacing with lauryl dimethyl ammonium, is called Polyquaternium 24 (the Polymer LM-for example obtaining from Amerchol company in industry
).
Be applicable to the cellulose copolymer containing quaternary nitrogen that also has those hydroxyethyl-celluloses that react with diallyldimethylammonium chloride of the present invention, in industry, be called polyquaternium 4 and (for example obtain from National Starch company
h-100).Be applicable to the cellulose ether containing quaternary nitrogen of the present invention and be described in United States Patent (USP) 3962418, be applicable to other the cellulose of etherificate and the copolymer of starch of the present invention and be described in United States Patent (USP) 3958581.Above-mentioned patent documentation is all incorporated to herein by reference.
cation melon that polymer
Being applicable to a cationoid polymer of the present invention is cation melon that polymer.You are galactomannan (melon that) gum derivative of the replacement of positively charged for melons.The molecular weight of these derivants is generally approximately 50,000 to approximately 2,500,000, and preferably approximately 50,000 to approximately 1,000,000, more preferably from about 100,000 to approximately 350,000.Preferred your instantiation of polymer of concrete cation melon comprises:
c 13S, its cationic charge density is 0.8meq/g (obtaining from Rhodia Company);
c 17, its cationic charge density is 1.6meq/g (obtaining from RhodiaCompany).Your polymer of other suitable cation melon comprises the cation melon that polymer of hydroxypropylation.Also have other suitable cationic polymer to comprise your copolymer of melon of etherificate, some of them example is described in United States Patent (USP) 3958581, and the present invention introduces this patent documentation as a reference.
Term " polymer " used herein " include the material that a kind of monomer polymerization produces or material (being copolymer) or the material being produced by various of monomer polymerization or the naturally occurring polymer that has two kinds of monomer polymerizations to produce.The cationic polymer preferably using in the present invention is one or more in cation guar gum, cassia gum Hydroxyproyl Trimethyl ammonia chloride, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, Polyquaternium-10, polyquaternary ammonium salt-11, Polyquaternium-67, polyquaternary ammonium salt-73, polyquaternary ammonium salt-74.
Water
In conditioning shampoo composition of the present invention, except said components and other auxiliary element, water (preferably deionized water) adds to requirement.
iI. optional components
Shampoo care composition of the present invention also optionally comprises one or more in following component: dandruff removing agent, suspending agent, natural on-off cycles of hair growth regulator, antistatic additive, foam booster, viscosity modifier and thickening agent, pH adjusting agent, dyestuff, organic solvent or diluent etc.These components and amount thereof can suitably be selected according to the actual needs of product, and join in compositions of the present invention.
dandruff removing agent
Dandruff removing agent of the present invention can be the material with antimicrobial acivity, for example pyrithione, selenium sulfide, micronize sulfur and compositions thereof.Preferably pyrithione.The example of the dandruff removing agent of an indefiniteness is ketoconazole.
suspending agent
In shampoo care composition of the present invention, can comprise in certain embodiments account for composition weight approximately 0.1% to approximately 10%, preferably approximately 0.3% to approximately 5.0%, more preferably from about 0.3% to approximately 2.5% be applicable to the suspending agent on hair or skin.The example of these suspending agents can include but not limited to: acyl derivative, long chain amine oxide, xanthan gum and composition thereof.
natural on-off cycles of hair growth regulator
In compositions of the present invention, optionally comprise growth regulator.On described natural on-off cycles of hair growth regulator, can strengthen the molecule of the natural on-off cycles of hair growth effect of the present composition.Described " natural on-off cycles of hair growth adjusting " refers to and comprises: stimulate natural on-off cycles of hair growth and/or hair thickening; Prevention, minimizing, prevention and/or delay hair damage and/or hair tail off; Increase the speed of growth of hair; Bring out the formation of more bunch; Increase and send out bunch diameter; Make to send out bunch elongated; Hair growth, and their combination.
antistatic additive
Operable optional antistatic additive can be for example water-insoluble cationic surfactant, and concentration is generally 0.1% to approximately 5% of composition weight.Such antistatic additive is answered not obvious serviceability and the benefit that affects shampoo care composition; Especially, described antistatic additive should not disturb anion surfactant.The concrete non-limiting example of suitable antistatic additive is three cetyl ammonio methacrylates.
