CN103845231B - Shampoo conditioning composition containing PPG-3 octyl ether - Google Patents
Shampoo conditioning composition containing PPG-3 octyl ether Download PDFInfo
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- CN103845231B CN103845231B CN201210514308.9A CN201210514308A CN103845231B CN 103845231 B CN103845231 B CN 103845231B CN 201210514308 A CN201210514308 A CN 201210514308A CN 103845231 B CN103845231 B CN 103845231B
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Abstract
A shampoo conditioning composition comprising a surfactant, PPG-3 octyl ether and a non-volatile silicone, a cationic polymer, and water is disclosed. The invention further discloses methods of cleansing and conditioning the hair by applying the shampoo conditioning compositions. In addition, the invention also discloses the application of the shampoo conditioning composition in preparing a shampoo product for cleaning and conditioning hair.
Description
Technical field
The present invention relates to a kind of conditioning shampoo composition, in particular it relates to a kind of include surfactant, PPG-3 octyl groups
The conditioning shampoo composition of ether and fixedness polysiloxanes, cationic polymer and water, the conditioning shampoo composition can
Improve the conditioning performance to hair while hair is cleaned.
Background technology
People are continuously increasing for improving the demand of hair conditioning in hair care product formula.Especially, it is necessary to
Wash the product that hair products aspect requires to possess conditioning performance while cleaning action is realized.
Many shampoo composites that cleaning hair and conditioning hair effect can be provided have been occurred in that in the market, this
A little shampoo composites contain detersive surfactant, cationic cellulose, cation guar gum, silicone conditioning agents etc. mostly
Various rinse additives.
However, these current products can not well meet the demand of people.For example, the performance of conditioner shampoo is at certain
The shampoo ability that conditioning polymer resistance is washed away during being washed away is depended in the degree of kind, i.e., so-called conditioning ingredients
" adhesive force ".Adhesive force can ensure that conditioner shampoo reaches required effect.But excessive attachment can cause shampoo cyclic washing
Some composition (particularly cationic polymer and silicone oil etc.) excessive buildups on hair and scalp afterwards.This accumulation can cause head
Hair quality sense is stiff and greasy, and also usually reduces glossiness and plentiful sense.On the other hand, with good cleaning efficacy (including
Anti-dandruff effect) and the compound action of conditioning performance be not easy to reach.For example, a kind of method for realizing nursing one's health effect is in shampoo
Using the cationic polymer of suitable high content in composition, but, can be with one kind not using the cationic polymer of high content
The mode of profit influences deposition of the material with cleaning action on hair and scalp and and then influence cationic polymer and the moon
Condensed phase is formed between ionic surface active agent.Therefore, realize that optimum balance therebetween is for a long time desired by people
's.
The content of the invention
The present inventor proposes, for a kind of preferable conditioning shampoo composition, need to consider to do, moist different aspect, including
Cardability and organoleptic attribute, particularly can in terms of in detail below comprehensive consideration and evaluate its conditioning performance：Good wet hair comb
Rationality, the soft and smooth sense of flushing, dry hair go entanglement, hair tail to go crude, elegant performance (not heavy), glossiness, etc..Based on above-mentioned
Consideration, the present inventor by many experiments, it was unexpectedly found that, shampoo composite of the invention can have excellent simultaneously
Cleaning action and conditioning performance, realize the demand.Specifically, the invention provides one kind comprising surfactant,
The shampoo care composition of PPG-3 Octyl Ethers and fixedness polysiloxanes, cationic polymer and water, the group of the component
Conjunction can effectively realize the demand.
Therefore, in the first aspect, the invention provides a kind of shampoo care composition, it is following that it includes by weight
Component：
A) 5% to 50% surfactant；
B) PPG-3 Octyl Ethers and fixedness polysiloxanes, content sum both it are 0.1% to 10%, and wherein institute
The content for stating fixedness polysiloxanes is not less than 0.01% but not higher than 2.5%；
C) 0.01% to 3% cationic polymer；With
D) water of 50-80%.
