CN102058493A - Cosmetic composition - Google Patents
Cosmetic composition Download PDFInfo
- Publication number
- CN102058493A CN102058493A CN2009101408252A CN200910140825A CN102058493A CN 102058493 A CN102058493 A CN 102058493A CN 2009101408252 A CN2009101408252 A CN 2009101408252A CN 200910140825 A CN200910140825 A CN 200910140825A CN 102058493 A CN102058493 A CN 102058493A
- Authority
- CN
- China
- Prior art keywords
- carboxylic acid
- alkyl carboxylic
- component
- composition
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 93
- 239000002537 cosmetic Substances 0.000 title claims abstract description 52
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 87
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 37
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 37
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 22
- 150000002148 esters Chemical class 0.000 claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 17
- 229920000570 polyether Polymers 0.000 claims abstract description 17
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 15
- 150000003077 polyols Chemical class 0.000 claims description 19
- 229920002545 silicone oil Polymers 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 16
- 239000000194 fatty acid Substances 0.000 claims description 16
- 229930195729 fatty acid Natural products 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 150000004665 fatty acids Chemical class 0.000 claims description 14
- 229920005862 polyol Polymers 0.000 claims description 14
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 239000000975 dye Substances 0.000 claims description 10
- 238000002834 transmittance Methods 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- XXBAQTDVRLRXEV-UHFFFAOYSA-N 3-tetradecoxypropan-1-ol Chemical compound CCCCCCCCCCCCCCOCCCO XXBAQTDVRLRXEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000005711 Benzoic acid Substances 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 235000010233 benzoic acid Nutrition 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229940116987 ppg-3 myristyl ether Drugs 0.000 claims description 6
- 230000032050 esterification Effects 0.000 claims description 5
- 238000005886 esterification reaction Methods 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 125000000217 alkyl group Polymers 0.000 claims description 4
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 4
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 4
- 229940070765 laurate Drugs 0.000 claims description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 claims description 3
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 238000005259 measurement Methods 0.000 claims description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 2
- IDTQVQPVUYLMJJ-UHFFFAOYSA-N 2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOCCOCCOCCOCCOCCO IDTQVQPVUYLMJJ-UHFFFAOYSA-N 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- IIRDTKBZINWQAW-UHFFFAOYSA-N hexaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCO IIRDTKBZINWQAW-UHFFFAOYSA-N 0.000 claims description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 claims description 2
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 claims description 2
- 230000002269 spontaneous effect Effects 0.000 claims description 2
- 229940093609 tricaprylin Drugs 0.000 claims description 2
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 3
- 125000003827 glycol group Chemical group 0.000 abstract 2
- 239000000047 product Substances 0.000 description 65
- 238000012360 testing method Methods 0.000 description 37
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 34
- 235000014593 oils and fats Nutrition 0.000 description 21
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 238000010257 thawing Methods 0.000 description 11
- 150000001721 carbon Chemical group 0.000 description 6
- 229940008099 dimethicone Drugs 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000013517 stratification Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 1
- LWLRMRFJCCMNML-UHFFFAOYSA-N 2-ethylhexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)CCCC LWLRMRFJCCMNML-UHFFFAOYSA-N 0.000 description 1
- MWKPHOIHTLQZIY-UHFFFAOYSA-N 2-hexyldecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC MWKPHOIHTLQZIY-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- 244000056139 Brassica cretica Species 0.000 description 1
- 235000003351 Brassica cretica Nutrition 0.000 description 1
- 235000003343 Brassica rupestris Nutrition 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- RWFQWIHFWRHDTA-UHFFFAOYSA-N C(CCC)(O)O.C(CCCCCCCCCCCCCCC(C)C)(=O)O Chemical class C(CCC)(O)O.C(CCCCCCCCCCCCCCC(C)C)(=O)O RWFQWIHFWRHDTA-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 235000005956 Cosmos caudatus Nutrition 0.000 description 1
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 description 1
- 125000005586 carbonic acid group Chemical group 0.000 description 1
- 150000004653 carbonic acids Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- ZYNDJIBBPLNPOW-UHFFFAOYSA-N eurucic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCCCCCC(=O)OC ZYNDJIBBPLNPOW-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229940100554 isononyl isononanoate Drugs 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940089456 isopropyl stearate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- ZYNDJIBBPLNPOW-KHPPLWFESA-N methyl erucate Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(=O)OC ZYNDJIBBPLNPOW-KHPPLWFESA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- NJTGANWAUPEOAX-UHFFFAOYSA-N molport-023-220-454 Chemical compound OCC(O)CO.OCC(O)CO NJTGANWAUPEOAX-UHFFFAOYSA-N 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- SZHOJFHSIKHZHA-UHFFFAOYSA-N n-Tridecanoic acid Natural products CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical group C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- WQDGUYZIAJKLAB-UHFFFAOYSA-N octan-2-yl nitrite Chemical compound CCCCCCC(C)ON=O WQDGUYZIAJKLAB-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 description 1
- 230000001835 salubrious effect Effects 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- IIYFAKIEWZDVMP-NJFSPNSNSA-N tridecane Chemical class CCCCCCCCCCCC[14CH3] IIYFAKIEWZDVMP-NJFSPNSNSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/03—Liquid compositions with two or more distinct layers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a cosmetic composition, which comprises (1) 20 to 40 weight percent of polydimethylsiloxane component with the viscosity of 5 to 50 cps, (2) 10 to 35 weight percent of amphipathic polyether glycol and alkyl carboxylic acid ester component and (3) 25 to 50 weight percent of polyalcohol component, wherein the amphipathic polyether glycol and alkyl carboxylic acid ester component is the ester of polyether glycol and alkyl carboxylic acid; the polyether glycol structure part and the alkyl carboxylic acid structure part both have the carbon numbers of 6 to 20; and an absolute value of a difference between the carbon numbers of the polyether glycol structure part and the alkyl carboxylic acid structure part is less than or equal to 2. The cosmetic composition can be used as a makeup removing composition, has high makeup removing and cleaning capability after being uniformly shaken for use, and can be well flushed and leave the skin feelings of softness and glossiness. A three-layer structure is recovered after the cosmetic composition is stood for a certain time, and each layer is transparent. In addition, the cosmetic composition also can be used as a skin care product remaining on the surface of skin or a hair care product remaining on the surface of hair to improve the glossiness and enhance a combing function.