foam booster
Optional foam booster for shampoo care composition of the present invention comprises fatty alkanol amide, particularly C
1-C
3alkanolamide.The concrete non-limiting example of such foam booster comprises coconut monoethanol amide, cocos nucifera oil diglycollic amide and composition thereof.
viscosity modifier and thickening agent
Optional viscosity modifier and thickening agent for shampoo care composition of the present invention are used for shampoo care composition of the present invention with available phosphorus conventionally, and making overall viscosity is that approximately 1,000 centistoke is to approximately 20,000 centistoke, preferably approximately 3,000 centistokes are to approximately 10,000 centistokes.The concrete non-limiting example of this viscosity modifier and thickening agent comprises sodium chloride, sodium sulfate and composition thereof.
iII production method
Shampoo care composition of the present invention can by any known or other be effectively suitable for providing the technology of shampoo composite prepare, prerequisite is that resulting composition provides outstanding as described in the present invention conditioning performance.The method of preparing shampoo care composition of the present invention comprises conventional preparation and hybrid technology.For example, can be with reference to the method described in United States Patent (USP) 5837661.
iV using method
On the other hand, the present invention also provides a kind of method of clean and conditioning hair, and described method comprises the shampoo care composition of the present invention of using effective dose to hair and/or scalp.Particularly, shampoo care composition of the present invention uses to clean with the usual manner of conditioning hair or skin.Described compositions can be coated on to the hair of moistening in advance (conventionally water) or other positions of health, then by compositions rinsing or rinse out.The scope of the compositions of effective dose is generally approximately 1 gram to approximately 50 grams, preferably approximately 1 gram to approximately 20 grams.Be applied on hair and generally include compositions is rubbed and smeared in hair, thereby the major part of making or all hair contact with compositions.
Method for clean and conditioning hair specifically comprises the steps: that (a) is by Hair grooming water-wet; (b) shampoo composite of effective dose is applied on hair, and (c) water rinsing shampoo composite from hair.These steps can be as required repeatedly, to reach look for clean, conditioning and anti-dandruff efficacy.
v purposes
The invention still further relates to the purposes of described shampoo care composition in the hair washing/hair products for the preparation of clean and conditioning hair.The invention still further relates to the purposes of PPG-3 Octyl Ether as hair conditioner, more specifically, relate to the purposes of PPG-3 Octyl Ether in the shampoo care composition for the preparation of clean and conditioning hair.The inventor finds by research, the use of PPG-3 Octyl Ether can make hair gloss degree be significantly improved, make that hair is smooth more easily to be arranged, entanglement can effectively remove hair flushing time, effectively prevent that hair is short-tempered, for can effectively prevent the local excessive deposition of polysiloxanes on hair containing the product of polysiloxane, make polysiloxanes can more efficiently be evenly distributed in root of hair to sending out the tip.
Embodiment
It is below the example of the indefiniteness of shampoo care composition of the present invention.Providing of these embodiment is only for illustrative purposes, and should not be construed as limitation of the invention.It will be understood by those skilled in the art that and can without departing from the spirit and scope of the present invention, carry out many changes and adjustment to the present invention.In description of the present invention and following instance, unless stated otherwise, all concentration is all percetage by weight." a small amount of material " refers to those optional materials, as antiseptic, viscosity modifier, pH adjusting agent, spice, foam booster etc.Those skilled in the art are very clear, and the selection of these a small amount of materials will be changed for the preparation of the physicochemical property of specific components of the present invention along with selected.
The preparation method of the shampoo care composition of the embodiment of the present invention is as follows: take the example I in table 1 as example, A phase component mix and blend being heated to 75-80 ℃ in agitated kettle continues to keep stirring within 15 minutes, to make its mix homogeneously, B phase component mix and blend being heated to 60-65 ℃ in another agitated kettle continues to keep stirring within 15 minutes, to make its mix homogeneously, the A phase component of mix homogeneously is cooled to after 60-65 ℃, by the B phase component of mix homogeneously and A phase component mixing and stirring and cool to 40-45 ℃, after C phase component being added one by one in the mixture of A and B phase, stir 30 minutes, obtain the example I shampoo in table 1.