The invention further relates to clean the method with conditioning hair, including adjusted to the shampoo of the invention that hair applies effective dose
Reason composition.Moreover, it relates to the shampoo care composition is being prepared for cleaning the hair washing/shield with conditioning hair
Purposes in hair product.
Conditioning shampoo composition of the invention provides the good composition of cleaning action and conditioning performance.Present invention conditioning
The component of shampoo composite, including those components and preparation method, application method and purposes that can be optionally added.
Specific embodiment
I components
The surfactant included in conditioning shampoo composition of the invention can be selected from anion surfactant, two
Property ionic surface active agent and nonionic surfactant in one kind or its any combination.
A. surfactant
Conditioning shampoo composition of the invention comprising accounting for composition weight preferably from about 5% to 50%, preferably 8% to
40%, 10% to 30%, more preferably 10% to 25%, 10% to 18% surfactant.The surfactant can be
Composition brings cleaning action and frothing capacity.In the case of anion surfactant, it can be with dilute with water
Cationic polymer component (as mentioned below) of the invention forms condensed phase.Believe that the cohesion helps to provide of the present invention
Effect and opsonic action.
Anionic surfactant component not only includes common anion surfactant, is additionally included in the pH of composition
Down for anionic property coupling part zwitterionic surfactant, or combinations thereof.Suitable for combination of the invention
The example of the anion surfactant in thing includes but is not limited to sulfate, sulfonate, sarcosinate and sarcosine derivative.
Preferred anion surfactant is alkyl and alkyl ether sulfate.The example of alkyl sulfate has Texapon Special, coconut palm
Oil base ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, NaLS, sodium cocosulfate, lauryl sulfate list second
Hydramine, cocoyl diethanolamine, lauryl sulfate diethanolamine, triethanolamine lauryl sulfate, the second of lauryl sulfate three
Amine and its mixture, particularly preferably Texapon Special；The example of alkyl ether sulfate has laureth sulphur
Sour ammonium, laureth potassium sulfate, sodium laureth sulfate, laureth sulfuric acid monoethanol
Amine, laureth sulfate, laureth sulfuric acid triethanolamine, laureth
Sulfuric acid triethylamine and its mixture, particularly preferably laureth ammonium sulfate.The anionic surface of sulfonate is lived
The example of property agent is including such as tridecyl benzene sulfonate, neopelex, lauryl sulfosuccinates etc..Flesh ammonia
The example of acid and sarcosine derivative includes sodium lauryl sarcosinate, cocoyl sarcosine, cocoyl sarcosine and its mixture,
Wherein preferred sodium lauryl sarcosinate.
Amphoteric surfactant suitable for shampoo care composition of the invention is it is known in the art that those can be used for
Material in hair nursing or other personal care cleansing compositions, as described in following patent document：United States Patent (USP) 5,104,
646, United States Patent (USP) 5,106,609.These amphoteric surfactantes include the table that those are secondary aliphatic amine and tertiary amines derived thing
Face activating agent, wherein the aliphatic group can be the group of straight or branched, and one in the aliphatic group
Can contain about 8-18 carbon atom, another can include a kind of anionic hydrophilic group such as carboxyl, sulfonic acid with, sulfate radical, phosphorus
Acid group or phosphonate radical.Also include as aliphatic quaternary ammonium, quaternary phosphines and season sulfonium chemical combination suitable for amphoteric surfactant of the invention
The surfactant of the derivative of thing, one of aliphatic group contains about 8-18 carbon atom, and another can be comprising one kind
Anionic hydrophilic group such as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.The preferably amphion of glycine betaine
Compound.