Description
Technical field
The present invention relates to a kind of cosmetic composition, said composition is divided into multilamellar after leaving standstill, and can be widely used in cosmetic industry, especially as cleansing composition.
Background technology
There has been the long period in biphase makeup removing liquid in personal care field, and it is apparent to be divided into two-layer liquid form product for clear, and it comprises water and oil phase usually, does not contain surface active ingredient, therefore because immiscible and do not have the emulsifying generation to be divided into two-layer.But such product has many shortcomings, only is to utilize oils and fats to dissolve the effect that color make-up plays makeup removing such as its effect, so the flushable property of tool not can only or be wiped by other detergent flush away.Be the biphase simple system of profit such as it again, therefore shaking up back layering excessive velocities, so use and inconvenience.It is exactly its double-deck transparent appearance that this series products attracts a major reason of consumer, and every layer also can be painted to different colors and makes it more eye-catching.Given this, the transparent trilaminar prescription of existing branch is developed, but its formulation principle mainly still utilizes the combination of water and two oil phases that intersolubility is very poor and density variation is bigger.Therefore this class prescription is not finally still had a washability.
Therefore, exist demand for the cleansing composition with flushable property, and wish that further this cleansing composition with flushable property can be divided into three layers after leaving standstill, each layer all was transparent before painted, and had branch interval velocity easy to use.
Summary of the invention
Therefore, the object of the present invention is to provide a kind of cosmetic composition with flushable property, and wish that further this cosmetic composition with flushable property can be divided into three layers after leaving standstill, each layer all was transparent before painted, and had branch interval velocity easy to use.
Beat allly be, the inventor finds that above-mentioned purpose is achieved by a kind of like this cosmetic composition, and said composition comprises following component based on its gross weight:
(1) the polydimethylsiloxane component of 20-40wt.%, the viscosity of this component are 5-50cps (Bu Shi rotating cylinder viscometer, No. 2 rotors, rotating speed 100rpm, and measurement under 25 ℃);
(2) the amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester component of 10-35wt.%, it is the ester of polyether polyol and alkyl carboxylic acid, wherein the carbon number of polyether polyol structure division and alkyl carboxylic acid structure division is all between 6-20, and the absolute value of the difference of the carbon number of polyether polyol structure division and alkyl carboxylic acid structure division is smaller or equal to 2; And
(3) polyol component of 25-50wt.%.
Cosmetic composition of the present invention can be divided into three layers after leaving standstill, its unique distinction is that its each layer all is transparent, shake up the back use and have good makeup removing and clean ability, and because of having adopted amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester to obtain good flushable property with Action of Surfactant, stay soft after the flushing and slick skin feel, leave standstill a period of time after (2-60 minute) recover three-decker again.
Cosmetic composition of the present invention is thermodynamically stable laminar product, its implication is meant: after the compositions of this no dyeing is rocked mixing, leave standstill, in 2-60 divides clock time, said composition can have clear interfacial three layers spontaneous being divided into, and each layer all be transparent, and preferably the light transmittance of each layer is more than or equal to 80%.
More preferably, cosmetic composition of the present invention is three layer compositions with suitable minute interval velocity, and its implication is meant: cosmetic composition of the present invention is rocked mixing, after leaving standstill 5-20 minute, just can obtain having clear interfacial three-decker.
According to the present invention, cosmetic composition comprises the polydimethylsiloxane component, and the viscosity of this component is 5-50cps, is preferably 10-20cps (Bu Shi rotating cylinder viscometer, No. 2 rotors, rotating speed 100rpm, and measurement under 25 ℃).The polydimethylsiloxane that this polydimethylsiloxane component relates to is the straight chain polydimethylsiloxane preferably, for being the oligomer that directly is connected with methyl on main chain and the silicon atom with silica (Si-O) key.The molecular weight ratio of this polydimethylsiloxane is lower, has lower viscosity.For the present invention, the straight chain polydimethylsiloxane for example is octamethyltrisiloxane, decamethyl tetrasiloxane, ten dimethyl, five siloxanes etc.