1. Preparation Example 1 (example I-VII)
Prepare example I-VII with said method, shown in its concrete table 1 composed as follows.
The composition of table 1 example I-VII
2. Preparation Example 2 (example VII A I-X and I)
Example VII A I-X and example I (not containing PPG-3 Octyl Ether) are prepared according to said method, shown in its concrete table 2 composed as follows.
The composition of table 2 example VII A I-X and example I
2. effect embodiment (conditioning effect evaluation)
Effect evaluation method for Preparation Example 1 (example I-VII) is: the compositions of Preparation Example I to VII compares test, issues test crowd (each 160 people) contrast and uses.
Professional test personnel design use questionnaire, and while using shampoo sample, according to identical method hair washing, shampoo uses two weeks at least continuously, and answers professional questionnaire.Tester according to oneself feel mark.Standards of grading adopt 7 points of systems, and 1 point the poorest, and 7 points best, and mark is more high better.
Effect evaluation method for Preparation Example 2 (example VII A I-X and example I in contrast) is: by example I in Preparation Example 2 and example VII A I, IX, the compositions of X compares test, by the tester of salon of professional training, every tester's of one group of 8 consumer hair is evenly divided into left half end and right half end, left side half a head to the same consumer and the right half a head respectively use a kind of shampoo hair washing respectively, wash and rear marking is evaluated in the left side and the right hair, standards of grading adopt ten point system, 1 be divided into the poorest, 10 be divided into best, mark is more high better.
Following table 3-4 is the data that respondent gathers product.
The conditioning performance questionnaire result of table 3 example I-VII
The conditioning performance questionnaire result of table 4 example VII A I-X and example I
(note: in table 3-4, the data representation of italics body tag is compared with comparative examples I, and t check P value is less than 0.05.)
Known according to above result, shampoo care composition of the present invention has excellent conditioning performance, reflection conditioning performance each concrete aspect there is outstanding general performance; Especially, compared with not containing the reference composition I of PPG-3 Octyl Ether, shampoo care composition of the present invention has significantly outstanding conditioning performance.
Claims (12)
1. a shampoo care composition, it comprises following component by weight:
A) 5% to 50% surfactant;
B) PPG-3 Octyl Ether and fixedness polysiloxanes, its two content sum is 0.1% to 10%, and the content of wherein said fixedness polysiloxanes is not less than 0.01% but not higher than 2.5%;
C) 0.01% to 3% cationic polymer; With
D) water of 50-80%.
2. according to the shampoo care composition of claim 1, the content sum of wherein said PPG-3 Octyl Ether and fixedness polysiloxanes be described compositions by weight 0.1% to 8.0%, be preferably 0.1% to 7.0%, more preferably 0.2% to 6.0%, more preferably 0.5% to 5.0%, more preferably 0.5% to 4.0%; And the content of wherein said fixedness polysiloxanes is not less than 0.05% but not higher than 3.0%, be preferably not less than 0.1% but not higher than 2.5%, be preferably not less than 0.1% but not higher than 2.0%.
3. according to the shampoo care composition of claim 1 or 2, wherein said surfactant is at least one being selected from anion surfactant, zwitterionic surfactant and non-ionic surface active agent.
4. according to the shampoo care composition of any one in claim 1-3, the content of wherein said surfactant is preferably by weight 5% to 25%, and more preferably 8% to 20%, most preferably be 10% to 18%.
5. according to the shampoo care composition of any one in claim 1-4, the viscosity of wherein said fixedness polysiloxanes at 25 ℃ is 20-2,000,000 centistoke, preferably 1,000-1,500,000 centistokes, most preferably 10,000-1,000,000 centistoke.
6. according to the shampoo care composition of any one in claim 1-5, wherein said cationic polymer is to be selected from one or more in cation guar gum, cassia gum Hydroxyproyl Trimethyl ammonia chloride, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, Polyquaternium-10, polyquaternary ammonium salt-11, Polyquaternium-67, polyquaternary ammonium salt-73, polyquaternary ammonium salt-74.
7. according to the shampoo care composition of any one in claim 1-6, the charge density of wherein said cationic polymer is between 0.1 to 4.0meq/g, be preferably charge density between 0.2 to 3.8meq/g, more preferably charge density is between 0.5 to 3.5meq/g, molecular weight is between 2500 to 2,500,000, be preferably molecular weight between 5000 to 2,000,000, more preferably molecular weight is between 10,000 to 1,000,000.