B.PPG-3 Octyl Ethers
PPG-3 Octyl Ethers (PPG-3octyl ether) are the Octyl Ether of polypropylene glycol -3, generally in cosmetic composition
As solvent or carrier etc..Inventors have surprisingly discovered that, PPG-3 Octyl Ethers can be used as in conditioning shampoo composition, rise
To the effect of excellent conditioner.Surprisingly, it was found that by using PPG-3 Octyl Ethers, can substantially reduce not
Desired conditioning performance is realized in the case of the consumption of Y 7175, so as to conditioning effect can be substantially improved.Especially
Ground, in terms of conditioning performance, the use of PPG-3 Octyl Ethers can make hair gloss be significantly improved, and make that hair is smooth easy to be beaten
Reason, can effectively remove entanglement when hair is rinsed, and effectively prevent hair short-tempered, can be effective for the product containing polysiloxane
Prevent local excessive of the polysiloxanes on hair from depositing, be distributed in root of hair to hair with enabling polysiloxanes more efficient uniform
The tip.
C. fixedness polysiloxanes
Fixedness polysiloxanes in conditioning shampoo composition of the invention is usually used conditioner, and its is normal
It is used to adjust dry comb and wet comb performance, hair sense, brightness and the easy property arranged.
Usable fixedness polysiloxanes include polyalkylsiloxane, polyarylsiloxane, poly- alkaryl siloxanes,
Polyether siloxane copolymer and its mixture.Terms used herein " fixedness " means the silicone material at ambient conditions
With low-down or no significant vapour pressure.Preferably insoluble fluid.Preferably, the poly- silica of fixedness of the invention
The viscosity at 25 DEG C of alkane be 20-2,000,000 centistoke, preferably 1,000-1,500,000 centistokes, most preferably 10,000-1,
000,000 centistoke.
On the other hand, the PPG-3 Octyl Ethers and fixedness polysiloxanes for containing in conditioning shampoo composition of the invention
Content sum is preferably 0.1% to 10% by weight, and the content of wherein described fixedness polysiloxanes is not less than
0.01% but not higher than 2.5%.Preferably, combined described in the PPG-3 Octyl Ethers and fixedness polysiloxane level sum
Thing by weight 0.1% to 8.0%, preferably 0.1% to 7.0%, 0.2% to 6.0%, more preferably 0.3% to
5.0%, 0.5% to 5.0%, more preferably 0.5% to 4.0%, 0.5% to 3.0%, 0.5% to 2.0%；And wherein institute
The content for stating fixedness polysiloxanes is not less than 0.05% but not higher than 3.0%, preferably not less than 0.1% but is not higher than
2.5%, preferably not less than 0.1% but not higher than 2.3%, more desirably not less than 0.1% but not higher than 2.2%, preferably not less than
0.1% but not higher than 2.1%, preferably not less than 0.1% but not higher than 2.0%.
The instantiation of usable fixedness polysiloxanes includes such as dimethyl silicone polymer, and it is available from such as
General Electric Company'sIt is with the Dow Coming 200 of DowCorning with the series of SF 96
Row；Usable Polyalkylaryl siloxane includes such as PSI, and it is available from such as General
The methyl phenyl fluids of SF 1075 of Electric Company or 556 cosmetic fluids of Dow Corning；Usable is poly-
Ether silicone copolymers include the dimethyl silicone polymer (such as DowComing DC-1248) of such as polypropylene oxide.
The visible such as US2,826,551 of bibliography on fixedness polysiloxanes, US3,964,500, US4,364,837,
US5,573,709, BP 849,433 and PCT application WO83/08787.These open source literatures are incorporated herein by reference.
D. cationic polymer
Cationic polymer can promote the deposition of polysiloxanes during shampoo use, washing in shampoo, dilute
The flocculation formed in journey can be helped effectively including the component deposition including polysiloxanes on hair fiber.
The selection of the cationic polymer in the present invention and amount need to cause that it is dissolved in shampoo composite, and excellent
Shampoo composite is dissolved in when being selected in dilution meets condensed phase.Preferably, when shampoo composite is diluted (such as in washing
During), condensed phase can be formed between cationic polymer of the invention and anion surfactant.Believe the sun of polymer
The anionicsite of ionic portions and surfactant combines to form insoluble compound, their precipitation (cohesions in dilution
Phase).The complex coacervation of cationic polymer can also mutually be formed together with other the optional anionic groups in shampoo composite.