In cosmetic composition of the present invention, the proportion of polydimethylsiloxane component is minimum relatively, therefore can appear at the upper strata usually.The molecular weight of polydimethylsiloxane is low more, and its proportion and viscosity are just more little, and stratified speed is just fast more, therefore in order to realize required branch interval velocity, can regulate by the viscosity of polydimethylsiloxane.The polydimethylsiloxane of viscosity more than 350cps is because of the reason of its density and viscosity, and can make is separated becomes difficult, therefore should not adopt.On the other hand, has volatile polydimethylsiloxane, be lower than the straight chain polydimethylsiloxane of 2cps such as viscosity, because evaporation rate is too fast, less residue in the system, also can cause system layering speed slow excessively, after 24 hours, still can't reach stable stratification state, therefore should not adopt.For the purpose of the present invention, in order to obtain acceptable branch interval velocity, the viscosity of the polydimethylsiloxane that the polydimethylsiloxane component is comprised can be 5-150cps usually, be preferably 10-50cps, condition is that the viscosity of the mixture (constituting the polydimethylsiloxane component) of all these polydimethylsiloxane is 5-50cps, and preferred 10-20cps gets final product.
Certainly, the present invention can use single kind of polydimethylsiloxane, also can use two or more polydimethylsiloxane, and for the latter, condition is that the viscosity of the mixture of all these polydimethylsiloxane is 5-50cps, and preferred 10-20cps gets final product.To this, those skilled in the art are to be understood that, when the present invention uses two or more polydimethylsiloxane, even the viscosity of wherein certain or some polydimethylsiloxane does not fall in the scope of 5-50cps, but as long as their overall viscosity when mixing are 5-50cps, preferred 10-20cps can use.Preferably, the viscosity of all polydimethylsiloxane of use is 5-50cps, preferred 10-20cps.
The polydimethylsiloxane component can be the product available from commodity DC200, the DC 225 by name of Dow Corning company, can also be by name available from the commodity of Evonik Degussa company
20,
50 product.
Polydimethylsiloxane component among the present invention is also referred to as dimethicone or methyl-silicone oil sometimes, and they are synonyms, can exchange use.
Consider cleaning capacity and layered effect, based on the gross weight of cosmetic composition of the present invention, the polydimethylsiloxane components contents is generally 20-40wt.%, is preferably 25-35wt.%.
Another important component in the cosmetic composition of the present invention is amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester, it is the ester of polyether polyol and alkyl carboxylic acid, wherein the carbon number of polyether polyol structure division and alkyl carboxylic acid structure division is all between 6-20, and the absolute value of the difference of the carbon number of polyether polyol structure division and alkyl carboxylic acid structure division is smaller or equal to 2.To this, polyether polyol is preferably polyoxypropylene polyol that polyether polyol that the glycerol condensation obtains, polyoxyethylene polyols that the ethylene oxide condensation obtains and/or propylene oxide condensation obtain etc., and the degree of polymerization is between 2-8; And alkyl carboxylic acid is preferably the fatty acid that carbon number is 6-20, and more preferably carbon number is the fatty acid of 6-16, for example caproic acid, sad, capric acid, lauric acid, tetradecanoic acid and hexadecanoic acid etc.In a preferred embodiment, this amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester comprises polyglycereol alkyl carboxylic acid ester and polyoxyethylated alkyl carboxylic acid ester.
For the polyglycereol alkyl carboxylic acid ester, the esters of preferred polyglycereol and fatty acid, further preferred average degree of polymerization is that polyglycereol and the carbon number of 3-5 are 8-16, are preferably the polyglyceryl fatty acid ester that the fatty acid esterification of 8-12 obtains, and wherein the absolute value of the difference of polyglycereol structure division and fatty acid structure part carbon number is smaller or equal to 2.As the example of this class ester, can mention as polyglycereol-3 decanoin that provides by Evonik Degussa company (
SOFT PC31), polyglycereol-4 decanoin (
SOFT PC41), polyglycereol-3 caprylate (
COSMO P813) and polyglycereol-4 laurate (
CARE PL 4).
For polyoxyethylated alkyl carboxylic acid ester, be preferably the esters of polyoxyethylene and fatty acid, further preferred average degree of polymerization is that polyoxyethylene and the carbon number of 2-8, preferred 5-8 are 6-18, the polyoxyethylene fatty acid ester that obtains of the fatty acid esterification of 8-16 preferably, wherein polyoxyethylene structure division and fatty acid structure partly separately the absolute value of difference of carbon number smaller or equal to 2.As the example of this class ester, can mention as PEG-6 decanoin, PEG-6 laurate, PEG-7 laurate and PEG-7 cocos nucifera oil acid esters.
In the present invention, the amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester can singlely use, and also can two or more be used in combination.Based on the gross weight of cosmetic composition of the present invention, amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester components contents is generally 10-35wt.%, is preferably 15-25wt.%.
