CN112336639A - Four-layer low-viscosity liquid cosmetic without perfluorinated compounds - Google Patents

Four-layer low-viscosity liquid cosmetic without perfluorinated compounds Download PDF

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CN112336639A
CN112336639A CN202011207076.3A CN202011207076A CN112336639A CN 112336639 A CN112336639 A CN 112336639A CN 202011207076 A CN202011207076 A CN 202011207076A CN 112336639 A CN112336639 A CN 112336639A
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池水兴
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Qianyan Cosmetics Technology Shanghai Co ltd
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Qianyan Cosmetics Technology Shanghai Co ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/03—Liquid compositions with two or more distinct layers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/10—General cosmetic use
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients

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  • Cosmetics (AREA)

Abstract

The invention discloses a four-layer low-viscosity liquid cosmetic without perfluorinated compounds, which comprises four layers of liquid phase bodies, namely an A liquid phase body, a B liquid phase body, a C liquid phase body and a D liquid phase body; the liquid phase A is a carbon chain alkane solvent with the mass percentage of 5-55%; the liquid phase B is polydimethylsiloxane and derivatives thereof with the mass percentage of 5-55%; the C liquid phase is a hydroalcoholic solvent with the mass percent of 5-55%; the D liquid phase is 1-35% of special oil ester by mass percent; the invention adopts common cosmetic raw materials, and aims to provide the four-layer low-viscosity liquid cosmetic which has no physical separation in the middle and still has a clear layered interface between layers, wherein the layers are mixed after shaking, can be quickly restored to a four-layer clear layered state after standing, continuously keeps a stable clear interface and has no oil drop wall hanging phenomenon after layering; according to different proportions of the raw materials, the skin care or cleaning effects such as moisture retention, moistening, makeup removal and the like can be provided.