The formation of condensed phase is usually relevant with the factor such as molecular weight, concentration of component, ionic strength, charge density, pH.On condensed phase body
The effect description of system and these parameters is in the following references：J.Caelles etc., Cosmetics＆Toiletries, 1991 year
The 49-54 pages of volume 106；And D.J.Burgess, Journal of Colloid and Interface Science, 1990
The 227-238 pages of volume 140 of year.All these documents are incorporated herein.
Believe that condensed phase can provide opsonic action, when using product particularly when hair is soaked, by helping to nurse one's health
Agent is deposited on hair and scalp and provides conditioning effect.
Mean molecule quantity suitable for cationic polymer of the invention is for about 2,500 to about 2,500,000, preferably from about 5,
000 to about 2,000,000, more preferably from about 10,000 to about 1,000,000.PH when the expection of shampoo care composition is used
Under, the cationic charge density for measuring polymer is about between 0.1 to 4.0meq/g, preferably from about 0.2 to 3.8meq/g, more preferably
About 0.5 to 3.5meq/g, particularly preferably about 0.6 to 3.0meq/g.The charge density of cationic polymer can be according to
Kjeldahl methods are determined.It will be appreciated by those skilled in the art that the charge density containing amino polymer will change with pH.Cause
This, pH during measure is usually pH value when shampoo composite is expected to use, it typically is about 3 to about 9, preferably from about 4 to about 7.
The content of present composition cationic polymer is by weight 0.01% to 3.0%, preferably 0.01%
To 2.0%, more preferably 0.01% to 1.5%, most preferably 0.01% to 1.0%.
Cationic polymer in conditioning shampoo composition of the invention may include following material：Cationic polysaccharide, ethene
Base monomer copolymer, vinylpyrrolidone copolymer, cation-modified protein and some polymer quaternary salts.
Cationic polysaccharide：
Cationic polysaccharide is based on C5-C6Sugar those polymer and on polysaccharide main chain grafted cation part and have
The derivative of cationic, including quaternary ammonium or cationic amine substitution monomeric unit and optionally combined with non-cationic monomer
Homopolymers, copolymer, ter-polymers of formation etc..Polysaccharide can be made up of a type of sugar or more than one sugar.Sun
Ion amine can be primary amine, secondary amine or tertiary amine (preferably secondary amine or tertiary amine), this depend on shampoo composite particular types and its
The pH value selected.Monomer can make straight or branched.The nonlimiting examples of cationic polysaccharide are described in documents below
In：CTFA Cosmetic Ingredient Dictionary, the 3rd edition, 1982.The document is incorporated herein by reference.
Cationic polymer includes cationic cellulose and hydroxyethyl cellulose；Cationic starch and hydroxyalkyl starch；Base
In the cationic polymer of the galactomannans for being referred to as guar gum obtained from the endosperm of cluster bean；Based on pectinose plant
The cationic polymer of glue；Cationic polymer derived from xylose polymer；Cation derived from marine alga glycopolymers gathers
Compound；Cationic polymer (such as inulin) derived from fructose polymer；Based on the sugared cationic polymer containing acid (for example
Galacturonic acid and glucuronic acid)；Cationic polymer based on amine sugar (such as galactolipin is pressed and aminoglucose)；Based on five and hexa-atomic
The cationic polymer of the polyalcohol of ring；Cationic polymer based on galactose monomers；And the sun based on mannosyl units
Ionomer；Etc..Preferably cationic cellulose and hydroxyethyl cellulose；Cationic starch and hydroxyalkyl starch；Base
In the cationic polymer of guar gum, and their mixture.