The cosmetic composition of the present invention that exists for of amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester component provides good cleaning power and flushable property.Because density is moderate, so the major part of this component will appear at the intermediate layer.
Another important component in the cosmetic composition of the present invention is a polyhydric alcohol.Preferably, this polyhydric alcohol is glycerol and/or propylene glycol, preferably glycerol.Glycerol is because proportion appears at orlop more greatly and mainly.
Based on the gross weight of cosmetic composition of the present invention, the content of polyol component is generally 25-50wt.%, is preferably 25-35wt.%.
In addition, cosmetic composition of the present invention can also comprise water.The effect that has several respects of water: can reduce cost, can improve the salubrious property of product, of paramount importance is that the adding of water can make the intermediate layer thickening, thereby regulates intermediary amphipathic emollient easily mutually and orlop polyhydric alcohol amount mutually.Based on the gross weight of cosmetic composition of the present invention, the content of water is generally 10-30wt.%, is preferably 15-30wt.%.When cosmetic composition of the present invention used glycerol as polyol component, the part by weight of G ﹠ W was preferably between 2: 1～1: 2.
In order to improve the performance of cosmetic composition of the present invention, make it to have more suitable branch interval velocity, also can comprise non-silicone oil oils and fats in the cosmetic composition of the present invention.Adding non-silicone oil oils and fats can increase the speed of three phase separation, and polarity is big more, and the speed that is separated is fast more.Therefore can regulate the speed of cosmetic composition three phase separation of the present invention by this greasy kind and consumption.
Be applicable to that non-silicone oil oils and fats of the present invention comprises straight chain and/or side chain monobasic and/or the dicarboxylic acids with 2-44 carbon atom and has the saturated or undersaturated straight chain of 1-22 carbon atom and/or the monobasic and the binary esters of branched-chain alcoho.Similarly, as being used for non-silicone oil oils and fats of the present invention, also can using difunctionality aliphatic alcohols with 2-36 carbon atom and ester with simple function aliphatic carboxylic acid of 1-22 carbon atom.
As being used for non-silicone oil oils and fats of the present invention, can also specifically preferably use the esters of fatty acid with 12-22 carbon atom, as methyl ester and isopropyl ester, for example methyl laurate, methyl stearate, methyl oleate, methyl erucate, isopropyl palmitate, isopropyl myristate, isopropyl stearate and/or acid isopropyl.
In addition, as being used for non-silicone oil oils and fats of the present invention, also concrete preferred n-butyl stearate, the just own ester of lauric acid, oleic acid ester in the positive last of the ten Heavenly stems, the different monooctyl ester of stearic acid, Palmic acid ester in the different ninth of the ten Heavenly Stems, isononyl isononanoate, Palmic acid 2-Octyl Nitrite, lauric acid 2-ethyl hexyl ester, stearic acid 2-hexyl decyl ester, 2-Palmic acid octyl group dodecane ester, oleic oil alkene ester, erucic acid oil alkene ester and/or oleic acid mustard ester.
As being used for non-silicone oil oils and fats of the present invention, also especially suitable is the dicarboxylic acids esters, for example Di-n-butyl Adipate, n-butyl sebacate, adipic acid two (2-ethylhexyl) ester, succinic acid two (2-hexyl decyl) ester and/or Azelaic Acid two different tridecane esters.As being used for non-silicone oil oils and fats of the present invention, also especially suitable is diol-lipid, for example two oleic acid glycol esters, two different tridecanoic acid glycol esters, two (2 ethyl hexanoic acid) propylene glycol ester, two isostearic acid butanediol esters and/or two sad DOPCP.
It is same that what be suitable for is the triglyceride of relative long-chain, i.e. triple esters of glycerol and three acid molecules, and at least one is the acid molecule of a relative long-chain in these acid molecules.What can mention by way of example here is the fatty acid triglycercide class, and this comprises the triglyceride of the mixture of synthetic caprylic/capric, the triglyceride of industrial oleic acid, the triglyceride of isostearic acid and the triglyceride of Petiolus Trachycarpi/oleic mixture.
Operable in addition is the straight or branched aliphatic alcohols, for example oleyl alcohol or octyldodecanol, and also have aliphatic alcohol ethers, for example dicaprylyl ether, PPG-3 myristyl ether etc.
What be suitable for equally is crude vegetal, for example olive oil, Oleum Helianthi, soybean oil, Oleum Arachidis hypogaeae semen, rapeseed oil, almond oil, Petiolus Trachycarpi oil or Jojoba oil, and also has the liquid part of Oleum Cocois or palm shell oil, and also have animal oil, for example as the liquid part of sperm oil, neat's foot oil or Adeps Bovis seu Bubali.
As being used for non-silicone oil oils and fats of the present invention, can also use hydro carbons oils and fats, particularly liquid paraffin and isoparaffin.The greasy example of operable hydro carbons is paraffin oil, white mineral oil, 2-Methylpentadecane, poly decene, petroleum jelly, light liquid paraffin or squalane.