8. according to the shampoo care composition of any one in claim 1-7, the content of wherein said cationic polymer is preferably by weight 0.01% to 2.0%, and more preferably 0.01% to 1.5%, most preferably be 0.01% to 1.0%.
9. according to the shampoo care composition of any one in claim 1 to 8, it also comprises one or more in following component: dandruff removing agent, suspending agent, natural on-off cycles of hair growth regulator, antistatic additive, foam booster, viscosity modifier and thickening agent, pH adjusting agent, dyestuff, organic solvent or diluent etc.
10. a method for clean and conditioning hair, comprises shampoo care composition from any one in the claim 1 to 8 of effective dose to hair that use.
The purposes of the shampoo care composition of any one in the hair washing product for the preparation of clean and conditioning hair in 11. claim 1 to 9.
12.PPG-3 Octyl Ether is as the purposes of hair conditioner.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107550746A (en) * | 2017-09-13 | 2018-01-09 | 广州环亚化妆品科技有限公司 | A kind of hair care composition and its preparation method and application |
| CN108024934A (en) * | 2015-09-23 | 2018-05-11 | 株式会社爱茉莉太平洋 | Transparent preparation compositions for hair |
| CN111714412A (en) * | 2020-07-10 | 2020-09-29 | 湖南雪天精细化工股份有限公司 | Water-soluble hair conditioner and preparation method and application thereof |
| CN112022741A (en) * | 2020-07-28 | 2020-12-04 | 名臣健康用品股份有限公司 | Mild low-stimulation hair washing mousse and preparation method thereof |
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| CN101632626A (en) * | 2008-06-27 | 2010-01-27 | 拜埃尔斯多尔夫股份公司 | Silicone-free conditioner for keratinic fibres |
| WO2010089228A1 (en) * | 2009-02-05 | 2010-08-12 | Rhodia Operations | Aqueous composition suitable as shampoo |
| CN102058493A (en) * | 2009-05-12 | 2011-05-18 | 赢创德固赛(中国)投资有限公司 | Cosmetic composition |
| CN102159593A (en) * | 2008-09-16 | 2011-08-17 | 路博润高级材料公司 | Cationic polymers and fixative applications therefor |
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| WO2006079632A1 (en) * | 2005-01-28 | 2006-08-03 | Basf Aktiengesellschaft | Use of a water-in-water emulsion polymers in the form of a thickener for cosmetic preparations |
| CN101632626A (en) * | 2008-06-27 | 2010-01-27 | 拜埃尔斯多尔夫股份公司 | Silicone-free conditioner for keratinic fibres |
| CN102159593A (en) * | 2008-09-16 | 2011-08-17 | 路博润高级材料公司 | Cationic polymers and fixative applications therefor |
| WO2010089228A1 (en) * | 2009-02-05 | 2010-08-12 | Rhodia Operations | Aqueous composition suitable as shampoo |
| CN102058493A (en) * | 2009-05-12 | 2011-05-18 | 赢创德固赛(中国)投资有限公司 | Cosmetic composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108024934A (en) * | 2015-09-23 | 2018-05-11 | 株式会社爱茉莉太平洋 | Transparent preparation compositions for hair |
| CN107550746A (en) * | 2017-09-13 | 2018-01-09 | 广州环亚化妆品科技有限公司 | A kind of hair care composition and its preparation method and application |
| CN107550746B (en) * | 2017-09-13 | 2021-07-13 | 广州环亚化妆品科技有限公司 | Hair care composition and preparation method and application thereof |
| CN111714412A (en) * | 2020-07-10 | 2020-09-29 | 湖南雪天精细化工股份有限公司 | Water-soluble hair conditioner and preparation method and application thereof |
| CN111714412B (en) * | 2020-07-10 | 2022-07-05 | 湖南雪天精细化工股份有限公司 | Water-soluble hair conditioner and preparation method and application thereof |
| CN112022741A (en) * | 2020-07-28 | 2020-12-04 | 名臣健康用品股份有限公司 | Mild low-stimulation hair washing mousse and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103845231B (en) | 2017-06-20 |
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