Description

Four-layer low-viscosity liquid cosmetic without perfluorinated compounds
Technical Field
The invention relates to the field of cosmetics, in particular to a four-layer low-viscosity liquid cosmetic free of perfluorinated compounds.
Background
The low-viscosity liquid cosmetics on the market are generally uniform and integrated, only a small part of the low-viscosity liquid cosmetics are two-layer, and few three-layer low-viscosity liquid cosmetics exist, but no four-layer low-viscosity liquid cosmetic product is sold. However, in the four-layer liquid cosmetic patents which have been applied and researched in the prior art, perfluorinated organic compound solvents with high density are used as important components, and the application of perfluorinated compounds has two small defects:
firstly, the method comprises the following steps: the perfluorinated compounds are not readily decomposed naturally and are therefore considered safe at the outset. After intensive research, the situation is not found to be the case. After being absorbed by human body, the sustained time in the body is very long, the half life can be more than 4 years to 8 years, and the harm to the health of the human body can be caused. Meanwhile, the oil-repellent and water-repellent characteristics of the paint can exist stably for a long time in the environment, and the environmental pollution problem of the paint is more and more interesting to society.
II, secondly: the perfluoro compound is quickly volatilized when the environmental temperature is slightly high due to the characteristic of low boiling point, and when a product containing the raw material is prepared, the preparation process and the environmental temperature have special requirements, the preparation is required to be carried out at the temperature of 20 ℃ or below, and meanwhile, the stirring speed needs to be controlled, so that the perfluoro compound is more complicated and inconvenient, and has larger challenges to large-scale production.
Therefore, further improvement is required in such four-layer low-viscosity liquid type cosmetic products.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides a four-layer low-viscosity liquid cosmetic without containing a perfluoro compound.
In order to achieve the purpose, the invention adopts the following technical scheme:
a four-layer low viscosity liquid cosmetic containing no perfluoro compounds comprises four layers of liquid phase including liquid A, liquid B, liquid C, and liquid D; the liquid phase A is a carbon chain alkane solvent with the mass percentage of 5-55%; the liquid phase B is polydimethylsiloxane and derivatives thereof with the mass percentage of 5-55%; the C liquid phase is a hydroalcoholic solvent with the mass percent of 5-55%; the D liquid phase is 1-35% of special oil ester by mass percent.
Preferably, the phase A liquid is one or more of polyisobutylene, hydrogenated polyisobutylene, polydecene, hydrogenated polydecene, isopropyl myristate, isooctane, isodecane, isododecane, isohexadecane, isoeicosane and mineral oil.
Preferably, the B liquid is one or more of liquid polydimethylsiloxane with the viscosity of 1-500cst and cyclomethicone.
Preferably, the C liquid phase is a mixture of more than one of water, propylene glycol, dipropylene glycol, glycerol, butanediol, pentanediol, hexanediol, polyglycerol with a polymerization degree of 3-10, and polyethylene glycol with a polymerization degree of 4-32.
Preferably, the D liquid phase is one or more of PEG-n glycerin fatty acid ester, PEG-n fatty acid ester, polyglycerol fatty acid ester, polysorbate-n, PEG-n castor oil, alkyl glycoside and other nonionic surfactants, and part of phenyl silicone oil, diethoxyethyl succinate and other special oil esters.
Preferably, pigments with different colors are added into at least two groups of the components of the A liquid phase, the B liquid phase, the C liquid phase and the D liquid phase, and the added pigments are oil-soluble pigments or water-soluble pigments commonly used in cosmetics, and the dosage of the added pigments accounts for 0.0001-0.001% of the total mass of the corresponding phases.
Preferably, the preparation method of the cosmetic comprises the following steps: s1 is prepared in a split manner; selecting the raw materials, and respectively preparing the liquid phase A, the liquid phase B, the liquid phase C and the liquid phase D; s2 mixing and preparing; mixing the prepared liquid A, liquid B, liquid C and liquid D at room temperature, and stirring for 30min to obtain the final product.
The invention has the beneficial effects that: the invention adopts common cosmetic raw materials, and aims to provide the four-layer low-viscosity liquid cosmetic which has no physical separation in the middle and still has a clear layering interface between layers. According to different proportions of the raw materials, the skin care or cleaning effects such as moisture retention, moistening, makeup removal and the like can be provided.
Drawings
FIG. 1 is a schematic view of a liquid-separating layer structure of the cosmetic of the present invention;
FIG. 2 is a table showing the ratios of liquid phase A in examples one to nine;
FIG. 3 is a table showing the ratios of liquid phases in examples B to B;
FIG. 4 is a table showing the ratios of the liquid phase C in examples one to nine;
FIG. 5 is a table showing the ratios of the liquid phase D in examples one to nine;
FIG. 6 is a table showing the liquid phase A in examples ten to thirteen;
FIG. 7 is a table showing the liquid phases of B in examples ten to thirteen;
FIG. 8 is a table showing the liquid phases of C in examples ten to thirteen;
FIG. 9 is a table showing the liquid phase ratios of D in examples ten to thirteen;
FIG. 10 is a table of efficacy results for the final liquids of examples one to thirteen.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