In addition, the esters of aryl carboxylic acid also is suitable, as benzoic esters, for example has the saturated or undersaturated straight or branched alcohols of 1-22 carbon atom and the benzoates that the benzoic acid esterification forms, for example benzoic acid iso stearyl ester and benzoic acid octyl group dodecane ester, preferred benzoic acid C
12-15Arrcostab.
As being used for non-silicone oil oils and fats of the present invention, can also use the carbonic diester class, as carbonic acid two-ethyl hexyl ester.
Be applicable to the preferred polarity of non-silicone oil oils and fats of the present invention be higher than equal white mineral oil have middle polarity and/or a high polar oils and fats.Oils and fats with middle polarity is carbonic acid two-ethyl hexyl ester, tricaprylin, benzoic acid C preferably
12-15Arrcostab and/or octyldodecanol; Have high polar oils and fats and preferably have the hydrophobicity oils and fats of polypropylene glycol (hereinafter referred is PPG) structure division, such as the PPG-3 myristyl ether that provides by Evonik Degussa company (
SOFT APM), the stearic alcohol ether of PPG-11 (
SOFT APS), the PPG-14 butyl ether (
SOFT PBE) and/or the stearic alcohol ether of PPG-15 (
SOFT E), preferred PPG-3 myristyl ether.These ether products it has been generally acknowledged that at cosmetic field and belong to hydrophobic oils and fats.
Excessive each layer transparency that cause easily of the greasy amount of the non-silicone oil of polarity descends, and slight muddiness just occurs.Therefore, based on the gross weight of cosmetic composition of the present invention, the common consumption of the non-silicone oil lubricant component of polarity is 0.1-10wt.%, and preferable amount is 0.5-5wt.%.
In addition,, can use coloring agent,, wherein upper strata, middle level and/or lower floor be carried out painted, especially carry out painted the intermediate layer as dyestuff in order to make the outward appearance of cosmetic composition of the present invention more attractive.The polarity of three layers of each layer of cosmetic product of the present invention is had nothing in common with each other.The inventor is surprised to find, and oil-soluble dyes can optionally dye to the intermediate layer of three layers of cosmetic product of the present invention, and keep the upper and lower not contaminated simultaneously, and water-soluble dye does not then have so outstanding selectivity.Preferably, can be used for oil-soluble dyes of the present invention and be selected from down group: D﹠amp; C yellow N ° 11 D C Yellow No. 10s; D﹠amp; C green N ° 6 solvents are green; D﹠amp; C violet N ° of 2 solvent violet 13 and D﹠amp; C red N ° 17 solvent red 23s.
The use amount of dyestuff can obtain the color purity and the lightness in dyeing district according to what, needs of product population and adjust, and this is conventional to those skilled in the art.
Cosmetic composition of the present invention just can make by general cosmetics preparation process, for example just can access after each component mix homogeneously, and it is thermodynamically stable three layers of product.
Cosmetic composition of the present invention can be divided into three layers after leaving standstill, and each layer all be transparent, and the light transmittance of each layer preferably can be up to 80% or higher.After this cosmetic composition shaken up, left standstill usually 2-60 minute, can form once more and have clear interfacial three layers.According to the present invention advantageously, control the viscosity of polydimethylsiloxane component and/or select greasy kind of the non-silicone oil of polarity and consumption by the dimethicone that mixes different viscosities, can realize that layer thoroughly separating the time that forms fine limit from mixing to three is 5-20 minute.
In general, two separating surfaces are divided into product roughly that 1: 1: 1 three-decker is that consumer is easy to accept.In fact, if expectation obtained roughly 1: 2: 3 or three layers of cosmetic product of 1: 2: 1 or other ratio roughly, can obtain by above-mentioned three components contents of suitable adjustment.
Though three layers of cosmetic product of the present invention can observe directly obvious two interfaces, which component each layer contains actually, and the distribution of each component in every layer is not fully aware of at present.
Though cosmetic composition product of the present invention is because of having good washability mainly as cleansing composition, but consider the mildness of this product and the performance of keeping humidity of polyether polyol alkyl carboxylic acid ester component, this product can also be used as and be deposited in the skin care item of skin surface, or is deposited in hair surface to increase the hair product of glossiness, raising cardability.
Set forth the present invention below by embodiment, but these embodiment should not be construed as limitation of the scope of the invention.
Embodiment
Embodiment 1
Shown in last table, fill a prescription,, promptly obtain cosmetic composition product 1 all components mix homogeneously.After leaving standstill 15 minutes, be observed visually this product and have roughly isopyknic three layers, the separating surface between every layer is clear, and middle one deck is a bluish violet, the two-layer up and down water white transparency that is.
During use, product 1 is rocked or shake mixing, get 0.5-1g subsequently and be applied in target site, easily the various color make-ups on the removal skin.Water is rinsed well, but and cleaning skin.Dermal sensation is along sliding soft after being used to complete.