Cationic cellulose derivative
Preferred cationic cellulose polymer is included but is not limited to, can be from Amerchol companies with its series of polymers
PolymerWithThose bought, as the epoxide reactive hydroxyethyl cellulose replaced with trimethyl ammonium
Salt, is referred to as (the JR for for example being obtained from Amerchol companies of Polyquaternium 10 in industry).Another preferably class
The non-limiting example of the cationic cellulose of type includes the epoxide reactive ethoxy replaced with lauryl dimethyl ammonium
The polymeric quaternary ammonium salts of cellulose, are referred to as Polyquaternium 24 and (are for example obtained from Amerchol companies in industry
Polymer LM-)。
There are those with the hydroxyethyl celluloses of diallyldimethylammonium chloride reaction containing season suitable for of the invention
The cellulose copolymer of nitrogen, is referred to as polyquaternium 4 and (is for example obtained from National Starch companies in industryH-100).It is described in United States Patent (USP) 3962418 suitable for the cellulose ether containing quaternary nitrogen of the invention, it is adaptable to
The cellulose of other etherificates of the invention and the copolymer of starch are described in United States Patent (USP) 3958581.Above-mentioned patent document
It is both incorporated herein by reference.
Cation Guar polymer
It is cation Guar polymer suitable for cationoid polymer of the invention.Guar is the substituted of positively charged
Galactomannans (Guar) gum derivative.The molecular weight of these derivatives is typically about 50,000 to about 2,500,000, preferably
About 50,000 to about 1,000,000, more preferably from about 100,000 to about 350,000.Preferred specific cation Guar polymer
Instantiation includes：C 13S, its cationic charge density is 0.8meq/g (being obtained from Rhodia Company)；C 17, its cationic charge density is 1.6meq/g (being obtained from RhodiaCompany).Other suitable sun from
Sub- Guar polymer includes the cation Guar polymer of hydroxypropylation.Also other suitable cationic polymers include etherificate
Guar copolymer, some of them example describe in United States Patent (USP) 3958581, present invention introduces the patent document as ginseng
Examine.
Terms used herein " polymer " includes a kind of material of monomer polymerization generation or has two kinds of monomers polymerizations to produce
Raw material (i.e. copolymer) or the material or naturally occurring polymer that are produced by various of monomer polymerization.It is excellent in the present invention
The cationic polymer that choosing is used is cation guar gum, cassia gum Hydroxyproyl Trimethyl ammonium chloride, polyquaternium -2, polyquaternary amine
In salt -4, polyquaternium -7, Polyquaternium-10, polyquaternium -11, Polyquaternium-67, polyquaternium -73, polyquaternium -74
One or more.
Water
In conditioning shampoo composition of the invention, in addition to said components and other auxiliary elements, with water (preferably go from
Sub- water) add to requirement.
II. optional components
Shampoo care composition of the invention is also optionally comprising one or more in following components：Dandruff removing agent,
Suspending agent, natural on-off cycles of hair growth conditioning agent, antistatic additive, foam booster, viscosity modifier and thickener, pH adjusting agent, dyestuff, have
Machine solvent or diluent etc..These components and its amount can suitably be selected according to being actually needed for product, and be added to this hair
In bright composition.
Dandruff removing agent
Dandruff removing agent of the invention can be the material with antimicrobial acivity, for example pyrithione, selenium sulfide, micro-
Granulation sulphur and combinations thereof.Preferably pyrithione.The example of one non-limiting dandruff removing agent is ketoconazole.
Suspending agent
Can in certain embodiments be included in shampoo care composition of the invention and account for composition weight about 0.1% to about
10%th, preferably from about 0.3% to about 5.0%, more preferably from about 0.3% to about 2.5% suitable for the suspending agent on hair or skin.
The example of these suspending agents can be included but is not limited to：Acyl derivative, long chain amine oxide, xanthans and its mixture.
Natural on-off cycles of hair growth conditioning agent
Growth regulator is optionally included in composition of the invention.This can be strengthened on the natural on-off cycles of hair growth conditioning agent
The molecule of the natural on-off cycles of hair growth effect of inventive composition." the natural on-off cycles of hair growth regulation " is referred to：Stimulate natural on-off cycles of hair growth and/or head
Hair thickening；Prevention, reduction, prevention and/or delay hair damage and/or hair tail off；Increase the speed of growth of hair；Induce more
The formation of many hair clusters；Increase hair cluster diameter；Make hair cluster elongated；Hair growth, and combinations thereof.