Referring to fig. 1 to 10, a four-layer low viscosity liquid cosmetic containing no perfluoro-compound comprises four layers of liquid phase, namely liquid phase A, liquid phase B, liquid phase C and liquid phase D; the liquid phase A is a carbon chain alkane solvent with the mass percentage of 5-55 percent; the liquid phase B is polydimethylsiloxane and derivatives thereof with the mass percentage of 5-55 percent; the C liquid phase is a hydroalcoholic solvent with the mass percent of 5-55%; the liquid phase D is special oil ester with the mass percent of 1-35%.
In this embodiment, the phase a liquid is one or more of polyisobutylene, hydrogenated polyisobutylene, polydecene, hydrogenated polydecene, isopropyl myristate, isooctane, isodecane, isododecane, isohexadecane, isoeicosane, and mineral oil.
In this embodiment, the liquid phase B is a mixture of one or more of liquid polydimethyl siloxane and cyclopolydimethyl siloxane with viscosity of 1-500 cst.
In this example, the liquid C is a mixture of at least one of water, propylene glycol, dipropylene glycol, glycerin, butylene glycol, pentanediol, hexylene glycol, polyglycerin having a polymerization degree of 3 to 10, and polyethylene glycol having a polymerization degree of 4 to 32.
In this embodiment, the liquid phase D is a mixture of one or more of nonionic surfactants such as PEG-n glycerides, PEG-n fatty acid esters, polyglycerol fatty acid esters, polysorbate-n surfactants, PEG-n castor oils, and alkyl glycosides, and special oil esters such as partially phenyl silicone oil and diethoxyethyl succinate.
In this embodiment, pigments with different colors are added to at least two groups of the liquid phase A, the liquid phase B, the liquid phase C and the liquid phase D, and the added pigments are oil-soluble pigments or water-soluble pigments commonly used in cosmetics, and the amount of the added pigments accounts for 0.0001-0.001% of the total mass of the corresponding phase.
In this example, the preparation method of the cosmetic of the present invention comprises the following steps: s1 is prepared in a split manner; selecting the raw materials, and respectively preparing the liquid phase A, the liquid phase B, the liquid phase C and the liquid phase D; s2 mixing and preparing; mixing the prepared liquid A, liquid B, liquid C and liquid D at room temperature, and stirring for 30min to obtain the final product.
The following examples are given by using specific ingredients, and the efficacy evaluation of the finished liquids obtained in examples one to nine, namely, the evaluation of the skin feel (smooth and easy to apply), the moisturizing effect and the makeup removing ability, is performed.
Example one
The phase A comprises the following components: 3g of hydrogenated polyisobutene, 2g of isopropyl myristate and 0.0004g of pigment.
The phase B comprises the following components: 1g of polydimethylsiloxane (1cst), 1g of polydimethylsiloxane (10cst), 1g of polydimethylsiloxane (100cst), 1g of polydimethylsiloxane (350cst) and 1g of cyclotetrasiloxane.
The phase C comprises the following components: 5g of 1, 3-propanediol, 5g of 1, 2-propanediol, 10g of dipropylene glycol, 5g of glycerol, 8g of 1, 3-butanediol, 1g of pentanediol, 1g of hexanediol and 0.0003g of pigment.
The phase D comprises the following components: 24.9993g of PEG-7 glyceryl cocoate, 10g of PEG-6 caprylic/capric glycerides, 10g of PEG-7 caprylic/capric glycerides and 10g of diethoxyethyl succinate.
Stirring the A, B, C, D four phases at room temperature, mixing, standing completely to obtain four layers of low viscosity liquid cosmetic with clear layers. After being shaken up, the skin care lotion can be used as four layers of skin care essence water or four layers of makeup removing lotion.
Example two
The phase A comprises the following components: 2g of polyisobutene, 1g of isooctane, 1g of isodecane and 1g of isododecane.
The phase B comprises the following components: 1g of polydimethylsiloxane (5cst), 1g of polydimethylsiloxane (50cst), 1g of polydimethylsiloxane (500cst), 1g of cyclopentadimethylsiloxane and 1g of cyclohexasiloxane.
The phase C comprises the following components: 10g of water, 4.9993g of polyglycerol-3, 10g of polyglycerol-10, 10g of polyethylene glycol-4, 10g of polyethylene glycol-10, 10g of polyethylene glycol-32 and 0.0003g of pigment.
The phase D comprises the following components: 5g of PEG-7 glycerol cocoate, 5g of trimethyl pentaphenyl trisiloxane, 5g of tetramethyl tetraphenyl trisiloxane and 10g of trimethyl silanoxyl phenyl polydimethylsiloxane.
EXAMPLE III
The phase A comprises the following components: 5g of polyisobutene, 5g of hydrogenated polyisobutene, 1g of polydecene, 1g of hydrogenated polydecene, 1g of isopropyl myristate, 1g of isohexadecane, 0.998g of isoeicosane, 5g of No. 26 white oil and 0.002g of pigment.
The phase B comprises the following components: 10g of polydimethylsiloxane (1cst), 10g of polydimethylsiloxane (5cst), 10g of polydimethylsiloxane (100cst), 10g of cyclotetramethylsiloxane and 10g of cyclopentyldimethicone.
The phase C comprises the following components: 2.99998g of dipropylene glycol and 0.00002g of pigment.
The phase D comprises the following components: 15g of PEG-7 glyceryl cocoate, 5g of PEG-6 caprylic/capric glycerides and 5g of diethoxyethyl succinate.
Example four
The phase A comprises the following components: 10g of hydrogenated polyisobutene, 4.998g of isododecane, 10g of No. 7 white oil, 10g of No. 10 white oil, 10g of No. 15 white oil, 10g of No. 26 white oil and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (100cst), 5g of polydimethylsiloxane (350cst) and 10g of cyclotetrasiloxane.
The phase C comprises the following components: 3g of water, 17g of dipropylene glycol and 0.0001g of pigment.
The phase D comprises the following components: 0.9999g of PEG-7 glycerol cocoate and 4g of diethoxyethyl succinate.
EXAMPLE five