Product 1 is called the upper, middle and lower by light to heavy three layers.Extend the middle position of each layer respectively with the disposable syringe syringe needle, carefully draw a part of sample.Adopting 2802 type ultraviolet-uisible spectrophotometers of Unico company, under 425nm wavelength condition, is that reference is respectively to the sample test light transmittance of the upper, middle and lower with the deionized water.According to the size of light transmittance, every layer transparency is marked:
Light transmittance 〉=90% is estimated 1 fen, and is transparent
Light transmittance 〉=80～＜90% is estimated 2 fens, little muddiness
Light transmittance 〉=30～＜80% is estimated 3 fens, and is translucent
Light transmittance 〉=5～＜30% is estimated 4 fens, and is opaque
Light transmittance＜5% is estimated 5 fens, and is opaque fully
Test with said method, last, the following trilaminar transparence evaluating of neutralization of product 1 are 1 fen.
In addition, also product 1 ambient-temp-stable property testing, heat resistant test and freezing-thawing test have been carried out respectively.The ambient-temp-stable property testing is meant to be preserved sample three months between room temperature 20-25 ℃, and heat resistant test promptly refers to sample was preserved three months down at 45 ℃, and freezing-thawing test promptly refers to sample is carried out cold cycling three times under-15 ℃/room temperature condition.As a result, phenomenons such as variable color do not appear in the stratification state when product 1 still keeps testing beginning through above-mentioned any test back outward appearance.Show that thus product 1 is stable.
Embodiment 2
Fill a prescription shown in last table, with all components mix homogeneously, promptly obtain cosmetic composition product 2, this product is not moisture.After leaving standstill 60 minutes, be observed visually this product and have roughly isopyknic three layers, the separating surface between every layer is clear, and from top to bottom, transparence evaluating was respectively 2 minutes, 1 minute and 2 minutes.In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 2 shows that product 2 is stable.
Embodiment 3
Shown in last table, fill a prescription,, promptly obtain cosmetic composition product 3 all components mix homogeneously.After leaving standstill 25 minutes, be observed visually this product and have roughly isopyknic three layers, the separating surface between every layer is clear, and each layer is water white transparency, and transparence evaluating is 1 fen.In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 3 shows that product 3 is stable.
Embodiment 4
Shown in last table, fill a prescription,, promptly obtain cosmetic composition product 4 all components mix homogeneously.After leaving standstill 25 minutes, be observed visually this product and have roughly isopyknic three layers, the separating surface between every layer is clear, and each layer is water white transparency, and transparence evaluating is 1 fen.In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 4 shows that product 4 is stable.
Embodiment 5
Shown in last table, fill a prescription,, promptly obtain cosmetic composition product 5 all components mix homogeneously.After leaving standstill 15 minutes, be observed visually this product and have roughly isopyknic three layers, the separating surface between every layer is clear, and each layer is water white transparency, and transparence evaluating is 1 fen.In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 5 shows that product 5 is stable.
Embodiment 6
Shown in last table, fill a prescription,, promptly obtain cosmetic composition product 6 all components mix homogeneously.After leaving standstill 15 minutes, be observed visually this product and have roughly isopyknic three layers, the separating surface between every layer is clear, and each layer is water white transparency, and transparence evaluating is 1 fen.In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 6 shows that product 6 is stable.
Comparative Examples 7 and embodiment 8-11
According to being respectively the prescription shown in Comparative Examples 7 and the embodiment 8-11 in the last table,, promptly obtain cosmetic composition product 7-11 with all components mix homogeneously of each prescription.
By embodiment 8-11 as can be seen, between the 5-50cps scope, the dimethyl-silicon oil viscosity is high more, and it is just long more that the needed time of obvious separating surface appears in standing demix.Those skilled in the art can expect, mix when forming the polydimethylsiloxane component with the dimethicone of multiple different viscosities, also can realize purpose of the present invention when the comprehensive viscosity of this component is in the 5-50cps scope.When viscosity was lower than 5cps, dimethyl-silicon oil volatility and permeability increased, and system is difficult to form three-decker (seeing Comparative Examples 7).
In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 8-11 shows that product 8-11 is stable.
Embodiment 12
Shown in last table, fill a prescription,, promptly obtain cosmetic composition product 12 all components mix homogeneously.After leaving standstill 60 minutes, be observed visually this product and have roughly isopyknic three layers, the separating surface between every layer is clear, and each layer is water white transparency, and transparence evaluating is 1 fen.In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 12 shows that product 12 is stable.
The non-silicone oil oils and fats of Semi-polarity of the present invention is selectable component, when adopting the lower dimethicone of viscosity, does not contain the polarity oils and fats of the non-silicone oil oils and fats of polarity such as this class of carbonic acid two-ethyl hexyl ester in the oil phase, also can realize branch interval velocity faster.For example, embodiment 12 contains the dimethicone that viscosity is 20cps, the product that contains the dimethicone of 20cps and carbonic acid two-ethyl hexyl ester with embodiment 10 relatively, the former needs 60 minutes, and the latter only needs 15-16 minute.
Embodiment 13-14
According to being respectively the prescription shown in the embodiment 13-14 in the last table,, promptly obtain cosmetic composition product 13-14 with all components mix homogeneously of each prescription.