Antistatic additive
The optional antistatic additive that can be used can be the cationic surfactant of such as water-insoluble, and concentration is usual
It is the 0.1% to about 5% of composition weight.Such antistatic additive should not appreciably affect the performance of shampoo care composition
And benefit；Especially, the antistatic additive should not disturb anion surfactant.The specific non-limit of suitable antistatic additive
Qualitative example is three spermaceti methyl ammoniums.
Foam booster
Optional foam booster for shampoo care composition of the invention includes fatty alkanol amide, particularly C1-C3
Alkanolamide.The specific non-limiting example of such foam booster includes coconut monoethanol amide, cocounut oil diethanol acyl
Amine and its mixture.
Viscosity modifier and thickener
Optional viscosity modifier and thickener for shampoo care composition of the invention are generally used for available phosphorus
In shampoo care composition of the invention so that overall viscosity is for about 1,000 centistoke to about 20,000 centistokes, preferably from about 3,000
Centistoke is to about 10,000 centistokes.The specific non-limiting example of this viscosity modifier and thickener includes sodium chloride, sulfuric acid
Sodium and its mixture.
III production methods
Shampoo care composition of the invention can by it is any known or other be effectively adapted to provide for shampoo composite
Technology prepare, on condition that resulting composition provides conditioning performance outstanding as described in the present invention.Prepare of the invention
The method of shampoo care composition includes conventional preparation and hybrid technology.For example, may be referred to as in United States Patent (USP) 5837661
Described method.
IV application methods
On the other hand, present invention also offers a kind of method cleaned with conditioning hair, methods described is included to hair
And/or scalp applies the shampoo care composition of the invention of effective dose.Specifically, shampoo care composition of the invention with
The usual manner of cleaning and conditioning hair or skin is used.The composition can be coated on and soaked in advance (generally with water)
Other positions of hair or body, composition then rinsed or rinsed out.The composition of effective dose generally ranges from about 1 gram
To about 50 grams, preferably from about 1 gram to about 20 grams.It is applied to generally include to rub composition in hair on hair smear, so that
Largely or entirely hair is contacted with composition.
For cleaning following steps are specifically included with the method for conditioning hair：A () soaks Hair grooming water；B () will be effective
The shampoo composite of amount is applied on hair, and (c) rinses shampoo composite with water from hair.These steps can be according to need
Will repeatedly, to reach sought cleaning, conditioning and anti-dandruff efficacy.
V purposes
Prepared for cleaning the hair washing/hair products with conditioning hair the invention further relates to the shampoo care composition
In purposes.The invention further relates to PPG-3 Octyl Ethers as hair conditioner purposes, more particularly, to PPG-3 Octyl Ethers
Purposes in preparing for cleaning the shampoo care composition with conditioning hair.The present inventor has found that PPG-3 is pungent by studying
The use of base ether can make hair gloss be significantly improved, and make that hair is smooth to be easier to arrange, and can effectively remove hair flushing
When entanglement, effectively prevent hair short-tempered, can effectively prevent polysiloxanes on hair for the product containing polysiloxane
Local excessive deposition, be distributed in root of hair with enabling polysiloxanes more efficient uniform to sending out the tip.
Embodiment
The following is the non-limiting example of shampoo care composition of the invention.These embodiments be given merely to
Descriptive purpose, and should not be construed as limitation of the invention.It will be understood by those skilled in the art that can not depart from it is of the invention
On the basis of spirit and scope, many changes and adjustment are carried out to the present invention.In specification of the invention and following instance, remove
Non-specifically illustrates that all of concentration is all percetage by weight." a small amount of material " refers to those optional materials, such as preservative,
Viscosity modifier, pH adjusting agent, spices, foam booster etc..It will be obvious to a person skilled in the art that the choosing to these a small amount of materials
Select as selected changes for preparing the physicochemical property of specific components of the invention.
The preparation method of the shampoo care composition of the embodiment of the present invention is as follows：By taking the embodiment I in table 1 as an example, stirring
To mix in pot mix A phase components and be heated to 75-80 DEG C and continue to be kept stirring for being well mixed it in 15 minutes, in another stirring
The mixing of B phase components is heated into 60-65 DEG C in pot to continue to be kept stirring for being well mixed it in 15 minutes, is made well mixed
After A phase components cool to 60-65 DEG C, by well mixed B phase components and A phase components mixing and stirring and 40-45 is cooled to
DEG C, stirring 30 minutes, that is, obtain the embodiment I shampoos in table 1 after C phase components are added one by one in the mixture of A and B phases.