The phase A comprises the following components: 5g of polyisobutene, 9.998g of isopropyl myristate, 10g of isohexadecane and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (1cst), 10g of polydimethylsiloxane (10cst), 5g of polydimethylsiloxane (350cst) and 5g of cyclotetrasiloxane.
The phase C comprises the following components: 5g of water, 5g of dipropylene glycol, 10g of glycerol, 5g of polyethylene glycol-4 and 0.0001g of pigment.
The phase D comprises the following components: 10g of PEG-7 glyceryl cocoate, 10g of PEG-6 caprylic/capric glycerides and 4.9999g of PEG-7 caprylic/capric glycerides.
EXAMPLE six
The phase A comprises the following components: 10g of hydrogenated polydecene, 4.998g of isodecane, 5g of No. 15 white oil and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (5cst), 5g of polydimethylsiloxane (50cst), 5g of polydimethylsiloxane (100cst), and 10g of polydimethylsiloxane (350 cst).
The phase C comprises the following components: 10g of 1, 2-propylene glycol, 5g of glycerol, 4.9999g of 1, 3-butanediol, 5g of pentanediol, 5g of polyglycerol-3, 5g of polyethylene glycol-10 and 0.0001g of pigment.
The phase D comprises the following components: 5g of PEG-6 caprylic/capric glycerides, 5g of PEG-7 caprylic/capric glycerides, 5g of trimethylpentaphenyltrisiloxane and 5g of tetramethyltetraphenyltriphenyltrisiloxane.
EXAMPLE seven
The phase A comprises the following components: 5g of isooctane, 4.998g of isohexadecane, 15g of No. 26 white oil and 0.002g of pigment.
The phase B comprises the following components: 10g of polydimethylsiloxane (100cst) and 20g of polydimethylsiloxane (350 cst).
The phase C comprises the following components: 20g of dipropylene glycol, 5g of glycerol and 0.0001g of pigment.
The phase D comprises the following components: 14.9999g of PEG-7 glyceryl cocoate and 10g of PEG-6 caprylic/capric glycerides.
Example eight
The phase A comprises the following components: 4.998g of hydrogenated polyisobutene, 5g of isododecane, 15g of No. 26 white oil and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (5cst), 20g of polydimethylsiloxane (350cst) and 5g of cyclohexasiloxane.
The phase C comprises the following components: 10g of dipropylene glycol, 9.9999g of glycerol and 0.0001g of pigment.
The phase D comprises the following components: : 4g of PEG-7 glyceryl cocoate, 1g of PEG-20 glyceryl tristearate, 10g of trimethyl pentaphenyl trisiloxane and 10g of tetramethyl tetraphenyl trisiloxane.
Example nine
The phase A comprises the following components: 5g of hydrogenated polydecene, 5g of isododecane, 5g of isohexadecane, 5g of isoeicosane, 4.998g of No. 15 white oil and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (10cst), 20g of polydimethylsiloxane (350cst) and 5g of polydimethylsiloxane (500 cst).
The phase C comprises the following components: 2g of water, 7.9999g of 1, 2-propylene glycol, 10g of dipropylene glycol, 5g of glycerol and 0.0001g of pigment.
The phase D comprises the following components: 5g of trimethylpentaphenyltrisiloxane, 5g of tetramethyltetraphenyltriphenylsiloxane, 5g of trimethylsiloxyphenylpolydimethylsiloxane and 5g of diethoxyethyl succinate.
Example ten
The phase A comprises the following components: 4.998g of hydrogenated polyisobutene, 5g of isodecane, 15g of No. 26 white oil and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (5cst) and 20g of polydimethylsiloxane (350 cst).
The phase C comprises the following components: 10g of dipropylene glycol, 9.9999g of glycerol and 0.0001g of pigment.
The phase D comprises the following components: 3g of PEG-7 glyceryl cocoate, 0.5g of PEG-8 diisostearate, 0.5g of PEG-12 diisostearate, 0.5g of PEG-10 isostearate and 0.5g of PEG-12 laurate.
EXAMPLE eleven
The phase A comprises the following components: 4.998g of hydrogenated polyisobutene, 5g of isododecane, 15g of No. 26 white oil and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (5cst) and 20g of polydimethylsiloxane (350 cst).
The phase C comprises the following components: 10g of dipropylene glycol, 9.9999g of glycerol and 0.0001g of pigment.
The phase D comprises the following components: 1g of PEG-7 glyceryl cocoate, 2g of PEG-6 caprylic/capric glycerides, 0.5g of polyglycerol-10 dioleate, 0.5g of polyglycerol-6-didecanoate, 0.5g of polyglycerol-2-oleate, 0.5g of polyglycerol-2-isostearate, 5g of trimethylpentaphenyltrisiloxane, 15g of tetramethyltetraphenyltriphenylsiloxane and 100g of diethoxyethyl succinate.
Example twelve
The phase A comprises the following components: 4.998g of hydrogenated polyisobutene, 5g of isododecane, 15g of No. 26 white oil and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (5cst) and 20g of polydimethylsiloxane (350 cst).
The phase C comprises the following components: 10g of dipropylene glycol, 9.9999g of glycerol and 0.0001g of pigment.
The phase D comprises the following components: 1g of PEG-7 glyceryl cocoate, 1g of PEG-6 caprylic/capric glycerides, 0.5g of polysorbate-85, 0.5g of polysorbate-21, 0.5g of polysorbate-20, 0.5g of polysorbate-40, 0.5g of polysorbate-60 and 0.5g of PEG-20 sorbitan isostearate.
EXAMPLE thirteen
The phase A comprises the following components: 4.998g of hydrogenated polyisobutene, 5g of isododecane, 15g of No. 26 white oil and 0.002g of pigment.
The phase B comprises the following components: 5g of polydimethylsiloxane (5cst) and 20g of polydimethylsiloxane (350 cst).
The phase C comprises the following components: 10g of dipropylene glycol, 9.9999g of glycerol and 0.0001g of pigment.
The phase D comprises the following components: 1g of PEG-6 caprylic/capric glycerides, 1g of PEG-7 hydrogenated castor oil, 1g of PEG-40 hydrogenated castor oil, 1g of PEG-60 hydrogenated castor oil, 1g of decyl glucoside, 15g of trimethylpentaphenyl trisiloxane, 5g of tetramethyltetraphenyl trisiloxane and 100g of diethoxyethyl succinate.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (7)