Found through experiments, greasy polarity is strong more, and it can accelerate to divide interval velocity more.For example embodiment 13 adds the carbonic acid two-ethyl hexyl ester in the stronger PPG-3 myristyl ether alternate embodiment 10 of polarity, then product promptly tangible separating surface can occur leaving standstill in 5 minutes, and needs just to occur in 15-16 minute tangible separating surface among the embodiment 10.The example that the more weak white oil of polarity replaces the carbonic acid two-ethyl hexyl ester among the embodiment 10 is shown in embodiment 14, and the time that its layering needs is then about 25 minutes.
In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 13 and 14 shows that product 13 and 14 is stable.
Embodiment 15-19
According to being respectively the prescription shown in the embodiment 15-19 in the last table,, promptly obtain cosmetic composition product 15-19 with all components mix homogeneously of each prescription.Be observed visually these products and all formed in 15-20 minute and have roughly isopyknic three layers, the separating surface between every layer is clear, and transparence evaluating is 1 fen.In addition, ambient-temp-stable property testing, heat resistant test and the freezing-thawing test to product 15-19 shows that product 15-19 is stable.
Above-mentioned experimental result explanation in order to obtain three coating systems, only has the painted effect of middle one deck, advantageously uses oil-soluble dyes.For example, embodiment 15 and 19 has equally used weld, but oil-soluble D﹠amp; C yellow N ° 11 is only painted to the intermediate layer, and water miscible D﹠amp; C yellow N ° of 5 pairs of lower two layers all have Color.
Above " trace " described in each table be meant: when being less than or equal to 100g for total composition, desire obtains dyeing district's purity and the medium product of lightness, and the use amount of dyestuff is generally less than 0.001g.
Claims (10)
1. cosmetic composition, based on the gross weight of said composition, it comprises following component:
(1) the polydimethylsiloxane component of 20-40wt.%, the viscosity of this component is 5-50cps, is preferably 10-20cps (Bu Shi rotating cylinder viscometer, No. 2 rotors, rotating speed 100rpm, and measurement under 25 ℃);
(2) the amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester component of 10-35wt.%, it is the ester of polyether polyol and alkyl carboxylic acid, wherein the carbon number of polyether polyol structure division and alkyl carboxylic acid structure division is all between 6-20, and the absolute value of the difference of the carbon number of polyether polyol structure division and alkyl carboxylic acid structure division is smaller or equal to 2; And
(3) polyol component of 25-50wt.%.
2. compositions as claimed in claim 1, wherein said amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester component is polyglycereol alkyl carboxylic acid ester, polyoxyethylated alkyl carboxylic acid ester or its mixture, described polyglycereol alkyl carboxylic acid ester is the esters of polyglycereol and fatty acid preferably, and to be more preferably polyglycereol and the carbon number that average degree of polymerization is 3-5 be 8-16, be preferably the polyglyceryl fatty acid ester that the fatty acid esterification of 8-12 obtains; And described polyoxyethylated alkyl carboxylic acid ester is preferably the esters of polyoxyethylene and fatty acid, and polyoxyethylene and the carbon number that is more preferably average degree of polymerization and is 2-8, preferred 5-8 is 6-18, the preferred polyoxyethylene fatty acid ester that obtains of the fatty acid esterification of 8-16.
3. compositions as claimed in claim 2, wherein said amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester be selected from down the group in one or more: polyglycereol-3 decanoin, polyglycereol-4 decanoin, polyglycereol-3 caprylate, polyglycereol-4 laurate, PEG-6 decanoin, PEG-6 laurate, PEG-7 laurate and PEG-7 cocos nucifera oil acid esters.
4. as each described compositions among the claim 1-3, wherein polyol component is glycerol, propylene glycol or its mixture.
5. as each described compositions among the claim 1-4, wherein based on the gross weight of said composition, said composition comprises: the polydimethylsiloxane component of 25-35wt.%, the amphipathic ethoxylated polyhydric alcohol alkyl carboxylic acid ester component of 15-25wt.%, the polyol component of 25-35wt.%, and the water of 10-30wt.%.
6. as each described compositions among the claim 1-5, wherein based on the gross weight of said composition, said composition comprises the water of 15-30wt.%.
7. as each described compositions among the claim 1-6, wherein based on the gross weight of said composition, said composition also comprises the non-silicone oil lubricant component of polarity of 0.1-10wt.%, preferred 0.5-5wt.%.
8. compositions as claimed in claim 7, the non-silicone oil lubricant component of wherein said polarity be selected from down the group in one or more: carbonic acid two-ethyl hexyl ester, tricaprylin, benzoic acid C
12-15Arrcostab, octyldodecanol, PPG-3 myristyl ether, the stearic alcohol ether of PPG-11, PPG-14 butyl ether and the stearic alcohol ether of PPG-15 are preferably carbonic acid two-ethyl hexyl ester or PPG-3 myristyl ether.
9. as each described compositions among the claim 1-8, also contain oil-soluble dyes, these oil-soluble dyes are preferably selected from down group: D﹠amp; C yellow N ° 11 D C Yellow No. 10s, D﹠amp; C green N ° of green, the D﹠amp of 6 solvents; C violet N ° of 2 solvent violet 13 and D﹠amp; C red N ° 17 solvent red 23s.