1. embodiment 1 (embodiment I-VII) is prepared
Method described above is prepared for embodiment I-VII, and its concrete composition is as shown in table 1 below.
The composition of the embodiment I-VII of table 1
2. embodiment 2 (embodiment VIII-X and I) is prepared
Embodiment VIII-X and embodiment I (without PPG-3 Octyl Ethers) are prepared for according to the above method, its concrete composition is such as
Shown in table 2 below.
The composition of the embodiment VIII-X of table 2 and embodiment I
2. effect example (conditioning effect evaluation)
For prepare embodiment 1 (embodiment I-VII) effect evaluation method be：Prepare the composition of embodiment I to VII
Test is compared, test crowd (each 160 people) contrast is issued and is used.
Professional test personnel design uses questionnaire, is washed hair in the same manner during using hair washing water sample, and shampoo is extremely
It is few continuous using two weeks, and answer professional questionnaire.Tester according to oneself feel scored.Standards of grading are made using 7 points,
1 point worst, and 7 points best, and the higher the better for fraction.
For prepare embodiment 2 (embodiment VIII-X and as compare embodiment I) effect evaluation method be：Will
Embodiment I and embodiment VIII, IX, the composition of X compare test in preparation embodiment 2, are surveyed by the salon of professional training
Examination personnel, are uniformly divided into left half end and right half end, respectively to same by the hair of one group of every tester of 8 consumers
The left side half a head and the right half a head of name consumer are respectively washed hair using a kind of shampoo, and the left side and the right hair are commented after washing
Valency is given a mark, and standards of grading use ten point system, and 1 point is worst, and 10 points is best, and the higher the better for fraction.
Table 3 below -4 is the data that respondent collects to product.
The conditioning performance questionnaire result of the embodiment I-VII of table 3
The conditioning performance questionnaire result of the embodiment VIII-X of table 4 and embodiment I
(note：The data of italic font mark are represented compared with comparative examples I in table 3-4, and t inspection P values are less than 0.05.)
It can be seen from result above, shampoo care composition of the invention has excellent conditioning performance, is nursed one's health in reflection
Each specific aspect of performance has outstanding general performance；Especially, with the reference composition I phases for not containing PPG-3 Octyl Ethers
Than shampoo care composition of the invention has significantly prominent conditioning performance.
Claims (11)
1. a kind of shampoo care composition, it includes following components by weight：
A) 5% to 50% surfactant；
B) PPG-3 Octyl Ethers and fixedness polysiloxanes, content sum both it be 0.1% to 10%, and wherein it is described not
The content of Y 7175 is not less than 0.01% but not higher than 2.5%；
C) 0.01% to 3% cationic polymer；With
D) water of 50-80%,
Wherein, the surfactant is selected from Texapon Special, laureth ammonium sulfate, cocoyl sarcosine
Sodium, and glycine betaine zwitterionic compound；
The fixedness polysiloxanes is selected from polyalkylsiloxane, polyarylsiloxane, poly- alkaryl siloxanes, polyethers silica
Alkyl copolymer and its mixture；
The cationic polymer is selected from cation guar gum, cassia gum hydroxypropyl-trimethyl ammonium chloride, polyquaternium -2, poly- season
Ammonium salt -4, polyquaternium -7, Polyquaternium-10, polyquaternium -11, Polyquaternium-67, polyquaternium -73, polyquaternium -74
In one or more；
Above-mentioned each component sum is no more than 100%.
2. shampoo care composition according to claim 1, wherein the PPG-3 Octyl Ethers and fixedness polysiloxanes contain
Amount sum is 0.1% to 8.0% by weight of the composition；And the content of wherein described fixedness polysiloxanes is not
Less than 0.05% but not higher than 2.5%.