1. A four-layer low viscosity liquid cosmetic without perfluor compound is characterized by comprising four layers of liquid phase bodies, namely an A liquid phase body, a B liquid phase body, a C liquid phase body and a D liquid phase body; the liquid phase A is a carbon chain alkane solvent with the mass percentage of 5-55%; the liquid phase B is polydimethylsiloxane and derivatives thereof with the mass percentage of 5-55%; the C liquid phase is a hydroalcoholic solvent with the mass percent of 5-55%; the D liquid phase is 1-35% of special oil ester by mass percent.
2. The four-layer low viscosity liquid cosmetic composition according to claim 1, wherein the phase A liquid is one or more selected from the group consisting of polyisobutylene, hydrogenated polyisobutylene, polydecene, hydrogenated polydecene, isopropyl myristate, isooctane, isodecane, isododecane, isohexadecane, isoeicosane, and mineral oil.
3. The four-layer low viscosity liquid cosmetic composition according to claim 1, wherein the liquid phase B is a mixture of one or more of liquid polydimethyl siloxane and cyclomethicone having a viscosity of 1-500 cst.
4. The four-layer low viscosity liquid cosmetic composition according to claim 1, wherein the C liquid phase is a mixture of at least one of water, propylene glycol, dipropylene glycol, glycerin, butylene glycol, pentylene glycol, hexylene glycol, polyglycerin having a polymerization degree of 3 to 10, and polyethylene glycol having a polymerization degree of 4 to 32.
5. The four-layer low viscosity liquid cosmetic composition according to claim 1, wherein the liquid phase D is a mixture of one or more of PEG-n glyceryl fatty acid esters, PEG-n fatty acid esters, polyglyceryl fatty acid esters, polysorbate-n nonionic surfactants, PEG-n castor oils, alkyl glycosides and other nonionic surfactants, and specific oil esters such as partially phenyl silicone oil and diethoxyethyl succinate.
6. The four-layer low viscosity liquid cosmetic composition according to claim 1, wherein pigments of different colors are added to at least two of the components of the liquid phase A, the liquid phase B, the liquid phase C and the liquid phase D, and the added pigments are oil-soluble pigments or water-soluble pigments commonly used in cosmetics, and the amount of the added pigments is 0.0001 to 0.001% by mass of the total mass of the corresponding phase.
7. The perfluorochemical-free four-layer low viscosity liquid cosmetic composition according to claim 1, which is prepared by a method comprising the steps of:
s1 is prepared in a split manner; selecting the raw materials, and respectively preparing the liquid phase A, the liquid phase B, the liquid phase C and the liquid phase D;
s2 mixing and preparing; mixing the prepared liquid A, liquid B, liquid C and liquid D at room temperature, and stirring for 30min to obtain the final product.
CN202011207076.3A 2020-11-03 2020-11-03 Four-layer low-viscosity liquid cosmetic without perfluorinated compounds Pending CN112336639A (en)

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JPH10130125A (en) * 1996-10-29 1998-05-19 Internatl Toiretsu Lease Kk Multilayered separated liquid substrate
US20030003069A1 (en) * 2001-04-04 2003-01-02 Carson John C. Multiple phase foaming personal cleansing products
KR20090004050A (en) * 2007-07-06 2009-01-12 한국콜마 주식회사 Cosmetic composition for cleansing having 4 layered structure and manufacturing method thereof
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