10. as each described compositions among the claim 1-9, wherein said composition is rocked after the mixing, leave standstill, in 2-60 divides clock time, said composition can spontaneous being divided into have clear interfacial three layers, and each layer all be transparent, and preferably the light transmittance of each layer is more than or equal to 80%.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101408252A CN102058493A (en) | 2009-05-12 | 2009-05-12 | Cosmetic composition |
| DE201010028585 DE102010028585A1 (en) | 2009-05-12 | 2010-05-05 | Multi-phase cosmetic composition |
| JP2010108195A JP2010265265A (en) | 2009-05-12 | 2010-05-10 | Multilayered cosmetic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2009101408252A CN102058493A (en) | 2009-05-12 | 2009-05-12 | Cosmetic composition |
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| CN102058493A true CN102058493A (en) | 2011-05-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2009101408252A Pending CN102058493A (en) | 2009-05-12 | 2009-05-12 | Cosmetic composition |
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| Country | Link |
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| JP (1) | JP2010265265A (en) |
| CN (1) | CN102058493A (en) |
| DE (1) | DE102010028585A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103845231A (en) * | 2012-12-04 | 2014-06-11 | 拜尔斯道夫股份有限公司 | Shampoo conditioning composition containing PPG-3 octyl ether |
| CN104771333A (en) * | 2015-04-24 | 2015-07-15 | 广州市科能化妆品科研有限公司 | Preservative-free make-up removal composition and preparation method thereof |
| TWI610689B (en) * | 2013-04-26 | 2018-01-11 | 資生堂股份有限公司 | Aqueous compound |
| CN112336639A (en) * | 2020-11-03 | 2021-02-09 | 前研化妆品科技(上海)有限公司 | Four-layer low-viscosity liquid cosmetic without perfluorinated compounds |
| CN114903800A (en) * | 2021-07-22 | 2022-08-16 | 楚雅化妆品(上海)有限公司 | Three-layer hair care composition and preparation method thereof |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6591960B2 (en) * | 2013-03-15 | 2019-10-16 | クローダ，インコーポレイティド | Alkoxylated fatty alcohol alkyl ethers and products containing the same |
| FR3004641B1 (en) * | 2013-04-17 | 2016-01-15 | Oreal | COSMETIC COMPOSITION COMPRISING A CUCURBIC ACID COMPOUND AND OXYALKYLENE POLY (POLY) OIL |
| US20160367959A1 (en) * | 2015-06-18 | 2016-12-22 | Avon Products, Inc. | Multiphase Compositions |
| WO2020016949A1 (en) * | 2018-07-18 | 2020-01-23 | 太陽化学株式会社 | Cleansing cosmetic composition |
| CN111686025A (en) * | 2020-04-24 | 2020-09-22 | 丽鑫生技化妆品（上海）有限公司 | Three-layer cleansing lotion and preparation method thereof |
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| CN101181185A (en) * | 2006-10-06 | 2008-05-21 | 戈尔德施米特有限公司 | Cosmetic emulsions manufactured at low temperature, with low viscosity and long-term stability, with coemulgators containing cationic groups |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04290810A (en) * | 1991-03-18 | 1992-10-15 | Kurooda Japan Kk | Theree-layered cosmetic |
| JPH10101529A (en) * | 1996-09-24 | 1998-04-21 | Shiseido Co Ltd | Multiphase separation type cleaning agent |
| JP2929372B2 (en) * | 1996-10-29 | 1999-08-03 | インターナショナル・トイレツリース株式会社 | Multilayer separation liquid substrate |
-
2009
- 2009-05-12 CN CN2009101408252A patent/CN102058493A/en active Pending
-
2010
- 2010-05-05 DE DE201010028585 patent/DE102010028585A1/en not_active Withdrawn
- 2010-05-10 JP JP2010108195A patent/JP2010265265A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101181185A (en) * | 2006-10-06 | 2008-05-21 | 戈尔德施米特有限公司 | Cosmetic emulsions manufactured at low temperature, with low viscosity and long-term stability, with coemulgators containing cationic groups |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103845231A (en) * | 2012-12-04 | 2014-06-11 | 拜尔斯道夫股份有限公司 | Shampoo conditioning composition containing PPG-3 octyl ether |
| CN103845231B (en) * | 2012-12-04 | 2017-06-20 | 拜尔斯道夫股份有限公司 | Shampoo conditioning composition containing PPG-3 octyl ether |
| TWI610689B (en) * | 2013-04-26 | 2018-01-11 | 資生堂股份有限公司 | Aqueous compound |
| CN104771333A (en) * | 2015-04-24 | 2015-07-15 | 广州市科能化妆品科研有限公司 | Preservative-free make-up removal composition and preparation method thereof |
| CN112336639A (en) * | 2020-11-03 | 2021-02-09 | 前研化妆品科技(上海)有限公司 | Four-layer low-viscosity liquid cosmetic without perfluorinated compounds |
| CN114903800A (en) * | 2021-07-22 | 2022-08-16 | 楚雅化妆品(上海)有限公司 | Three-layer hair care composition and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102010028585A1 (en) | 2010-12-02 |
| JP2010265265A (en) | 2010-11-25 |
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