3. according to the shampoo care composition of claim 1 or 2, wherein the content of the surfactant is by weight 5%
To 25%.
4. according to the shampoo care composition of claim 1 or 2, wherein viscosity of the fixedness polysiloxanes at 25 DEG C
It is 20-2,000,000 centistokes.
5. according to the shampoo care composition of claim 1 or 2, wherein the charge density of the cationic polymer 0.1 to
Between 4.0meq/g, molecular weight is between 2500 to 2,500,000.
6. according to the shampoo care composition of claim 1 or 2, wherein the content of the cationic polymer is for by weight
0.01% to 2.0%.
7., according to the shampoo care composition of claim 1 or 2, it is also comprising one or more in following components：Anti-dandruff
Agent, suspending agent, natural on-off cycles of hair growth conditioning agent, antistatic additive, foam booster, viscosity modifier, pH adjusting agent, dyestuff, You Jirong
Agent or diluent.
8., according to the shampoo care composition of claim 1 or 2, it also includes thickener.
9. a kind of method cleaned with conditioning hair, including the perfume (or spice) that any one of the claim 1 to 6 of effective dose is applied to hair
Ripple care composition.
10. the shampoo care composition of any one of claim 1 to 8 is being prepared for cleaning the hair washing product with conditioning hair
In purposes.
11.PPG-3 Octyl Ethers prevent polysiloxanes local mistake on hair in the shampoo care composition containing polysiloxane
Degree is deposited, makes the equally distributed purposes of polysiloxanes.
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| CN201210514308.9A CN103845231B (en) | 2012-12-04 | 2012-12-04 | Shampoo conditioning composition containing PPG-3 octyl ether |
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| CN103845231B true CN103845231B (en) | 2017-06-20 |
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| KR102418098B1 (en) * | 2015-09-23 | 2022-07-08 | (주)아모레퍼시픽 | A transparent composition for hair |
| CN107550746B (en) * | 2017-09-13 | 2021-07-13 | 广州环亚化妆品科技有限公司 | Hair care composition and preparation method and application thereof |
| CN111714412B (en) * | 2020-07-10 | 2022-07-05 | 湖南雪天精细化工股份有限公司 | Water-soluble hair conditioner and preparation method and application thereof |
| CN112022741A (en) * | 2020-07-28 | 2020-12-04 | 名臣健康用品股份有限公司 | Mild low-stimulation hair washing mousse and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006079632A1 (en) * | 2005-01-28 | 2006-08-03 | Basf Aktiengesellschaft | Use of a water-in-water emulsion polymers in the form of a thickener for cosmetic preparations |
| CN101632626A (en) * | 2008-06-27 | 2010-01-27 | 拜埃尔斯多尔夫股份公司 | Silicone-free conditioner for keratinic fibres |
| WO2010089228A1 (en) * | 2009-02-05 | 2010-08-12 | Rhodia Operations | Aqueous composition suitable as shampoo |
| CN102058493A (en) * | 2009-05-12 | 2011-05-18 | 赢创德固赛(中国)投资有限公司 | Cosmetic composition |
| CN102159593A (en) * | 2008-09-16 | 2011-08-17 | 路博润高级材料公司 | Cationic polymers and fixative applications therefor |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006079632A1 (en) * | 2005-01-28 | 2006-08-03 | Basf Aktiengesellschaft | Use of a water-in-water emulsion polymers in the form of a thickener for cosmetic preparations |
| CN101632626A (en) * | 2008-06-27 | 2010-01-27 | 拜埃尔斯多尔夫股份公司 | Silicone-free conditioner for keratinic fibres |
| CN102159593A (en) * | 2008-09-16 | 2011-08-17 | 路博润高级材料公司 | Cationic polymers and fixative applications therefor |
| WO2010089228A1 (en) * | 2009-02-05 | 2010-08-12 | Rhodia Operations | Aqueous composition suitable as shampoo |
| CN102058493A (en) * | 2009-05-12 | 2011-05-18 | 赢创德固赛(中国)投资有限公司 | Cosmetic composition |
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